PPTC heaters and materials with stable power and self-limiting behavior

Abstract

To provide a polymer positive temperature coefficient (PPTC) element which can be used as an over-current protection device or an over-heat protection device, and a current sensor or a temperature sensor in variable usages.SOLUTION: A PPT heater may contain an electrode assembly having: a polymer positive temperature coefficient (PPTC) material in which a resistance heater defines a heater main body, and which is arranged in a ring shape; and two or larger electrodes arranged at two or more larger positions so as to be contacted with the heater main body. The PPTC material contains: a polymer matrix defining a PPTC main body; and a conductive filing agent component arranged in the polymer matrix.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] Embodiments relate to the field of resistive heaters, and more particularly to heaters based on PPTC materials. [Background technology]

[0002] Polymeric positive temperature coefficient (PPTC) elements can be used as overcurrent or overheat protection devices and current or temperature sensors, among other applications. Polymeric positive temperature coefficient materials exhibit an increase in electrical resistance with increasing temperature due to the thermal expansion of a polymer matrix containing dispersed conductors (fillers), such as conductive metal particles, conductive carbon particles, or ceramic conductive phases. At a trip temperature, where the polymer matrix may undergo a phase transition, such as a melting transition, the accompanying large volume increase in the polymer can cause the conductive filler particles to separate from each other, destroying the conductive pathway, resulting in a sudden increase in resistance. Upon cooling, the volume contraction of the polymer can cause the resistivity of the PPTC material to return to a relatively low value below the trip temperature. This behavior makes PPTC materials suitable for applications such as resettable fuses. Generally, the overall conductivity of a PPTC material and the increase in resistance with temperature depend on the conductive filler content. For PPTC materials with high resistivity (10-10,000 ohm-cm), the electrical resistance tends to increase more significantly with increasing temperature, even below the trip temperature, due to the low conductive filler content. The increase in resistance below the trip temperature can lead to increased IR heating of the PPTC material, potentially leading to erratic tripping of the PPTC element. Therefore, known PPTC materials may not be very useful in applications where stable electrical operation below the trip temperature is useful.

[0003] It is with respect to this and other considerations that the present disclosure is provided. Summary of the Invention

[0004] In one embodiment, a resistive heater may include a polymeric positive temperature coefficient (PPTC) material arranged in a ring shape defining a heater body, and an electrode assembly having two or more electrodes arranged in contact with the heater body at two or more locations, the PPTC material including a polymer matrix defining the PPTC body and a conductive filler component disposed in the polymer matrix.

[0005] In another embodiment, the camera may include a transparent lens portion and a resistive heater disposed around the transparent lens portion. The resistive heater may include a polymeric positive temperature coefficient (PPTC) material arranged in a ring shape in a plane and defining a heater body, the PPTC material including a polymer matrix defining the PPTC body and a conductive filler component disposed in the polymer matrix. The resistive heater may further include an electrode assembly including a lower electrode on a first side of the heater body and an upper electrode disposed on a second side of the heater body opposite the first side. [Brief explanation of the drawings]

[0006] [Figure 1] 1 illustrates a PPTC component according to several embodiments of the present disclosure.

[0007] [Figure 2] 1 illustrates another PPTC component according to embodiments of the present disclosure.

[0008] [Figure 3] 1 illustrates resistance as a function of temperature for an exemplary PPTC material, according to several embodiments of the present disclosure.

[0009] [Figure 4] 1 shows a schematic diagram of the processing of PPTC components according to embodiments of the present disclosure.

[0010] [Figure 5] 1 illustrates an exemplary process flow.

[0011] [Figure 6A] 1 illustrates an exemplary resistance curve as a function of temperature for an exemplary resistive heater, according to embodiments of the present disclosure. [Figure 6B] 1 illustrates an exemplary power output curve as a function of temperature for an exemplary resistive heater, according to embodiments of the present disclosure.

[0012] [Figure 7A] 10 illustrates an exemplary resistance curve as a function of temperature for another exemplary resistive heater, according to embodiments of the present disclosure. [Figure 7B] 10 illustrates an exemplary power output curve as a function of temperature for another exemplary resistive heater, according to embodiments of the present disclosure.

[0013] [Figure 7C] 10 illustrates an exemplary resistance curve as a function of temperature for another exemplary resistive heater, according to embodiments of the present disclosure. [Figure 7D] 10 illustrates an exemplary power output curve as a function of temperature for another exemplary resistive heater, according to embodiments of the present disclosure.

[0014] [Figure 8] 10 illustrates an exemplary power output curve as a function of temperature for another exemplary resistive heater, according to embodiments of the present disclosure.

[0015] [Figure 8A] 1 shows an exemplary test circuit for measuring the electrical behavior of a PPTC element.

[0016] [Figure 9] 1 shows a power output curve as a function of temperature for a reference exemplary heater.

[0017] [Figure 10A] 3 shows a side view of an exemplary PPTC resistive heater 350 according to embodiments of the present disclosure.

[0018] [Figure 10B]10B illustrates, in plan view, an alternative variation of the resistive heater component of FIG. 10A. [Figure 10C] 10B illustrates, in plan view, an alternative variation of the resistive heater component of FIG. 10A.

[0019] [Figure 11] 1 provides a circuit diagram of an exemplary PPTC-based resistive heater.

[0020] [Figure 12] 1 illustrates an exemplary PPTC-based resistive heater component according to multiple embodiments of the present disclosure.

[0021] [Figure 13] 1 provides a circuit diagram of an exemplary PPTC-based resistive heater.

[0022] [Figure 14] 1 illustrates an exemplary PPTC resistive heater according to multiple embodiments of the present disclosure.

[0023] [Figure 15A] 1 illustrates a cross section of a novel camera according to multiple embodiments of the present disclosure.

[0024] [Figure 15B] 1A-1D show plan and perspective views of heater components according to multiple embodiments of the present disclosure. DETAILED DESCRIPTION OF THE INVENTION

[0025] The present embodiments will now be described more fully hereinafter with reference to the accompanying drawings, in which exemplary embodiments are shown. These embodiments should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the embodiments to those skilled in the art. In the drawings, like numbers refer to like elements throughout.

[0026] In the following description and / or claims, the terms “on,” “overlying,” “disposed on,” and “over” may be used in the following description and claims. “On,” “on,” “disposed on,” and “above” may be used to indicate that two or more elements are in direct physical contact with each other. The terms “on,” “on,” “disposed on,” and “above” may also mean that two or more elements are not in direct contact with each other. For example, “above” may mean that one element is above another element but is not in contact with each other, and that there may be one or more other elements between the two elements. Furthermore, the term “and / or” may mean “and,” “or,” “exclusive or,” “one,” “some but not all,” “neither,” and / or “both,” although the scope of the claimed subject matter is not limited in this respect.

[0027] In various embodiments, novel PPTC materials are provided, including conductive fillers with nanosized carbon filler materials, such as single-walled carbon nanotubes, multi-walled carbon nanotubes, or graphene. The PPTC materials can include a polymer matrix, such as polyethylene, polyethylene copolymers, polyesters, polyurethanes, polyamides, fluoropolymer resins, or blends of fluoropolymers with other polymers. In various non-limiting embodiments, the PPTC materials can include additives such as antioxidants, dispersants, crosslinkers, and arc suppressants. As described in more detail below, an advantage of the PPTC materials of the present embodiments is that their power remains stable over a temperature range from room temperature to the maximum operating temperature, with power varying by less than 60%, e.g., 50% to 60%, and in some embodiments, by less than 30%, e.g., 20% to 30%.

[0028] Certain embodiments are based on polymeric positive temperature coefficient (PPTC) materials formed from graphene fillers and a semi-crystalline polymer matrix. The stable resistance behavior provided by such PPTC materials enables new applications, such as resistive heaters employing PPTC components. The stable resistance behavior leads to stable heater power behavior at temperatures below the melting point of the polymer matrix, which is generally associated with the trip temperature of the PPTC component. Another advantage is uniform and effective heat transfer. Furthermore, the resistivity and trip temperature can be adjusted by adjusting the type of polymer, conductive filler, and volume fraction of the conductive filler, allowing for customized power consumption and power limit temperatures according to the resistive heater application.

[0029] In certain embodiments, the PPTC material can be arranged as a polymer matrix having a shape and size that defines the PPTC body according to a desired application. For example, the PPTC heater can be arranged as a planar heater, including a ring-shaped heater or other suitable shape. The PPTC material can also include a graphene filler component disposed in the polymer matrix, the graphene filler component being formed from multiple graphene sheets aligned along a predetermined plane of the PPTC body, such as the major plane of a ring-shaped PPTC component.

[0030] In some embodiments, the PPTC material may include conductive fillers formed solely of graphene fillers, while in other embodiments, a second conductive filler, such as a known carbon filler, may be added in addition to the graphene fillers. FIG. 1 illustrates a PPTC component according to several embodiments of the present disclosure. The PPTC component 100 includes a PPTC body 102, which includes a polymer matrix 104 and graphene fillers 106 dispersed as tiny sheets in the polymer matrix 104. The PPTC component 100 further includes a pair of opposing electrodes, shown as electrodes 108, through which an external voltage can be applied to drive a current through the PPTC body 104. Non-limiting examples of polymers suitable for the polymer matrix 104 include semi-crystalline polymers such as polyethylene, polyester, polyvinylidene fluoride, ethylene tetrafluoroethylene, ethylene vinyl acetate, ethylene and acrylic acid copolymer, ethylene butyl acrylate copolymer, and poly-perfluoroalkoxy.

[0031] The volume percentage of the polymer matrix in the PPTC body 102 can range from 50 to 99% in some embodiments, and from 60 to 95% in certain embodiments. In various non-limiting embodiments, the volume fraction of graphene can range from 1 to 50% and from 4 to 30% in certain embodiments. The graphene for the graphene filler 106 can be prepared by mechanical or chemical means, and the graphene particles are formed from layers of graphene sheets, with the number of graphene sheets in the particle ranging from one to several hundred, and from one to about 30, in certain embodiments, according to various embodiments. Thus, graphene particles formed from several graphene sheets can have a two-dimensional, sheet-like shape. According to some embodiments, the size of the resulting graphene particles can range from 0.1 μm to 100 μm, particularly from 1 μm to 30 μm.

[0032] By way of background, graphene is a crystalline allotrope of carbon with two-dimensional properties. These carbon atoms are closely packed within graphene in a regular, atomic-scale hexagonal pattern. Graphene has a thermal conductivity of 1500-2500 W.m. -1 .K -1 1, the graphene fillers are arranged as sheet-like particles, with the plane of the particles, i.e., the sheets, generally aligned along a predetermined plane of the PPTC body 104, e.g., along the XY plane of the Cartesian coordinate system shown. The high thermal conductivity of the graphene fillers 106 not only effectively enables heat transfer to the environment along the Z direction, but also enables uniform heat transfer in the XY plane. These thermal properties are particularly useful for heater applications. Furthermore, the bulk electrical resistivity of the graphene sheets is 10 -6 Ω-cm, and the bulk resistivity of most conductive metals is 2×10 -6 Furthermore, the 2D structure of graphene allows the semi-crystalline polymer in the polymer matrix 104 to contact two sides of the graphene particles, which allows the PPTC material to respond to temperature in a synchronized manner once the polymer matrix 104 reaches its melting point.

[0033] 2 illustrates another PPTC component 120 according to embodiments of the present disclosure. In this example, the PPTC component 120 may be arranged generally in the same manner as the PPTC component 100 described above, with similar components being numbered the same. The PPTC component 120 differs from the PPTC component 100 in that the PPTC body 112 further includes a conductive component 110, which may be a carbon filler and / or a ceramic conductive component disposed as a plurality of carbon particles or ceramic conductive particles (such as TiC or WC) in the polymer matrix 106. As such, the conductive component 110 may modify the electrical properties of the PPTC component 120 relative to the electrical properties of the PPTC component 100.

[0034] FIG. 3 shows the resistance as a function of temperature for exemplary PPTC materials according to embodiments of the present disclosure. In this case, the two different curves generally represent the behavior of two different PPTC materials as aligned in FIGS. 1 and 2, respectively. The lower curve corresponds to PPTC component 100, and the upper curve corresponds to PPTC component 120. In both examples, the resistance is relatively low and stable from room temperature to approximately 140°C-150°C, but increases rapidly at the trip temperature of 170°C. For the pure graphene component, the resistance increases to over 900 Ohms, and for the PPTC component with graphene and carbon filler, the resistance increases to over 24,000 Ohms. Notably, in both examples, the low-temperature resistance below the trip temperature is very stable.

[0035] 4 shows a schematic diagram of processing a PPTC component according to embodiments of the present disclosure. To form a PPTC component suitable for heater applications, etc., a PPTC material can be extruded in an extrusion device to form a layer or sheet of PPTC. Generally, a PPTC material 220, such as a mixture of a polymer material and graphene particles, can be added to a receptacle 202 coupled to an extrusion chamber 204, and the PPTC material 220 can be mixed, heated, and drawn by an extrusion component 206 to form a PPTC body 210 in the form of a sheet or layer.

[0036] FIG. 5 shows an exemplary process flow 302. In block 302, a polymer material, a conductive powder, and optional additives are mixed. The polymer material may be a powder of a semi-crystalline polymer, while the conductive filler includes graphene particles and, optionally, carbon particles and / or conductive ceramic particles. In block 304, a hot-melt process is performed, in which the mixed components, such as the polymer and the conductive filler, are heated to a temperature that melts the polymer and, accordingly, more uniformly disperses the conductive filler particles in the polymer matrix. In block 306, sheet extrusion is performed to form a sheet of PPTC material, in which the molten mixture of the polymer and the conductive filler is extruded to form a PPTC sheet or layer. In block 308, conductive metal layers (foils) can be applied to the top and bottom surfaces of the extruded PPTC sheet to form a laminate. In block 310, the laminate is singulated to form individual components, including a PPTC body sandwiched between opposing electrodes, thereby forming one or more PPTC components. In some examples, the singulated PPTC bodies may have a ring shape, such as a circular ring, a rectangular ring, an oval ring, an elliptical ring, or a polygonal ring. In block 312, the singulated PPTC bodies are assembled into a device, such as a heater. For example, the singulated PPTC bodies may be attached to leads (wires) that connect to their opposing electrodes to form a PPTC heater. Optionally, the heater may be incorporated into another structure, such as a heated camera or other structure. In block 314, an insulating coating may be applied to encapsulate the components of the PPTC heater. For example, the insulating coating may be formed by electrophoretic deposition in a chemical bath, followed by CVD to form a parylene coating, or other insulating coating.

[0037] 6A and 6B, exemplary resistance and power curves as a function of temperature are shown for an exemplary resistive heater according to embodiments of the present disclosure. The exemplary heater is formed from a PPTC material with a polymer matrix and graphene fillers. As shown in FIG. 6A, the resistance remains substantially unchanged from 25°C to approximately 150°C, then increases sharply above 170°C. Conversely, power consumption remains between 3.3 watts and 3 watts up to 100°C, gradually decreases to 1.8 W at 150°C, and then decreases more sharply above 150°C to approximately 0.2 W at 175°C, limiting power near the melting point of the polymer.

[0038] 7A and 7B show exemplary resistance and power curves, respectively, as a function of temperature for another exemplary resistive heater according to embodiments of the present disclosure. The exemplary heater is formed from a PPTC material having a carbon filler and a polymer matrix in addition to graphene fillers. As shown in FIG. 7A, the resistance remains substantially unchanged from 25°C to approximately 150°C, then increases sharply above 170°C. Conversely, power consumption decreases from 3.3 watts to approximately 2.6 watts up to 100°C, then decreases more rapidly to near zero watts at 170°C. The above results demonstrate how heater properties can be tuned by adding carbon to a graphene-based PPTC body.

[0039] In other embodiments of the present disclosure, a PPTC heater can be formed from a PPTC material with a filler formed from a carbon nanotube material, such as a single-walled or multi-walled carbon nanotube material. Figures 7C and 7D show exemplary resistance and power curves, respectively, as a function of temperature for another exemplary resistive heater according to embodiments of the present disclosure. The exemplary heater is formed from a PPTC material with a polymer matrix and a carbon nanotube filler. As shown in Figure 7D, below 150°C, the power level is relatively stable compared to a PTC heater based on a carbon filler, as described below with respect to Figure 9.

[0040] FIG. 8 shows exemplary output curves as a function of temperature for another exemplary resistive heater according to embodiments of the present disclosure. FIG. 8A shows an exemplary test circuit for measuring the electrical behavior of a PPTC element. Two output curves are shown in FIG. 8: one for when 16 V is applied to the heater and the other for when 13.5 V is applied to the heater. It can be seen that higher voltages drive higher power (3.4 watts compared to 2.4 watts). However, in both cases, the power remains fairly constant between 20°C and 140°C, then rapidly decreases above 150°C before reaching a power level of less than 1 watt above 170°C. The decrease in power above 150°C reflects the tripping of the PPTC heater, where a rapid increase in resistance limits the current and total power for a given applied voltage. Thus, the PPTC material heater element of FIG. 8 functions to provide uniform power over a wide temperature range before decreasing to a limited power above the trip temperature.

[0041] For comparison, FIG. 9 shows the power output curve as a function of temperature for a reference heater based on PPTC without graphene filler. FIG. 9 also shows two power output curves: one for when 16 V is applied to the heater and one for when 13.5 V is applied to the heater. It can be seen that the higher voltage drives higher power (2.1 watts compared to 1.5 watts). However, in both cases, the power decreases continuously and substantially between 20°C and 140°C, essentially reaching zero watts of power above 150°C. Therefore, such resistive heaters do not exhibit stable power output over a useful temperature range between room temperature and 150°C, such as below the trip temperature.

[0042] According to various embodiments of the present disclosure, PPTC heaters can be adapted for use in components such as cameras. The following embodiments, illustrated with reference to FIGS. 10A through 15, illustrate novel configurations of PPTC resistive heaters, including the incorporation of PPTC resistive heaters into cameras. According to various embodiments, the PPTC resistive heaters may be based on known PPTC materials, such as carbon-filled polymers, as generally described in the previous embodiments, or may be based on graphene-filled polymers. PPTC heaters based on graphene-filled polymers may be particularly suitable for applications requiring stable current operation over a wide temperature range.

[0043] FIG. 10A shows a side view of an exemplary PPTC resistive heater 350 according to several embodiments of the present disclosure. The resistive heater 350 includes a PPTC resistive heater component 360 and an external wire 370. The resistive heater component may be generally arranged, for example, as described above with respect to the embodiment of FIGS. 1 and 2. The resistive heater component 360 may have a ring shape when viewed in plan view to abut the periphery of a heated component, such as a camera. Arrows indicate the current path for current flowing from the wire 370 on the left side through the PPTC resistive heater component 360 and out of the wire 370 on the right side. FIGS. 10B and 10C show an alternative variation of the resistive heater component 360 in plan view. The resistive heater component 360 includes a PPTC body 362 arranged as a circular ring body and an opposing electrode, shown as electrode 364. As shown in FIG. 10B , for example, resistive heater component 360A is arranged with its opposing electrodes as two ring segments, shown as segments 364A and 364B, with portions of the circular ring body exposed at exposed regions 362A and 362B, as shown. The configurations of FIGS. 10A and 10B differ from each other in the relative placement of segments 364A and 364B and the shape and size of exposed regions 362A and 362B. Because of this configuration, as shown in FIG. 10A , current flowing via the path of least resistance can flow vertically from the left wire 370 to the lower one of the electrodes 364, then laterally along the electrode 364 along the lower surface of the PPTC body. Breaks in electrode 364 then allow current to flow vertically to the top surface, then laterally along the top surface, vertically from the top to the bottom surface of the PPTC body, laterally along the lower electrode, and vertically out of the right wire 370.

[0044] 11 provides a circuit diagram of the example PPTC-based resistive heater of FIG. 10. Elements R0 and R7 represent resistance from wire 370. Elements R1, R4, and R6 represent resistance from the foil, and elements R2, R3, and R5 represent resistance from the PTC ring body. As shown, the resistance of element R3 may be greater than the resistances of R2 and R5, which occur on the left and right sides of the PTC ring.

[0045] 12 illustrates an exemplary PPTC-based resistive heater component, designated PPTC heater component 400, according to multiple embodiments of the present disclosure. In this example, PPTC heater component 400 has a flattened ring shape, as shown in side view (top and bottom) and top view (center). PPTC heater component 400 may be arranged generally as shown in the embodiment of FIGS. 1 and 2, with the PPTC body sandwiched between opposing electrodes. In this case, these opposing electrodes may cover most of the upper and lower ring surfaces.

[0046] Figure 13 provides a circuit diagram of the exemplary PPTC-based resistive heater of Figure 12. Elements R0 and R7 represent resistance from external wires connected to the PPTC heater 400. Elements R1, R2, R5, and R6 represent resistance from the solder pads, and elements R3 and R4 represent resistance from the PTC body.

[0047] 14 shows a side view of an exemplary PPTC resistive heater 450 according to multiple embodiments of the present disclosure. The resistive heater 450 includes a PPTC resistive heater component 400 and an external wire 410. Arrows indicate the current path for current flowing from the wire 410 on the left side through the PPTC resistive heater component 400 and out of the wire 410 on the right side. As shown, current can flow vertically from the wire 410 on the left side to the top surface of the PPTC body, then laterally along the upper electrode, vertically from the top surface to the bottom surface of the PPTC body, laterally along the lower electrode, and out of the wire 410 on the right side.

[0048] In various embodiments, the PPTC heater can be integrated into a printed circuit board (PCB). For example, the resistive heater component 400 can be integrated into a resistive heater using a PCB to support a surface mount PTC resistive heater configuration.

[0049] As mentioned, the PPTC resistive heater according to the present embodiment can be incorporated into a camera. FIG. 15A shows a novel camera 500 including a PPTC resistive heater component 400A arranged as a ring that is incorporated into a camera lens assembly. The PPTC resistive heater component 400A can be in thermal contact with the camera lens 430 to heat the camera lens via resistive heating. Due to the ring shape, the outer periphery of the camera lens 430 can be directly heated. In this manner, the camera lens can be heated to a predetermined amount to, for example, drive off moisture or sediment.

[0050] In the specific embodiment of FIG. 15A , the heater component 400A can conduct current as shown for the heater component 400 above. The heater component 400A includes a PTC body 412, a metal foil layer 414, a conductive metal portion 418, and an insulating layer 416. The heater component 400A can be bonded to a wire 410 via contact metal 419. FIG. 15B shows a plan view of the heater component 400A, with the top of FIG. 15A corresponding to cross section AA along the semicircular path shown in FIG. 15B . Thus, the heater component 400A can be arranged according to surface mount technology. In particular, the heater component 400A can be supported on a PCB ring 420, with the heater component 400A and the PCB ring 420 having a ring shape as shown in FIG. 15B . The heater component 400A can be divided into two segments as shown to generate a current path generally as shown in FIG. 14 . In particular, current between wires 410 can travel in two semicircular parallel paths. In various non-limiting embodiments, the total thickness of heater component 400A can be about 2 mm, and the thickness of PCB ring 420 is less than 1.5 mm. Non-limiting examples of suitable materials for PCB ring 420 include FR4, copper inlay PCB, or ceramic PCB such as Al2O3 or AlN.

[0051] When a PPTC resistive heater according to the present embodiments is incorporated into a camera or other device to be heated, the following advantages may be realized: 1) a self-balancing power distribution design, 2) a component that is thin yet completely insulated from the camera housing, 3) a specially shaped heater that can fit into very small areas, 4) a component whose power vs. temperature performance can be tuned by adjusting the filler recipe, such as optional carbon particles and graphene particle volume fraction (in the case of graphene-based PPTC materials) added to the polymer matrix, 5) a resistive heater with stable power vs. temperature behavior over a wide temperature range, e.g., up to the maximum operating temperature (in the case of graphene-based PPTC materials), 6) higher power generation in colder environments, 7) lower power generation in warmer environments, and 8) a power-self-limited resistive heater.

[0052] Although the present embodiments have been disclosed with reference to particular embodiments, numerous modifications, alterations, and variations can be made to the described embodiments without departing from the sphere and scope of the present disclosure, as defined by the appended claims. Accordingly, the present embodiments should not be limited to the described embodiments, but rather may have full scope defined by the language of the following claims and equivalents thereof.

Claims

1. a polymeric positive temperature coefficient (PPTC) material configured in a ring shape defining a heater body; an electrode assembly having two or more electrodes disposed in contact with the heater body at two or more locations, the two or more electrodes including a lower electrode disposed on a first surface of the heater body and an upper electrode disposed on a second surface of the heater body; A resistive heater comprising: The PPTC material is a polymer matrix defining a PPTC body; a conductive filler component disposed within the polymer matrix; Including, the upper electrode and the lower electrode each include two segments, a first pair of segments in the upper electrode being separated from one another by first and second gaps, and a second pair of segments in the lower electrode being separated from one another by third and fourth gaps; current entering the resistive heater is directed to flow laterally along the first surface, vertically to the second surface, laterally along the second surface, and vertically to the first surface; Resistive heater.

2. The resistive heater of claim 1 , wherein the ring shape comprises a circular ring, a rectangular ring, an elliptical ring, an oval ring, or a polygonal ring.

3. The resistive heater of claim 1 or 2, wherein the conductive filler component comprises a carbon filler and / or a conductive ceramic component disposed as a plurality of carbon particles in the polymer matrix.

4. A resistive heater described in any one of claims 1 to 3, wherein the volume percentage of the polymer matrix is 50 to 99%.

5. The resistive heater of claim 1 , wherein the conductive filler component comprises a graphene filler component and / or a carbon nanotube filler component.

6. 6. The resistive heater of claim 1, further comprising a first lead and a second lead electrically connected to the electrode assembly, the first lead and the second lead extending perpendicular to the plane of the heater body.

7. A resistive heater as described in any one of claims 1 to 6, wherein the upper electrode and the lower electrode are generally configured in a ring shape.

8. The resistive heater of claim 1 , wherein the heater body is disposed on a printed circuit board (PCB) substrate, the PCB substrate being configured in a ring shape.

9. 9. The resistive heater of claim 8, wherein the heater body and the electrode assembly have a combined thickness in the range of 2 mm, and the PCB substrate has a thickness of less than 1 mm.

10. The PCB substrate can be FR4, copper inlay PCB, or Al ２ O ３ 10. A resistive heater according to claim 8 or 9, comprising a ceramic PCB such as AlN.

11. A transparent lens part, a resistive heater disposed around the transparent lens portion; A camera comprising: The resistive heater is a polymeric positive temperature coefficient (PPTC) material arranged in a ring shape in a plane and defining a heater body; a polymer matrix defining a PPTC body; a conductive filler component disposed within the polymer matrix; a PPTC material comprising: an electrode assembly including a lower electrode on a first surface of the heater body and an upper electrode disposed on a second surface of the heater body opposite the first surface, the upper electrode and the lower electrode being configured in a generally ring shape; and the upper electrode and the lower electrode each include two segments, a first pair of segments in the upper electrode being separated from one another by first and second gaps, and a second pair of segments in the lower electrode being separated from one another by third and fourth gaps; current entering the resistive heater is directed to flow laterally along the first surface, vertically to the second surface, laterally along the second surface, and vertically to the first surface; camera.

12. The camera of claim 11 , wherein the ring shape comprises a circular ring, a rectangular ring, an elliptical ring, an oval ring, or a polygonal ring.

13. 13. The camera of claim 11 or 12, wherein the conductive filler component comprises a carbon filler component disposed as a plurality of carbon particles in the polymer matrix.

14. a first lead and a second lead electrically connected to the electrode assembly, the first lead and the second lead extending perpendicular to the plane of the heater body; The camera of claim 11 further comprising:

15. 15. The camera of claim 11, wherein the conductive filler component comprises a graphene filler component and / or a carbon nanotube filler component.

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