Lubricating compositions for fuel efficient motorcycle applications

Abstract

To provide a lubricant composition configured for a motorcycle, and a method for achieving improved fuel economy by lubricating an engine, a transmission, and clutch assembly of the motorcycle generally, using a single lubricant composition provided from a common sump or reservoir.SOLUTION: A lubricant composition having a viscosity grade selected from 0W-20, 0W-16, 0W-12, or 0W-8 comprises: (a) at least one base oil of lubricating viscosity; (b) a non-dispersant poly(meth)acrylate copolymer viscosity modifier having a weight average molecular weight of about 500,000 or less; and optionally, (c) molybdenum dialkyldithiocarbamate. The lubricant composition has a high temperature high shear (HTHS) viscosity at 150°C of at least 2.9 cP and a clutch friction rating of MA, MA1, MA2, or MB.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present disclosure relates to lubricating compositions, particularly lubricating compositions suitable for motorcycle applications. [Background technology]

[0002] In motorcycles, a common fluid provides lubrication to the engine and driveline components, including the transmission and / or wet clutch. As such, lubricating compositions used in motorcycle engines are formulated to have a balance of both frictional properties suitable for the driveline and lubricating properties suitable for the engine. This is in contrast to lubricants for other vehicles, such as passenger cars, where the engine or crankcase is lubricated by one type of lubricant and the driveline is lubricated with a second type of lubricant. This dual-purpose fluid in motorcycle applications poses formulation challenges, since it is often desirable to reduce viscosity and friction in the engine crankcase to improve fuel economy, but on the other hand, it is important to maintain sufficient friction in the transmission and / or clutch assembly for proper operation. As such, lubricants formulated for passenger car applications are generally not suitable for motorcycle applications, since passenger car fluids may exhibit, among other characteristics, a coefficient of friction that is too low to lubricate most motorcycle transmission and / or clutch components.

[0003] Given the unique challenges associated with motorcycle lubricants, the industry has developed standards to adequately evaluate the quality and performance of lubricants for motorcycle applications. In particular, JASO T 903:2016 defines performance requirements for motorcycle lubricants, requiring, among other criteria, certain high temperature high shear viscosity minimums (HTHS) to meet friction and / or wear requirements for transmission and / or clutch assemblies in motorcycles. Traditionally, HTHS requirements for motorcycle lubricants have tended to limit viscosity grades suitable for such applications to lubricants with viscosity grades of 10W-30 and above. It has not heretofore been possible to formulate lower viscosity motorcycle lubricants that achieve passing HTHS and wet clutch performance requirements. Summary of the Invention

[0004] In one approach or embodiment, the disclosure relates to a method for improving fuel economy of a motorcycle using a lubricating oil composition. The method includes lubricating an engine crankcase and a transmission, including a wet clutch, of the motorcycle with the lubricating oil composition from a common sump. The lubricating composition has a viscosity grade selected from 0W-20, 0W-16, 0W-12, or 0W-8 and includes (a) at least one base oil of lubricating viscosity, (b) a non-dispersant poly(meth)acrylate copolymer viscosity modifier having a weight average molecular weight of about 500,000 or less, and, optionally, (c) a molybdenum dialkyldithiocarbamate. The lubricating composition has a high temperature, high shear (HTHS) viscosity at 150°C of at least 2.9 cP, as measured in accordance with JASO T 903:2016, and a clutch friction rating of MA, MA1, MA2, or MB, and the fuel economy of a motorcycle, as measured in accordance with the WMTC cycle, is improved by at least 1 percent better than when measured using the WMTC cycle, when the motorcycle is lubricated with the higher viscosity grade 10W-30 lubricant.

[0005] In other embodiments, the method of the preceding paragraph may also include embodiments having any combination of optional features or steps. The optional features, steps, or embodiments may include one or more of the following: cSt less than about 6 to about 9 cSt and / or the lubricating composition has a viscosity index of about 250 to about 350, and / or the non-dispersant poly(meth)acrylate copolymer has a KV100 of up to about 700. Has a weight average molecular weight Monomer ester moiety In The non-dispersant poly(meth)acrylate copolymer has polymerized monomer units including at least (meth)acrylate monomer units having a hydrocarbyl group, and optionally includes (meth)acrylate monomer units having a hydrocarbyl group in the monomer ester portion of about 6,000 to about 8,000, has a weight average molecular weight of about 200,000 to about 500,000, has a polydispersity index of about 1.5 to about 2.5, and has a molecular weight of about 500 to about 700. Weight average molecular weight Monomer ester moiety In and / or the lubricating composition comprises from about 10 to about 20 weight percent of a poly(meth)acrylate copolymer, and / or the lubricating composition is devoid of molybdenum dialkyldithiocarbamate, and / or the lubricating composition has less than about 800 ppm molybdenum provided by a molybdenum dialkyldithiocarbamate, and / or the motorcycle has a 150 cm 3 It has the following engine capacities:

[0006] In another embodiment, the disclosure also describes a method of lubricating a crankcase and wet clutch of a motorcycle, the method comprising lubricating an engine crankcase and a transmission, including a wet clutch of the motorcycle, with a lubricating oil composition from a common sump, the lubricating composition having: (i) a viscosity grade selected from 0W-20, 0W-16, 0W-12, or 0W-8; (ii) from about 5 to about 20 weight percent of a polymeric viscosity modifier selected from an ethylene-propylene olefin copolymer and / or a non-dispersant poly(meth)acrylate copolymer having a weight average molecular weight of from about 20,000 to about 500,000; and (iii) optionally, up to about 800 ppm of molybdenum provided from a molybdenum dialkyldithiocarbamate friction modifier. In the approach, the lubricating composition (i) exhibits a clutch friction rating of MA, MA1, MA2, or MB, as measured in accordance with JASO T 903:2016, and (ii) exhibits a high temperature high shear (HTHS) viscosity at 150° C. in accordance with JASO T 903:2016 that is within about 20 percent of the HTHS viscosity of a 10W-30 lubricant, such that a motorcycle lubricated with the lubricating composition has a fuel economy measured in accordance with the WMTC cycle that is at least 1 percent better than the fuel economy measured on the motorcycle when lubricated with the higher viscosity grade 10W-30 lubricant.

[0007] In other embodiments, the method of the preceding paragraph may further include embodiments having any combination of optional features or steps. The optional features, steps, or embodiments may include one or more of the following: the lubricating composition has a high temperature high shear (HTHS) viscosity at 150° C. of at least 2.9 cP, as measured according to JASO T 903:2016, and / or the lubricating composition has a viscosity index of from about 160 to about 350, and / or the polymeric viscosity modifier has, as polymerized monomer units, a viscosity index of at least about 500 to about 700. Weight average molecular weight Monomer ester moiety Inand / or the polymeric viscosity modifier has a weight average molecular weight of about 200,000 to about 300,000, and / or the lubricating composition is a non-dispersant poly(meth)acrylate copolymer having a (meth)acrylate monomer unit having a hydrocarbyl group, and optionally a (meth)acrylate monomer unit having a hydrocarbyl group in the monomer ester portion of about 6,000 to about 8,000. cSt and / or the motorcycle has a viscosity of less than 150 cm 3 It has the following engine capacities:

[0008] In yet another embodiment, motorcycle lubricating compositions effective for lubricating both engine crankcases and transmissions including wet clutches are described herein. In an approach, the motorcycle lubricating compositions further comprise at least one base oil of lubricating viscosity having a viscosity grade selected from 0W-20, 0W-16, 0W-12, or 0W-8, a non-dispersant poly(meth)acrylate copolymer viscosity modifier having a weight average molecular weight of about 20,000 to about 450,000 and, optionally, having, as polymerized monomer units, (meth)acrylate monomer units having up to about 700 hydrocarbyl groups in the monomer ester portion, a viscosity index of about 250 to about 350, and up to about 800 ppm molybdenum provided from a molybdenum dialkyldithiocarbamate, wherein the lubricating composition meets the JASO T and a clutch friction rating of MA, MA1, MA2, or MB, when measured in accordance with US 903:2016, and a motorcycle lubricated with the lubricating composition exhibits fuel economy, measured in accordance with the WMTC cycle, that is at least 1 percent better than the fuel economy measured on the motorcycle when lubricated with a higher viscosity grade 10W-30 lubricant.

[0009] In other embodiments, the motorcycle lubricating composition of the preceding paragraph may further include embodiments having any combination of optional features or components. The optional features, components, or embodiments may include one or more of the following: cStless than about 6 to about 9 cSt and / or the lubricating composition comprises from about 10 to about 20 weight percent of a non-dispersant poly(meth)acrylate copolymer, and / or the lubricating composition is devoid of a molybdenum dialkyldithiocarbamate friction modifier, and / or the lubricating composition comprises from about 10 ppm to about 800 ppm of molybdenum provided from a molybdenum dialkyldithiocarbamate, and / or the motorcycle has a KV100 of 150 cm 3 It has the following engine capacities: DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0010] The present disclosure relates to lubricating compositions configured for motorcycles and generally to a method of lubricating the engine, transmission, and clutch assembly of a motorcycle with a single lubricating composition provided from a common sump or reservoir. As mentioned in the background, lubricants for motorcycles are required to do more than simply lubricate the engine crankcase. Motorcycle lubricants also lubricate the driveline components, including the transmission and clutch. Because of this, the testing and requirements for the fluids are quite different than typical lubricants for passenger car motor oils.

[0011] In particular, high temperature high shear viscosity (HTHS) and wet clutch performance are unique requirements for motorcycle lubricants. Tables 1 and 2 below provide an overview of motorcycle oil standards set by JASO T903:2016. As shown in Table 1, the minimum value of HTHS viscosity of 2.9 cP was determined with consideration of transmission and clutch protection performance, and as mentioned in the background art, this minimum value tends to preliminarily limit the viscosity grade of motorcycle engine oils to 10W-30 or higher. Attempts to achieve such high temperature viscosity have been problematic when reducing the fluid viscosity of motorcycle lubricants.

[0012] [Table 1] a For viscosity see SAE J300. b The test is conducted under standard test conditions (30 cycles) using the diesel injector method.

[0013] [Table 2]

[0014] Developing a low viscosity motorcycle lubricating composition that also achieves HTHS and wet clutch performance has the additional benefit of improved fuel economy. Unexpectedly, the lubricating compositions herein with lower viscosity grades of 0W-20, 0W-16, 0W-12, or 0W-8 achieve the HTHS and wet clutch performance levels of the higher viscosity 10W-30 lubricants. Such lubricating compositions also achieve at least 1 percent or more, at least 1.2 percent or more, at least 1.4 percent or more, at least 1.6 percent or more, or at least 1.8 percent or more (or any range therebetween) higher fuel economy (compared to the 10W-30 baseline lubricant) without affecting the specific performance requirements of motorcycle engine oils, such as transmission protection and clutch performance.

[0015] In one approach or embodiment, a method for improving fuel economy in motorcycles (such as motorcycles having engine capacities of 150cc or less) comprises using a lower viscosity, particularly a grease having a viscosity of about 10 cSt Less than or equal to 6 to 9 cStand a selected lubricating oil composition configured to also achieve the required transmission protection and clutch performance at a KV100 of 0.01 to 0.100. In one embodiment, the method includes lubricating an engine crankcase and a transmission including a motorcycle wet clutch with the lubricating oil composition from a common sump. The lubricating composition has a viscosity grade selected from 0W-20, 0W-16, 0W-12, or 0W-8 and includes (a) at least one base oil of lubricating viscosity, (b) a polymeric viscosity modifier selected from either an ethylene-propylene olefin copolymer or a non-dispersant poly(meth)acrylate copolymer having a weight average molecular weight of about 500,000 or less, and optionally (c) a molybdenum dialkyldithiocarbamate. In one approach, the method and its lubricating compositions exhibit a high temperature, high shear (HTHS) viscosity at 150° C. of at least 2.9 cP and a clutch friction rating of MA, MA1, MA2, or MB, as measured according to JASO T 903:2016. In another approach, the method and its lubricating compositions exhibit an HTHS viscosity at 150° C. within + / - 20 percent of the HTHS viscosity of a 10W-30 lubricant (in other approaches, an HTHS viscosity within about 15 percent, within less than about 14 percent, or within about 12 percent of the HTHS viscosity of a 10W-30 lubricant). Even with such low viscosity grades and passing friction and clutch properties, the measured fuel economy of a motorcycle when lubricated with a fluid herein is improved by at least about 1 percent (alternatively at least 1.2 percent or more, at least 1.4 percent or more, at least 1.6 percent or more, or at least 1.8 percent or more (or any range therebetween)) over the fuel economy of a motorcycle lubricated with a higher viscosity grade 10W-30 lubricant as measured according to the World Motorcycle Test Cycle (WMTC). Such methods and lubricant compositions are particularly suitable for Class 1 motorcycles under the WMTC having engine capacities of 150 cc or less, or in other embodiments, from about 80 to about 130 cc, or from about 100 to about 130 cc.

[0016] The motorcycle lubricating compositions herein include selected polymeric viscosity modifiers that exhibit higher viscosity indexes and unexpectedly achieve acceptable HTHS viscosity and wet clutch performance in low viscosity lubricants that achieve improved fuel economy compared to higher viscosity 10W-30 lubricants. Suitable polymeric viscosity modifiers may include ethylene-propylene olefin copolymers, non-dispersant poly(meth)acrylate copolymers, or combinations thereof, when the specific properties of the viscosity modifier are met. The lubricating compositions herein may have a higher than normal viscosity index for motorcycle lubricants of about 160 to about 350 with the selected polymeric additives of the present disclosure. Each suitable polymeric additive will be further described below.

[0017] Poly(meth)acrylate copolymer In one aspect, the motorcycle lubricants herein include a selected poly(meth)acrylate copolymer. In some approaches, the selected poly(meth)acrylate copolymer is configured to achieve a higher viscosity index of the lubricants herein compared to conventional motorcycle lubricants, and in other approaches, the selected poly(meth)acrylate copolymer may also have a specific molecular weight and / or specific pendant side group or arm that may be a blend of one or more distinct molecular weight pendant arms, such as low molecular weight, medium molecular weight, and / or high molecular weight pendant hydrocarbyl groups in the ester portion of the (meth)acrylate monomer units forming the copolymer. In embodiments, the lubricants herein may include up to about 20 weight percent poly(meth)acrylate copolymer, and in other approaches, about 3 to about 18 weight percent, or about 4 to about 16 weight percent. Polymer treat rates are provided on a liquid (diluted with base oil) basis unless otherwise indicated. In one exemplary approach, the poly(meth)acrylate copolymer may have the structure of Formula I below, where z is an integer sufficient to achieve a weight average molecular weight of from about 20,000 to about 1,500,000 (in other approaches, from about 100,000 to about 500,000, or from about 200,000 to about 450,000, or from about 200,000 to about 300,000), where R is hydrogen when the monomer unit is an acrylate or a methyl group when the monomer unit is a methacrylate, and R' is a linear or branched hydrocarbyl group sized to achieve an arm molecular weight as described herein.

[0018] [ka]

[0019] Lubricants comprising the poly(meth)acrylate copolymers herein may have a viscosity index (as determined by ASTM D2270) of from about 250 to about 350, preferably from about 270 to about 320, or more preferably from about 280 to about 310. The poly(meth)acrylate copolymers described herein may have different (meth)acrylate monomer units randomly spaced throughout the polymer, as described below.

[0020] Suitable monomers or reactants for forming the copolymers for the unique motorcycle fluids herein include at least one selected from (1) (meth)acrylate monomers having a low to medium weight average molecular weight hydrocarbyl group in the ester portion of up to about 700, or preferably from about 100 to about 700 or from about 400 to about 700, and, optionally, (2) (meth)acrylate monomers having a high weight average molecular weight hydrocarbyl group in the ester portion of the monomer of from about 6,000 to about 10,000 or from about 6,000 to about 8,000, and, optionally, a blend of at least two different (meth)acrylate monomers or reactants. As used herein, "(meth)acrylate" refers to both methacrylate and / or acrylate monomers or monomer units (or mixtures). Also, as used herein, the molecular weight of the hydrocarbyl group of the ester in the monomer includes the hydrocarbyl chain as well as the ester oxygen, but does not include the carbonyl group.

[0021] Typically, the formed or resulting poly(meth)acrylate copolymer has an amount of monomers effective to achieve a total copolymer number average molecular weight of about 20,000 or more, in some cases about 250,000 or less, or about 200,000 or less, such as about 140,000 to about 240,000 or about 140,000 to about 200,000. The poly(meth)acrylate copolymer may also have a polydispersity index (Mw / Mn) of about 2.8 or less, or about 2.6 or less, and in other approaches, in the range of about 1.8 to about 2.6. In still other approaches, the copolymers herein may have two differently sized pendant arms, in such circumstances having a molecular weight ratio between the higher molecular weight arm and the lower molecular weight arm of about 10:1 to about 50:1, in other approaches about 11:1 to about 30:1, and in still other approaches about 12:1 to about 25:1. In other cases, the copolymers herein have a molecular weight ratio between the higher and lower molecular weight arms of about 1.5:1 to about 25:1, and in other approaches, about 1.5:1 to about 16:1.

[0022] In an approach or embodiment, the poly(meth)acrylate copolymers herein comprise the reaction product in the form of a linear, random copolymer of selected amounts of pendant low to medium and / or (optionally) high molecular weight hydrocarbyl (meth)acrylate monomers. These monomers and monomer units are further described below and contain both linear and / or branched hydrocarbyl groups on the respective ester chains, forming in some embodiments comb copolymers having at least one, and optionally at least two, distinct molecular weight pendant arms.

[0023] In an embodiment or approach, the low molecular weight hydrocarbyl (meth)acrylate units or monomers are derived from alkyl (meth)acrylates having linear or branched hydrocarbyl groups in the ester portion, preferably linear or branched alkyl groups in the ester portion having a total carbon chain length of the monomer ester portion (including any branching) of 6 to 20 carbons and preferably 12 to 16 carbons. An exemplary low molecular weight hydrocarbyl (meth)acrylate monomer may be lauryl (meth)acrylate, which may include a blend of (meth)acrylate monomers or monomer units having alkyl chain lengths in the range of C12 to C16, specifically alkyl chains of 12, 14, and 16 carbons, of which C12 alkyl (meth)acrylates are in the majority in the blend. In another embodiment or approach, the low or medium molecular weight hydrocarbyl (meth)acrylate units are derived from hydrocarbyl (meth)acrylate monomers having hydrocarbyl groups or total hydrocarbyl ester length (including any branching) and have a weight average molecular weight of at least about 500 up to about 700. These molecular weight chains can be derived from macromonomers of olefins or polymeric alcohols, optionally esterified with (meth)acrylic acid. The macromonomers may be derived from alkenes or alkadienes, including ethylene, propylene, butene, butadiene, isoprene, or combinations thereof, and have a molecular weight of about 700 or less, such as about 500 to about 700.

[0024] In yet another embodiment or approach, the optional high molecular weight hydrocarbyl (meth)acrylate units, or monomers, are derived from hydrocarbyl (meth)acrylate monomers having hydrocarbyl groups or total hydrocarbyl ester lengths (including any branching) having a weight average molecular weight of at least about 6,000 and up to about 10,000, or from about 6,000 to about 8,000. These high molecular weight chains can be derived from macromonomers of polymeric alcohols esterified with (meth)acrylic acid. The macromonomers can be derived from alkenes or alkadienes, including ethylene, propylene, butene, butadiene, isoprene, or combinations thereof, and have a molecular weight of about 10,000 or less, or about 8,000 or less, such as about 500 to about 10,000, or from about 6,000 to about 8,000.

[0025] In optional embodiments, the poly(meth)acrylate copolymers herein may also include other optional monomers and monomer units, including, for example, hydroxyalkyl (meth)acrylates and / or various dispersant monomers and monomer units. The poly(meth)acrylate copolymers herein may also be optionally functionalized with one or more dispersant monomers or monomer units, however, it is preferred that the poly(meth)acrylate copolymers are non-dispersant polymers and thus do not include or are devoid of dispersant moieties as referred to herein.

[0026] In one optional approach, the dispersant monomer or monomer unit may be a nitrogen-containing monomer or unit thereof. Such monomers, when used, may impart dispersant functionality to the polymer. In some approaches, the nitrogen-containing monomer may be a (meth)acrylic monomer, such as a methacrylate, methacrylamide, or the like. In some approaches, the attachment of the nitrogen-containing moiety to the acrylic moiety may be through a nitrogen atom or alternatively an oxygen atom, in which case the nitrogen of the monomer will be located elsewhere in the monomer. The nitrogen-containing monomer may be other than a (meth)acrylic monomer, such as a vinyl-substituted nitrogen heterocyclic monomer and a vinyl-substituted amine. Nitrogen-containing monomers include, for example, those in U.S. Pat. No. 6,331,603. Other suitable dispersant monomers include, but are not limited to, dialkylaminoalkyl acrylates, dialkylaminoalkyl (meth)acrylates, dialkylaminoalkyl acrylamides, dialkylaminoalkyl methacrylamides, N-tertiary alkyl acrylamides, and N-tertiary alkyl methacrylamides, where the alkyl or aminoalkyl groups may independently contain 1 to 8 carbon atoms. For example, the dispersant monomer may be dimethylaminoethyl (meth)acrylate. The nitrogen-containing monomer may be, for example, t-butylacrylamide, dimethylaminopropyl (meth)acrylamide, dimethylaminoethyl methacrylamide, N-vinylpyrrolidone, N-vinylimidazole, or N-vinylcaprolactam. It may also be (meth)acrylamides based on any of the aromatic amines disclosed in WO2005 / 087821, including 4-phenylazoaniline, 4-aminodiphenylamine, 2-aminobenzimidazole, 3-nitroaniline, 4-(4-nitrophenylazo)aniline, N-(4-amino-5-methoxy-2-methyl-phenyl)-benzamide, N-(4-amino-2,5-dimethoxy-phenyl)-benzamide, N-(4-amino-2,5-diethoxy-phenyl)-benzamide, N-(4-amino-phenyl)-benzamide, 4-amino-2-hydroxy-benzoic acid.

[0027] The (meth)acrylate copolymers of the present disclosure are typically synthesized to have a number average molecular weight of about 20,000 or more, and in other approaches, about 250,000 or less, or about 200,000 or less. Suitable ranges of number average molecular weight include about 140,000 to about 250,000, and in other approaches, about 150,000 to about 200,000. Such copolymers herein typically have a polydispersity index in the range of about 1 to about 4, and in other approaches, about 1.2 to about 3.5, and in yet other approaches, about 1.5 to about 3, and in yet other approaches, about 1.6 to about 2.5.

[0028] The (meth)acrylate copolymers may be prepared by any suitable conventional or controlled free radical polymerization technique. Examples include conventional free radical polymerization (FRP), reversible addition-fragmentation chain transfer (RAFT), atom transfer radial polymerization (ATRP), and other controlled types of polymerization known in the art. Polymerization procedures are known to those skilled in the art and include, for example, the use of common polymerization initiators (such as Vazo™ 67 (2.2′-azobis(2-methylbutyronitrile)), chain transfer agents (such as dodecyl mercaptan) when using conventional FRP, or RAFT agents (such as 4-cyano-4-[(dodecylsulfanylthiocarbonyl)sulfanyl]pentanoic acid) when using RAFT polymerization. Other initiators, chain transfer agents, RAFT agents, ATRP catalysts, and initiator systems can be used as known in the art, depending on the polymerization method selected, as needed for a particular application.

[0029] Olefin Copolymer In another embodiment, the polymeric viscosity modifiers for motorcycle lubricants herein comprise ethylene and one or more C 3 ~C 10 It may be an olefin copolymer derived from an alpha olefin. 3 ~C 10 Alpha olefins include, for example, C 3 Or C 4It may be an alpha olefin. Preferably, copolymers of ethylene and propylene or ethylene and butylene may be used. In embodiments, the lubricants herein may contain up to about 15 weight percent, or in other approaches, about 3 to about 14 weight percent of the olefin copolymer, in other approaches, about 4 to about 12 weight percent, or about 6 to about 10 weight percent. Polymer treat rates are provided on a liquid (diluted with base oil) basis unless otherwise indicated. In one exemplary approach, the olefin copolymer may have the structure of Formula II below, where m and n are integers sufficient to achieve a weight average molecular weight of about 20,000 to about 250,000, and the monomers associated with m and n are randomly spaced within the polymer.

[0030] [ka]

[0031] Lubricants including the polyolefin copolymers herein may also have a higher viscosity index than conventional motorcycle lubricants, approaching a viscosity index (as determined by ASTM D2270) of about 160 to about 220, preferably about 170 to about 210, or more preferably about 170 to about 200. Although Formula II illustrates ethylene and propylene monomers, any of the monomers described herein may form olefin copolymers similar to that of Formula II.

[0032] In some cases, more complex olefin polymers, often referred to as interpolymers, can be prepared using at least three monomers. For example, the monomers can include ethylene, propylene, and a third monomer selected from C4-C10 alpha-olefins and / or non-conjugated dienes and trienes. The non-conjugated diene component is one having 5 to 14 carbon atoms in the chain. Preferably, the diene monomer is characterized by the presence of a vinyl group in its structure and can include cyclic and bicyclic compounds. Representative dienes include 1,4-hexadiene, 1,4-cyclohexadiene, dicyclopentadiene, 5-ethylidene-2-norbornene, 5-methylene-2-norbornene, 1,5-heptadiene, and 1,6-octadiene. Mixtures of two or more dienes can be used to prepare interpolymers. The preferred non-conjugated diene for preparing terpolymer or interpolymer substrates is 1,4-hexadiene. The triene component will have at least two non-conjugated double bonds and up to about 30 carbon atoms in the chain. Exemplary trienes useful in preparing the interpolymers of the present disclosure are 1-isopropylidene-3a,4,7,7a-tetrahydroindene, 1-isopropylidenedicyclopentadiene, dihydro-isodicyclopentadiene, and 2-(2-methylene-4-methyl-3-pentenyl)[2.2.1]bicyclo-5-heptene.

[0033] The ethylene-propylene or higher alpha-olefin copolymers are from about 15 to about 80 mole percent ethylene and from about 85 to about 20 mole percent C 3 ~C 10 The alpha-olefin may comprise an alpha-olefin, the preferred molar ratio being about 35 to 75 mole percent ethylene and about 65 to 25 mole percent C 3 ~C 10 The preferred molar ratio is about 50 to about 70 mole percent ethylene and about 50 to about 30 mole percent C. 3 ~C 10The most preferred proportions are about 55 to about 65 mole percent ethylene and about 45 to about 35 mole percent C. 3 ~C 10 In yet another approach, the olefin copolymers herein are from about 40 to about 60 mole percent ethylene and from about 60 to about 40 mole percent C 3 ~C 10 The olefin copolymer may comprise an alpha-olefin. In any embodiment herein, ethylene and propylene are preferred comonomers for the olefin copolymer. Terpolymer variations of the foregoing polymers may contain about 0.1 to 10 mole percent of a non-conjugated diene or triene.

[0034] In some approaches, the terms polymer and copolymer are used generally to encompass copolymers, terpolymers, or interpolymers. As mentioned, preferably the olefin copolymers are ethylene-propylene copolymers, although these materials may contain small amounts of other olefin monomers as long as the basic properties of the ethylene copolymer are not substantially altered.

[0035] In some approaches or embodiments, the weight average molecular weight of the olefin copolymer viscosity modifier can be from about 20,000 to about 1,500,000, in other approaches from about 20,000 to about 1,000,000, in other approaches from about 100,000 to about 500,000, in other approaches from about 100,000 to about 300,000, and in other approaches from about 100,000 to about 250,000, as determined by gel permeation chromatography (GPC) using polystyrene as a calibration standard. In yet other approaches, the number average molecular weight of the olefin copolymer viscosity modifier can range from about 20,000 to about 500,000, from about 50,000 to about 300,000, from about 75,000 to about 250,000, from about 90,000 to about 200,000, or from about 100,000 to about 150,000.

[0036] Oil-soluble molybdenum compounds The motorcycle lubricants herein may optionally include one or more oil-soluble molybdenum-containing compounds. The oil-soluble molybdenum compounds may have the functional performance of antiwear agents, antioxidants, friction modifiers, or mixtures thereof, which were previously considered necessary to achieve fuel economy goals in motorcycle applications, but are optional in the formulations herein. The oil-soluble molybdenum compounds may be any of molybdenum dithiocarbamates, molybdenum dialkyldithiophosphates, molybdenum sulfides, molybdenum disulfides, molybdenum dithiophosphinates, amine salts of molybdenum compounds, molybdenum xanthates, molybdenum thioxanthates, molybdenum sulfides, molybdenum carboxylates, molybdenum alkoxides, trinuclear organomolybdenum compounds, and / or mixtures thereof. The molybdenum-containing compounds may be sulfur-containing or non-sulfur-containing compounds. The molybdenum disulfide may be in the form of a stable dispersion.

[0037] In one embodiment, the oil-soluble molybdenum compound can be selected from the group of molybdenum dithiocarbamates, molybdenum dialkyldithiophosphates, sulfur-free organomolybdenum complexes of organic amides, and mixtures thereof. In one embodiment, the oil-soluble molybdenum compound can be molybdenum dithiocarbamates. Exemplary sulfur-free organomolybdenum complexes of organic amides are disclosed in U.S. Patent No. 5,137,647.

[0038] In one approach or embodiment, suitable molybdenum dithiocarbamates can be represented by the formula:

[0039] [ka] In the formula, R 5 , R 6 , R 7 , and R 8 are each independently a hydrogen atom, C 1 ~C 20 Alkyl group, C6 ~C 20 C containing a cycloalkyl, aryl, alkylaryl, or aralkyl group, or optionally an ester, ether, alcohol, or carboxyl group 3 ~C 20 is a hydrocarbyl group, X 1 , X 2 , Y 1 and Y 2 Each R is independently a sulfur atom or an oxygen atom. 5 , R 6 , R 7 , and R 8 Examples of suitable groups for each of R include 2-ethylhexyl, nonylphenyl, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, n-hexyl, n-octyl, nonyl, decyl, dodecyl, tridecyl, lauryl, oleyl, linoleyl, cyclohexyl, and phenylmethyl. 5 , R 6 , R 7 , and R 8 are C 6 ~C 18 X may have an alkyl group. 1 and X 2 can be identical, and Y 1 and Y 2 can be the same. X 1 and X 2 Both contain sulfur atoms, and Y 1 and Y 2 may both contain oxygen atoms. Further examples of molybdenum dithiocarbamates include C 6 ~C 18 Included are dialkyl or diaryl dithiocarbamates or alkyl-aryl dithiocarbamates such as dibutyl-, diamyl-di-(2-ethylhexyl)-, dilauryl-, dioleyl-, and dicyclohexyl-dithiocarbamate.

[0040] Suitable examples of molybdenum compounds that may be used include commercially available materials sold under trade names such as Molyvan® 822, Molyvan® A, Molyvan® 2000, Molyvan® 807 and Molyvan® 855 manufactured by RT Vanderbilt Co., Ltd., Sakura-Lube™ S-165, S-200, S-300, S-310G, S-525, S-600, S-700, and S-710 available from Adeka Corporation, and mixtures thereof. Suitable molybdenum components are described in U.S. Pat. No. 5,650,381, U.S. Reissue Pat. Nos. 37,363 (E1), 38,929 (E1), and 40,595 (E1), the entireties of which are incorporated herein by reference.

[0041] In one embodiment, if included in the formulation, the molybdenum compound may be present in a fully formulated motorcycle lubricant in an amount to provide up to about 800 ppm molybdenum, or from about 5 ppm to 800 ppm molybdenum. By way of further example, the molybdenum compound may be present in an amount to provide from about 10 to about 500 ppm molybdenum, or from about 10 to 250 ppm molybdenum, or from about 10 to 175 ppm molybdenum. In another approach, the formulations herein may be devoid of molybdenum dialkyldithiocarbamate, and in this context, the formulation may have about 0.05 weight percent or less of molybdenum dialkyldithiocarbamate, about 0.01 weight percent or less of molybdenum dialkyldithiocarbamate, or may have no molybdenum dialkyldithiocarbamate at all.

[0042] Base oil or base oil blend: The base oil used in the motorcycle lubricating compositions herein may be an oil of lubricating viscosity and may be selected from any of the base oils in American Petroleum Institute (API) Groups I to V as set forth in the API Base Oil Interchangeability Guidelines. The five base oil groups are generally set forth in Table 1 below.

[0043] [Table 3]

[0044] Group I, Group II, and Group III are mineral oil process feedstocks. Group IV base oils contain true synthetic molecular species produced by polymerization of olefinically unsaturated hydrocarbons. Many Group V base oils are also true synthetic products and may include diesters, polyol esters, polyalkylene glycols, alkylated aromatics, polyphosphate esters, polyvinyl ethers, and / or polyphenyl ethers, etc., but may also be natural oils such as vegetable oils. It should be noted that Group III base oils are derived from mineral oils, but the rigorous processing these fluids undergo makes their physical properties very similar to some true synthetic oils such as PAOs. Thus, oils derived from Group III base oils may be referred to as synthetic fluids in the industry. Group II+ may include high viscosity index Group II.

[0045] The base oil blends used in the disclosed lubricating oil compositions may be mineral, animal, vegetable, synthetic, synthetic oil blends, or mixtures thereof. Suitable oils may be derived from hydrocracked, hydrogenated, hydrofinished, unrefined, refined, and rerefined oils, and mixtures thereof.

[0046] Unrefined oils are derived from natural, mineral, or synthetic sources with little or no further purification treatment. Refined oils are similar to unrefined oils, except that they have been treated with one or more purification steps that may result in the improvement of one or more properties. Examples of suitable purification techniques are solvent extraction, secondary distillation, acid or base extraction, filtration, percolation, etc. Oils refined to edible quality may or may not be useful. Edible oils may also be called white oils. In some embodiments, the lubricating oil composition does not include edible oils or white oils.

[0047] Rerefined oils are also known as reclaimed or reprocessed oils. These oils are obtained similarly to refined oils using the same or similar processes. Often these oils are further processed by techniques directed to the removal of spent additives and oil breakdown products.

[0048] Mineral oils may include oils obtained by drilling or from plants and animals, or any mixture thereof. For example, such oils may include, but are not limited to, castor oil, lard oil, olive oil, peanut oil, corn oil, soybean oil, and linseed oil, as well as mineral lubricating oils, such as liquid petroleum oils, and solvent- or acid-treated mineral lubricating oils of the paraffinic, naphthenic, or mixed paraffinic-naphthenic types. Such oils may be partially or fully hydrogenated, if desired. Oils derived from coal or shale may also be useful.

[0049] Useful synthetic lubricating oils may include hydrocarbon oils such as polymerized, oligomerized, or interpolymerized olefins (e.g., polybutylene, polypropylene, propylene isobutylene copolymers); poly(1-hexene), poly(1-octene), trimers or oligomers of 1-decene, such as poly(1-decene) (such materials are often referred to as alpha-olefins), and mixtures thereof; alkyl-benzenes (e.g., dodecylbenzene, tetradecylbenzene, dinonylbenzene, di-(2-ethylhexyl)-benzene); polyphenyls (e.g., biphenyl, terphenyl, alkylated polyphenyls); diphenylalkanes, alkylated diphenylalkanes, alkylated diphenyl ethers, and alkylated diphenyl sulfides, and derivatives, analogs, and homologs thereof, or mixtures thereof. The polyalphaolefins are typically hydrogenated materials.

[0050] Other synthetic lubricating oils include polyol esters, diesters, liquid esters of phosphorus-containing acids (e.g., tricresyl phosphate, trioctyl phosphate, and diethyl ester of decane phosphonic acid), or polymeric tetrahydrofurans. Synthetic oils can be produced by the Fischer-Tropsch reaction and typically can be hydroisomerized Fischer-Tropsch hydrocarbons or waxes. In one embodiment, the oils can be prepared by the Fischer-Tropsch gas-liquid synthesis procedure, as well as other gas-liquid oils.

[0051] A major amount of base oil included in the lubricating composition may be selected from the group consisting of Group I, Group II, Group III, Group IV, Group V, and combinations of two or more of the foregoing, where the major amount of base oil is other than the base oil resulting from the provision of an additive component or viscosity index improver in the composition. In another embodiment, a major amount of base oil included in the lubricating composition may be selected from the group consisting of Group II, Group III, Group IV, Group V, and combinations of two or more of the foregoing, where the major amount of base oil is other than the base oil resulting from the provision of an additive component or viscosity index improver in the composition.

[0052] The amount of oil of lubricating viscosity present may be the remainder remaining after subtracting the sum of the amounts of performance additives, including viscosity index improver(s) and / or pour point depressant(s) and / or other top treat additives, from 100% by weight. For example, the oil of lubricating viscosity may be present in the final fluid in a "major amount," e.g., greater than about 50% by weight, greater than about 60% by weight, greater than about 70% by weight, greater than about 80% by weight, greater than about 85% by weight, or greater than about 90% by weight.

[0053] In some approaches or embodiments, the fully formulated motorcycle lubricants herein include one or more of Group I through Group V base oils and may have a KV100 of about 2 to about 20 cSt, in other approaches about 2 to about 10 cSt, about 4 to about 9 cSt, in yet other approaches about 5 to about 9 cSt, and in other approaches about 6 to about 8.5 cSt. The fully formulated lubricants herein may have a viscosity grade of 0W-20, 0W-16, 0W-12, or 0W-8 and may surprisingly simultaneously achieve the desired HTHS viscosity and clutch performance requirements.

[0054] As used herein, the terms "oil composition," "lubricating composition," "lubricating oil composition," "lubricating oil," "lubricant composition," "fully formulated lubricant composition," "lubricant," and "lubricating and cooling fluid" are considered synonymous and fully interchangeable terms that refer to a finished lubricating product that includes a majority amount of a base oil component and minor amounts of detergents and other optional components.

[0055] Optional Additives: The lubricating oil compositions herein may also contain a number of optional additives to meet performance specifications, which are described in the following paragraphs.

[0056] Dispersants: The lubricating oil composition may optionally contain one or more other dispersants or mixtures thereof. Dispersants are often referred to as ashless type dispersants because they do not contain ash-forming metals prior to mixing with the lubricating oil composition and do not normally contribute ash when added to the lubricant. Ashless type dispersants are characterized in that polar groups are attached to a relatively high molecular weight hydrocarbon chain. Typical ashless dispersants include N-substituted long chain alkenyl succinimides. Examples of N-substituted long chain alkenyl succinimides include polyisobutylene succinimides in which the number average molecular weight of the polyisobutylene substituent ranges from about 350 to about 50,000, or from about 5,000, or from about 3,000, as measured by GPC. Succinimide dispersants and their preparation are disclosed, for example, in U.S. Pat. No. 7,897,696 or U.S. Pat. No. 4,234,435. The alkenyl substituent may be prepared from polymerizable monomers containing from about 2 to about 16, or from about 2 to about 8, or from about 2 to about 6 carbon atoms. Succinimide dispersants are typically imides formed from polyamines, typically poly(ethyleneamines).

[0057] Preferred amines are selected from polyamines and hydroxyamines. Examples of polyamines that may be used include, but are not limited to, diethylenetriamine (DETA), triethylenetetramine (TETA), tetraethylenepentamine (TEPA), and higher homologs such as pentaethylaminehexamine (PEHA).

[0058] Suitable heavy polyamines are mixtures of polyalkylene-polyamines containing small amounts of lower polyamine oligomers such as TEPA and PEHA (pentaethylenehexamine), but primarily oligomers with 6 or more nitrogen atoms, 2 or more primary amines per molecule, and more extensive branching than conventional polyamine mixtures. Heavy polyamines preferably include polyamine oligomers containing 7 or more nitrogen atoms per molecule and having 2 or more primary amines per molecule. Heavy polyamines contain greater than 28% by weight (e.g., >32% by weight) total nitrogen and an equivalent weight of 120-160 grams of primary amine groups per equivalent.

[0059] In some approaches, suitable polyamines, commonly known as PAM, contain a mixture of ethyleneamines, with TEPA and pentaethylenehexamine (PEHA) being the major portion of the polyamine, usually less than about 80%.

[0060] Typically, PAM has 8.7-8.9 milliequivalents of primary amine per gram (115-112 gram equivalents per equivalent of primary amine) and a total nitrogen content of about 33-34% by weight. Heavier cuts of PAM oligomers that are substantially free of TEPA and contain only small amounts of PEHA, but contain primarily oligomers with more than 6 nitrogens and more extensive branching, may produce dispersants with improved dispersancy.

[0061] In an embodiment, the present disclosure further comprises at least one polyisobutylene succinimide dispersant derived from a polyisobutylene having a number average molecular weight, as determined by GPC, in the range of from about 350 to about 50,000, or to about 5000, or to about 3000. The polyisobutylene succinimide may be used alone or in combination with other dispersants.

[0062] In some embodiments, polyisobutylene, if present, may have a terminal double bond content of greater than 50 mol%, greater than 60 mol%, greater than 70 mol%, greater than 80 mol%, or greater than 90 mol%. Such PIB is also referred to as highly reactive PIB ("HR-PIB"). HR-PIB having a number average molecular weight in the range of about 800 to about 5000 as determined by GPC is suitable for use in embodiments of the present disclosure. Conventional PIB typically has a terminal double bond content of less than 50 mol%, less than 40 mol%, less than 30 mol%, less than 20 mol%, or less than 10 mol%.

[0063] HR-PIB having a number average molecular weight in the range of about 900 to about 3000 as determined by GPC may be suitable. Such HR-PIB is commercially available or can be synthesized by polymerization of isobutene in the presence of a non-chlorinated catalyst such as boron trifluoride as described in U.S. Patent No. 4,152,499 to Boerzel, et al. and U.S. Patent No. 5,739,355 to Gateau, et al. When used in the thermal ene reaction, HR-PIB can result in higher conversion during the reaction due to improved reactivity, as well as less formation of precipitate. A suitable method is described in U.S. Patent No. 7,897,696.

[0064] In one embodiment, the present disclosure further comprises at least one dispersant derived from polyisobutylene succinic anhydride ("PIBSA"), which may have an average of about 1.0 to about 2.0 succinic moieties per polymer.

[0065] The percent actives of the alkenyl or alkyl succinic anhydride can be determined using chromatographic techniques, which are described in U.S. Patent No. 5,334,321, columns 5 and 6.

[0066] Polyolefin conversion is calculated from the percent actives using the formula in columns 5 and 6 of US Pat. No. 5,334,321.

[0067] Unless otherwise specified, all percentages are weight percent and all molecular weights are number average molecular weights as determined by gel permeation chromatography (GPC) using commercially available polystyrene standards (having number average molecular weights of 180 to about 18,000) as calibration standards.

[0068] In one embodiment, the dispersant may be derived from a polyalphaolefin (PAO) succinic anhydride. In one embodiment, the dispersant may be derived from an olefin maleic anhydride copolymer. As an example, the dispersant may be described as poly-PIBSA. In one embodiment, the dispersant may be derived from an anhydride grafted to an ethylene-propylene copolymer.

[0069] A suitable class of nitrogen-containing dispersants may be derived from olefin copolymers (OCPs), more specifically ethylene-propylene dispersants that may be grafted with maleic anhydride. A more complete list of nitrogen-containing compounds that may be reacted with the functionalized OCPs is described in U.S. Patent Nos. 7,485,603, 7,786,057, 7,253,231, 6,107,257, and 5,075,383, and / or is commercially available.

[0070] One class of suitable dispersants may also be Mannich bases. Mannich bases are materials formed by condensation of higher molecular weight alkyl-substituted phenols, polyalkylene polyamines, and aldehydes such as formaldehyde. Mannich bases are described in more detail in U.S. Pat. No. 3,634,515.

[0071] A suitable class of dispersants may also be high molecular weight esters or half ester amides. Suitable dispersants may also be post-treated by reacting with any of a variety of agents by conventional methods. Among these are boron, urea, thiourea, dimercaptothiadiazole, carbon disulfide, aldehydes, ketones, carboxylic acids, hydrocarbon-substituted succinic anhydrides, maleic anhydrides, nitriles, epoxides, carbonates, cyclic carbonates, hindered phenol esters, and phosphorus compounds. U.S. Patent No. 7,645,726, U.S. Patent No. 7,214,649, and U.S. Patent No. 8,048,831 are incorporated herein by reference in their entirety.

[0072] In addition to the carbonate and boric acid post-treatments, any of the compounds may be post-treated or further post-treated with a variety of post-treatments designed to improve or impart different properties. Such post-treatments include those summarized in columns 27-29 of U.S. Pat. No. 5,241,003, which is incorporated herein by reference. Such treatments include treatment with inorganic phosphoric acids or anhydrides (e.g., U.S. Pat. Nos. 3,403,102 and 4,648,980), organic phosphorus compounds (e.g., U.S. Pat. No. 3,502,677), phosphorus pentasulfide, boron compounds as already mentioned above (e.g., U.S. Pat. Nos. 3,178,663 and 4,652,387), carboxylic acids, polycarboxylic acids, anhydrides, and / or acid halides (e.g., U.S. Pat. Nos. 3,708,522 and 4,948,386), epoxides, polyepoxy compounds, and the like. esters or thioepoxides (e.g., U.S. Pat. Nos. 3,859,318 and 5,026,495), aldehydes or ketones (e.g., U.S. Pat. No. 3,458,530), carbon disulfide (e.g., U.S. Pat. No. 3,256,185), glycidol (e.g., U.S. Pat. No. 4,617,137), urea, thiourea, or guanidine (e.g., U.S. Pat. Nos. 3,312,619, 3,865,813, and British Patent No. 1,065,595), organic sulfones, acids (e.g., U.S. Pat. No. 3,189,544 and British Patent No. 2,140,811), alkenyl cyanides (e.g., U.S. Pat. Nos. 3,278,550 and 3,366,569), diketenes (e.g., U.S. Pat. No. 3,546,243), diisocyanates (e.g., U.S. Pat. No. 3,573,205), alkanesultones (e.g., U.S. Pat. No. 3,749,695), 1,3-dicarbonyl compounds (e.g., U.S. Pat. No. 4,579,675), alkane sultones (e.g., U.S. Pat. No. 4,579,675), alkane nitriles ... No. 3,954,639), cyclic lactones (e.g., U.S. Pat. Nos. 4,617,138, 4,645,515, 4,668,246, 4,963,275, and 4,971,711), cyclic carbonates or thiocarbonates, linear monocarbonates or polycarbonates, or chloroformates (e.g., U.S. Pat. Nos. 4,612,132, 4,647,390, 4,648,886, 4,670,170), nitrogen-containing carboxylic acids (e.g., U.S. Pat. No. 4,971,598 and British Patent No. 2,140,811), hydroxy-protected chlorodicarbonyloxy compounds (e.g., U.S. Pat. No. 4,614,522), lactams, thiolactams, thiolactones, or dithiolactones (e.g., U.S. Pat. Nos. 4,614,603 and 4,666,460), cyclic carbonates or thiocarbonates, linear monocarbonates or polycarbonates, or chloroformates (e.g., U.S. Pat. Nos. 4,614,603 and 4,666,460). Nos. 4,612,132, 4,647,390, 4,646,860, and 4,670,170), nitrogen-containing carboxylic acids (e.g., U.S. Pat. No. 4,971,598 and British Patent No. 2,440,811), hydroxy-protected chlorodicarbonyloxy compounds (e.g., U.S. Pat. No. 4,614,522), lactams, thiolactams, thiolactones, or dithiolactones (e.g., U.S. Pat. Nos. 4,614,603 and 4,666,460), cyclic carbamates, cyclic thiocarbamates, or cyclic dithiocarbamates (e.g., U.S. Pat. Nos. 4,612,132, 4,647,390, 4,646,860, and 4,670,170), For example, U.S. Pat. Nos. 4,663,062 and 4,666,459), hydroxyaliphatic carboxylic acids (e.g., U.S. Pat. Nos. 4,482,464, 4,521,318, and 4,713,189), oxidizing agents (e.g., U.S. Pat. No. 4,379,064), combinations of phosphorus pentasulfide and polyalkylene polyamines (e.g., U.S. Pat. No. 3,185,647), combinations of carboxylic acids or aldehydes or ketones and sulfur or sulfur chloride (e.g., U.S. Pat. Nos. 3,390,086 and 3,470,098), hydrazine and carbon disulfide. No. 3,519,564), combinations of aldehydes and phenols (e.g., U.S. Pat. Nos. 3,649,229, 5,030,249, and 5,039,307), combinations of aldehydes and O-diesters of dithiophosphoric acids (e.g., U.S. Pat. No. 3,865,740), combinations of hydroxyaliphatic carboxylic acids and boric acid (e.g., U.S. Pat. No. 4,554,086), combinations of hydroxyaliphatic carboxylic acids followed by formaldehyde and phenols (e.g., U.S. Pat. No. 4,636,No. 322), combinations of hydroxyaliphatic carboxylic acids and then aliphatic dicarboxylic acids (e.g., U.S. Pat. No. 4,663,064), combinations of formaldehyde and phenols and then glycolic acid (e.g., U.S. Pat. No. 4,699,724), combinations of hydroxyaliphatic carboxylic acids or oxalic acid and then a diisocyanate (e.g., U.S. Pat. No. 4,713,191), combinations of inorganic acids or anhydrides of phosphorus or their partial or total sulfur analogs and boron compounds (e.g., U.S. Pat. No. 4,857,21 No. 4), an organic diacid, followed by an unsaturated fatty acid, followed by a nitrosoaromatic amine, optionally followed by a boron compound, and then a glycosylation agent (e.g., U.S. Pat. No. 4,973,412), an aldehyde and a triazole (e.g., U.S. Pat. No. 4,963,278), an aldehyde and a triazole, followed by a boron compound (e.g., U.S. Pat. No. 4,981,492), a cyclic lactone and a boron compound (e.g., U.S. Pat. Nos. 4,963,275 and 4,971,711). The above-mentioned patents are hereby incorporated in their entirety.

[0073] The TBN of suitable dispersants may be from about 10 to about 65 mg KOH / g on an oil-free basis, which equates to about 5 to about 30 TBN when measured on a dispersant sample containing about 50% diluent oil. TBN is measured by the method of ASTM D2896.

[0074] In yet another embodiment, the optional dispersant additive may be a hydrocarbyl-substituted succinamide or succinimide dispersant. In this approach, the hydrocarbyl-substituted succinamide or succinimide dispersant may be derived from a hydrocarbyl-substituted acylating agent reacted with a polyalkylene polyamine, where the hydrocarbyl substituent of the succinamide or succinimide dispersant is a linear or branched hydrocarbyl group having a number average molecular weight of about 250 to about 5,000 as determined by GPC using polystyrene as the calibration standard.

[0075] In some approaches, the polyalkylene polyamine used to form the dispersant has the formula:

[0076] [ka] wherein each R and R' is independently a divalent C1-C6 alkylene linker; 1 and R 2 are independently hydrogen, a C1-C6 alkyl group, or together with the nitrogen atom to which they are attached form a 5- or 6-membered ring optionally fused to one or more aromatic or non-aromatic rings, and n is an integer from 0 to 8. In another approach, the polyalkylene polyamine is selected from the group consisting of a mixture of polyethylene polyamines having an average of 5 to 7 nitrogen atoms, triethylenetetramine, tetraethylenepentamine, and combinations thereof.

[0077] Dispersants, when present, may be used in an amount sufficient to provide up to about 20% by weight, based on the final weight of the lubricating oil composition. Alternative amounts of dispersants that may be used may be from about 0.1% to about 15% by weight, or from about 0.1% to about 10% by weight, or from about 0.1 to 8% by weight, or from about 1% to about 10% by weight, or from about 1% to about 8% by weight, or from about 1% to about 6% by weight, based on the final weight of the lubricating oil composition. In some embodiments, the lubricating oil composition utilizes a mixed dispersant system. A single type or a mixture of two or more types of dispersants in any desired ratio may be used.

[0078] Antioxidants: The lubricating oil composition herein may also optionally contain one or more antioxidants. Antioxidant compounds are known and include, for example, phenates, phenate sulfides, sulfurized olefins, phosphosulfurized terpenes, sulfurized esters, aromatic amines, alkylated diphenylamines (e.g., nonyldiphenylamine, di-nonyldiphenylamine, octyldiphenylamine, di-octyldiphenylamine), phenyl-alpha-naphthylamines, alkylated phenyl-alpha-naphthylamines, hindered non-aromatic amines, phenols, hindered phenols, oil-soluble molybdenum compounds, polymeric antioxidants, or mixtures thereof. The antioxidant compounds may be used alone or in combination.

[0079] The hindered phenol antioxidant may contain secondary butyl and / or tertiary butyl groups as steric hindrance groups. The phenol group may be further substituted with a hydrocarbyl group and / or a bridging group that connects to a second aromatic group. Examples of suitable hindered phenol antioxidants include 2,6-di-tert-butylphenol, 4-methyl-2,6-di-tert-butylphenol, 4-ethyl-2,6-di-tert-butylphenol, 4-propyl-2,6-di-tert-butylphenol or 4-butyl-2,6-di-tert-butylphenol, or 4-dodecyl-2,6-di-tert-butylphenol. In one embodiment, the hindered phenol antioxidant may be an ester and may include, for example, Irganox™ L-135 available from BASF or an adduct derived from 2,6-di-tert-butylphenol and an alkyl acrylate, where the alkyl group may contain from about 1 to about 18, or from about 2 to about 12, or from about 2 to about 8, or from about 2 to about 6, or about 4 carbon atoms. Another commercially available hindered phenol antioxidant may be an ester and may include Ethanox™ 4716 available from Albemarle Corporation.

[0080] Useful antioxidants may include diarylamines and high molecular weight phenols. In one embodiment, the lubricating oil composition may contain a mixture of diarylamines and high molecular weight phenols, such that each antioxidant may be present in an amount sufficient to provide up to about 5 wt. %, based on the final weight of the lubricating oil composition. In one embodiment, the antioxidant may be a mixture of about 0.3 to about 1.5 wt. % diarylamines and about 0.4 to about 2.5 wt. % high molecular weight phenols, based on the final weight of the lubricating oil composition.

[0081] Examples of suitable olefins that can be sulfurized to form sulfurized olefins include propylene, butylene, isobutylene, polyisobutylene, pentene, hexene, heptene, octene, nonene, decene, undecene, dodecene, tridecene, tetradecene, pentadecene, hexadecene, heptadecene, octadecene, nonadecene, eicosene, or mixtures thereof. In one embodiment, hexadecene, heptadecene, octadecene, nonadecene, eicosene, or mixtures thereof, as well as their dimers, trimers, and tetramers, are particularly useful olefins. Alternatively, the olefins can be Diels-Alder adducts of dienes such as 1,3-butadiene and unsaturated esters such as butyl acrylate.

[0082] Another class of sulfurized olefins includes sulfurized fatty acids and their esters. The fatty acids are often derived from vegetable or animal oils and typically contain from about 4 to about 22 carbon atoms. Examples of suitable fatty acids and their esters include triglycerides, oleic acid, linoleic acid, palmitoleic acid, or mixtures thereof. Often, the fatty acids are derived from lard oil, tall oil, peanut oil, soybean oil, cottonseed oil, sunflower seed oil, or mixtures thereof. The fatty acids and / or esters may be mixed with olefins, such as α-olefins.

[0083] In another alternative embodiment, the antioxidant composition contains a molybdenum-containing antioxidant in addition to the phenolic and / or aminic antioxidants described above. When a combination of these three antioxidants is used, preferably the treat rate ratio of the phenolic to the amine to the molybdenum-containing component is (0-3):(0-3):(0-3).

[0084] The one or more antioxidants may be present in the range of from about 0% to about 20%, or from about 0.1% to about 10%, or from about 1% to about 5% by weight of the lubricating oil composition.

[0085] Anti-wear agents: The lubricating oil composition herein may also optionally contain one or more antiwear agents. Examples of suitable antiwear agents include, but are not limited to, metal thiophosphates, metal dialkyldithiophosphates; phosphate esters or salts thereof; phosphoric acid esters; phosphites; phosphorus-containing carboxylic acid esters, ethers, or amides; sulfurized olefins; thiocarbamate-containing compounds, such as thiocarbamate esters, alkylene-linked thiocarbamates, and bis(S-alkyldithiocarbamyl) disulfides; and mixtures thereof. A suitable antiwear agent may be molybdenum dithiocarbamate. Phosphorus-containing antiwear agents are described in more detail in EP 612839. The metal in the dialkyldithiophosphate salt may be an alkali metal, alkaline earth metal, aluminum, lead, tin, molybdenum, manganese, nickel, copper, titanium, or zinc. A useful antiwear agent may be zinc dialkyldithiophosphate.

[0086] Further examples of suitable antiwear agents include titanium compounds, tartrates, tartrimides, oil-soluble amine salts of phosphorus compounds, sulfurized olefins, phosphites (e.g., dibutyl phosphite), phosphonates, thiocarbamate-containing compounds such as thiocarbamate esters, thiocarbamate amides, thiocarbamic acid ethers, alkylene-linked thiocarbamates, and bis(S-alkyldithiocarbamyl) disulfides. The tartrates or tartrimides may contain alkyl-ester groups, and the total of carbon atoms on the alkyl group may be at least 8. The antiwear agent may include citrates in one embodiment.

[0087] The antiwear agent may be present in a range including from about 0% to about 15%, or from about 0.01% to about 10%, or from about 0.05% to about 5%, or from about 0.1% to about 3% by weight of the lubricating oil composition.

[0088] Boron-containing compounds: The lubricating oil compositions herein may optionally contain one or more boron-containing compounds. Examples of boron-containing compounds include borate esters, borated fatty amines, borated epoxides, borated detergents, and borated dispersants such as borated succinimide dispersants, as disclosed in U.S. Pat. No. 5,883,057. The boron-containing compounds, when present, may be used in an amount sufficient to provide up to about 8 wt. %, about 0.01 wt. % to about 7 wt. %, about 0.05 wt. % to about 5 wt. %, or about 0.1 wt. % to about 3 wt. % of the lubricating oil composition.

[0089] Cleaning agent: The lubricating oil composition may optionally further comprise one or more neutral, low-based, or overbased detergents, and mixtures thereof. Suitable detergent substrates include phenates, sulfur-containing phenates, sulfonates, calixarates, salixarates, salicylates, carboxylic acids, phosphoric acids, mono- and / or dithiophosphoric acids, alkylphenols, sulfur-bound alkylphenol compounds, or methylene-bridged phenols. Suitable detergents and their preparation methods are described in more detail in numerous patent publications, including U.S. Pat. No. 7,732,390 and references cited therein.

[0090] The detergent substrate may be salified with an alkali or alkaline earth metal, such as, but not limited to, calcium, magnesium, potassium, sodium, lithium, barium, or mixtures thereof. In some embodiments, the detergent does not contain barium. In some embodiments, the detergent may contain trace amounts of other metals, such as magnesium or calcium, in amounts such as 50 ppm or less, 40 ppm or less, 30 ppm or less, 20 ppm or less, or 10 ppm or less. Suitable detergents may include alkali or alkaline earth metal salts of petroleum sulfonic acids and long chain mono- or di-alkylaryl sulfonic acids, where the aryl groups are benzyl, tolyl, and xylyl. Examples of suitable detergents include, but are not limited to, calcium phenate, calcium sulfur-containing phenate, calcium sulfonate, calcium calixarate, calcium salixarate, calcium salicylate, calcium carboxylic acid, calcium phosphoric acid, calcium mono- and / or dithiophosphoric acid, calcium alkyl phenol, calcium sulfur-bound alkyl phenol compound, calcium methylene bridged phenol, magnesium phenate, magnesium sulfur-containing phenate, magnesium sulfonate, magnesium calixarate, magnesium salixarate, magnesium salicylate, magnesium carboxylic acid, magnesium phosphoric acid, magnesium mono- and / or dithiophosphoric acid, magnesium alkyl phenol, magnesium sulfur-bound alkyl phenol compound, magnesium methylene bridged phenol, sodium phenate, sodium sulfonate, sodium calixarate, sodium salixarate, sodium salicylate, sodium carboxylic acid, sodium phosphoric acid, sodium mono- and / or dithiophosphoric acid, sodium alkyl phenol, sodium sulfur-bound alkyl phenol compound, or sodium methylene bridged phenol.

[0091] Overbased detergent additives are well known in the art and can be alkali or alkaline earth metal overbased detergent additives. Such detergent additives can be prepared by reacting a metal oxide or metal hydroxide with a substrate and carbon dioxide gas. The substrate is typically an acid, such as an aliphatic substituted sulfonic acid, an aliphatic substituted carboxylic acid, or an aliphatic substituted phenol.

[0092] The term "overbased" refers to metal salts, such as metal salts of sulfonates, carboxylates, and phenates, in which the amount of metal present exceeds the stoichiometric amount. Such salts may have a conversion level of more than 100% (i.e., such salts may contain more than 100% of the theoretical amount of metal required to convert the acid to its "normal" or "neutral" salt). The expression "metal ratio", often abbreviated as MR, is used to indicate the ratio of the total chemical equivalents of the metal in an overbased salt to the chemical equivalents of the metal in a neutral salt, according to known chemical reactivity and stoichiometry. In normal or neutral salts, the metal ratio is 1, while in overbased salts the MR is greater than 1. They are generally referred to as overbased, hyperbasic, or superbasic salts and may be salts of organic sulfur acids, carboxylic acids, or phenols.

[0093] The overbased detergent of the lubricating oil composition may have a total base number (TBN) of about 200 mg KOH / g or greater, or, as a further example, about 250 mg KOH / g or greater, or about 350 mg KOH / g or greater, or about 375 mg KOH / g or greater, or about 400 mg KOH / g or greater, as measured by the method of ASTM D2896.

[0094] Examples of suitable overbased detergents include, but are not limited to, overbased calcium phenate, overbased calcium sulfur-containing phenate, overbased calcium sulfonate, overbased calcium calixarate, overbased calcium salixarate, overbased calcium salicylate, overbased calcium carboxylic acid, overbased calcium phosphate, overbased calcium mono- and / or dithiophosphate, overbased calcium alkylphenol, overbased calcium sulfur-bound alkylphenol compound, overbased calcium methylene bridged phenol, overbased magnesium phenate, overbased magnesium sulfur-containing phenate, overbased magnesium sulfonate, overbased magnesium calixarate, overbased magnesium salixarate, overbased magnesium salicylate, overbased magnesium carboxylic acid, overbased magnesium phosphate, overbased magnesium and / or dithiophosphate, overbased magnesium alkylphenol, overbased magnesium sulfur-bound alkylphenol compound, or overbased magnesium methylene bridged phenol.

[0095] The overbased calcium phenate detergents have a total base number of at least about 150 mg KOH / g, at least about 225 mg KOH / g, at least about 225 mg KOH / g to about 400 mg KOH / g, at least about 225 mg KOH / g to about 350 mg KOH / g, or from about 230 mg KOH / g to about 350 mg KOH / g, all measured by the method of ASTM D 2896. When such detergent compositions are formed in an inert diluent, such as a process oil, usually a mineral oil, the total base number reflects the basicity of the entire composition, including the diluent and any other materials (e.g., accelerators, etc.) that may be included in the detergent composition.

[0096] The overbased detergent may have a metal to substrate ratio of from 1.1:1, or from 2:1, or from 4:1, or from 5:1, or from 7:1, or from 10:1. In some embodiments, the detergent is effective in reducing or preventing rust in engines or other automotive components such as transmissions or gears. The detergent may be present in the lubricating composition at from about 0 wt.% to about 10 wt.%, or from about 0.1 wt.% to about 8 wt.%, or from about 1 wt.% to about 4 wt.%, or from greater than about 4 wt.% to about 8 wt.%.

[0097] Extreme Pressure Agents: The lubricating oil compositions herein may also optionally contain one or more extreme pressure agents. Extreme pressure (EP) agents that are soluble in oil include sulfur and chlorosulfur containing EP agents, chlorinated hydrocarbon EP agents, and phosphorus EP agents. Examples of such EP agents include chlorinated waxes, organic sulfides and polysulfides such as dibenzyl disulfide, bis(chlorobenzyl) disulfide, dibutyl tetrasulfide, sulfurized methyl ester of oleic acid, sulfurized alkylphenols, sulfurized dipentenes, sulfurized terpenes, and sulfurized Diels-Alder adducts, phosphorus sulfurized hydrocarbons such as the reaction products of phosphorus sulfide with turpentine or methyl oleate; dihydrocarbyl and trihydrocarbyl phosphites, for example, phosphate esters such as dibutyl phosphite, diheptyl phosphite, dicyclohexyl phosphite, pentyl phenyl phosphite; dipentyl phenyl phosphite, tridecyl phosphite, distearyl phosphite, and polypropylene substituted phenyl phosphites; metal thiocarbamates such as zinc dioctyldithiocarbamate and barium heptylphenol diacid; amine salts of alkyl and dialkyl phosphoric acids, including, for example, the amine salts of the reaction products of dialkyl dithiophosphoric acids with propylene oxide, and mixtures thereof.

[0098] Friction Modifiers: The lubricating oil composition herein may optionally contain one or more friction modifiers.Suitable friction modifiers may include metal-containing and metal-free friction modifiers, and may include, but are not limited to, imidazolines, amides, amines, succinimides, alkoxylated amines, alkoxylated ether amines, amine oxides, amidoamines, nitriles, betaines, quaternary amines, imines, amine salts, aminoguanidines, alkanolamides, phosphonates, metal-containing compounds, glycerol esters, sulfurized fatty compounds and olefins, sunflower oil, other naturally occurring vegetable or animal oils, dicarboxylic acid esters, esters or partial esters of polyols and one or more aliphatic or aromatic carboxylic acids, and the like.

[0099] Suitable friction modifiers may contain hydrocarbyl groups selected from linear, branched, or aromatic hydrocarbyl groups, or mixtures thereof, and may be saturated or unsaturated. The hydrocarbyl groups may be composed of carbon and hydrogen or heteroatoms such as sulfur or oxygen. The hydrocarbyl groups may range from about 12 to about 25 carbon atoms. In some embodiments, the friction modifier may be a long chain fatty acid ester. In other embodiments, the long chain fatty acid ester may be a monoester, or a diester, or a (tri)glyceride. The friction modifier may be a long chain fatty amide, a long chain fatty ester, a long chain fatty epoxide derivative, or a long chain imidazoline.

[0100] Other suitable friction modifiers may include organic, ashless (metal-free), nitrogen-free mechanical friction modifiers. Such friction modifiers include esters formed by reacting carboxylic acids and anhydrides with alkanols, and may generally include polar end groups (e.g., carboxyl or hydroxyl) covalently attached to an oleophilic hydrocarbon chain. An example of an organic ashless, nitrogen-free friction modifier is generally known as glycerol monooleate (GMO), which may include mono-, di-, and tri-esters of oleic acid. Other suitable friction modifiers are described in U.S. Patent No. 6,723,685, the entirety of which is incorporated herein by reference.

[0101] Aminic friction modifiers may include amines or polyamines. Such compounds may have hydrocarbyl groups that are linear, saturated, unsaturated, or a mixture thereof, and may contain from about 12 to about 25 carbon atoms. Further examples of suitable friction modifiers include alkoxylated amines and alkoxylated ether amines. Such compounds may have hydrocarbyl groups that are linear, saturated, unsaturated, or a mixture thereof. They may contain from about 12 to about 25 carbon atoms. Examples include ethoxylated amines and ethoxylated ether amines.

[0102] The amines and amides may be used by themselves or in the form of adducts or reaction products with boron compounds such as boron oxides, boron halides, metaborates, boric acid or mono-, di-, or tri-alkyl borates. Other suitable friction modifiers are described in U.S. Patent No. 6,300,291, which is incorporated herein by reference in its entirety.

[0103] Friction modifiers may optionally be present in ranges such as from about 0% to about 10% by weight, or from about 0.01% to about 8% by weight, or from about 0.1% to about 4% by weight.

[0104] Further molybdenum-containing ingredients: The lubricating oil composition herein may also optionally contain one or more molybdenum-containing compounds. The oil-soluble molybdenum compounds may have the functional properties of antiwear agents, antioxidants, friction modifiers, or mixtures thereof. The oil-soluble molybdenum compounds may include molybdenum dithiocarbamates, molybdenum dialkyldithiophosphates, molybdenum dithiophosphinates, amine salts of molybdenum compounds, molybdenum xanthates, molybdenum thioxanthates, molybdenum sulfides, molybdenum carboxylates, molybdenum alkoxides, trinuclear organomolybdenum compounds, and / or mixtures thereof. Molybdenum sulfides include molybdenum disulfide. The molybdenum disulfide may be in the form of a stable dispersion. In one embodiment, the oil-soluble molybdenum compounds may be selected from the group consisting of molybdenum dithiocarbamates, molybdenum dialkyldithiophosphates, amine salts of molybdenum compounds, and mixtures thereof. In one embodiment, the oil soluble molybdenum compound can be a molybdenum dithiocarbamate.

[0105] Suitable examples of molybdenum compounds that may be used include commercially available materials sold under trade names such as Molyvan® 822, Molyvan® A, Molyvan® 2000, Molyvan® 1055, Molyvan® 3000, and Molyvan® 855 manufactured by RT Vanderbilt Co., Ltd., and Adeka Sakura-Lube® S-165, S-200, S-300, S-310G, S-515, S-525, S-600, S-700, and S-710 available from Adeka Corporation, and mixtures thereof. Suitable molybdenum components are described in US 5,650,381, US RE 37,363 E1, US RE 38,929 E1, and US RE 40,595 E1, the entireties of which are incorporated herein by reference.

[0106] Additionally, the molybdenum compound can be an acidic molybdenum compound, including molybdic acid, ammonium molybdate, sodium molybdate, potassium molybdate, and other alkali metal molybdates and other molybdenum salts, such as sodium hydrogen molybdate, MoOCl 4 , MoO 2 Br 2 , Mo 2 O 3 Cl 6 , molybdenum trioxide, or a similar acidic molybdenum compound. Alternatively, the composition can provide the molybdenum via a molybdenum / sulfur complex of a basic nitrogen compound, as described, for example, in U.S. Pat. Nos. 4,263,152, 4,285,822, 4,283,295, 4,272,387, 4,265,773, 4,261,843, 4,259,195, and 4,259,194, and WO 94 / 06897, the foregoing patents being incorporated herein by reference in their entireties.

[0107] Another class of suitable organo-molybdenum compounds is the trinuclear molybdenum compounds, e.g., those of the formula Mo 3 S k L n Q z and mixtures thereof, where S represents sulfur, L represents an independently selected ligand having an organic group having a sufficient number of carbon atoms to render the compound soluble or dispersible in oil, n is 1 to 4, k varies from 4 to 7, Q is selected from the group of neutral electron donor compounds, such as water, amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5, including non-stoichiometric values. There may be at least 21 total carbon atoms in the organic groups of all the ligands, such as at least 25, at least 30, or at least 35 carbon atoms. Additional suitable molybdenum compounds are described in U.S. Pat. No. 6,723,685, which is incorporated herein by reference in its entirety.

[0108] The oil soluble molybdenum compound may be present in an amount sufficient to provide from about 0.5 ppm to about 2000 ppm, from about 1 ppm to about 700 ppm, from about 1 ppm to about 550 ppm, from about 5 ppm to about 300 ppm, or from about 20 ppm to about 250 ppm of molybdenum.

[0109] Other Viscosity Index Improvers: The lubricating oil composition herein may also optionally contain one or more additional viscosity index improvers, provided that the requirements described above are not compromised. Suitable viscosity index improvers may include polyolefins, olefin copolymers, ethylene / propylene copolymers, polyisobutene, hydrogenated styrene-isoprene polymers, styrene / maleic acid ester copolymers, hydrogenated styrene / butadiene copolymers, hydrogenated isoprene polymers, alpha-olefin maleic anhydride copolymers, polymethacrylates, polyacrylates, polyalkylstyrenes, hydrogenated alkenylaryl conjugated diene copolymers, or mixtures thereof. Viscosity index improvers may include star polymers, suitable examples of which are described in U.S. Publication No. 2012 / 0101017(A1).

[0110] The lubricating oil compositions herein may also optionally contain one or more dispersant viscosity index improvers in addition to or in place of the viscosity index improver. Suitable viscosity index improvers may include functionalized polyolefins, such as ethylene-propylene copolymers functionalized with the reaction product of an acylating agent (such as maleic anhydride) with an amine, amine-functionalized polymethacrylates, or esterified maleic anhydride-styrene copolymers reacted with amines.

[0111] The total amount of viscosity index improver and / or dispersant viscosity index improver may be from about 0% to about 20% by weight, from about 0.1% to about 15% by weight, from about 0.1% to about 12% by weight, or from about 0.5% to about 10% by weight of the lubricating oil composition.

[0112] Other optional additives: Other additives may be selected to perform one or more functions required in a lubricating fluid. Additionally, one or more of the aforementioned additives may be multifunctional and may provide functions in addition to or other than those described herein.

[0113] The lubricating oil composition according to the present disclosure may optionally contain other performance additives. The other performance additives may be in addition to the specific additives of the present disclosure and / or may include one or more of metal deactivators, viscosity index improvers, detergents, ashless TBN boosters, friction modifiers, antiwear agents, corrosion inhibitors, rust inhibitors, dispersants, dispersant viscosity index improvers, extreme pressure agents, antioxidants, foam suppressants, demulsifiers, emulsifiers, pour point depressants, seal swell agents, and mixtures thereof. Typically, a fully formulated lubricating oil will contain one or more of these performance additives.

[0114] Suitable metal deactivators may include derivatives of benzotriazole (typically tolyltriazole), dimercaptothiadiazole derivatives, 1,2,4-triazole, benzimidazole, 2-alkyldithiobenzimidazole, or 2-alkyldithiobenzothiazole; foam suppressors including copolymers of ethyl acrylate and 2-ethylhexyl acrylate and optionally vinyl acetate; demulsifiers including trialkyl phosphates, polyethylene glycol, polyethylene oxide, polypropylene oxide, and (ethylene oxide-propylene oxide) polymers; pour point depressants including esters of maleic anhydride-styrene, polymethacrylates, polyacrylates, or polyacrylamides.

[0115] Suitable suds suppressors include silicon-based compounds such as siloxanes.

[0116] Suitable pour point depressants may include polymethyl methacrylate or mixtures thereof. The pour point depressant may be present in an amount sufficient to provide from about 0 wt. % to about 1 wt. %, from about 0.01 wt. % to about 0.5 wt. %, or from about 0.02 wt. % to about 0.04 wt. %, based on the final weight of the lubricating oil composition.

[0117] A suitable rust inhibitor can be a single compound or a mixture of compounds that have the property of inhibiting corrosion of ferrous metal surfaces. Non-limiting examples of rust inhibitors useful herein include oil-soluble high molecular weight organic acids such as 2-ethylhexanoic acid, lauric acid, myristic acid, palmitic acid, oleic acid, linoleic acid, linolenic acid, behenic acid, and cerotic acid, as well as oil-soluble polycarboxylic acids including dimer and trimer acids such as those produced from tall oil fatty acids, oleic acid, and linoleic acid. Other suitable corrosion inhibitors include long chain alpha, omega-dicarboxylic acids in the molecular weight range of about 600 to about 3000, and alkenyl succinic acids in which the alkenyl group contains about 10 or more carbon atoms, such as tetrapropenyl succinic acid, tetradecenyl succinic acid, and hexadecenyl succinic acid. Another useful class of acidic corrosion inhibitors are the half esters of alkenyl succinic acids having about 8 to about 24 carbon atoms in the alkenyl group with alcohols such as polyglycols. The corresponding half amides of such alkenyl succinic acids are also useful.Useful rust inhibitors are high molecular weight organic acids.

[0118] When present, the rust inhibitor may be used in an amount sufficient to provide from about 0 wt. % to about 5 wt. %, from about 0.01 wt. % to about 3 wt. %, from about 0.1 wt. % to about 2 wt. %, based on the final weight of the lubricating oil composition.

[0119] Generally speaking, suitable lubricants containing detergent metals herein may contain additive components in the ranges listed in the table below.

[0120] [Table 4]

[0121] The percentages of each component above represent the weight percent of each component based on the weight of the final lubricant composition. The remainder of the lubricant composition consists of one or more base oils. The additives used in formulating the compositions described herein can be blended into the base oil individually or in various partial combinations. However, it may be preferred to blend all of the components simultaneously using an additive concentrate (i.e., additives plus a diluent such as a hydrocarbon solvent). Fully formulated lubricants conventionally contain an additive package, referred to herein as a dispersant / inhibitor package or DI package, that provides the characteristics required in the formulation.

[0122] definition For purposes of this disclosure, the chemical elements are identified according to the Periodic Table of the Elements, CAS version, Handbook of Chemistry and Physics, 75th Ed. Additionally, general principles of organic chemistry are described in "Organic Chemistry", Thomas Sorrell, University Science Books, Sausolito: 1999, and "March's Advanced Organic Chemistry", 5th Ed., Ed.: Smith, M. B. and March, J., John Wiley & Sons, New York: 2001, the entire contents of which are incorporated herein by reference.

[0123] As described herein, the compounds may be optionally substituted with one or more substituents as exemplified generally above, or as exemplified by the specific classes, subclasses, and species of the present disclosure.

[0124] Unless otherwise clear from the context, the term "major amount" is understood to mean an amount of 50 weight percent or more, for example, about 80 to about 98 weight percent, based on the total weight of the composition. Also, as used herein, the term "minor amount" is understood to mean an amount of less than 50 weight percent, based on the total weight of the composition.

[0125] As used herein, the term "hydrocarbyl group" or "hydrocarbyl" is used in its ordinary sense, well known to those skilled in the art. Specifically, it refers to a group having a carbon atom directly attached to the remainder of the molecule and having predominantly hydrocarbon character. Examples of hydrocarbyl groups include: (1) hydrocarbon substituents, i.e., aliphatic (e.g., alkyl or alkenyl), alicyclic (e.g., cycloalkyl, cycloalkenyl) and aromatic, aliphatic and alicyclic substituted aromatic substituents, as well as cyclic substituents in which a ring is completed through another portion of the molecule (e.g., two substituents taken together form an alicyclic radical); (2) substituted hydrocarbon substituents, i.e., substituents containing non-hydrocarbon groups (e.g., halo (especially chloro and fluoro), hydroxy, alkoxy, mercapto, alkylmercapto, nitro, nitroso, amino, alkylamino, and sulfoxy) that do not alter the predominantly hydrocarbon substituent in the context of this disclosure; (3) hetero substituents, i.e., substituents that, while having predominantly hydrocarbon character in the context of this disclosure, contain other than carbon in the ring or chain or are otherwise composed of carbon atoms. Heteroatoms include sulfur, oxygen, and nitrogen, and encompass such substituents as pyridyl, furyl, thienyl, and imidazolyl. Generally, no more than 2, or as a further example, only one non-hydrocarbon substituent will be present for every 10 carbon atoms in the hydrocarbyl group, and in some embodiments, there will be no non-hydrocarbon substituents in the hydrocarbyl group.

[0126] As used herein, the term "aliphatic" encompasses the terms alkyl, alkenyl, alkynyl, each of which is optionally substituted as described below.

[0127] As used herein, an "alkyl" group refers to a saturated aliphatic hydrocarbon group containing 1 to 12 (e.g., 1 to 8, 1 to 6, or 1 to 4) carbon atoms. The alkyl group can be straight or branched. Examples of alkyl groups include, but are not limited to, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, n-heptyl, or 2-ethylhexyl. An alkyl group can have one or more substituents, such as halo, phospho, alicyclic [e.g., cycloalkyl or cycloalkenyl], heteroalicyclic [e.g., heterocycloalkyl or heterocycloalkenyl], aryl, heteroaryl, alkoxy, aroyl, heteroaroyl, acyl [e.g., (aliphatic)carbonyl, (alicyclic)carbonyl, or (heteroalicyclic)carbonyl], nitro, cyano, amido [e.g., (cycloalkylalkyl)carbonylamino, arylcarbonylamino, aralkylcarbonylamino, (heterocycloalkyl)carbonylamino, (heterocycloalkylalkyl)carbonylamino, heteroarylcarbonylamino, heteroaralkylcarbonylaminoalkylaminocarbonyl, cycloalkylaminocarbonyl, heterocycloalkylaminocarbonyl, arylaminocarbonyl, or heteroarylaminocarbonyl], amino, [e.g., aliphatic amino, alicyclic amino, or heteroalicyclic amino], sulfonyl [e.g., aliphatic -SO 2-], sulfinyl, sulfanyl, sulfoxy, urea, thiourea, sulfamoyl, sulfamido, oxo, carboxy, carbamoyl, alicyclicoxy, heterocycloaliphaticoxy, aryloxy, heteroaryloxy, aralkyloxy, heteroarylalkoxy, alkoxycarbonyl, alkylcarbonyloxy, or hydroxy. Some non-limiting examples of substituted alkyl include carboxyalkyl (e.g., HOOC-alkyl, alkoxycarbonylalkyl, and alkylcarbonyloxyalkyl), cyanoalkyl, hydroxyalkyl, alkoxyalkyl, acylalkyl, aralkyl, (alkoxyaryl)alkyl, (sulfonylamino)alkyl (e.g., (alkyl-SO 2 -amino)alkyl), aminoalkyl, amidoalkyl, (alicyclic)alkyl, or haloalkyl.

[0128] As used herein, an "alkenyl" group refers to an aliphatic carbon group containing 2 to 8 (e.g., 2 to 12, 2 to 6, or 2 to 4) carbon atoms and at least one double bond. Like an alkyl group, an alkenyl group can be linear or branched. Examples of alkenyl groups include, but are not limited to, allyl, isoprenyl, 2-butenyl, and 2-hexenyl. An alkenyl group can be one or more substituents, such as halo, phospho, alicyclic [e.g., cycloalkyl or cycloalkenyl], heteroalicyclic [e.g., heterocycloalkyl or heterocycloalkenyl], aryl, heteroaryl, alkoxy, aroyl, heteroaroyl, acyl [e.g., (aliphatic)carbonyl, (alicyclic)carbonyl, or (heteroalicyclic)carbonyl], nitro, cyano, amido [e.g., (cycloalkylalkyl)carbonylamino, arylcarbonylamino, aralkylcarbonylamino, (heterocycloalkyl)carbonylamino, (heterocycloalkylalkyl)carbonylamino, heteroarylcarbonylamino, heteroaralkylcarbonylaminoalkylaminocarbonyl, cycloalkylaminocarbonyl, heterocycloalkylaminocarbonyl, arylaminocarbonyl, or heteroarylaminocarbonyl], amino, [e.g., aliphatic amino, alicyclic amino, heteroalicyclic amino, or aliphatic sulfonylamino], sulfonyl [e.g., alkyl-SO 2 -, alicyclic-SO 2 - or aryl-SO 2 -], sulfinyl, sulfanyl, sulfoxy, urea, thiourea, sulfamoyl, sulfamido, oxo, carboxy, carbamoyl, cycloaliphatic oxy, heterocycloaliphatic oxy, aryloxy, heteroaryloxy, aralkyloxy, heteroaralkoxy, alkoxycarbonyl, alkylcarbonyloxy, or hydroxy. Some non-limiting examples of substituted alkenyls include cyanoalkenyl, alkoxyalkenyl, acylalkenyl, hydroxyalkenyl, aralkenyl, (alkoxyaryl)alkenyl, (sulfonylamino)alkenyl (e.g., (alkyl-SO 2-amino)alkenyl), aminoalkenyl, amidoalkenyl, (alicyclic)alkenyl, or haloalkenyl.

[0129] As used herein, an "alkynyl" group refers to an aliphatic carbon group containing 2 to 8 (e.g., 2 to 12, 2 to 6, or 2 to 4) carbon atoms and having at least one triple bond. The alkynyl group may be linear or branched. Examples of alkynyl groups include, but are not limited to, propargyl and butynyl. An alkynyl group may be substituted with one or more substituents, such as, for example, aroyl, heteroaroyl, alkoxy, cycloalkyloxy, heterocycloalkyloxy, aryloxy, heteroaryloxy, aralkyloxy, nitro, carboxy, cyano, halo, hydroxy, sulfo, mercapto, sulfanyl [e.g., aliphatic sulfanyl or cycloaliphatic sulfanyl], sulfinyl [e.g., aliphatic sulfinyl or cycloaliphatic finyl], sulfonyl [e.g., aliphatic -SO 2 -, Aliphatic amino-SO 2 - or alicyclic -SO 2 -], amido [e.g., aminocarbonyl, alkylaminocarbonyl, alkylcarbonylamino, cycloalkylaminocarbonyl, heterocycloalkylaminocarbonyl, cycloalkylcarbonylamino, arylaminocarbonyl, arylcarbonylamino, aralkylcarbonylamino, (heterocycloalkyl)carbonylamino, (cycloalkylalkyl)carbonylamino, heteroaralkylcarbonylamino, heteroarylcarbonylamino, or heteroarylaminocarbonyl], urea, thiourea, sulfamoyl, sulfamido, alkoxycarbonyl, alkylcarbonyloxy, alicyclic, heteroalicyclic, aryl, heteroaryl, acyl [e.g., (alicyclic)carbonyl or (heteroalicyclic)carbonyl], amino [e.g., aliphatic amino], sulfoxy, oxo, carboxy, carbamoyl, (alicyclic)oxy, (heteroalicyclic)oxy, or (heteroaryl)alkoxy.

[0130] As used herein, an "amino" group refers to an -NR X R Y In the formula, R X and R Y Each of is independently hydrogen, alkyl, cycloalkyl, (cycloalkyl)alkyl, aryl, aralkyl, heterocycloalkyl, (heterocycloalkyl)alkyl, heteroaryl, carboxy, sulfanyl, sulfinyl, sulfonyl, (alkyl)carbonyl, (cycloalkyl)carbonyl, ((cycloalkyl)alkyl)carbonyl, arylcarbonyl, (aralkyl)carbonyl, (heterocycloalkyl)carbonyl, ((heterocycloalkyl)alkyl)carbonyl, (heteroaryl)carbonyl, or (heteroaralkyl)carbonyl, each of which is defined herein and optionally substituted. Examples of amino groups include alkylamino, dialkylamino, or arylamino. When the term "amino" is not a terminal group (e.g., alkylcarbonylamino), it is not limited to -NR X - Represented by R X is as defined above.

[0131] As used herein, a "cycloalkyl" group refers to a saturated carbocyclic monocyclic or bicyclic (fused or bridged) ring of 3 to 10 (e.g., 5 to 10) carbon atoms. Examples of cycloalkyl groups include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, adamantyl, norbornyl, cubyl, octahydroindenyl, decahydronaphthyl, bicyclo[3.2.1]octyl, bicyclo[2.2.2]octyl, bicyclo[3.3.1]nonyl, bicyclo[3.3.2.]decyl, bicyclo[2.2.2]octyl, adamantyl, or ((aminocarbonyl)cycloalkyl)cycloalkyl.

[0132] As used herein, a "heterocycloalkyl" group refers to a 3- to 10-membered mono- or bicyclic (fused or bridged) (e.g., 5- to 10-membered mono- or bicyclic) saturated ring structure in which one or more of the ring atoms is a heteroatom (e.g., N, O, S, or combinations thereof). Examples of heterocycloalkyl groups include piperidyl, piperazyl, tetrahydropyranyl, tetrahydrofuryl, 1,4-dioxolanyl, 1,4-dithianyl, 1,3-dioxolanyl, oxazolidyl, isoxazolidyl, morpholinyl, thiomorpholyl, octahydrobenzofuryl, octahydrochromenyl, octahydrothiochromenyl, octahydroindolyl, octahydropyrindinyl, decahydroquinolinyl, octahydrobenzo[b]thiophenyl, 2-oxa-bicyclo[2.2.2]octyl, 1-aza-bicyclo[2.2.2]octyl, 3-aza-bicyclo[3.2.1]octyl, and 2,6-dioxa-tricyclo[3.3.1.0]nonyl. Monocyclic heterocycloalkyl groups can be fused with a phenyl moiety to form structures such as tetrahydroisoquinoline, which would be classified as heteroaryls.

[0133] As used herein, a "heteroaryl" group refers to a monocyclic, bicyclic, or tricyclic ring system having 4 to 15 ring atoms, where one or more ring atoms are heteroatoms (e.g., N, O, S, or combinations thereof), and the monocyclic ring system is aromatic, or at least one of the rings in the bicyclic or tricyclic ring system is aromatic. Heteroaryl groups include benzo-fused ring systems having 2 to 3 rings. For example, benzo-fused groups include benzo fused to one or two 4-8 membered heterocyclic aliphatic moieties (e.g., indolisyl, indolyl, isoindolyl, 3H-indolyl, indolinyl, benzo[b]furyl, benzo[b]thiophenyl, quinolinyl, or isoquinolinyl). Some examples of heteroaryl are pyridyl, 1H-indazolyl, furyl, pyrrolyl, thienyl, thiazolyl, oxazolyl, imidazolyl, tetrazolyl, benzofuryl, isoquinolinyl, benzthiazolyl, xanthene, thioxanthene, phenothiazine, dihydroindole, benzo[1,3]dioxole, benzo[b]furyl, benzo[b]thiophenyl, indazolyl, benzimidazolyl, benzthiazolyl, puryl, cinnolyl, quinolyl, quinazolyl, cinnolyl, phthalazyl, quinazolyl, quinoxalyl, isoquinolyl, 4H-quinolidyl, benzo-1,2,5-thiadiazolyl, or 1,8-naphthyridyl.

[0134] Monocyclic heteroaryls include, but are not limited to, furyl, thiophenyl, 2H-pyrrolyl, pyrrolyl, oxazolyl, thazolyl, imidazolyl, pyrazolyl, isoxazolyl, isothiazolyl, 1,3,4-thiadiazolyl, 2H-pyranyl, 4-H-pyranyl, pyridyl, pyridazyl, pyrimidyl, pyrazolyl, pyrazyl, or 1,3,5-triazyl. Monocyclic heteroaryls are numbered according to standard chemical nomenclature.

[0135] Bicyclic heteroaryls include indolizyl, indolyl, isoindolyl, 3H-indolyl, indolinyl, benzo[b]furyl, benzo[b]thiophenyl, quinolinyl, isoquinolinyl, indolizinyl, isoindolyl, indolyl, benzo[b]furyl, bexo[b]thiophenyl, indazolyl, benzimidazyl, benzthiazolyl, purinyl, 4H-quinolizyl, quinolyl, isoquinolyl, cinnolyl, phthalazyl, quinazolyl, quinoxalyl, 1,8-naphthyridyl, or pteridyl. Bicyclic heteroaryls are numbered according to standard chemical nomenclature.

[0136] As used herein, the term "treat rate" refers to the weight percentage of a component in a lubricating and cooling fluid.

[0137] The weight average molecular weight (Mw) and number average molecular weight (Mn) may be determined using a gel permeation chromatography (GPC) instrument from Waters or similar instrumentation and Waters Empower Software or similar software. The GPC instrument may be equipped with a Waters separation module and a Waters refractive index detector (or similar optional instrumentation). GPC operating conditions may include a guard column, four Agilent PLgel columns (length 300×7.5 mm, particle size 5μ, and pore size range 100-10000 Å), and a column temperature of about 40° C. Non-stabilized HPLC grade tetrahydrofuran (THF) may be used as the solvent at a flow rate of 1.0 mL / min. The GPC instrument may be calibrated with commercially available poly(methyl methacrylate) (PMMA) standards with narrow molecular weight distributions ranging from 960 to 1,568,000 g / mol. The calibration curve may be extrapolated for samples with masses less than 500 g / mol. Samples and PMMA standards are dissolved in THF and prepared at concentrations of 0.1-0.5% by weight and can be used without filtration. GPC measurements are also described in U.S. Pat. No. 5,266,223, which is incorporated herein by reference. The GPC method also provides molecular weight distribution information. See, for example, W.W. Yau, J.J. Kirkland and D.D. Ly, "Modern Size Exclusion Liquid Chromatography", John Wiley and Sons, New York, 1979, which is incorporated herein by reference. EXAMPLES

[0138] A better understanding of the present disclosure and its many advantages can be made clear with the following examples. The following examples are illustrative and are not intended to be limiting in scope or spirit. Those skilled in the art will readily understand that variations of the components, methods, steps, and devices described in these examples can be used. Unless otherwise stated or apparent from the context of the following examples and discussion throughout this disclosure, all percentages, ratios, and parts described in this disclosure are by weight.

[0139] Example 1 A blend study of lubricants with polymethacrylate (PMA) polymers was evaluated for suitability for use in motorcycles. The lubricants evaluated for this study contained one of three different polymer additives and the same additive package in an API Group III base oil. High temperature high shear viscosity was measured according to JASO T 903:2016. The polymers in this evaluation included PMA1, which has a weight average molecular weight of about 510,000, PMA2, ​​which has a weight average molecular weight of about 290,000, or PMA3, which has a weight average molecular weight of about 420,000.

[0140] A lubricant having about 7 weight percent PMA1 has a KV100 of about 10.0 cSt, a KV200 of about 2.86 cP A lubricant having about 14 weight percent PMA2 had a KV100 of about 8.5 cSt, a viscosity index of about 3.0, and a viscosity index of about 316, which was not suitable for motorcycle lubricants. cP The lubricant had a HTHS viscosity of about 1.0 cSt, a KV100 of about 8.5 cSt, and a viscosity index of about 296, making it suitable for motorcycle lubricants. cP and a viscosity index of about 288, making it suitable for motorcycle lubricants. Viscosity index was determined according to ASTM D2270.

[0141] Example 2 Motorcycle lubricants were evaluated for improved fuel economy compared to a 10W-30 baseline lubricant. In this example, the motorcycle was a 125cc scooter and the reference lubricant was Honda Ultra E1 10W-30 with MoDTC, KV100 of 10.4 cSt, KV40 of 66.0 cSt, HTHS viscosity of 3.1 cP at 150C, viscosity index of about 145, and wet clutch rating of MB. The lubricants in Table 5 contained the polymer additives mentioned, and all fluids contained the same additive package and amounts of dispersants, detergents, pour point depressants, anti-wear additives, antioxidants, friction modifiers, and API Group III base oils. High temperature high shear viscosity and wet clutch rating were measured according to JASO T 903:2016, and fuel economy was measured using the World Motorcycle Test Cycle (WMTC) at the Japan Automobile Transport Technology Association (or other industrial emissions test house). The PMA used in this example was PMA2 from Example 1. The OCP had a weight average molecular weight of about 155,000.

[0142] [Table 5]

[0143] As shown in Table 5, all lubricants had improved fuel economy compared to the baseline lubricant, even at higher viscosity indexes than the baseline, and had passing wet clutch ratings and passing HTHS viscosities or HTHS viscosities within 20 percent of the baseline fluid. Clutch testing was performed using an SAE#2 test rig according to JASO T903:2106 standard, and fuel economy was evaluated using a WMTC cycle with a Class 1 motorcycle. Fuel economy improvements were averaged over multiple test runs compared to the 10W-30 baseline (2 runs in low temperature mode and 6 runs in high temperature mode). Viscosity index was determined according to ASTM D2270.

[0144] It should be noted that, as used in this specification and the appended claims, the singular forms "a," "an," and "the" include plural referents unless expressly and unambiguously limited to one referent. Thus, for example, reference to an "antioxidant" includes two or more different antioxidants. As used herein, the term "comprising" and grammatical variations thereof are intended to be open-ended such that the recitation of items in a list excludes other similar items that may be substituted for or added to the items in the list.

[0145] For purposes of this specification and the appended claims, unless otherwise indicated, all numbers expressing quantities, percentages or proportions, and other numerical values ​​used in the specification and claims should be understood in all instances to be modified by the term "about". Accordingly, unless indicated to the contrary, the numerical parameters set forth in the following specification and appended claims are approximations that may vary depending on the desired properties sought to be obtained by the present disclosure. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques.

[0146] It is understood that each component, compound, substituent, or parameter disclosed herein should be construed as disclosed for use alone or in combination with one or more of any and all other components, compounds, substituents, or parameters disclosed herein.

[0147] It is further to be understood that each range disclosed herein should be construed as a disclosure of each specific value within the disclosed range having the same number of significant digits. Thus, for example, a range of 1 to 4 should be construed as an explicit disclosure of not only the values ​​1, 2, 3, and 4, but any range of such values.

[0148] It is further understood that each lower limit of each range disclosed herein should be interpreted as being disclosed in combination with each upper limit of each range and each specific value within each range disclosed herein for the same component, compound, substituent, or parameter. Thus, the present disclosure should be interpreted as a disclosure of all ranges derived by combining each lower limit of each range with each upper limit of each range or each specific value within each range, or by combining each upper limit of each range with each specific value within each range. That is, it is further understood that any range between the endpoint values ​​within the broad range is also contemplated herein. Thus, a range of 1 to 4 also means a range of 1 to 3, 1 to 2, 2 to 4, 2 to 3, etc.

[0149] Furthermore, a specific amount / value of a component, compound, substituent, or parameter disclosed in the description or examples should be construed as a disclosure of either a lower or upper limit of a range and therefore can be combined with any other lower or upper limit of a range or specific amount / value for the same component, compound, substituent, or parameter disclosed elsewhere in this application to form a range for that component, compound, substituent, or parameter.

[0150] While particular embodiments have been described, alternatives, modifications, variations, improvements, and substantial equivalents may occur that are not presently anticipated or that cannot be currently anticipated by the applicants or others skilled in the art. It is therefore intended that the appended claims as filed, and the appended claims as they may be amended, cover all such alternatives, modifications, variations, improvements, and substantial equivalents.

Claims

1. 1. A method for improving fuel economy in a motorcycle using a lubricating oil composition comprising: lubricating an engine crankcase and a transmission including a wet clutch of the motorcycle with a lubricating oil composition from a common sump; the lubricating oil composition having a viscosity grade selected from 0W-20, 0W-16, 0W-12, or 0W-8, and comprising: (a) at least one base oil of lubricating viscosity; (b) from 10 to 20 weight percent of a linear morphology non-dispersant poly(meth)acrylate copolymer viscosity modifier having a weight average molecular weight of 500,000 or less; and, optionally, (c) a molybdenum dialkyldithiocarbamate; the lubricating oil composition has a high temperature high shear (HTHS) viscosity at 150° C. of at least 2.9 cP, as measured in accordance with JASO T 903:2016, and a clutch friction rating of MA, MA1, MA2, or MB; wherein the fuel economy of the motorcycle, when measured according to a WMTC cycle, is improved by at least 1 percent better than when measured using a WMTC cycle when the motorcycle is lubricated with the higher viscosity grade 10W-30 lubricant.

2. The lubricating oil composition has a KV100 of less than 10 cSt and / or the motorcycle has a torque of 150 cm 3 2. The method of claim 1 having an engine capacity of:

3. The method of claim 2, wherein the lubricating oil composition has a viscosity index of 250 to 350.

4. the non-dispersant poly(meth)acrylate copolymer viscosity modifier has a polydispersity index of 1.5 to 2.5 and a weight average molecular weight of 200,000 to 500,000; and 2. The method of claim 1, wherein the non-dispersant poly(meth)acrylate copolymer viscosity modifier comprises (meth)acrylate monomer units having hydrocarbyl groups in a monomer ester moiety having a weight average molecular weight of up to 700.

5. 5. The method of claim 4, wherein the lubricating oil composition is devoid of the molybdenum dialkyldithiocarbamate or the lubricating oil composition contains 800 ppm or less of molybdenum provided from the molybdenum dialkyldithiocarbamate.

6. 1. A method for lubricating a crankcase and wet clutch of a motorcycle, comprising: lubricating an engine crankcase and a transmission including a wet clutch of the motorcycle with a lubricating oil composition from a common sump; the lubricating oil composition having (i) a viscosity grade selected from 0W-20, 0W-16, 0W-12, or 0W-8; (ii) from 10 to 20 weight percent of a non-dispersant poly(meth)acrylate copolymer viscosity modifier in linear form having a weight average molecular weight of from 20,000 to 500,000; and (iii) optionally, not more than 800 ppm of molybdenum provided from a molybdenum dialkyldithiocarbamate friction modifier; the lubricating oil composition (i) exhibits a clutch friction rating of MA, MA1, MA2, or MB when measured in accordance with JASO T 903:2016; and (ii) exhibits a high temperature high shear (HTHS) viscosity at 150° C. in accordance with JASO T 903:2016 that is within 20 percent of the HTHS viscosity of a 10W-30 lubricant; wherein the motorcycle lubricated with the lubricating oil composition has a fuel economy measured according to a WMTC cycle that is at least 1 percent better than the fuel economy measured on the motorcycle when lubricated with a higher viscosity grade 10W-30 lubricant.

7. The lubricating oil composition has a high temperature, high shear (HTHS) viscosity at 150° C. of at least 2.9 cP, as measured in accordance with JASO T 903:2016, and / or the motorcycle has a 150 cm 3 7. The method of claim 6, having an engine capacity of:

8. The method of claim 7, wherein the lubricating oil composition has a viscosity index of 160 to 350.

9. The method of claim 8, wherein the non-dispersant poly(meth)acrylate copolymer viscosity modifier has a weight average molecular weight of 200,000 to 300,000.

10. The method of claim 6, wherein the lubricating oil composition has a KV100 viscosity of less than 10 cSt.

11. 1. A motorcycle lubricating oil composition effective to lubricate both an engine crankcase and a transmission including a wet clutch, comprising: a viscosity grade selected from 0W-20, 0W-16, 0W-12, or 0W-8; at least one base oil of lubricating viscosity; 10 to 20 weight percent of a non-dispersant poly(meth)acrylate copolymer viscosity modifier in linear form having a weight average molecular weight of 20,000 to 500,000; A viscosity index of 250 to 350; 800 ppm or less of molybdenum provided by a molybdenum dialkyldithiocarbamate; the lubricating oil composition has a high temperature high shear (HTHS) viscosity at 150° C. of at least 2.9 cP, as measured in accordance with JASO T 903:2016, and a clutch friction rating of MA, MA1, MA2, or MB; A lubricating oil composition, wherein a motorcycle lubricated with the lubricating oil composition exhibits fuel economy, measured according to a WMTC cycle, that is at least 1 percent better than the fuel economy measured on the motorcycle when lubricated with a higher viscosity grade 10W-30 lubricant.

12. 12. The lubricating oil composition of claim 11, wherein the non-dispersant poly(meth)acrylate copolymer viscosity modifier comprises (meth)acrylate monomer units having hydrocarbyl groups in a monomer ester moiety having a weight average molecular weight of up to 700.

13. 13. The lubricating oil composition of claim 12, wherein the lubricating oil composition has a KV100 of less than 10 cSt.

14. 14. The lubricating oil composition of claim 13, wherein the lubricating oil composition is devoid of the molybdenum dialkyldithiocarbamate or the lubricating oil composition contains from 10 ppm to 800 ppm of molybdenum provided from the molybdenum dialkyldithiocarbamate.

15. The motorcycle is 150 cm 3 12. The lubricating oil composition of claim 11 having an engine capacity of:

16. 10. The method of claim 1 or 6, wherein the content of the non-dispersant poly(meth)acrylate copolymer viscosity modifier is 14 weight percent or greater.

17. 12. The lubricating oil composition of claim 11, wherein the content of the non-dispersant poly(meth)acrylate copolymer viscosity modifier is 14 weight percent or greater.

18. 7. The method of claim 6, wherein the non-dispersant poly(meth)acrylate copolymer viscosity modifier comprises (meth)acrylate monomer units having hydrocarbyl groups in a monomer ester moiety having a weight average molecular weight of up to 700.

19. 20. The method of claim 4 or 18, wherein the weight average molecular weight of the hydrocarbyl groups in the monomeric ester moieties is 400 or greater.

20. 13. The lubricating oil composition of claim 12, wherein the weight average molecular weight of the hydrocarbyl groups in the monomeric ester moieties is 400 or greater.

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