Aqueous composition

Abstract

[Problem] To configure an aqueous composition so as to be non-greasy while having suitable viscosity, and to have excellent makeup durability while correcting irregularities such as pores. [Solution] The aqueous composition includes (A) a crosslinked siloxane elastomer, (B) a lipophilic porous powder, and (C) an aqueous medium.

Description

[Technical field]

[0001] The present invention relates to an aqueous composition. [Background technology]

[0002] There has been a demand for cosmetics with a high unevenness correction effect that makes skin irregularities such as pores and fine wrinkles less noticeable and makes the skin look smoother. For example, Patent Document 1 describes a cosmetic composition that combines a crosslinked polysiloxane elastomer and light-scattering particles. This uses the crosslinked polysiloxane elastomer to form a film that covers the pores, making them appear flat.

[0003] Patent Document 2 describes that by using a silicone powder consisting of a crosslinked silicone-network silicone block copolymer in combination with a crosslinked polymethyl methacrylate (PMMA) powder in a silicone gel base, it is possible to produce an oil-based cosmetic that has an excellent unevenness correction effect that makes wrinkles, pores, etc. less noticeable, and also has a natural finish, a bare skin feel, and a high level of transparency. Furthermore, Patent Document 3 describes that a cosmetic composition containing an oil wax gel that contains silicone oil and wax causes diffuse reflection of light at wrinkled areas, even without using powder, and effectively fills in the wrinkled areas of the skin, making it possible to temporarily hide wrinkles.

[0004] On the other hand, compositions containing lipophilic porous powders are known as compositions that have the appearance and feel of skin care cosmetics, but can correct unevenness such as pores without using inorganic powders with high concealing power (e.g., Patent Documents 4 to 6). Cosmetics containing lipophilic porous powders have the advantage that the powder absorbs sebum secreted on the skin over time, suppressing the generation of a sticky feeling and maintaining a smooth feeling, and the spherical lipophilic porous powder has the effect of making unevenness on the skin less noticeable visually. [Prior art documents] [Patent documents]

[0005] [Patent Document 1] Special Publication No. 2007-510691 [Patent Document 2] JP 2005-41795 A [Patent Document 3] Special Publication No. 2019-510783 [Patent Document 4] International Publication No. 2017 / 073758 [Patent Document 5] International Publication No. 2018 / 198737 [Patent Document 6] JP 2017-165675 A DISCLOSURE OF THEINVENTION [Problem to be solved by the invention]

[0006] Incidentally, the compositions described in Patent Documents 4 to 6 preferably have a low viscosity if they are to have a similar feel to skin care cosmetics such as serums or milky lotions. On the other hand, there is a demand for high viscosity in the case of makeup cosmetics and the like. Generally, in order to increase the viscosity, a thickener is added or the amount is increased, but this tends to cause stickiness. If the feel after application is sticky, it is difficult to apply the composition evenly to the skin, the effect of correcting unevenness such as pores is reduced, and the makeup tends to last less. As a result of extensive research, the present inventors discovered that by using a combination of specific components, it is possible to reduce stickiness while at the same time synergistically improving viscosity, and thus completed the present invention.

[0007] That is, an object of the present invention is to provide an aqueous composition which has a suitable viscosity but is not sticky, corrects irregularities such as pores, and provides good cosmetic wear. [Means for solving the problem]

[0008] The aqueous composition of the present invention comprises (A) a crosslinked siloxane elastomer; (B) a lipophilic porous powder; (C) an aqueous medium; It includes.

[0009] (B) The lipophilic porous powder preferably contains cross-linked polymethyl methacrylate as a main material.

[0010] The aqueous composition of the present invention preferably further contains (D) a water-soluble thickener.

[0011] The aqueous composition of the present invention further comprises (E) a surfactant, and this surfactant is preferably a polyoxyethylene-polyoxyalkylene alkyl ether block polymer having an HLB value of 9 to 17 or a polyoxyethylene fatty acid glyceryl.

[0012] The aqueous composition of the present invention may further contain (F) a polar oil.

[0013] (F) The polar oil may be an ultraviolet light absorber.

[0014] The ratio of the lipophilic porous powder (B) to the aqueous medium (C) is preferably 0.1 or more.

[0015] The aqueous compositions of the present invention may be oil-in-water compositions. Effect of the Invention

[0016] The aqueous composition of the present invention comprises (A) a crosslinked siloxane elastomer; (B) a lipophilic porous powder; (C) an aqueous medium; Since the cosmetic composition contains the above component, it can correct unevenness such as pores, etc., while having a moderate viscosity, without being sticky, and can provide good makeup wear. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0017] The present invention will be described in detail below. The aqueous composition of the present invention comprises (A) a crosslinked siloxane elastomer; (B) a lipophilic porous powder; (C) an aqueous medium; It includes. Each component will be described in detail below. Each component may be simply referred to as component (A), component (B), etc. In addition, in this specification, PEG is an abbreviation for polyethylene glycol, PPG is an abbreviation for polypropylene glycol, EO is an abbreviation for ethylene oxide, PO is an abbreviation for propylene oxide, POE is an abbreviation for polyoxyethylene, POP is an abbreviation for polyoxypropylene, and VP is an abbreviation for vinylpyrrolidone.

[0018] (A) Crosslinked siloxane elastomer The crosslinked siloxane elastomer (A) incorporated in the aqueous composition of the present invention is a siloxane elastomer (silicone elastomer) in which polydimethylsiloxane is three-dimensionally crosslinked, and includes both emulsifying and non-emulsifying ones.

[0019] The emulsifiable crosslinked siloxane elastomer is not particularly limited, but may be crosslinked polyoxyethylene methylpolysiloxane, alkyl group-containing crosslinked polyoxyethylene methylpolysiloxane, crosslinked polyglycerin-modified silicone, alkyl group-containing crosslinked polyglycerin-modified silicone, etc. These emulsifiable crosslinked siloxane elastomers may be commercially available in the form of a swollen product swollen with various oils such as silicone oil, mineral oil, triethylhexanoin, squalane, etc. Specific examples include the following.

[0020] Examples of swollen polyoxyethylene methylpolysiloxane crosspolymers include KSG-210 ((PEG-10 / 15) / dimethicone crosspolymer, a mixture of dimethicone with 20-30% crosslinked product) (manufactured by Shin-Etsu Chemical Co., Ltd.), 9011 Silicone Elastomer Blend ((PEG-12 / dimethicone) crosspolymer, a mixture of cyclomethicone) (manufactured by Dow Corning Toray Co., Ltd.), and the like.

[0021] Examples of swollen alkyl group-containing polyoxyethylene methylpolysiloxane crosspolymers include KSG-310 (a mixture of (PEG-15 / lauryl dimethicone) crosspolymer and mineral oil, crosslinked product is 25-35%), KSG-320 (a mixture of (PEG-15 / lauryl dimethicone) crosspolymer and isododecane, crosslinked product is 20-30%), KSG-330 (a mixture of (PEG-15 / lauryl dimethicone) crosspolymer and triethylhexanoin, crosslinked product is 15-25%), and KSG-340 (a mixture of (PEG-15 / lauryl dimethicone) crosspolymer, (PEG-10 / lauryl dimethicone) crosspolymer and squalane, crosslinked product is 25-35%) (all manufactured by Shin-Etsu Chemical Co., Ltd.).

[0022] Examples of swollen polyglycerin-modified silicone crosspolymers include KSG-710 (dimethicone / polyglycerin-3 crosspolymer, a mixture of dimethicone with a crosslinking content of 20 to 30% (manufactured by Shin-Etsu Chemical Co., Ltd.)).

[0023] Examples of swollen alkyl group-containing polyglycerin-modified silicone crosspolymers include KSG-810 (a mixture of (lauryl dimethicone / polyglycerin 3) crosspolymer and mineral oil, with 25-35% crosslinked product), KSG-820 (a mixture of (lauryl dimethicone / polyglycerin 3) crosspolymer and isododecane, with 20-30% crosslinked product), KSG-830 (a mixture of (lauryl dimethicone / polyglycerin 3) crosspolymer and triethylhexanoin, with 15-25% crosslinked product), and KSG-840 (a mixture of (lauryl dimethicone / polyglycerin 3) crosspolymer and squalane, with 25-35% crosslinked product) (all manufactured by Shin-Etsu Chemical Co., Ltd.).

[0024] The non-emulsifying crosslinked siloxane elastomer is not particularly limited, but includes methyl polysiloxane crosspolymer, methylphenyl polysiloxane crosspolymer, vinyl dimethicone / lauryl dimethicone crosspolymer, lauryl polydimethylsiloxyethyl dimethicone / bis-vinyl dimethicone crosspolymer, alkyl (C30-45) cetearyl dimethicone crosspolymer, cetearyl dimethicone crosspolymer, etc. These non-emulsifying crosslinked siloxane elastomers can be commercially available in the form of a swollen product swollen with various oils such as silicone oil, mineral oil, triethylhexanoin, and squalane. Specific examples include the following.

[0025] The swelling products of methylpolysiloxane crosspolymer are 9040 silicone elastomer blend (mixture of dimethicone crosspolymer and cyclopentasiloxane, crosslinked 12%), 9041 silicone elastomer blend (mixture of dimethicone crosspolymer and dimethicone 5 mPa·s, crosslinked 16%), 9045 silicone elastomer blend (mixture of dimethicone crosspolymer and cyclopentasiloxane, crosslinked 12.5%), EL-8040ID silicone organic blend (mixture of dimethicone crosspolymer and isododecane, crosslinked 18%) (above) and Dow Corning Toray Co., Ltd.) and swollen dimethicone / vinyl dimethicone crosspolymers such as KSG-15 (dimethicone / vinyl dimethicone crosspolymer, a mixture of cyclopentasiloxane, 4-10% crosslinked), KSG-16 (dimethicone / vinyl dimethicone crosspolymer, a mixture of dimethicone 6 mPa s, 20-30% crosslinked), and KSG-1610 (dimethicone / vinyl dimethicone crosspolymer, a mixture of methyl trimethicone, 15-20% crosslinked) (all manufactured by Shin-Etsu Chemical Co., Ltd.).

[0026] Examples of swollen methylphenylpolysiloxane crosspolymers include KSG-18A (a mixture of (dimethicone / phenylvinyldimethicone) crosspolymer and diphenylsiloxyphenyltrimethicone, with a crosslinked content of 10 to 20%) (manufactured by Shin-Etsu Chemical Co., Ltd.).

[0027] Examples of swollen vinyl dimethicone / lauryl dimethicone crosspolymers include KSG-41A (a mixture of vinyl dimethicone / lauryl dimethicone crosspolymer and mineral oil, crosslinked product is 20-30%), KSG-42A (a mixture of vinyl dimethicone / lauryl dimethicone crosspolymer and isododecane, crosslinked product is 15-25%), KSG-43 (a mixture of vinyl dimethicone / lauryl dimethicone crosspolymer and triethylhexanoin, crosslinked product is 25-35%), and KSG-44 (a mixture of vinyl dimethicone / lauryl dimethicone crosspolymer and squalane, crosslinked product is 25-35%) (all manufactured by Shin-Etsu Chemical Co., Ltd.).

[0028] Examples of swollen lauryl polydimethylsiloxyethyl dimethicone / bis-vinyl dimethicone crosspolymer include KSG-042Z (a mixture of (lauryl polydimethylsiloxyethyl dimethicone / bis-vinyl dimethicone) crosspolymer, isododecane; crosslinked product is approximately 20%) and KSG-045Z (a mixture of (lauryl polydimethylsiloxyethyl dimethicone / bis-vinyl dimethicone) crosspolymer, cyclopentasiloxane; crosslinked product is approximately 20%) (both manufactured by Shin-Etsu Chemical Co., Ltd.).

[0029] Examples of swollen alkyl (C30-45) cetearyl dimethicone crosspolymer include VELVESIL 125 (a mixture of alkyl (C30-45) cetearyl dimethicone crosspolymer and cyclopentasiloxane; crosslinked content is approximately 12.5%) and VELVESIL 034 (a mixture of alkyl (C30-45) cetearyl dimethicone crosspolymer and caprylyl methicone; crosslinked content is approximately 16%) (both manufactured by Momentive Performance Materials).

[0030] Examples of swollen cetearyl dimethicone crosspolymers include VELVESIL DM (cetearyl dimethicone crosspolymer, a mixture of dimethicone 5 mPa·s with approximately 17% crosslinked) (manufactured by Momentive Performance Materials).

[0031] The blending amount of the (A) component is preferably 0.01 to 20 mass% based on the total amount of the aqueous composition, more preferably 0.01 to 10 mass%, furthermore 0.1 to 8 mass%, and most preferably 0.5 to 8 mass%. By blending the (A) component in an amount of 0.01 mass% or more, the viscosity can be improved synergistically by combining with the (B) component described below. Furthermore, by blending the (A) component in an amount of 20 mass% or less, the stickiness can be further reduced.

[0032] The component (A) can be one or a combination of two or more selected from the above-mentioned emulsifying crosslinked siloxane elastomers and non-emulsifying crosslinked siloxane elastomers.

[0033] (B) Lipophilic porous powder Examples of lipophilic porous powders to be blended in the aqueous composition of the present invention include crosslinked polymethyl methacrylate and nylon porous powder. These powders may contain other components, such as silica, in an amount of several mass % or less. It is more preferable that the lipophilic porous powder is mainly made of crosslinked polymethyl methacrylate, and the main material means that it may contain other components, such as silica, in an amount of several mass % or less, as described above. In addition, it is preferable that the lipophilic porous powder is spherical. When the powder is spherical, the average particle size is not particularly limited, but is preferably 0.1 to 100 μm, preferably 0.5 to 50 μm, and more preferably about 1 to 20 μm.

[0034] Either a material that is itself lipophilic, or a material that is hydrophilic and coated with a lipophilic substance, such as hydrophobized silica, can be used. In the case of coating, it is preferable that the inside of the pores is also lipophilized.

[0035] The maximum oil absorption capacity of the lipophilic porous powder is preferably 100% by mass or more relative to the powder. This is because the maximum oil absorption capacity is closely related to the porous volume, and the porous form affects the light diffusion. When the maximum oil absorption capacity is 100% by mass or more, the light diffusion effect is sufficient, and a sufficient pore correction effect can be obtained.

[0036] The amount of the lipophilic porous powder is preferably 0.5 to 30% by mass, more preferably 0.5 to 20% by mass, based on the total amount of the composition. When the amount is 0.5% by mass or more, the viscosity can be more appropriately improved, and the pore correction effect and the smooth feeling sustaining effect can be more effectively obtained, while when the amount is 30% by mass or less, good dispersibility of the powder can be ensured.

[0037] (C) Aqueous medium The aqueous medium in the present invention is a medium containing water as a main component, and may be water alone or may contain a lower alcohol and / or a polyhydric alcohol. The term "main component" means that the water content in the aqueous medium is 50% by mass or more.

[0038] The water in the present invention may be ion-exchanged water, purified water, or tap water. Examples of the lower alcohol include ethanol, propanol, and isopropanol. Examples of polyhydric alcohols include dihydric alcohols such as ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, and 2,3-butylene glycol, and trihydric alcohols such as glycerin.

[0039] The proportion of lower alcohols and polyhydric alcohols in the aqueous medium is preferably 30% by mass or less, and more preferably 25% by mass or less.

[0040] The blending amount of the (C) aqueous medium in the present invention is preferably 10 to 80% by mass based on the total amount of the composition. When the blending amount is 10% by mass or more, the dispersibility of the (B) component in the composition can be improved, and when the blending amount is 80% by mass or less, the cosmetic lasting power can be improved.

[0041] The ratio of the lipophilic porous powder (B) to the aqueous medium (C) is preferably 0.01 or more, more preferably in the range of 0.01-2, and even more preferably in the range of 0.1-1. 0.01 By satisfying the above, the viscosity can be further improved.

[0042] (D) Water-soluble thickener The aqueous composition of the present invention can have a high viscosity due to the components (A) and (B), but may further contain a water-soluble thickener (D) to improve dispersibility. As the water-soluble thickener (D), any thickener that can be generally used in cosmetics can be used.

[0043] Examples of water-soluble thickeners include plant-based polymers such as gum arabic, tragacanth, galactan, carob gum, guar gum, karaya gum, carrageenan, xanthan gum, pectin, agar, quince seed, and algae colloid (brown algae extract); microbial polymers such as dextran, succinoglucan, and pullulan; animal polymers such as collagen, casein, albumin, and gelatin; and starch-based polymers such as starch (rice, corn, potato, and wheat), carboxymethyl starch, and methylhydroxypropyl starch.

[0044] Other examples include cellulose-based polymers such as methyl cellulose, nitrocellulose, ethyl cellulose, methylhydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, and cellulose powder; and alginic acid-based polymers such as sodium alginate and propylene glycol alginate.

[0045] Further examples include vinyl polymers such as polyvinyl methyl ether and carboxyvinyl polymers, polyoxyethylene polymers, polyoxyethylene polyoxypropylene copolymer polymers, acrylic polymers such as polyethyl acrylate and polyacrylamide, polyethyleneimine, cationic polymers, bentonite, magnesium aluminum silicate, laponite, hectorite, inorganic water-soluble polymers such as silicic anhydride, PEG-240 / decyltetradeceth-20 / hexamethylene diisocyanate copolymers, (dimethylacrylamide / Na acryloyldimethyltaurate) crosspolymers, (Na acrylate / acryloyldimethyltaurate) copolymers, (alkyl acrylate / steareth-20 methacrylate) copolymers, (ammonium acryloyldimethyltaurate / VP) copolymers, and the like.

[0046] The blending amount of the water-soluble thickener (D) is preferably 0.005 to 2% by mass based on the total amount of the composition. By blending the component (D) in an amount of 0.005% by mass or more, dispersibility and dispersion stability can be improved. In addition, by blending the component (D) in an amount of 2% by mass or less, stickiness can be suppressed.

[0047] (E) Surfactant When a surfactant is blended with the aqueous composition of the present invention (for example, when the aqueous composition is made into an oil-in-water type), it is preferable to use a polyoxyethylene-polyoxyalkylene alkyl ether block polymer or a polyoxyethylene fatty acid glyceryl having an HLB value of 9 to 17, from the viewpoint of low adsorption to component (B) and high contribution to emulsification; in other words, emulsion stability can be ensured even with a small amount of surfactant.

[0048] HLB is calculated by the Kawakami formula, which is expressed by the following formula 1 (where MW represents the molecular weight of the hydrophilic group, and MO represents the molecular weight of the lipophilic group). Additivity is recognized in HLB values, and when two or more nonionic surfactants are used in combination, the overall HLB value is expressed as the weighted average of the HLB values ​​of each individual surfactant.

[0049]

number

[0050] (Polyoxyethylene-polyoxyalkylene alkyl ether block polymer with HLB value of 9-17) An example of the polyoxyethylene-polyoxyalkylene alkyl ether block polymer is the polyoxyethylene-polyoxyalkylene alkyl ether block polymer represented by the following general formula (1).

[0051] RO-(PO) m -(EO) n -H (1)

[0052] In the general formula (1), R1 is a hydrocarbon group having 16 to 18 carbon atoms, and is preferably a saturated or unsaturated aliphatic hydrocarbon group, such as palmityl, stearyl, isostearyl, oleyl, and linolyl. PO is an oxypropylene group, and EO is an oxyethylene group. In general formula (1), PO and EO must be bonded in a block configuration. If they are bonded randomly, sufficient formulation stability cannot be obtained. There is no particular restriction on the order in which propylene oxide and ethylene oxide are added. In addition, the block configuration includes not only two-stage blocks, but also three or more stages. m and n respectively represent the average number of moles of PO and EO added, and are 70>m>4, 70>n>10, and n>m.

[0053] The molecular weight of the block polymer of general formula (1) is preferably 800 or more, more preferably 1500 or more. If the molecular weight is less than 800, the effect is low. Although the upper limit of the molecular weight cannot be particularly specified, a sticky feeling tends to occur as the molecular weight increases. Examples of the block polymer represented by the general formula (1) include "Nikkol PBC44" (HLB=12.5), "Nikkol PBC33" (HLB=10.5), and "Nikkol PBC34" (HLB=16.5), all manufactured by Nikko Chemicals Co., Ltd.

[0054] (Polyoxyethylene fatty acid glyceryl with HLB value of 9 to 17) Examples of polyoxyethylene fatty acid glyceryl include POE glyceryl monoisostearate (8E.O.) (=PEG-8 glyceryl monoisostearate) ["EMALEX GWIS-108" manufactured by Nippon Emulsion Co., Ltd., HLB=10], POE (20) glyceryl monoisostearate (=PEG-20 glyceryl monoisostearate) ["EMALEX GWIS-120" manufactured by Nippon Emulsion Co., Ltd., HLB=13], and POE (7) coconut oil fatty acid glyceryl (=PEG-7 glyceryl coconut oil fatty acid) ["Cetiol HE" manufactured by Cognis Japan Co., Ltd., HLB=13].

[0055] The blending amount of the component (E) is preferably 0.01 to 5 mass % based on the total amount of the composition, and more preferably 0.5 to 3 mass %. E By making the blending amount of the ) component 0.01% by mass or more and 5% by mass or less, better emulsion stability can be ensured.

[0056] (F) Polar oil The aqueous composition of the present invention may contain a polar oil component (F). By incorporating the surfactant of the component (E) above, the emulsion stability can be further improved even when a polar oil component is incorporated.

[0057] The IOB value of the polar oil is not particularly limited, but is preferably 0.05 to 0.80. The IOB value is an abbreviation for Inorganic / Organic Balance, which is a value that represents the ratio of inorganic values ​​to organic values, and is an index that indicates the degree of polarity of an organic compound. IOB value = inorganic value / organic value Here, for each of the "inorganic value" and "organic value", for example, the "organic value" for one carbon atom in a molecule is 20, and the "inorganic value" for one hydroxyl group in the molecule is 100, the "inorganic value" and "organic value" are set according to various atoms or functional groups, and the IOB value of an organic compound can be calculated by integrating the "inorganic value" and "organic value" of all atoms and functional groups in the organic compound (see, for example, Fujita, "Chemical Region", Vol. 11, No. 10, pp. 719-725, 1957).

[0058] Representative examples of polar oils include ester oils and ultraviolet absorbents. Specific examples of ester oils include tripropylene glycol dineopentanoate, isononyl isononanoate, isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, cetyl ethylhexanoate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, tetra-2- Pentaerythrityl ethylhexanoate, triethylhexanoin (tri-2-ethylhexanoic acid glycerin), trioctanoic acid glycerin, triisopalmitic acid glycerin, triisostearate trimethylolpropane, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, trimyristate glycerin, tri-2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceryl amide, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, and triethyl citrate.

[0059] The ultraviolet absorbent may be a wide variety of oil-based ultraviolet absorbents with high polarity that are generally used in cosmetics, and is not particularly limited. For example, benzoic acid derivatives, salicylic acid derivatives, cinnamic acid derivatives, dibenzoylmethane derivatives, β,β-diphenylacrylate derivatives, benzophenone derivatives, benzylidene camphor derivatives, phenylbenzimidazole derivatives, triazine derivatives, phenylbenzotriazole derivatives, anthranil derivatives, imidazoline derivatives, benzalmalonate derivatives, 4,4-diarylbutadiene derivatives, etc. are exemplified below. Specific examples and trade names are listed below, but are not limited thereto.

[0060] Examples of benzoic acid derivatives include ethyl para-aminobenzoate (PABA), ethyl-dihydroxypropyl PABA, ethylhexyl-dimethyl PABA (e.g., "Escarol 507"; ISP), glyceryl PABA, PEG-25-PABA (e.g., "Uvinal P25"; BASF), and diethylaminohydroxybenzoylhexylbenzoate (e.g., "Uvinal A Plus"), etc.

[0061] Examples of salicylic acid derivatives include homosalate (e.g., "Eusolex HMS"; Rona / EM Industries), ethylhexyl salicylate (e.g., "NeoHeliopan OS"; Herman & Reimer), dipropylene glycol salicylate (e.g., "Dipsal"; Skel), and TEA salicylate (e.g., "NeoHeliopan TS"; Herman & Reimer).

[0062] Examples of cinnamic acid derivatives include octyl methoxycinnamate or ethylhexyl methoxycinnamate (e.g., Parsol MCX; Hoffmann-La Roche), isopropyl methoxycinnamate, isoamyl methoxycinnamate (e.g., Neo-Heliopan E1000; Herman & Reimer), cinnoxate, DEA methoxycinnamate, diisopropyl methylcinnamate, glyceryl-ethylhexanoate-dimethoxycinnamate, and di-(2-ethylhexyl)-4'-methoxybenzalmalonate. Examples of dibenzoylmethane derivatives include 4-tert-butyl-4'-methoxydibenzoylmethane (eg, Parsol 1789).

[0063] An example of a β,β-diphenylacrylate derivative is octocrylene (eg, "Uvinal N539"; BASF). Examples of benzophenone derivatives include benzophenone-1 (e.g., "Uvinal 400"; BASF), benzophenone-2 (e.g., "Uvinal D50"; BASF), benzophenone-3 or oxybenzone (e.g., "Uvinal M40"; BASF), benzophenone-4 (e.g., "Uvinal MS40"; BASF), benzophenone-5, benzophenone-6 (e.g., "Helisorb 11"; Norquay), benzophenone-8 (e.g., "Spectra-Sorb UV-24"; American Cyanamid), benzophenone-9 (e.g., "Uvinal DS-49"; BASF), and benzophenone-12.

[0064] Examples of benzylidene camphor derivatives include 3-benzylidene camphor (e.g., "Mexoryl SD"; Symex), 4-methylbenzylidene camphor, benzylidene camphorsulfonic acid (e.g., "Mexoryl SL"; Symex), benzalkonium camphor methosulfate (e.g., "Mexoryl SO"; Symex), terephthalide discamphorsulfonic acid (e.g., "Mexoryl SX"; Symex), and polyacrylamide methyl benzylidene camphor (e.g., "Mexoryl SW"; Symex). Examples of phenylbenzimidazole derivatives include phenylbenzimidazole sulfonic acid (eg, "Eutholex 232"; Merck), and disodium phenyldibenzimidazole tetrasulfonate (eg, "Neo-Heliopan AP"; Herman & Reimer).

[0065] Examples of triazine derivatives include anisotriazine (e.g., "Tinosorb S"; Ciba Specialty Chemicals), ethylhexyl triazone (e.g., "Uvinal T150"; BASF), diethylhexylbutamidotriazone (e.g., "Uvasorb HEB"; Sigma 3V), and 2,4,6-tris(diisobutyl-4'-aminobenzalmalonate)-s-triazine. Examples of phenylbenzotriazole derivatives include drometrizole trisiloxane (eg, "Silatrizole"; Rhodia-Chemie), methylene bis(benzotriazolyl tetramethylbutylphenol) (eg, "Tinosorb M"; Ciba Specialty Chemicals), and the like. Examples of anthranil derivatives include menthyl anthranilate (eg, "Neo Heliopan MA"; Herman & Reimer). The imidazoline derivatives include ethylhexyldimethoxybenzylidene dioxoimidazoline propionate. Examples of benzalmalonate derivatives include polyorganosiloxanes having benzalmalonate functional groups (for example, polysilicone-15; "Parsol SLX"; DSM Nutrition Japan). An example of a 4,4-diarylbutadiene derivative is 1,1-dicarboxy(2,2'-dimethylpropyl)-4,4-diphenylbutadiene.

[0066] The amount of the polar oil (F) can be adjusted appropriately depending on the properties and purpose, but in the case of an oil-in-water type, it is preferably 1 to 40 mass%, more preferably 1 to 30 mass%, and more preferably 5 to 25 mass% based on the total amount of the aqueous composition. The amount of the ultraviolet absorber contained in the polar oil (F) is preferably 40 mass% or more, preferably 50 mass% or more, more preferably 60 mass% or more of the polar oil, and all of the polar oil may be an ultraviolet absorber. By making the polar oil (F) 1 mass% or more, whitening due to the porous powder can be further prevented, and by making it 40 mass% or less, stickiness can be further suppressed.

[0067] In addition to the above-mentioned components, the aqueous composition of the present invention may contain one or more of the following components that are commonly used in cosmetics and quasi-drugs, such as moisturizers, powder components (excluding component (A)), liquid oils and fats, solid oils and fats, waxes, hydrocarbon oils, higher alcohols, surfactants (excluding component (E)), thickeners (excluding component (D)), sugars, etc. Examples of the components that can be added are given below.

[0068] Examples of moisturizing agents include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, sodium lactate, bile salts, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO)PO adduct, Rosa rugosa extract, Achillea millefolium extract, and Melilot extract.

[0069] Examples of powder components other than component (A) include inorganic powders (e.g., talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, red mica, black mica, vermiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, tungstate metal salts, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (calcined gypsum), calcium phosphate, fluorapatite, hydroxyapatite, Ceramic powder, metal soap (e.g., zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc.); organic powder (e.g., polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, etc.); inorganic white pigment (e.g., zinc oxide, etc.); inorganic red pigment (e.g., iron titanate, etc.); inorganic purple pigment (e.g., mango violet, cobalt violet, etc.); inorganic green pigment (e.g., chromium oxide, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigment (e.g., ultramarine, Prussian blue, etc.); pearl pigment (e.g., titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, etc.); metal powder pigment (e.g., aluminum powder, copper powder, etc.); organic pigment such as zirconium, barium or aluminum lake ( For example, organic pigments such as Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 228, Red No. 405, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401, and Blue No. 404; Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3, and Blue No. 1; natural pigments (e.g., chlorophyll, β-carotene, etc.), and the like. However, when inorganic powder with a high refractive index (such as a refractive index of 2 or more) is blended, its amount is preferably 5% by mass or less, and more preferably 1% by mass or less, in the composition.

[0070] Examples of liquid oils and fats include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil, perilla oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, Chinese tung oil, Japanese tung oil, jojoba oil, germ oil, and triglycerin.

[0071] Examples of solid fats and oils include cacao butter, coconut oil, horse tallow, hardened coconut oil, palm oil, beef tallow, mutton tallow, hardened beef tallow, palm kernel oil, lard, beef bone fat, Japan Rice Kernel Oil, hardened oil, beef foot fat, Japan Rice, and hardened castor oil.

[0072] Examples of waxes include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ivory wax, whale wax, montan wax, bran wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugarcane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, and POE hydrogenated lanolin alcohol ether.

[0073] Examples of the hydrocarbon oil include liquid paraffin, ozokerite, pristane, paraffin, ceresin, squalene, petrolatum, and microcrystalline wax.

[0074] Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, tallic acid, isostearic acid, linoleic acid, linoleic acid, eicosapentaenoic acid (EPA), and docosahexaenoic acid (DHA).

[0075] Examples of higher alcohols include straight-chain alcohols (e.g., lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, etc.); branched-chain alcohols (e.g., monostearyl glycerin ether (batyl alcohol), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, octyldodecanol, etc.); and the like.

[0076] Furthermore, the aqueous composition of the present invention may contain various surfactants other than the component (E) as emulsifiers. Examples of anionic surfactants include fatty acid soaps (e.g., sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (e.g., sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates (e.g., POE-lauryl triethanolamine sulfate, sodium POE-lauryl sulfate, etc.); N-acylsarcosinates (e.g., sodium lauroyl sarcosinate, etc.); higher fatty acid amide sulfonates (e.g., sodium N-myristoyl-N-methyl taurine, sodium coconut oil fatty acid methyl tauride, sodium lauryl methyl tauride, etc.); phosphates (sodium POE-oleyl ether phosphate, sodium POE-stearyl ether phosphate, etc.); sulfosuccinates (e.g., sodium di-2-ethylhexyl sulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol ... sodium succinate, etc.); alkylbenzene sulfonates (e.g., sodium linear dodecylbenzene sulfonate, triethanolamine linear dodecylbenzene sulfonate, linear dodecylbenzene sulfonic acid, etc.); higher fatty acid ester sulfate salts (e.g., sodium hydrogenated coconut oil fatty acid glycerin sulfate, etc.); N-acyl glutamates (e.g., monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, monosodium N-myristoyl-L-glutamate, etc.); sulfated oils (e.g., turmeric oil, etc.); POE-alkyl ether carboxylic acids; POE-alkyl allyl ether carboxylates; α-olefin sulfonates; higher fatty acid ester sulfonates; secondary alcohol sulfate salts; higher fatty acid alkylolamide sulfate salts; sodium lauroyl monoethanolamide succinate; ditriethanolamine N-palmitoyl aspartate; sodium caseinate, etc.

[0077] Examples of cationic surfactants include alkyltrimethylammonium salts (e.g., stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (e.g., cetylpyridinium chloride, etc.); distearyldimethylammonium chloride, dialkyldimethylammonium salts; poly(N,N'-dimethyl-3,5-methylenepiperidinium chloride); alkyl quaternary ammonium salts; alkyldimethylbenzylammonium salts; alkylisoquinolinium salts; dialkylmorphonium salts; POE-alkylamines; alkylamine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride, etc.

[0078] Examples of amphoteric surfactants include imidazoline-based amphoteric surfactants (e.g., 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, etc.); betaine-based surfactants (e.g., 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryl dimethylaminoacetic acid betaine, alkyl betaine, amido betaine, sulfobetaine, etc.).

[0079] Examples of lipophilic nonionic surfactants include sorbitan fatty acid esters (e.g., sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexyl acid, diglycerol sorbitan tetra-2-ethylhexyl acid, etc.); glycerin polyglycerin fatty acids (e.g., glycerin monocottonseed oil fatty acid, glycerin monoerucate, glycerin sesquioleate, glycerin monostearate, α,α'-oleic acid pyroglutamic acid, glycerin monostearate malic acid, etc.); propylene glycol fatty acid esters (e.g., propylene glycol monostearate, etc.); hydrogenated castor oil derivatives; and glycerin alkyl ethers.

[0080] Examples of hydrophilic nonionic surfactants include POE-sorbitan fatty acid esters (e.g., POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate, etc.); POE sorbit fatty acid esters (e.g., POE-sorbitan monolaurate, POE-sorbitan monooleate, POE-sorbitan pentaoleate, POE-sorbitan monostearate, etc.); POE-glycerin fatty acid esters (e.g., POE-glycerin monostearate, POE-monooleates such as POE-glycerol monoisostearate, POE-glycerol triisostearate, etc.; POE-fatty acid esters (e.g., POE-distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (e.g., POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic types (e.g., Pluronic POE·POP-alkyl ethers (e.g., POE·POP-cetyl ether, POE·POP-2-decyltetradecyl ether, POE·POP-monobutyl ether, POE·POP-hydrogenated lanolin, POE·POP-glycerin ether, etc.); tetraPOE·tetraPOP-ethylenediamine condensates (e.g., Tetronic, etc.); POE-castor oil hydrogenated castor oil derivatives (e.g., POE-castor oil, POE-hydrogenated castor oil, POE-hydrogenated castor oil monoisostearate, POE-hydrogenated castor oil tri ... E-hydrogenated castor oil monopyroglutamic acid monoisostearate diester, POE-hydrogenated castor oil maleic acid, etc.); POE-beeswax and lanolin derivatives (e.g., POE-sorbitol beeswax, etc.); alkanolamides (e.g., coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid esters; POE-alkylamines; POE-fatty acid amides; sucrose fatty acid esters; alkylethoxydimethylamine oxide; trioleyl phosphate, etc.

[0081] A thickener other than component (D) may be blended as a thickener, such as dextrin, sodium pectinate, sodium alginate, dialkyldimethylammonium cellulose sulfate, aluminum magnesium silicate, bentonite, hectorite, AlMg silicate (Veegum), laponite, and anhydrous silicic acid.

[0082] Examples of monosaccharides include trioses (e.g., D-glyceryl aldehyde, dihydroxyacetone, etc.); tetraoses (e.g., D-erythrose, D-erythrulose, D-threose, etc.); pentoses (e.g., L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc.); hexoses (e.g., D-glucose, D-talose, D-busicose, D-galactose, D-fructose, L-galactose, L-mannoside, etc.); heptose, D-tagatose, etc.); heptose (e.g., aldoheptose, heptose, etc.); octose (e.g., octose, etc.); deoxy sugars (e.g., 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, etc.); amino sugars (e.g., D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.); uronic acids (e.g., D-glucuronic acid, D-mannuronic acid, L-guluronic acid, D-galacturonic acid, L-iduronic acid, etc.), etc.

[0083] Examples of oligosaccharides include sucrose, gunthianose, umbelliferose, lactose, planteose, isolichinoses, α,α-trehalose, raffinose, lychinoses, umbilicin, stachyose, verbascoses, and the like.

[0084] Examples of the amino acid include neutral amino acids (e.g., threonine, cysteine, etc.), basic amino acids (e.g., hydroxylysine, etc.), etc. Examples of the amino acid derivatives include sodium acyl sarcosine (sodium lauroyl sarcosine), acyl glutamate, sodium acyl β-alanine, glutathione, pyrrolidone carboxylic acid, etc.

[0085] Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol.

[0086] Examples of alkylene oxide derivatives include POE(9)POP(2) dimethyl ether, POE(14)POP(7) dimethyl ether, POE(10)POP(10) dimethyl ether, POE(6)POP(14) dimethyl ether, POE(15)POP(5) dimethyl ether, POE(25)POP(25) dimethyl ether, POE(7)POP(12) dimethyl ether, POE(22)POP(40) dimethyl ether, and POE(35)POP(40) dimethyl. POE(50)POP(40) dimethyl ether, POE(55)POP(30) dimethyl ether, POE(30)POP(34) dimethyl ether, POE(25)POP(30) dimethyl ether, POE(27)POP(14) dimethyl ether, POE(55)POP(28) dimethyl ether, POE(36)POP(41) dimethyl ether, POE(7)POP(12) dimethyl ether, POE(17)POP(4) dimethyl ether, and the like.

[0087] Examples of sequestering agents include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, tetrasodium edetate, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, and trisodium ethylenediaminehydroxyethyltriacetate.

[0088] Examples of the antioxidant aid include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, cephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.

[0089] Other possible ingredients include preservatives (ethylparaben, butylparaben, etc.); skin whitening agents (e.g., placenta extract, saxifrage extract, arbutin, etc.); blood circulation promoters (nicotinic acid, benzyl nicotinate, tocopherol nicotinate, β-butoxy nicotinate ester, minoxidil or its analogues, γ-oryzanol, alkoxycarbonylpyridine N-oxide, carpronium chloride, and acetylcholine or its derivatives, etc.); various extracts (e.g., cinnamoyl glyceryl ester, acetylcholine, acetylcholine derivatives, etc.); Examples of effective active ingredients include ginger, angelica tree, coptis rhizome, lithospermum root, birch, loquat, carrot, aloe, mallow, iris, grape, loofah, lily, saffron, cnidium, angelica, hypericum, ononis, garlic, chili pepper, tangerine, angelica tree, peony, seaweed, etc.), activators (e.g., panthenyl ethyl ether, nicotinamide, biotin, pantothenic acid, royal jelly, cholesterol derivatives, etc.); antiseborrheic agents (e.g., pyridoxines, thianthol, etc.), etc.

[0090] The viscosity of the aqueous composition of the present invention varies depending on the form of the composition, but it is preferable that the viscosity is in the range of 10,000 to 100,000 mPa·s at 25° C. When the viscosity of the composition is 10,000 mPa·s or more, the formulation can be kept more stable. 100000 A viscosity of not more than mPa·s enables the composition to be applied evenly to the skin, etc.

[0091] The form of the aqueous composition of the present invention is not particularly limited, and the composition can be widely applied in any form that is conventionally used in cosmetics, such as basic cosmetics such as lotion, milky lotion, cream, facial cleanser, gel, essence (beauty serum), and packs, makeup cosmetics such as lipstick, eye shadow, eyeliner, mascara, foundation, and sunscreen, oral cosmetics, fragrance cosmetics, hair cosmetics, and body cosmetics. EXAMPLES

[0092] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples. In the following examples, the blend amounts are expressed in mass % unless otherwise specified. Aqueous compositions were prepared in the usual manner according to the formulations shown in Tables 1 and 2 below, and were evaluated according to the following criteria.

[0093] (viscosity) The viscosity of the composition was measured at 30°C using a BL type viscometer (VS-A type, manufactured by Shibaura Systems) at 12 rpm for 1 minute using a rotor No. 3 when the viscosity was less than 10,000 mPa s, or a rotor No. 4 when the viscosity was 10,000 mPa s or more.

[0094] (dispersibility) The prepared aqueous composition was placed in a 50 ml sample tube (diameter 3 cm) and rotated at 45 rpm at 25° C. for 4 hours to perform a rolling test. The degree of powder agglomeration was observed with the naked eye and evaluated according to the following criteria. A: No flocculation or precipitation B: Some flocculation or precipitation C: Aggregation or precipitation occurs

[0095] (Makeup retention) The prepared aqueous compositions were used by 10 expert panelists, who evaluated the cosmetic staying power of the compositions according to the following criteria: <Evaluation score> 5 points: very good 4 points: Good 3 points: normal 2 points: Defective 1 point: Very poor <Evaluation criteria> A: Average score is 4.5 or higher B: Average score is between 3.5 and 4.5 points C: Average score is between 2.5 and 3.5 points D: Average score is less than 2.5 points

[0096] The formulations and evaluation results are shown in Tables 1 and 2. Details of the main formulations (commercially available products) shown in the tables are as follows. Methyl methacrylate crosspolymer (porous): Techpolymer MBP-8HP (manufactured by Sekisui Plastics Co., Ltd.) Methyl methacrylate crosspolymer (non-porous): Ganzpearl GMX-0810 (manufactured by Aica Kogyo Co., Ltd.) Hydrophobic silica: Porous silica beads SA-SB-705 (Miyoshi Chemicals Co., Ltd.) (Vinyl dimethicone / methicone silsesquioxane) crosspolymer: Silicone powder KSP102 (Shin-Etsu Chemical Co., Ltd.) Cornstarch: Starch C Silica: Sunsphere L-51S (AGC Si-Tech) Dimethicone / Dimethicone Crosspolymer: Elastomer Blend DC9041 (Dimethicone Crosspolymer content (16% pure), manufactured by Dow Corning Toray Co., Ltd.) (Acryloyldimethyltaurate ammonium / VP) copolymer: Aristoflex AVC (Clariant Japan) (Acrylates / alkyl acrylate (C10-30)) crosspolymer: PEMULEN TR-2 (manufactured by Lubrizol Advanced Materials, Inc.) Polysorbate 20: Nikkol TL-10 (manufactured by Nikko Chemicals)

[0097] [Table 1]

[0098] [Table 2]

[0099] As shown in Table 1, the aqueous compositions of Examples 1 to 4 had significantly higher viscosities than Comparative Examples 1 to 4 in which the type of powder was changed, and were excellent in both cosmetic staying power and dispersibility. Examples 5 to 7 in Table 2 are obtained by changing the amount of component (B) in Example 1, but the viscosity of Example 7, which has the lowest content, was significantly higher than that of Comparative Example 5, which does not contain component (B), and Comparative Example 6, which does not contain component (A). Furthermore, the viscosity was significantly higher in Examples 1 and 5, in which the ratio of crosslinked siloxane elastomer to the aqueous medium was 0.1 or more.

[0100] Next, oil-in-water compositions were prepared in a conventional manner according to the formulations shown in Table 3 below, and were evaluated according to the following criteria.

[0101] (stability) The oil-in-water composition thus prepared was stored in a 50 ml glass bottle at room temperature, and the condition of the sample after 4 months was visually confirmed. A: No separation is observed B: A slightly transparent layer is visible. C: A transparent layer is visible in more than one-tenth of the total area.

[0102] The formulations and evaluation results are shown in Table 3. The details of the main formulations (commercially available products) shown in Table 3 are as follows. PEG-60 glyceryl isostearate: Emalex GWIS-160N (manufactured by Nippon Emulsion Co., Ltd.) PEG-20 glyceryl isostearate: Emalex GWIS-120 (manufactured by Nippon Emulsion Co., Ltd.) PPG-8 Ceteth-20: Nikkor PBC-44 (manufactured by Nikko Chemicals) PPG-4 Ceteth-10: Nikkor PBC-33 (manufactured by Nikko Chemicals) PPG-4 Ceteth-20: Nikkor PBC-34 (manufactured by Nikko Chemicals)

[0103] [Table 3]

[0104] As shown in Table 3, when (F) an ultraviolet absorber that is a polar oil was contained, the stability was good in Examples 8 to 13 in which the surfactant was a polyoxyethylene-polyoxyalkylene alkyl ether block polymer or a polyoxyethylene fatty acid glyceryl having an HLB value of 9 to 17. On the other hand, in the case of a surfactant having an HLB value outside the range, a satisfactory level of stability was not obtained.

[0105] Formulation examples of the aqueous composition are shown below. Formulation example 1: Oil-in-water base Raw material name (mass%) water residue Glycerin 2 Dipropylene glycol 8 (Acryloyldimethyltaurate ammonium / VP) copolymer 0.5 Ammonium acryloyldimethyltaurate / beheneth-25 methacrylate crosspolymer 0.5 Methyl methacrylate crosspolymer 5 Polysorbate 20 2 PEG-10 Dimethicone 1 Dimethicone Crosspolymer 5 PPG-8 Ceteth-20 0.5 PEG-60 hydrogenated castor oil 0.1 PEG-20 Glyceryl Isostearate 1 PPG-17 1 Isostearic acid 0.2 Ethylhexyl methoxycinnamate 7.5 Ethylhexyl Salicylate 5 t-Butyl methoxydibenzoylmethane 2.5 Octocrylene 3 Dimethicone 28 Iron oxide 0.01 Sulfate Ba 1 Glycylglycine 2 Sodium metaphosphate 0.1 Phenoxyethanol 0.5 Methylparaben 0.15 Ethylparaben 0.1

Claims

1. An oil-in-water aqueous composition comprising: (A) a crosslinked siloxane elastomer; (B) a lipophilic porous powder; (C) an aqueous medium; Including, The composition further comprises (E) a surfactant, the surfactant being a polyoxyethylene-polyoxyalkylene alkyl ether block polymer or a polyoxyethylene fatty acid glyceryl having an HLB value of 9 to 17; The blending amount of the (A) component is 0.01 to 20% by mass based on the total amount of the aqueous composition, and The blending amount of the (B) component is 0.5 to 30 mass% based on the total amount of the aqueous composition. Aqueous composition.

2. 2. The aqueous composition according to claim 1, wherein the lipophilic porous powder (B) is mainly made of crosslinked polymethyl methacrylate.

3. 3. The aqueous composition according to claim 1, further comprising (D) a water-soluble thickener.

4. The aqueous composition according to any one of claims 1 to 3, further comprising (F) a polar oil component.

5. The aqueous composition according to claim 4, wherein the polar oil component (F) is an ultraviolet absorber.

6. 6. The aqueous composition according to claim 1, wherein the ratio of the lipophilic porous powder (B) to the aqueous medium (C) is 0.01 or more.

7. 7. The aqueous composition according to claim 6, wherein the ratio of said lipophilic porous powder (B) to said aqueous medium (C) is 0.1 or more.

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