Polyoxyalkylene polymer and curable composition

Abstract

To provide a hydrolyzable silyl group-containing polyoxyalkylene-based polymer capable of forming a cured product having enhanced restorative properties while exhibiting low modulus.SOLUTION: There is provided a polyoxyalkylene-based polymer having a polyoxyalkylene main chain structure and a terminal structure bonded to the end of the main chain structure, wherein the terminal structure has a hydrolyzable silyl group, a terminal olefin group and / or an internal olefin group, the total number of hydrolyzable silyl groups, terminal olefin groups and internal olefin groups is 1.0 or more per terminal structure on average and the molar number of hydrolyzable silyl groups in the polyoxyalkylene-based polymer / (the total molar number of hydrolyzable silyl groups, terminal olefin groups and internal olefin groups) is 0.3 to 0.7.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a polyoxyalkylene polymer having a hydrolyzable silyl group, and a curable composition containing the polymer. [Background technology]

[0002] Polymers containing hydrolyzable silyl groups are known as moisture-reactive polymers and are used in a wide range of industrial products, including adhesives, sealants, coatings, paints, and pressure-sensitive adhesives.

[0003] Known examples of the main chain skeleton of such polymers include polyoxyalkylene polymers, saturated hydrocarbon polymers, and (meth)acrylic acid ester polymers. In particular, polyoxyalkylene polymers having hydrolyzable silyl groups have a wide range of applications due to their relatively low viscosity at room temperature and ease of handling, and the cured products obtained after the reaction also exhibit good elasticity.

[0004] Patent Document 1 discloses a room-temperature-curable composition containing a polyoxyalkylene polymer having a hydrolyzable silyl group at at least one end, and describes a method for producing the polymer, in which a terminal hydroxyl group of the polyoxyalkylene polymer is converted into an alkoxide group, and then an organic halide such as allyl chloride is reacted therewith to introduce a carbon-carbon double bond at the end, and further, a hydrosilane is subjected to an addition reaction to convert the double bond into a hydrolyzable silyl group.

[0005] Furthermore, Patent Document 2 discloses a polyoxyalkylene polymer having two or more hydrolyzable silyl groups at one terminal site, and describes a method for producing the polymer, in which terminal hydroxyl groups of the polymer are first converted to alkoxide groups, followed by reaction with an epoxy compound having a carbon-carbon double bond, and further reaction with an organic halide having a carbon-carbon double bond, such as allyl chloride, thereby introducing two or more carbon-carbon double bonds at one terminal site, and then subjecting the polymer to an addition reaction with hydrosilanes.

[0006] Meanwhile, in recent years, the construction market has been demanding sealants that are less prone to bleed-out. For this reason, studies have been conducted on curable compositions for sealants that do not use conventional phthalate ester plasticizers or PPG plasticizers, and instead use reactive diluents with hydrolyzable silyl groups introduced at only one end of the polymer molecular chain. [Prior art documents] [Patent documents]

[0007] [Patent Document 1] Japanese Patent Application Publication No. 52-73998 [Patent Document 2] International Publication No. 2013 / 180203 Summary of the Invention [Problem to be solved by the invention]

[0008] When such a reactive diluent is blended into a curable composition containing a hydrolyzable silyl group-containing polyoxyalkylene polymer, bleed-out can be suppressed, but the recovery property (the ability to return to the original shape after a predetermined deformation) of the cured product tends to decrease. To address this, a possible approach is to improve the recovery property by increasing the modulus (the stress required to impart a predetermined deformation, in this case, particularly the stress when a dumbbell-shaped test specimen is elongated) of the cured product of the hydrolyzable silyl group-containing polyoxyalkylene polymer, which is the base polymer. However, It is desirable to keep the modulus low, as an increase in modulus can lead to a decrease in flexibility.

[0009] In view of the above-mentioned current situation, an object of the present invention is to provide a hydrolyzable silyl group-containing polyoxyalkylene polymer that can form a cured product having a low modulus and improved recovery, and a curable composition containing the same. [Means for solving the problem]

[0010] As a result of intensive research conducted by the present inventors to solve the above-mentioned problems, they have found that a polyoxyalkylene polymer having a hydrolyzable silyl group and a terminal olefin group and / or an internal olefin group in a terminal structure, in which the total number of hydrolyzable silyl groups, terminal olefin groups and internal olefin groups is on average more than 1.0 per terminal structure, and the ratio of the number of moles of hydrolyzable silyl groups to the total number of moles of hydrolyzable silyl groups, terminal olefin groups and internal olefin groups is set to a relatively low value of 0.3 to 0.7, can provide a hydrolyzable silyl group-containing polyoxyalkylene polymer that can form a cured product that exhibits a low modulus (i.e., high flexibility) and has high recovery, thereby completing the present invention.

[0011] Specifically, the present invention relates to a polyoxyalkylene polymer (A) having a polyoxyalkylene main chain structure and a terminal structure bonded to an end of the main chain structure, wherein the terminal structure has a hydrolyzable silyl group and a terminal olefin group and / or an internal olefin group, the total number of hydrolyzable silyl groups, terminal olefin groups and internal olefin groups is on average more than 1.0 per terminal structure, and the molar ratio of hydrolyzable silyl groups in the polyoxyalkylene polymer to (the total molar ratio of hydrolyzable silyl groups, terminal olefin groups and internal olefin groups) is 0.3 to 0.7.

[0012] Preferably, the terminal structure contains a moiety derived from an epoxy compound having a terminal olefin group, and more preferably, the number of moieties derived from the epoxy compound having a terminal olefin group is greater than 1.0 on average per terminal structure.

[0013] Preferably, the hydrolyzable silyl group is represented by the general formula (1): -(Si(R 1 2-b )(Y′ b )O) m SiR 2 3-a Y a (1) (In the formula, R 1 and R2 are the same or different and represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms, or a triorganosiloxy group represented by (R')3SiO-. R' are the same or different and represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms. Y and Y' are the same or different and represent a hydroxyl group or a hydrolyzable group. a represents 0, 1, 2, or 3. b represents 0, 1, or 2, but when m is 2 or greater, different numbers may coexist as b. m represents an integer from 0 to 19, provided that a + m × b represents an integer of 1 or greater. ) is preferably used. R 1 , R 2 Or, R' represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 3 carbon atoms.

[0014] More preferably, the hydrolyzable silyl group is represented by the general formula (2): -SiR 2 3-a Y a (2) (In the formula, R 2 are the same or different and represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms, or a triorganosiloxy group represented by (R')3SiO-. R' are the same or different and represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms. Y are the same or different and represent a hydroxyl group or a hydrolyzable group. a is 1, 2, or 3.

[0015] More preferably, the hydrolyzable silyl group is a trimethoxysilyl group, a triethoxysilyl group, a tris(2-propenyloxy)silyl group, a triacetoxysilyl group, a methyl dimethoxysilyl group, methyldiethoxysilyl group, dimethoxyethylsilyl group, (chloromethyl)dimethoxysilyl group, (chloromethyl)diethoxysilyl group, (methoxymethyl)dimethoxysilyl group, (methoxymethyl)diethoxysilyl group, (N,N-diethylaminomethyl)dimethoxysilyl group, or (N,N-diethylaminomethyl)diethoxysilyl group.

[0016] Even more preferably, the hydrolyzable silyl group is represented by the general formula (3): -SiR 2 Y2(3) (In the formula, R 2 represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms, or a triorganosiloxy group represented by (R')3SiO-. R's may be the same or different and represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms. Y may be the same or different and represent a hydroxyl group or a hydrolyzable group.

[0017] Preferably, the number of hydrolyzable silyl groups per terminal structure is 0.85 or more on average.

[0018] Preferably, the total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups per terminal structure is 1.1 or more on average, more preferably 1.3 or more on average, and preferably 10 or less on average per terminal structure.

[0019] Preferably, the terminal olefin group is represented by the following general formula (4): H2C=C(R 3 )-CH2- (4) and the internal olefin group is represented by the following general formula (5): H3C-C(R 3 )=CH- (5) In the formulas (4) and (5), R 3 represents hydrogen, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 10 carbon atoms, or a substituted or unsubstituted aralkyl group having 7 to 10 carbon atoms. 3 represents hydrogen or a methyl group.

[0020] Preferably, the ratio (the number of moles of hydrolyzable silyl groups / the total number of moles of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups) is 0.65 or less, more preferably 0.6 or less, even more preferably 0.55 or less, and particularly preferably 0.5 or less. The ratio is preferably 0.35 or more, more preferably 0.4 or more.

[0021] Preferably, the cured product of the polyoxyalkylene polymer (A) has a recovery rate of 90% or more, and preferably, the cured product of the polyoxyalkylene polymer (A) has a stress at 100% elongation of 0.40 MPa or less.

[0022] The present invention also relates to a curable composition containing the polyoxyalkylene polymer (A). The curable composition may further contain a reactive diluent (D), which is a polymer having an average of 0.5 to less than 1.2 hydrolyzable silyl groups per molecule and having a lower viscosity at 23°C than the polyoxyalkylene polymer (A). The curable composition may further contain a (meth)acrylate polymer (B) having a hydrolyzable silyl group.

[0023] The present invention also relates to a cured product of the curable composition. Furthermore, the present invention also relates to uses of the polyoxyalkylene polymer (A) in sealing materials, adhesives, pressure-sensitive adhesives, insulating materials, paints, sealants, or waterproofing materials. [Effects of the Invention]

[0024] According to the present invention, it is possible to provide a hydrolyzable silyl group-containing polyoxyalkylene polymer that can form a cured product having a low modulus and improved recovery, and a curable composition containing the same. DETAILED DESCRIPTION OF THE INVENTION

[0025] Hereinafter, embodiments of the present invention will be described in detail.

[0026] <Polyoxyalkylene polymer (A)> The polyoxyalkylene polymer (A) of the present invention has a polyoxyalkylene main chain structure and a terminal structure bonded to the end of the main chain structure.

[0027] The main chain structure refers to a polymer main chain composed of oxyalkylene repeating units. The main chain structure may be linear or branched. The main chain structure is preferably a polymer main chain composed only of oxyalkylene repeating units, or a polymer main chain that contains, in addition to oxyalkylene repeating units, a structure derived from an initiator used during polymerization and is composed solely of these. Here, the oxyalkylene repeating unit refers to a repeating unit that constitutes a polyether, and is, for example, an oxyalkylene unit having 2 to 6 carbon atoms, preferably 2 to 4 carbon atoms.

[0028] The main chain structure of the polyoxyalkylene is not particularly limited, but examples thereof include polyoxyethylene, polyoxypropylene, polyoxybutylene, polyoxytetramethylene, polyoxyethylene-polyoxypropylene copolymer, polyoxypropylene-polyoxybutylene copolymer, etc. Polyoxypropylene is preferred. As the main chain structure, only one type may be used, or two or more types may be used in combination.

[0029] The terminal structure refers to a portion that does not contain an oxyalkylene repeating unit constituting the main chain structure and is bonded to the end of the main chain structure. When the main chain structure is linear, two terminal structures are present per polymer molecule, and when the main chain structure is branched, three or more terminal structures are present per polymer molecule. When the main chain structure is a mixture of linear and branched chain structures, the number of terminal structures per polymer molecule can be an average of two to three. It is preferable that the terminal structure is bonded to the oxyalkylene unit located at the end of the main chain structure via an oxygen atom.

[0030] The terminal structure of the polyoxyalkylene polymer (A) of the present invention has a hydrolyzable silyl group and either or both of a terminal olefin group and an internal olefin group. This does not refer to the terminal structure of a specific molecule of the polymer, but means that the terminal structure of the entire polymer containing a large number of polymer molecules may have a hydrolyzable silyl group and a terminal olefin group and / or an internal olefin group. That is, the terminal structure of a specific molecule of the polymer may have only a hydrolyzable silyl group and no terminal olefin group or no internal olefin group, or it may have either or both of a terminal olefin group and an internal olefin group but no hydrolyzable silyl group.

[0031] The hydrolyzable silyl group refers to a silyl group that can form a siloxane bond by hydrolysis and dehydration condensation, and bond to each other. The polyoxyalkylene polymer (A) of the present invention exhibits curability based on a dehydration condensation reaction due to the presence of the hydrolyzable silyl group. Specifically, the hydrolyzable silyl group is represented by the following general formula (1): -(Si(R 1 2-b )(Y′ b )O) m SiR 2 3-a Y a (1) In formula (1), R 1 and R 2 are the same or different and have 1 to 20 carbon atoms. or a triorganosiloxy group represented by (R')3SiO-. R' may be the same or different and represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms. Y and Y' may be the same or different and represent a hydroxyl group or a hydrolyzable group. a represents 0, 1, 2, or 3. b represents 0, 1, or 2, provided that when m is 2 or greater, different numbers may coexist as b. m represents an integer from 0 to 19, provided that a + m × b represents an integer of 1 or greater.

[0032] R 1 or R2 In the substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms represented by the formula (I), the number of carbon atoms is preferably 1 to 10, more preferably 1 to 8, even more preferably 1 to 6, still more preferably 1 to 3, and particularly preferably 1 or 2. When the hydrocarbon group has a substituent, the substituent is not particularly limited, and examples thereof include halogen groups such as a chloro group, alkoxy groups such as a methoxy group, and amino groups such as an N,N-diethylamino group.

[0033] R' in the triorganosiloxy group represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms. The number of carbon atoms is preferably 1 to 10, more preferably 1 to 8, even more preferably 1 to 6, even more preferably 1 to 3, and particularly preferably 1 or 2. When the hydrocarbon group has a substituent, the substituent is not particularly limited, and examples thereof include halogen groups such as a chloro group, alkoxy groups such as a methoxy group, and amino groups such as an N,N-diethylamino group. The three R's may be the same or different.

[0034] R 1 and R 2 Examples of the alkyl group include unsubstituted alkyl groups such as methyl, ethyl, n-propyl, isopropyl, n-butyl, tert-butyl, n-hexyl, 2-ethylhexyl, and n-dodecyl; substituted alkyl groups such as chloromethyl, methoxymethyl, and N,N-diethylaminomethyl; unsaturated hydrocarbon groups such as vinyl, isopropenyl, and allyl; cycloalkyl groups such as cyclohexyl; aryl groups such as phenyl, toluyl, and 1-naphthyl; aralkyl groups such as benzyl; and triorganosiloxy groups represented by (R')3SiO- in which R' is a methyl group, phenyl group, or the like. Substituted or unsubstituted alkyl groups are preferred, more preferably methyl, ethyl, chloromethyl, or methoxymethyl, even more preferably methyl or ethyl, and particularly preferably methyl. 1 and R 2 As the alkyl group, only one type of group may be used, or two or more types of groups may be used in combination.

[0035] Examples of Y and Y' include a hydroxyl group, hydrogen, halogen, an alkoxy group, an acyloxy group, a ketoximate group, an amino group, an amide group, an acid amide group, an aminooxy group, a mercapto group, and an alkenyloxy group. The alkoxy group and the like may have a substituent. Because of their mild hydrolysis and ease of handling, an alkoxy group is preferred, a methoxy group, an ethoxy group, an n-propoxy group, and an isopropoxy group are more preferred, a methoxy group and an ethoxy group are even more preferred, and a methoxy group is particularly preferred. As Y and Y', only one type of group may be used, or two or more types of groups may be used in combination.

[0036] As described above, m represents an integer of 0 to 19, and preferably represents 0. When m is 0, the general formula (1) can be expressed by the following general formula (2): -SiR 2 3-a Y a (2) In this general formula (2), a represents 1, 2 or 3.

[0037] Examples of the hydrolyzable silyl group represented by general formula (2) include a trimethoxysilyl group, a triethoxysilyl group, a tris(2-propenyloxy)silyl group, a triacetoxysilyl group, a methyldimethoxysilyl group, a methyldiethoxysilyl group, a dimethoxyethylsilyl group, a (chloromethyl)dimethoxysilyl group, a (chloromethyl)diethoxysilyl group, a (methoxymethyl)dimethoxysilyl group, a (methoxymethyl)diethoxysilyl group, and (N, Examples of such groups include (N-diethylaminomethyl)dimethoxysilyl groups and (N,N-diethylaminomethyl)diethoxysilyl groups. Among these, methyldimethoxysilyl groups, trimethoxysilyl groups, triethoxysilyl groups, (chloromethyl)dimethoxysilyl groups, (methoxymethyl)dimethoxysilyl groups, (methoxymethyl)diethoxysilyl groups, and (N,N-diethylaminomethyl)dimethoxysilyl groups are preferred because they exhibit high reactivity and can produce cured products with good mechanical properties. From the viewpoint of reactivity, trimethoxysilyl groups, (chloromethyl)dimethoxysilyl groups, and (methoxymethyl)dimethoxysilyl groups are more preferred. From the viewpoint of stability, methyldimethoxysilyl groups, methyldiethoxysilyl groups, and triethoxysilyl groups are more preferred, with methyldiethoxysilyl groups and triethoxysilyl groups being even more preferred. Furthermore, trimethoxysilyl groups, triethoxysilyl groups, and methyldimethoxysilyl groups are more preferred because they are easy to produce. Of these, the methyldimethoxysilyl group is most preferred.

[0038] In the general formula (2), in order to achieve both the storage stability and reactivity of the polymer and the flexibility of the cured product, it is preferable that a represents 2. When a is 2, the general formula (2) is represented by the following general formula (3): -SiR 2 Y2(3) In the formula, R 2 and Y are as defined above, provided that in the general formula (1) or (2), two or more types of hydrolyzable silyl groups having different a's may be used in combination.

[0039] The terminal olefin group refers to a carbon-carbon double bond having a methylidene group (HC=), and specifically, a terminal olefin group represented by the following general formula (4): H2C=C(R 3 )-CH2- (4) In equation (4), R 3represents hydrogen, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 10 carbon atoms, or a substituted or unsubstituted aralkyl group having 7 to 10 carbon atoms. The alkyl group preferably has 1 to 8 carbon atoms, more preferably 1 to 6 carbon atoms, even more preferably 1 to 3 carbon atoms, and particularly preferably 1 or 2 carbon atoms. The aryl group preferably has 6 to 8 carbon atoms, more preferably 6 to 7 carbon atoms. The aralkyl group more preferably has 7 to 8 carbon atoms. When the alkyl group, aryl group, or aralkyl group has a substituent, the substituent is not particularly limited, and examples thereof include a halogen group such as a chloro group, an alkoxy group such as a methoxy group, and an amino group such as an N,N-diethylamino group.

[0040] R 3 Examples of the alkyl group include hydrogen, alkyl groups such as methyl, ethyl, propyl, and butyl, aryl groups such as phenyl, and aralkyl groups such as benzyl. 3 As R, hydrogen and an alkyl group are preferred, hydrogen, a methyl group and an ethyl group are more preferred, and hydrogen and a methyl group are even more preferred. 3 may be the same or different from each other.

[0041] The internal olefin group refers to a carbon-carbon double bond that does not have a methylidene group (HC=), and specifically, an internal olefin group represented by the following general formula (5): H3C-C(R 3 )=CH- (5) It can be expressed as: R in Equation (5) 3 is usually R in the formula (4). 3 represents the same group as R 3 Within the scope of the definition of R in formula (4), 3 In addition, multiple R 3 may be the same or different from each other.

[0042] The internal olefin group is a group that can be generated by an internal rearrangement reaction of the terminal olefin group, as described below. 3=H), the internal olefin group produced by this internal rearrangement reaction is a 1-propenyl group.

[0043] The polyoxyalkylene polymer (A) of the present invention has a hydrolyzable silyl group and a terminal olefin group and / or an internal olefin group in its terminal structure, and the total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups is greater than 1.0 on average per terminal structure. As a result, a cured product of the polyoxyalkylene polymer (A) of the present invention can exhibit a lower modulus, given the same amount of hydrolyzable silyl groups introduced, compared to a cured product of a polyoxyalkylene polymer having an average total number of 1.0 or less per terminal structure. The total number is preferably 1.1 or more, more preferably 1.3 or more, and even more preferably 1.5 or more. It is further preferable that the total number is greater than 1.5, particularly preferably 2.0 or more, and most preferably 2.5 or more. While there are no upper limits to the total number, from the viewpoints of economic efficiency and the introduction efficiency of the relevant structure, it is preferably 10 or less, more preferably 8 or less, even more preferably 6 or less, and particularly preferably 5 or less.

[0044] The total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups per terminal structure can also be expressed as the average ratio of the total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups to the number of terminals of the main chain structure, or as the total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups per polymer molecule / the number of terminals of the main chain structure in one polymer molecule.

[0045] In the present invention, the total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups per terminal structure can be appropriately determined by a person skilled in the art. As an example, when the polyoxyalkylene polymer (A) of the present invention is produced by reacting a hydroxyl-terminated polyoxyalkylene polymer (E) with an epoxy compound having a terminal olefin group, and then reacting with an organic halide having a terminal olefin group, as described below, the total number can be calculated by adding the number of equivalents of the epoxy compound relative to the hydroxyl groups in the hydroxyl-terminated polyoxyalkylene polymer (E) (the number of olefin groups introduced by the epoxy compound) plus 1 (the number of olefin groups introduced by the organic halide). In addition ... polyoxyalkylene polymer (A) of the present invention or its precursor intermediate, 1 It can also be calculated by analyzing the iodine value / hydroxyl value by H NMR or titration.

[0046] Furthermore, the polyoxyalkylene polymer (A) of the present invention can form a cured product with improved recovery while maintaining a low modulus by relatively reducing the proportion of hydrolyzable silyl groups relative to the total of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups. That is, in the polyoxyalkylene polymer (A) of the present invention, the ratio of the number of moles of hydrolyzable silyl groups to the total number of moles of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups is, on average, from 0.3 to 0.7. By adjusting this ratio to from 0.3 to 0.7, a cured product containing the polyoxyalkylene polymer (A) of the present invention can achieve both a low modulus and good recovery. To further reduce the modulus of a cured product containing the polyoxyalkylene polymer (A) of the present invention, the ratio is preferably 0.65 or less, more preferably 0.6 or less, even more preferably 0.55 or less, and even more preferably 0.5 or less. In order to further improve the recovery of a cured product containing the polyoxyalkylene polymer (A) of the present invention, the ratio is preferably 0.35 or more, more preferably 0.4 or more. The "molar number of hydrolyzable silyl groups / (total mole number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups)" can also be expressed as the "hydrolyzable silyl group introduction rate." The ratio can also be expressed as a percentage; for example, a ratio of 0.3 and a ratio of 30% have the same meaning.

[0047] In the present invention, the ratio is: 1 For example, when the terminal olefin group is an allyl group, a hydrolyzable silyl group can be introduced into the terminal structure by subjecting a hydrosilane compound having a hydrolyzable silyl group to a hydrosilylation reaction, as described below. In this case, calculation can be performed using the integral values ​​of each signal below. Hydrolyzable silyl group: CH2 (around 0.6 ppm, 2H) bonded to a silyl group Terminal olefin group: Methylidene group CH2 (around 5.2 ppm, 2H) Internal olefin group: CH bonded to terminal CH3 group (total of around 4.3 ppm and around 4.8 ppm, 1H) If other signals overlap, the integral values ​​of those signals are excluded from the calculation.

[0048] The polyoxyalkylene polymer (A) of the present invention has hydrolyzable silyl groups in a range that satisfies both the above-mentioned total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups, and the ratio of the number of moles of hydrolyzable silyl groups to (the total number of moles of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups). The number of hydrolyzable silyl groups per terminal structure is preferably 0.7 or more on average, more preferably 0.85 or more, even more preferably 1.0 or more, and particularly preferably 1.2 or more. This allows the polyoxyalkylene polymer (A) of the present invention to exhibit good curability. The number of hydrolyzable silyl groups per terminal structure can be calculated by multiplying the above-mentioned "total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups per terminal structure" by the above-mentioned "ratio of hydrolyzable silyl groups to the total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups."

[0049] The terminal structure of the polyoxyalkylene polymer (A) of the present invention is not particularly limited as long as it has a hydrolyzable silyl group and a terminal olefin group and / or an internal olefin group. An example of a terminal structure having a hydrolyzable silyl group and a terminal olefin group is a terminal structure represented by the following general formula (6):

[0050] [ka]

[0051] Another example is the following general formula (7):

[0052] [ka]

[0053] The oxygen atom at the left end in general formulas (6) and (7) represents the oxygen atom in the oxyalkylene unit located at the terminal of the main chain structure of the polyoxyalkylene. In general formulas (6) and (7), the hydrolyzable silyl group is represented by the group represented by general formula (2), but the present invention is not limited thereto.

[0054] In general formulas (6) and (7), d and e each represent an integer of 0 or greater, with the sum of d and e being greater than 0 on average per terminal structure. The sum of d and e is preferably 0.1 or greater, more preferably 0.3 or greater, and even more preferably 0.5 or greater. It is also preferably greater than 0.5, particularly preferably 1.0 or greater, and most preferably 1.5 or greater. The sum of d and e is preferably 9 or less, more preferably 7 or less, even more preferably 5 or less, and particularly preferably 4 or less.

[0055] R 2 and R 3 are as described above. There are multiple R 2 or R 3 may be the same or different from each other.

[0056] In general formulas (6) and (7), R 4 represents a direct bond or a divalent organic group having 1 to 6 carbon atoms which may have an oxygen atom. The number of carbon atoms in the organic group is preferably 1 to 4, more preferably 1 or 2, and even more preferably 2. R 4 is preferably a divalent organic group having 1 to 6 carbon atoms which may have an oxygen atom, more preferably -CH2-, -CH2O-, -CH2OCH2-, or -C(=O)-O-CH2-, and even more preferably -CH2OCH2-. 4 may be the same or different from each other.

[0057] In general formulas (6) and (7), R 5 represents a direct bond or a divalent organic group having 1 to 6 carbon atoms which may have an oxygen atom. The number of carbon atoms in the organic group is preferably 1 to 4, more preferably 1 or 2, and even more preferably 1. R 5is preferably a direct bond or a divalent hydrocarbon group having 1 to 6 carbon atoms, more preferably a direct bond, -CH2- or -CH2CH2-, further preferably a direct bond or -CH2-, and particularly preferably -CH2-.

[0058] The terminal structure represented by general formula (6) has (e+1) hydrolyzable silyl groups and d terminal olefin groups. The terminal structure represented by general formula (7) has e hydrolyzable silyl groups and (d+1) terminal olefin groups. The d terminal olefin group-containing units and the e hydrolyzable silyl group-containing units shown in general formula (6) or (7) each correspond to a moiety derived from an epoxy compound having a terminal olefin group, as described below.

[0059] The terminal structure represented by general formula (6) or (7) represents one terminal structure bonded to one end of the polymer main chain. Although multiple hydrolyzable silyl groups and / or terminal olefin groups are shown in formula (6) or (7), each of formula (6) and (7) represents two or more It does not represent a terminal structure of the formula (6) or (7), but represents one terminal structure, and indicates that one terminal structure contains multiple hydrolyzable silyl groups and / or terminal olefin groups. Furthermore, formula (6) or (7) does not represent the oxyalkylene repeating units that constitute the polymer main chain. In other words, the structures in parentheses that exist in the number d or e in formula (6) or (7) do not correspond to the oxyalkylene repeating units that constitute the polymer main chain.

[0060] These general formulas are merely illustrative examples, and the terminal structures in the present invention are not limited to these chemical structures. The terminal olefin groups contained in general formulas (6) and (7) may be internal olefin groups. In particular, some of the multiple terminal olefin groups may be internal olefin groups. The bonding order of d terminal olefin group-containing units and e hydrolyzable silyl group-containing units is not limited to the order shown in general formulas (6) and (7). The specific structural formula of the terminal structure possessed by the polyoxyalkylene polymer (A) of the present invention is not limited to a single one, and usually, various structural formulas can coexist. The terminal structure represented by general formula (6) and the terminal structure represented by general formula (7) may also coexist.

[0061] The number-average molecular weight of the polyoxyalkylene polymer (A) of the present invention is not particularly limited, but is preferably 3,000 to 100,000, more preferably 3,000 to 50,000, and even more preferably 3,000 to 30,000, as measured by GPC in terms of polystyrene. If the number-average molecular weight is less than 3,000, the relative amount of hydrolyzable silyl groups to the entire polymer increases, which may be inconvenient in terms of production costs. If the number-average molecular weight exceeds 100,000, the polymer may become highly viscous, resulting in reduced workability.

[0062] The molecular weight distribution (Mw / Mn) of the polyoxyalkylene polymer (A) of the present invention is not particularly limited, but is preferably narrow. Specifically, it is preferably less than 2.0, more preferably 1.6 or less, even more preferably 1.5 or less, and particularly preferably 1.4 or less. The molecular weight distribution (Mw / Mn) can be calculated from the number average molecular weight and weight average molecular weight determined by GPC measurement.

[0063] The polyoxyalkylene polymer (A) of the present invention preferably has a stress at 100% elongation (100% modulus) of 0.40 MPa or less, more preferably 0.35 MPa or less, in order to maintain the flexibility of the cured product of a curable composition containing the polyoxyalkylene polymer (A) of the present invention. On the other hand, in order to maintain the mechanical properties of the cured product, the stress at 100% elongation of the cured product of the polymer is preferably 0.10 MPa or more, more preferably 0.15 MPa or more. Here, the stress at 100% elongation of the cured product of the polymer is defined as a value measured under the following conditions.

[0064] <Method for measuring stress at 100% elongation of cured polymer> A mixture of polyoxyalkylene polymer / tin(II) octylate / laurylamine / distilled water (weight ratio: 40 / 1.2 / 0.2 / 0.24) was filled into a 3 mm thick sheet mold. After storing at 23°C and 50% relative humidity for at least 1 hour, it was cured in a 70°C dryer for 20 hours to obtain a sheet-like cured product. The resulting cured product is punched into a No. 3 dumbbell-shaped test piece in accordance with JIS K 6251. Using the resulting test piece, a tensile test (tensile speed 200 mm / min) is carried out using an autograph at 23°C and a relative humidity of 50%, and the stress at 100% elongation is measured.

[0065] The polyoxyalkylene polymer (A) of the present invention preferably has a recovery rate of 90% or more after curing, since this increases the recovery rate of the cured product of the curable composition containing the polyoxyalkylene polymer (A) of the present invention. It is defined as the value measured at

[0066] <Method for measuring recovery rate of cured polymer> A mixture of polyoxyalkylene polymer, 3-(N-2-aminoethylamino)propyltrimethoxysilane, tin(II) octoate, laurylamine, and distilled water in a weight ratio of 40:1.2:1.2:0.2:0.32 was filled into a 3 mm thick sheet mold. It was cured at 23°C and 50% relative humidity for 3 days, and then aged in a 50°C dryer for 4 days to obtain a sheet-like cured product. The above cured sheet material is punched into a No. 7 dumbbell shape to obtain a dumbbell-shaped test specimen. Two benchmark lines are drawn 10 mm apart in the necked portion of the dumbbell-shaped test specimen. The dumbbell-shaped test specimen is stretched and fixed so that the gap between the benchmark lines is 15 mm, and then left to stand in a dryer at 50°C. After 5 hours, the test specimen is released from the fixed state, and after 1 hour at 23°C and 50% relative humidity, the gap between the benchmark lines is measured to determine the recovery rate.

[0067] <Method for producing polyoxyalkylene polymer (A)> Next, a method for producing the polyoxyalkylene polymer (A) of the present invention will be described. The polyoxyalkylene polymer (A) of the present invention can be produced by introducing an average of more than 1.0 terminal olefin groups per terminal structure into a hydroxyl-terminated polyoxyalkylene polymer (E) by utilizing the reactivity of the hydroxyl groups, and then reacting the polymer with a hydrolyzable silyl group-containing compound reactive with the terminal olefin groups to introduce the hydrolyzable silyl groups.

[0068] The method for producing the polyoxyalkylene polymer (A) of the present invention will be specifically described below, but is not limited thereto. First, a hydroxyl-terminated polyoxyalkylene polymer (E) is reacted with an epoxy compound (8) having a terminal olefin group, and then with an organic halide (10) having a terminal olefin group, thereby introducing an average of more than 1.0 terminal olefin groups per terminal structure of the polymer. Next, the terminal olefin groups are subjected to a hydrosilylation reaction with a hydrosilane compound (12) having a hydrolyzable silyl group, thereby introducing hydrolyzable silyl groups into the terminal structures, thereby obtaining the polyoxyalkylene polymer (A) of the present invention. In the above production method, the reaction of the terminal structures of the polymer can be represented, for example, by the following reaction formula: In the formula, X represents a halogen and M represents an alkali metal.

[0069] [ka]

[0070] In the present invention, when introducing hydrolyzable silyl groups, instead of reacting all of the reactive terminal olefin groups with the hydrosilane compound, the reaction rate is suppressed so that some of the terminal olefin groups remain unreacted, thereby making it possible to obtain the polyoxyalkylene polymer (A) of the present invention in which the ratio of the number of moles of hydrolyzable silyl groups / (the total number of moles of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups) satisfies the range of 0.3 to 0.7.

[0071] The internal olefin group can be generated as a side reaction during the hydrosilylation reaction by an internal rearrangement reaction (isomerization) of a terminal olefin group. The generated internal olefin group has low hydrosilylation activity and therefore does not react with a hydrosilane compound in the hydrosilylation reaction, and remains in the polyoxyalkylene polymer (A) of the present invention.

[0072] Hereinafter, one embodiment of the method for producing the polyoxyalkylene polymer (A) of the present invention will be described in detail, but the method for producing the polyoxyalkylene polymer (A) of the present invention is not limited thereto.

[0073] (polymerization) The main chain structure of the polyoxyalkylene polymer is formed by a conventionally known method. The hydroxyl-terminated polyoxyalkylene polymer (E) can be formed by polymerizing an epoxy compound with an initiator containing the hydroxyl-terminated polyoxyalkylene polymer (E). Although the specific polymerization method is not particularly limited, a polymerization method using a composite metal cyanide complex catalyst such as zinc hexacyanocobaltate glyme complex is preferred because it can produce a hydroxyl-terminated polymer with a narrow molecular weight distribution (Mw / Mn).

[0074] The initiator having a hydroxyl group is not particularly limited, and examples thereof include organic compounds having one or more hydroxyl groups, such as ethylene glycol, propylene glycol, glycerin, pentaerythritol, low molecular weight polyoxypropylene glycol, low molecular weight polyoxypropylene triol, allyl alcohol, low molecular weight polyoxypropylene monoallyl ether, and low molecular weight polyoxypropylene monoalkyl ether.

[0075] The epoxy compound is not particularly limited, but examples thereof include alkylene oxides such as ethylene oxide and propylene oxide, and glycidyl ethers such as methyl glycidyl ether and butyl glycidyl ether, with propylene oxide being preferred.

[0076] (Introduction of terminal olefin groups) A preferred method for introducing an average of more than 1.0 terminal olefin groups per terminal structure of a polymer is to react an alkali metal salt with a hydroxyl-terminated polyoxyalkylene polymer (E) to convert the terminal hydroxyl groups to alkoxide groups, then react the polymer with an epoxy compound (8) having a terminal olefin group, and then react the polymer with an organic halide (10) having a terminal olefin group. Alternatively, a double metal cyanide complex catalyst can be used instead of the alkali metal salt.

[0077] The alkali metal salt is not particularly limited, but examples thereof include sodium hydroxide, sodium alkoxide, potassium hydroxide, potassium alkoxide, lithium hydroxide, lithium alkoxide, cesium hydroxide, and cesium alkoxide. From the viewpoint of ease of handling and solubility, sodium hydroxide, sodium methoxide, sodium ethoxide, potassium hydroxide, potassium methoxide, and potassium ethoxide are preferred, and sodium methoxide and potassium methoxide are more preferred. From the viewpoint of availability, sodium methoxide is particularly preferred. The alkali metal salt may be subjected to the reaction in a state dissolved in a solvent.

[0078] The amount of the alkali metal salt used is not particularly limited, but the molar ratio relative to the hydroxyl groups of the hydroxyl-terminated polyoxyalkylene polymer (E) is preferably 0.5 or more, more preferably 0.6 or more, even more preferably 0.7 or more, and even more preferably 0.8 or more. The molar ratio is preferably 1.2 or less, more preferably 1.1 or less. If the amount of alkali metal salt used is too small, the reaction may not proceed sufficiently. Conversely, if the amount used is too large, the alkali metal salt may remain as an impurity, which may cause a side reaction.

[0079] The alkali metal salt is used to convert the hydroxyl groups of the hydroxyl-terminated polyoxyalkylene polymer (E) into alkoxide groups, and in order to efficiently proceed with this conversion reaction, it is preferable to remove water and substances having hydroxyl groups other than the polyoxyalkylene polymer from the reaction system in advance. For removal, known methods may be used, such as thermal evaporation, reduced pressure devolatilization, spray evaporation, thin film evaporation, azeotropic devolatilization, etc.

[0080] The temperature for reacting with the alkali metal salt can be appropriately set by those skilled in the art, but is preferably from 50° C. to 150° C., more preferably from 110° C. to 145° C. The time for reacting with the alkali metal salt is preferably from 10 minutes to 5 hours, more preferably from 30 minutes to 3 hours.

[0081] Next, an epoxy compound (8) having a terminal olefin group is subjected to a ring-opening addition reaction with the polyoxyalkylene polymer to form a terminal structure (9) containing a moiety derived from the epoxy compound having a terminal olefin group.

[0082] The epoxy compound having a terminal olefin group can be represented by, but is not limited to, chemical formula (8) in the reaction scheme above. Specific examples of the epoxy compound include allyl glycidyl ether, methallyl glycidyl ether, glycidyl acrylate, glycidyl methacrylate, butadiene monoxide, and 1,4-cyclopentadiene monoepoxide, with allyl glycidyl ether being particularly preferred.

[0083] The amount of the epoxy compound (8) having a terminal olefin group used is not particularly limited and may be appropriately determined taking into consideration the total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups in the terminal structure of the target polymer, as well as the reactivity of the epoxy compound used. Specifically, the molar ratio of the amount of epoxy compound (8) used to the hydroxyl groups in the hydroxyl-terminated polyoxyalkylene polymer (E) is preferably 0.1 or more, more preferably 0.3 or more, and even more preferably 0.5 or more. Furthermore, it is preferably greater than 0.5, particularly preferably 1.0 or more, and most preferably 1.5 or more. Furthermore, the molar ratio is preferably 9 or less, more preferably 7 or less, even more preferably 5 or less, and particularly preferably 4 or less.

[0084] The reaction temperature for the ring-opening addition reaction of the epoxy compound (8) having a terminal olefin group can be appropriately set by those skilled in the art, but is preferably from 60° C. to 150° C., more preferably from 110° C. to 145° C. The reaction time is preferably from 10 minutes to 5 hours, more preferably from 1 hour to 4 hours.

[0085] Next, a polyoxyalkylene polymer having a terminal structure (9) containing a moiety derived from an epoxy compound having a terminal olefin group is reacted with an organic halide (10) having a terminal olefin group to form an ether bond through a halogen substitution reaction, and the alkoxide groups at the polymer terminals are converted to terminal olefin groups, thereby forming terminal structures (11) having an average of more than 1.0 terminal olefin groups per terminal structure.

[0086] The organic halide having a terminal olefin group can be represented by chemical formula (10) in the reaction scheme above, but is not limited thereto. Specific examples of the organic halide include vinyl chloride, allyl chloride, methallyl chloride, vinyl bromide, allyl bromide, methallyl bromide, vinyl iodide, allyl iodide, and methallyl iodide. Allyl chloride and methallyl chloride are preferred for ease of handling.

[0087] The amount of the organic halide (10) having a terminal olefin group to be used is not particularly limited, but the molar ratio relative to the hydroxyl groups of the hydroxyl-terminated polyoxyalkylene polymer (E) is preferably 0.7 or more, more preferably 1.0 or more, and the molar ratio is preferably 5.0 or less, more preferably 2.0 or less.

[0088] The temperature for reacting the organic halide (10) having a terminal olefin group can be appropriately set by those skilled in the art, but is preferably 50° C. to 150° C., more preferably 110° C. to 140° C. The reaction time is preferably 10 minutes to 5 hours, more preferably 20 minutes to 2 hours.

[0089] (Introduction of hydrolyzable silyl groups) The number of terminal olefins per terminal structure obtained by the above method is more than 1.0 on average. A polyoxyalkylene polymer having a terminal structure (11) containing a hydroxyl group is subjected to a hydrosilylation reaction with a hydrosilane compound (12) containing a hydrolyzable silyl group to introduce hydrolyzable silyl groups into some of the terminal olefin groups. During this reaction, the remaining terminal olefin groups remain in the polymer without reacting with the hydrosilane compound (12). Furthermore, as described above, the hydrosilylation reaction may cause some of the terminal olefin groups to be isomerized to internal olefin groups due to a side reaction. In this manner, the polyoxyalkylene polymer (A) of the present invention having a hydrolyzable silyl group and terminal structures (6) and / or (7) containing a terminal olefin group and / or an internal olefin group can be produced. The hydrosilylation reaction has the advantages of being simple to carry out, easy to adjust the amount of hydrolyzable silyl groups introduced, and stable physical properties of the resulting polymer.

[0090] The hydrosilane compound having a hydrolyzable silyl group can be represented by chemical formula (12) in the above reaction scheme, but is not limited thereto. Specific examples of the hydrosilane compound include halogenated silanes such as trichlorosilane, dichloromethylsilane, chlorodimethylsilane, dichlorophenylsilane, (chloromethyl)dichlorosilane, (dichloromethyl)dichlorosilane, bis(chloromethyl)chlorosilane, (methoxymethyl)dichlorosilane, (dimethoxymethyl)dichlorosilane, and bis(methoxymethyl)chlorosilane; trimethoxysilane, triethoxysilane, dimethoxymethylsilane, diethoxymethylsilane, dimethoxyphenylsilane, ethyldimethoxysilane, methoxydimethylsilane, ethoxydimethylsilane, (chloromethyl)methylmethoxysilane, (chloromethyl)dimethoxysilane, (chloromethyl)diethoxysilane, bis(chloromethyl)methoxysilane, (methoxymethyl)methylmethoxysilane, (methoxymethyl)dimethoxysilane, bis(methoxymethyl)methoxysilane, (methoxymethyl)diethoxysilane, (ethoxymethyl)diethoxysilane, and (3,3,3-trifluoropropylsilane. (N,N-diethylaminomethyl)dimethoxysilane, (N,N-diethylaminomethyl)diethoxysilane, [(chloromethyl)dimethoxysilyloxy]dimethylsilane, [(chloromethyl)diethoxysilyloxy]dimethylsilane, [(methoxymethyl)dimethoxysilyloxy]dimethylsilane, [(methoxymethyl)diethoxysilyloxy]dimethylsilane, [(diethylaminomethyl)dimethoxysilyloxy]dimethylsilane, [(3,3,3-trifluoromethyl) alkoxysilanes such as (chloropropyl)dimethoxysilyloxy]dimethylsilane; acyloxysilanes such as diacetoxymethylsilane and diacetoxyphenylsilane; ketoximate silanes such as bis(dimethylketoximate)methylsilane and bis(cyclohexylketoximate)methylsilane; and isopropenyloxysilanes (deacetone type) such as triisopropenyloxysilane, (chloromethyl)diisopropenyloxysilane, and (methoxymethyl)diisopropenyloxysilane.

[0091] The amount of the hydrolyzable silyl group-containing hydrosilane compound (12) used may be appropriately determined taking into consideration the amount of terminal olefin groups in the polyoxyalkylene polymer before the hydrosilylation reaction so that the ratio (molar number of hydrolyzable silyl groups) / (total mole number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups) falls within the range of 0.3 to 0.7. Specifically, the molar ratio of the hydrosilane compound to the terminal olefin groups in the polyoxyalkylene polymer before the hydrosilylation reaction is preferably 0.3 to 0.7.

[0092] The hydrosilylation reaction is preferably carried out in the presence of a hydrosilylation catalyst to promote the reaction. Known hydrosilylation catalysts include metals such as cobalt, nickel, iridium, platinum, palladium, rhodium, and ruthenium, as well as complexes thereof. Specific examples of suitable hydrosilylation catalysts include platinum supported on a support such as alumina, silica, or carbon black; chloroplatinic acid; chloroplatinic acid complexes composed of chloroplatinic acid and alcohols, aldehydes, or ketones; and platinum-olefin complexes [e.g., Pt(CH2=CH2)2(PPh3)]. , Pt(CH2=CH2)2Cl2]; platinum-vinylsiloxane complexes [e.g., Pt{(vinyl)Me2SiOSiMe2(vinyl)}, Pt{Me(vinyl)SiO}4]; platinum-phosphine complexes [e.g., Ph(PPh3)4, Pt(PBu3)4]; platinum-phosphite complexes [e.g., Pt{P(OPh)3}4], etc. From the viewpoint of reaction efficiency, platinum catalysts such as chloroplatinic acid and platinum-vinylsiloxane complexes are preferred.

[0093] The temperature conditions for the hydrosilylation reaction are not particularly limited and can be appropriately determined by those skilled in the art. However, for the purpose of reducing the viscosity of the reaction system and improving reactivity, the reaction is preferably carried out under heated conditions. Specifically, the reaction is more preferably carried out at 50°C to 150°C, and even more preferably at 70°C to 120°C. The reaction time may also be appropriately determined, but it is preferable to adjust the reaction time together with the temperature conditions so as not to cause an unintended condensation reaction of the polymer. Specifically, the reaction time is preferably from 30 minutes to 5 hours, more preferably 3 hours or less.

[0094] The hydrosilylation reaction may also be carried out in the presence of a trialkyl orthocarboxylic acid ester, which can suppress thickening during the hydrosilylation reaction and improve the storage stability of the resulting polymer.

[0095] Examples of the orthocarboxylic acid trialkyl ester include trimethyl orthoformate, triethyl orthoformate, trimethyl orthoacetate, triethyl orthoacetate, etc. Preferred are trimethyl orthoformate and trimethyl orthoacetate.

[0096] When a trialkyl orthocarboxylic acid ester is used, the amount used is not particularly limited, but is preferably about 0.1 to 10 parts by weight, more preferably about 0.1 to 3 parts by weight, per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention.

[0097] <Curable composition> The present invention can provide a curable composition containing the polyoxyalkylene polymer (A).

[0098] (Silanol condensation catalyst) The curable composition of the present invention preferably contains a silanol condensation catalyst for the purpose of promoting the hydrolysis and condensation reaction of the hydrolyzable silyl groups of the polyoxyalkylene polymer (A) of the present invention, that is, the curing reaction.

[0099] As the silanol condensation catalyst, any known catalyst can be used, and specifically, an organic tin compound, a metal carboxylate, an amine compound, a carboxylic acid, an alkoxy metal, an inorganic acid, etc. can be used.

[0100] Specific examples of organotin compounds include dibutyltin dilaurate, dibutyltin dioctanoate, dibutyltin bis(butyl maleate), dibutyltin diacetate, dibutyltin oxide, dibutyltin bis(acetylacetonate), a reaction product of dibutyltin oxide with a silicate compound, a reaction product of dibutyltin oxide with a phthalate ester, dioctyltin diacetate, dioctyltin dilaurate, dioctyltin bis(ethyl maleate), dioctyltin bis(octyl maleate), dioctyltin bis(acetylacetonate), a reaction product of dioctyltin oxide with a silicate compound, etc. In view of the growing concern about the environment in recent years, dioctyltin compounds are preferred.

[0101] Specific examples of metal carboxylates include tin carboxylate, bismuth carboxylate, titanium carboxylate, zirconium carboxylate, iron carboxylate, etc. The carboxylic acid group can be a combination of the following carboxylic acids with various metals.

[0102] Specific examples of the amine compound include amines such as octylamine, 2-ethylhexylamine, laurylamine, and stearylamine; nitrogen-containing heterocyclic compounds such as pyridine, 1,8-diazabicyclo[5,4,0]undecene-7 (DBU), and 1,5-diazabicyclo[4,3,0]nonene-5 (DBN); guanidines such as guanidine, phenylguanidine, and diphenylguanidine; biguanides such as butylbiguanide, 1-o-tolylbiguanide, and 1-phenylbiguanide; amino group-containing silane coupling agents; and ketimine compounds.

[0103] Specific examples of carboxylic acids include acetic acid, propionic acid, butyric acid, 2-ethylhexanoic acid, lauric acid, stearic acid, oleic acid, linoleic acid, neodecanoic acid, and versatic acid.

[0104] Specific examples of alkoxy metals include titanium compounds such as tetrabutyl titanate titanium tetrakis(acetylacetonate) and diisopropoxytitanium bis(ethylacetoacetate), aluminum compounds such as aluminum tris(acetylacetonate) and diisopropoxyaluminum ethylacetoacetate, and zirconium compounds such as zirconium tetrakis(acetylacetonate).

[0105] Other silanol condensation catalysts that can be used include fluorine anion-containing compounds, photoacid generators, and photobase generators.

[0106] The silanol condensation catalyst may be a combination of two or more different catalysts. For example, the combination of the above-mentioned amine compound and carboxylic acid may have the effect of improving reactivity.

[0107] The amount of silanol condensation catalyst is preferably 0.001 to 20 parts by weight, more preferably 0.01 to 15 parts by weight, and particularly preferably 0.01 to 10 parts by weight, per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention. If the amount of silanol condensation catalyst is less than 0.001 part by weight, the reaction rate may be insufficient. On the other hand, if the amount of silanol condensation catalyst is more than 20 parts by weight, the reaction rate is too fast, shortening the usable time of the composition and tending to result in poor workability and poor storage stability. Furthermore, some silanol condensation catalysts may ooze onto the surface of the cured product after the curable composition has cured, or may contaminate the surface of the cured product. In such cases, using 0.01 to 3.0 parts by weight of the silanol condensation catalyst can ensure good curability while maintaining good surface condition of the cured product.

[0108] The curable composition of the present invention preferably further contains a reactive diluent (D), which is a polymer having an average of 0.5 to less than 1.2 hydrolyzable silyl groups per molecule and having a viscosity measured at 23°C lower than that of the polyoxyalkylene polymer (A) of the present invention. In the present invention, the incorporation of such a reactive diluent (D) can reduce the viscosity of the composition and suppress bleed-out while maintaining high recovery. Examples of the main chain skeleton of such a reactive diluent (D) include polyoxyalkylene polymers, saturated hydrocarbon polymers, (meth)acrylic acid ester polymers, and polyorganosiloxane polymers. Among these, polyoxyalkylene polymers are preferred as the main chain skeleton of the reactive diluent (D) from the viewpoint of compatibility with the polyoxyalkylene polymer (A) of the present invention.

[0109] The hydrolyzable silyl groups in the reactive diluent (D) may be located at the molecular chain terminals, side chains, or both. In particular, when the hydrolyzable silyl groups are located at the molecular chain terminals, the molecular weight between crosslinking points increases, making it easier to obtain a rubber-like cured product with good mechanical properties, which is more preferable. The number of hydrolyzable silyl groups per molecule is, on average, 0.5 or more and less than 1.2, but the lower limit is preferably 0.6 or more from the viewpoint of mechanical properties during curing, and is preferably less than 1.0 to efficiently reduce the modulus of the cured product. Furthermore, the reactive diluent (D) may have terminal olefin groups and / or internal olefin groups in addition to hydrolyzable silyl groups, or may have no terminal olefin groups and / or internal olefin groups, but the total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups may be, on average, 1.0 or less per terminal structure.

[0110] The polymer that is the reactive diluent (D) preferably has a number average molecular weight, as measured by GPC and converted into polystyrene, of 3,000 or more and less than 15,000. If the number average molecular weight is less than 3,000, sufficient mechanical properties may not be obtained, and if it is 15,000 or more, the viscosity may become too high and a sufficient dilution effect may not be obtained.

[0111] The molecular weight distribution of the reactive diluent (D) is not particularly limited, but is preferably less than 2.0, more preferably 1.6 or less, and particularly preferably 1.4 or less.

[0112] The main chain structure of the reactive diluent (D) may be a linear or branched structure, or a structure having multiple hydrolyzable silyl groups at one end. Among these, a linear polymer having a hydrolyzable silyl group introduced at only one end is more preferred. Furthermore, the main chain structure does not have to be a single one; each polymer may be produced separately and mixed, or may be produced simultaneously to obtain any desired polymer.

[0113] The hydrolyzable silyl group of the reactive diluent (D) can be selected arbitrarily, but it is preferable that the reactive diluent (D) has the same hydrolyzable silyl group as that of the polyoxyalkylene polymer (A) of the present invention, since this makes it easier to adjust the physical properties of the cured product. In particular, a methyldimethoxysilyl group is preferable.

[0114] The amount of reactive diluent (D) added is preferably 1 part by weight or more and 200 parts by weight or less, and more preferably 10 parts by weight or more and 100 parts by weight or less, per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention. If the amount is less than 1 part by weight, the viscosity-reducing effect of the composition is small, and if the amount is more than 200 parts by weight, the mechanical properties of the cured product tend to deteriorate.

[0115] The curable composition of the present invention preferably further contains a (meth)acrylic acid ester polymer (B) having a hydrolyzable silyl group. By further containing the (meth)acrylic acid ester polymer (B), the weather resistance of the cured product tends to be improved. The position of the hydrolyzable silyl group in the (meth)acrylic acid ester polymer (B) may be at the terminal or in the middle of the polymer main chain.

[0116] The (meth)acrylic acid ester monomer constituting the main chain of the (meth)acrylic acid ester polymer (B) is not particularly limited, and various types can be used. Specifically, methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, tert-butyl (meth)acrylate, n-pentyl (meth)acrylate, n-hexyl (meth)acrylate, cyclohexyl (meth)acrylate, n-heptyl (meth)acrylate, n-octyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, and nonyl (meth)acrylate can be used. Nyl, (meth)acrylate decyl, (meth)acrylate dodecyl, (meth)acrylate phenyl, (meth)acrylate toluyl, (meth)acrylate benzyl, (meth)acrylate 2-methoxyethyl, (meth)acrylate 3-methoxybutyl, (meth)acrylate 2-hydroxyethyl, (meth)acrylate 2-hydroxypropyl, (meth)acrylate stearyl, (meth)acrylate glycidyl, (meth)acrylate (3-trimethoxysilyl)propyl, (meth)acrylate (3-dimethacrylate

[0033] Examples of (meth)acrylic acid monomers include (meth)acrylic acid (2-trimethoxysilyl)propyl, (2-trimethoxysilyl)ethyl (meth)acrylate, (2-dimethoxymethylsilyl)ethyl (meth)acrylate, trimethoxysilylmethyl (meth)acrylate, (dimethoxymethylsilyl)methyl (meth)acrylate, ethylene oxide adducts of (meth)acrylic acid, trifluoromethylmethyl (meth)acrylate, 2-trifluoromethylethyl (meth)acrylate, 2-perfluoroethylethyl (meth)acrylate, 2-perfluoroethyl-2-perfluorobutylethyl (meth)acrylate, perfluoroethyl (meth)acrylate, trifluoromethyl (meth)acrylate, bis(trifluoromethyl)methyl (meth)acrylate, 2-trifluoromethyl-2-perfluoroethylethyl (meth)acrylate, 2-perfluorohexylethyl (meth)acrylate, 2-perfluorodecylethyl (meth)acrylate, and 2-perfluorohexadecylethyl (meth)acrylate.

[0117] Examples of monomer units other than those mentioned above include acrylic acids such as acrylic acid and methacrylic acid; amide groups such as N-methylol acrylamide and N-methylol methacrylamide; epoxy groups such as glycidyl acrylate and glycidyl methacrylate; and monomers containing nitrogen-containing groups such as diethylaminoethyl acrylate and diethylaminoethyl methacrylate.

[0118] The (meth)acrylic acid ester polymer (B) may be a polymer obtained by copolymerizing a (meth)acrylic acid ester monomer with a vinyl monomer copolymerizable therewith. The vinyl monomer is not particularly limited, and examples thereof include styrene monomers such as styrene, vinyltoluene, α-methylstyrene, chlorostyrene, styrenesulfonic acid and its salts; fluorine-containing vinyl monomers such as perfluoroethylene, perfluoropropylene, and vinylidene fluoride; silicon-containing vinyl monomers such as vinyltrimethoxysilane and vinyltriethoxysilane; maleic anhydride, maleic acid, mono- and di-alkyl esters of maleic acid; fumaric acid, mono- and di-alkyl esters of fumaric acid; maleimide, methylmaleimide, ethylmaleimide, propylmaleimide, butylmaleimide, hexylmaleimide, octylmaleimide, dodecylmaleimide, stearylmaleimide, phenylmaleimide, and cyclohexylmaleimide. nitrile group-containing vinyl monomers such as acrylonitrile and methacrylonitrile; amide group-containing vinyl monomers such as acrylamide and methacrylamide; vinyl ester monomers such as vinyl acetate, vinyl propionate, vinyl pivalate, vinyl benzoate, and vinyl cinnamate; alkenyl monomers such as ethylene and propylene; conjugated diene monomers such as butadiene and isoprene; vinyl chloride, vinylidene chloride, allyl chloride, and allyl alcohol, and a plurality of these can also be used as copolymerization components.

[0119] The number of hydrolyzable silyl groups in the (meth)acrylic acid ester polymer (B) is preferably 0.5 to 5.0 on average per molecule, more preferably 1.0 or more from the viewpoint of the mechanical properties of the curable composition when cured, and more preferably 3.0 or less from the viewpoint of the stability of the (meth)acrylic acid ester polymer (B).

[0120] There are no particular limitations on the method for introducing hydrolyzable silyl groups into a (meth)acrylic acid ester polymer, and the following methods can be used, for example: (iv) A method in which a compound having a polymerizable unsaturated group and a hydrolyzable silyl group is copolymerized with the above-mentioned monomer. When this method is used, the hydrolyzable silyl groups tend to be introduced randomly into the main chain of the polymer. (v) A method in which a (meth)acrylic acid ester polymer is polymerized using a mercaptosilane compound having a hydrolyzable silyl group as a chain transfer agent. When this method is used, the hydrolyzable silyl group can be introduced into the polymer terminal. (vi) A method in which a polymerizable unsaturated group and a reactive functional group (V (vii) A method of copolymerizing a compound having a V group (V group) and then reacting the hydrolyzable silyl group with a compound having a functional group reactive with the V group. Specific examples include copolymerizing 2-hydroxyethyl acrylate and then reacting the hydroxyl group with an isocyanate silane having a hydrolyzable silyl group, or copolymerizing glycidyl acrylate and then reacting the epoxy group with an aminosilane compound having a hydrolyzable silyl group. (vii) A method of modifying the terminal functional group of a (meth)acrylic acid ester polymer synthesized by living radical polymerization to introduce a hydrolyzable silyl group. It is easy to introduce a functional group into the polymer terminal of a (meth)acrylic acid ester polymer obtained by living radical polymerization, and by modifying the polymer, it is possible to introduce a hydrolyzable silyl group into the polymer terminal.

[0121] Examples of silicon compounds that can be used to introduce hydrolyzable silyl groups into (meth)acrylic acid ester polymers using the above methods include the following compounds. Compounds having a polymerizable unsaturated group and a hydrolyzable silyl group that can be used in method (iv) include 3-(trimethoxysilyl)propyl (meth)acrylate, 3-(dimethoxymethylsilyl)propyl (meth)acrylate, 3-(triethoxysilyl)propyl (meth)acrylate, (trimethoxysilyl)methyl (meth)acrylate, (dimethoxymethylsilyl)methyl (meth)acrylate, (triethoxysilyl)methyl (meth)acrylate, (diethoxymethylsilyl)methyl (meth)acrylate, and 3-((methoxymethyl)dimethoxysilyl)propyl (meth)acrylate. From the standpoint of availability, 3-trimethoxysilylpropyl (meth)acrylate and 3-(dimethoxymethylsilyl)propyl (meth)acrylate are particularly preferred.

[0122] Examples of the mercaptosilane compound having a hydrolyzable silyl group used in the method (v) include 3-mercaptopropyltrimethoxysilane, 3-mercaptopropyldimethoxymethylsilane, 3-mercaptopropyltriethoxysilane, mercaptomethyltrimethoxysilane, (mercaptomethyl)dimethoxymethylsilane, and mercaptomethyltriethoxysilane.

[0123] Examples of compounds having a hydrolyzable silyl group and a functional group reactive with group V to be used in method (vi) include isocyanate silane compounds such as 3-isocyanatepropyltrimethoxysilane, 3-isocyanatepropyldimethoxymethylsilane, 3-isocyanatepropyltriethoxysilane, isocyanatemethyltrimethoxysilane, isocyanatemethyltriethoxysilane, isocyanatemethyldimethoxymethylsilane, and isocyanatemethyldiethoxymethylsilane; 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropyltriethoxysilane, 3-glycidoxypropyldimethoxymethylsilane, glycidoxymethyltrimethoxysilane, and glycidoxymethyltriethoxysilane; Examples of the epoxy silane compounds include glycidoxymethyldimethoxymethylsilane and glycidoxymethyldiethoxymethylsilane; and aminosilane compounds such as 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3-aminopropyldimethoxymethylsilane, aminomethyltrimethoxysilane, aminomethyltriethoxysilane, aminomethyldimethoxymethylsilane, N-cyclohexylaminomethyltriethoxysilane, N-cyclohexylaminomethyldiethoxymethylsilane, N-phenylaminomethyltrimethoxysilane, N-(2-aminoethyl)aminomethyltrimethoxysilane, and N-(2-aminoethyl)-3-aminopropyltrimethoxysilane.

[0124] In the above method (vii), any modification reaction can be used. For example, there is a method using a compound having a hydrolyzable silyl group and a functional group capable of reacting with the terminal reactive group obtained by polymerization, or a method using a compound having a double bond and a functional group capable of reacting with the terminal reactive group to introduce a double bond into the polymer terminal, and then introducing a hydrolyzable silyl group thereto by hydrosilylation or the like. It can be used.

[0125] These methods may be used in any combination. For example, by combining method (vi) and method (v), a (meth)acrylic acid ester polymer having hydrolyzable silyl groups at both the molecular chain terminals and / or side chains can be obtained.

[0126] The hydrolyzable silyl group contained in the (meth)acrylate polymer (B) is represented by the following general formula (8), similar to the hydrolyzable silyl group contained in the polyoxyalkylene polymer (A) of the present invention: -(Si(R 1 2-b )(Y′ b )O) m SiR 2 3-a Y a (8) It can be expressed as R 1 , R 2 , Y, Y′, a, b, and m are the same as those in the general formula (1). When m is 0, the general formula (8) can be expressed by the following general formula (9): -SiR 2 3-a Y a (9) In this general formula (9), a represents 1, 2, or 3. Specific examples of the hydrolyzable silyl group contained in the (meth)acrylic acid ester polymer (B) include a methyldimethoxysilyl group, a methyldiethoxysilyl group, a trimethoxysilyl group, and a triethoxysilyl group. Furthermore, from the viewpoint of achieving both storage stability and curability of a curable composition containing the (meth)acrylic acid ester polymer (B), a methyldimethoxysilyl group is more preferred, and a trimethoxysilyl group is more preferred since it can enhance the restorability of a cured product of the composition.

[0127] Those skilled in the art generally select the monomer composition of the (meth)acrylic acid ester polymer (B) depending on the application and purpose, but for applications requiring flexibility such as sealants, those with a relatively low glass transition temperature (Tg) are preferred, preferably those with a Tg of -100°C or higher and 100°C or lower, more preferably -60°C or higher and 0°C or lower. Tg can be calculated using the Fox formula below. Fox's formula: 1 / (Tg(K))=Σ(Mi / Tgi) (In the formula, Mi represents the weight fraction of the monomer i component constituting the polymer, and Tgi represents the glass transition temperature (K) of the homopolymer of the monomer i.)

[0128] The number average molecular weight of the (meth)acrylic acid ester polymer (B) is not particularly limited, but is preferably 500 to 100,000, more preferably 1,500 to 50,000, and particularly preferably 5,000 to 30,000, in terms of polystyrene, as measured by GPC.

[0129] Methods of blending a polyoxyalkylene polymer with a (meth)acrylic acid ester polymer have been proposed in JP-A-59-122541, JP-A-63-112642, JP-A-6-172631, JP-A-11-116763, etc. Another method that can be used is to polymerize a (meth)acrylic acid ester monomer in the presence of a polyoxypropylene polymer having a hydrolyzable silyl group. This production method is specifically disclosed in JP-A-59-78223, JP-A-60-228516, JP-A-60-228517, etc. The polyoxyalkylene polymer (A) and (meth)acrylic acid ester polymer (B) of the present invention can also be blended by a similar method, but the blending method is not limited to these.

[0130] The mixing ratio of the polyoxyalkylene polymer (A) and the (meth)acrylic acid ester polymer (B) of the present invention is not particularly limited, but is preferably 95:5 to 10:90 by weight, more preferably 90:10 to 20:80, and particularly preferably 80:20 to 40:60. The polyoxyalkylene polymer (A) and the (meth)acrylic acid ester polymer (B) of the present invention may each be used alone or in combination of two or more.

[0131] (Other additives) The curable composition of the present invention may contain other additives, such as silicon compounds, adhesion promoters, plasticizers, solvents, diluents, silicates, fillers, anti-sagging agents, antioxidants, light stabilizers, UV absorbers, physical property adjusters, tackifier resins, epoxy group-containing compounds, photocurable substances, oxygen-curable substances, surface property improvers, epoxy resins, other resins, flame retardants, and foaming agents. Furthermore, the curable composition of the present invention may contain various additives, as needed, for the purpose of adjusting the physical properties of the curable composition or the cured product. Examples of such additives include curability adjusters, radical inhibitors, metal deactivators, antiozonants, phosphorus-based peroxide decomposers, lubricants, pigments, and mildew inhibitors.

[0132] <Filler> The composition of the present invention can contain various fillers. Examples of fillers include heavy calcium carbonate, colloidal calcium carbonate, magnesium carbonate, diatomaceous earth, clay, talc, titanium oxide, fumed silica, precipitated silica, crystalline silica, fused silica, silicic anhydride, hydrated silicic acid, carbon black, ferric oxide, fine aluminum powder, zinc oxide, activated zinc oxide, PVC powder, PMMA powder, glass fiber, and filament. The above fillers can be used alone or in combination of two or more.

[0133] The amount of the filler used is preferably 1 to 300 parts by weight, particularly preferably 10 to 250 parts by weight, per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention.

[0134] Organic or inorganic balloons may be added to reduce the weight (specific gravity) of the composition. Balloons are spherical fillers with hollow interiors, and examples of materials for these balloons include inorganic materials such as glass, shirasu, and silica, and organic materials such as phenolic resin, urea resin, polystyrene, and saran. The above balloons may be used alone or in combination of two or more types.

[0135] The amount of balloons used is preferably 0.1 to 100 parts by weight, particularly preferably 1 to 20 parts by weight, per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention.

[0136] <Adhesion promoter> The composition of the present invention may contain an adhesion promoter, such as a silane coupling agent or a reaction product of a silane coupling agent.

[0137] Specific examples of the silane coupling agent include amino group-containing silanes such as γ-aminopropyltrimethoxysilane, γ-aminopropylmethyldimethoxysilane, N-β-aminoethyl-γ-aminopropyltrimethoxysilane, N-β-aminoethyl-γ-aminopropylmethyldimethoxysilane, N-phenyl-γ-aminopropyltrimethoxysilane, and (2-aminoethyl)aminomethyltrimethoxysilane; γ-isocyanatepropyltrimethoxysilane, γ-isocyanatepropyltriethoxysilane, and γ-isopropyltriethoxysilane. Examples of suitable adhesives include isocyanate group-containing silanes such as cyanatepropylmethyldimethoxysilane, α-isocyanatemethyltrimethoxysilane, and α-isocyanatemethyldimethoxymethylsilane; mercapto group-containing silanes such as γ-mercaptopropyltrimethoxysilane, γ-mercaptopropyltriethoxysilane, and γ-mercaptopropylmethyldimethoxysilane; and epoxy group-containing silanes such as γ-glycidoxypropyltrimethoxysilane and β-(3,4-epoxycyclohexyl)ethyltrimethoxysilane. Reaction products of various silane coupling agents can also be used. The above adhesion promoters may be used alone or in combination of two or more.

[0138] The amount of the adhesion promoter used is 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention. The amount is preferably 0.1 to 20 parts by weight, and particularly preferably 0.5 to 10 parts by weight, based on the total weight of the compound.

[0139] <Plasticizer> A plasticizer may be added to the composition of the present invention. Specific examples of plasticizers include phthalate ester compounds such as dibutyl phthalate, diisononyl phthalate (DINP), diheptyl phthalate, di(2-ethylhexyl) phthalate, diisodecyl phthalate (DIDP), and butyl benzyl phthalate; terephthalate ester compounds such as bis(2-ethylhexyl)-1,4-benzenedicarboxylate; non-phthalate ester compounds such as 1,2-cyclohexanedicarboxylic acid diisononyl ester; aliphatic polycarboxylic acid ester compounds such as dioctyl adipate, dioctyl sebacate, dibutyl sebacate, diisodecyl succinate, and acetyl tributyl citrate; unsaturated fatty acid ester compounds such as butyl oleate and methyl acetylricinoleate; alkylsulfonic acid phenyl esters; phosphate ester compounds; trimellitic acid ester compounds; chlorinated paraffins; hydrocarbon oils such as alkyl diphenyls and partially hydrogenated terphenyls; process oils; and epoxy plasticizers such as epoxidized soybean oil and epoxy benzyl stearate.

[0140] Polymer plasticizers can also be used. Specific examples of polymer plasticizers include vinyl polymers, polyester plasticizers, polyether polyols such as polyethylene glycol and polypropylene glycol having a number average molecular weight of 500 or more, and polyethers such as derivatives in which the hydroxy groups of these polyether polyols are converted to ester groups, ether groups, etc., polystyrenes, polybutadiene, polybutene, polyisobutylene, butadiene-acrylonitrile, polychloroprene, etc.

[0141] The amount of plasticizer used is preferably 5 to 150 parts by weight, more preferably 10 to 120 parts by weight, and particularly preferably 20 to 100 parts by weight, per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention. If the amount is less than 5 parts by weight, the effect of the plasticizer will not be exhibited, and if it exceeds 150 parts by weight, the mechanical strength of the cured product will be insufficient. The plasticizer may be used alone or in combination of two or more types.

[0142] <Solvents, diluents> A solvent or diluent can be added to the composition of the present invention. The solvent and diluent are not particularly limited, but examples thereof include aliphatic hydrocarbons, aromatic hydrocarbons, alicyclic hydrocarbons, halogenated hydrocarbons, alcohols, esters, ketones, and ethers. When using a solvent or diluent, the boiling point of the solvent is preferably 150°C or higher, more preferably 200°C or higher, and particularly preferably 250°C or higher, in consideration of the problem of air pollution when the composition is used indoors. The above-mentioned solvents or diluents may be used alone or in combination of two or more.

[0143] <Anti-sagging agent> If necessary, an anti-sagging agent may be added to the composition of the present invention to prevent sagging and improve workability. The anti-sagging agent is not particularly limited, but examples thereof include polyamide waxes; hydrogenated castor oil derivatives; and metal soaps such as calcium stearate, aluminum stearate, and barium stearate. These anti-sagging agents may be used alone or in combination of two or more.

[0144] The amount of the anti-sagging agent used is preferably 0.1 to 20 parts by weight based on 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention.

[0145] <Antioxidants> The composition of the present invention may contain an antioxidant (antiaging agent). The use of an antioxidant can improve the weather resistance of the cured product. Examples of antioxidants include hindered phenols, monophenols, bisphenols, and polyphenols. Specific examples of antioxidants are also described in JP-A-4-283259 and JP-A-9-194731.

[0146] The amount of antioxidant used is preferably 0.1 to 10 parts by weight, particularly preferably 0.2 to 5 parts by weight, based on 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention.

[0147] <Light stabilizer> A light stabilizer can be used in the composition of the present invention. The use of a light stabilizer can prevent photooxidative degradation of the cured product. Examples of light stabilizers include benzotriazole-based, hindered amine-based, and benzoate-based compounds, with hindered amine-based compounds being particularly preferred.

[0148] The amount of the light stabilizer used is preferably 0.1 to 10 parts by weight, particularly preferably 0.2 to 5 parts by weight, based on 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention.

[0149] <UV absorber> An ultraviolet absorber can be used in the composition of the present invention. The use of an ultraviolet absorber can improve the surface weather resistance of the cured product. Examples of ultraviolet absorbers include benzophenone-based, benzotriazole-based, salicylate-based, substituted tolyl-based, and metal chelate-based compounds, with benzotriazole-based compounds being particularly preferred, and examples thereof include those commercially available under the names Tinuvin P, Tinuvin 213, Tinuvin 234, Tinuvin 326, Tinuvin 327, Tinuvin 328, Tinuvin 329, and Tinuvin 571 (all manufactured by BASF).

[0150] The amount of the ultraviolet absorber used is preferably 0.1 to 10 parts by weight, particularly preferably 0.2 to 5 parts by weight, based on 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention.

[0151] <Physical property adjusters> The curable composition of the present invention may optionally contain a physical property modifier to adjust the tensile properties of the resulting cured product. The physical property modifier is not particularly limited, but examples include alkylalkoxysilanes such as phenoxytrimethylsilane, methyltrimethoxysilane, dimethyldimethoxysilane, trimethylmethoxysilane, and n-propyltrimethoxysilane; arylalkoxysilanes such as diphenyldimethoxysilane and phenyltrimethoxysilane; alkylisopropenoxysilanes such as dimethyldiisopropenoxysilane, methyltriisopropenoxysilane, and γ-glycidoxypropylmethyldiisopropenoxysilane; trialkylsilylborates such as tris(trimethylsilyl)borate and tris(triethylsilyl)borate; silicone varnishes; and polysiloxanes. The use of such a physical property modifier can increase the hardness of the cured composition of the present invention, or, conversely, decrease the hardness and increase the elongation at break. The physical property modifiers may be used alone or in combination of two or more.

[0152] In particular, compounds that produce a compound having a monovalent silanol group in the molecule upon hydrolysis have the effect of reducing the modulus of the cured product without increasing the stickiness of the surface of the cured product. Compounds that produce trimethylsilanol are particularly preferred. Examples of compounds that produce a compound having a monovalent silanol group in the molecule upon hydrolysis include silicon compounds that are derivatives of alcohols such as hexanol, octanol, phenol, trimethylolpropane, glycerin, pentaerythritol, and sorbitol, and that produce silane monool upon hydrolysis.

[0153] The amount of the physical property adjusting agent used is 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention. The amount is preferably 0.1 to 10 parts by weight, and particularly preferably 0.5 to 5 parts by weight.

[0154] <Tackifying resin> In the present invention, a tackifying resin can be added for the purpose of improving adhesion or adhesion to a substrate or for other reasons. There are no particular limitations on the tackifying resin, and any commonly used resin can be used.

[0155] Specific examples include terpene resins, aromatic modified terpene resins, hydrogenated terpene resins, terpene-phenol resins, phenol resins, modified phenol resins, xylene-phenol resins, cyclopentadiene-phenol resins, coumarone-indene resins, rosin resins, rosin ester resins, hydrogenated rosin ester resins, xylene resins, low-molecular-weight polystyrene resins, styrene copolymer resins, styrene block copolymers and hydrogenated products thereof, petroleum resins (e.g., C5 hydrocarbon resins, C9 hydrocarbon resins, C5C9 hydrocarbon copolymer resins, etc.), hydrogenated petroleum resins, DCPD resins, etc. These may be used alone or in combination of two or more.

[0156] The amount of the tackifier resin used is preferably 2 to 100 parts by weight, more preferably 5 to 50 parts by weight, and even more preferably 5 to 30 parts by weight, per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention. If the amount is less than 2 parts by weight, it is difficult to obtain adhesion and bonding effects to the substrate, and if the amount exceeds 100 parts by weight, the viscosity of the composition becomes too high, which may make it difficult to handle.

[0157] <Compounds containing epoxy groups> A compound containing an epoxy group can be used in the composition of the present invention. The use of a compound having an epoxy group can improve the recovery of the cured product. Examples of compounds having an epoxy group include epoxidized unsaturated fats and oils, epoxidized unsaturated fatty acid esters, alicyclic epoxy compounds, epichlorohydrin derivatives, and mixtures thereof. Specific examples include epoxidized soybean oil, epoxidized linseed oil, bis(2-ethylhexyl)-4,5-epoxycyclohexane-1,2-dicarboxylate (E-PS), epoxy octyl stearate, and epoxy butyl stearate. The epoxy compound is preferably used in an amount of 0.5 to 50 parts by weight per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention.

[0158] <Photocurable substance> A photocurable material can be used in the composition of the present invention. When a photocurable material is used, a film of the photocurable material is formed on the surface of the cured product, improving the stickiness and weather resistance of the cured product. Many compounds of this type are known, including organic monomers, oligomers, resins, and compositions containing them. Representative examples include unsaturated acrylic compounds, which are monomers or oligomers having one or more acrylic or methacrylic unsaturated groups, or mixtures thereof, polyvinyl cinnamates, and azido resins.

[0159] The photocurable substance is preferably used in an amount of 0.1 to 20 parts by weight, more preferably 0.5 to 10 parts by weight, per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention. If the amount is less than 0.1 part by weight, there is no effect of improving weather resistance, and if the amount is more than 20 parts by weight, the cured product becomes too hard and tends to crack.

[0160] <Oxygen curing substance> The composition of the present invention can contain an oxygen-curable substance. Examples of oxygen-curable substances include unsaturated compounds that can react with oxygen in the air, which react with oxygen in the air to form a cured film near the surface of the cured product, thereby preventing surface stickiness and the adhesion of dirt and dust to the surface of the cured product. Specific examples of oxygen-curable substances include drying oils such as tung oil and linseed oil, and various alkyd resins obtained by modifying these compounds; acrylic polymers, epoxy resins, and silicone resins modified with drying oils; butadiene, chloroprene, isoprene, Examples include liquid polymers such as 1,2-polybutadiene and 1,4-polybutadiene obtained by polymerizing or copolymerizing diene compounds such as 1,3-pentadiene, and polymers of C5 to C8 dienes. These may be used alone or in combination of two or more.

[0161] The amount of oxygen-curable substance used is preferably in the range of 0.1 to 20 parts by weight, more preferably 0.5 to 10 parts by weight, per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention. If the amount used is less than 0.1 part by weight, the improvement in stain resistance will be insufficient, while if it exceeds 20 parts by weight, the tensile properties of the cured product will tend to be impaired. As described in JP-A-3-160053, it is recommended that the oxygen-curable substance be used in combination with a photocurable substance.

[0162] <Epoxy resin> The composition of the present invention can be used in combination with an epoxy resin. Compositions containing an epoxy resin are particularly suitable as adhesives, especially adhesives for exterior wall tiles. Examples of epoxy resins include bisphenol A epoxy resins and novolac epoxy resins.

[0163] The ratio by weight of these epoxy resins to the polyoxyalkylene polymer (A) of the present invention is preferably polyoxyalkylene polymer (A) / epoxy resin = 100 / 1 to 1 / 100. If the ratio of polyoxyalkylene polymer (A) / epoxy resin is less than 1 / 100, it becomes difficult to obtain the effect of improving the impact strength and toughness of the cured epoxy resin, and if the ratio of polyoxyalkylene polymer (A) / epoxy resin exceeds 100 / 1, the strength of the cured polymer becomes insufficient.

[0164] When an epoxy resin is added, a curing agent for curing the epoxy resin can be used in combination with the composition of the present invention. There are no particular restrictions on the epoxy resin curing agent that can be used, and any commonly used epoxy resin curing agent can be used.

[0165] When a curing agent for epoxy resin is used, the amount used is preferably in the range of 0.1 to 300 parts by weight per 100 parts by weight of the epoxy resin.

[0166] <<Preparation of Curable Composition>> The curable composition of the present invention can be prepared as a one-component type in which all ingredients are mixed in advance and stored in a sealed container, and then cured by moisture in the air after application, or as a two-component type in which ingredients such as a silanol condensation catalyst, filler, plasticizer, and water are mixed separately as a curing agent, and then the ingredients and the organic polymer composition are mixed before use. From the viewpoint of workability, the one-component type is preferred.

[0167] When the curable composition is a one-component type, all of the components are blended in advance, and therefore it is preferable to dehydrate and dry the components containing water before use, or to dehydrate them by reducing the pressure during blending and kneading. In addition to the dehydration and drying method, the storage stability can be further improved by adding an alkoxysilane compound such as n-propyltrimethoxysilane, vinyltrimethoxysilane, vinylmethyldimethoxysilane, γ-mercaptopropylmethyldimethoxysilane, γ-mercaptopropylmethyldiethoxysilane, or γ-glycidoxypropyltrimethoxysilane.

[0168] The amount of the dehydrating agent, particularly a silicon compound capable of reacting with water such as vinyltrimethoxysilane, to be used is 0.1 to 20 parts by weight per 100 parts by weight of the polyoxyalkylene polymer (A) of the present invention. It is preferably used in the range of 0.5 to 10 parts by weight, more preferably 0.5 to 10 parts by weight.

[0169] <Application> The curable composition of the present invention can be used as a pressure-sensitive adhesive, a sealing material for buildings, ships, automobiles, roads, etc., an adhesive, a waterproofing material, a waterproof coating material, a mold release agent, an anti-vibration material, a vibration-damping material, a sound-proofing material, a foam material, a paint, or a spray material. The cured product obtained by curing the curable composition of the present invention has excellent flexibility and adhesiveness, and therefore can be suitably used as a sealant or adhesive.

[0170] The curable composition of the present invention can also be used in a variety of applications, including electrical and electronic component materials such as a back surface sealant for solar cells, electrical insulating materials for electrical and electronic components such as insulating coating materials for electric wires and cables, acoustic insulating materials, elastic adhesives, binders, contact adhesives, spray sealants, crack repair materials, tiling adhesives, adhesives for asphalt waterproofing materials, powder coatings, casting materials, medical rubber materials, medical pressure sensitive adhesives, medical adhesive sheets, medical device sealants, dental impression materials, food packaging materials, and joint sealants for exterior materials such as sizing boards. These compounds can be used in a wide variety of applications, including coatings, anti-slip coatings, buffer materials, primers, conductive materials for electromagnetic wave shielding, thermally conductive materials, hot melt materials, potting agents for electrical and electronic applications, films, gaskets, concrete reinforcement materials, temporary adhesives, various molding materials, and as anti-rust and waterproof sealants for wired glass and laminated glass edge (cut sections), as well as liquid sealants used in automobile parts, large vehicle parts such as trucks and buses, train parts, aircraft parts, marine parts, electrical components, and various machine parts. For example, in automobiles, they can be used for a wide variety of applications, including adhesive attachment of plastic covers, trim, flanges, bumpers, window mounting, interior components, and exterior components. Furthermore, because they can adhere to a wide range of substrates, such as glass, porcelain, wood, metal, and resin moldings, either alone or with the aid of a primer, they can also be used as various types of sealing and adhesive compositions. The curable composition of the present invention can also be used as an adhesive for interior panels, exterior panels, tile adhesives, stone veneers, ceiling finishes, floor finishes, wall finishes, vehicle panels, electrical, electronic, and precision equipment assembly adhesives, adhesives for bonding leather, textiles, fabrics, paper, boards, and rubber, reactive post-crosslinking pressure-sensitive adhesives, direct glazing sealants, double-glazing sealants, SSG construction sealants, building working joint sealants, civil engineering and bridge materials, and as adhesive materials such as adhesive tapes and sheets. [Example]

[0171] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples.

[0172] Example 1 Using a polyoxypropylene diol with a number-average molecular weight of approximately 3,000 as an initiator, propylene oxide was polymerized in the presence of a zinc hexacyanocobaltate glyme complex catalyst to obtain hydroxyl-terminated polyoxypropylene (E-1) with a number-average molecular weight of 19,000. Subsequently, a methanol solution of 1.0 equivalent of sodium methoxide was added to the hydroxyl groups of this hydroxyl-terminated polyoxypropylene, and the methanol was distilled off at 140°C. 0.3 equivalents of allyl glycidyl ether was added at 140°C and reacted for 2 hours to introduce unsaturated bonds. 1.5 equivalents of 3-chloro-1-propene were then added to convert the terminal hydroxyl groups to allyl groups. Next, 36 ppm of platinum divinyldisiloxane complex (a 3% by mass platinum equivalent isopropyl alcohol solution) and 1.47 parts by weight of methyldimethoxysilane were added to 100 parts by weight of the obtained allyl group-terminated polyoxypropylene, and the mixture was allowed to react at 90°C for 2 hours to determine the total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups per terminal structure (hereinafter referred to as terminal A linear polyoxypropylene (A-1) having methyldimethoxysilyl groups at its terminals was obtained, having a molar ratio (referred to as the total number of groups per terminal structure) of 1.3, a molar ratio of hydrolyzable silyl groups / (total molar ratio of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups) (hereinafter referred to as the hydrolyzable silyl group introduction rate) of 68%, a number of hydrolyzable silyl groups per terminal structure of 0.88, and a number average molecular weight of 19,000.

[0173] Example 2 The same procedure as in Example 1 was followed, except that the amount of allyl glycidyl ether used was 2.0 equivalents and the amount of methyldimethoxysilane used was 1.89 parts by weight, to obtain a linear polyoxypropylene (A-2) having a terminal methyldimethoxysilyl group, with a total number of groups per terminal structure of 3.0, a hydrolyzable silyl group introduction rate of 46%, the number of hydrolyzable silyl groups per terminal structure of 1.38, and a number average molecular weight of 19,000.

[0174] Example 3 The same procedure as in Example 1 was followed, except that the amount of allyl glycidyl ether used was 3.0 equivalents and the amount of methyldimethoxysilane used was 2.23 parts by weight, to obtain a linear polyoxypropylene (A-3) having a terminal methyldimethoxysilyl group, with a total number of groups per terminal structure of 4.0, a hydrolyzable silyl group introduction rate of 42%, the number of hydrolyzable silyl groups per terminal structure of 1.68, and a number average molecular weight of 19,000.

[0175] (Comparative Example 1) The same procedure as in Example 1 was followed, except that allyl glycidyl ether was not used and the amount of methyldimethoxysilane used was 1.31 parts by weight, to obtain a linear polyoxypropylene (C-1) having methyldimethoxysilyl groups at its terminals, with a total number of groups per terminal structure of 1.0, a hydrolyzable silyl group introduction rate of 74%, the number of hydrolyzable silyl groups per terminal structure of 0.74, and a number average molecular weight of 19,000.

[0176] Example 4 Using a polyoxypropylene diol with a number-average molecular weight of approximately 3,000 as an initiator, propylene oxide was polymerized in the presence of a zinc hexacyanocobaltate glyme complex catalyst to obtain hydroxyl-terminated polyoxypropylene (E-2) with a number-average molecular weight of 16,000. Subsequently, a methanol solution of 1.0 equivalent of sodium methoxide was added to the hydroxyl groups of this hydroxyl-terminated polyoxypropylene, and the methanol was distilled off at 140°C. 2.0 equivalents of allyl glycidyl ether was added at 140°C and reacted for 2 hours to introduce unsaturated bonds. 1.5 equivalents of 3-chloro-1-propene was then added to convert the terminal hydroxyl groups to allyl groups. Next, 36 ppm of a platinum divinyldisiloxane complex (a 3% by mass isopropyl alcohol solution in terms of platinum) and 2.02 parts by weight of methyldimethoxysilane were added to 100 parts by weight of the obtained allyl group-terminated polyoxypropylene, and the mixture was allowed to react at 90°C for 2 hours to obtain a linear polyoxypropylene (A-4) having methyldimethoxysilyl groups at its terminals, with a total number of groups per terminal structure of 3.0, a hydrolyzable silyl group introduction rate of 42%, the number of hydrolyzable silyl groups per terminal structure of 1.26, and a number average molecular weight of 16,000.

[0177] Example 5 The same procedure as in Example 4 was followed, except that the amount of methyldimethoxysilane used was 2.29 parts by weight, to obtain a linear polyoxypropylene (A-5) having methyldimethoxysilyl groups at its terminals, with a total number of groups per terminal structure of 3.0, a hydrolyzable silyl group introduction rate of 48%, the number of hydrolyzable silyl groups per terminal structure of 1.44, and a number average molecular weight of 16,000.

[0178] (Comparative Example 2) The same procedure as in Example 4 was followed, except that allyl glycidyl ether was not used and the amount of methyldimethoxysilane used was 1.45 parts by weight, to obtain a linear polyoxypropylene (C-2) having methyldimethoxysilyl groups at its terminals, with a total number of groups per terminal structure of 1.0, a hydrolyzable silyl group introduction rate of 77%, the number of hydrolyzable silyl groups per terminal structure of 0.77, and a number average molecular weight of 16,000.

[0179] Example 6 Using a polyoxypropylene diol with a number-average molecular weight of approximately 3,000 as an initiator, propylene oxide was polymerized with a zinc hexacyanocobaltate glyme complex catalyst to obtain hydroxyl-terminated polyoxypropylene (E-3) with a number-average molecular weight of 28,000. Next, 1.0 equivalent of sodium methoxide in methanol was added to the hydroxyl groups of this hydroxyl-terminated polyoxypropylene, and the methanol was distilled off at 140°C. 1.0 equivalent of allyl glycidyl ether was added at 140°C and reacted for 2 hours to introduce unsaturated bonds. 1.5 equivalents of 3-chloro-1-propene were then added to convert the terminal hydroxyl groups to allyl groups. Next, 36 ppm of a platinum divinyldisiloxane complex (a 3% by mass isopropyl alcohol solution in terms of platinum) and 1.26 parts by weight of methyldimethoxysilane were added to 100 parts by weight of the obtained allyl group-terminated polyoxypropylene, and the mixture was allowed to react at 90°C for 2 hours to obtain a linear polyoxypropylene (A-6) having methyldimethoxysilyl groups at its terminals, with a total number of groups per terminal structure of 2.0, a hydrolyzable silyl group introduction rate of 58%, the number of hydrolyzable silyl groups per terminal structure of 1.16, and a number average molecular weight of 28,000.

[0180] (Comparative Example 3) The same procedure as in Example 6 was followed, except that allyl glycidyl ether was not used and the amount of methyldimethoxysilane used was 0.94 parts by weight, to obtain a linear polyoxypropylene (C-3) having methyldimethoxysilyl groups at its terminals, with a total number of groups per terminal structure of 1.0, a hydrolyzable silyl group introduction rate of 78%, the number of hydrolyzable silyl groups per terminal structure of 0.78, and a number average molecular weight of 28,000.

[0181] Comparative Example 4 The same procedure as in Example 6 was followed, except that the amount of methyldimethoxysilane used was 1.85 parts by weight, to obtain a linear polyoxypropylene (C-4) having methyldimethoxysilyl groups at its terminals, with a total number of groups per terminal structure of 2.0, a hydrolyzable silyl group introduction rate of 80%, a number of hydrolyzable silyl groups per terminal structure of 1.60, and a number average molecular weight of 28,000.

[0182] Example 7 Using polyoxypropylene triol with a number-average molecular weight of approximately 3,000 as an initiator, propylene oxide was polymerized with a zinc hexacyanocobaltate glyme complex catalyst to obtain hydroxyl-terminated polyoxypropylene (E-4) with a number-average molecular weight of 20,000. Next, a methanol solution of 1.0 equivalent of sodium methoxide was added to the hydroxyl groups of this hydroxyl-terminated polyoxypropylene, and the methanol was distilled off at 140°C. 1.6 equivalents of allyl glycidyl ether was added at 140°C and reacted for 2 hours to introduce unsaturated bonds. 1.5 equivalents of 3-chloro-1-propene were then added to convert the terminal hydroxyl groups to allyl groups. Next, 36 ppm of a platinum divinyldisiloxane complex (a 3% by mass isopropyl alcohol solution in terms of platinum) and 1.69 parts by weight of methyldimethoxysilane were added to 100 parts by weight of the obtained allyl group-terminated polyoxypropylene, and the mixture was allowed to react at 90°C for 2 hours to obtain a branched polyoxypropylene (A-7) having methyldimethoxysilyl groups at its terminals, with a total number of groups per terminal structure of 2.6, a hydrolyzable silyl group introduction rate of 38%, the number of hydrolyzable silyl groups per terminal structure of 0.99, and a number average molecular weight of 20,000.

[0183] (Comparative Example 5) The same procedure as in Example 7 was followed, except that allyl glycidyl ether was not used and the amount of methyldimethoxysilane used was 1.22 parts by weight, to obtain a branched polyoxypropylene (C-5) having a terminal methyldimethoxysilyl group, with a total number of groups per terminal structure of 1.0, a hydrolyzable silyl group introduction rate of 61%, a number of hydrolyzable silyl groups per terminal structure of 0.61, and a number average molecular weight of 20,000.

[0184] Example 8 Using a polyoxypropylene diol with a number-average molecular weight of approximately 3,000 as an initiator, propylene oxide was polymerized in the presence of a zinc hexacyanocobaltate glyme complex catalyst to obtain hydroxyl-terminated polyoxypropylene (E-5) with a number-average molecular weight of 21,000. Subsequently, a methanol solution of 1.0 equivalent of sodium methoxide was added to the hydroxyl groups of this hydroxyl-terminated polyoxypropylene, and the methanol was distilled off at 140°C. 2.2 equivalents of allyl glycidyl ether was added at 140°C and reacted for 2 hours to introduce unsaturated bonds. 1.5 equivalents of 3-chloro-1-propene was then added to convert the terminal hydroxyl groups to allyl groups. Next, 36 ppm of a platinum divinyldisiloxane complex (a 3% by mass isopropyl alcohol solution in terms of platinum) and 1.89 parts by weight of methyldimethoxysilane were added to 100 parts by weight of the obtained allyl group-terminated polyoxypropylene, and the mixture was allowed to react at 90°C for 2 hours to obtain a linear polyoxypropylene (A-8) having methyldimethoxysilyl groups at its terminals, with a total number of groups per terminal structure of 3.2, a hydrolyzable silyl group introduction rate of 47%, the number of hydrolyzable silyl groups per terminal structure of 1.50, and a number average molecular weight of 21,000.

[0185] (Comparative Example 6) The same procedure as in Example 8 was followed, except that allyl glycidyl ether was not used and the amount of methyldimethoxysilane used was 1.17 parts by weight, to obtain a linear polyoxypropylene (C-6) having a terminal methyldimethoxysilyl group, with a total number of groups per terminal structure of 1.0, a hydrolyzable silyl group introduction rate of 77%, the number of hydrolyzable silyl groups per terminal structure of 0.77, and a number average molecular weight of 21,000.

[0186] Example 9 The same procedure as in Example 1 was followed, except that the amount of allyl glycidyl ether used was 2.0 equivalents and the amount of methyldimethoxysilane used was 1.69 parts by weight, to obtain a linear polyoxypropylene (A-9) having a terminal methyldimethoxysilyl group, with a total number of groups per terminal structure of 3.0, a hydrolyzable silyl group introduction rate of 41%, the number of hydrolyzable silyl groups per terminal structure of 1.23, and a number average molecular weight of 19,000.

[0187] Example 10 The same procedure as in Example 1 was followed, except that the amount of allyl glycidyl ether used was 2.0 equivalents and the amount of methyldimethoxysilane used was 1.73 parts by weight, to obtain a linear polyoxypropylene (A-10) having a terminal methyldimethoxysilyl group, with a total number of groups per terminal structure of 3.0, a hydrolyzable silyl group introduction rate of 43%, the number of hydrolyzable silyl groups per terminal structure of 1.29, and a number average molecular weight of 19,000.

[0188] Example 11 The same procedure as in Example 1 was followed, except that the amount of allyl glycidyl ether used was 2.0 equivalents and the amount of methyldimethoxysilane used was 2.00 parts by weight, to obtain a linear polyoxypropylene (A-11) having a terminal methyldimethoxysilyl group, with a total number of groups per terminal structure of 3.0, a hydrolyzable silyl group introduction rate of 47%, a number of hydrolyzable silyl groups per terminal structure of 1.41, and a number average molecular weight of 19,000.

[0189] Example 12 The same procedure as in Example 1 was followed, except that the amount of allyl glycidyl ether used was 2.0 equivalents and the amount of methyldimethoxysilane used was 2.10 parts by weight, to obtain a linear polyoxypropylene (A-12) having a terminal methyldimethoxysilyl group, with a total number of groups per terminal structure of 3.0, a hydrolyzable silyl group introduction rate of 49%, the number of hydrolyzable silyl groups per terminal structure of 1.47, and a number average molecular weight of 19,000.

[0190] Example 13 The same procedure as in Example 1 was followed, except that the amount of allyl glycidyl ether used was 2.0 equivalents and the amount of methyldimethoxysilane used was 2.56 parts by weight, to obtain a linear polyoxypropylene (A-13) having a terminal methyldimethoxysilyl group, with a total number of groups per terminal structure of 3.0, a hydrolyzable silyl group introduction rate of 60%, the number of hydrolyzable silyl groups per terminal structure of 1.80, and a number average molecular weight of 19,000.

[0191] (Comparative Example 7) The same procedure as in Example 1 was followed, except that the amount of allyl glycidyl ether used was 2.0 equivalents and the amount of methyldimethoxysilane used was 3.15 parts by weight, to obtain a linear polyoxypropylene (C-7) having a terminal methyldimethoxysilyl group, with a total number of groups per terminal structure of 3.0, a hydrolyzable silyl group introduction rate of 75%, the number of hydrolyzable silyl groups per terminal structure of 2.25, and a number average molecular weight of 19,000.

[0192] (Synthesis Example 1) A four-necked flask equipped with a stirrer was charged with 54.5 parts by weight of isobutyl alcohol and heated to 105°C under a nitrogen atmosphere. A mixed solution of 10.0 parts by weight of methyl methacrylate, 71.5 parts by weight of butyl acrylate, 15.0 parts by weight of stearyl methacrylate, 3.5 parts by weight of 3-(dimethoxymethylsilyl)propyl methacrylate, and 0.5 parts by weight of 2,2'-azobis(2-methylbutyronitrile) dissolved in 10.0 parts by weight of isobutyl alcohol was added dropwise over 5 hours. Polymerization was further carried out at 105°C for 2 hours to obtain an isobutyl alcohol solution (solids content 60% by weight) of poly(meth)acrylate (B-1) having an average of 1.6 methyldimethoxysilyl groups per molecule, a number average molecular weight of 10,500, and a weight average molecular weight of 25,000.

[0193] (Synthesis Example 2) A four-necked flask equipped with a stirrer was charged with 52.1 parts by weight of isobutyl alcohol and heated to 90°C under a nitrogen atmosphere. A mixed solution of 14.5 parts by weight of methyl methacrylate, 68.2 parts by weight of butyl acrylate, 14.9 parts by weight of stearyl methacrylate, 2.4 parts by weight of 3-(dimethoxymethylsilyl)propyl methacrylate, and 0.3 parts by weight of 2,2'-azobis(2-methylbutyronitrile) dissolved in 12.4 parts by weight of isobutyl alcohol was added dropwise over 7 hours. Polymerization was further carried out at 90°C for 2 hours to obtain an isobutyl alcohol solution (solids content 60% by weight) of poly(meth)acrylate (B-2) having an average of 1.8 methyldimethoxysilyl groups per molecule, a number average molecular weight of 17,000, and a weight average molecular weight of 48,000.

[0194] (Synthesis Example 3) A four-necked flask equipped with a stirrer was charged with 54.5 parts by weight of isobutyl alcohol, and the temperature was raised to 105°C under a nitrogen atmosphere. A mixed solution of 10.0 parts by weight of methyl methacrylate, 71.2 parts by weight of butyl acrylate, 15.0 parts by weight of stearyl methacrylate, 3.8 parts by weight of 3-(trimethoxysilyl)propyl methacrylate, and 0.5 parts by weight of 2,2'-azobis(2-methylbutyronitrile) dissolved in 10.0 parts by weight of isobutyl alcohol was added dropwise thereto over 5 hours. Polymerization was further carried out at 105°C for 2 hours, resulting in an average of 1.5 per molecule. An isobutyl alcohol solution (solid content 60 wt %) of poly(meth)acrylic acid ester (B-3) having 1,000 trimethoxysilyl groups and having a number average molecular weight of 9,800 and a weight average molecular weight of 23,000 was obtained.

[0195] (Synthesis Example 4) A four-necked flask equipped with a stirrer was charged with 54.5 parts by weight of isobutyl alcohol and heated to 105°C under a nitrogen atmosphere. A mixed solution of 10.0 parts by weight of methyl methacrylate, 71.7 parts by weight of butyl acrylate, 15.0 parts by weight of stearyl methacrylate, 3.3 parts by weight of 3-(trimethoxysilyl)propyl methacrylate, and 0.5 parts by weight of 2,2'-azobis(2-methylbutyronitrile) dissolved in 10.0 parts by weight of isobutyl alcohol was added dropwise over 5 hours. Polymerization was further carried out at 105°C for 2 hours to obtain an isobutyl alcohol solution (solids content 60% by weight) of poly(meth)acrylate (B-4) having an average of 1.3 trimethoxysilyl groups per molecule, a number average molecular weight of 9,800, and a weight average molecular weight of 23,000.

[0196] Example 14 70 parts by weight of polymer (A-10) obtained in Example 10 and 50 parts by weight of an isobutyl alcohol solution of polymer (B-1) obtained in Synthesis Example 1 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (A-10) / polymer (B-1) weight ratio of 70 / 30. The obtained polymer mixture was used in Example 36.

[0197] Example 15 70 parts by weight of the polymer (A-2) obtained in Example 2 and 50 parts by weight of an isobutyl alcohol solution of the polymer (B-1) obtained in Synthesis Example 1 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (A-2) / polymer (B-1) weight ratio of 70 / 30. The obtained polymer mixture was used in Example 37.

[0198] Example 16 70 parts by weight of polymer (A-10) obtained in Example 10 and 50 parts by weight of an isobutyl alcohol solution of polymer (B-3) obtained in Synthesis Example 3 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (A-10) / polymer (B-3) weight ratio of 70 / 30. The obtained polymer mixture was used in Example 38.

[0199] Example 17 70 parts by weight of polymer (A-2) obtained in Example 2 and 50 parts by weight of an isobutyl alcohol solution of polymer (B-3) obtained in Synthesis Example 3 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (A-2) / polymer (B-3) weight ratio of 70 / 30. The obtained polymer mixture was used in Example 39.

[0200] Example 18 70 parts by weight of polymer (A-10) obtained in Example 10 and 50 parts by weight of an isobutyl alcohol solution of polymer (B-4) obtained in Synthesis Example 4 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (A-10) / polymer (B-4) weight ratio of 70 / 30. The obtained polymer mixture was used in Example 40.

[0201] Example 19 70 parts by weight of polymer (A-2) obtained in Example 2 and 50 parts by weight of an isobutyl alcohol solution of polymer (B-4) obtained in Synthesis Example 4 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (A-2) / polymer (B-4) weight ratio of 70 / 30. The obtained polymer mixture was used in Example 41.

[0202] (Comparative Example 8) 70 parts by weight of the polymer (C-1) obtained in Comparative Example 1 and 50 parts by weight of an isobutyl alcohol solution of the polymer (B-1) obtained in Synthesis Example 1 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (C-1) / polymer (B-1) weight ratio of 70 / 30. The obtained polymer mixture was used in Comparative Example 17.

[0203] Example 20 70 parts by weight of polymer (A-8) obtained in Example 8 and 50 parts by weight of an isobutyl alcohol solution of polymer (B-1) obtained in Synthesis Example 1 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (A-8) / polymer (B-1) weight ratio of 70 / 30. The obtained polymer mixture was used in Example 42.

[0204] Example 21 70 parts by weight of polymer (A-7) obtained in Example 7 and 50 parts by weight of an isobutyl alcohol solution of polymer (B-1) obtained in Synthesis Example 1 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (A-7) / polymer (B-1) weight ratio of 70 / 30. The obtained polymer mixture was used in Example 43.

[0205] Example 22 70 parts by weight of polymer (A-6) obtained in Example 6 and 50 parts by weight of an isobutyl alcohol solution of polymer (B-2) obtained in Synthesis Example 2 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (A-6) / polymer (B-2) weight ratio of 70 / 30. The obtained polymer mixture was used in Example 44.

[0206] (Comparative Example 9) 70 parts by weight of polymer (C-3) obtained in Comparative Example 3 and 50 parts by weight of an isobutyl alcohol solution of polymer (B-2) obtained in Synthesis Example 2 were mixed, and the isobutyl alcohol was distilled off under reduced pressure to obtain a polymer mixture having a polymer (C-3) / polymer (B-2) weight ratio of 70 / 30. The obtained polymer mixture was used in Comparative Example 18.

[0207] (Synthesis Example 5) Using n-butanol as an initiator, propylene oxide was polymerized with a zinc hexacyanocobaltate glyme complex catalyst to obtain polyoxypropylene with a number average molecular weight of 8,000 and a hydroxyl group at one end. Subsequently, a methanol solution of 1.0 equivalent of sodium methoxide was added to the hydroxyl group of this polyoxypropylene with a hydroxyl group at one end, and the methanol was distilled off at 140°C. 1.5 equivalents of 3-chloro-1-propene was added to convert the hydroxyl group at the end to an allyl group. Next, 100 parts by weight of the resulting polyoxypropylene having an allyl group at one end was mixed with 36 ppm of a platinum divinyldisiloxane complex (a 3% by weight isopropyl alcohol solution in terms of platinum) and 1.80 parts by weight of methyldimethoxysilane, and the mixture was allowed to react at 90°C for 2 hours to obtain reactive diluent (D-1), a linear polyoxypropylene polymer having a number-average molecular weight of 8,000 and an average of 0.8 hydrolyzable methyldimethoxysilyl groups per molecule at one end. (D-1) was a polymer that exhibited a lower viscosity at 23°C than the polymers or polymer mixtures obtained in Examples 1 to 22 and Comparative Examples 1 to 9.

[0208] (Examples 23 to 44 and Comparative Examples 10 to 18) The polymers or polymer mixtures produced in Examples 1 to 22 or Comparative Examples 1 to 9 were evaluated as follows.

[0209] <Method for measuring stress or recovery rate at 100% elongation of cured polymer> The stress at 100% elongation or recovery rate of the cured product of each polymer was measured by the above-mentioned measurement method. For the polymer mixtures obtained in Examples 14 to 22 and Comparative Examples 8 and 9, the stress at 100% elongation was measured using the polymer mixtures under the same conditions.

[0210] <Method for evaluating composition properties> Each polymer or polymer mixture was thoroughly mixed with the various additives listed below: filler, titanium oxide, anti-sagging agent, light stabilizer, and UV absorber. The mixture was then passed through a triple-roll mill three times to disperse the mixture and prepare a base resin. A dehydrating agent, adhesion promoter, and silanol condensation catalyst were then added and thoroughly mixed, followed by uniform kneading and degassing using a planetary mixer to prepare each curable composition. Using each of the prepared curable compositions, various test specimens were prepared in a constant temperature and humidity atmosphere of 23°C and 50% relative humidity, and various evaluations were performed.

[0211] (Various additives used in the examples and comparative examples for evaluating the physical properties of the compositions) The following additives were used in evaluating the physical properties of the compositions of Examples 23 to 44 and Comparative Examples 10 to 18. The blending amounts are in parts by weight per 100 parts by weight of each polymer or polymer mixture that is the base polymer. Reactive diluent (D): Reactive diluent (D-1), 76 parts by weight Filler: (i) 120 parts by weight of fatty acid-treated precipitated calcium carbonate (Shiraenka CCR, manufactured by Shiraishi Kogyo Co., Ltd.) (ii) 40 parts by weight of heavy calcium carbonate (Whiten SB Red, manufactured by Shiraishi Calcium Co., Ltd.) Titanium oxide: Typaque R-820, manufactured by Ishihara Sangyo Kaisha, Ltd., 10 parts by weight Anti-sagging agent: fatty acid amide wax (Disparlon #6500, Kusumoto Chemical Co., Ltd.), 2 parts by weight Light stabilizer: bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate (Tinuvin 770, manufactured by BASF), 1 part by weight Ultraviolet absorber: 2-(5-chloro-2H-benzotriazol-2-yl)-4-methyl-6-tert-butylphenol (Tinuvin 326, manufactured by BASF), 1 part by weight Dehydrating agent: vinyltrimethoxysilane (A-171, manufactured by Momentive Co., Ltd.), 2 parts by weight Adhesion promoter: 3-(N-2-aminoethylamino)propyltrimethoxysilane (A-1120, manufactured by Momentive Co., Ltd.), 3 parts by weight Silanol condensation catalyst: dioctyltin dilaurate (U-810, manufactured by Nitto Kasei Co., Ltd.), 2 parts by weight

[0212] (Dumbbell properties) The curable composition was filled into a 3 mm thick sheet mold at 23°C and 50% relative humidity. After curing for 3 days at 23°C and 50% relative humidity, the composition was aged in a dryer at 50°C for 4 days to obtain a sheet-like cured product. The resulting cured product was punched into a No. 3 dumbbell-shaped test piece according to JIS K 6251. Using the resulting test piece, a tensile test (tensile speed: 200 mm / min) was performed using an autograph at 23°C and 50% relative humidity to measure the stress at 50% elongation, stress at 100% elongation, stress at break, and elongation at break.

[0213] (Resilience) The above-mentioned sheet-like cured product was punched into a No. 7 dumbbell shape to obtain a dumbbell-shaped test specimen. Two benchmark lines were drawn 20 mm apart, centered on the necked portion of the dumbbell-shaped test specimen. The dumbbell-shaped test specimen was fixed in an elongated state so that the distance between the benchmark lines was 40 mm, and then left to stand in a dryer at 50°C. After 24 hours, the test specimen was released from the fixing position, and the distance between the benchmark lines was measured at 23°C and 50% relative humidity to determine the recovery rate.

[0214] The results obtained above are shown in Tables 1 to 8. Table 1 shows the results for polymers (A-1), (A-2), (A-3), and (C-1) synthesized using hydroxyl-terminated polyoxypropylene (E-1) as a raw material. Similarly, Table 2 shows the results for each polymer synthesized using hydroxyl-terminated polyoxypropylene (E-2) as a raw material. Table 3 shows the results for each polymer synthesized using hydroxyl-terminated polyoxypropylene (E-3) as a raw material. Table 4 shows the results for each polymer synthesized using hydroxyl-terminated polyoxypropylene (E-4) as a raw material. Table 5 shows the results for each polymer synthesized using hydroxyl-terminated polyoxypropylene (E-5) as a raw material. Furthermore, Table 6 shows the results for each polymer synthesized using hydroxyl-terminated polyoxypropylene (E-1) as a raw material and having a total number of groups per terminal structure of 3.0.

[0215] Table 7 shows the results of an embodiment in which the polyoxyalkylene polymer (A) of the present invention or the polyoxyalkylene polymer (C) not satisfying the requirements of the present invention, which were synthesized using hydroxyl-terminated polyoxypropylene (E-1) as a raw material, was used in combination with the (meth)acrylic acid ester polymer (B). Table 8 shows the results of an embodiment in which the polyoxyalkylene polymer (A) of the present invention or the polyoxyalkylene polymer (C) not satisfying the requirements of the present invention, which were synthesized using a raw material other than hydroxyl-terminated polyoxypropylene (E-1), was used in combination with the (meth)acrylic acid ester polymer (B).

[0216] [Table 1]

[0217] [Table 2]

[0218] [Table 3]

[0219] [Table 4]

[0220] [Table 5]

[0221] [Table 6]

[0222] [Table 7]

[0223] [Table 8]

[0224] The results shown in each table reveal that the cured products of the compositions of each Example containing the polyoxyalkylene polymer (A) of the present invention exhibit high recovery despite having a similarly low modulus compared to the cured products of the compositions of Comparative Examples 10 to 12, 14, 15, 17, and 18 containing the polyoxyalkylene polymer (C) which has an equivalent main chain structure but does not satisfy the requirements of the present invention because the total number of groups per terminal structure is 1.0. Furthermore, no significant differences were observed in the dumbbell properties.

[0225] On the other hand, the compositions of Comparative Examples 13 and 16, which contain polyoxyalkylene polymer (C) that does not satisfy the requirements of the present invention because the introduction rate of hydrolyzable silyl groups exceeds 70% although the total number of groups per terminal structure exceeds 1.0, show that although the cured product exhibits high recovery, the modulus of the cured product is too high, and therefore, are not suitable as sealants.

[0226] From the above results, it can be seen that the polyoxyalkylene polymer (A) of the present invention can be suitably used as a base polymer for a highly resilient sealant that is less likely to bleed out, since the cured product of the curable composition containing the polyoxyalkylene polymer (A) exhibits low modulus but high resilience and other physical properties are equivalent to those of existing products.

Claims

1. A polyoxyalkylene polymer having a polyoxyalkylene main chain structure and a terminal structure bonded to an end of the main chain structure, the terminal structure has a hydrolyzable silyl group and a terminal olefin group and / or an internal olefin group, the total number of hydrolyzable silyl groups, terminal olefin groups and internal olefin groups is more than 1.0 on average per terminal structure, The polyoxyalkylene polymer (A) has a molar ratio of hydrolyzable silyl groups in the polyoxyalkylene polymer to the total molar ratio of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups of 0.3 to 0.

5.

2. A polyoxyalkylene polymer having a polyoxyalkylene main chain structure and a terminal structure bonded to an end of the main chain structure, the terminal structure has a hydrolyzable silyl group and a terminal olefin group and / or an internal olefin group, the total number of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups is 2.5 or more on average per terminal structure, The polyoxyalkylene polymer (A) has a molar ratio of hydrolyzable silyl groups in the polyoxyalkylene polymer to the total molar ratio of hydrolyzable silyl groups, terminal olefin groups, and internal olefin groups of 0.3 to 0.

7.

3. The polyoxyalkylene polymer (A) according to claim 1 or 2, wherein the terminal structure includes a moiety derived from an epoxy compound having a terminal olefin group.

4. The polyoxyalkylene polymer (A) according to claim 3, wherein the number of moieties derived from the epoxy compound having a terminal olefin group is more than 1.0 on average per terminal structure.

5. The hydrolyzable silyl group is represented by the general formula (3): -SiR ２ Y ２ (3) (In the formula, R ２ is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms, or (R') ３ represents a triorganosiloxy group represented by SiO—; R′ may be the same or different and represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms; and Y may be the same or different and represent a hydroxyl group or a hydrolyzable group. The polyoxyalkylene polymer (A) according to any one of claims 1 to 4, represented by:

6. The polyoxyalkylene polymer (A) according to any one of claims 1 to 5, wherein the number of the hydrolyzable silyl groups per terminal structure is 0.85 or more on average.

7. The polyoxyalkylene polymer (A) according to any one of claims 1 to 6, wherein the polyoxyalkylene polymer (A) has a recovery rate of 90% or more after curing.

8. The polyoxyalkylene polymer (A) according to any one of claims 1 to 7, wherein a stress at 100% elongation of a cured product of the polyoxyalkylene polymer (A) is 0.40 MPa or less.

9. A curable composition comprising the polyoxyalkylene polymer (A) according to any one of claims 1 to 8.

10. 10. The curable composition according to claim 9, further comprising a reactive diluent (D) which is a polymer having an average of 0.5 to less than 1.2 hydrolyzable silyl groups per molecule and having a viscosity at 23°C lower than that of the polyoxyalkylene polymer (A).

11. The curable composition according to claim 9 or 10, further comprising a (meth)acrylic acid ester polymer (B) having a hydrolyzable silyl group.

12. A cured product of the curable composition according to any one of claims 9 to 11.

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