Fragrance having a cyclopropyl structure

Abstract

Formula (I) R 1 -R 2 (I) [wherein, R 1 represents a cyclopropyl or C1-C6-alkylcyclopropyl group; R 2 represents -CO-R 3 or -(CH2) n -R 4 group; R 3 represents a linear or branched C1-C6 alkyl; R 4 represents -CH2OH or -CH=O; and -n represents an integer of 1 to 12] A cyclopropyl derivative satisfying is proposed. The derivative is characterized by a very strong fragrance, but the fragrance also varies greatly depending on its structure.

Description

Technical Field

[0001] Field of the Invention The present invention relates to the field of fragrances and perfumery and to new fragrances having a cyclopropyl structure.

Background Art

[0002] Background of the Invention In the fragrance industry, the creation of new fragrances is always in demand. However, the creation of new fragrances or fragrance compositions involves many challenges. For example, in order to meet specific market needs and provide a product that matches a specific profile sought by customers, it is necessary to select specific configurations of a small number of fragrances from a virtually infinite number of possible structures known from the prior art. While appropriate fragrances exhibit very beneficial performance, when combined with other fragrances, they can generate unpleasant and thereby harmful odor characteristics, which can make them difficult or impossible to use for specific purposes.

[0003] The second important issue relates to the need to provide fragrance compositions that not only match a specific odor profile but also possess so-called secondary beneficial properties. In fact, many fragrance compositions known in the market have significant drawbacks in use, such as low solubility and storage stability, as well as subjective problems such as richness and charisma. Furthermore, many known fragrance compositions require high dosages to obtain desirable odor results. Another requirement for fragrances today is to have high biodegradability as well as dermatological and toxicological safety. As a result, there is a particularly high demand for fragrances that can have a significant impact on other fragrance products even at low dosages, rather changing an unpleasant odor impression into a positive one and / or enhancing a pleasant odor impression.

[0004] Related Prior Art Several cyclopropyl derivatives are known, for example:

[0005] U.S. Patent 2008103085 AA (GIVAUDAN) relates to 5-(2,2-dimethyl-cyclopropyl)-3-methyl-pent-2-enenitrile and its use in fragrance or flavor applications.

[0006] U.S. Patent 20111124924 AA (GIVAUDAN) discloses a process for the preparation of cyclopropylcarbinol by cyclopropanation of unsaturated alcoholates using a reagent system selected from (A) magnesium metal and dibromomethane, and (B) dibromomethane and a tertiary Grignard reagent, and carrying out the reaction in the presence of an ether solvent. The product is useful as a flavor and fragrance.

[0007] U.S. Patent 6,025,527 B (IFF) relates to trimethylcyclohexenylcyclopropyl ketone having a structure in which one of the dashed lines is a carbon-carbon double bond and the other dashed line is a carbon-carbon single bond, and their use for enhancing, intensifying or imparting fragrance in, or to, fragrance compositions, colognes and scented articles, and mixtures that are homogenous with 3-methyl-1-phenylpentanol-5 and / or butanoylcyclohexane derivatives and / or acetic or propionic esters of o-methylphenylisopropanol.

[0008] U.S. Patent 5,767,305 A and U.S. Patent 7,074,967 BA (IFF) disclose cyclopropylcarboxylic acid esters and 3-cyclopropyl-1-propanone compounds as fragrances

[0009] Chinese Patent Application Publication No. 101503345 A (SHANGHAI INST TECHNOLOGY) discloses 2-(2-ethyl-cyclopropyl)aldehyde and a preparation method.

Prior Art Documents

Patent Documents

[0010]

Patent Document 1

Patent Document 2

Patent Document 3

Patent Document 4

Patent Document 5

Summary of the Invention

Problems to be Solved by the Invention

[0011] Object of the Invention Thus, the fundamental problem of the present invention was to provide a new group of fragrances having the additional ability to enhance the positive and beneficial characteristics of other fragrances. In particular, the new fragrances should also be characterized by an improvement in the stability, solubility and overall performance of other fragrances, as well as by a reduction in the required dosage. Furthermore, the new fragrances should be renewable and stable. Finally, the fragrance composition itself should have excellent biodegradability and be harmless to humans and the environment.

Modes for Carrying Out the Invention

[0012] Brief Description of the Invention The first object of the present invention is the following formula (I) R 1 -R 2 (I) [Wherein, ·R 1 represents a cyclopropyl or C1-C6-alkylcyclopropyl group; ·R 2 represents -CO-R 3 or -(CH2) n -R 4 group; ·R 3 represents a linear or branched C1-C6 alkyl; ·R 4 represents -CH2OH or -CH=O; and ·n represents an integer from 1 to 12] relates to a cyclopropyl derivative satisfying the following.

[0013] Surprisingly, it has been found that the cyclopropyl derivatives of the present invention exhibit very strong fragrance notes that vary greatly in structure, such as fresh like mint, nutty, and green. The derivatives of formula I are useful for imparting, modifying, and / or enhancing the positive characteristics of fragrances, particularly for making them rounder, more natural, more voluminous, clearer, fresher, stronger, and / or more fruity. In addition to the first property, i.e., the olfactory property, the derivatives of formula I further have positive second properties, in particular, high persistence compared to fragrances with similar olfactory properties, as well as high stability, high diffusibility, and biodegradability in certain media and preparations. Furthermore, the new cyclopropyl derivatives have been found to be useful for increasing the strength of fragrance mixtures. Accordingly, the compounds described herein can be used to impart roundness, naturalness, volume, transparency, freshness, strength, and / or fruitiness to fragrance compositions.

[0014] Cyclopropyl derivative Preferred derivatives according to the present invention are either cyclopropyl derivatives or methylcyclopropyl derivatives.

[0015] In the first option, the cyclopropyl derivatives according to the invention can be obtained by cyclopropanation of each olefin structure, known as the Johnson-Corey-Chaykovsky reaction. This reaction involves adding a sulfur ylide to a ketone, aldehyde, imine, or enone to form the corresponding three-membered ring. This reaction is diastereoselective and favors the trans substitution of the product as shown in the following general scheme, regardless of the initial stereochemistry: [Chemical formula]

[0016] This reaction is described in more detail in the report “The complexity of catalysis: origins of enantio- and diastereocontrol in sulfur ylide mediated epoxidation reactions” by Aggarwal et al. in Chemical Communications (21, p2644 - 2651 (2003)).

[0017] In the second option, the derivative can also be obtained by the Simmons-Smith reaction, an organotropic reaction involving an organozinc carbenoid that reacts with an alkene (or alkyne) to form a cyclopropane. A methylene free radical intermediate is delivered simultaneously to both carbons of the alkene, and thus the configuration of the double bond is preserved in the product and the reaction is stereospecific. This method is shown in the following figure: [Chemical formula]

[0018] The Simmons-Smith reaction is generally preferred over other cyclopropanation methods, but it can be expensive due to the high cost of diiodomethane. Improvements have been developed that include cheaper alternatives such as dibromomethane or diazomethane and zinc iodide. The reactivity of the system can also be enhanced by the Furukawa method of replacing the zinc-copper couple with diethylzinc. This reaction is described in more detail in two papers: “A new synthesis of cyclopropanes from olefins” by Simmons et al., JACS 80(19), p5323-5324 (1958) and “A new synthesis of cyclopropanes” by Smith et al., JACS 81(16), p4256-4264(1959).

[0019] Preferred species include (a) R 2 which is a straight-chain or branched alkyl group having 3 or 4 carbon atoms -CO-R 3 and R 3 which is preferably obtained by the Johnson-Corey-Chaikovskii reaction, or (b) R 2 which is -(CH2) n -R 4 where R 4 represents -CH=O and n represents an integer from 8 to 10, and is preferably obtained by the Simmons-Smith reaction, Derivatives of formula (I) are included.

[0020] Cyclopropyl derivatives according to formula (II), (III) or (IV)

Chemical formula

[0021] Manufacturing method Another object of the present invention is using the Johnson-Corey-Chaikovskii reaction, the following formula (I) R 1 -R 2(I) [In the formula, ·R 1 represents a cyclopropyl or C1-C6-alkylcyclopropyl group; ·R 2 represents a -CO-R 3 group; and ·R 3 represents a linear or branched C1-C6 alkyl] A first method for obtaining a cyclopropyl derivative satisfying the following formula (V) CH3-CH=CH-R 2 (V) [In the formula, R 2 has the same meaning as above] An enone satisfying - is subjected to cyclopropanation in the presence of a sulfur ylide having the + structure [In the formula, Hal represents bromine, chlorine or iodine] . The method is preferably carried out in the presence of DMSO and sodium hydride to form a methylsulfinyl carbanion (dimsulfylanion ion) that acts as a strong nucleophile. The reaction may be carried out in the presence or absence of an aprotic solvent. However, preferred solvents are DCM or chloroform.

[0022] Another object of the present invention is By using the Simmons-Smith reaction, the following formula (I) R 1 -R 2 (I) [In the formula, ·R 1 represents a cyclopropyl or C1-C6-alkylcyclopropyl group; ·R 2 represents a -(CH2) n -R 4 group; ·R 4 represents -CH2OH or -CH=O; and ·n represents an integer from 1 to 12] ​A second method for obtaining a cyclopropyl derivative satisfying (a) In a first step, the following formula (VI) CH2=CH-(CH2) n -CH2OH [wherein n has the same meaning as above] An ω-unsaturated fatty alcohol satisfying is subjected to cyclopropanation in the presence of an organozinc carbenoid having a Hal-ZnCH2-Hal structure [wherein Hal represents bromine, chlorine or preferably iodine] and optionally (b) The hydroxyl group of the reaction product obtained from step (i) is subjected to oxidation to form an aldehyde group.

[0023] The carbenoid is typically obtained from the reaction of zinc with a methylene halide such as CH2I2. The reaction may be carried out in the presence or absence of an aprotic solvent. However, preferred solvents are DCM or chloroform. Oxidizing the terminal hydroxyl group to form an aldehyde functional group can be carried out with any suitable oxidizing agent. However, the following scheme is particularly recommended:

Chemical formula

[0024] In this reaction, a hypervalent iodine reagent similar to IBX is used to selectively and gently oxidize an alcohol to an aldehyde or ketone. This reaction is usually carried out in a chlorine-based solvent such as dichloromethane or chloroform. The reaction can be carried out at room temperature and is completed immediately. Many other functional groups are not affected by this reaction.

[0025] Flavor mixture Another object of the present invention relates to a fragrance mixture comprising, as a first fragrance, a cyclopropyl derivative as defined above, and at least one second fragrance different from the first fragrance. The second fragrance can be selected from the group consisting of: · [(3,7-dimethyl-6-octenyl)-xy]-cetaldehyde, · 1-(p-menthen-6(2)-yl)-1-propanone, · 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, · 10-undecen-1-al, · 10-undecen-1-ol, · 1-decanal, · 1-dodecanal, · 1-methyl-3-(4-methylpentyl)-3-cyclohexenecarboxaldehyde, · 1-methyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde, · 1-nonanal, · 1-octanal, · 1-octen-3-ol, · 1-p-menthene-q-carboxaldehyde, · 1-undecanal, · 2-(2-(4-methyl-3-cyclohexen-1-yl)propyl)cyclopentanone, · 2,4,4,7-tetramethyl-oct-6-en-3-one, · 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, · 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde 4-methoxybenzaldehyde, · 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde, · 2,6,10-trimethyl-5,9-undecadienal, · 2,6,10-Trimethyl-9-undecenal, 3-dodecen-1-al, · 2,6-Dimethyl-5-heptenal; · 2,6-Dimethylhept-5-en-1-al, · 2,6-Dimethylheptan-2-ol, · 2,6-Nonadienal, · 2-Acetyl-3,3-di-methyl-norbornane, · 2-Methyldecanal, · 2-Methyloctanal, · 2-Methylundecanal, · 2-Methyl-3-(4-tert-butyl) propanal, · 2-Methyl-3-(isopropyl-phenyl) propanal, · 2-Methyl-3-(para-methoxy-phenylpropanal), · 2-Methyl-3-phenyl-2-propen-1-al, · 2-Methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal, · 2-Methylbutanol, · 2-Methylpentanol, · 2-Phenoxyethanol, · 2-Phenylpropan-1-al, · 2-Phenylpropanol, · 2-tert-Butylcyclohexanol, · 3-(3,4-Methylenedioxy-phenyl)-2-methylpropan-1-al, · 3-(3-Isopropylphenyl)-butane-1-al, · 3-(4-Ethylphenyl)-2,2-dimethylpropan-1-al, · 3-(4-Ethylphenyl)-2,2-dimethylpropanal, · 3-(4-Isopropylphenyl)-2-methylpropan-1-al, · 3-(4-Methoxyphenyl)-2-methylpropanal, · 3-(4-tert-Butylphenyl)-2-methyl-propanal, · 3-(4-tert-Butylphenyl)propanal, · 3,4-Dimethoxybenzaldehyde, · 3,4-Methylenedioxybenzaldehyde, · 3,5,5-Trimethylcyclohexanol, · 3,5,5-Trimethylhexanal, · 3,5,6-Trimethyl-3-cyclohexenecarboxaldehyde, · 3,7-Dimethyl-2-methylene-6-octenal, · 3,7-Dimethyl-6-octen-1-al, · 3,7-Dimethyloctan-1-al, · 3-Ethoxy-4-hydroxybenzaldehyde, · 3-Hexanol, · 3-Methoxy-4-hydroxy-benzaldehyde, · 3-Methyl-5-phenyl-1-pentanal, · 3-Methyl-5-phenylpentanol, · 3-Octanol, · 3-Phenyl-2-hexylprop-2-enal, · 3-Phenyl-2-pentylprop-2-en-1-al, · 3-Phenyl-2-propenal, · 3-Phenylprop-2-en-1-al, · 3-Phenylpropanol, · 3-Propyl-bicyclo[2.2.1]-hept-5-en-2-carboxaldehyde, · 4-(1-Ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanone, · 4-(3)(4-Methyl-3-pentenyl)-3-cyclohexene-carboxaldehyde, · 4-(4-Hydroxy-3-methoxyphenyl)-2-butanone, · 4-(4-Hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde, · 4-(Tricyclo[5.2.1.0(2,6)]-decyliden-8)-butanal; · 4-Damascone, · 4-Heptenol, · 4-Hydroxy-3-methoxybenzaldehyde, · 4-Isopropylbenzaldehyde (4-isopropyl benzyaldehyde), · 4-Isopropylcyclohexanol, · 4-Methoxybenzaldehyde, · 4-Methylphenylacetaldehyde, · 4-tert-Butylcyclohexanol, · 5,9-Dimethyl-4,8-decadienal, · 5-Methoxyhexahydro-4,7-methanoindane-1-carboxaldehyde, · 5-Methoxyhexahydro-4,7-methanoindane-2-carboxaldehyde, · 6,10-Dimethyl-3-oxa-5,9-undecadien-1-al, · 6,6-Dimethyl-2-norpinene-2-propionaldehyde, · 6,7-Dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, · 6,8-Dimethyl-2-nonanol, 6-nonen-1-ol, · 6-Isopropyl-decahydro-2-naphthone, · 6-Methoxyhexahydro-4,7-methanoindane-1-carboxaldehyde, · 6-Methoxyhexahydro-4,7-methanoindane-2-carboxaldehyde, · 7-Hydroxy-3,7-dimethyloctanal, · 7-Methoxy-3,7-dimethyloctan-1-al, · 9-Decen-1-ol, · 9-Decenal, · Acetophenone, · Adoxal · Allylcyclohexyl propionate, · Alpha lonone, · Ambroxan, · Amyl salicylate, · Anethole, · Anisaldehyde, · Benzaldehyde, · Benzophenone, · Benzyl acetate, · Benzylacetone, · Benzyl alcohol, · Benzyl salicylate, · Benzylethyl ether, · Bourgeonal, · Butyloxime, · Butyl salicylate, · Camphor, · Cantaloxal, · Carvone, · Cassione, · Celery ketone, · Chloral hydrate, · Cinnamic alcohol, · cis- / trans-3,7-Dimethyl-2,6-octadien-1-al, · cis-Jasmone, · Citral or its mixture, · Citronellal, · Citronellol, · Citronellyloxyacetaldehyde, · Cumal, · Cyclamen aldehyde, · Cyclohexyl salicylate, · Cymaral, · Dammarose, · Damascenone, · Decanol, · Decyl aldehyde, · Delphone, · Dihydrojasmone, · Dihydromyrcenol, · Dihydrodimethyaldehyde, · Dihydro-β-ionone, · Dimethylbenzyl carbinol, · Dimethylbenzylvinyl acetate, · Dimethylheptanol, · Dimethyloctanol, · Dimethyloctenone, · Dalcinyl, · Ethyl salicylate, · Ethylvanillin, · Ethylmethylphenylglycinate, · Eugenol, · Fenchone, · Floramon, · Floralozone, · Floramat, · Florhydral, · Gerson, · Geraniol, · Hedion, · Helional, · Heliorotopin, · Heptanol, · Hexahydro-4,7-methanoindane-1-carboxaldehyde, · Hexahydro-8,8-dimethyl-2-naphthaldehyde, · Hexalone, · Hexyl salicylate, · Hydroxycitronellal, · Isoborneol, · Isodamascon, · Isoeugenol, · Isojasmone, · Isopregol, · Jasmasyclatatt, · Corebon, · Laurinaldehyde, · Ligustral, · Lilial citral, · Lilial, · Limonene, · Linalool, · Linalyl acetate, · Ribscon, · Lyrral, · m-Cymen-7-carboxaldehyde, · Melonal, · Melasat, · Menthol, · Menthone, · Methyl acetophenone, · Methyl cedrenyl ketone, · Methyl cedrylon, · Methyl cedrylone, · Methyl cyclocitron, · Methyl dihydrojasmonate, · Methyl heptenone, · Methyl lavender ketone, · Methyl dihydrojasmonate, · Methyl nonyl acetaldehyde, · Methyl-β-naphthyl ketone, · Musk indanone, · Muscone, · Milthenol, · n-Dodecanal, · Neobutenone, · Nerol, · n-Hexanol, · Nonanol, · n-Undecanal, · Octahydro-4,7-methano-1H-indenecarboxaldehyde; · Octanal, · Octanol, · o-Methoxyzimtaldehyde, · Orivone, · p-Ethyl-α,α-dimethylhydrozimtaldehyde · Phenol, · Phenoxyacetaldehyde; · Phenoxyisobutyrate, · Phenylacetaldehyde, · Phenyl salicylate, · Phenyl ethyl acetate, · Phenyl ethyl alcohol, · p-Hydroxyphenyl butanone, · Pinene, · Pricaltone, · p-Menthan-7-ol, · p-Methoxyacetophenone, · p-Methylphenoxyacetaldehyde, · p-tert.-Bucinal, · p-tert.-Butyl cyclohexanone, · p-tert.-Cyclohexyl acetate, · p-Tolyl acetaldehyde, · Styralyl propionate, · Tetrahydrogeraniol, · Tetrahydrolinalool, · Tetramelane, · Thymol, · Tonalid / Musk Plus, · Trans-2-cis-6-nonadienol, · Trans-2-nonen-1-ol, · Trans-2-octenol, · Trans-4-decenal, · Triplal, · Undecanal, · Undecanol, · Undecylenraldehyde, · Vanillin, · Belouton, · Verdone, · α.-Methyl-3,4-(methylenedioxy)-hydrocinnamaldehyde, · α-Damascone, · α-Methylbenzyl alcohol, · α-Methyl-4-(1-methylethyl) benzeneacetaldehyde, · α-Methylphenylacetaldehyde, · α-n-Amylzimtaldehyde · α-n-Hexyl-cinnamaldehyde · α-Terpineol · β-Damascone · β-Ionone · β-Terpineol · γ-Methylionone · δ-Damascone

[0026] The perfume mixture may contain at least one cyclopropyl derivative according to the invention and said second fragrance in an amount in the range of from about 0.01:99.99 to about 10:90, preferably from about 0.1:99.9 to 1:99.

[0027] Solvent In a preferred embodiment, the mixture according to the invention may contain at least one solvent. Suitable solvents are selected from the group consisting of water, ethanol, propylene glycol, dipropylene glycol, glycerol, and triethyl citrate. Usually, said at least one solvent is present in the mixture in an amount in the range of from about 10 to about 90 weight percent, preferably from about 25 to about 50 weight percent.

[0028] Cosmetics and personal care preparations Another object of the present invention relates to a cosmetic or personal care preparation comprising the cyclopropyl derivative or the perfume composition described above. Said preparation contains said component in an amount in the range of from about 0.01 to about 2 weight percent, preferably from about 0.1 to 1 weight percent, calculated based on the preparation. Said composition can represent, for example, a cosmetic cream, lotion, spray, emulsion, ointment, gel or mousse.

[0029] The formulations according to the present invention may contain, as additional auxiliaries and additives, anti-dandruff agents, anti-irritation agents, irritation inhibitors, antioxidants, astringents, antiperspirants, preservatives, antistatic agents, binders, buffers, carrier materials, chelating agents, cell stimulants, cleansing agents, care agents, deodorants, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibers, film-forming agents, fixing agents, foam-forming agents, foam stabilizers, anti-foaming substances, foam boosters, gel agents, gel-forming agents, hair care agents, hair setting agents, hair straightening agents, agents providing moisture, moisture substances, moisture-retaining substances, bleaching agents, reinforcing materials, stain removers, optical brightening agents, impregnating agents, soil repellents, friction reducers, lubricants, moisturizing creams, ointments, opacifiers, plasticizers, coating agents, brightening agents, polymers, powders, proteins, reolyzers, abrasives, silicones, skin calming agents, skin cleansing agents, skin care agents, skin healing agents, skin lightening agents, skin protecting agents, skin softening agents, hair growth promoters, cooling agents, skin cooling agents, warming agents, skin warming agents, stabilizers, UV absorbers, UV filters, detergents, fabric conditioners, suspending agents, sunburn agents, thickeners, vitamins, oils, waxes, fats, phospholipids, saturated fatty acids, mono- or poly-unsaturated fatty acids, α-hydroxy acids, polyhydroxy fatty acids, liquefiers, dyes, color protectors, pigments, anticorrosives, fragrances, fragrance additives, odoriferous substances, polyols, surfactants, electrolytes, organic solvents or silicone derivatives, etc.

[0030] Surfactants Preferred auxiliaries and additives are anionic and / or amphoteric or zwitterionic surfactants. Nonionic and cationic surfactants can also be present in the composition. Suitable examples are described together with the paragraph dealing with emulsifiers.

[0031] Typical examples of anionic and zwitterionic surfactants include the following: almond amidopropylamine oxide, almond amidopropyl betaine, aminopropyl lauryl glutamate, ammonium C12-15 alkyl sulfate, ammonium C12-16 alkyl sulfate, ammonium capryles sulfate, ammonium coco monoglyceride sulfate, ammonium coco sulfate, ammonium coco oil isethionate, ammonium coco oil sarcosinate, ammonium C12-15 pareth sulfate, ammonium C9-10 perfluoroalkyl sulfonate, ammonium dinonyl sulfosuccinate, ammonium dodecylbenzene sulfonate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7 sulfate, ammonium laureth-9 sulfate, ammonium laureth-12 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myreth sulfate, ammonium myristyl sulfate, ammonium nonoxynol-4 sulfate, ammonium nonoxynol-30 sulfate, ammonium oleate, ammonium palm kernel sulfate, ammonium stearate, ammonium tartrate, AMPD-isostearoyl hydrolyzed collagen, AMPD-rosin hydrolyzed collagen, AMP-isostearoyl hydrolyzed collagen, AMP-isostearoyl hydrolyzed keratin, AMP-isostearoyl hydrolyzed soy protein, AMP-isostearoyl hydrolyzed wheat protein, apricot amidopropyl betaine, arachidic acid, arginine hexyl decyl phosphate, avocado amidopropyl betaine, avocado oil glyceryl-8 ester, babassu acid, babassu amidopropylamine oxide, babassu amidopropyl betaine, beeswaxAcid), behenamidopropyl betaine, behenamine oxide, behenes-25, behenes-30, behenic acid, behenyl betaine, bis-butyl dimethicone polyglyceryl-3, butoxynol-5 carboxylic acid, butoxynol-19 carboxylic acid, butyldimonium hydroxypropyl butyl glucoside chloride, butyldimonium hydroxypropyl lauryl glucoside chloride, butyl glucoside, butyl glucoside caprate, butyl glucoside hydroxypropyl trimonium chloride, butyl octanoic acid, C18-36 acid, C20-40 acid, C30-50 acid, C16-22 acid amide MEA, calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C9-16 alkane / cycloalkane, C10-14 alkylbenzenesulfonic acid, C12-14 alkyldiaminoethyl glycine HCL, C9-15 alkyl phosphate, Candida Bombicola / glucose / Methyl Rapeseedate ferment, canolamidopropyl betaine, capric acid, caproic acid, caproyl ethyl glucoside, capryl / capramidopropyl betaine, capryless-4 carboxylic acid, capryless-6 carboxylic acid, capryless-9 carboxylic acid, caprylic acid, caproyl collagen amino acid, caproyl glycine, caproyl hydrolyzed collagen, caproyl hydrolyzed keratin, caproyl keratin amino acid, caproyl silk amino acid, caprylyl / capryl glucoside, caprylyl / capryl wheat bran / straw glycosides, caprylyl glucoside,

[0032] Caprylyl Glyceryl Ether, Caprylyl Pyrrolidone, Carnitine, Cetearyl Alcohol-20, Cetearyl Alcohol-23, Cetearyl Alcohol-24, Cetearyl Alcohol-25, Cetearyl Alcohol-27, Cetearyl Alcohol-28, Cetearyl Alcohol-29, Cetearyl Alcohol-30, Cetearyl Alcohol-33, Cetearyl Alcohol-34, Cetearyl Alcohol-40, Cetearyl Alcohol-50, Cetearyl Alcohol-55, Cetearyl Alcohol-60, Cetearyl Alcohol-80, Cetearyl Alcohol-100, Cetearyl Alcohol-25 Carboxylic Acid, Cetearyl Alcohol-2 Phosphate, Cetearyl Alcohol-4 Phosphate, Cetearyl Alcohol-5 Phosphate, Cetearyl Alcohol-10 Phosphate, Cetesol-20, Cetesol-23, Cetesol-24, Cetesol-25, Cetesol-30, Cetesol-40, Cetesol-45, Cetesol-150, Cetesol-8 Phosphate, Cetesol-10 Phosphate, Cetesol-20 Phosphate, Cetreth-22, Cetreth-24, Cetreth-25, Cetreth-30, Cetyl Betaine, Chrysanthemum Sinense Flower Extract, C12-14 Hydroxyalkyl Hydroxyethyl Beta-Alanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidopropylamine Oxide, Cocamidopropyl Betaine Amide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocaminopropionic Acid, Cocs-7 Carboxylic Acid, Cocs-4 Glucoside, Cocoa Amphodipropionate, Cocobetaine Amide Amphopropionate, Cocobetaine, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Corn Protein, Cocoglucoside, Cocoglucoside Hydroxypropyltrimonium Chloride, Cocohydroxysultaine, Cocomorpholine Oxide, Coconut Acid, Coconut Oil Glyceryl-8 Ester, Coco / Oleamide Propyl Betaine, Cocusultaine, Coco / Sunflower Amide Propyl Betaine, Cocoylcholine Methosulfate,

[0033] Coconut oil glutamic acid, coconut oil hydrolyzed collagen, coconut oil hydrolyzed keratin, coconut oil hydrolyzed oat protein, coconut oil hydrolyzed rice protein, coconut oil hydrolyzed silk, coconut oil hydrolyzed soybean protein, coconut oil hydrolyzed wheat protein, coconut oil sarcosine, corn acid, cottonseed acid, cottonseed oil glycerides - 8 ester, C10 - 16 pareth - 1, C10 - 16 pareth - 2, C11 - 13 pareth - 6, C11 - 13 pareth - 9, C11 - 13 pareth - 10, C11 - 15 pareth - 30, C11 - 15 pareth - 40, C12 - 13 pareth - 1, C12 - 13 pareth - 23, C12 - 14 pareth - 5, C12 - 14 pareth - 9, C13 - 15 pareth - 21, C14 - 15 pareth - 8, C20 - 22 pareth - 30, C20 - 40 pareth - 40, C20 - 40 pareth - 95, C22 - 24 pareth - 33, C30 - 50 pareth - 40, C9 - 11 pareth - 6 carboxylic acid, C9 - 11 pareth - 8 carboxylic acid, C11 - 15 pareth - 7 carboxylic acid, C12 - 13 pareth - 5 carboxylic acid, C12 - 13 pareth - 7 carboxylic acid, C12 - 13 pareth - 8 carboxylic acid, C12 - 13 pareth - 12 carboxylic acid, C12 - 15 pareth - 7 carboxylic acid, C12 - 15 pareth - 8 carboxylic acid, C12 - 15 pareth - 12 carboxylic acid, C14 - 15 pareth - 8 carboxylic acid, C6 - 10 pareth - 4 phosphate, C12 - 13 pareth - 2 phosphate, C12 - 13 pareth - 10 phosphate, C12 - 15 pareth - 6 phosphate, C12 - 15 pareth - 8 phosphate, C12 - 15 pareth - 10 phosphate, C12 - 16 pareth - 6 phosphate, C4 - 18 perfluoroalkyl ethyl thiohydroxypropyl trimonium chloride, cupuassuamidopropyl betaine (CupuassuamidopropylBetaine), DEA-C12-13 alkyl sulfate, DEA-C12-15 alkyl sulfate, DEA-ceteareth-2 phosphate, DEA-cetyl sulfate, DEA-cocamide dipropionate, DEA-C12-13 pareth-3 sulfate, DEA-cyclocarboxypropyloleate, DEA-dodecylbenzenesulfonate, DEA-isostearate, DEA-laureth sulfate, DEA-lauryl sulfate, DEA-linoleate, DEA-methyl myristate sulfonate, DEA-myreth sulfate, DEA-myristate, DEA-myristyl sulfate, DEA-oleth-5 phosphate, DEA-oleth-20 phosphate, DEA PG-oleate, deceth-7 carboxylic acid, deceth-7 glucoside, deceth-9 phosphate, decylamine oxide, decyl betaine, decyl glucoside, decyltetradeceth-30, decyltetradecylamine oxide,

[0034] Diammonium lauroamido-MEA sulfosuccinate, diammonium lauryl sulfosuccinate, diammonium oleamide PEG-2 sulfosuccinate, dibutoxymethane, Di-C12-15 Pareth-2 Phosphate, Di-C12-15 Pareth-4 Phosphate, Di-C12-15 Pareth-6 Phosphate, Di-C12-15 Pareth-8 Phosphate, Di-C12-15 Pareth-10 Phosphate, didodecyl butanetetracarboxylate, diethylamine lauryl sulfate, diethylhexyl sodium sulfosuccinate, dihydroxyethyl C8-10 alkoxypropylamine oxide, dihydroxyethyl C9-11 alkoxypropylamine oxide, dihydroxyethyl C12-15 alkoxypropylamine oxide, dihydroxyethyl cocamine oxide, dihydroxyethyl lauramine oxide, dihydroxyethyl stearamine oxide, dihydroxyethyl tallowamine oxide, dimethicone PEG-7 phosphate, dimethicone PEG-10 phosphate, dimethicone PEG / PPG-7 / 4 phosphate, dimethicone PEG / PPG-12 / 4 phosphate, dimethicone / polyglycerin-3 copolymer, dimethicone propyl PG-betaine, dimyristyl phosphate, dioleoyl amidoethyl hydroxyethylmonium methosulfate, DIPA-hydrogenated cocoate, DIPA-lanolate, DIPA-myristate, dipotassium capryloyl glutamate, dipotassium lauryl sulfosuccinate, dipotassium undecylenoyl glutamate, disodium babassamid MEA-sulfosuccinate, disodium caproamphodiacetate, disodium caproamphodipropionate, disodium capryloamphodiacetate, disodium capryloamphodipropionate, disodium capryloyl glutamate, disodium cetearyl sulfosuccinate, disodium cetyl phenyl ether disulfonate, disodium cetyl sulfosuccinate, disodium cocamid MEA-sulfosuccinate, disodium cocamid MIPA PEG-4 sulfosuccinate,

[0035] Disodium cocoamido MIPA sulfosuccinate, disodium cocoamido PEG-3 sulfosuccinate, disodium coceth-3 sulfosuccinate, disodium cocoamphocarboxyethyl hydroxypropyl sulfonate, disodium cocoamphodiacetate, disodium cocoamphodipropionate, disodium coco-glucoside sulfosuccinate, disodium coco-sulfosuccinate, disodium cocoyl butyl gluceth-10 sulfosuccinate, disodium cocoyl glutamate, disodium C12-14 pareth-1 sulfosuccinate, disodium C12-14 pareth-2 sulfosuccinate, disodium C12-15 pareth sulfosuccinate, disodium C12-14 Sec-pareth-3 sulfosuccinate, disodium C12-14 Sec-pareth-5 sulfosuccinate, disodium C12-14 Sec-pareth-7 sulfosuccinate, disodium C12-14 Sec-pareth-9 sulfosuccinate, disodium C12-14 Sec-pareth-12 sulfosuccinate, disodium deceth-5 sulfosuccinate, disodium deceth-6 sulfosuccinate, disodium decyl phenyl ether disulfonate, disodium dihydroxyethyl sulfosuccinyl undecylenate, disodium ethylenedicocoamido PEG-15 disulfate, disodium hydrogenated cottonseed glyceride sulfosuccinate, disodium hydrogenated tallow glutamate, disodium hydroxydecyl sorbitol citrate, disodium isodecyl sulfosuccinate, disodium isostearamido MEA sulfosuccinate, disodium isostearamido MIPA-sulfosuccinate, disodium isostearamphodiacetate, disodium isostearamphodipropionate, disodium isostearyl sulfosuccinate, disodium laneth-5 sulfosuccinate, disodium lauramido MEA-sulfosuccinate, disodium lauramido MIPA glycol sulfosuccinate, disodium lauramido PEG-2 sulfosuccinate, disodium lauramido PEG-5 sulfosuccinate, disodium laureth-5 carboxy amphodiacetate, disodium laureth-7 citrate (Disodium Laureth-7Citrate), sodium lauryl disulfosuccinate, disodium lauryl-6-sulfosuccinate, disodium lauryl-9-sulfosuccinate, disodium lauryl-12-sulfosuccinate, disodium lauriminobis(hydroxypropyl)sulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate,

[0036] Dipotassium tocopheryl phosphate lauriminodipropionate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium N-lauroyl aspartate, disodium lauroyl glutamate, disodium lauryl phenyl ether disulfonate, disodium lauryl sulfosuccinate, disodium myristamid MEA-sulfosuccinate, disodium nonoxynol-10 sulfosuccinate, disodium oleamid MEA-sulfosuccinate, disodium oleamid MIPA-sulfosuccinate, disodium oleamid PEG-2 sulfosuccinate, disodium oleoamphodipropionate, disodium olés-3 sulfosuccinate, disodium oleyl phosphate, disodium oleyl sulfosuccinate, disodium palmitamid PEG-2 sulfosuccinate, disodium palmitoleamid PEG-2 sulfosuccinate, disodium PEG-4 cocamid MIPA sulfosuccinate, disodium PEG-12 dimethicone sulfosuccinate, disodium PEG-8 palm glyceride sulfosuccinate, disodium PPG-2-isododeceth-7 carboxy amphodiacetate, disodium ricinoleamid MEA sulfosuccinate, disodium cytosteres-14 sulfosuccinate, disodium soy amphodiacetate, disodium stearamid MEA-sulfosuccinate, disodium steariminodipropionate, disodium stearoamphodiacetate, disodium stearoyl glutamate, disodium stearyl sulfosuccinamate, disodium stearyl sulfosuccinate, disodium 2-sulfolaurate, disodium 2-sulfopalmitate, disodium taramid MEA sulfosuccinate, disodium tallowamid MEA sulfosuccinate, disodium tallowamphodiacetate, disodium tallowiminodipropionate, disodium tallow sulfosuccinate, disodium tridecyl sulfosuccinate, disodium undecylenamid MEA sulfosuccinate, disodium undecylenamid PEG-2 sulfosuccinate, disodium undecylenoyl glutamate, disodium wheat germamidoMEA-Sulfosuccinate), wheat germ PEG-2 disodium sulfosuccinate,

[0037] Triticum germ ampho-diglycinate, diTEA-cocamidodiacetate, diTEA-oleamid PEG-2 sulfosuccinate, diTEA-palmitoyl aspartate, ditridecyl sodium sulfosuccinate, dodecylbenzene sulfonic acid, erucamidopropyl hydroxysultaine, ethylhexes-3 carboxylic acid, ethyl PEG-15 cocamine sulfate, glyceryl caprylether, hexyldecanoic acid, hydrogenated coconut acid, hydrogenated lanolin-25, hydrogenated menhaden acid, hydrogenated palm acid, hydrogenated palm kernel amine oxide, hydrogenated tallow acid, hydrogenated tallow amine oxide, hydrogenated tallow betaine, hydrogenated talloweth-25, hydrogenated tallowoyl glutamic acid, hydrolyzed candida bombicola extract, hydroxysetes-60, hydroxyethyl acetomonium PG-dimethicone, hydroxyethyl butylamine lauryl sulfate, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamine oxide, hydroxylauryllhydroxymyristyl betaine, hydroxystearic acid, hydroxysuccinimidyl C10-40 isoalkylAcidate), hydroxysuccinimidyl C21-22 isoalkyl acidate, hydroxysultaine, IPDI / PEG-15 soyamine oxide copolymer, IPDI / PEG-15 soyethonium ethosulfate copolymer, IPDI / PEG-15 soy glycinate copolymer, isocetes-30, isolaureth-4 phosphate, isopolyglyceryl-3 dimethicone, isopolyglyceryl-3 dimethiconol, isopropanolamine lanolate, isopropylamine dodecylbenzene sulfonate, isostearamidopropylamine oxide, isostearamidopropyl betaine, isostearamidopropyl morpholine oxide, isosteareth-8, isosteareth-16, isosteareth-22, isosteareth-25, isosteareth-50, isostearic acid, isostearoyl hydrolyzed collagen, jojoba oil PEG-150 ester, jojoba wax PEG-80 ester, jojoba wax PEG-120 ester, laneth-20, laneth-25, laneth-40,

[0038] Laness-50, Laness-60, Laness-75, lanolinic acid, lauramidopropylamine oxide, lauramidopropyl betaine, lauramidopropyl hydroxysultaine, lauramine oxide, lauraminopropionic acid, lauryldimonium hydroxypropyl decyl glucoside chloride, lauryldimonium hydroxypropyl lauryl glucoside chloride, Laureth-16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-38, Laureth-40, Laureth-3 carboxylic acid, Laureth-4 carboxylic acid, Laureth-5 carboxylic acid, Laureth-6 carboxylic acid, Laureth-8 carboxylic acid, Laureth-10 carboxylic acid, Laureth-11 carboxylic acid, Laureth-12 carboxylic acid, Laureth-13 carboxylic acid, Laureth-14 carboxylic acid, Laureth-17 carboxylic acid, Laureth-6 citrate, Laureth-7 citrate, Laureth-1 phosphate, Laureth-2 phosphate, Laureth-3 phosphate, Laureth-4 phosphate, Laureth-7 phosphate, Laureth-8 phosphate, Laureth-7 tartrate, lauric acid, lauriminobispropanediol, lauriminodipropionic acid, lauroamphodipropionic acid, lauroyl beta-alanine, lauroyl collagen amino acid, lauroyl ethyltrimonium methosulfate, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methyl glucamide, lauroyl sarcosine, lauroyl silk amino acid, lauryl betaine, lauryl dimethicone / polyglycerin-3 copolymer, lauryldimonium hydroxypropyl coco glucoside chloride, lauryl glucoside, lauryl glucoside hydroxypropyl trimonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysultaine, lauryl malamide, lauryl methyl glucamide, lauryl / myristyl glycol hydroxypropyl ether, lauryl / myristyl wheat bran / straw glycosides, lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, lauryl pyrrolidone, lauryl sultaine, linoleic acid, linolenic acid, linseed acid, lysine cocoate,

[0039] Macadamia seed oil glyceryl-8 ester, magnesium coceth sulfate, magnesium coco sulfate, magnesium isododecylbenzene sulfonate, magnesium laureth-11 carboxylate, magnesium lauryl sulfate, magnesium laureth-5 sulfate, magnesium laureth-8 sulfate, magnesium laureth-16 sulfate, magnesium laureth-3 sulfosuccinate, magnesium lauryl hydroxypropyl sulfonate, magnesium lauryl sulfate, magnesium methyl cocoyl taurate, magnesium myristyl sulfate, magnesium oleyl sulfate, magnesium / TEA-cocosulfate, Manicouagan Clay, MEA-cocoaate, MEA-laurate-6 carboxylate, MEA-lauryl sulfate, MEA-lauryl sulfate, MEA PPG-6 laurate-7 carboxylate, MEA-PPG-8-stearate-7 carboxylate, MEA-undecylenate, meroxapol 108, meroxapol 174, meroxapol 178, meroxapol 254, meroxapol 255, meroxapol 258, meroxapol 314, methoxyPEG-450 amide glutaryl succinimide, methoxyPEG-450 amide hydroxy succinimidyl succinate, methoxyPEG-450 maleimide, methyl morpholine oxide, milk amide propylamine oxide, milk amide propyl betaine, mink amide propylamine oxide, mink amide propyl betaine, MIPA C12-15 pareth sulfate, MIPA-dodecylbenzene sulfonate, MIPA-lauryl sulfate, MIPA-lauryl sulfate, mixed isopropanolaminesLanolate), Mixed Isopropanolamine Lauryl Sulfate, Mixed Isopropanolamine Myristate, Morpholine Oleate, Morpholine Stearate, Miristic-3-Carboxylic Acid, Miristic-5-Carboxylic Acid, Myristalconium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysultaine, Myristamidopropyl PG-Dimonium Chloride Phosphate, Myristamine Oxide, Myristaminopropionic Acid, Myristic Acid, Myristoylethyl Trimonium Methosulfate, Myristoyl Glutamic Acid,

[0040] Myristoyl hydrolyzed collagen, myristoyl sarcosine, myristyl betaine, myristyl / cetyl amine oxide, myristyldimonium hydroxypropyl cocoglucoside chloride, myristyl glucoside, myristyl phosphate, nonoxynol-20, nonoxynol-23, nonoxynol-25, nonoxynol-30, nonoxynol-35, nonoxynol-40, nonoxynol-44, nonoxynol-50, nonoxynol-100, nonoxynol-120, nonoxynol-5 carboxylic acid, nonoxynol-8 carboxylic acid, nonoxynol-10 carboxylic acid, nonoxynol-3 phosphate, nonoxynol-4 phosphate, nonoxynol-6 phosphate, nonoxynol-9 phosphate, nonoxynol-10 phosphate, nonylnonoxynol-30, nonylnonoxynol-49, nonylnonoxynol-100, nonylnonoxynol-150, nonylnonoxynol-7 phosphate, nonylnonoxynol-8 phosphate, nonylnonoxynol-9 phosphate, nonylnonoxynol-10 phosphate, nonylnonoxynol-11 phosphate, nonylnonoxynol-15 phosphate, nonylnonoxynol-24 phosphate, Oatamidopropyl Betaine, octoxynol-16, octoxynol-25, octoxynol-30, octoxynol-33, octoxynol-40, octoxynol-70, octoxynol-20 carboxylic acid, octyldodeceth-20, octyldodeceth-25, octyldodeceth-30, oleamidopropyl amine oxide, oleamidopropyl betaine, oleamidopropyl hydroxysultaine, oleamine oxide, oleic acid, oleoyl hydrolyzed collagen, oleoyl sarcosine, oleth-20, oleth-23, oleth-24, oleth-25, oleth-30, oleth-35, oleth-40, oleth-44, oleth-50, oleth-3 carboxylic acid, oleth-6 carboxylic acid, oleth-10 carboxylic acid, oleyl betaine, olivamidopropyl amine oxide, olivamidopropyl betaine, olive acid, olivoyl hydrolyzed wheat protein, Ophiopogon ExtractStearate), Ozonated Oleth-10, Ozonated PEG-10 Oleate, Ozonated PEG-14 Oleate, Ozonated Polysorbate 80, Palmitic Acid, Palmidopropyl Betaine,

[0041] Palmeth-2 Phosphate, Palmitamidopropylamine Oxide, Palmitamidopropyl Betaine, Palmitamine Oxide, Palmitic Acid, Palmitoyl Collagen Amino Acids, Palmitoyl Glycine, Palmitoyl Hydrolyzed Collagen, Palmitoyl Hydrolyzed Milk Protein, Palmitoyl Hydrolyzed Wheat Protein, Palmitoyl Keratin Amino Acids, Palmitoyl Oligopeptide, Palmitoyl Silk Amino Acids, Palm Kernel Acid, Palm Kernel Amidopropyl Betaine, Peach Kernel Oil Glycereth-8 Ester, Peanut Acid, PEG-10 Castor Oil, PEG-40 Castor Oil, PEG-44 Castor Oil, PEG-50 Castor Oil, PEG-54 Castor Oil, PEG-55 Castor Oil, PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, PEG-6 Cocamide Phosphate, PEG-4 Cocamine, PEG-8 Cocamine, PEG-12 Cocamine, PEG-150 Dibehenate, PEG-90 Diisostearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Cocoate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Soyate (PEG-30 GlycerylSoyate), PEG-25 glyceryl stearate, PEG-30 glyceryl stearate, PEG-40 glyceryl stearate, PEG-120 glyceryl stearate, PEG-200 glyceryl stearate, PEG-28 glyceryl tallate, PEG-80 glyceryl tallate, PEG-82 glyceryl tallate, PEG-130 glyceryl tallate, PEG-200 glyceryl tallate, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-30 hydrogenated lanolin,

[0042] PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isostearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glyceride (PEG-70 MangoGlycerides), PEG-20 Mannitan Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Methyl Glucose Trioleate, PEG-4 Montanate, PEG-30 Oleamine, PEG-20 Oleate, PEG-23 Oleate, PEG-32 Oleate, PEG-36 Oleate, PEG-75 Oleate, PEG-150 Oleate, PEG-20 Palmitate, PEG-150 Polyglyceryl-2 Tristearate, PEG / PPG-28 / 21 Acetate Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG-10 / 30 Copolymer, PEG / PPG-10 / 65 Copolymer, PEG / PPG-12 / 35 Copolymer, PEG / PPG-16 / 17 Copolymer, PEG / PPG-20 / 9 Copolymer, PEG / PPG-20 / 20 Copolymer, PEG / PPG-20 / 60 Copolymer, PEG / PPG-20 / 65 Copolymer, PEG / PPG-22 / 25 Copolymer, PEG / PPG-28 / 30 Copolymer, PEG / PPG-30-35 Copolymer, PEG / PPG-30 / 55 Copolymer, PEG / PPG-35 / 40 Copolymer, PEG / PPG-50 / 40 Copolymer, PEG / PPG-150 / 35 Copolymer, PEG / PPG-160 / 30 Copolymer, PEG / PPG-190 / 60 Copolymer, PEG / PPG-200 / 40 Copolymer, PEG / PPG-300 / 55 Copolymer,

[0043] PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate, PEG / PPG-4 / 2 Propylheptyl Ether, PEG / PPG-6 / 2 Propylheptyl Ether, PEG-7 / PPG-2 Propylheptyl Ether, PEG / PPG-8 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Propylheptyl Ether, PEG / PPG-14 / 2 Propylheptyl Ether, PEG / PPG-40 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol (PEG-5 RapeseedSterol), PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glyceride, PEG-75 Shea Butter Glyceride, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearamide Carboxylic Acid, PEG-9 Stearamide Carboxylic Acid, PEG-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, PEG-40 Stearate, PEG-45 Stearate, PEG-50 Stearate, PEG-55 Stearate, PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG-120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallowate, PEG-50 Tallowamide, PEG-2 Tallowamide DEA, PEG-20 Tallowate, PEG-66 Trihydroxystearin, PEG-200 Trihydroxystearin, PEG-60 Tsubakiate Glycerides, Pelargonic Acid, Pentadoxynol-200, Phenes-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288,

[0044] Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomaderris Kumerahou Flower / Leaf Extract, Poria Cocos Extract, Abitol Hydrolyzed Collagen Potassium, Potassium Babassuic Acid, Potassium Behenate, Potassium C9-15 Alkyl Phosphate, Potassium C11-15 Alkyl Phosphate, Potassium C12-13 Alkyl Phosphate, Potassium C12-14 Alkyl Phosphate, Potassium Caprate, Potassium Capryloyl Glutamate, Potassium Capryloyl Hydrolyzed Comethane Pak, Potassium Castorate, Potassium Coconut Fatty Acid (PotassiumCocoate), potassium cocooyl glutamate, potassium cocooyl glycinate, potassium cocooyl hydrolyzed casein, potassium cocooyl hydrolyzed collagen, potassium cocooyl hydrolyzed corn protein, potassium cocooyl hydrolyzed keratin, potassium cocooyl hydrolyzed oat protein, potassium cocooyl hydrolyzed potato protein, potassium cocooyl hydrolyzed rice bran protein, potassium cocooyl hydrolyzed rice protein, potassium cocooyl hydrolyzed silk, potassium cocooyl hydrolyzed soybean protein, potassium cocooyl hydrolyzed wheat protein, potassium cocooyl hydrolyzed yeast protein,

[0045] Potassium Cocoyl PCA, Potassium Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Cornate, Potassium Cyclocarboxypropyloleate, Potassium Dihydroxyethyl Cocamine Oxide Phosphate, Potassium Dimethicone PEG-7 Phosphate, Potassium Dodecylbenzenesulfonate, Potassium Hempseedate, Potassium Hydrogenated Cocoate, Potassium Hydrogenated Palmate, Potassium Hydrogenated Tallowate, Potassium Hydroxystearate, Potassium Isostearate, Potassium Lanolate, Potassium Laurate, Potassium Lauress-3 Carboxylate, Potassium Lauress-4 Carboxylate, Potassium Lauress-5 Carboxylate, Potassium Lauress-6 Carboxylate, Potassium Lauress-10 Carboxylate, Potassium Lauress Phosphate, Potassium Lauroyl Collagen Amino Acids, Potassium Lauroyl Glutamate, Potassium Lauroyl Hydrolyzed Collagen, Potassium Lauroyl Hydrolyzed Pea Protein, Potassium Lauroyl Hydrolyzed Soy Protein, Potassium Lauroyl PCA, Potassium Lauroyl Pea Amino Acids, Potassium Lauroyl Sarcosinate, Potassium Lauroyl Silk Amino Acids, Potassium Lauroyl Wheat Amino Acids, Potassium Lauryl Phosphate, Potassium Lauryl Sulfate, Potassium Linoleate, Potassium Metaphosphate, Potassium Methyl Cocoyl Taurate, Potassium Myristate, Potassium Myristoyl Glutamate, Potassium Myristoyl Hydrolyzed Collagen, Potassium Octoxynol-12 Phosphate, Potassium Oleate, Potassium Oleoyl Hydrolyzed Collagen, Potassium Olivate, Potassium Olivoyl Hydrolyzed Oat Protein, Potassium Olivoyl Hydrolyzed Wheat Protein, Potassium Olivoyl / Lauroyl Wheat Amino Acids, Potassium Olivoyl PCA, Potassium Palmate (PotassiumPalmate), potassium palmitate, palmitoyl hydrolyzed corn protein potassium, palmitoyl hydrolyzed oat protein potassium, palmitoyl hydrolyzed rice protein potassium, palmitoyl hydrolyzed sweet almond protein potassium,

[0046] Potassium palmitoyl hydrolyzed wheat protein, potassium palm kernelate, potassium peanutate, potassium rapeseed oil fatty acid, potassium ricinoleate, Potassium Safflowerate, potassium soybeanate, potassium stearate, potassium stearoyl hydrolyzed collagen, Potassium Tallate, potassium tarate, potassium taurine laurate, potassium trideceth-3 carboxylate, potassium trideceth-4 carboxylate, potassium trideceth-7 carboxylate, potassium trideceth-15 carboxylate, potassium trideceth-19 carboxylate, potassium trideceth-6 phosphate, potassium trideceth-7 phosphate, potassium camellate, potassium undecylenate, potassium undecylenoyl hydrolyzed collagen, potassium undecylenoyl hydrolyzed wheat protein, PPG-30-buteth-30, PPG-36-buteth-36, PPG-38-buteth-37, PPG-30-capryleth-4 phosphate, PPG-10 cetyl ether phosphate, PPG-2 C9-11 pareth-8, PPG-1-deceth-5, PPG-3-deceth-2 carboxylate, PPG-30 ethylhexeth-4 phosphate, PPG-20 glyceryl-30, PPG-2 hydroxyethyl coc / isostearamide, PPG-2-isodeceth-8, PPG-2-isodeceth-10, PPG-2-isodeceth-18, PPG-2-isodeceth-25, PPG-4-isodeceth-10, propyltrimonium hydrolyzed collagen, quaternium-24, quaternium-52, quaternium-87, rapeseed oil fatty acid, rice bran acid, rice oil glyceryl-8 ester, ricinoleamidopropyl betaine, ricinoleic acid, ricinoleth-40, Safflower Acid, Sapindus Oahuensis fruit extract, Saponaria Officinalis root powder, saponin, soap-K, soap-Na / K, soap base (SekkenSoji), Soap Base-K, Sesame Oil Glyceryl-8 Ester, Sesamidopropylamine Oxide, Sesamidopropyl Betaine, Shea Butteramidopropyl Betaine, Shea Butter Glyceryl-8 Ester, Sodium Arachidate, Sodium Argan Amphodiacetate, Sodium Astrocaryum Murumuruate, Sodium Avocadoate, Sodium Babassu Amphodiacetate, Sodium Babassuate, Sodium Babassu Sulfate, Sodium Behenate,

[0047] Sodium bisglycol ricinosulfosuccinate, Sodium bis(hydroxyethyl) glycinate coco glucoside cross polymer, Sodium bis(hydroxyethyl) glycinate lauryl glucoside cross polymer, Boragediamidopropyl PG-dimonium chloride phosphate sodium, Sodium butoxynol-12 sulfate, Sodium butyl glucoside hydroxypropyl phosphate, Sodium C13-17 alkane sulfonate, Sodium C14-18 alkane sulfonate, Sodium C12-15 alkoxypropyliminodipropionate, Sodium C10-16 alkyl sulfate, Sodium C11-15 alkyl sulfate, Sodium C12-13 alkyl sulfate, Sodium C12-15 alkyl sulfate, Sodium C12-18 alkyl sulfate, Sodium C16-20 alkyl sulfate, Sodium C9-22 alkyl Sec sulfonate, Sodium C14-17 alkyl Sec sulfonate, Sodium caprate, Sodium caproamphoacetate, Sodium caproamphohydroxypropyl sulfonate, Sodium caproamphopropionate, Sodium caproylmethyl taurate, Sodium caprylate, Sodium capryless-2 carboxylate, Sodium capryless-9 carboxylate, Sodium capryloamphoacetate, Sodium capryloamphohydroxypropyl sulfonate, Sodium capryloamphopropionate, Sodium capryloyl glutamate, Sodium capryloyl hydrolyzed wheat protein, Sodium caprylyl PG-sulfonate, Sodium caprylyl sulfonate, Sodium castor fatty acid, Sodium ceteareth-13 carboxylate, Sodium cetearyl sulfate, Sodium cetes-13 carboxylate, Sodium cetyl sulfate, Sodium cocamidopropyl PG-dimonium chloride phosphate, Sodium cocaminopropionate, Sodium coces sulfate, Sodium coces-30 sulfate, Sodium cocoabutter amphoacetate, Sodium cocoabutterate, Sodium coco amphoacetate, Sodium coco amphohydroxypropyl sulfonate, Sodium coco amphopropionate, Sodium coconut fatty acid, Sodium coco / babassu / andirobaSulfate), coco / babassu sodium sulfate, coco glucoside hydroxypropyl sodium phosphate,

[0048] Sodium cocoglucoside hydroxypropyl sulfonate, sodium cocoglucoside tartrate, sodium cocoglyceryl ether sulfonate, sodium coco / hydrogenated tallow sulfate, sodium cocoiminodiacetate, sodium coco monoglyceride sulfate, sodium coco monoglyceride sulfonate, sodium cocoyl PG-dimonium chloride phosphate, sodium coco sulfate, sodium coco sulfacetate, Sodium Cocoyl Alaninate, sodium cocoyl amino acid, sodium cocoyl collagen amino acid, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutaminate, sodium cocoyl glycinate, sodium cocoyl / hydrogenated tallow glutamate, sodium cocoyl hydrolyzed collagen, sodium cocoyl hydrolyzed keratin, sodium cocoyl hydrolyzed wheat protein, sodium cocoyl hydrolyzed silk, sodium cocoyl hydrolyzed soybean protein, sodium cocoyl hydrolyzed sweet almond protein, sodium cocoyl hydrolyzed wheat protein, sodium cocoyl hydrolyzed wheat gluten glutamate, sodium cocoyl isethionate, sodium cocoyl methylaminopropionate, sodium cocoyl oat amino acid, Sodium Cocoyl / Palmoyl / Sunfloweroyl Glutamate, sodium cocoyl proline, sodium cocoyl sarcosinate, sodium cocoyl taurine, sodium cocoyl threonine, sodium cocoyl wheat amino acid, Sodium C12-14 Olefin Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14-18 Olefin Sulfonate, Sodium C16-18 Olefin Sulfonate, sodium corn amphopropionate, sodium cottonseed amphoacetate (SodiumCottonseed amphoacetate), Sodium C13-15 pareth-8 phosphate, Sodium C9-11 pareth-6 carboxylate, Sodium C11-15 pareth-7 carboxylate, Sodium C12-13 pareth-5 carboxylate, Sodium C12-13 pareth-8 carboxylate, Sodium C12-13 pareth-12 carboxylate, Sodium C12-15 pareth-6 carboxylate, Sodium C12-15 pareth-7 carboxylate, Sodium C12-15 pareth-8 carboxylate, Sodium C14-15 pareth-8 carboxylate, Sodium C12-14 Sec-pareth-8 carboxylate,

[0049] Sodium C14-15 pareth-sulfate, Sodium C12-13 pareth-2 phosphate, Sodium C13-15 pareth-8 phosphate, Sodium C9-15 pareth-3 sulfate, Sodium C10-15 pareth sulfate, Sodium C10-16 pareth-2 sulfate, Sodium C12-13 pareth sulfate, Sodium C12-15 pareth sulfate, Sodium C12-15 pareth-3 sulfate, Sodium C13-15 pareth-3 sulfate, Sodium C12-14 Sec-pareth-3 sulfate, Sodium C12-15 pareth-3 sulfonate, Sodium C12-15 pareth-7 sulfonate, Sodium C12-15 pareth-15 sulfonate, Sodium deceth-2 carboxylate, Sodium deceth sulfate, Sodium decylbenzene sulfonate, Sodium decyl glucoside hydroxypropyl phosphate, Sodium decyl glucoside hydroxypropyl sulfonate, Sodium dilauryl citrate, Sodium dilauryl phosphate, Sodium dilinoleamidopropyl PG-dimonium chloride phosphate, Sodium dilinoleate, Sodium dioleth-8 phosphate, Sodium dodecylbenzene sulfonate, Sodium ethyl 2-sulfolaurate, Sodium Glyceryl Oleate Phosphate, Sodium grapeseedamidopropyl PG-dimonium chloride phosphate, Sodium grapeseed amphoacetate, Sodium Grapeseedate, Sodium hempseed amphoacetate, Sodium hexeth-4 carboxylate, Sodium hydrogenated cocoate, Sodium hydrogenated cocoyl methyl isethionate, Sodium hydrogenated palm oil fatty acid, Sodium hydrogenated tallowate, Sodium hydrogenated tallowoyl glutamate, Sodium hydroxy lauryldimonium ethyl phosphate, Sodium hydroxypropyl palm kernel acid sulfonate, Sodium hydroxypropyl phosphate decyl glucoside copolymer, Sodium hydroxypropyl phosphate lauryl glucoside copolymer, Sodium hydroxypropyl sulfonate coco glucoside copolymer, Sodium hydroxypropyl sulfonate decyl glucoside copolymer, Sodium hydroxypropyl sulfonate lauryl glucoside copolymer

[0050] Sodium hydroxystearate, sodium isostearate, sodium isosteares-6-carboxylate, sodium isosteares-11-carboxylate, sodium isostearoamphoacetate, sodium isostearoamphopropionate, sodium N-isostearoyl methyltaurate, sodium laneth sulfate, sodium lanolin fatty acid, Sodium Lardate, sodium lauramidodiacetate, sodium lauraminopropionate, sodium laurate, sodium laures-3-carboxylate, sodium laures-4-carboxylate, sodium laures-5-carboxylate, sodium laures-6-carboxylate, sodium laures-8-carboxylate, sodium laures-11-carboxylate, sodium laures-12-carboxylate, sodium laures-13-carboxylate, sodium laures-14-carboxylate, sodium laures-16-carboxylate, sodium laures-17-carboxylate, sodium laures sulfate, sodium laures-5 sulfate, sodium laures-7 sulfate, sodium laures-8 sulfate, sodium laures-12 sulfate, sodium laures-40 sulfate, sodium laures-7 tartrate, sodium lauriminodipropionate, sodium lauroamphoacetate, sodium lauroamphohydroxypropylsulfonate, sodium lauroampho PG-acetate phosphate, sodium lauroamphopropionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, sodium lauroyl glycine propionate, sodium lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropylsulfonate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl methylisethionate, sodium lauroyl millet aminoAcids), sodium lauroyl / myristoyl aspartate, sodium lauroyl oat amino acid, sodium lauroyl sarcosinate, sodium lauroyl silk amino acid, sodium lauroyl taurine, sodium lauroyl wheat amino acid, sodium lauryldiethylenediaminoglycinate, sodium lauryl glucose carboxylate, sodium lauryl glucoside hydroxypropyl phosphate,

[0051] Sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl glycol carboxylate, sodium lauryl hydroxyacetamide sulfate, sodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium linoleate, Sodium Macadamiaseedate, sodium mango amphoacetate, sodium mangoseedate (SodiumMangoseedate), sodium / MEA lauryl-2-sulfosuccinate, methoxy PPG-2 sodium acetate, sodium methyl cocoyl taurate, sodium methyl lauroyl taurate, sodium methyl myristoyl taurate, sodium methyl oleoyl taurate, sodium methyl palmitoyl taurate, sodium methyl stearoyl taurate, sodium methyl 2-sulfolaurate, sodium methyl 2-sulfopalmitate, sodium methyl isopalmitamidotaurate, sodium methyl taurate cocoyl methyl taurate, sodium myreth sulfate, sodium myristate, sodium myristoamphoacetate, sodium myristoyl glutamate, sodium myristoyl hydrolyzed collagen, sodium myristoyl isethionate, sodium myristoyl sarcosinate, sodium myristyl sulfate, sodium nonoxynol-6 phosphate, sodium nonoxynol-9 phosphate, sodium nonoxynol-1 sulfate, sodium nonoxynol-3 sulfate, sodium nonoxynol-4 sulfate, sodium nonoxynol-6 sulfate, sodium nonoxynol-8 sulfate, sodium nonoxynol-10 sulfate, sodium nonoxynol-25 sulfate, sodium octoxynol-2 ethanesulfonate, sodium octoxynol-2 sulfate, sodium octoxynol-6 sulfate, sodium octoxynol-9 sulfate, sodium oleate, sodium oleoamphoacetate, sodium oleoamphohydroxypropylsulfonate, sodium oleopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl isethionate, sodium oles sulfate, sodium oleyl methyl isethionate, sodium oleyl sulfate, sodium oliveamphoacetate, sodium olive fatty acid, sodium oliboyl glutamate, sodium palmamphoacetate, sodium palm fatty acid, sodium palm glyceride sulfonate,

[0052] Sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat gluten, sodium palmitoyl sarcosinate, sodium palm kernelate, sodium palm kerneloyl isethionate, sodium palmolyl glutamate, Sodium Passiflora Edulis Seedate, sodium peanut amphoacetate, Sodium Peanutate, sodium PEG-6 cocamidocarboxylate, sodium PEG-8 cocamidocarboxylate, sodium PEG-4 cocamidosulfate, sodium PEG-3 lauramidocarboxylate, sodium PEG-4 lauramidocarboxylate, sodium PEG-8 palm glyceride carboxylate, pentaerythrityl hydroxypropyliminodiacetic acid dendrimer sodium, sodium propoxypPG-2 acetate, sodium rapeseed oil fatty acid, sodium rice bran amphoacetate, sodium ricinoleate, sodium ricinoleoamphoacetate, sodium rose hip amphoacetate, sodium rosinate, sodium safflower oil fatty acid, sodium saffloweroyl hydrolyzed soybean protein, sodium sesame seed oil fatty acid, sodium sesamum amphoacetate (SodiumSesamphoacetate), Sodium Cyabutter Amphoacetate, Sodium Soybean Oil Fatty Acid, Sodium Hydrolyzed Soybean Collagen, Sodium Stearate, Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Stearoyl Casein, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Corn Protein, Sodium Stearoyl Hydrolyzed Silk, Sodium Stearoyl Hydrolyzed Soy Protein, Sodium Stearoyl Hydrolyzed Wheat Protein, Sodium Stearoyl Lactalbumin, Sodium Stearoyl Methyl Isethionate, Sodium Stearoyl Oat Protein, Sodium Stearoyl Pea Protein, Sodium Stearoyl Soy Protein, Sodium Stearyldimethylglycine, Sodium Stearyl Sulfate, Sodium Sunflower Seed Amphoacetate, Sodium Surfactin, Sodium Sweet Almond Amphoacetate, Sodium Sweet Almondate, Sodium Tallamphopropionate, Sodium Tallate,

[0053] Sodium Taro Amphoacetate, Sodium Taroate, Sodium Taro Sulfate, Sodium Tamanuseedate, Sodium Taurate, Sodium Taurine Cocoyl Methyl Taurate, Sodium Taurine Laurate, Sodium / TEA-Lauroyl Collagen Amino Acids, Sodium / TEA-Lauroyl Hydrolyzed Collagen, Sodium / TEA-Lauroyl Hydrolyzed Keratin, Sodium / TEA-Lauroyl Keratin Amino Acids, Sodium / TEA-Undecylenoyl Collagen Amino Acids, Sodium / TEA-Undecylenoyl Hydrolyzed Collagen, Sodium / TEA-Undecylenoyl Hydrolyzed Corn Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Soy Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Wheat Protein, Sodium Theobroma Grandiflorum Seedate, Sodium Trideceth-3 Carboxylate, Sodium Trideceth-4 Carboxylate, Sodium Trideceth-6 Carboxylate, Sodium Trideceth-7 Carboxylate, Sodium Trideceth-8 Carboxylate, Sodium Trideceth-12 Carboxylate, Sodium Trideceth-15 Carboxylate, Sodium Trideceth-19 Carboxylate, Sodium Trideceth Sulfate, Sodium Tridecylbenzene Sulfonate, Sodium Tridecyl Sulfate, Sodium Trimethylolpropane Hydroxypropyliminodiacetate Dendrimer, Sodium Undeceth-5 Carboxylate, Sodium Undecylenate, Sodium Undecylenoyl Amphoacetate, Sodium Undecylenoyl Amphopropionate, Sodium Undecylenoyl Glutamate, Sodium Wheat Germ AmphoacetateGermamphoacetate), Sorves-160 tristearate, soybean acid, soyamidopropylamine oxide, soyamidopropyl betaine, soybean oil glyceres-8 ester, stearamidopropylamine oxide, stearamidopropyl betaine, stearamine oxide, Steares-15, Steares-16, Steares-20, Steares-21, Steares-25, Steares-27, Steares-30, Steares-40, Steares-50, Steares-80, Steares-100, Steares-2 phosphate, Steares-3 phosphate, stearic acid, stearoxypropyltrimonium chloride, stearoyl glutamate,

[0054] Stearoyl sarcosine, stearyl betaine, stearyl dimonium hydroxypropyl butyl glucoside chloride, stearyl dimonium hydroxypropyl decyl glucoside chloride, stearyl dimonium hydroxypropyl lauryl glucoside chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower amide MEA, sunflower seed acid, sunflower seed amide propyl hydroxyethyl dimonium chloride, sunflower seed oil glyceryl esters - 8, tall oil fatty acid, tall oil acid, tall oil amide propyl amine oxide, tall oil amide propyl betaine, tall oil amide propyl hydroxysultaine, tall oil amine oxide, tall oil betaine, tall oil dihydroxyethyl betaine, talloyl ethyl glucoside, TEA - abietoyl hydrolyzed collagen, TEA - C12 - 14 alkyl phosphate, TEA - C10 - 15 alkyl sulfate, TEA - C11 - 15 alkyl sulfate, TEA - C12 - 13 alkyl sulfate, TEA - C12 - 14 alkyl sulfate, TEA - C12 - 15 alkyl sulfate, TEA - C14 - 17 alkyl Sec sulfonate, TEA - canolate, TEA - cocamidodiacetate, TEA - cocoate, TEA - coco - sulfate, TEA - cocoyl alaninate, TEA - cocoyl glutamate, TEA - cocoyl glutamine, TEA - cocoyl glycinate, TEA - cocoyl hydrolyzed collagen, TEA - cocoyl hydrolyzed soy protein, TEA - cocoyl sarcosinate, TEA - dimethicone PEG - 7 phosphate, TEA - dodecyl benzene sulfonate, TEA - hydrogenated cocoate, TEA - hydrogenated talloyl glutamate, TEA - isostearate, TEA - isostearoyl hydrolyzed collagen, TEA - lauraminopropionate, TEA - laurate, TEA - laurate / mystate, TEA - laureth sulfate, TEA - lauroyl collagen amino acid, TEA - lauroyl glutamate, TEA - lauroyl hydrolyzed collagen, TEA - lauroyl keratin amino acid, TEA - lauroyl methyl aminopropionate, TEA - lauroyl / mystoyl aspartate, TEA - lauroyl sarcosinate,TEA-lauryl phosphate, TEA-lauryl sulfate, TEA-myristaminopropionate, TEA-myristate, TEA-myristoyl hydrolyzed collagen,

[0055] TEA-oleate, TEA-oleoyl hydrolyzed collagen, TEA-oleoyl sarcosinate, TEA-oleyl sulfate, TEA-palmitate, TEA-palm kernel sarcosinate, TEA-PEG-3 cocamide sulfate, TEA-rosinate, TEA-stearate, TEA-Tallate, TEA-tridecylbenzene sulfonate, TEA-undecylenate, TEA-undecylenoyl hydrolyzed collagen, tetramethyldecyne diol, tetrasodium dicarboxyethyl stearyl sulfosuccinamate, TIPA-lauryl sulfate, TIPA-lauryl sulfate, TIPA-myristate, TIPA-stearate, tocopherol phosphate, trehalose undecylenate, TM-C12-15 pareth-2 phosphate, TM-C12-15 pareth-6 phosphate, TM-C12-15 pareth-8 phosphate, TM-C12-15 pareth-10 phosphate, trideceth-20, trideceth-50, trideceth-3 carboxylic acid, trideceth-4 carboxylic acid, trideceth-7 carboxylic acid, trideceth-8 carboxylic acid, trideceth-15 carboxylic acid, trideceth-19 carboxylic acid, trideceth-10 phosphate, tridecylbenzene sulfonic acid, trilauryl citrate, trimethylolpropane hydroxypropylbis-hydroxyethylamine dendrimer, trisodium lauroampho PG-acetate chloride phosphate, undecanoic acid, undeceth-5 carboxylic acid, undecylenamide propylamine oxide, undecylenamide propyl betaine, undecylenic acid, undecylenoyl collagen amino acid, undecylenoyl glycine, undecylenoyl hydrolyzed collagen, undecylenoyl wheat amino acid, undecyl glucoside, wheat germ acid, wheat germ amide propylamine oxide, wheat germ amide propyl betaine, Yucca Schidigera leaf / root / stem extract, Yucca Schidigera stem extract, cocos zinc sulfate and coco zinc sulfate.

[0056] Preferred are one or more compounds selected from the group consisting of sodium lauryl sulfate, cocamidopropyl betaine, sodium cocoamphoacetate, coco glucoside, and ammonium lauryl sulfosuccinate.

[0057] Based on the preparation, the surfactant content in the preparation may be 0.1 to 10% by weight, preferably 0.5 to 5% by weight.

[0058] Oil body Suitable oil bodies that are components of the O / W emulsion include, for example, gellu alcohol based on fatty alcohols having 6 to 18, preferably 8 to 10 carbon atoms, linear C6-C 22 Fatty acids and linear or branched C6-C 22 Esters with fatty alcohols, or branched C6-C 13 Carboxylic acids and linear or branched C6-C 22Esters with fatty alcohols, such as myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, oleyl isostearate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate and erucyl erucate. Similarly suitable are linear C6-C 22 Esters of fatty acids with branched alcohols, especially 2-ethylhexanol, C 18 -C 38 Esters of alkyl hydroxycarboxylic acids with linear or branched C6-C 22 fatty alcohols, especially dioctyl maleate, esters of linear and / or branched fatty acids with polyhydric alcohols (e.g., propylene glycol, dimer diol, trimer triol) and / or geranylgeraniol, C6-C 10 Triglycerides based on fatty acids, C6-C 18 Liquid mono / di / triglyceride mixtures based on fatty acids, C6-C 22 Esters of fatty alcohols and / or geranylgeraniol with aromatic carboxylic acids, especially benzoic acid, C2-C 12Esters of dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C6-C 22 Fatty alcohol carbonates, such as dicaprylyl carbonate (Cetiol® CC), gelbe carbonates based on fatty alcohols having 6 to 18, preferably 8 to 10 carbon atoms, esters of benzoic acid with linear and / or branched C6-C 22 alcohols (e.g., Finsolv® TN), linear or branched, symmetric or asymmetric dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as dicaprylyl ether (Cetiol® OE), ring-opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicone, silicone methylcongrade, etc.) and / or aliphatic or naphthenic hydrocarbons, such as squalane, squalene or dialkylcyclohexane.

[0059] Emulsifiers Other nonionic or cationic surfactants may also be added to the preparation as emulsifiers, for example, the following are included: · Products obtained by adding 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear C 8-22 fatty alcohols, C 12-22 fatty acids, and alkylphenols containing 8 to 15 carbon atoms in the alkyl group · Addition products of 1 to 30 mol of ethylene oxide to glycerol, C 12 / 18 Fatty acid monoesters and diesters · Glycerol mono- and diesters, sorbitan mono- and diesters of saturated and unsaturated fatty acids containing 6 to 22 carbon atoms, and their ethylene oxide addition products · Addition products of 15 to 60 moles of ethylene oxide to castor oil and / or hydrogenated castor oil · Polyol esters, especially polyglycerol esters, such as polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimerate isostearate. Mixtures of some compounds of these classes are also suitable. · Addition products of 2 to 15 moles of ethylene oxide to castor oil and / or hydrogenated castor oil · Linear, branched, unsaturated or saturated C 6 / 22 Partial esters based on fatty acids, ricinoleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (e.g., sorbitol), alkyl glucosides (e.g., methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (e.g., cellulose). · Mono-, di- and trialkyl phosphates, and mono-, di- and / or tri-PEG-alkyl phosphates, and their salts · Wool wax alcohol · Polysiloxane / polyalkyl polyether copolymers and corresponding derivatives · Mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohols and / or C 6-22 Mixed esters of fatty acids, methyl glucose and polyols, preferably glycerol or polyglycerol. · Polyalkylene glycols, and · Glycerol carbonate.

[0060] Addition products of ethylene oxide and / or propylene oxide to fatty alcohols, fatty acids, alkylphenols, mono- and diesters of fatty acids with glycerol and sorbitan mono- and diesters, or to castor oil are known commercially available products. These are homolog mixtures in which the average degree of alkoxylation corresponds to the ratio of the amount of substrate to which ethylene oxide and / or propylene oxide undergoes an addition reaction. C which is an addition product of ethylene oxide to glycerol12 / 18 Fatty acid monoesters and diesters are known as lipid layer enhancers for cosmetic preparations. Preferred emulsifiers will be described in detail below.

[0061] Partial glycerides Typical examples of suitable partial glycerides are monoglyceryl hydroxystearate, diglyceryl hydroxystearate, monoglyceryl isostearate, diglyceryl isostearate, monoglyceryl oleate, diglyceryl oleate, monoglyceryl ricinoleate, diglyceryl ricinoleate, monoglyceryl linoleate, diglyceryl linoleate, monoglyceryl linolenate, diglyceryl linolenate, monoglyceryl erucate, diglyceryl erucate, monoglyceryl tartrate, diglyceryl tartrate, monoglyceryl citrate, diglyceryl citrate, monoglyceryl malate, diglyceryl malate, and these industrial mixtures which may contain small amounts of triglycerides from the manufacturing process. Also suitable are the addition products of 1 to 30, preferably 5 to 10 moles of ethylene oxide to the aforementioned partial glycerides.

[0062] Sorbitan esters Suitable sorbitan esters are sorbitan monoisostearate, sorbitan sesquisoisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan dierucate, sorbitan trierucate, sorbitan monolinoleate, sorbitan sesquilinoleate, sorbitan dilinoleate, sorbitan trilinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and industrial mixtures thereof. Also suitable are addition products of 1 to 30, preferably 5 to 10 moles of ethylene oxide to the aforementioned sorbitan esters.

[0063] Polyglycerol ester Typical examples of suitable polyglycerol esters are polyglyceryl-2 dipolyhydroxystearate (Dehymuls® PGPH), polyglycerin-3-diisostearate (Lameform® TGI), polyglyceryl-4 isostearate (Isolan® GI 34), polyglyceryl-3 oleate, diisostearoyl polyglyceryl-3 diisostearate (Isolan® PDI), polyglyceryl-3 methylglucose distearate (Tego Care® 450), polyglyceryl-3 beeswax (Cera Bellina®), polyglyceryl-4 caprate (Polyglycerol Caprate T2010 / 90), polyglyceryl-3 cetyl ether (Chimexane® NL), polyglyceryl-3 distearate (Cremophor® GS 32) and polyglyceryl polyricinoleate (Admul® WOL 1403), polyglyceryl dimelate isostearate and mixtures thereof. Examples of other suitable polyol esters are mono-, di- and triesters of trimethylolpropane or pentaerythritol with lauric acid, coconut fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid, etc. optionally reacted with 1 to 30 mol of ethylene oxide.

[0064] Tetraalkylammonium salts Surfactants that are active as cations contain, in the cation, a hydrophobic polymer group necessary for surfactant activity by dissociating in an aqueous solution. An important representative group of cationic surfactants has the general formula: (R 1 R 2 R 3 R 4 N + )X - are tetraalkylammonium salts. Here, R 1 represents C1-C8 alkyl or alkenyl (alk(en)yl), and R 2 , R 3 and R 4Each independently represents an alkyl or alkenyl group having 1 to 22 carbon atoms. X is a counterion, preferably selected from the group consisting of halides, alkyl sulfates and alkyl carbonates. Cationic surfactants in which the nitrogen group is substituted with two long acyl groups and two short alkyl or alkenyl groups are particularly preferred.

[0065] Esterquats A further class of cationic surfactants that are particularly useful as co-surfactants in the present invention is represented by the so-called esterquats. Esterquats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by relevant methods of preparative organic chemistry. In this regard, reference is made to International Patent Application WO91 / 01295, in which triethanolamine is partially esterified with a fatty acid in the presence of hypophosphorous acid, air is passed through the reaction mixture, and the whole is quaternized with dimethyl sulfate or ethylene oxide. Further, German Patent No. 4308794 describes a process for producing solid esterquats in which the quaternization of triethanolamine esters is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0066] Typical examples of esterquats suitable for use in accordance with the present invention are products in which the acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, where RCO is an acyl group containing 6 to 10 carbon atoms, and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and their industrial mixtures, such as so-called head-fractionated fatty acids. Esterquats in which the acyl component is derived from a monocarboxylic acid containing 8 to 10 carbon atoms are preferably used. Other esterquats are those in which the acyl component is derived from a dicarboxylic acid such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, preferably adipic acid. Overall, mixtures of monocarboxylic acids in which the acyl component contains 6 to 22 carbon atoms and esterquats derived from adipic acid are preferably used. The molar ratio of monocarboxylic acid to dicarboxylic acid in the final esterquat may range from 1:99 to 99:1, preferably from 50:50 to 90:10, more particularly from 70:30 to 80:20. In addition to quaternized fatty acid triethanolamine esters salts, other suitable esterquats are quaternized ester salts of diethanolalkylamines or 1,2-dihydroxypropyldialkylamines with mono / dicarboxylic acid mixtures. Esterquats may be obtained from fatty acids or from the corresponding triglycerides admixed with the corresponding dicarboxylic acid. European Patent No. 0750606 proposes such a process as a representative of the relevant prior art. To produce the quaternized ester, a mixture of monocarboxylic acid and dicarboxylic acid and triethanolamine may be used in a molar ratio of 1.1:1 to 3:1 (based on the available carboxyl functional groups). Considering the performance of the esterquat, a ratio of 1.2:1 to 2.2:1, preferably 1.5:1 to 1.9:1 has proven to be particularly advantageous. Preferred esterquats are industrial mixtures of mono-, di-, triesters with an average degree of esterification of 1.5 to 1.9.

[0067] Superfatting Agents and Consistency Factors Superfatting agents may be selected from substances such as lanolin and lecithin, polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides. Fatty acid alkanolamides also function as foam stabilizers.

[0068] The consistency factors mainly used are fatty alcohols or hydroxy fatty alcohols containing 12 to 22, preferably 16 to 18 carbon atoms, as well as partial glycerides, fatty acids or hydroxy fatty acids. Combinations of these substances with alkyl oligoglucosides and / or fatty acid N-methyl glucamides and / or polyglycerol poly-12-hydroxystearates of the same chain length are preferably used.

[0069] Thickeners and Rheology Additives Suitable thickeners are polymeric thickeners such as Aerosil® type (hydrophilic silica), polysaccharides, more particularly xanthan gum, guar gum, agar agar, alginate and tylose, carboxymethyl cellulose and hydroxyethyl cellulose, as well as relatively high molecular weight polyethylene glycol monoesters and diesters of fatty acids, polyacrylates (e.g. Carbopols® [Goodrich] or Synthalens® [Sigma]), polyacrylamides, polyvinyl alcohol and polyvinyl pyrrolidone, surfactants such as ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, a narrow range of fatty alcohol ethoxylates, and electrolytes such as sodium chloride and ammonium chloride.

[0070] Polymers Suitable cationic polymers include, for example, cationic cellulose derivatives such as quaternized hydroxyethyl cellulose available under the name Polymer JR 400 (registered trademark) from Amerchol, cationic starch, copolymers of diallyl ammonium salts and acrylamide, quaternized vinyl pyrrolidone / vinyl imidazole polymers such as Luviquat (registered trademark) (BASF), condensates of polyglycols and amines, quaternized collagen polypeptides such as lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat (registered trademark) L, Grunau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers such as amodimethicone, copolymers of adipic acid and dimethylaminohydroxypropyl diethylenetriamine (Cartaretine (registered trademark), Sandoz), copolymers of acrylic acid and dimethyldiallylammonium chloride (Merquat (registered trademark) 550, Chemviron), polyaminopolyamides and their crosslinked water-soluble polymers, cationic chitin derivatives such as quaternized chitosan (optionally with a microcrystalline distribution), condensation products of dihaloalkyls such as dibromobutane and bis-dialkylamines such as bis-dimethylamino-1,3-propane, cationic guar gums such as Jaguar (registered trademark) CBS, Jaguar (registered trademark) C-17, Jaguar (registered trademark) C-16 from Celanese, quaternized ammonium salt polymers such as Mirapol (registered trademark) A-15, Mirapol (registered trademark) AD-1, Mirapol (registered trademark) AZ-1 from Miranol, and various polyquaternium types (such as 6, 7, 32 or 37) commercially available under the trade names Rheocare (registered trademark) CC and Ultragel (registered trademark) 300.

[0071] Suitable anionic, zwitterionic, amphoteric and non-ionic polymers are, for example, vinyl acetate / crotonic acid copolymers, vinyl pyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copolymers and their esters, uncrosslinked and polyol-crosslinked polyacrylic acids, acrylamidopropyltrimethylammonium chloride / acrylate copolymers, octylacrylamide / methyl methacrylate / tert.-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymers, vinyl pyrrolidone / dimethylaminoethyl methacrylate / vinyl caprolactam terpolymers and optionally derivatized cellulose ethers and silicones.

[0072] Pearlizing Waxes Suitable pearlizing waxes are, for example, alkylene glycol esters, especially ethylene glycol distearate; fatty acid alkanolamides, especially coco fatty acid diethanolamide; partial glycerides, especially stearic acid monoglyceride; esters of polybasic, optionally hydroxy-substituted carboxylic acids with fatty alcohols containing 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; fatty compounds, such as fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, each containing at least 24 carbon atoms, especially lauron and distearyl ether; fatty acids, such as stearic acid, hydroxystearic acid or behenic acid, ring-opening products of olefin epoxides containing 12 to 22 carbon atoms with fatty alcohols containing 12 to 22 carbon atoms and / or polyols containing 2 to 15 carbon atoms and 2 to 10 hydroxyl groups, and mixtures thereof.

[0073] Silicones Suitable silicones can be selected from the group consisting of: acetylmethylsilanol mannuronate, acetylmethionylmethylsilanol elastinate acrylates / behenyl, acrylate / dimethicone methacrylate copolymer, acrylate / behenyl methacrylate / dimethicone methacrylate copolymer, acrylate / bis-hydroxypropyl dimethicone crosspolymer, acrylate / dimethicone copolymer, acrylate / dimethicone methacrylate / ethylhexyl acrylate copolymer, acrylate / dimethiconol acrylate copolymer, acrylate / ethylhexyl acrylate / dimethicone methacrylate copolymer, acrylate / octylacrylamide / diphenyl amodimethicone copolymer, acrylate / polytrimethylsiloxymethacrylate copolymer, acrylate / propyltrimethicone methacrylate copolymer, acrylate / stearyl acrylate / dimethicone methacrylate copolymer, acrylate / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate copolymer, acrylate / trifluoropropyl methacrylate / polytrimethylsiloxymethacrylate copolymer, aminobispropyl dimethicone, aminoethylaminopropyl dimethicone, aminopropyl dimethicone, aminopropylphenyltrimethicone, aminopropyltriethoxysilane, ammonium dimethicone PEG-7 sulfate, amodimethicone, amodimethicone hydroxystearate, amodimethicone / silsesquioxane copolymer, ascorbyl carboxydecyltrisiloxane, ascorbylmethylsilanol pectinate, behenoxy dimethicone, behentrimonium dimethicone PEG-8 phthalate, behenyldimethicone, bisamino PEG / PPG-41 / 3 aminoethyl PG-propyl dimethicone, bis-amino-propyl / ethoxyaminopropyl dimethicone, bis(butylbenzoate) diaminotriazine aminopropyltrisiloxane, bis-butyl dimethicone polyglyceryl-3, bis-butoxy amodimethicone / PEG-60 copolymer, bis(C13-15 alkoxy) hydroxybutyramide amodimethicone, bis(C13-15 alkoxy) PG-amodimethicone,Bis(C1-8 alkyl lauroyl lysine decyl carboxamide) dimethicone, bis-cetyl cetyl dimethicone,

[0074] Bis-cetyl / PEG-8 cetyl PEG-8 dimethicone, bis-diphenylethyldisiloxane, bis-ethylethylmethicone, bis-gluconamidoethyaminopropyldimethicone, bis-hydrogendimethicone, bis-hydroxyethoxypropyldimethicone bis-hydroxylauryl, dimethicone / IPDI copolymer, bis-hydroxy / methoxyamodimethicone, bis-hydroxypropyldimethicone behenate, bis-hydroxypropyldimethicone / SMDI copolymer, bis-isobutyl PEG-14 / amodimethicone copolymer, bis-isobutyl PEG-15 / amodimethicone copolymer, bis-isobutyl PEG / PPG-20 / 35 / amodimethicone copolymer, bis-isobutyl PEG / PPG-10 / 7 / dimethicone copolymer, bis-isobutyl PEG-24 / PPG-7 / dimethicone copolymer, bis-PEG-1 dimethicone, bis-PEG-4 dimethicone, bis-PEG-8 dimethicone, bis-PEG-12 dimethicone, bis-PEG-20 dimethicone, bis-PEG-12 dimethicone beeswax, bis-PEG-12 dimethicone candelillate, bis-PEG-15 dimethicone / IPDI copolymer, bis-PEG-15 methyl ether dimethicone, bis-PEG-18 methyl ether dimethylsilane, bis-PEG / PPG-14 / 14 dimethicone, bis-PEG / PPG-15 / 5 dimethicone, bis-PEG / PPG-18 / 6 dimethicone, bis-PEG / PPG-20 / 20 dimethicone, bis-PEG / PPG-16 / 16 PEG / PPG-16 / 16 dimethicone, bis-PEG / PPG-20 / 5 PEG / PPG-20 / 5 dimethicone, bisphenylhexamethicone, bis-phenylpropyldimethicone, bispolyethylenedimethicone, bis-(polyglyceryl-3 oxyphenylpropyl)dimethicone, bis-(polyglyceryl-7 oxyphenylpropyl)dimethicone, bis-PPG-15 dimethicone / IPDI copolymer, bis(PPG-7 undecenes-21)dimethicone, bis-stearyldimethicone, bis-trimethoxysilylethyltetramethyldisiloxyethyldimethicone, bis-vinyldimethicone, bis-vinyldimethicone / dimethicone copolymer, borage seed oil (Borage SeedOil) PEG-7 Dimethicone Esters, Butyl Acrylate / C6-14 Perfluoroalkyl Ethyl Acrylate / Mercaptopropyldimethylsilicone Copolymer, Butyl Acrylate / Hydroxypropyl Dimethicone Acrylate Copolymer,

[0075] Butyldimethylconacrylate / Cyclohexyl Methacrylate / Ethylhexyl Acrylate Copolymer, Butyldimethylcon Methacrylate / Methyl Methacrylate Crosspolymer, t-Butyldimethylsilyl Grape Seed Extract, Butylpolydimethylsiloxyethylene / Propylene / Vinyl Norbornene Copolymer, C6-8 Alkyl C3-6 Alkyl Glucoside Dimethicone, C20-24 Alkyl Dimethicone, C24-28 Alkyl Dimethicone, C26-28 Alkyl Dimethicone, C30-45 Alkyl Dimethicone, C30-60 Alkyl Dimethicone, C32 Alkyl Dimethicone, C30-45 Alkyl Dimethicone / Policyclohexene Oxide Crosspolymer, C26-28 Alkyl Dimethylsilyl Polypropylsilsesquioxane, C30-45 Alkyl Dimethylsilyl Polypropylsilsesquioxane, C20-24 Alkyl Methicone, C24-28 Alkyl Methicone, C26-28 Alkyl Methicone, C30-45 Alkyl Methicone, C20-28 Alkyl Perfluorodecylethoxydimethicone, C26-54 Alkyl Tetradecyldimethicone, Caprylyl Dimethicone, Caprylyl Dimethicone Ethoxyglycoside, Caprylyl Methicone, Caprylyl Trimethicone, Carboxydecyl Trisiloxane, Castor Oil Bis-Hydroxypropyl Dimethicone Ester Cerotyl Dimethicone, Cetearyl Dimethicone Crosspolymer, Cetearyl Dimethicone / Vinyl Dimethicone Crosspolymer, Cetearyl Methicone, Cetrimonium Carboxydecyl PEG-8 Dimethicone, Cetrimonium Dimethicone PEG-7 Phthalate, Cetyl Behenyl Dimethicone, Cetyl Dimethicone, Cetyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Cetyl Hexacosyl Dimethicone, Cetyl Oxydimethicone, Cetyl PEG-8 Dimethicone, Cetyl PEG / PPG-15 / 15 Butyl Ether Dimethicone, Cetyl PEG / PPG-7 / 3 Dimethicone, Cetyl PEG / PPG-10 / 1 Dimethicone, Cetyl Triethylmonium Dimethicone PEG-8 Phthalate, Cetyl Triethylmonium Dimethicone PEG-8 Succinate, Copper Acetyltyrosine Methylsilanol, Copper PCA Methylsilanol, C4-14 Perfluoroalkyl Ethoxydimethicone, Cycloethoxymethicone, Cycloheptasiloxane, CyclohexasiloxaneCyclomethicone,

[0076] Cyclopentasiloxane, Cyclophenylmethylcon, Cyclotetrasiloxane, m-Cyclovinylmethylcon, Cystine Bis-PG-Propylsilane Triol, DEA PG-Propyl PEG / PPG-18 / 21 Dimethicone, Diisostearoyl Trimethylolpropane Siloxysilicate, Dilauroyl Trimethylolpropane Siloxysilicate, Dilinoleamidopropyl Dimethylamine Dimethicone PEG-7 Phosphate, Dimethicone, Dimethicone Crosspolymer, Dimethicone Crosspolymer-3, Dimethicone / Divinyldimethylsilane / Silsesquioxane Crosspolymer, Dimethicone Ethoxy Glucoside, Dimethicone Hydroxypropyltrimonium Chloride, Dimethicone / Mercaptopropylmethylcon Copolymer, Dimethicone PEG-15 Acetate, Dimethicone PEG-8 Adipate, Dimethicone PEG-7 Avocadoate, Dimethicone PEG-8 Avocadoate, Dimethicone PEG-8 Beeswax, Dimethicone PEG-8 Benzoate, Dimethicone PEG-8 Borageate, Dimethicone PEG-7 Cocoate, Dimethicone / PEG-10 Crosspolymer, Dimethicone / PEG-10 / 15 Crosspolymer, Dimethicone / PEG-15 Crosspolymer, Dimethicone PEG-7 Isostearate, Dimethicone PEG-8 Isostearate, Dimethicone PEG-7 Lactate, Dimethicone PEG-8 Lanolate, Dimethicone PEG-8 Laurate, Meadowfoam Oil Fatty Acid PEG-8 Dimethicone, Dimethicone PEG-7 Octyldodecyl Citrate, Dimethicone PEG-7 Olivate, Dimethicone PEG-8 Olivate, Dimethicone PEG-7 Phosphate, Dimethicone PEG-8 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG-7 Phthalate, Dimethicone PEG-8 Phthalate, Dimethicone PEG-8 Polyacrylate, Dimethicone PEG / PPG-20 / 23 Benzoate, Dimethicone PEG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phosphate, Dimethicone PEG-7 Succinate, Dimethicone PEG-8 Succinate, Dimethicone PEG-7 Sulfate, Dimethicone PEG-7 Undecylenate,

[0077] Dimethicone PG - Diethylmonium Chloride, Dimethicone / Phenylvinyl Dimethicone Crosspolymer, Dimethicone / Polyglycerin - 3 Crosspolymer, Dimethicone / PPG - 20 Crosspolymer, Dimethiconepropyl Ethylenediamine Behenate, Dimethiconepropyl PG - Betaine, Dimethicone / Silsesquioxane Copolymer, Dimethicone Silylate, Dimethicone / Inyl Dimethicone Crosspolymer, Dimethicone / Vinyltrimethylsiloxysilicate Crosspolymer, Dimethiconol, Dimethiconol Arginine, Dimethiconol Beeswax, Dimethiconol Behenate, Dimethiconol Borate, Dimethiconol Candelilla, Dimethiconol Carnauba, Dimethiconol Cysteine, Dimethiconol Dhupa Butterate, Dimethiconol Fluoroalcohol Dilinoate, Dimethiconol Hydroxystearate, Dimethiconol Illipe Butterate, Dimethiconol / IPDI Copolymer, Dimethiconol Isostearate, Dimethiconol Kokum Butterate, Dimethiconol Lactate, Dimethiconol Meadowfoam Oil Fatty Acid Salt, Dimethiconol Methionine, Dimethiconol / Methylsilanol / Silicate Crosspolymer, Dimethiconol Mohwa Butterate, Dimethiconol Panthenol, Dimethiconol SalButterate), dimethiconol / silica cross-polymer, dimethiconol / silsesquioxane copolymer, dimethiconol stearate, dimethiconol / stearyl, methicone / phenyltrimethicone copolymer, dimethoxysilylethylenediaminopropyldimethicone, dimethylaminopropylamide PCA dimethicone, dimethyloxobenzodioxasilane, dimethylsilanol hyaluronate, dioleyl tocopheryl methyl silanol, diphenyl amodimethicone, diphenyl dimethicone, diphenyl dimethicone cross-polymer diphenyl dimethicone? / inyl diphenyl dimethicone / silsesquioxane cross-polymer (Diphenyl Dimethicone Crosspolymer Diphenyl Dimethicone? / inyl Diphenyl Dimethicone / Silsesquioxane Crosspolymer), diphenylethylbenzyl oxy disiloxane, diphenylisopropyldimethicone, diphenylsiloxyphenyl / propyltrimethicone,

[0078] Diphenylsiloxyphenyltrimethicone disiloxane, Amodimethicone succinamide disodium, PEG-12 dimethicone sulfosuccinate disodium, PEG-8 lauryl dimethicone sulfosuccinate disodium, Divinyl dimethicone / dimethicone copolymer, Divinyl dimethicone / dimethicone crosspolymer, Drometrizole trisiloxane, Ethylhexyl acrylate / VP / dimethicone methacrylate copolymer, Ethyl methyl silicone, Ethyl trisiloxane, Fluoro C2-8 alkyldimethyl silicone, Gluconamide propylaminopropyl dimethicone, 4-(2-beta-glucopyranosyloxy)propoxy-2-hydroxybenzophenone, Glyceryl undecyldimethyl silicone, Glycidoxy dimethicone, Hexadecyl methyl silicone, Hexyl dimethyl silicone, Hexyl methyl silicone, Hexyl trimethoxysilane, Hydrogen dimethicone, Hydrogen dimethicone / octylsilsesquioxane copolymer, Hydrolyzed collagen PG-propyl dimethiconol, Hydrolyzed collagen PG-propyl methyl silanediol, Hydrolyzed collagen PG-propyl silanetriol, Hydrolyzed keratin PG-propyl methyl silanediol, Hydrolyzed sesame protein PG-propyl methyl silanediol, Hydrolyzed silk PG-propyl methyl silanediol, Hydrolyzed silk PG-propyl methyl silanediol crosspolymer, Hydrolyzed soybean protein / dimethicone PEG-7 acetate, Hydrolyzed soybean protein PG-propyl methyl silanediol, Hydrolyzed vegetable protein PG-propyl silanetriol, Hydrolyzed wheat protein / cystine bis-PG-propyl silanetriol copolymer, Hydrolyzed wheat protein / dimethicone PEG-7 acetate, Hydrolyzed wheat protein / dimethicone PEG-7 phosphate copolymer, Hydrolyzed wheat protein PG-propyl methyl silanediol, Hydrolyzed wheat protein PG-propyl silanetriol, Hydroxyethyl acetomonium PG-dimethicone, Hydroxypropyl dimethicone, Hydroxypropyl dimethicone behenate, Hydroxypropyl dimethicone isostearate, Hydroxypropyl dimethicone stearate,

[0079] Isobutyl methacrylate / bis-hydroxypropyl dimethicone acrylate copolymer, Isobutyl methacrylate / trifluoroethyl methacrylate / bis-hydroxypropyl dimethicone acrylate copolymer, Isopentyl trimethoxycinnamate trisiloxane, Isopoly glyceryl-3 dimethicone, Isopoly glyceryl-3 dimethiconol, Isopropyl titanium triisostearate / triethoxysilyl ethyl, Polydimethylsiloxyethyl dimethicone crosspolymer, Isostearyl carboxy decyl PEG-8 dimethicone, Lactoyl methyl silanol elastinate, Lauryl dimethicone, Lauryl dimethicone PEG-15 crosspolymer, Lauryl dimethicone PEG-10 phosphate, Lauryl dimethicone / poly glyceryl-3 crosspolymer, Lauryl methylicone, Lauryl PEG-8 dimethicone, Lauryl PEG-10 methyl ether dimethicone, Lauryl PEG-9 polydimethylsiloxyethyl dimethicone, Lauryl PEG / PPG-18 / 18 methylicone, Lauryl phenyl isopropyl methylicone, Lauryl phenyl propyl methylicone, Lauryl polydimethylsiloxyethyl dimethicone / bis-vinyl dimethicone crosspolymer, Lauryl poly glyceryl-3 polydimethylsiloxyethyl dimethicone, Lauryl trimethicone, Linoleamidopropyl PG-dimonium chloride phosphate dimethicone, Methacryloylpropyl trimethoxysilane, Methylicone, Methoxy amodimethicone / silsesquioxane copolymer, Methoxy cinnamidopropyl polysilsesquioxane, Methoxy cinnamoylpropyl silsesquioxane silicate, Methoxy PEG-13 ethyl polysilsesquioxane, Methoxy PEG / PPG-7 / 3 aminopropyl dimethicone, Methoxy PEG / PPG-25 / 4 dimethicone, Methoxy PEG-10 propyl trimethoxysilane, Methyl eugenyl PEG-8 dimethicone, Methyl polysiloxane emulsion, Methyl silanol acetyl methionate, Methyl silanol acetyl tyrosine, Methyl silanol ascorbate, Methyl silanol carboxymethyl theophylline, Methyl silanol carboxymethyl theophylline arginate, Methyl silanol elastinate, Methyl silanol glycyrrhetinate,Methylsilanol hydroxyproline,

[0080] Methylsilanol hydroxyproline aspartate, methylsilanol mannuronate, methylsilanol PCA, methylsilanol PEG-7 glyceryl cocoate, methylsilanol / silicate copolymer, methylsilanol spirulinate, methylsilanol tri-PEG-8 glyceryl cocoate, methyltrimethicone, methyltrimethoxysilane, myristylamidopropyldimethylamine dimethicone PEG-7 phosphate, myristyl dimethicone, myristyl trisiloxane, nylon-611 / dimethicone copolymer, PCA dimethicone, PEG-7 amodimethicone, PEG-8 amodimethicone, PEG-8 cetyl dimethicone, PEG-3 dimethicone, PEG-6 dimethicone, PEG-7 dimethicone, PEG-8 dimethicone, PEG-9 dimethicone, PEG-10 dimethicone, PEG-12 dimethicone, PEG-14 dimethicone, PEG-17 dimethicone, PEG-10 dimethicone cross polymer, PEG-12 dimethicone cross polymer, PEG-8 dimethicone dimer dilinoleate, PEG-8 dimethicone / dimer dilinoleic acid copolymer, PEG-10 dimethicone / vinyl dimethicone cross polymer, PEG-8 distearyldimonium chloride PG-dimethicone, PEG-10 / lauryl dimethicone cross polymer, PEG-15 / lauryl dimethicone cross polymer, PEG-15 / lauryl polydimethylsiloxyethyl dimethicone cross polymer, PEG-8 dimethicone, PEG-6 dimethicone acetate, PEG-6 methyl ether dimethicone, PEG-7 methyl ether dimethicone, PEG-8 methyl ether dimethicone, PEG-9 methyl ether dimethicone, PEG-10 methyl ether dimethicone, PEG-11 methyl ether dimethicone, PEG-32 methyl ether dimethicone, PEG-8 methyl ether triethoxysilane, PEG-10 nonafluorohexyl dimethicone copolymer, PEG-4 PEG-12 dimethicone, PEG-8 PG-cocoglucoside dimethicone, PEG-9 polydimethylsiloxyethyl dimethicone, PEG / PPG-20 / 22 butyl ether dimethicone, PEG / PPG-22 / 22 butyl ether dimethicone,

[0081] PEG / PPG-23 / 23 Butyl Ether Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-27 / 9 Butyl Ether Dimethicone, PEG / PPG-3 / 10 Dimethicone, PEG / PPG-4 / 12 Dimethicone, PEG / PPG-6 / 4 Dimethicone, PEG / PPG-6 / 11 Dimethicone, PEG / PPG-8 / 14 Dimethicone, PEG / PPG-8 / 26 Dimethicone, PEG / PPG-10 / 2 Dimethicone, PEG / PPG-12 / 16 Dimethicone, PEG / PPG-12 / 18 Dimethicone, PEG / PPG-14 / 4 Dimethicone, PEG / PPG-15 / 5 Dimethicone, PEG / PPG-15 / 15 Dimethicone, PEG / PPG-16 / 2 Dimethicone, PEG / PPG-16 / 8 Dimethicone, PEG / PPG-17 / 18 Dimethicone, PEG / PPG-18 / 6 Dimethicone, PEG / PPG-18 / 12 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG / PPG-20 / 6 Dimethicone, PEG / PPG-20 / 15 Dimethicone, PEG / PPG-20 / 20 Dimethicone, PEG / PPG-20 / 23 Dimethicone, PEG / PPG-20 / 29 Dimethicone, PEG / PPG-22 / 23 Dimethicone, PEG / PPG-22 / 24 Dimethicone, PEG / PPG-23 / 6 Dimethicone, PEG / PPG-25 / 25 Dimethicone, PEG / PPG-27 / 27 Dimethicone, PEG / PPG-30 / 10 Dimethicone, PEG / PPG-25 / 25 Dimethicone / Acrylate Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG / PPG-24 / 24 Methyl Ether Glycidoxy Dimethicone, PEG / PPG-10 / 3 Oleyl Ether Dimethicone, PEG / PPG-5 / 3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trifluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorocaprylyl riethoxysilylethyl methyl silicone (Perfluorocaprylyl riethoxysilylethylMethicone), perfluorononyldimethylsilicone, perfluorononyldimethylsilicone / methicone / amidomethicone copolymer, perfluorononylethylcarboxydecyl behenyldimethylsilicone, perfluorononylethylcarboxydecyl hexacosyldimethylsilicone, perfluorononylethylcarboxydecyl lauryl / behenyldimethylsilicone, perfluorononylethylcarboxydecyl lauryldimethylsilicone, perfluorononylethylcarboxydecyl PEG-8 dimethylsilicone, perfluorononylethylcarboxydecyl PEG-10 dimethylsilicone,

[0082] Perfluorononyl ethyl dimethicone / methicone copolymer, perfluorononyl ethyl PEG-8 dimethicone, perfluorononyl ethyl stearyl dimethicone, perfluorooctyl ethyl / diphenyldimethylsilicone copolymer, perfluorooctyl ethyl triethoxysilane, perfluorooctyl ethyl trimethoxysilane, perfluorooctyl ethyl trisiloxane, perfluorooctyl triethoxysilane, PG-aminodimethicone, phenethyl dimethicone, phenethyl disiloxane, phenyl dimethicone, phenyl isopropyl dimethicone, phenyl methicone, phenyl methiconol, phenylpropyl dimethylsiloxysilicate, phenylpropyl ethyl methicone, phenylpropyl trimethicone, phenylpropyl trimethicone / diphenylmethicone, phenyl trimethicone, platinum divinyldisiloxane, polyacrylate-6, polydiethylsiloxane, polydimethylsiloxyethyl dimethicone / bis-vinyl dimethicone cross polymer, polydimethylsiloxyethyl dimethicone / methicone copolymer, polydimethylsiloxy PEG / PPG-24 / 19 butyl ether silsesquioxane, polydimethylsiloxy PPG-13 butyl ether silsesquioxane, polyglyceryl-3 disiloxane dimethicone, polyglyceryl-3 / lauryl polydimethylsiloxyethyl dimethicone cross polymer, polyglyceryl-3 polydimethylsiloxyethyl dimethicone, poly(glycol adipate) / bis-hydroxyethoxypropyl dimethicone copolymer, polymethyl silsesquioxane, polymethyl silsesquioxane / trimethylsiloxysilicate, polyphenyl silsesquioxane, polypropyl silsesquioxane, polysilicone-1, polysilicone-2, polysilicone-3, polysilicone-4, polysilicone-5, polysilicone-6, polysilicone-7, polysilicone-8, polysilicone-9, polysilicone-10, polysilicone-11, polysilicone-12, polysilicone-13, polysilicone-14, polysilicone-15

[0083] Polysilicone-16, Polysilicone-17, Polysilicone-18, Polysilicone-19, Polysilicone-20, Polysilicone-21, Cetyl Phosphate of Polysilicone-18, Cross Polymer of Polysilicone-1, Stearate of Polysilicone-18, Polyurethane-10, Dimethicone PEG-7 Potassium Pantothenate, Dimethicone PEG-7 Potassium Phosphate, PPG-12 Butyl Ether Dimethicone, PPG-2 Dimethicone, PPG-12 Dimethicone, PPG-27 Dimethicone, PPG-4 Oleth-10 Dimethicone, Propoxytetramethyl Piperidinyl Dimethicone, Propyltrimethicone, Quaternium-80, Retinoxytrimethylsilane, Silanediol Salicylate, Silanetriol, Silanetriol Alginate, Silanetriol Glutamate, Silanetriol Lysinate, Silanetriol Melaninate, Silanetriol Trehalose Ether, Silica, Dimethicone Silylate of Silica, Dimethylsilylate of Silica, Silylate of Silica, Silicon Carbide, Silicone Quaternium-1, Silicone Quaternium-2, Panthenol Succinate of Silicone Quaternium-2, Silicone Quaternium-3, Silicone Quaternium-4, Silicone Quaternium-5, Silicone Quaternium-6, Silicone Quaternium-7, Silicone Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15, Silicone Quaternium-16, Cross Polymer of Silicone Quaternium-16 / Glycidoxy Dimethicone, Silicone Quaternium-17, Silicone Quaternium-18, Silicone Quaternium-19, Silicone Quaternium-20, Silicone Quaternium-21, Silicone Quaternium-22, Silicone Quaternium-24, Silicone Quaternium-25, Siloxane Triol Alginate, Phytate of Siloxane Triol, Simethicone, Sodium of Carboxydecyl PEG-8 Dimethicone, Sodium of Dimethicone PEG-7 Acetylmethyl Taurate, Sodium of Dimethylsilanol Hyaluronate, Sodium of Methylsilanol Lactate, Sodium of Methylsilanol Mannuronate, Sodium of Methylsilanol PCA,PG-propyl dimethicone sodium thiosulfate copolymer, PG-propyl thiosulfate dimethicone sodium,

[0084] Sodium propoxyhydroxypropylthiosulfate silica, sorbitol silanediol, soy triethoxysilylpropyl dimonium chloride, stearalconium dimethicone PEG-8 phthalate, stearamidopropyl dimethicone, stearal dimonium hydroxypropyl panthenyl PEG-7 dimethicone phosphate chloride, stearal dimonium hydroxypropyl PEG-7 dimethicone phosphate chloride, stearoxy dimethicone, stearoxy methylicone / dimethicone copolymer, stearoxy trimethylsilane, stearyl aminopropyl methylicone, stearyl dimethicone, stearyl / lauryl methacrylate crosspolymer, stearyl methylicone, stearyl triethoxysilane (Stearyl Triethoxysilanek), stearyl trimethicone, styrene / acrylate / dimethylicone acrylate crosspolymer, styrene / acrylate / dimethylicone copolymer, TEA-dimethylicone PEG-7 phosphate, tetrabutoxypropyltrisiloxane, tetramethylhexaphenyltetrasiloxane, tetramethyltetraphenyltrisiloxane, tocopheryl oxypropyltrisiloxane, trideceth-9 PG-aminodimethicone, triethoxycaprylylsilane, triethoxysilylethyldimethylicone / methylicone copolymer, triethoxysilylethylpolydimethylsiloxyethyldimethylicone, triethoxysilylethylpolydimethylsiloxyethylhexyldimethylicone, triethoxysilylpropylcarbamoylethoxypropylbutyldimethylicone, trifluoromethyl C1-4 alkyldimethylicone, trifluoropropyl cyclopentasiloxane, trifluoropropyl cyclotetrasiloxane, trifluoropropyl dimethicone, trifluoropropyl dimethicone / PEG-10 crosspolymer, trifluoropropyl dimethicone / trifluoropropyldivinyldimethylicone crosspolymer, trifluoropropyl dimethicone / vinyltrifluoropropyl, dimethicone / silsesquioxane crosspolymer, trifluoropropyl dimethiconol, trifluoropropyl dimethyl / trimethylsiloxysilicate,

[0085] Trifluoropropylmethylcon, trimethoxycaprylylsilane, trimethoxysilyldimethylcon, trimethylpentaphenyltrisiloxane, trimethylsiloxamodimethylcon, trimethylsiloxyphenyldimethylcon, trimethylsiloxysilicate, trimethylsiloxysilicate / dimethylcon copolymer, trimethylsiloxysilicate / dimethylconol copolymer, trimethylsiloxysilylcarbamoyl pullulan, trimethylsilyl hydrolyzed conchiolin protein PG - propylmethylsilane diol copolymer, trimethylsilyl hydrolyzed silk PG - propylmethylsilane diol copolymer, trimethylsilyl hydrolyzed wheat protein PG - propylmethylsilane diol copolymer, trimethylsilyl pullulan, trimethylsilyl trimethylsiloxy glycolate, trimethylsilyl trimethylsiloxy lactate, trimethylsilyl trimethylsiloxy salicylate, triphenyltrimethicone, trisiloxane, tris - tributoxysiloxymethylsilane, undecyl acrylendimethylcon, vinyldimethylcon, vinyldimethylcon / lauryldimethylcon copolymer, vinyldimethylcon / methylcon silsesquioxane copolymer, vinyldimethyl / trimethylsiloxysilicate stearyldimethylcon copolymer, VP / dimethylconyl acrylate / polycarbamyl / polyglycol ester, carboxydecyltrisiloxane zinc and dimethylcon PEG - 8 succinate zinc, and mixtures thereof.

[0086] More preferably, the silicones that can be included in the mixture according to the present invention are dimethylcon, cyclomethicone, phenyltrimethicone, cyclohexasiloxane and cyclopentasiloxane. A detailed overview of suitable volatile silicones can be found in Todd et al., in Cosm. Toil. 91, 27 (1976).

[0087] Waxes and stabilizers In addition to the natural oils used, waxes may also be present in the preparation, more particularly natural waxes such as candelilla wax, carnauba wax, Japan wax, esparto grass wax, cork wax, guaruma wax, rice oil wax, sugar cane wax, oryctoleum wax, montan wax, beeswax, shellac wax, spermaceti, lanolin (wool wax), uropygial fat, ceresin, ozokerite (earth wax), petrolatum, paraffin wax and micro wax; chemically modified waxes (hard waxes) such as montan ester wax, Sasol wax, hydrogenated jojoba wax, and synthetic waxes such as polyalkylene wax and polyethylene glycol wax.

[0088] Metal salts of fatty acids such as magnesium, aluminum and / or zinc stearate or ricinoleate etc. may be used as stabilizers.

[0089] PRIMARY SUN PROTECTION FACTORS The primary sun protection factors in the context of the present invention are, for example, organic substances (light filters) which are liquid or crystalline at room temperature, absorb ultraviolet light and can release the absorbed energy in the form of radiation of a longer wavelength, for example heat.

[0090] The preparation according to the invention advantageously contains at least one UV-A filter and / or at least one UV-B filter and / or a broadband filter and / or at least one inorganic pigment. The preparation according to the invention preferably contains at least one UV-B filter or a broadband filter, more particularly preferably at least one UV-A filter and at least one UV-B filter.

[0091] The following UV filters can be preferably used within the context of the present invention, but are of course not limited thereto. The preferably used UV filters are selected from the group consisting of 1, 2, 3, 4, 5 or more of the following species: TIFF2025520126000005.tif239163

[0092] In a preferred embodiment, the sunscreen filter-forming component (ii) represents a blend of UVA filters and UVB filters selected from the group consisting of homosalate, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, butyl methoxydibenzoylmethane, ethylhexyl salicylate, and mixtures thereof. Particularly preferred is a blend of all these filters which is marketed under the trademark NeoHeliopan® Flat (SYMRISE) and also according to WO2020088778A1.

[0093] Suitable pigments include titanium oxide (TiO2), zinc oxide (ZnO), iron oxide (Fe2O3), zirconium oxide (ZrO2), silicon oxide (SiO2), manganese oxide (e.g., MnO), aluminum oxide (Al2O3), cerium oxide (e.g., Ce2O3) and / or mixtures thereof.

[0094] In a further preferred embodiment, the preparation according to the invention comprises a total amount of sunscreen agents, i.e., in particular UV filters and / or inorganic pigments (UV filter pigments), such that the preparation according to the invention can have a sun protection factor of 5 or more and 50 or less. Such a preparation according to the invention is particularly suitable for protecting the skin and hair.

[0095] SECONDARY SUN PROTECTION FACTORS In addition to the group of the first sunburn prevention factors described above, a second sunburn prevention factor of the antioxidant type may be used. The second sunburn prevention factor of the antioxidant type is one that interrupts the photochemical reaction chain that begins when ultraviolet rays penetrate the skin. Typical examples are amino acids (e.g., glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g., urocanic acid) and their derivatives, peptides, such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g., anserine), carotenoids, carotenes (e.g., α-carotene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g., dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (e.g., thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, α-linoleyl, cholesteryl and glyceryl esters) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and very small amounts of compatible amounts of sulfoximine compounds (e.g., buthionine sulfoximine, homocysteine sulfoximine, buthionine sulfone, penta-, hexa- and hepta-thionine sulfoximine), (metal) chelating agents (e.g., α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g., citric acid, lactic acid, malic acid), humic acids, bile acids, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g., linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (e.g., ascorbyl palmitate, Mg ascorbyl phosphate, ascorbyl acetate), tocopherol and its derivatives (e.g., vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate) and coniferyl benzoate of benzoin resin,Rutin and its derivatives, glycosyl rutin, ferulic acid, furfurylidene glucitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiaretic resin acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (for example, a dispersion in ethanol), zinc and its derivatives (for example, ZnO, ZnSO4), selenium and its derivatives (for example, selenomethionine), stilbene and its derivatives (for example, stilbene oxide, trans-stilbene oxide), and derivatives (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of these active substances suitable for the purposes of the present invention.

[0096] Advantageous inorganic second light-protecting pigments are finely dispersed metal oxides and metal salts, which are also mentioned in WO 2005 / 123101. The total amount of inorganic pigments, in particular hydrophobic inorganic micro-pigments, in the final cosmetic preparation according to the invention is advantageously in each case 0.1 to 30% by weight, preferably 0.5 to 10.0% by weight, based on the total weight of the formulation.

[0097] Equally preferred are particulate UV filters or inorganic pigments which can optionally be hydrophobized, for example oxides of titanium (TiO2), oxides of zinc (ZnO), oxides of iron (Fe2O3), oxides of zirconium (ZrO2), oxides of silicon (SiO2), oxides of manganese (for example MnO), oxides of aluminum (Al2O3), oxides of cerium (for example Ce2O3) and / or mixtures thereof can be used.

[0098] Agents of biological origin and antioxidants Examples of biogenic agents include, for example, tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, (deoxy)ribonucleic acid and its fragmented products, β-glucan, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudo-ceramides, essential oils, plant extracts such as Prunus genus extracts and Bambara groundnut extracts, and vitamin complexes.

[0099] The anti-oxidant agent breaks the chain of photochemical reactions caused by UV radiation penetrating the skin. Typical examples of these substances include amino acids (e.g., glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazole (e.g., urocanic acid) and its derivatives, peptides, such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g., anserine), carotenoids, carotenes (e.g., β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g., dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (e.g., thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, linoleyl, cholesteryl and glyceryl esters) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and their derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts), as well as sulfoximine compounds at very low tolerance levels (e.g., pmol~μmol / kg) (e.g., buthionine sulfoximine, homocysteine sulfoximine, buthionine sulfone, penta-, hexa-, heptathionine sulfoximine), and furthermore (metal) chelating agents (e.g., hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), hydroxy acids (e.g., citric acid, lactic acid, malic acid), humic acids, bile acids, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g., linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (e.g., ascorbyl palmitate, ascorbyl phosphate Mg, ascorbyl acetate), tocopherol and derivatives (e.g., vitamin E acetate), vitamin A and derivatives (vitamin A palmitate), and conifer aryl benzoate of benzoic resinbenzoate), rutinic acid and its derivatives, glycosylrutin, ferulic acid, furfurylidene glucitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiaretic resin acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (e.g., ZnO, ZnSO4), selenium and its derivatives (e.g., selenomethionine), stilbene and their derivatives (e.g., styrene oxide, trans-stilbene oxide) and suitable derivatives (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of these active ingredients according to the present invention are mentioned.

[0100] Active substances that regulate hair pigmentation Preferred active ingredients for brightening hair are selected from the group consisting of: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol derivatives, preferably 4-alkylresorcinols and 4-(1-phenylethyl)-1,3-dihydroxybenzene (phenylethylresorcinol), cyclohexylcarbamate (preferably one or more cyclohexylcarbamates disclosed in WO 2010 / 122178 and WO 2010 / 097480), sulfur-containing molecules, preferably glutathione or cysteine, α-hydroxy acids (preferably citric acid, lactic acid, malic acid), their salts and esters, N-acetyltyrosine and derivatives, undecylenoyl phenylalanine, gluconic acid, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethylphosphinic acid, thiourea derivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, preferably zinc chloride or zinc gluconate, tsujapricin and derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably senkyunolide, vinyl guaiacol, ethyl guaiacol, dioic acids, preferably octadecenedioic acid and / or azelaic acid, inhibitors of nitric oxide synthesis, preferably L-nitroarginine and its derivatives, 2,7-dinitroindazole or thiositruline, a metal chelating agent (preferably α-hydroxy fatty acid, phytic acid, humic acid, bile acid, bile extract, EDTA, EGTA and their derivatives), retinoid, soy milk and extract, a serine protease inhibitor or lipoic acid, or other synthetic or natural active substances for brightening the skin and hair, the latter being preferably used in the form of extracts from plants, preferably kumakoke-momo extract, rice extract, papaya extract, turmeric extract, mulberry fruit extract, benkoan extract, hamasuge extract, licorice root extract or components concentrated or isolated therefrom, preferably glabridin or licocalcone A, artocarpus extract, extracts of the gishigishi and ramulus species, extract of pine seeds (pine nuts), seed extract of the genus Vitis or stilbene derivatives isolated or concentrated therefrom, saxifraga extract, scutellaria extract, grape extract and / or microalgae extract, particularly in the form of Tetraselmis sueica extract.,

[0101] In this regard, advantageous skin and hair tanning active ingredients are substrates or substrate analogs of tyrosinase such as L-tyrosine, N-acetyltyrosine, L-DOPA or L-dihydroxyphenylalanine, xanthine alkaloids such as caffeine, theobromine and theophylline and their derivatives, proopiomelanocortin peptides such as ACTH, α-MSH, peptide analogs thereof and other substances that bind to melanocortin receptors, peptides such as Val-Gly-Val-Ala-Pro-Gly, Lys-Ile-Gly-Arg-Lys or Leu-Ile-Gly-Lys, purines, pyrimidines, folic acid, copper salts such as copper gluconate, copper chloride or copper pyrrolidonate, 1,3,4-oxadiazole-2-thiols such as 5-pyrazin-2-yl-1,3,4-oxadiazole-2-thiol, curcumin, zinc diglycinate (Zn(Gly)2), for example the manganese(II) bicarbonate complex ("pseudo-catalase") described in European Patent 0584178, for example the tetrasubstituted cyclohexene derivatives described in International Publication 2005 / 032501, isoprenoids described in International Publications 2005 / 102252 and 2006 / 010661, melanin derivatives such as Melasyn-100 and MelanZe, diacylglycerol, aliphatic or cyclic diols, psoralen, prostaglandins and their analogs, activators of adenylate cyclase, and compounds that activate the transfer of melanosomes to keratinocytes such as, for example, serine protease or PAR-2 receptor agonists, extracts of plants and plant parts of the Chrysanthemum species, Sangisorba species, curcuma extract, ulukum extract, rhubarb extract, microalgae extract, especially Isochrysis galbana extract, trehalose, erythrulose and dihydroxyacetone. Flavonoids that bring about skin and hair coloring or browning (for example, quercetin, rhamnetin, kaempferol, fisetin, genistein, daidzein, chrysin and apigenin, epicatechin, diosmin and diosmetin, morin, quercitrin, naringenin, hesperidin, phloridzin and phloretin) can also be used.

[0102] The amount of the above-mentioned example of the additional active ingredient (one or more compounds) for adjusting the pigmentation of the skin and hair in the product according to the present invention is preferably 0.00001 to 30% by weight, preferably 0.0001 to 20% by weight, particularly preferably 0.001 to 5% by weight based on the total weight of the preparation.

[0103] Hair growth activator or inhibitor The preparations and products according to the invention may also contain one or more hair growth activators, i.e., agents that stimulate hair growth. The hair growth activators are preferably pyrimidine derivatives such as 2,4-diaminopyrimidine-3-oxide (aminoxyl), 2,4-diamino-6-piperidinopyrimidine-3-oxide (minoxidil) and its derivatives, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidinopyrimidine and its derivatives, xanthine alkaloids such as caffeine, theobromine, theophylline and their derivatives, quercetin and its derivatives, dihydroquercetin (taxifolin) and its derivatives, potassium channel openers, antiandrogens, synthetic or natural 5-reductase inhibitors, nicotinic acid esters such as tocopheryl nicotinate, benzyl nicotinate, C1-C6 alkyl nicotinates, for example tripeptide Lys-Pro-Val, difenicipren, hormones, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives, proteins such as cyproterone acetate, spironolactone and other diuretics, calcineurin inhibitors such as FK506 (tacrolimus, fujimycin) and its derivatives, cyclosporin A and its derivatives, zinc and zinc salts, polyphenols, procyanidins, proanthocyanidins, plant sterols such as beta-sitosterol, biotin, eugenol, (±)-beta-citronellol, panthenol, for example glycogen derived from seaweed, microorganisms, algae, plants and for example from the genus Taraxacum (Leontodon or Taraxacum), Orthosiphon, Vitex, Coffea, Paullinia, Theobroma, Asiasarum, the genus Cucurbita or Styphnolobium, Serenoa repens (saw palmetto), Sophora flavescens, Pygeum africanum, Panicum miliaceum (PanicumIt is selected from the group consisting of extracts from plant parts such as Setaria italica, Cimicifuga racemosa, Glycine max, Eugenia caryophyllata, Cotinus coggygria, Hibiscus rosa-sinensis, Camellia sinensis, Ilex paraguariensis, Isochrysis galbana, licorice, grape, apple, barley or hop, or hydrolysates of rice or wheat.

[0104] Alternatively, the preparations and products according to the invention may comprise one or more hair growth inhibitors as defined above, i.e. agents which inhibit or prevent hair growth. The hair growth inhibitors are preferably activin, an activin derivative or an activin agonist, an ornithine decarboxylase inhibitor such as α-difluoromethylornithine, or pentacyclic triterpenes such as, for example, ursolic acid, betulin, betulinic acid, oleanolic acid and their derivatives, 5α-reductase inhibitors, androgen receptor antagonists, S-adenosylmethionine decarboxylase inhibitors, γ-glutamyltranspeptidase inhibitors, transglutaminase inhibitors, serine protease inhibitors derived from soybeans, microorganisms, algae, various microalgae or plants, and extracts from plant parts such as, for example, the families Fabaceae, Solanaceae, Poaceae, Convolvulaceae or Cucurbitaceae, the genus Chondrus, the genus Gloiopeltis, the genus Ceramium, Durvillea, Glycine max, Sanguisorba officinalis, Calendula officinalis, Hamamelis virginiana, Arnica montana, Salix alba, Hypericum perforatum or Gymnema sylvestre.

[0105] Physiological cooling agents and warming agents The physiological cooling agent is preferably selected from the group formed by the species shown in the following table (including its optical isomers and racemates). TIFF2025520126000006.tif253141 TIFF2025520126000007.tif105143

[0106] The physiological warming agent can be selected from the group consisting of capsaicin, dihydrocapsaicin, nordihydrocapsaicin, homocapsaicin, homodihydrocapsaicin nonivamide, and pepper extract.

[0107] Anti-inflammatory agent A suitable anti-inflammatory agent may be selected from the group formed by the following: (i) Steroidal anti-inflammatory substances of the corticosteroid type, particularly hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone (ii) Non-steroidal anti-inflammatory substances, particularly oxicams such as piroxicam or tenoxicam, salicylates such as aspirin, disalcid, solprin or fendosal, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin or clidanac, fenamates such as mefenamic, meclofenamic, flufenamic or niflumic, propionic acid derivatives such as ibuprofen, naproxen or benoxaprofen, pyrazoles such as phenylbutazone, oxyphenbutazone, febrazone or azapropazone (iii) Natural or naturally occurring anti-inflammatory substances, or substances that reduce redness and / or itching, in particular extracts or fractions from chamomile, aloe vera, Commiphora species, Rubia species, willow, speedwell, oats, calendula, arnica, St. John's wort, ivy, rosemary, Passiflora incarnata, witch hazel, ginger, echinacea, or their single active compounds, (iv) Histamine receptor antagonists, serine protease inhibitors (e.g., soybean extract), TRPV1 antagonists (e.g., 4-t-butylcyclohexanol), NK1 antagonists (e.g., aprepitant, hydroxyphenylpropanamide benzoic acid), cannabinoid receptor agonists (e.g., palmitoylethanolamine) and TRPV3 antagonists.

[0108] Antibacterial agents Suitable antibacterial agents are, in principle, all substances effective against Gram-positive bacteria, such as, for example, 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 2,4,4'-trichloro-2'-hydroxydiphenyl ether (triclosan), 4-chloro-3,5-dimethylphenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl)phenol, 2-benzyl-4-chlorophenol, 3-(4-chlorophenoxy)-1,2-propanediol, 3-iodo-2-propynyl butylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antibacterial fragrances, thymol, thyme oil, eugenol, clove oil, menthol, mint oil, farnesol, phenoxyethanol, glycerol monocaprate, glycerol monocaprylate, glycerol monolaurate (GML), diglycerol monocaprate (DMC), N-alkylamides of salicylic acid, such as n-octyl salicylamide or n-decyl salicylamide.

[0109] Enzyme inhibitors Suitable enzyme inhibitors are, for example, esterase inhibitors. These are preferably trialkyl citrates such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate, especially triethyl citrate (Hydagen CAT). These substances inhibit the enzyme activity and thereby reduce the formation of odors. Other substances suitable as esterase inhibitors are sterol sulfates or phosphates such as lanosterol, cholesterol, campesterol, stigmasterol and sitosterol sulfates or phosphates, dicarboxylic acids and their esters such as glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid and diethyl malonate, hydroxycarboxylic acids and their esters such as citric acid, malic acid, tartaric acid or diethyl tartrate, and zinc glycinate.

[0110] Odor absorbers and antiperspirant active ingredients A suitable odor absorbent is a substance that can absorb and retain most of the compounds that form odors. These substances lower the partial pressure of the individual components, thereby reducing their diffusion rate. In this process, it is important to ensure that the fragrance is not impaired. Odor absorbers have no effect on bacteria. These include, for example, as the main component, the complex zinc salt of ricinoleic acid, or certain almost odorless fragrances known to those skilled in the art as "fixatives", such as extracts of labdanum or styrax, or certain abietic acid derivatives. Odor masking agents are fragrances or essential oils that, in addition to functioning as odor masking agents, impart their respective fragrance notes to deodorants. Essential oils that may be mentioned are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracts from flowers, stems and leaves, fruits, peels, roots, woods, herbs and grasses, needles and branches, as well as resins and balsams. Similarly suitable are animal-derived ones, such as civet and castoreum. Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon types. Ester-type fragrance compounds are, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allylcyclohexyl propionate, styrallyl propionate and benzyl salicylate. Ethers include, for example, benzyl ethyl ether, aldehydes include, for example, straight-chain alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal, ketones include, for example, ionone and methyl cedryl ketone, alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol, and hydrocarbons mainly include terpenes and balsams.However, it is preferred to use mixtures of different fragrances that together create a pleasant fragrance note. Relatively low volatility essential oils are mainly used as aroma components and are also suitable as perfume oils, such as sage oil, chamomile oil, clove oil, Melissa oil, mint oil, cinnamon leaf oil, linden flower oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil, labdanum oil and lavandin oil. The use of bergamot oil, dihydromyrcenol, linalool, lyral, citronellol, phenylethyl alcohol, α-hexylcinnamaldehyde, geraniol, benzylacetone, cyclamen aldehyde, linalool, boisambrene forte, ambroxan, indole, hedione, sandelice, lemon oil, mandarin oil, orange oil, allylamyl glycolate, cyclovertal, lavandin oil, clarissa oil, β-damascone, geranium oil bourbon, cyclohexyl salicylate, Vertofix coeur, iso-E-super, Fixolide NP, evernyl, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, irotyl and floramat alone or in mixtures is preferred.

[0111] Suitable convergence antiperspirant active ingredients are primary salts of aluminum, zirconium or zinc. Such suitable antiperspirant active ingredients are, for example, aluminum chloride, aluminum chlorohydrate, aluminum dichlorohydrate, aluminum sesquichlorohydrate and their composite compounds, for example composite compounds with 1,2-propylene glycol, aluminum hydroxyallantoinate, aluminum chloride tartrate, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate and their composite compounds, for example composite compounds with amino acids such as glycine.

[0112] Film-forming agent and dandruff inhibitor Standard film-forming agents are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, acrylic polymers, quaternary cellulose derivatives, collagen, hyaluronic acid and its salts, and similar compounds.

[0113] Suitable anti-dandruff agents are piroctone olamine (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), Baypival® (climbazole), Ketoconazol® (4-acetyl-1-{4-[2-(2,4-dichlorophenyl)r-2-(1H-imidazol-1-ylmethyl)-1,3-dioxolan-c-4-ylmethoxyphenyl}-piperazine), ketoconazole, elubiol, selenium disulfide, colloidal sulfur, sulfur polyethylene glycol sorbitan monooleate, sulfur ricinole polyethoxylate, sulfur tar distillate, salicylic acid (or in combination with hexachlorophene), undecylenic acid, sodium monoethanolamide sulfosuccinate, Lamepon® UD (protein / undecylenic acid condensate), zinc pyrithione, aluminum pyrithione and magnesium pyrithione / dipyrithione magnesium sulfate.

[0114] Carriers and hydrotropes Preferred cosmetic carrier materials are solid or liquid (including highly viscous substances) at 25 °C and 1013 mbar, for example glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water and mixtures of two or more of the said liquid carrier materials with water. Optionally, these preparations according to the invention may be manufactured using preservatives or solubilizing agents. Other preferred liquid carrier substances which can be components of the preparations according to the invention are selected from the group consisting of oils such as vegetable oils, neutral oils and mineral oils.

[0115] Preferred solid carrier materials which can be constituents of the preparations according to the invention are hydrocolloids such as starch, degraded starch, chemically or physically modified starch, dextrin, (powdered) maltodextrin (preferably with a dextrose equivalent value of 5 to 25, preferably 10 to 20), lactose, silicon dioxide, glucose, modified cellulose, gum arabic, ghatti gum, tragacanth, karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar flour, carob bean flour, alginate, agar, pectin and inulin, and mixtures of two or more of these solids, in particular maltodextrin (preferably with a dextrose equivalent of 15 to 20), lactose, silicon dioxide and / or glucose.

[0116] Furthermore, hydrotropes such as ethanol, isopropyl alcohol or polyols may be used to improve the flow behavior. Suitable polyols preferably contain 2 to 15 carbon atoms and at least two hydroxyl groups. The polyol may contain other functional groups, more particularly amino groups, or may be modified with nitrogen. Typical examples are · glycerol · alkylene glycols such as ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycol with an average molecular weight of 100 to 1000 daltons · industrial oligoglycerol mixtures with a self-condensation degree of 1.5 to 10, such as industrial diglycerol mixtures with a diglycerol content of 40 to 50% by weight · methylol compounds such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol · lower alkyl glucosides, in particular those containing 1 to 8 carbon atoms in the alkyl group, such as methyl and butyl glucoside · sugar alcohols containing 5 to 12 carbon atoms, such as sorbitol or mannitol · Sugars containing 5 to 12 carbon atoms, such as glucose or sucrose · Amino sugars, such as glucosamine · Dialcoholamines, such as diethanolamine or 2-aminopropane-1,3-diol It is.

[0117] Preservatives and / or product protectants Suitable preservatives are listed in Annex 6, Parts A and B of the Kosmetikverordnung (Cosmetics Directive).

[0118] Suitable species can be selected from the group consisting of preservatives selected from the group consisting of the following. Benzoic acid and p-hydroxybenzoic acid, their esters and salts, benzyl benzoate, propionic acid and its salts, salicylic acid and its salts, 2,4-hexadienoic acid (sorbic acid) and its salts, levulinic acid and its salts, anisic acid and its salts, perillic acid and its salts, cinnamic acid and its salts, formaldehyde and paraformaldehyde, 4-hydroxybenzaldehyde, ortho-, meta- and para-anisaldehyde, cinnamaldehyde, cinnamic alcohol, 2-hydroxybiphenyl ether and its salts, 2-zinc-sulfide pyridine-N-oxide, inorganic sulfites and bisulfites, sodium iodate, chlorobutanol, 4-ethylmercury-(II) 5-amino-1,3-bis(2-hydroxybenzoic acid), its salts and esters, dehydroacetic acid, formic acid, 1,6-bis(4-amidino-2-bromophenoxy)-n-hexane and its salts, sodium salt of ethylmercury(II)-thiosalicylic acid, phenylmercury and its salts, 10-undecenoic acid and its salts, 5-amino-1,3-bis(2-ethylhexyl)-5-methyl-hexahydropyrimidine, 5-bromo-5-nitro-1,3-dioxane, 2-bromo-2-nitro-1,3-propanediol, 2,4-dichlorobenzyl alcohol, N-(4-chlorophenyl)-N‘-(3,4-dichlorophenyl)-urea, 4-chloro-m-cresol, 2,4,4’-trichloro-2’-hydroxy-diphenyl ether, 4-chloro-3,5-dimethylphenol, 1,1’-methylene-bis(3-(1-hydroxymethyl-2,4-dioxoimidazolidin-5-yl)urea), poly-(hexamethylenediguanidine) hydrochloride, (benzyloxymethoxy)-methanol hexamethylenetetramine, 1-(3-chloroallyl)-3,5,7-triaza-1-azonia-adamantane chloride, 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethyl-2-butanone, 1,3-bis-(hydroxymethyl)-5.5-Dimethyl-2,4-imidazolidinedione, 1,2-dibromo-2,4-dicyanobutane, 2,2'-methylene-bis(6-bromo-4-chlorophenol), bromochlorophenol, 5-chloro-2-methyl-3(2H)-isothiazolinone, 2-methyl-3(2H)-isothiazolinone and a mixture of magnesium chloride and magnesium nitrate, 2-octyl-2H-isothiazol-3-one, 1,2-benzisothiazol-3(2H)-one, 2-benzyl-4-chlorophenol, 3-(4-chlorophenoxy)-1,2-propanediol (chlorphenesin), 2-chloroacetamide, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, N-alkyl(C. 12 -C 22 ) trimethylammonium bromide and chloride, 4,4-dimethyl-1,3-oxazolidine, N-hydroxymethyl-N-(1,3-di(hydroxymethyl)-2,5-dioxoimidazolidin-4-yl)-N'-hydroxymethylurea, 1,6-bis(4-amidino-phenoxy)-n-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, 3-(4-chlorophenoxy)-1,2-propanediol, hyamine, alkyl-(C8-C 18 )-dimethylbenzyl-ammonium chloride, alkyl-(C8-C 18 )-dimethyl-benzyl-ammonium bromide, alkyl-(C8-C 18)-Dimethyl-benzyl-ammonium saccharinate, benzyl hemiformal, 3-iodo-2-propynyl butylcarbamate, hydroxymethyl-aminoacetate sodium or hydroxymethylaminoacetate sodium, imidazolidinyl urea, diazolidinyl urea, hydroxymethylglycinate sodium, DMDM hydantoin, tropolone, (ethylenedioxy)dimethanol, 2-bromo-2-(bromomethyl)pentanedinitrile, N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine, α,α’,α”-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol, pyridine-2-thiol-1-oxide, sodium salt, tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo[4,5-d]imidazole-2,5(1H,3H)-dione, 1,3-bis(hydroxymethyl)-1-(1,3,4-tris(hydroxy-methyl)-2,5-dioxoimidazolidin-4-yl)urea (diazolidinyl urea), 1,3-bis(hydroxy-methyl)-5,5-dimethylimidazolidine-2,4-dione, 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, cetylpyridinium chloride, caprylic hydroxamic acid, sorbic hydroxamic acid and mixtures thereof;1,3 - propanediol, methylpropanediol, 1,2 - pentanediol, 1,2 - hexanediol, 1,2 - octanediol, 1,2 - decanediol, 1,5 - pentanediol, 1,6 - hexanediol, 1,8 - octanediol, 1,2 - decanediol, ethylhexylglycerin, hexyloxy - propane - 1,2 - diol, heptyloxy - propane - 1,2 - diol, octyloxy - propane - 1,2 - diol, 3 - phenoxy - propane - 1,2 - diol, 3 - benzyloxy - propane - 1,2 - diol, 3 - phenylethyloxy - propane - 1,2 - diol, 3 - phenylpropyloxy - propane - 1,2 - diol, 3 - methylbenzyloxy - propane - 1,2 - diol, sorbitan caprylate, triclosan, climbazole, octopirox (1 - hydroxy - 4 - methyl - 6 - (2,4,4 - trimethylpentyl) - 2(1H) - pyridone, 2 - aminoethanol), chitosan, farnesol, 2 - butyloctanoic acid, 2 - benzylheptan - 1 - ol, glycerol monolaurate, bis(2 - pyridylthio)zinc 1,1’ - dioxide, N,N’ - (decane - 1,10) - diylbis(pyridin - 1 - yl - 4 - ylidene) - dioctan - 1 - amine dihydrochloride (octenidine dihydrochloride), thymol, eugenol, benzyl alcohol, 2 - phenylethyl alcohol, 3 - phenylpropanol, 2 - phenoxyethanol, 1 - phenoxy - propan - 2 - ol, 3 - phenoxypropanol, benzyloxymethanol, 4 - hydroxyacetophenone and mixtures thereof.;

[0119] Essential oil A suitable fragrance oil is a mixture of natural and synthetic fragrances. Natural fragrances include extracts of flowers (lily, lavender, rose, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, caraway, juniper), peels (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus, iris, calamus), woods (pinewood, sandalwood, guaiacwood, cedarwood, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), needles and twigs (fir, spruce, pine, cypress), resins and balsams (galbanum, elemi, benzoin, myrrh, olibanum, opoponax). Animal-derived raw materials, such as civet and beaver, can also be used.

[0120] Woody-scented fragrance A suitable woody-scented fragrance is selected from the following group: TIFF2025520126000008.tif158164

[0121] Amber-scented fragrance A suitable amber-scented fragrance is selected from the following group: TIFF2025520126000009.tif54164

[0122] Fruity-scented fragrance A suitable fruity-scented fragrance is selected from the following group: TIFF2025520126000010.tif192164 TIFF2025520126000011.tif183162

[0123] Musk-scented fragrance A suitable musk-scented fragrance is selected from the following group: TIFF2025520126000012.tif86164 The fragrance summarized above also represents a preferred embodiment of the second fragrance that forms the main component of the claimed perfume composition.

[0124] Dye Suitable dyes are, for example, substances suitable for cosmetic purposes and approved as described in the publication "Kosmetische Farbemittel" by the Farbstoff-kommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, pages 81 - 106. Examples thereof include cochineal red A (C.I. 16255), patent blue V (C.I. 42051), indigotin (C.I. 73015), chlorophyllin (C.I. 75810), quinoline yellow (C.I. 47005), titanium dioxide (C.I. 77891), indanthrene blue RS (C.I. 69800) and madder lake (C.I. 58000). Luminol may be present as a luminescent dye. Advantageous coloring pigments are, for example, titanium dioxide, mica, iron oxides (e.g., Fe2O3, Fe3O4, FeO(OH)) and / or tin oxides. Advantageous dyes are, for example, carmine, Berlin blue, chromium oxide green, ultramarine blue and / or manganese violet.

[0125] Preparation Preferred compositions according to the invention are selected from the group of products for the treatment, protection, care and cleansing of the skin and / or hair or as makeup products, preferably leave-on products (meaning that one or more compounds remain on the skin and / or hair for a longer period compared to rinse-off products).

[0126] The preparation according to the invention is preferably an emulsion, for example a W / O (water-in-oil), O / W (oil-in-water), W / O / W (water-in-oil-in-water), O / W / O (oil-in-water-in-oil) emulsion, PIT emulsion, Pickering emulsion, low-oil emulsion, microemulsion or nanoemulsion, a solution, for example an oil (fatty oil or fatty acid ester, in particular C6-C 32 Fatty acid C2-C 30Depending on the solution in an ester or silicone oil, manufacturing method and components, it can be in the form of a dispersion, suspension, cream, lotion or milk, gel (including hydrogel, hydrodispersion gel, oleogel), spray (e.g., pump spray or spray with a propellant), foam or impregnating liquid for cosmetic wipes, detergents such as soaps, synthetic detergents, liquid detergents, shower agents and bath agents, bath products (capsules, oils, tablets, salts, bath salts, soaps, etc.), foaming preparations, skin care products such as emulsions (as described above), ointments, pastes, gels (as described above), oils, balsams, serums, powders (e.g., face powder, body powder), eau de parfum, eau de toilette, aftershave, masks, pencils, sticks, roll-ons, pumps, aerosols (foaming, non-foaming, post-foaming), deodorants and / or antiperspirants, mouthwash and mouth rinse, foot care products (including keratolytic agents, deodorant agents), insect repellents, sunscreens, aftersun preparations, shaving products, aftershave balm, pre- and aftershave lotion, depilatory agents, hair care products such as shampoos (including 2-in-1 shampoos, anti-dandruff shampoos, baby shampoos, dry scalp shampoos, concentrated shampoos), conditioners, hair tonics, hair waters, hair rinses, styling creams, pomades, perms and setting lotions, hair sprays, styling aids (e.g., gels or waxes), hair smoothing agents (detangling agents, relaxers), hair dyes such as temporary direct hair dyes, semi-permanent hair dyes, permanent hair dyes, hair conditioners, hair mousses, eye care products, makeup, makeup removers or baby products.

[0127] Auxiliary substances and additives can be included in an amount of 5 to 99% by weight, preferably 10 to 80% by weight, based on the total weight of the preparation. The amounts of the cosmetic or dermatological auxiliary substances and additives and fragrances used in each case can be easily determined by a person skilled in the art by simple trial and error depending on the nature of the particular product.

[0128] The preparation can also contain water in an amount of up to 99 weight percent, preferably about 5 to about 80 weight percent, more preferably about 10 to about 50 or about 60 to about 80 weight percent, based on the total weight of the preparation.

[0129] Detergent preparation Another object of the present invention relates to a detergent preparation comprising a cyclopropyl derivative or a perfume mixture as described above. The preparation may contain said components in an amount in the range of about 0.01 to about 2 weight percent, preferably about 0.1 to 1 weight percent, calculated based on the preparation. Suitable examples of detergents include heavy-duty powder detergents, heavy-duty liquid detergents, light-duty powder detergents, light-duty liquid detergents, detergent tablets, fabric softeners, manual dishwashing detergents, multi-purpose cleaners, and the like.

[0130] The detergent composition of the present invention may contain any components normally contained in such a composition, for example, anionic, nonionic, cationic, amphoteric or zwitterionic (co)surfactants, organic solvents, builders, enzymes, and additional adjuvants such as soil-release agents, thickeners, colorants, perfumes, and the like.

[0131] Typical examples of anionic and zwitterionic surfactants include the following: almond amidopropylamine oxide, almond amidopropyl betaine, aminopropyl lauryl glutamate, ammonium C12-15 alkyl sulfate, ammonium C12-16 alkyl sulfate, ammonium capryles sulfate, ammonium coco monoglyceride sulfate, ammonium coco sulfate, ammonium coco oil isethionate, ammonium coco oil sarcosinate, ammonium C12-15 pareth sulfate, ammonium C9-10 perfluoroalkyl sulfonate, ammonium dinonyl sulfosuccinate, ammonium dodecylbenzene sulfonate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7 sulfate, ammonium laureth-9 sulfate, ammonium laureth-12 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myreth sulfate, ammonium myristyl sulfate, ammonium nonoxynol-4 sulfate, ammonium nonoxynol-30 sulfate, ammonium oleate, ammonium palm kernel sulfate, ammonium stearate, ammonium tartrate, AMPD-isostearoyl hydrolyzed collagen, AMPD-rosin hydrolyzed collagen, AMP-isostearoyl hydrolyzed collagen, AMP-isostearoyl hydrolyzed keratin, AMP-isostearoyl hydrolyzed soy protein, AMP-isostearoyl hydrolyzed wheat protein, apricot amidopropyl betaine, arachidic acid, arginine hexyl decyl phosphate, avocado amidopropyl betaine, avocado oil glyceryl-8 ester, babassu acid, babassu amidopropylamine oxide, babassu amidopropyl betaine, beeswax acid (BeeswaxAcid), behenamidopropyl betaine, behenamine oxide, behenes-25, behenes-30, behenic acid, behenyl betaine, bis-butyl dimethicone polyglyceryl-3, butoxynol-5 carboxylic acid, butoxynol-19 carboxylic acid, butyldimonium hydroxypropyl butyl glucoside chloride, butyldimonium hydroxypropyl lauryl glucoside chloride, butyl glucoside, butyl glucoside caprate, butyl glucoside hydroxypropyl trimonium chloride, butyl octanoic acid, C18-36 acid, C20-40 acid, C30-50 acid, C16-22 acid amide MEA, calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C9-16 alkane / cycloalkane, C10-14 alkylbenzenesulfonic acid, C12-14 alkyldiaminoethyl glycine HCL, C9-15 alkyl phosphate, Candida Bombicola / glucose / Methyl Rapeseedate ferment, canolamidopropyl betaine, capric acid, caproic acid, caproylethyl glucoside, capryl / capramidopropyl betaine, capryless-4 carboxylic acid, capryless-6 carboxylic acid, capryless-9 carboxylic acid, caprylic acid, capryloyl collagen amino acid, capryloyl glycine, capryloyl hydrolyzed collagen, capryloyl hydrolyzed keratin, capryloyl keratin amino acid, capryloyl silk amino acid, caprylyl / capryl glucoside, caprylyl / capryl wheat bran / straw glycosides, caprylyl glucoside,

[0132] Capriloyl Glyceryl Ether, Caprylyl Pyrrolidone, Carnitine, Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 Carboxylic Acid, Ceteareth-2 Phosphate, Ceteareth-4 Phosphate, Ceteareth-5 Phosphate, Ceteareth-10 Phosphate, Cetes-20, Cetes-23, Cetes-24, Cetes-25, Cetes-30, Cetes-40, Cetes-45, Cetes-150, Cetes-8 Phosphate, Cetes-10 Phosphate, Cetes-20 Phosphate, Cetress-22, Cetress-24, Cetress-25, Cetress-30, Cetyl Betaine, Chrysanthemum Sinense Flower Extract, C12-14 Hydroxyalkyl Hydroxyethyl Beta-Alanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidopropylamine Oxide, Cocamidopropyl Betaine Amide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocaminopropionic Acid, Cocess-7 Carboxylic Acid, Cocess-4 Glucoside, Cocoa Amphodipropionate, Cocobetaine Amide Amphopropionate, Cocobetaine, Cocodimonium Hydroxypropyl Hydrolyzed Corn Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocoglucoside, Cocoglucoside Hydroxypropyltrimonium Chloride, Cocohydroxysultaine, Cocomorpholine Oxide, Coconut Acid, Coconut Oil Glycereth-8 Ester, Coco / Oleamide Propyl Betaine, Cocusultaine, Coco / Sunflower Amide Propyl Betaine, Cocoylcholine Methosulfate,

[0133] Coconut oil glutamic acid, coconut oil hydrolyzed collagen, coconut oil hydrolyzed keratin, coconut oil hydrolyzed oat protein, coconut oil hydrolyzed rice protein, coconut oil hydrolyzed silk, coconut oil hydrolyzed soybean protein, coconut oil hydrolyzed wheat protein, coconut oil sarcosine, corn acid, cottonseed acid, cottonseed oil glycereth-8 ester, C10-16 pareth-1, C10-16 pareth-2, C11-13 pareth-6, C11-13 pareth-9, C11-13 pareth-10, C11-15 pareth-30, C11-15 pareth-40, C12-13 pareth-1, C12-13 pareth-23, C12-14 pareth-5, C12-14 pareth-9, C13-15 pareth-21, C14-15 pareth-8, C20-22 pareth-30, C20-40 pareth-40, C20-40 pareth-95, C22-24 pareth-33, C30-50 pareth-40, C9-11 pareth-6 carboxylic acid, C9-11 pareth-8 carboxylic acid, C11-15 pareth-7 carboxylic acid, C12-13 pareth-5 carboxylic acid, C12-13 pareth-7 carboxylic acid, C12-13 pareth-8 carboxylic acid, C12-13 pareth-12 carboxylic acid, C12-15 pareth-7 carboxylic acid, C12-15 pareth-8 carboxylic acid, C12-15 pareth-12 carboxylic acid, C14-15 pareth-8 carboxylic acid, C6-10 pareth-4 phosphate, C12-13 pareth-2 phosphate, C12-13 pareth-10 phosphate, C12-15 pareth-6 phosphate, C12-15 pareth-8 phosphate, C12-15 pareth-10 phosphate, C12-16 pareth-6 phosphate, C4-18 perfluoroalkyl ethyl thiohydroxypropyl trimonium chloride, cupuassuamidopropyl betaine (CupuassuamidopropylBetaine), DEA-C12-13 alkyl sulfate, DEA-C12-15 alkyl sulfate, DEA-ceteareth-2 phosphate, DEA-cetyl sulfate, DEA-cocamide dipropionate, DEA-C12-13 pareth-3 sulfate, DEA-cyclocarboxypropyloleate, DEA-dodecylbenzenesulfonate, DEA-isostearate, DEA-laureth sulfate, DEA-lauryl sulfate, DEA-linoleate, DEA-methyl myristate sulfonate, DEA-myreth sulfate, DEA-myristate, DEA-myristyl sulfate, DEA-oleth-5 phosphate, DEA-oleth-20 phosphate, DEA PG-oleate, deceth-7 carboxylic acid, deceth-7 glucoside, deceth-9 phosphate, decylamine oxide, decyl betaine, decyl glucoside, decyltetradeceth-30, decyltetradecylamine oxide,

[0134] Diammonium lauramidomethyl MEA sulfosuccinate, diammonium lauryl sulfosuccinate, diammonium oleamidomethyl PEG-2 sulfosuccinate, dibutoxymethane, Di-C12-15 Pareth-2 Phosphate, Di-C12-15 Pareth-4 Phosphate, Di-C12-15 Pareth-6 Phosphate, Di-C12-15 Pareth-8 Phosphate, Di-C12-15 Pareth-10 Phosphate, didodecyl butanetetracarboxylate, diethylamine lauryl sulfate, diethylhexyl sodium sulfosuccinate, dihydroxyethyl C8-10 alkoxypropylamine oxide, dihydroxyethyl C9-11 alkoxypropylamine oxide, dihydroxyethyl C12-15 alkoxypropylamine oxide, dihydroxyethyl cocoamine oxide, dihydroxyethyl lauramine oxide, dihydroxyethyl stearamine oxide, dihydroxyethyl tallowamine oxide, dimethicone PEG-7 phosphate, dimethicone PEG-10 phosphate, dimethicone PEG / PPG-7 / 4 phosphate, dimethicone PEG / PPG-12 / 4 phosphate, dimethicone / polyglycerin-3 copolymer, dimethicone propyl PG-betaine, dimyristyl phosphate, dioleoylamidoethyl hydroxyethylmonium methosulfate, DIPA-hydrogenated cocoate, DIPA-lanolate, DIPA-myristate, dipotassium capryloyl glutamate, dipotassium lauryl sulfosuccinate, dipotassium undecylenoyl glutamate, disodium babassamidomethyl MEA sulfosuccinate, disodium caproamphodiacetate, disodium caproamphodipropionate, disodium capryloamphodiacetate, disodium capryloamphodipropionate, disodium capryloyl glutamate, disodium cetearyl sulfosuccinate, disodium cetyl phenyl ether disulfonate, disodium cetyl sulfosuccinate, disodium cocamidomethyl MEA sulfosuccinate, disodium cocamidomethyl MIPA PEG-4 sulfosuccinate,

[0135] Disodium cocoamido MIPA sulfosuccinate, disodium cocoamido PEG-3 sulfosuccinate, disodium coceth-3 sulfosuccinate, disodium cocoamphocarboxyethyl hydroxypropylsulfonate, disodium cocoamphodiacetate, disodium cocoamphodipropionate, disodium coco-glucoside sulfosuccinate, disodium coco-sulfosuccinate, disodium cocoyl butyl gluceth-10 sulfosuccinate, disodium cocoyl glutamate, disodium C12-14 pareth-1 sulfosuccinate, disodium C12-14 pareth-2 sulfosuccinate, disodium C12-15 pareth sulfosuccinate, disodium C12-14 Sec-pareth-3 sulfosuccinate, disodium C12-14 Sec-pareth-5 sulfosuccinate, disodium C12-14 Sec-pareth-7 sulfosuccinate, disodium C12-14 Sec-pareth-9 sulfosuccinate, disodium C12-14 Sec-pareth-12 sulfosuccinate, disodium deceth-5 sulfosuccinate, disodium deceth-6 sulfosuccinate, disodium decyl phenyl ether disulfonate, disodium dihydroxyethyl sulfosuccinyl undecylenate, disodium ethylenedicocoamido PEG-15 disulfate, disodium hydrogenated cottonseed glyceride sulfosuccinate, disodium hydrogenated tallow glutamate, disodium hydroxydecyl sorbitol citrate, disodium isodecyl sulfosuccinate, disodium isostearamido MEA sulfosuccinate, disodium isostearamido MIPA-sulfosuccinate, disodium isostearamphodiacetate, disodium isostearamphodipropionate, disodium isostearyl sulfosuccinate, disodium laneth-5 sulfosuccinate, disodium lauramido MEA-sulfosuccinate, disodium lauramido MIPA glycol sulfosuccinate, disodium lauramido PEG-2 sulfosuccinate, disodium lauramido PEG-5 sulfosuccinate, disodium laureth-5 carboxy amphodiacetate, disodium laureth-7 citrate (Disodium Laureth-7Citrate), sodium lauryl disulfosuccinate, sodium lauryl-6-sulfosuccinate, sodium lauryl-9-sulfosuccinate, sodium lauryl-12-sulfosuccinate, sodium lauriminobis(hydroxypropyl)sulfonate, disodium lauriminodiacetate, disodium lauriminodipropionate,

[0136] Dipotassium tocopheryl phosphate lauriminodipropionate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium N-lauroyl aspartate, disodium lauroyl glutamate, disodium lauryl phenyl ether disulfonate, disodium lauryl sulfosuccinate, disodium myristamid MEA-sulfosuccinate, disodium nonoxynol-10 sulfosuccinate, disodium oleamid MEA-sulfosuccinate, disodium oleamid MIPA-sulfosuccinate, disodium oleamid PEG-2 sulfosuccinate, disodium oleoamphodipropionate, disodium oleth-3 sulfosuccinate, disodium oleyl phosphate, disodium oleyl sulfosuccinate, disodium palmitamid PEG-2 sulfosuccinate, disodium palmitoleamid PEG-2 sulfosuccinate, disodium PEG-4 cocamid MIPA sulfosuccinate, disodium PEG-12 dimethicone sulfosuccinate, disodium PEG-8 palm glyceride sulfosuccinate, disodium PPG-2-isododeceth-7 carboxy amphodiacetate, disodium ricinoleamid MEA sulfosuccinate, disodium sitostereth-14 sulfosuccinate, disodium soy amphodiacetate, disodium stearamid MEA-sulfosuccinate, disodium steariminodipropionate, disodium stearoamphodiacetate, disodium stearoyl glutamate, disodium stearyl sulfosuccinamate, disodium stearyl sulfosuccinate, disodium 2-sulfolaurate, disodium 2-sulfopalmitate, disodium tallamid MEA sulfosuccinate, disodium tallowamid MEA sulfosuccinate, disodium tallowamphodiacetate, disodium tallowiminodipropionate, disodium tallow sulfosuccinate, disodium tridecyl sulfosuccinate, disodium undecylenamid MEA sulfosuccinate, disodium undecylenamid PEG-2 sulfosuccinate, disodium undecylenoyl glutamate, disodium wheat germamidoMEA - Sulfosuccinate), wheat germ PEG - 2 disodium sulfosuccinate,

[0137] Wheat germ ampho-diglycinate, diTEA-cocamidodiacetate, diTEA-oleamid PEG-2 sulfosuccinate, diTEA-palmitoyl aspartate, ditridecyl sodium sulfosuccinate, dodecylbenzenesulfonic acid, erucamidopropyl hydroxysultaine, ethylhexes-3-carboxylic acid, ethyl PEG-15 cocamine sulfate, glyceryl caprylether, hexyldecanoic acid, hydrogenated coconut acid, hydrogenated lanolin-25, hydrogenated menhaden acid, hydrogenated palm acid, hydrogenated palm kernel amine oxide, hydrogenated tallow acid, hydrogenated tallow amine oxide, hydrogenated tallow betaine, hydrogenated talloweth-25, hydrogenated tallowoyl glutamic acid, hydrolyzed candida bombicola extract, hydroxysetes-60, hydroxyethylacetomonium PG-dimethicone, hydroxyethylbutylamine lauryl sulfate, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamine oxide, hydroxylauryllhydroxymyristyl betaine, hydroxystearic acid, hydroxysuccinimidyl C10-40 isoalkylAcidate), hydroxysuccinimidyl C21-22 isoalkyl acidate, hydroxysultaine, IPDI / PEG-15 soyamine oxide copolymer, IPDI / PEG-15 soyethonium ethosulfate copolymer, IPDI / PEG-15 soy glycinate copolymer, isocetes-30, isolaureth-4 phosphate, isopolyglyceryl-3 dimethicone, isopolyglyceryl-3 dimethiconol, isopropanolamine lanolate, isopropylamine dodecylbenzenesulfonate, isostearamidopropylamine oxide, isostearamidopropyl betaine, isostearamidopropyl morpholine oxide, isosteareth-8, isosteareth-16, isosteareth-22, isosteareth-25, isosteareth-50, isostearic acid, isostearoyl hydrolyzed collagen, jojoba oil PEG-150 ester, jojoba wax PEG-80 ester, jojoba wax PEG-120 ester, laneth-20, laneth-25, laneth-40,

[0138] Lanes-50, Lanes-60, Lanes-75, lanolinic acid, lauramidopropylamine oxide, lauramidopropyl betaine, lauramidopropyl hydroxysultaine, lauramine oxide, lauraminopropionic acid, laurdimonium hydroxypropyl decyl glucoside chloride, laurdimonium hydroxypropyl lauryl glucoside chloride, Laureth-16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-38, Laureth-40, Laureth-3 carboxylic acid, Laureth-4 carboxylic acid, Laureth-5 carboxylic acid, Laureth-6 carboxylic acid, Laureth-8 carboxylic acid, Laureth-10 carboxylic acid, Laureth-11 carboxylic acid, Laureth-12 carboxylic acid, Laureth-13 carboxylic acid, Laureth-14 carboxylic acid, Laureth-17 carboxylic acid, Laureth-6 citrate, Laureth-7 citrate, Laureth-1 phosphate, Laureth-2 phosphate, Laureth-3 phosphate, Laureth-4 phosphate, Laureth-7 phosphate, Laureth-8 phosphate, Laureth-7 tartrate, lauric acid, lauriminobispropane diol, lauriminodipropionic acid, lauroamphodipropionic acid, lauroyl beta-alanine, lauroyl collagen amino acid, lauroyl ethyl trimonium methosulfate, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methyl glucamide, lauroyl sarcosine, lauroyl silk amino acid, lauryl betaine, lauryl dimethicone / polyglycerin-3 copolymer, lauryl dimonium hydroxypropyl coco glucoside chloride, lauryl glucoside, lauryl glucoside hydroxypropyl trimonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysultaine, lauryl malamide, lauryl methyl glucamide, lauryl / myristyl glycol hydroxypropyl ether, lauryl / myristyl wheat bran / straw glycosides, lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, lauryl pyrrolidone, lauryl sultaine, linoleic acid, linolenic acid, linseed acid, lysine cocoate,

[0139] Macadamia seed oil glyceryl-8 ester, magnesium coceth sulfate, magnesium coco sulfate, magnesium isododecylbenzene sulfonate, magnesium laureth-11 carboxylate, magnesium lauryl sulfate, magnesium laureth-5 sulfate, magnesium laureth-8 sulfate, magnesium laureth-16 sulfate, magnesium laureth-3 sulfosuccinate, magnesium lauryl hydroxypropyl sulfonate, magnesium lauryl sulfate, magnesium methyl cocoyl taurate, magnesium myreth sulfate, magnesium oleth sulfate, magnesium / TEA-cocosulfate, Manicouagan Clay, MEA-cocoaate, MEA-laurate-6 carboxylate, MEA-lauryl sulfate, MEA-lauryl sulfate, MEA PPG-6 laurate-7 carboxylate, MEA-PPG-8-stearate-7 carboxylate, MEA-undecylenate, meroxapol 108, meroxapol 174, meroxapol 178, meroxapol 254, meroxapol 255, meroxapol 258, meroxapol 314, methoxy PEG-450 amide glutaryl succinimide, methoxy PEG-450 amide hydroxy succinimidyl succinate, methoxy PEG-450 maleimide, methyl morpholine oxide, milk amide propyl amine oxide, milk amide propyl betaine, mink amide propyl amine oxide, mink amide propyl betaine, MIPA C12-15 pareth sulfate, MIPA-dodecylbenzene sulfonate, MIPA-lauryl sulfate, MIPA-lauryl sulfate, mixed isopropanolaminesLanolate), Mixed Isopropanolamine Lauryl Sulfate, Mixed Isopropanolamine Myristate, Morpholine Oleate, Morpholine Stearate, Mirist-3-Carboxylic Acid, Mirist-5-Carboxylic Acid, Myristalconium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysultaine, Myristamidopropyl PG-Dimonium Chloride Phosphate, Myristamine Oxide, Myristaminopropionic Acid, Myristic Acid, Myristoylethyl Trimonium Methosulfate, Myristoyl Glutamic Acid,

[0140] Myristoyl hydrolyzed collagen, myristoyl sarcosine, myristyl betaine, myristyl / cetyl amine oxide, myristyldimonium hydroxypropyl cocoglucoside chloride, myristyl glucoside, myristyl phosphate, nonoxynol-20, nonoxynol-23, nonoxynol-25, nonoxynol-30, nonoxynol-35, nonoxynol-40, nonoxynol-44, nonoxynol-50, nonoxynol-100, nonoxynol-120, nonoxynol-5 carboxylic acid, nonoxynol-8 carboxylic acid, nonoxynol-10 carboxylic acid, nonoxynol-3 phosphate, nonoxynol-4 phosphate, nonoxynol-6 phosphate, nonoxynol-9 phosphate, nonoxynol-10 phosphate, nonylnonoxynol-30, nonylnonoxynol-49, nonylnonoxynol-100, nonylnonoxynol-150, nonylnonoxynol-7 phosphate, nonylnonoxynol-8 phosphate, nonylnonoxynol-9 phosphate, nonylnonoxynol-10 phosphate, nonylnonoxynol-11 phosphate, nonylnonoxynol-15 phosphate, nonylnonoxynol-24 phosphate, oatamidopropyl betaine, octoxynol-16, octoxynol-25, octoxynol-30, octoxynol-33, octoxynol-40, octoxynol-70, octoxynol-20 carboxylic acid, octyldodeceth-20, octyldodeceth-25, octyldodeceth-30, oleamidopropyl amine oxide, oleamidopropyl betaine, oleamidopropyl hydroxysultaine, oleamine oxide, oleic acid, oleoyl hydrolyzed collagen, oleoyl sarcosine, oleth-20, oleth-23, oleth-24, oleth-25, oleth-30, oleth-35, oleth-40, oleth-44, oleth-50, oleth-3 carboxylic acid, oleth-6 carboxylic acid, oleth-10 carboxylic acid, oleyl betaine, olivamidopropyl amine oxide, olivamidopropyl betaine, olive acid, olivoyl hydrolyzed wheat protein, ophiopogon extract stearateStearate), Ozonated Oleth-10, Ozonated PEG-10 Oleate, Ozonated PEG-14 Oleate, Ozonated Polysorbate 80, Palmitic Acid, Palmidopropyl Betaine,

[0141] Palmeth-2 Phosphate, Palmidopropylamine Oxide, Palmidopropyl Betaine, Palmitamide Oxide, Palmitic Acid, Palmitoyl Collagen Amino Acid, Palmitoyl Glycine, Palmitoyl Hydrolyzed Collagen, Palmitoyl Hydrolyzed Milk Protein, Palmitoyl Hydrolyzed Wheat Protein, Palmitoyl Keratin Amino Acid, Palmitoyl Oligopeptide, Palmitoyl Silk Amino Acid, Palm Kernel Acid, Palm Kernel Amidopropyl Betaine, Peach Kernel Oil Glycereth-8 Ester, Peanut Acid, PEG-10 Castor Oil, PEG-40 Castor Oil, PEG-44 Castor Oil, PEG-50 Castor Oil, PEG-54 Castor Oil, PEG-55 Castor Oil, PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, PEG-6 Cocamide Phosphate, PEG-4 Cocamine, PEG-8 Cocamine, PEG-12 Cocamine, PEG-150 Dibehenate, PEG-90 Diisostearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Cocoate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Soyate (PEG-30 GlycerylSoyate), PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-28 Glyceryl Tallate, PEG-80 Glyceryl Tallate, PEG-82 Glyceryl Tallate, PEG-130 Glyceryl Tallate, PEG-200 Glyceryl Tallate, PEG-45 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG-54 Hydrogenated Castor Oil, PEG-55 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogenated Castor Oil, PEG-30 Hydrogenated Lanolin,

[0142] PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isostearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glyceride (PEG-70 MangoGlycerides), PEG-20 Mannitan Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Methyl Glucose Trioleate, PEG-4 Montanate, PEG-30 Oleamine, PEG-20 Oleate, PEG-23 Oleate, PEG-32 Oleate, PEG-36 Oleate, PEG-75 Oleate, PEG-150 Oleate, PEG-20 Palmitate, PEG-150 Polyglyceryl-2 Tristearate, PEG / PPG-28 / 21 Acetate Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG-10 / 30 Copolymer, PEG / PPG-10 / 65 Copolymer, PEG / PPG-12 / 35 Copolymer, PEG / PPG-16 / 17 Copolymer, PEG / PPG-20 / 9 Copolymer, PEG / PPG-20 / 20 Copolymer, PEG / PPG-20 / 60 Copolymer, PEG / PPG-20 / 65 Copolymer, PEG / PPG-22 / 25 Copolymer, PEG / PPG-28 / 30 Copolymer, PEG / PPG-30-35 Copolymer, PEG / PPG-30 / 55 Copolymer, PEG / PPG-35 / 40 Copolymer, PEG / PPG-50 / 40 Copolymer, PEG / PPG-150 / 35 Copolymer, PEG / PPG-160 / 30 Copolymer, PEG / PPG-190 / 60 Copolymer, PEG / PPG-200 / 40 Copolymer, PEG / PPG-300 / 55 Copolymer,

[0143] PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate, PEG / PPG-4 / 2 Propylheptyl Ether, PEG / PPG-6 / 2 Propylheptyl Ether, PEG-7 / PPG-2 Propylheptyl Ether, PEG / PPG-8 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Propylheptyl Ether, PEG / PPG-14 / 2 Propylheptyl Ether, PEG / PPG-40 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol (PEG-5 RapeseedSterol), PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glyceride, PEG-75 Shea Butter Glyceride, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearamide Carboxylic Acid, PEG-9 Stearamide Carboxylic Acid, PEG-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, PEG-40 Stearate, PEG-45 Stearate, PEG-50 Stearate, PEG-55 Stearate, PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG-120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallate, PEG-50 Tallow Amide, PEG-2 Tallow Amide DEA, PEG-20 Tallowate, PEG-66 Trihydroxystearin, PEG-200 Trihydroxystearin, PEG-60 Tsubakiate Glycerides, Pelargonic Acid, Pentadoxynol-200, Phenes-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288

[0144] Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomaderris Kumerahou Flower / Leaf Extract, Poria Cocos Extract, Abitol Hydrolyzed Collagen Potassium, Potassium Babassuic Acid, Potassium Behenate, Potassium C9-15 Alkyl Phosphate, Potassium C11-15 Alkyl Phosphate, Potassium C12-13 Alkyl Phosphate, Potassium C12-14 Alkyl Phosphate, Potassium Caprate, Potassium Capryloyl Glutamate, Potassium Capryloyl Hydrolyzed Comethane Pak, Potassium Castorate, Potassium Coconut Fatty Acid (PotassiumPotassium cocoate, potassium cocooyl glutamate, potassium cocooyl glycinate, potassium cocooyl hydrolyzed casein, potassium cocooyl hydrolyzed collagen, potassium cocooyl hydrolyzed corn protein, potassium cocooyl hydrolyzed keratin, potassium cocooyl hydrolyzed oat protein, potassium cocooyl hydrolyzed potato protein, potassium cocooyl hydrolyzed rice bran protein, potassium cocooyl hydrolyzed rice protein, potassium cocooyl hydrolyzed silk, potassium cocooyl hydrolyzed soybean protein, potassium cocooyl hydrolyzed wheat protein, potassium cocooyl hydrolyzed yeast protein,

[0145] Potassium Cocoyl PCA, Potassium Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Cornate, Potassium Cyclocarboxypropyloleate, Potassium Dihydroxyethyl Cocamine Oxide Phosphate, Potassium Dimethicone PEG-7 Phosphate, Potassium Dodecylbenzenesulfonate, Potassium Hempseedate, Potassium Hydrogenated Cocoate, Potassium Hydrogenated Palmate, Potassium Hydrogenated Tallowate, Potassium Hydroxystearate, Potassium Isostearate, Potassium Lanolate, Potassium Laurate, Potassium Lauress-3 Carboxylate, Potassium Lauress-4 Carboxylate, Potassium Lauress-5 Carboxylate, Potassium Lauress-6 Carboxylate, Potassium Lauress-10 Carboxylate, Potassium Lauress Phosphate, Potassium Lauroyl Collagen Amino Acids, Potassium Lauroyl Glutamate, Potassium Lauroyl Hydrolyzed Collagen, Potassium Lauroyl Hydrolyzed Pea Protein, Potassium Lauroyl Hydrolyzed Soy Protein, Potassium Lauroyl PCA, Potassium Lauroyl Pea Amino Acids, Potassium Lauroyl Sarcosinate, Potassium Lauroyl Silk Amino Acids, Potassium Lauroyl Wheat Amino Acids, Potassium Lauryl Phosphate, Potassium Lauryl Sulfate, Potassium Linoleate, Potassium Metaphosphate, Potassium Methyl Cocoyl Taurate, Potassium Myristate, Potassium Myristoyl Glutamate, Potassium Myristoyl Hydrolyzed Collagen, Potassium Octoxynol-12 Phosphate, Potassium Oleate, Potassium Oleoyl Hydrolyzed Collagen, Potassium Olivate, Potassium Olivoyl Hydrolyzed Oat Protein, Potassium Olivoyl Hydrolyzed Wheat Protein, Potassium Olivoyl / Lauroyl Wheat Amino Acids, Potassium Olivoyl PCA, Potassium Palmate (PotassiumPalmate), potassium palmitate, palmitoyl hydrolyzed corn protein potassium, palmitoyl hydrolyzed oat protein potassium, palmitoyl hydrolyzed rice protein potassium, palmitoyl hydrolyzed sweet almond protein potassium,

[0146] Potassium Palmitoyl Hydrolyzed Wheat Protein, Potassium Palm Kernelate, Potassium Peanutate, Potassium Rapeseed Oil Fatty Acid, Potassium Ricinoleate, Potassium Safflowerate, Potassium Soyate, Potassium Stearate, Potassium Stearoyl Hydrolyzed Collagen, Potassium Tallate, Potassium Tarate, Potassium Taurine Laurate, Potassium Trideceth-3 Carboxylate, Potassium Trideceth-4 Carboxylate, Potassium Trideceth-7 Carboxylate, Potassium Trideceth-15 Carboxylate, Potassium Trideceth-19 Carboxylate, Potassium Trideceth-6 Phosphate, Potassium Trideceth-7 Phosphate, Potassium Camellate, Potassium Undecylenate, Potassium Undecylenoyl Hydrolyzed Collagen, Potassium Undecylenoyl Hydrolyzed Wheat Protein, PPG-30-Buteth-30, PPG-36-Buteth-36, PPG-38-Buteth-37, PPG-30-Capryleth-4 Phosphate, PPG-10 Cetyl Ether Phosphate, PPG-2 C9-11 Pareth-8, PPG-1-Deceth-5, PPG-3-Deceth-2 Carboxylate, PPG-30 Ethylhexeth-4 Phosphate, PPG-20 Glyceryl Ether, PPG-2 Hydroxyethyl Cocoisostearamide, PPG-2-Isodeceth-8, PPG-2-Isodeceth-10, PPG-2-Isodeceth-18, PPG-2-Isodeceth-25, PPG-4-Isodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Oil Fatty Acid, Wheat Germ Acid, Wheat Germ Glyceryl Ester, Ricinoleamidopropyl Betaine, Ricinoleic Acid, Ricinoleth-40, Safflower Acid, Sapindus Oahuensis Fruit Extract, Saponaria Officinalis Root Powder, Saponin, Soap-K, Soap-Na / K, Soap Base (SekkenSoji), Soap Base-K, Sesame Oil Glycereth-8 Ester, Sesamidopropylamine Oxide, Sesamidopropyl Betaine, Shea Butteramidopropyl Betaine, Shea Butter Glycereth-8 Ester, Sodium Arachidate, Sodium Argan Amphodiacetate, Sodium Astrocaryum Murumuruate, Sodium Avocadoate, Sodium Babassu Amphodiacetate, Sodium Babassuate, Sodium Babassu Sulfate, Sodium Behenate,

[0147] Sodium bisglycol ricinosulfosuccinate, sodium bis(hydroxyethyl) glycinate coco glucoside cross polymer, sodium bis(hydroxyethyl) glycinate lauryl glucoside cross polymer, boragediamidopropyl PG-dimonium chloride phosphate sodium, sodium butoxynol-12 sulfate, sodium butyl glucoside hydroxypropyl phosphate, sodium C13-17 alkane sulfonate, sodium C14-18 alkane sulfonate, sodium C12-15 alkoxypropyliminodipropionate, sodium C10-16 alkyl sulfate, sodium C11-15 alkyl sulfate, sodium C12-13 alkyl sulfate, sodium C12-15 alkyl sulfate, sodium C12-18 alkyl sulfate, sodium C16-20 alkyl sulfate, sodium C9-22 alkyl Sec sulfonate, sodium C14-17 alkyl Sec sulfonate, sodium caprate, sodium caproamphoacetate, sodium caproamphohydroxypropyl sulfonate, sodium caproamphopropionate, sodium caproylmethyl taurate, sodium caprylate, sodium capryles-2 carboxylate, sodium capryles-9 carboxylate, sodium capryloamphoacetate, sodium capryloamphohydroxypropyl sulfonate, sodium capryloamphopropionate, sodium capryloyl glutamate, sodium capryloyl hydrolyzed wheat protein, sodium caprylyl PG-sulfonate, sodium caprylyl sulfonate, sodium castor fatty acid, sodium ceteareth-13 carboxylate, sodium cetearyl sulfate, sodium cetes-13 carboxylate, sodium cetyl sulfate, sodium cocamidopropyl PG-dimonium chloride phosphate, sodium cocaminopropionate, sodium coces sulfate, sodium coces-30 sulfate, sodium cocoabutter amphoacetate, sodium cocoabutterate, sodium coco amphoacetate, sodium coco amphohydroxypropyl sulfonate, sodium coco amphopropionate, sodium coconut fatty acid, sodium coco / babassu / andiroba sulfateSulfate), Sodium coco / babassu sulfate, Sodium cocoglucoside hydroxypropyl phosphate,

[0148] Sodium Cocoglucoside Hydroxypropyl Sulfonate, Sodium Cocoglucoside Tartrate, Sodium Cocoglyceryl Ether Sulfonate, Sodium Coco / Hydrogenated Tallow Sulfate, Sodium Cociminodiacetate, Sodium Cocomonoglyceride Sulfate, Sodium Cocomonoglyceride Sulfonate, Sodium Cocoyl PG-Dimonium Chloride Phosphate, Sodium Coco Sulfate, Sodium Cocosulfoacetate, Sodium Cocoyl Alaninate, Sodium Cocoyl Amino Acid, Sodium Cocoyl Collagen Amino Acid, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutaminate, Sodium Cocoyl Glycinate, Sodium Cocoyl / Hydrogenated Tallow Glutamate, Sodium Cocoyl Hydrolyzed Collagen, Sodium Cocoyl Hydrolyzed Keratin, Sodium Cocoyl Hydrolyzed Wheat Protein, Sodium Cocoyl Hydrolyzed Silk, Sodium Cocoyl Hydrolyzed Soy Protein, Sodium Cocoyl Hydrolyzed Sweet Almond Protein, Sodium Cocoyl Hydrolyzed Wheat Protein, Sodium Cocoyl Hydrolyzed Wheat Protein Glutamate, Sodium Cocoyl Isethionate, Sodium Cocoyl Methylaminopropionate, Sodium Cocoyl Oat Amino Acid, Sodium Cocoyl / Palmoyl / Sunfloweroyl Glutamate, Sodium Cocoyl Proline, Sodium Cocoyl Sarcosinate, Sodium Cocoyl Taurinate, Sodium Cocoyl Threoninate, Sodium Cocoyl Wheat Amino Acid, Sodium C12-14 Olefin Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14-18 Olefin Sulfonate, Sodium C16-18 Olefin Sulfonate, Sodium Corn Amphopropionate, Sodium Cottonseed Amphoacetate (SodiumCottonseed amphoacetate, sodium C13-15 pareth-8 phosphate, sodium C9-11 pareth-6 carboxylate, sodium C11-15 pareth-7 carboxylate, sodium C12-13 pareth-5 carboxylate, sodium C12-13 pareth-8 carboxylate, sodium C12-13 pareth-12 carboxylate, sodium C12-15 pareth-6 carboxylate, sodium C12-15 pareth-7 carboxylate, sodium C12-15 pareth-8 carboxylate, sodium C14-15 pareth-8 carboxylate, sodium C12-14 Sec-pareth-8 carboxylate

[0149] Sodium C14-15 pareth-sulfate, Sodium C12-13 pareth-2 phosphate, Sodium C13-15 pareth-8 phosphate, Sodium C9-15 pareth-3 sulfate, Sodium C10-15 pareth sulfate, Sodium C10-16 pareth-2 sulfate, Sodium C12-13 pareth sulfate, Sodium C12-15 pareth sulfate, Sodium C12-15 pareth-3 sulfate, Sodium C13-15 pareth-3 sulfate, Sodium C12-14 Sec-pareth-3 sulfate, Sodium C12-15 pareth-3 sulfonate, Sodium C12-15 pareth-7 sulfonate, Sodium C12-15 pareth-15 sulfonate, Sodium deceth-2 carboxylate, Sodium deceth sulfate, Sodium decylbenzene sulfonate, Sodium decyl glucoside hydroxypropyl phosphate, Sodium decyl glucoside hydroxypropyl sulfonate, Sodium dilaurate-7 citrate, Sodium dilaurate-10 phosphate, Sodium dilinoleamidopropyl PG-dimonium chloride phosphate, Sodium dilinoleate, Sodium dioleate-8 phosphate, Sodium dodecylbenzene sulfonate, Sodium ethyl 2-sulfolaurate, Sodium Glyceryl Oleate Phosphate, Sodium grapeseedamidopropyl PG-dimonium chloride phosphate, Sodium grapeseed amphoacetate, Sodium Grapeseedate, Sodium hempseed amphoacetate, Sodium hexeth-4 carboxylate, Sodium hydrogenated cocoate, Sodium hydrogenated cocooyl methyl isethionate, Sodium hydrogenated palm oil fatty acid, Sodium hydrogenated tallowate, Sodium hydrogenated tallowoyl glutamate, Sodium hydroxy lauryldimonium ethyl phosphate, Sodium hydroxypropyl palm kernel acid sulfonate, Sodium hydroxypropyl phosphate decyl glucoside cross polymer, Sodium hydroxypropyl phosphate lauryl glucoside cross polymer, Sodium hydroxypropyl sulfonate coco glucoside cross polymer, Sodium hydroxypropyl sulfonate decyl glucoside cross polymer, Sodium hydroxypropyl sulfonate lauryl glucoside cross polymer

[0150] Sodium hydroxystearate, sodium isostearate, sodium isosteares-6-carboxylate, sodium isosteares-11-carboxylate, sodium isostearoamphoacetate, sodium isostearoamphopropionate, sodium N-isostearoyl methyltaurate, sodium laneth sulfate, sodium lanolin fatty acid, Sodium Lardate, sodium lauramidodiacetate, sodium lauraminopropionate, sodium laurate, sodium laures-3-carboxylate, sodium laures-4-carboxylate, sodium laures-5-carboxylate, sodium laures-6-carboxylate, sodium laures-8-carboxylate, sodium laures-11-carboxylate, sodium laures-12-carboxylate, sodium laures-13-carboxylate, sodium laures-14-carboxylate, sodium laures-16-carboxylate, sodium laures-17-carboxylate, sodium laures sulfate, sodium laures-5 sulfate, sodium laures-7 sulfate, sodium laures-8 sulfate, sodium laures-12 sulfate, sodium laures-40 sulfate, sodium laures-7 tartrate, sodium lauriminodipropionate, sodium lauroamphoacetate, sodium lauroamphohydroxypropylsulfonate, sodium lauroampho PG-acetate phosphate, sodium lauroamphopropionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, sodium lauroyl glycine propionate, sodium lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropylsulfonate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl methylisethionate, sodium lauroyl millet aminoAcids), Sodium Lauroyl / Myristoyl Aspartate, Sodium Lauroyl Oat Amino Acid, Sodium Lauroyl Sarcosinate, Sodium Lauroyl Silk Amino Acid, Sodium Lauroyl Taurine, Sodium Lauroyl Wheat Amino Acid, Sodium Lauryl Diethylenediaminoglycinate, Sodium Lauryl Glucose Carboxylate, Sodium Lauryl Glucoside Hydroxypropyl Phosphate,

[0151] Sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl glycol carboxylate, sodium lauryl hydroxyacetamide sulfate, sodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium linoleate, Sodium Macadamiaseedate, sodium mango amphoacetate, sodium mangoseedate (SodiumMangoseedate), sodium / MEA lauryl-2-sulfosuccinate, methoxy PPG-2 sodium acetate, sodium methyl cocoyl taurate, sodium methyl lauroyl taurate, sodium methyl myristoyl taurate, sodium methyl oleoyl taurate, sodium methyl palmitoyl taurate, sodium methyl stearoyl taurate, sodium methyl 2-sulfolaurate, sodium methyl 2-sulfopalmitate, sodium methyl isopalmitamidotaurate, sodium methyl taurate cocoyl methyl taurate, sodium myreth sulfate, sodium myristate, sodium myristoamphoacetate, sodium myristoyl glutamate, sodium myristoyl hydrolyzed collagen, sodium myristoyl isethionate, sodium myristoyl sarcosinate, sodium myristyl sulfate, sodium nonoxynol-6 phosphate, sodium nonoxynol-9 phosphate, sodium nonoxynol-1 sulfate, sodium nonoxynol-3 sulfate, sodium nonoxynol-4 sulfate, sodium nonoxynol-6 sulfate, sodium nonoxynol-8 sulfate, sodium nonoxynol-10 sulfate, sodium nonoxynol-25 sulfate, sodium octoxynol-2 ethanesulfonate, sodium octoxynol-2 sulfate, sodium octoxynol-6 sulfate, sodium octoxynol-9 sulfate, sodium oleate, sodium oleoamphoacetate, sodium oleoamphohydroxypropylsulfonate, sodium oleoamphopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl isethionate, sodium oresulfate, sodium oleyl methyl isethionate, sodium oleyl sulfate, sodium oliveamphoacetate, sodium olive fatty acid, sodium oliboyl glutamate, sodium palmamphoacetate, sodium palm fatty acid, sodium palm glyceride sulfonate,

[0152] Sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat gluten, sodium palmitoyl sarcosinate, sodium palm kernelate, sodium palm kerneloyl isethionate, sodium palmolyl glutamate, Sodium Passiflora Edulis Seedate, sodium peanut amphoacetate, Sodium Peanutate, sodium PEG-6 cocamidocarboxylate, sodium PEG-8 cocamidocarboxylate, sodium PEG-4 cocamidosulfate, sodium PEG-3 lauramidocarboxylate, sodium PEG-4 lauramidocarboxylate, sodium PEG-8 palm glyceride carboxylate, pentaerythrityl hydroxypropyliminodiacetic acid dendrimer sodium, sodium propoxy PPG-2 acetate, sodium rapeseed oil fatty acid, sodium rice bran amphoacetate, sodium ricinoleate, sodium ricinoleoamphoacetate, sodium rose hip amphoacetate, sodium rosinate, sodium safflower oil fatty acid, sodium saffloweroyl hydrolyzed soybean protein, sodium sesame seed oil fatty acid, sodium sesamum amphoacetate (SodiumSesamphoacetate, Sodium Cyabutter Amphoacetate, Sodium Soybean Oil Fatty Acid, Sodium Hydrolyzed Soybean Collagen, Sodium Stearate, Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Stearoyl Casein, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Corn Protein, Sodium Stearoyl Hydrolyzed Silk, Sodium Stearoyl Hydrolyzed Soy Protein, Sodium Stearoyl Hydrolyzed Wheat Protein, Sodium Stearoyl Lactalbumin, Sodium Stearoyl Methyl Isethionate, Sodium Stearoyl Oat Protein, Sodium Stearoyl Pea Protein, Sodium Stearoyl Soy Protein, Sodium Stearyldimethylglycine, Sodium Stearyl Sulfate, Sodium Sunflower Seed Amphoacetate, Sodium Surfactin, Sodium Sweet Almond Amphoacetate, Sodium Sweet Almondate, Sodium Tallamphopropionate, Sodium Tallate

[0153] Sodium Taro Amphoacetate, Sodium Taroate, Sodium Taro Sulfate, Sodium Tamanuseedate, Sodium Taurate, Sodium Taurine Cocoyl Methyl Taurate, Sodium Taurine Laurate, Sodium / TEA-Lauroyl Collagen Amino Acids, Sodium / TEA-Lauroyl Hydrolyzed Collagen, Sodium / TEA-Lauroyl Hydrolyzed Keratin, Sodium / TEA-Lauroyl Keratin Amino Acids, Sodium / TEA-Undecylenoyl Collagen Amino Acids, Sodium / TEA-Undecylenoyl Hydrolyzed Collagen, Sodium / TEA-Undecylenoyl Hydrolyzed Corn Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Soy Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Wheat Protein, Sodium Theobroma Grandiflorum Seedate, Sodium Trideceth-3 Carboxylate, Sodium Trideceth-4 Carboxylate, Sodium Trideceth-6 Carboxylate, Sodium Trideceth-7 Carboxylate, Sodium Trideceth-8 Carboxylate, Sodium Trideceth-12 Carboxylate, Sodium Trideceth-15 Carboxylate, Sodium Trideceth-19 Carboxylate, Sodium Trideceth Sulfate, Sodium Tridecylbenzene Sulfonate, Sodium Tridecyl Sulfate, Sodium Trimethylolpropane Hydroxypropyliminodiacetate Dendrimer, Sodium Undeceth-5 Carboxylate, Sodium Undecylenate, Sodium Undecylenoyl Amphoacetate, Sodium Undecylenoyl Amphopropionate, Sodium Undecylenoyl Glutamate, Sodium Wheat Germ AmphoacetateGermamphoacetate), Sorves-160 tristearate, soybean acid, soyamidopropylamine oxide, soyamidopropyl betaine, soybean oil glyceres-8 ester, stearamidopropylamine oxide, stearamidopropyl betaine, stearamine oxide, Steares-15, Steares-16, Steares-20, Steares-21, Steares-25, Steares-27, Steares-30, Steares-40, Steares-50, Steares-80, Steares-100, Steares-2 phosphate, Steares-3 phosphate, stearic acid, stearoxypropyltrimonium chloride, stearoyl glutamate,

[0154] Stearoyl sarcosine, stearyl betaine, stearyldimonium hydroxypropyl butyl glucoside chloride, stearyldimonium hydroxypropyl decyl glucoside chloride, stearyldimonium hydroxypropyl lauryl glucoside chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower amide MEA, sunflower seed acid, sunflower seed amide propyl hydroxyethyl dimonium chloride, sunflower seed oil glyceryl esters - 8, tall oil fatty acid, tall oil acid, tall oil amide propyl amine oxide, tall oil amide propyl betaine, tall oil amide propyl hydroxysultaine, tall oil amine oxide, tall oil betaine, tall oil dihydroxyethyl betaine, talloyl ethyl glucoside, TEA - abietoyl hydrolyzed collagen, TEA - C12 - 14 alkyl phosphate, TEA - C10 - 15 alkyl sulfate, TEA - C11 - 15 alkyl sulfate, TEA - C12 - 13 alkyl sulfate, TEA - C12 - 14 alkyl sulfate, TEA - C12 - 15 alkyl sulfate, TEA - C14 - 17 alkyl Sec sulfonate, TEA - canolate, TEA - cocamidodiacetate, TEA - cocoate, TEA - coco - sulfate, TEA - cocoyl alaninate, TEA - cocoyl glutamate, TEA - cocoyl glutamine, TEA - cocoyl glycinate, TEA - cocoyl hydrolyzed collagen, TEA - cocoyl hydrolyzed soy protein, TEA - cocoyl sarcosinate, TEA - dimethicone PEG - 7 phosphate, TEA - dodecyl benzene sulfonate, TEA - hydrogenated cocoate, TEA - hydrogenated talloyl glutamate, TEA - isostearate, TEA - isostearoyl hydrolyzed collagen, TEA - lauraminopropionate, TEA - laurate, TEA - laurate / mystate, TEA - laureth sulfate, TEA - lauroyl collagen amino acids, TEA - lauroyl glutamate, TEA - lauroyl hydrolyzed collagen, TEA - lauroyl keratin amino acids, TEA - lauroyl methyl aminopropionate, TEA - lauroyl / mystoyl aspartate, TEA - lauroyl sarcosinate,TEA-lauryl phosphate, TEA-lauryl sulfate, TEA-myristaminopropionate, TEA-myristate, TEA-myristoyl hydrolyzed collagen,

[0155] TEA-oleate, TEA-oleoyl hydrolyzed collagen, TEA-oleoyl sarcosinate, TEA-oleyl sulfate, TEA-palmitate, TEA-palm kernel sarcosinate, TEA-PEG-3 cocamide sulfate, TEA-rosinate, TEA-stearate, TEA-Tallate, TEA-tridecylbenzene sulfonate, TEA-undecylenate, TEA-undecylenoyl hydrolyzed collagen, tetramethyldecyne diol, tetrasodium dicarboxyethyl stearyl sulfosuccinamate, TIPA-lauryl sulfate, TIPA-lauryl sulfate, TIPA-myristate, TIPA-stearate, tocopherol phosphate, trehalose undecylenate, TM-C12-15 pareth-2 phosphate, TM-C12-15 pareth-6 phosphate, TM-C12-15 pareth-8 phosphate, TM-C12-15 pareth-10 phosphate, trideceth-20, trideceth-50, trideceth-3 carboxylic acid, trideceth-4 carboxylic acid, trideceth-7 carboxylic acid, trideceth-8 carboxylic acid, trideceth-15 carboxylic acid, trideceth-19 carboxylic acid, trideceth-10 phosphate, tridecylbenzene sulfonic acid, trilauryl citrate, trimethylolpropane hydroxypropylbis-hydroxyethylamine dendrimer, trisodium lauroampho PG-acetate chloride phosphate, undecanoic acid, undeceth-5 carboxylic acid, undecylenamide propylamine oxide, undecylenamide propyl betaine, undecylenic acid, undecylenoyl collagen amino acids, undecylenoyl glycine, undecylenoyl hydrolyzed collagen, undecylenoyl wheat amino acids, undecyl glucoside, wheat germ acid, wheat germ amide propylamine oxide, wheat germ amide propyl betaine, Yucca Schidigera leaf / root / stem extract, Yucca Schidigera stem extract, cocos zinc sulfate and coco zinc sulfate.

[0156] Nonionic surfactant Alcohol alkoxylate The nonionic surfactant to be added is preferably alkoxylated and / or propoxylated, and in particular is a primary alcohol having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per mole of alcohol. C8-C 16 -alcohol alkoxylate, preferably ethoxylated and / or propoxylated C 10 -C 15 -alcohol alkoxylate, especially having an ethoxylation degree of 2 to 10, preferably 3 to 8 and / or a propoxylation degree of 1 to 6, preferably 1.5 to 5 of C 12 -C 14 -alcohol alkoxylate is particularly preferred. The cited ethoxylation degree and propoxylation degree constitute statistical average values and can be whole or fractional numbers for a particular product. Preferred alcohol ethoxylates and propoxylates have a narrow homolog distribution (narrow range of ethoxylates / propoxylates, NRE / NRP). In addition to these nonionic surfactants, aliphatic alcohols having more than 12 EO can also be used. These examples are (tallow) aliphatic alcohols having 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO.

[0157] Alkyl glucoside (APG (registered trademark)) Furthermore, as an additional nonionic surfactant, an alkyl glucoside satisfying the general formula RO(G)x can be added, for example, as a compound, especially together with an anionic surfactant, where R represents a primary straight-chain or methyl-branched, especially 2-methyl-branched aliphatic group containing 8 to 22, preferably 12 to 18 carbon atoms, G represents a glucose unit containing 5 or 6 carbon atoms, preferably represents glucose. The degree of oligomerization x defining the distribution of monoglycosides and oligoglycosides is any number between 1 and 10, preferably any number between 1.1 and 1.4.

[0158] Fatty acid ester alkoxylate As the sole nonionic surfactant or in combination with other nonionic surfactants, Another type of preferred nonionic surfactant, especially used together with alkoxylated aliphatic alcohols and / or alkyl glucosides, is an alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl ester (preferably containing 1 to 4 carbon atoms in the alkyl chain), more specifically, for example, as described in JP-A-58-217598 or preferably a fatty acid methyl ester produced by the process described in WO 90 / 13533, an international patent application. C containing an average of 3 to 15 EO, especially an average of 5 to 12 EO 12 -C 18 Methyl esters of fatty acids are particularly preferred.

[0159] Amine oxide Amine oxide type nonionic surfactants, such as N-cocoalkyl-N,N-dimethylamine oxide and N-tallowalkyl-N,N-dihydroxyethylamine oxide and fatty acid alkanolamides are also suitable. The amount of these nonionic surfactants used is preferably less than or equal to the amount of ethoxylated aliphatic alcohol used, especially less than half of that amount.

[0160] Gemini surfactant So-called gemini surfactants can be regarded as further surfactants. Generally, such compounds are understood to mean compounds having two hydrophilic groups and two hydrophobic groups per molecule. Generally, these groups are separated from each other by a "spacer". The spacer is usually a hydrocarbon chain intended to be long enough so that the hydrophilic groups are separated by a distance sufficient for them to act independently of each other. These types of surfactants are generally characterized by an unusually low critical micelle concentration and the ability to strongly reduce the surface tension of water. However, in exceptional cases, not only dimers but also trimer surfactants are meant by the term gemini surfactant. Suitable gemini surfactants are, for example, sulfated hydroxy mixed ethers according to German Patent Application Publication No. DE 4321022 A1 or dimer alcohol bis- and trimer alcohol tris-sulfates and ether sulfates according to International Patent Application Publication No. WO 96 / 23768 A1. Dimers and trimers of blocked end groups according to German Patent Application Publication No. DE 19513391 A1 are particularly characterized by their bifunctionality and polyfunctionality. Gemini polyhydroxy fatty acid amides or polyhydroxy fatty acid amides, such as those described in International Patent Application Publications No. WO 95 / 19953 A1, WO 95 / 19954 A1 and WO 95 / 19955 A1, can also be used.

[0161] Cationic surfactant Tetraalkylammonium salt Cationically active surfactants contain, by dissociation in aqueous solution, a hydrophobic polymeric group necessary for the surface activity of the cation. An important representative group of cationic surfactants is of the general formula: (R 1 R 2 R 3 R 4 N + )X - tetraalkylammonium salts. Here, R 1 represents C1-C8 alkyl (alkenyl), R 2 , R 3 and R4 independently of one another, represents an alkyl (alkenyl) radical having 1 to 22 carbon atoms. X is a counter ion, preferably selected from the group consisting of halides, alkyl sulfates and alkyl carbonates. A cationic surfactant in which the nitrogen group is substituted with two long acyl groups and two short alkyl (alkenyl) groups is particularly preferred.

[0162] Esterquat A further class of cationic surfactants that are particularly useful as co-surfactants in the present invention is represented by so-called esterquats. Esterquats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by relevant methods of preparative organic chemistry. In this regard, reference is made to International Patent Application Publication No. WO 91 / 01295 A1, according to which triethanolamine is partially esterified with a fatty acid in the presence of hypophosphorous acid, air is passed through the reaction mixture, and then the whole is quaternized with dimethyl sulfate or ethylene oxide. Further, German Patent No. DE 4308794 C1 describes a process for the production of solid esterquats in which the quaternization of triethanolamine esters is carried out in the presence of a suitable dispersant, preferably an aliphatic alcohol.

[0163] Typical examples of esterquats suitable for use according to the present invention are products derived from monocarboxylic acids corresponding to the formula RCOOH where the acyl component is an acyl group containing 6 to 10 carbon atoms in RCO, and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and their industrial mixtures, such as so-called head fraction fatty acids. Esterquats derived from monocarboxylic acids containing 8 to 10 carbon atoms in the acyl component are preferably used. Other esterquats are those where the acyl component is derived from dicarboxylic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, preferably adipic acid. Overall, esterquats derived from mixtures of monocarboxylic acids containing 6 to 22 carbon atoms and adipic acid are preferably used. The molar ratio of mono- and dicarboxylic acids in the final esterquat may range from 1:99 to 99:1, preferably from 50:50 to 90:10, more particularly from 70:30 to 80:20. In addition to quaternized fatty acid triethanolamine esters salts, other suitable esterquats are quaternized ester salts with diethanolalkylamines or 1,2-dihydroxypropyldialkylamines of mono- / dicarboxylic acid mixtures. The esterquats may be obtained from both the corresponding triglycerides in mixtures of fatty acids and the corresponding dicarboxylic acids. One such process intended to represent the relevant prior art is proposed in European Patent EP 0750606 B1. For producing the quaternized esters, a mixture of mono- and dicarboxylic acids and triethanolamine (based on the available carboxyl functional groups) may be used in a molar ratio of 1.1:1 to 3:1. Bearing in mind the performance characteristics of the esterquats, a ratio of 1.2:1 to 2.2:1, preferably 1.5:1 to 1.9:1 has proven to be particularly advantageous. Preferred esterquats are industrial mixtures of mono-, di- and triesters having an average esterification degree of 1.5 to 1.9.

[0164] Amphoteric surfactant Betaine Amphoteric or zwitterionic surfactants have multiple functional groups that can be ionized in aqueous solution, thereby imparting anionic or cationic properties to the compound depending on the conditions of the medium (see DIN 53900, July 1972). Near the isoelectric point (pH about 4), amphoteric surfactants form internal salts and become poorly soluble or insoluble in water. Amphoteric surfactants are subdivided into zwitterions and betaines, the latter existing as dipolar ions in solution. Zwitterions are compounds that have both acidic and basic hydrophilic groups, i.e., compounds that behave as acids or bases depending on the conditions. In particular, betaines are known surfactants and are mainly produced by the carboxyalkylation, preferably carboxymethylation, of amine compounds. The starting materials are preferably condensed with a halocarboxylic acid or its salt, more particularly sodium chloroacetate, and 1 mol of salt is formed per mol of betaine. The addition of unsaturated carboxylic acids such as acrylic acid is also possible. Examples of suitable betaines are compounds corresponding to the formula R 1 R 2 R 3 N-(CH2) q COOX (wherein R 1 is an alkyl radical having 6 to 22 carbon atoms, R 2 is hydrogen or an alkyl group containing 1 to 4 carbon atoms, R 3 is an alkyl group containing 1 to 4 carbon atoms, q is a number from 1 to 6, and X is an alkali and / or alkaline earth metal or ammonium), which are carboxyalkylation products of secondary and especially tertiary amines. Typical examples are hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, C 12 / 14 -cocoalkyl dimethylamine, myristyl dimethylamine, cetyl dimethylamine, stearyl dimethylamine, stearyl ethylmethylamine, oleyl dimethylamine, C 16 / 18- They are carboxymethylation products of tallow alkyl dimethylamines and their industrial mixtures, especially dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine and their industrial mixtures.

[0165] Alkylamidobetaine Other suitable betaines are of the formula R 1 CO(R 3 )(R 4 )-NH-(CH2) p -N-(CH2) q COOX and are carboxyalkylation products of amidoamines corresponding thereto, where R 1 CO is an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, R 2 is hydrogen or an alkyl radical having 1 to 4 carbon atoms, R 3 is an alkyl radical having 1 to 4 carbon atoms, p is a number from 1 to 6, q is a number from 1 to 3 and X is an alkali and / or alkaline earth metal or ammonium. Typical examples are fatty acids having 6 to 22 carbon atoms, such as caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linolic acid, linoleic acid, eleostearic acid, arachidonic acid, gadoleic acid, behenic acid, erucic acid and their technical mixtures, and reaction products with N,N-dimethylaminoethylamine, N,N-dimethylaminopropylamine, N,N-diethylaminopropylamine, N,N-diethylaminoethylamine and N,N-diethylamino-propylamine, which are condensed with sodium chloroacetate. Commercially available products include Dehyton® K and Dehyton® PK (Cognis Deutschland GmbH & Co., KG) and Tego® betaine (Goldschmidt).

[0166] Another suitable starting material for the betaine used for the purposes of the present invention is imidazoline. These substances are also known and can be obtained, for example, by cyclocondensation of 1 to 2 moles of C6-C 22 fatty acids with polyfunctional amines such as aminoethyl ethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. A typical example is the condensation product of the above-mentioned fatty acids with AEEA, preferably an imidazoline based on lauric acid, which are subsequently betainized with sodium chloroacetate. Commercially available products include Dehyton® G (Cognis Deutschland GmbH & Co., KG).

[0167] The amount of (co)surfactant contained in the composition of the present invention is preferably from 0.1% to 90% by weight, in particular from 10% to 80% by weight and particularly preferably from 20% to 70% by weight.

[0168] Organic solvent Liquid light or heavy detergents may contain an organic solvent, preferably one miscible with water . Polydiols, ethers, alcohols, ketones, amides and / or esters are preferably used as organic solvents for this purpose in an amount of from 0 to 90% by weight, preferably from 0.1 to 70% by weight, in particular from 0.1 to 60% by weight. Low molecular weight polar substances such as methanol, e thanol, propylene carbonate, acetone, acetonylacetone, diacetone alcohol , ethyl acetate, 2-propanol, ethylene glycol, propylene glycol, g lycerin, diethylene glycol, dipropylene glycol monomethyl ether and di methylformamide or mixtures thereof are preferred.

[0169] Enzyme Cellulase enzyme The cellulase enzyme optionally used in the present detergent composition, when present, is preferably incorporated at a level sufficient to provide up to about 5 mg, more preferably about 0.01 mg to about 3 mg of active enzyme per gram of the composition. Unless otherwise stated, the compositions herein preferably contain from about 0.001% to about 5%, preferably from 0.01% to 1% by weight of a commercially available enzyme preparation.

[0170] Cellulases suitable for the present invention include either bacterial or fungal cellulases. Preferably, they have an optimal pH of 5 to 9.5. Suitable cellulases are fungal cellulases produced from Humicola insolens and Humicola strain DSM1800 or cellulase 212-producing bacteria belonging to the genus Aeromonas, and suitable cellulases extracted from the hepatopancreas of the marine mollusk Dolabella Auricula Solander are also described in UK Patent Application Publication No. 2,075,028A. Furthermore, cellulases particularly suitable for use herein are disclosed in International Publication No. 1992013057A1. Most preferably, the cellulase used in the detergent composition of the present invention is commercially available under the trade names CAREZYMEO and CELLUZYMEO from NOVO Industries A / S.

[0171] Other enzymes For example, additional enzymes can be included in the detergent compositions herein for a wide range of fabric washing purposes, such as the removal of proteinaceous, carbohydrate, or triglyceride stains, and the prevention of migration of fugitive dyes, and the restoration of fabrics. The additional enzymes to be incorporated include proteases, amylases, lipases, and peroxidases, and mixtures thereof. Other types of enzymes can also be included. They can be of any suitable origin, such as of plant, animal, bacterial, fungal, and yeast origin. However, their selection is influenced by several factors, such as optimization of pH-activity and / or stability, thermal stability, stability towards surfactants, builders, and the potential to cause malodors during use. In this regard, bacterial or fungal enzymes, such as bacterial amylases and proteases, are preferred.

[0172] Enzymes are typically incorporated at levels sufficient to provide from about 5 mg up to, more typically, from about 0.01 mg to about 3 mg of active enzyme per gram of the composition. In other words, the compositions herein typically contain from about 0.001 wt% to about 5 wt%, preferably 0.01 wt% to 1 wt% of a commercially available enzyme preparation. Protease enzymes are typically present in such commercially available preparations at levels sufficient to provide from 0.005 to 0.1 Anson units (AU) of activity per gram of the composition.

[0173] Suitable examples of proteases are subtilisins obtained from certain strains of B. subtilis and B. licheniforms. Another suitable protease is obtained from a Bacillus strain that has maximum activity over the pH range of 8 - 12 and is developed and sold under the trade name ESPERASE® by Novo Industries A / S. The preparation of this enzyme and similar enzymes is described in Novo's British Patent No. 1,243,784. Proteolytic enzymes suitable for removing commercially available proteinaceous stains include those sold under the trade names ALCALASE® and SAVINASE® by Novo Industries A / S and MAXATASE® by International Bio-Synthetics, Inc. Other proteases include protease A; protease B, and proteases manufactured according to U.S. Patent No. 5,204,015 and U.S. Patent No. 5,244,791 by Genencor International, Inc.

[0174] Examples of amylases include α - amylases such as RAPIDASE® from International Bio-Synthetics, Inc. and TERMAMYL® from Novo Industries.

[0175] Suitable lipase enzymes for use in detergents include those produced by microorganisms of the genus Pseudomonas, such as Pseudomonas stutzeri ATCC19154. This lipase is commercially available from Amano Pharmaceutical Co., Ltd. under the trade name Lipase P "Amano". Other commercially available lipases include Amano-CES, lipases derived from Chromobacter viscosum, such as Chromobacter viscosum var. lipolyticum NRRLB3673 (commercially available from Toyo Jozo Co.), and further Chromobacter viscosum lipases from U.S. Biochemical Corp. and Disoynth Co., as well as lipases from Pseudomonas gladioli. The LIPOLASE® enzyme derived from Humicola lanuginosa (commercially available from Novo Industries A / S) is a preferred lipase for use herein.

[0176] Peroxidase enzymes are used in combination with an oxygen source, such as percarbonate, perborate, persulfate, hydrogen peroxide, etc. They are used for "solution bleaching", i.e., to prevent the transfer of dyes or pigments removed from the substrate during the washing operation to other substrates in the washing solution. Peroxidase enzymes are known in the art and include, for example, horseradish peroxidase, ligninase, and haloperoxidases such as chloroperoxidase and bromoperoxidase. Peroxidase-containing detergent compositions are disclosed, for example, in WO 1989099813 A1.

[0177] Enzyme stabilizer The enzymes used herein are stabilized by the presence of a water-soluble source of calcium and / or magnesium ions in the final detergent composition which provides such ions to the enzyme. (Calcium ions are generally somewhat more effective than magnesium ions and are preferred herein if only one type of cation is used.) Further stability can be provided by the presence of various other stabilizers disclosed in the art, particularly borate species (see U.S. Patent No. 4,537,706 which is incorporated herein by reference in its entirety). Typical detergents, particularly liquids, contain from about 1 to about 30, preferably from about 2 to about 20, more preferably from about 5 to about 15, most preferably from about 8 to about 12 millimoles of calcium ions per liter of the final composition. In solid detergent compositions, the formulation can contain an amount of a water-soluble calcium ion source sufficient to provide such an amount in the wash liquor. Alternatively, natural water hardness is sufficient.

[0178] It should be understood that the above levels of calcium and / or magnesium ions are sufficient to provide enzyme stability. To provide a further measure of grease removal performance, more calcium and / or magnesium ions can be added to the composition. Thus, as a general proposition, the compositions herein typically contain from about 0.05 wt% to about 2 wt% of a water-soluble source of calcium or magnesium ions or both. The amount can, of course, vary depending on the amount and type of enzyme used in the composition.

[0179] The compositions of the present specification can also optionally, but preferably, contain various additional stabilizers, particularly borate type stabilizers. Typically, such stabilizers are used in the composition at a level of about 0.25 wt% to about 10 wt%, preferably about 0.5 wt% to about 5 wt%, more preferably about 0.75 wt% to about 3 wt% (calculated based on boric acid) of boric acid or other borate compounds that can produce boric acid in the composition. Boric acid is preferred, but other compounds such as boron oxide, borax, and other alkali metal borates (e.g., sodium ortho-, meta-, and pyroborates and sodium pentaborate) are suitable. Substituted boric acids (e.g., phenylboronic acid, butaneboronic acid, and p-bromophenylboronic acid) can also be used in place of boric acid.

[0180] Builder Zeolite As a builder, a finely crystalline synthetic zeolite containing bound water, for example, preferably zeolite A and / or P can be used. Zeolite MAP.RTM (a commercially available product from Crosfield) is particularly preferred as zeolite P. However, mixtures of zeolite X and A, X, Y, and / or P are also suitable. A co-crystallized sodium / potassium aluminosilicate from zeolite A and zeolite X, which is available as Vegobond® RX (a commercially available product from Condea Augusta S.p.A.), is also of particular interest. Preferably, the zeolite can be used as a spray-dried powder. When the zeolite is added as a suspension, this contains a small amount of a non-ionic surfactant as a stabilizer, for example, an ethoxylated C12-C18 aliphatic alcohol having 2-5 ethylene oxide groups, 1-3 wt% based on the zeolite, a C 12 -C 14It can contain aliphatic alcohols or ethoxylated isotridecanol. Suitable zeolites have an average particle size of less than 10 μm (test method: volume distribution Coulter counter), preferably contain 18 to 22% by weight, especially 20 to 22% by weight of bound water. Separately from this, phosphates can also be used as builders.

[0181] Layered silicate Preferred alternatives or partial alternatives to phosphates and zeolites are crystalline sodium layered silicates. These types of crystalline layered silicates are described, for example, in European Patent Application Publication No. 0164514 A1, which is a European patent application. Preferred crystalline layered silicates are those obtained, for example, from the process described in International Publication No. 91 / 08171 A1, which is an international patent application.

[0182] Amorphous silicate Preferred builders also contain amorphous sodium silicate having a modulus (Na2O:SiO2 ratio) of 1:2 to 1:3.3, preferably 1:2 to 1:2.8, more preferably 1:2 to 1:2.6, which dissolves slowly and exhibits multiple wash cycle characteristics. The delay in dissolution compared to conventional amorphous sodium silicate can be obtained in various ways, for example, by surface treatment, compounding, compression / compaction, or overdrying. In the context of the present invention, the term "amorphous" also means "X-ray amorphous". In other words, the silicate does not produce sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but gives rise to one or more maxima of scattered X-rays having a width of several degrees at the diffraction angle. However, particularly good builder properties can be achieved even when the silicate particles produce diffuse diffraction maxima or sharp diffraction maxima in electron diffraction experiments. This should be interpreted to mean that the product has microcrystalline regions with sizes of 10 to several 100 nm, with values of 50 nm or less, particularly 20 nm or less being preferred. This type of X-ray amorphous silicate having a similarly slow dissolution compared to conventional water glass is described, for example, in German Patent Application Publication No. 4400024 A1. Compressed / compacted amorphous silicate, compound amorphous silicate and overdried X-ray amorphous silicate are particularly preferred.

[0183] Phosphate Also, generally known phosphates can also be added as builders, provided their use should not be avoided for ecological reasons. Sodium salts of orthophosphate, pyrophosphate, particularly tripolyphosphate are particularly suitable. Their content is generally 25% by weight or less, preferably 20% by weight or less, based on the respective finished composition. In some cases, tripolyphosphate has been shown to provide a synergistic improvement in secondary detergency in small amounts, already up to 10% by weight at most, in combination with other builders, based on the finished composition. The preferred amount of phosphate is less than 10% by weight, particularly 0% by weight.

[0184] Co-builder Polycarboxylic acid Useful organic cobuilders are, for example, polycarboxylic acids which can be used in the form of their sodium salts, and polycarboxylic acids are understood to be carboxylic acids having more than one acid functional group. Examples include citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA) and its derivatives and mixtures thereof. Preferred salts are salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.

[0185] Organic acid The acids themselves can also be used. In addition to their building effects, the acids also typically have the properties of acidifying components and thus also serve to establish a relatively low and mild pH in the detergent or cleansing composition. In this regard, citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and mixtures thereof are particularly mentioned. Further suitable acidifying agents are known pH regulators such as sodium hydrogen carbonate and sodium hydrogen sulfate.

[0186] Polymer Particularly suitable polymeric cobuilders are polyacrylates preferably having a molecular weight of from 2,000 to 20,000 g / mol. Because of their excellent solubility, preferred representatives of this group are also short-chain polyacrylates having a molecular weight of from 2,000 to 10,000 g / mol, more preferably from 3,000 to 5,000 g / mol. Suitable polymers can also contain substances consisting in part or completely of vinyl alcohol units or derivatives thereof.

[0187] Even more suitable copolymer polycarboxylates are, in particular, those of acrylic acid and methacrylic acid, and those of acrylic acid or methacrylic acid and maleic acid. Copolymers of acrylic acid and maleic acid, containing 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid, have been found to be particularly suitable. Its relative molecular weight based on the free acid is generally in the range of 2,000 to 70,000 g / mol, preferably 20,000 to 50,000 g / mol, and particularly 30,000 to 40,000 g / mol. The (co)polymeric polycarboxylate can be added as an aqueous solution or, preferably, as a powder. To improve water solubility, the polymer can also contain allyl sulfonic acid as a monomer, such as allyloxybenzene sulfonic acid and methallyl sulfonic acid, as described in European Patent No. 0727448 B1.

[0188] Biodegradable polymers containing more than two different monomer units are particularly preferred, examples being those containing acrylate and maleate, and further vinyl alcohol or vinyl alcohol derivatives as monomers, as described in, for example, German Patent Application Publication No. 4300772 A1, or those containing acrylate and salts of 2-alkylallyl sulfonic acid, and sugar derivatives as monomers. Even more preferred copolymers are those described in German Patent Application Publication Nos. 4303320 A1 and 4417734 A1, preferably those containing acrolein and acrylic acid / acrylic salt or acrolein and vinyl acetate as monomers.

[0189] Similarly, other preferred builders are polymeric aminodicarboxylic acids, their salts or precursors. Polyaspartic acid or its salts and derivatives disclosed in German Patent Application Publication No. 19540086 A1, a German patent application, are particularly preferred as having a bleaching stabilizing effect in addition to cobuilder properties.

[0190] Even more suitable builders are polyacetals that can be obtained by treating a dialdehyde with a polyol carboxylic acid having 5 to 7 carbon atoms and at least 3 hydroxyl groups, as described in European Patent Application Publication No. 0280223A1. Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof, and from polycarboxylic acids such as gluconic acid and / or glucoheptonic acid.

[0191] Carbohydrate Even more suitable organic builders are dextrins, which are oligomers or polymers of carbohydrates that can be obtained, for example, by partial hydrolysis of starch. The hydrolysis can be carried out using typical processes, such as acidic or enzymatic catalytic processes. The hydrolysis product preferably has an average molecular weight in the range of 400 to 500,000 g / mol. Polysaccharides with a dextrose equivalent (DE) of 0.5 to 40, more particularly 2 to 30, are preferred, where DE is a measure of the reducing effect of the polysaccharide compared to dextrose having a DE of 100. Both maltodextrins with a DE of 3 to 20 and dried glucose syrup with a DE of 20 to 37, as well as so-called yellow dextrins and white dextrins with a relatively high molecular weight of 2,000 to 30,000 g / mol, may be used. Preferred dextrins are described in British Patent Application Publication No. 9419091.

[0192] Such oxidized derivatives of dextrins relate to the reaction products with oxidation compositions that can oxidize at least one alcohol functional group of the saccharide ring to a carboxylic acid functional group. Such oxidized dextrins and their manufacturing processes are known, for example, from European Patent Application Publication No. 0232202A1. Products oxidized at C6 of the saccharide ring can be particularly advantageous.

[0193] Oxydisuccinate and other derivatives of succinate, preferably ethylenediaminedisuccinate, are also more suitable builders. Here, ethylenediamine-N,N'-disuccinate (EDDS) (the synthesis of which is described, for example, in U.S. Patent No. 3,158,615) is preferably used in the form of its sodium or magnesium salts. In this context, glycerol disuccinate and glycerol trisuccinate as described in U.S. Patent No. 4,524,009 are particularly preferred. The appropriate addition amount in zeolite-containing and / or silicate-containing formulations ranges from 3 to 15% by weight.

[0194] Lactone Other useful organic builders are, for example, acetylated hydroxycarboxylic acids and their salts which may optionally be present in lactone form and contain at least 4 carbon atoms, at least one hydroxyl group and at most 2 acid groups. Such builders are described, for example, in International Publication No. WO 95 / 20029 A1 which is an international patent application.

[0195] Bleaching compounds, bleaching agents and bleach activators The detergent compositions herein can optionally contain bleaching agents and bleaching compositions comprising a bleaching agent and one or more bleach activators. When present, the bleaching agent is typically at a level of about 1% to about 30%, more typically about 5% to about 20% of the detergent composition (especially for fabric laundering). When present, the amount of bleach activator is typically about 0.1% to about 60%, more typically about 0.5% to about 40% of the bleaching composition comprising the bleaching agent + bleach activator.

[0196] The bleaching agents used herein can be any bleaching agent useful in detergent compositions for fabric cleaning, hard surface cleaning, or other cleaning purposes now known or to be known. These include oxygen bleaching agents and other bleaching agents. Perborate bleaching agents, such as sodium perborate (e.g., the monohydrate or tetrahydrate), can be used herein.

[0197] Another category of bleaching agents that can be used without limitation includes percarboxylic acid bleaching agents and their salts. Suitable examples of this type of agent include magnesium monoperoxyphthalate hexahydrate, magnesium salt of metachloroperbenzoic acid, 4-nonylamino-4-oxoperoxybutyric acid, and diperoxydodecanedioic acid.

[0198] Peroxide bleaching agents can also be used. Suitable peroxide bleaching compounds include sodium carbonate peroxide and equivalent "percarbonate" bleaching agents, sodium pyrophosphate peroxide, urea peroxide, and sodium peroxide. Persulfate bleaching agents (e.g., OXONEO® commercially available from DuPont) can also be used.

[0199] Preferred percarbonate bleaching agents include dry particles having an average particle size in the range of about 500 micrometers to about 1,000 micrometers, with no more than about 10 weight percent of the particles being smaller than about 200 micrometers and no more than about 10 weight percent of the particles being larger than about 1,250 micrometers. Optionally, the percarbonate can be coated with a silicate, borate, or water-soluble surfactant. Percarbonates are available from various commercial sources.

[0200] Mixtures of bleaching agents can also be used.

[0201] Peroxide bleaching agents, perborates, percarbonates, etc. are preferably combined with a bleach activator to provide in-situ production (i.e., during the washing process) of the corresponding peroxy acid in an aqueous solution. Nonanoyloxybenzenesulfonate (NOBS) and tetraacetylethylenediamine (TAED) activators are typical, and mixtures thereof can also be used.

[0202] Preferred amide-derived bleach activators include (6-octanamido-caproyl)oxybenzenesulfonate, (6-nonanamidocaproyl)oxybenzenesulfonate, (6-decanamido-caproyl)oxybenzenesulfonate, and mixtures thereof.

[0203] Another class of bleach activators includes the benzoxazine-type activators disclosed in U.S. Patent No. 4,96 6,723, which is incorporated herein by reference.

[0204] Highly preferred lactam activators include benzoylcaprolactam, octanoylcaprolactam, 3,5,5-trimethylhexanoylcaprolactam, nonanoylcaprolactam, decanoylcaprolactam, undecylenoylcaprolactam, benzoylvalerolactam, octanoylvalerolactam, decanoylvalerolactam, undecylenoylvalerolactam, nonanoylvalerolactam, 3,5,5-trimethylhexanoylvalerolactam, and mixtures thereof, optionally adsorbed on a solid carrier, such as acylcaprolactam adsorbed on sodium perborate, preferably benzoylcaprolactam.

[0205] Bleaching agents other than oxygen bleaching agents are also known in the art and can be used here. One type of particularly important non-oxygen bleaching agent includes photoactivatable bleaching agents such as sulfonated zinc and / or aluminum phthalocyanine. When used, the detergent composition typically contains from about 0.025% to about 1.25% by weight of such a bleaching agent, particularly zinc phthalocyanine sulfonate.

[0206] If desired, the bleaching compound can be catalyzed by a manganese compound. Such manganese-based catalysts are well known in the art, such as Mn IV 2(μ-O)3(1,4,7-trimethyl-1,4,7-triazacyclononane)2(PF6)2, Mn III2(μ-O)1(μ-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)2, Mn IV 4(μ-O)6(1,4,7-triazacyclononane)4(ClO4)4, Mn III Mn IV 4(μ-O)1(μ-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)3, Mn IV (1,4,7-trimethyl-1,4,7-triazacyclononane)-(OCH3)3(PF6), and mixtures thereof.

[0207] As a practical matter, without limitation, the compositions and processes of the present specification can be adjusted to provide an active bleach catalyst species on the order of at least one part per ten million parts in an aqueous cleaning solution, preferably providing from about 0.1 ppm to about 700 ppm, more preferably from about 1 ppm to about 500 ppm of the catalyst species in the wash liquor.

[0208] Polymeric soil release agents In the detergent compositions and processes of the present invention, any polymeric soil release agent known to those skilled in the art can optionally be used. Polymeric soil release agents are characterized by having both a hydrophilic segment that hydrophilizes the surface of hydrophobic fibers such as polyester and nylon, and a hydrophobic segment that deposits on the hydrophobic fibers and remains attached after completion of the washing and rinsing cycles, thus serving as an anchor for the hydrophilic segment. This makes it possible to more easily clean the soil generated after treatment with a soil release agent in subsequent washing procedures.

[0209] Polymeric soil release agents useful herein include, in particular, (a) a polyoxyethylene segment having a degree of polymerization of at least 2, or (ii) an oxypropylene or polyoxypropylene segment having a degree of polymerization of 2 to 10, wherein this hydrophilic segment does not include oxypropylene units unless bonded to an adjacent moiety at each end by an ether linkage, or (iii) a mixture of oxyalkylene units containing oxyethylene and 1 to about 30 oxypropylene units, wherein this mixture contains a sufficient amount of oxyethylene units such that the hydrophilic component has a hydrophilicity large enough to increase the hydrophilicity of the surface of conventional polyester synthetic fibers upon deposition of the soil release agent on the surface, and this hydrophilic segment preferably consists essentially of a mixture containing at least about 25% oxyethylene units, more preferably about 20 to 30 oxypropylene units, and at least about 50% oxyethylene units, with respect to such components, one or more nonionic hydrophilic components, or (b) (i) a C3 oxyalkylene terephthalate segment, wherein when this hydrophobic component also contains oxyethylene terephthalate, the ratio of oxyethylene terephthalate:C3 oxyalkylene terephthalate units is about 2:1 or less, (ii) a C4-C6 alkylene or oxy C4-C6 alkylene segment, or a mixture thereof, (iii) a poly(vinyl ester) segment having a degree of polymerization of at least 2, preferably polyvinyl acetate, or (iv) a C1-C4 alkyl ether or C4 hydroxyalkyl ether substituent or a mixture thereof, wherein this substituent is present in the form of a C1-C4 alkyl ether and / or C4 hydroxyalkyl ether cellulose derivative or a mixture thereof, and such cellulose derivatives are amphoteric, whereby they adhere to the surface of conventional polyester synthetic fibers, retain a sufficient level of hydroxyls, and, once adsorbed on such a conventional synthetic fiber surface, have C1-C4 alkyl ether or C4 hydroxyalkyl ether units at a level sufficient to increase the hydrophilicity of the fiber surface, one or more hydrophobic components including those having such units, or a soil release agent having a combination of (a) and (b) is included.

[0210] Typically, the polyoxyethylene segment of (a)(i) has a degree of polymerization of about 200, but higher levels, preferably 3 to about 150, more preferably 6 to about 100 can be used. Suitable oxy C4-C6 alkylene hydrophobic segments include, but are not limited to, end caps of polymeric soil release agents.

[0211] Polymeric soil release agents useful in the present invention also include cellulose derivatives such as hydroxyether cellulose-based polymers, ethylene terephthalate or propylene terephthalate and copolymeric blocks of polyethylene oxide or polypropylene oxide terephthalate. Such agents are commercially available and include hydroxyethers of cellulose such as METHOCEL® (Dow). Cellulosic soil release agents for use herein also include those selected from the group consisting of C1-C4 alkyl and C4 hydroxyalkyl celluloses.

[0212] Soil release agents characterized by poly(vinyl ester) hydrophobic segments include graft copolymers of poly(vinyl ester), such as C1-C6 vinyl esters, preferably grafted onto a polyalkylene oxide backbone, such as a polyethylene oxide backbone, and reference is made to European Patent No. 0219048, which is hereby incorporated by reference in its entirety. Commercially available soil release agents of this type include SOKALAN® type materials, such as SOKALAN® HP-22 (available from BASF).

[0213] One type of preferred soil release agent is a copolymer having random blocks of ethylene terephthalate and polyethylene oxide (PEO) terephthalate. The molecular weight of this polymeric soil release agent is preferably in the range of about 25,000 to about 55,000.

[0214] Another preferred polymeric soil release agent is a polyester having repeating units of ethylene terephthalate units and containing 10 to 15% by weight of ethylene terephthalate units together with 90 to 80% by weight of polyoxyethylene terephthalate units derived from polyoxyethylene glycol having an average molecular weight of 300 to 5,000. Examples of this polymer include the commercially available materials ZELCON® 5126 (manufactured by DuPont) and MILEASE® T (manufactured by ICI).

[0215] Another preferred polymeric soil release agent is a sulfonated product of a substantially linear ester oligomer comprising a terephthaloyl and oxyalkyleneoxy repeating unit oligomeric ester backbone and terminal moieties covalently bonded to the backbone. These soil release agents are fully described in U.S. Patent No. 4,968,451. Other suitable polymeric soil release agents include the terephthalate polyesters of U.S. Patent No. 4,711,730, the anionic end-capped oligomeric esters of U.S. Patent No. 4,721,580, the block polyester oligomer compounds of U.S. Patent No. 4,702,857, and the anionic, particularly sulfoaroyl end-capped terephthalate esters of U.S. Patent No. 4,877,896, all of these patents being hereby incorporated by reference in their entirety.

[0216] Yet another preferred soil release agent is an oligomer having repeating units of terephthaloyl units, sulfoisoterephthaloyl units, oxyethyleneoxy units and oxy-1,2-propylene units. The repeating units form the backbone of the oligomer and preferably terminate with modified isethionate end caps. A particularly preferred soil release agent of this type contains about 1 sulfoisophthaloyl unit, 5 terephthaloyl units, oxyethyleneoxy units and oxy-1,2-propyleneoxy units in a ratio of about 1.7 to about 1.8, and two end cap units of sodium 2-(2-hydroxyethoxy)-ethanesulfonate. This soil release agent also contains from about 0.5 wt% to about 20 wt% of a crystallization reducing stabilizer of the oligomer, which is preferably selected from the group consisting of xylene sulfonate, cumene sulfonate, toluene sulfonate, and mixtures thereof.

[0217] When used, the soil release agent is generally included at a level of from about 0.01 wt% to about 10.0 wt%, typically from about 0.1 wt% to about 5 wt%, preferably from about 0.2 wt% to about 3.0 wt% of the detergent compositions herein.

[0218] Polymeric dispersant The polymeric dispersant can be advantageously utilized in the detergent compositions herein, particularly in the presence of zeolite and / or layered silicate builders, at levels of from about 0.1 wt% to about 7 wt%. Suitable polymeric dispersants include polymeric polycarboxylates and polyethylene glycols, but other known in the art can also be used. Without intending to be limited by theory, polymeric dispersants are thought to enhance overall detergent builder performance when used in combination with other builders (including low molecular weight polycarboxylates) by inhibiting crystal growth, deflocculating particulate soil release and preventing redeposition.

[0219] Polymeric polycarboxylate materials can be prepared, preferably in their acid form, by polymerizing or copolymerizing suitable unsaturated monomers. Unsaturated monomer acids that can be polymerized to form suitable polymeric polycarboxylates include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid, and methylenemalonic acid. The presence of polymeric polycarboxylate or monomeric segments of this specification that do not contain carboxylate radicals, such as vinyl methyl ether, styrene, ethylene, etc., is preferred, provided that such segments do not exceed about 40% by weight.

[0220] Particularly preferred polymeric polycarboxylates can be derived from acrylic acid. Such acrylic acid-based polymers useful herein are water-soluble salts of polymerized acrylic acid. The average molecular weight of the acid form of such polymers is preferably in the range of about 2,000 to 10,000, more preferably about 4,000 to 7,000, and most preferably about 4,000 to 5,000. Water-soluble salts of such acrylic acid polymers can include, for example, alkali metal, ammonium, and substituted ammonium salts. This type of soluble polymer is a known material. The use of this type of polyacrylate in detergent compositions is disclosed, for example, in U.S. Patent No. 3,308,067.

[0221] Acrylic / maleic acid copolymers can also be used as a preferred component of the dispersion / redeposition inhibitor. Such materials include water-soluble salts of copolymers of acrylic acid and maleic acid. The average molecular weight of the acid form of such copolymers is preferably in the range of about 2,000 to 100,000, more preferably about 5,000 to 75,000, and most preferably about 7,000 to 65,000. The ratio of acrylate to maleate segments in such copolymers generally ranges from about 30:1 to about 1:1, more preferably from about 10:1 to 2:1. The water-soluble salts of such acrylic acid / maleic acid copolymers can include, for example, alkali metal, ammonium, and substituted ammonium salts. This type of soluble acrylate / maleate copolymer is a known material described in European Patent Application Publication No. 0193360A1, and such polymers containing hydroxypropyl acrylate are also described. Further useful dispersants include maleic acid / acrylic acid / vinyl alcohol terpolymers, such as a 45 / 45 / 10 terpolymer of acrylic acid / maleic acid / vinyl alcohol.

[0222] Another polymer material that can be included is polyethylene glycol (PEG). PEG not only exhibits the performance of a dispersant but also can act as a clay soil removal - redeposition inhibitor. The typical molecular weight range for these purposes is from about 500 to about 100,000, preferably from about 1,000 to about 50,000, and more preferably from about 1,500 to about 10,000.

[0223] Polyaspartate and polyglutamate dispersants can also be used, especially in combination with zeolite builders. Dispersants such as polyaspartate preferably have a molecular weight (average) of about 10,000.

[0224] Foam inhibitor / foaming inhibitor In particular, when used in an automatic washing process, it may be advantageous to add a conventional foam inhibitor to the composition. Suitable foam inhibitors include, for example, C 18 -C24 Soaps of natural or synthetic origin with a high fatty acid content are mentioned. Suitable non-surfactant foam suppressants are, for example, organopolysiloxanes and their mixtures with optionally silanized fine silica, as well as paraffins, waxes, microcrystalline waxes and their mixtures with silanized silica or bis-stearylethylenediamine. Mixtures of various foam suppressants, such as mixtures of silicone, paraffin or wax, are also advantageously used. Preferably, the foam suppressant, especially the silicone-containing and / or paraffin-containing foam suppressant, is filled into a particulate water-soluble or dispersible carrier material. In particular in this case, a mixture of paraffin and bis-stearylethylenediamide is preferred.

[0225] Compounds for reducing or suppressing foam formation can be incorporated into the detergent compositions of the present invention. Foam suppression can be particularly important in so-called "high-concentration cleaning processes" and in front-loading of European-style washing machines.

[0226] A wide variety of materials can be used as foam suppressants, and foam suppressants are well known to those skilled in the art. See, for example, Kirk Othmer Encyclopedia of Chemical Technology, Third Edition, Volume 7, pages 430 - 447 (John Wiley & Sons, Inc., 1979). One category of foam suppressants of particular interest includes aliphatic monocarboxylic acids and their soluble salts. The aliphatic monocarboxylic acids and their salts used as foam suppressants typically have a hydrocarbyl chain of 10 to about 24 carbon atoms, preferably 12 to 18 carbon atoms. Suitable salts include alkali metal salts such as sodium salts, potassium salts and lithium salts, as well as ammonium salts and alkanolammonium salts.

[0227] The detergent compositions herein can also contain non-surfactant foam suppressants. These include, for example, paraffins, fatty acid esters (e.g., fatty acid triglycerides), fatty acid esters of monohydric alcohols, aliphatic C18 -C 40 It contains high molecular weight hydrocarbons such as ketones (e.g., stearin). Other foam suppressants include cyanuric chloride and 2 or 3 moles of primary or secondary amines containing 1 to 24 carbon atoms, propylene oxide and monostearyl phosphate, such as monostearyl alcohol phosphate ester and the product of monostearyl dialkali metal (e.g., K, Na, and Li) phosphate and phosphate ester, N-alkylated aminotriazines, such as tri- to hexaalkylmelamine or di- to tetraalkyldiamine chlorotriazine. Hydrocarbons such as paraffin and haloparaffin can be utilized in liquid form. The liquid hydrocarbon is liquid at room temperature and atmospheric pressure, has a pour point in the range of about -40°C to about 50°C and a minimum boiling point of about 110°C (atmospheric pressure) or higher. It is also known to use waxy hydrocarbons having a melting point preferably less than about 100°C. Hydrocarbon foam suppressants are known in the art and include aliphatic, alicyclic, aromatic, and heterocyclic saturated or unsaturated hydrocarbons having about 12 to about 70 carbon atoms. The term "paraffin" used in the discussion of this foam suppressant is intended to include mixtures of true paraffins and cyclic hydrocarbons.

[0228] Another preferred category of non-surfactant foam suppressants includes silicone foam suppressants. This category includes polyorganosiloxane oils, such as polydimethylsiloxane, dispersions or emulsions of polyorganosiloxane oils or resins, and combinations of polyorganosiloxane and silica particles, where the polyorganosiloxane is chemisorbed or condensed on the silica. Silicone foam suppressants are well-known in the art.

[0229] Other silicone foam suppressants are disclosed in U.S. Patent No. 3,455,839, which is hereby incorporated by reference in its entirety, and relate to compositions and processes for defoaming aqueous solutions by incorporating small amounts of polydimethylsiloxane fluid therein.

[0230] A mixture of silicone and silanized silica is described, for example, in German Patent Application Publication No. (DE-OS) 2124526, the entire disclosure of which is incorporated herein by reference. Silicone defoamers and foam suppressants in granular detergent compositions are disclosed in U.S. Patent No. 4,652,392, the entire disclosure of which is incorporated herein by reference.

[0231] In the preferred silicone foam suppressants used herein, the continuous phase solvent is composed of a specific polyethylene glycol or polyethylene - polypropylene glycol copolymer or mixtures thereof (preferably) or polypropylene glycol. The primary silicone foam suppressants are branched / crosslinked and preferably not linear.

[0232] The silicone foam suppressants herein preferably include polyethylene glycols and polyethylene glycol / polypropylene glycol copolymers having an average molecular weight of less than about 1,000, preferably about 100 - 800. The polyethylene glycols and polyethylene / polypropylene copolymers herein have a solubility in water of greater than about 2 wt%, preferably greater than about 5 wt% at room temperature.

[0233] The preferred solvents herein are polyethylene glycols having an average molecular weight of less than about 1,000, more preferably about 100 - 800, most preferably 200 - 400, and polyethylene glycol / polypropylene glycol, preferably the copolymer of PPG200 / PEG300. A weight ratio of polyethylene glycol: copolymer of polyethylene - polypropylene glycol of about 1:1 to 1:10, most preferably 1:3 to 1:6 is preferred.

[0234] The preferred silicone foam suppressants used herein do not contain polypropylene glycol having a molecular weight of 4,000 in particular. They also preferably do not contain block copolymers of ethylene oxide and propylene oxide such as PLURONIC® L101.

[0235] Other foam suppressants useful herein include secondary alcohols (e.g., 2-alkylalkanols) and mixtures of such alcohols with silicone oils. The secondary alcohols include C6-C 16 alkyl alcohols having a C1-C 16 chain. A preferred alcohol is 2-butyloctanol, which is available from Condea under the trade name ISOFOL® 12. Mixtures of secondary alcohols are available from Enichem under the trademark ISALCHEM® 123. The mixed foam suppressants typically contain a mixture of alcohol + silicone in a weight ratio of 1:5 to 5:1.

[0236] The compositions herein generally contain from 0% to about 5% of a foam suppressant. When used as a foam suppressant, aliphatic monocarboxylic acids and their salts are typically present in an amount up to about 5% by weight of the detergent composition. Preferably, about 0.5% to about 3% of an aliphatic monocarboxylate foam suppressant is utilized. Silicone foam suppressants are typically used in an amount up to about 2.0% by weight of the detergent composition, although higher amounts can be used. This upper limit is practically useful primarily due to concerns about minimizing cost and the effectiveness of a small amount for effectively controlling foaming. Preferably, about 0.01% to about 1%, more preferably about 0.25% to about 0.5% of a silicone foam suppressant is used. As used herein, these weight percent values include any silica that can be utilized in combination with the polyorganosiloxane, and any auxiliary materials that can be utilized. Monostearyl phosphate foam suppressants are generally utilized in an amount in the range of about 0.1% to about 2% by weight of the composition. Hydrocarbon foam suppressants are typically utilized in an amount in the range of about 0.01% to about 5.0%, although higher levels can be used. Alcohol foam suppressants are typically used at 0.2 - 3% by weight of the finished composition.

[0237] Metal ion sequestering agents and chelating agents The salts of polyphosphonic acids can be considered as sequestering agents or stabilizers for peroxide compounds and enzymes that are particularly sensitive to heavy metal ions. Here, for example, the sodium salts of 1-hydroxyethane-1,1-diphosphonate, diethylenetriaminepentamethylenephosphonate or ethylenediaminetetramethylenephosphonate are used in an amount of 0.1 to 5% by weight.

[0238] The detergent compositions herein can also optionally contain one or more iron and / or manganese chelating agents. Such chelating agents can be selected from the group consisting of aminocarboxylates, aminophosphonates, polyfunctional substituted aromatic chelating agents and mixtures thereof, as defined hereinafter. Without wishing to be bound by theory, the advantage of these materials is thought to be due in part to their exceptional ability to remove iron and manganese ions from the washing solution by forming soluble chelates. It is understood that some of the aforementioned detergent builders can function as chelating agents and that such detergent builders are present in sufficient amounts to provide both functions.

[0239] Aminocarboxylates useful as optional chelating agents include ethylenediaminetetraacetate, N-hydroxyethylethylenediaminetriacetate, nitrilotriacetate, ethylenediaminetetrapropionate, triethylenetetraminehexaacetate, diethylenetriaminepentaacetate and ethanol diglyceride, alkali metal, ammonium and substituted ammonium salts thereof and mixtures thereof.

[0240] Aminophosphonates are suitable for use as chelating agents in the compositions of the present invention when at least low concentrations of total phosphorus are tolerated in the detergent composition and include ethylenediaminetetrakis(methylenephosphonate) as DEQUEST. These aminophosphonates preferably do not contain an alkyl or alkenyl group having more than about 6 carbon atoms.

[0241] Multifunctional substituted aromatic chelating agents are also useful in the compositions herein. Preferred compounds of this type in acid form are dihydroxydisulfobenzene, such as 1,2-dihydroxy-3,5-disulfobenzene.

[0242] A preferred biodegradable chelating agent for use herein is ethylenediaminedisuccinate ("EDDS"), particularly the [S,S] isomer.

[0243] When utilized, these chelating agents generally constitute from about 0.1 wt% to about 10 wt% of the detergent compositions herein. More preferably, when utilized, the chelating agent constitutes from about 0.1 wt% to about 3.0 wt% of such compositions.

[0244] Clay soil removal / redeposition inhibitor The detergent compositions of the present invention can optionally contain a water-soluble ethoxylated amine having clay soil removal and redeposition inhibiting properties. Granular detergent compositions containing these compounds typically contain from about 0.01 wt% to about 10.0 wt% of the water-soluble ethoxylated amine; liquid detergent compositions typically contain from about 0.01% to about 5%.

[0245] The most preferred soil release and redeposition inhibitors are ethoxylated tetraethylenepentamine. Exemplary ethoxylated amines are further described in U.S. Patent No. 4,597,898. Another group of preferred clay soil removal-redeposition inhibitors are the cationic compounds disclosed in European Patent Application Publication No. 0111965A1, the ethoxylated amine polymers disclosed in European Patent Application Publication No. 0111984A1, the zwitterionic polymers disclosed in European Patent Application Publication No. 0112592A1, and the amine oxides disclosed in U.S. Patent No. 4,548,744. Another type of preferred redeposition inhibitor includes carboxymethylcellulose (CMC) materials. These materials are well known in the art.

[0246] Anti-graying agent The anti-grayness agent has a function of maintaining the dirt removed from the fibers suspended in the cleaning liquid, thereby preventing the dirt from redepositing. Water-soluble colloids mainly having organic properties, such as water-soluble salts of (co)polymeric carboxylic acids, pastes, gelatin, salts of ether carboxylic acids or ether carboxylic acids of starch or cellulose, or salts of ether carboxylic acids or ether sulfonic acids of starch or cellulose, or salts of acidic sulfuric esters of cellulose or starch, are suitable for this. Water-soluble acid group-containing polyamides are also suitable for this purpose. Also, soluble starch preparations, etc. can be used as the above starch products such as starch degradation products, aldehyde starches, etc. Polyvinylpyrrolidone can also be used. However, the use of cellulose ethers, such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and their mixtures, and polyvinylpyrrolidone is preferred, and these can be added, for example, in an amount of 0.1 to 5% by weight based on the composition.

[0247] Fluorescent brighteners and UV absorbers Any fluorescent brightener or other brightening agent or whitening agent known in the art can typically be incorporated into the detergent compositions herein at levels of about 0.05% to about 1.2% by weight. Commercially available fluorescent brighteners that may be useful in the present invention can be classified into subgroups, and these include, but are not necessarily limited to, stilbene derivatives, pyrazolines, coumarins, carboxylic acids, methylene cyanines, dibenzothiophene-5,5-dioxide, azoles, 5-membered and 6-membered heterocycles, and other miscellaneous agents.

[0248] Preferred brightening agents include the brightening agents of the PHORWHITE® series from Verona. Other brightening agents disclosed in this reference include: Tinopal® UNPA, Tinopal CBS and Tinopal 5 BM; available from Ciba-Geigy; Artic White® CC and Artic White CWD (available from Hilton-Davis); 2-(4-stryl-phenyl)-2H-naphthol[1,2-d]triazole; 4,4'-bis-(1,2,3-triazol-2-yl)-stilbene; 4,4'-bis(stryl)biphenyl; and aminocoumarin. Specific examples of these brightening agents include 4-methyl-7-diethyl-aminocoumarin; 1,2-bis(-benzimidazol-2-yl)ethylene; 1,3-diphenyl-furazoline; 2,5-bis(benzoxazol-2-yl)thiophene; 2-stryl-naphtho-[1,2-d]oxazole; and 2-(stilben-4-yl)-2H-naphtho-[1,2-d]triazole. Anionic brightening agents are preferred herein.

[0249] This composition may, for example, contain a derivative of diaminostilbene disulfonic acid or an alkali metal salt thereof as a fluorescent brightening agent. Suitable fluorescent brightening agents are, for example, 4,4'-bis-(2-anilino-4-morpholino-1,3,5-triazinyl-6-amino)stilbene-2,2'-di-sulfonic acid or compounds of similar structure containing a diethanolamino group, a methylamino group, an anilino group or a 2-methoxyethylamino group instead of the morpholino group. Alkaline metal salts of substituted diphenylstyryl type brightening agents, for example, 4,4'-bis(2-sulfostyryl)diphenyl, 4,4'-bis(4-chloro-3-sulfostyryl)diphenyl or 4-(4-chlorostyryl)-4'-(2-sulfostyryl)diphenyl may be present. Mixtures of the above-mentioned brightening agents may also be used.

[0250] Also, a UV absorber may be added. These are compounds having a distinct absorption capacity for ultraviolet rays that not only contribute as UV stabilizers but also improve the light stability of both the colorants and pigments of the fibers of the textile product and the skin of the wearer of the textile product by protecting against the UV rays passing through the fabric. Generally, efficient non-radiative deactivation compounds are derivatives of benzophenone substituted mainly with hydroxyl and / or alkoxy groups at the 2- and / or 4-positions. Substituted benzotriazoles, further phenyl-substituted acrylates (cinnamic acid derivatives) at the 3-position, acrylates optionally having a cyano group at the 2-position, salicylates, organic Ni complexes, and natural substances such as umbelliferone and endogenous urocanic acid are also suitable. In a preferred embodiment, the UV absorber absorbs UV-A and UV-B radiation as well as possible UV-C radiation and re-emits light having a blue wavelength, thereby further having a fluorescence whitening effect. Preferred UV absorbers include triazine derivatives such as hydroxyaryl-1,3,5-triazine, sulfonated 1,3,5-triazine, o-hydroxyphenyl-benzotriazole and 2-aryl-2H-benzotriazole, and bis(anilinotriazinyl-amino)stilbenedisulfonic acid and its derivatives. As the ultraviolet absorber, an ultraviolet absorbing pigment such as titanium dioxide can also be used.

[0251] 〔Anti-migration agent〕 The detergent composition of the present invention can also contain one or more materials effective for suppressing the movement of dyes from one fabric to another during the cleaning process. Generally, such anti-migration agents include polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese phthalocyanine, peroxidase, and mixtures thereof. When used, these agents typically constitute from about 0.01% to about 10% by weight, preferably from about 0.01% to about 5% by weight, more preferably from about 0.05% to about 2% by weight of the composition.

[0252] More specifically, the polyamine N-oxide polymers preferred for use herein are described in U.S. Patent No. 6,491,728, which is incorporated herein by reference.

[0253] Any polymer backbone can be used as long as the resulting amine oxide polymer is water-soluble and has anti-migration properties. Examples of suitable polymer backbones are polyvinyl, polyalkylene, polyester, polyether, polyamide, polyimide, polyacrylate and mixtures thereof. These polymers include random copolymers or block copolymers where one monomer type is an amine N-oxide and the other monomer type is an N-oxide. The amine N-oxide polymers typically have an amine to amine N-oxide ratio of from 10:1 to 1:1,000,000. However, the number of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerization or by an appropriate degree of N-oxidation. The polyamine oxides can be obtained at substantially any degree of polymerization. Typically, the average molecular weight is in the range of 500 to 1,000,000, more preferably 1,000 to 500,000; most preferably in the range of 5,000 to 100,000. This preferred class of materials can be referred to as "PVNO".

[0254] The most preferred polyamine N-oxide useful in the detergent compositions herein is poly(4-vinylpyridine-N-oxide) having an average molecular weight of about 50,000 and an amine to amine N-oxide ratio of about 1:4.

[0255] Copolymers of N-vinylpyrrolidone and N-vinylimidazole polymers (classified as "PVPVI") are also preferred for use herein. Preferably, PVPVI has an average molecular weight in the range of 5,000 to 1,000,000, more preferably 5,000 to 200,000, and most preferably 10,000 to 20,000. PVPVI copolymers typically have a molar ratio of N-vinylimidazole to N-vinylpyrrolidone of 1:1 to 0.2:1, more preferably 0.8:1 to 0.3:1, and most preferably 0.6:1 to 0.4:1. These copolymers can be linear or branched.

[0256] The compositions of the present invention can also use polyvinylpyrrolidone ("PVP") having an average molecular weight of about 5,000 to about 400,000, preferably about 5,000 to about 200,000, and more preferably about 5,000 to about 50,000. PVP is known to those skilled in the detergent art. Compositions containing PVP can also contain polyethylene glycol ("PEG") having an average molecular weight of about 500 to about 100,000, preferably about 1,000 to about 10,000. Preferably, the ratio of PEG to PVP on a ppm basis delivered in the cleaning solution is about 2:1 to about 50:1, more preferably about 3:1 to about 10:1.

[0257] The detergent compositions herein can also optionally contain about 0.005 wt% to 5 wt% of certain types of hydrophilic optical brighteners, which also provide an anti-migration effect. When used, the compositions herein preferably contain about 0.01 wt% to 1 wt% of such optical brighteners.

[0258] One preferred brightening agent is 4,4'-bis[(4-anilino-6-(N-2-bis-hydroxyethyl)-s-triazin-2-yl)amino]-2,2'-stilbenedisulfonic acid and the disodium salt. This particular brightening agent species is commercially available from Ciba-Geigy Corporation under the trade name Tinopal-UNPA-GX®. Tinopal-UNPA-GX is a preferred hydrophilic fluorescent brightening agent useful in the detergent compositions of the present specification.

[0259] Another preferred brightening agent is 4,4'-bis[(4-anilino-6-(N-2-hydroxyethyl-N-methylamino)-s-triazin-2-yl)amino]2,2'-stilbenedisulfonic acid disodium salt. This particular brightening agent species is commercially available from Ciba-Geigy Corporation under the trade name Tinopal 5BM-GX®.

[0260] Another preferred fluorescent brightening agent is 4,4'-bis[(4-anilino-6-morpholino-s-triazin-2-yl)amino]2,2'-stilbenedisulfonic acid, sodium salt. This particular brightening agent species is commercially available from Ciba Geigy Corporation under the trade name Tinopal AMS-GX®.

[0261] The specific fluorescent brightener species selected for use in the present invention provide the advantage of particularly effective anti-migration performance when used in combination with the selected polymeric anti-migration agents described above. Such a combination of a selected polymeric material (e.g., PVNO and / or PVPVI) and a selected fluorescent brightener (e.g., Tinopal UNPA-GX, Tinopal 5 BM-GX and / or Tinopal AMS-GX) provides significantly superior anti-migration in an aqueous cleaning solution compared to using either of these two detergent composition components alone. Without being bound by theory, it is believed that such brighteners act in this way because they have a high affinity for the fabric in the cleaning solution and thus adhere to these fabrics relatively rapidly. The extent to which a brightener adheres to the fabric in the cleaning solution can be defined by a parameter called the "exhaustion coefficient". The exhaustion coefficient is generally the ratio of a) the brightening material adhered to the fabric to b) the initial brightener concentration in the cleaning solution. Brighteners with a relatively high exhaustion coefficient are most suitable for preventing migration in the context of the present invention.

[0262] Of course, it is understood that other conventional fluorescent brightener type compounds can optionally be used in the present composition to provide the advantage of "brightness" of conventional fabrics rather than an actual anti-migration effect. Such use is conventional and well known in detergent formulations.

[0263] Thickening agent The composition can also include common thickening and anti-deposition compositions, as well as viscosity modifiers such as polyacrylates, polycarboxylic acids, polysaccharides and their derivatives, polyurethanes, polyvinylpyrrolidone, castor oil derivatives, polyamine derivatives such as quaternized and / or ethoxylated hexamethylenediamine and any mixtures of these. Preferred compositions have a viscosity of less than 10,000 mPa -1 s when measured with a Brookfield viscometer at a temperature of 20 °C and a shear rate of 50 min * .

[0264] Inorganic salts Further suitable components of the composition are water-soluble inorganic salts such as bicarbonates, carbonates, amorphous silicates or mixtures thereof; alkali carbonates and amorphous silicates, in particular sodium silicates with a molar ratio of Na2O:SiO2 of 1:1 to 1:4.5, preferably 1:2 to 1:3.5 are used. Preferred compositions contain alkali salts, builders and / or cobuilders, preferably sodium carbonate, zeolite, crystalline layered sodium silicate and / or trisodium citrate, in an amount of 0.5 to 70% by weight, preferably 0.5 to 50% by weight, in particular 0.5 to 30% by weight, based on the anhydrous substance.

[0265] Fragrances and colorants The composition can contain components typical of detergents and cleansing compositions, such as fragrances and / or colorants, where it is preferred that no or only negligible coloring is left on the fabric being washed. The preferred amount of the total amount of colorant added is less than 1% by weight, preferably less than 0.1% by weight, based on the composition. The composition can also contain white pigments such as, for example, TiO2.

[0266] Industrial applications Another object of the present invention relates to the use of the cyclopropyl derivatives of the present invention as fragrances.

[0267] Examples Example 1 Synthesis of 2-methyl-1-(2-methylcyclopropyl)butan-1-one (1:1 isomer) Cyclopropanation of 5-methylhept-2-en-4-one (via the Johnson–Corey–Chaykovsky reaction) according to a procedure known from the literature providing the title compound.

Chemical formula

[0268] Example 2 Two-step synthesis of 9-cyclopropylnonanal

Chemical formula

Chemical formula

[0269] Under an N2 atmosphere, a solution of trifluoroacetic acid (6.64 mL, 89.42 mmol) in DCM (45 mL) was slowly added to a suspension of Et2Zn (99.4 mL, 89.42 mmol) and DCM (90 mL) at 0 - 5 °C, and the same temperature was maintained for 30 minutes to allow the reaction to proceed. Subsequently, a solution of CH2I2 (7.21 mL, 89.42 mmol) in DCM (45 mL) was added, and the mixture was maintained for 30 minutes. Subsequently, a solution of alcohol (9 mL, 44.71 mmol) in DCM (45 mL) was added. The reaction was maintained at room temperature overnight (about 20 hours), quenched with saturated NH4Cl (200 mL), and the compound was extracted from the aqueous layer using cyclohexane (100 mL x 3). The combined organic layers were washed with saturated NaHCO3, water, and brine, dried over Na2SO4, filtered, and evaporated to obtain a crude product (10.6 g). Purification by classical column chromatography (cyclohexane:ethyl acetate) yielded the title compound as a colorless oil (6.54 g, 79%).

[0270] (2) Synthesis of 9 - cyclopropylnonanal

Chemical Structure

[0271] A solution of 9 - cyclopropylnonan - 1 - ol (6.54 g, 35.46 mmol) in DCM (40 mL) was added to a suspension of Dess - Martin periodinane (22.56 g, 53.19 mmol) in DCM (395 mL), and the reaction was allowed to proceed at room temperature overnight (about 20 hours). Et2O (400 mL) was added thereto, and the mixture was washed with 1 M NaOH (500 mL x 2), dried over Na2SO4, filtered, and evaporated to obtain a crude product (6.3 g). Purification by classical column chromatography (cyclohexane:diethyl ether) yielded the title compound as a colorless oil with a very strong odor (4.99 g, 77%). MS: 182, 135, 126, 111, 97, 81, 67, 55, 41, 29 11H NMR (400 MHz, C6D6) δ 9.34 (t, J = 1.7 Hz, 1H), 1.82 (td, J = 7.3, 1.7 Hz, 2H), 1.45 - 0.99 (m, 14H), 0.61 (dddt, J = 13.0, 8.2, 6.9, 3.4 Hz, 1H), 0.46 - 0.34 (m, 2H), 0.06 - 0.00 (m, 2H). 13 13C NMR (101 MHz, C6D6) δ 200.71, 43.91, 35.15, 30.06, 29.86, 29.72, 29.72, 29.41, 22.25, 11.32, 4.86, 4.86. Odor: Strong aldehyde, soapy, green, watery

Claims

1. The following formula (I): R １ -R ２ (I) [wherein, ・R １ is cyclopropyl or C １ -C ６ -alkylcyclopropyl group; ・R ２ is -CO-R ３ or -(CH ２ ) ｎ -R ４ represents a group; ・R ３ represents a linear or branched C １ -C ６ alkyl; ・R ４ represents -CH ２ OH or -CH=O; and - n represents an integer from 1 to 12] A cyclopropyl derivative satisfying the above formula.

2. R ２ represents -CO-R ３ wherein R ３ represents a linear or branched alkyl group having 3 or 4 carbon atoms, the cyclopropyl derivative according to claim 1.

3. R ２ represents -(CH ２ ) ｎ -R ４ , R ４ represents -CH=O, and n represents an integer from 8 to 10. The cyclopropyl derivative according to claim 1.

4. The following formula (II): 【Chemical 1】 The cyclopropyl derivative according to Claim 1, represented by the above formula.

5. The following formula (III) or (IV): [Chemical 2] The cyclopropyl derivative according to Claim 1, represented by the above formula, or a mixture thereof.

6. A method for obtaining a cyclopropyl derivative of the following formula (I) using the Johnson-Corey-Chaikovskii reaction: R １ -R ２ (I) [wherein, - R １ is cyclopropyl or C １ - C ６ - alkylcyclopropyl group; ・R ２ represents a -CO-R ３ group; and ・R ３ represents a linear or branched C １ -C ６ alkyl]] Satisfying the above formula, the method comprising subjecting to cyclopropanation in the presence of a sulfur ylide having the following formula (V): The following formula (V) CH ３ -CH=CH-R ２ (V) [wherein, R ２ has the same meaning as described above] Enone satisfying the condition is Me ３ S － Hal ＋ Structure [wherein Hal represents bromine, chlorine or iodine] A method of subjecting to cyclopropanation in the presence of a sulfur ylide having the above formula.

7. The method according to Claim 6, wherein the reaction is carried out in the presence of DMSO and sodium hydride.

8. A method for obtaining a cyclopropyl derivative of the following formula (I) using the Simmons-Smith reaction: R １ -R ２ (I) [wherein, ・R １ is cyclopropyl or C １ -C ６ -alkylcyclopropyl group; - R ２ represents a - (CH ２ ) ｎ - R ４ group; ・R ４ represents -CH ２ OH or -CH=O; and - n represents an integer from 1 to 12] Satisfying the above formula, the method comprising: (a) In a first step, subjecting to cyclopropanation in the presence of an organozinc carbenoid having the following formula (VI): CH ２ =CH-(CH ２ ) ｎ -CH ２ OH [wherein n has the same meaning as above] An ω-unsaturated fatty acid alcohol satisfying the condition is reacted with Hal-ZnCH ２ -Hal structure [wherein Hal represents bromine, chlorine or preferably iodine] And optionally (b) Subjecting the hydroxyl group of the reaction product obtained from step (i) to oxidation to form an aldehyde group.

9. Hal-ZnCH ２ -Hal structure [wherein Hal represents bromine, chlorine or iodine] The method according to Claim 8, wherein the reaction is carried out in the presence of an organozinc carbenoid having the above formula.

10. The method according to Claim 6 or Claim 8, wherein the reaction is carried out in dichloromethane or chloroform as a solvent.

11. (a) At least one cyclopropyl derivative satisfying formula (I) as a first fragrance, and (b) At least one second fragrance different from (a) A fragrance mixture comprising or consisting of the above components.

12. The mixture according to Claim 11, wherein the components (a) and (b) are present in a weight ratio of about 0.01:99.99 to 10:

90.

13. The mixture according to Claim 11, further comprising a solvent.

14. A cosmetic composition, personal care composition or detergent composition comprising the cyclopropyl derivative according to Claim 1 or the fragrance mixture according to Claim 11.

15. Use of the cyclopropyl derivative according to Claim 1 as a fragrance.

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