Process and plant for producing a synthesis product
By storing a reaction mixture instead of hydrogen alone and using existing syngas compressors, the process reduces environmental impact and production costs, addressing the challenges of carbon dioxide emissions and suboptimal hydrogen storage in existing technologies.
Patent Information
- Application Number
- PCT/EP2024/082833
- Authority / Receiving Office
- WO · WO
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2023-11-29
- Filing Date
- 2024-11-19
- Publication Date
- 2025-06-05
AI Technical Summary
Existing processes for producing hydrogen-based synthetic products, such as ammonia and methanol, often result in the release of carbon dioxide into the atmosphere, leading to environmental concerns. Additionally, the storage of hydrogen requires additional equipment and operates at suboptimal conditions, increasing costs.
The proposed process involves producing hydrogen through electrolysis using renewable electricity and mixing it with other gaseous reactants to form a reaction mixture. This mixture is stored under pressure instead of hydrogen alone, allowing the existing syngas compressor to be used, thereby reducing investment and operating costs. The reaction mixture is then fed to a synthesis reactor to produce the desired synthesis product.
This approach reduces the environmental impact by minimizing carbon dioxide emissions and lowers production costs by optimizing the use of existing compressor equipment, ensuring more frequent operation at optimal conditions.
Smart Images

Figure EP2024082833_05062025_PF_FP_ABST
Abstract
Description
[0001] Description
[0002] Process and plant for the production of a synthesis product
[0003] The invention relates to a process and a plant for producing a synthesis product, for example ammonia, synthetic methane or methanol.
[0004] background
[0005] Hydrogen must be supplied for the production of hydrogen-based synthetic products, such as ammonia from hydrogen and nitrogen, synthetic natural gas (SNG), or methanol from hydrogen and carbon monoxide. Hydrogen is traditionally produced by converting carbonaceous feedstocks, e.g., using steam reforming, partial oxidation, autothermal reforming, or a combination of these processes. These processes produce carbon dioxide, which is separated from a product mixture of the aforementioned processes, for example, using a known chemical or physical scrubbing process or pressure swing adsorption.
[0006] If the separated carbon dioxide is not required in a subsequent process, such as the production of the aforementioned compounds, it is conventionally released into the atmosphere. In this case, it is also referred to as so-called gray products, i.e., gray hydrogen, gray ammonia, gray synthetic methane, gray methanol, and the like.
[0007] Recently, the extraction of so-called blue products has gained importance. The aim here is to avoid the release of carbon dioxide into the atmosphere as much as possible through suitable process steps. After its separation, the carbon dioxide is typically compressed, purified, and then liquefied before being permanently stored, for example, in a storage facility. This is also referred to as sequestration. Processes for the extraction of so-called green hydrogen and corresponding synthesis products are also increasingly being used. This differs from the aforementioned processes in particular in that the formation of carbon dioxide is avoided from the outset.For this purpose, hydrogen can be produced in particular by electrolysis of water using electricity generated from renewable sources, whereby “renewable electricity” is a short term for electrical power generated using suitable renewable energy sources such as wind, sun and / or water.
[0008] As is well known, the generation of renewable electricity is subject to price and availability fluctuations resulting from the energy sources used. Therefore, the aim is to adapt the energy requirements of processes for the production of synthesis products to the availability of electricity. When producing synthesis products from hydrogen generated by electrolysis of water using renewable electricity, the hydrogen can be temporarily stored during phases of high electricity availability and used to produce the synthesis products during other phases.
[0009] There is a need for processes for the production of synthetic products that at least partially overcome the disadvantages of known processes.
[0010] overview
[0011] A method and a system having the features of the independent claims are proposed. Further embodiments are the subject of the dependent claims and the following description.
[0012] The proposed process for producing a synthesis product comprises providing gaseous hydrogen by electrolysis of water and subjecting it to a reaction with one or more gaseous reactants to form the synthesis product.
[0013] It is provided that during a first process mode, the hydrogen and the one or more reactants are mixed to obtain a gaseous reaction mixture and the reaction mixture or a part thereof is stored under pressure in a storage unit, and that during a second process mode, the gaseous reaction mixture stored under pressure in the first process mode or a part thereof is removed from the storage unit and fed to the conversion to the synthesis product.
[0014] It is known from the state of the art to temporarily store hydrogen in the production of synthesis products using hydrogen generated by electrolysis using renewable electricity in order to use it to bridge periods of wind or solar lulls and to ensure a continuous supply of the synthesis products.
[0015] The designs proposed here are based on the surprising finding that, instead of intermediate storage of hydrogen, storage of a reaction mixture, for example of three molar proportions of hydrogen and one molar proportion of nitrogen in the case of ammonia synthesis, is advantageous, despite the larger storage volume to be expected.
[0016] To temporarily store hydrogen from electrolysis as high-purity hydrogen, conventional processes require a separate hydrogen compressor that compresses hydrogen into a storage unit during periods of high power availability. Depending on the hydrogen surplus, the hydrogen compressor is usually only operated at partial load and rarely at its optimal operating point. Furthermore, the type of compressor (piston compressor) requires redundancy to fill the hydrogen buffer.
[0017] If a suitable reaction mixture is already temporarily stored instead of hydrogen, the existing synthesis gas compressor can be used, for example, for ammonia synthesis. No additional equipment is required to operate the "synthesis gas storage," which leads to lower investment costs. Since the synthesis gas compressor is used both for ammonia synthesis and for filling the synthesis gas storage, it is operated more frequently at the optimal operating point and thus has lower operating costs. The same applies to other process products. The invention also provides for the use of an existing compressor used for compressing a reaction mixture, such as an ammonia synthesis gas compressor, to fill a storage unit, so that no additional investment costs are incurred.Since a corresponding compressor, also referred to here as a “compressor unit,” is used both to fill the storage unit and to feed the synthesis reactor used in the process, the compressor is operated more frequently at its optimal operating point, which leads to savings in operating costs.
[0018] In certain embodiments, in a third process mode, the gaseous hydrogen can be provided by the electrolysis of water and subjected to a reaction with the one or more gaseous reactants to form the synthesis product. The hydrogen and the one or more reactants are mixed to obtain the reaction mixture, and the reaction mixture or a portion thereof is fed to the reaction to form the synthesis product, bypassing the storage unit. This operating mode can be carried out in particular when the storage unit is filled and electrical energy is still available to provide the hydrogen.
[0019] In certain embodiments, in the first process mode, the reaction mixture or its temporarily stored portion can be compressed to a storage pressure level prior to temporary storage, and in the second process mode, the reaction mixture temporarily stored in the first process mode can be removed from the storage unit at the storage pressure level and compressed to a conversion pressure level before being fed to the conversion to form the synthesis product. The conversion pressure level is above the storage pressure level. Compression is therefore also carried out in the second process mode, so that the compression unit is correspondingly utilized and storage can take place at a pressure level below the conversion pressure level. The latter allows for a simpler structural implementation of the storage unit, particularly with lower material costs.
[0020] In certain embodiments, compression to the storage pressure level and the conversion pressure level can be carried out using a multi-stage compressor unit, which offers corresponding removal and return options for material flows and a high degree of flexibility.
[0021] In certain embodiments, in the first process mode, the reaction mixture or its pressure-stored portion can be supplied to the compressor unit on the suction side and removed via an intermediate removal point at the storage pressure level. In the second process mode, the reaction mixture stored under pressure in the first process mode can be supplied to the compressor unit on the suction side and removed on the pressure side at the conversion pressure level. In this way, a corresponding reaction mixture can be easily provided at different pressure levels.
[0022] In certain embodiments, the storage pressure level can be between 135 and 145 bar, for example approximately 140 bar, and the conversion pressure level can be between 145 and 155 bar, for example approximately 150 bar. The storage pressure level can also be between 30 and 210 bar, in particular between 70 and 150 bar, and the conversion pressure level can be between 100 and 250 bar, in particular between 115 and 180 bar. In general, the storage and conversion pressure levels differ by at least 5 bar. Particularly in the case of ammonia synthesis, the conversion pressure level can be 5 to 15, 8 to 12, 9 to 11, or approximately 10 bar above the storage pressure level. In general, the storage pressure level can be between a suction pressure of the compressor unit and an intermediate pressure at which extraction takes place. In a piston compressor, the conversion pressure level can be 200 bar and more.
[0023] In certain embodiments, components of the reaction mixture that have not been converted in the synthesis reactor can be fed back to the compressor unit as a recycle stream via an intermediate feed. This is the case, for example, in ammonia synthesis, where the recycle stream consists of hydrogen and / or nitrogen that has not been converted in the synthesis reactor.
[0024] The compressor unit preferably comprises a radial and / or axial turbocompressor and / or a piston compressor. In certain embodiments, the compressor unit can be a radial compressor unit and have four compressor stages, whereby the intermediate extraction can be provided between the third and fourth compressor stages, viewed from the suction side. In such an embodiment, the different pressure levels, in particular, can be implemented particularly easily.
[0025] In certain embodiments, the mixing to form the reaction mixture can be carried out using a mixing drum and / or monitored using a density measuring unit arranged on the suction side of the compressor unit. In this way, safe operation of the compressor unit and the conversion to the process product can be ensured at all times.
[0026] In certain embodiments, the electrolysis can be carried out using renewably generated electricity. For the advantages of using the embodiments proposed here, please refer to the explanations above.
[0027] In certain embodiments, the first operating mode can be performed during a period of higher power availability, and the second operating mode can be performed during a period of lower power availability. The first operating mode can also be performed during a period of lower power costs, and the second operating mode can be performed during a period of higher power costs. In this way, resources can be conserved and production costs minimized.
[0028] In certain embodiments, the synthesis product can be ammonia and the hydrogen reactant can be nitrogen. However, embodiments of the process are also suitable for cases in which the synthesis product is synthetic methane or methanol and the reactant(s) is / are carbon dioxide and / or carbon monoxide. In methanol synthesis, the reaction mixture contains, for example, one mole of carbon monoxide and two moles of hydrogen gas, or one mole of carbon dioxide and three moles of hydrogen gas, or combinations thereof. In the synthesis of synthetic methane, the reaction mixture contains, for example, one mole of carbon monoxide and three moles of hydrogen gas, or one mole of carbon dioxide and four moles of hydrogen gas, or combinations thereof.The proposed plant for producing a synthesis product is designed to provide gaseous hydrogen by electrolysis of water and to subject it to a reaction with one or more gaseous reactants to form the synthesis product.
[0029] The proposed plant is further configured to mix the hydrogen and the one or more reactants to obtain a reaction mixture during a first process mode and to pressure-store the reaction mixture or a portion thereof in a storage unit, and to remove the reaction mixture or a portion thereof pressure-stored in the first process mode from the storage unit during a second process mode and to feed it to a synthesis reactor for conversion to the synthesis product.
[0030] For further features and advantages of a corresponding system and embodiments thereof, reference is expressly made to the above explanations concerning the method proposed according to the invention and its embodiments, since these apply equally to this.
[0031] The same applies to a system which, according to an embodiment of the invention, is designed to carry out a method according to any embodiment of the present invention.
[0032] Drawings
[0033] Embodiments of the invention are described below purely by way of example with reference to the accompanying drawings, in which
[0034] Figure 1 schematically illustrates a method according to an embodiment in a first method mode, and
[0035] Figure 2 schematically illustrates the method according to Figure 1 in a second method mode. Embodiments
[0036] The embodiments described below are described solely for the purpose of assisting the reader in understanding the claimed and previously discussed features. They are merely representative examples and are not intended to be exhaustive and / or limiting with regard to the features of the invention. It is to be understood that the advantages, embodiments, examples, functions, features, structures, and / or other aspects described above and below are not to be considered as limitations on the scope of the invention as defined in the claims or as limitations on equivalents to the claims, and that other embodiments may be utilized and changes may be made without departing from the scope of the claimed invention.
[0037] Different embodiments of the invention may include, comprise, consist of, or consist essentially of other useful combinations of the described elements, components, features, parts, steps, means, etc., even if such combinations are not specifically described herein. Furthermore, the disclosure may encompass other inventions that are not currently claimed but that may be claimed in the future, particularly if they are encompassed within the scope of the independent claims.
[0038] Explanations relating to devices, apparatus, arrangements, systems, etc. according to embodiments of the present invention may also apply to methods, processes, methods, etc. according to the embodiments of the present invention, and vice versa. Elements, method steps, etc. that are identical, have the same effect, are functionally equivalent, are structurally identical, or are comparable may be identified by identical reference numerals.
[0039] The present invention and embodiments thereof are explained below with reference to electrolysis with a proton exchange membrane. However, as mentioned several times, the invention is not limited thereto. The following explanations and definitions, which relate to some of the principles of the invention, can apply to all or part of the embodiments presented here, and the explanation of certain aspects in connection with only part or one of the embodiments should not be understood to mean that these aspects cannot also be realized with other or all embodiments, as far as technically possible and reasonable.
[0040] Hydrogen production processes are widely described in the literature. Among many others, reference is made to the article by AO Oni et al., "Comparative assessment of blue hydrogen from steam methane reforming, autothermal reforming, and natural gas decomposition technologies for natural gas-producing regions," Energy Conversion and Management 254 (2022) 115245, which shows such processes in Figures 2 to 4 and describes them in the corresponding text passages.
[0041] The production of hydrogen by water electrolysis is also well known and is described, for example, in the article “Hydrogen” in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, June 15, 2000, DOI: 10.1002 / 14356007.a13_297, particularly in Section 4.2, “Electrolysis”.
[0042] In conventional water electrolysis, an aqueous alkaline solution, typically potassium hydroxide, is used as the electrolyte (AEL, alkaline electrolysis). Electrolysis with a unipolar or bipolar electrode arrangement takes place at atmospheric pressure, or on an industrial scale, significantly higher. Recent developments in water electrolysis include the use of proton-conducting ion exchange membranes (SPE, Solid Polymer Electrolysis; PEM, Proton Exchange Membranes), in which the water to be electrolyzed is provided at the anode side. Electrolysis using anion exchange membranes (AEM, Anion Exchange Membranes) is also known.
[0043] The water electrolysis processes mentioned so far are low-temperature processes in which the water to be electrolyzed is in the liquid phase. Steam electrolysis is also used, which can also be carried out with alkaline electrolytes (i.e., AEL) with adapted membranes, such as polysulfone membranes, or using solid oxide electrolysis cells (SOECs). The latter include, in particular, doped zirconium dioxide or oxides of other rare earths, which become more conductive at high temperatures. The term "electrolysis" will be used below to encompass all of these processes. Low-temperature electrolysis (PEM, AEL, AEM) is particularly suitable for flexible operation, supporting the energy transition to renewable energies. All processes can be used in the processes and corresponding configurations proposed here.
[0044] Ammonia production has been described in many places, for example, in M. Appl, "Ammonia: Principles and Industrial Practice," Wiley-VCH, 1999. Typically, variants of the Haber-Bosch process are used. The ammonia produced is typically stored at atmospheric pressure and a temperature of -33°C. To generate the ammonia as a liquid product under these conditions, a refrigeration system is typically used for condensation and purification of the ammonia.
[0045] A “compressor” or a “compressor unit” as understood here is a device which is designed to compress at least one gaseous stream from at least one inlet pressure at which it is supplied to the compressor or the compressor unit to at least one final pressure at which it is removed from the compressor or the compressor unit.
[0046] A compressor or compressor unit can form an integrated structural unit, which can, however, have multiple "compressor stages" in the form of piston, screw, and / or impeller or turbine arrangements (i.e., axial or radial compressor stages). In particular, corresponding compressor stages are driven by a common drive, for example, via a common shaft or via multiple shafts connected by gears, and, for example, by an electric motor.
[0047] Liquid and gaseous streams, gas mixtures, or the like, as used herein, may be "rich" or "poor" in one or more components, where "rich" may mean a content of at least 50%, 75%, 90%, 95%, 99%, 99.5%, 99.9%, or 99.99%, and "poor" may mean a content of at most 50%, 25%, 10%, 5%, 1%, 0.1%, or 0.01% on a molar, weight, or volume basis. Liquid and gaseous streams, gas mixtures, or the like, as used herein, may further be enriched or depleted in one or more components, where these terms refer to a content in another stream used to form the stream. A material stream under consideration is “enriched” if it contains at least 2 times, 5 times, 10 times, 100 times or 1.000 times the content of the designated component(s), and ‘depleted’ if it has at most 0.5 times, 0.1 times, 0.01 times or 0.001 times the content of the designated component(s), in each case in relation to the material stream from which the material stream in question was formed.
[0048] Statements such as “essentially comprising” and the like should be understood here in particular to mean that a composition, material stream, etc. described thereby may contain further components in addition to the mandatory components stated or resulting from the designation of the gas mixture (e.g. “hydrogen”), provided that the essential characteristics of the composition described thereby are not significantly changed by these. The same applies to statements such as “essentially free of” and the like. A gas or gas mixture “essentially” containing or consisting of one or more components may in particular contain more than 95, 99, 99.9 or 99.99% of these components in total or as individual values. Conversely, a gas or gas mixture is “essentially free” of one or more components if it contains less than 5, 1, 0.1 or 0.01% of these components in total or as individual values.
[0049] All percentages used here may refer to molar, quantitative, or volume fractions. Pressures in bar are to be understood as absolute pressures, unless otherwise stated.
[0050] The conjunction "and / or", when used before the last term in a list, should be understood to mean that all terms mentioned previously in the list can be combined with one another in any way. In other words, "A, B and / or C" means "A and / or B and / or C" or "at least one of the elements A, B and C in any combination". If a "portion" of a material stream is mentioned here, this can be a proportion with the same composition that has simply been diverted from an initial stream, but also a proportion of a different composition and possibly only a component of the initial stream that is formed by means of a process such as condensation, evaporation, boiling, distillation, rectification, absorption, adsorption, flashing, membrane separation, separation or the like, or remains as a residue in a corresponding step.A “part” may also be present after a combination of any of the steps mentioned above, for example after separation of a diverted portion.
[0051] Figures 1 and 2 illustrate a method according to one embodiment and are designated overall by 100. Figure 1 illustrates a first method mode with a high power supply, for example, due to high wind speeds, and Figure 2 illustrates a second method mode with a low power supply, for example, during a lull in the wind. Formed material flows are represented by solid flow arrows, while undeveloped material flows are represented by dotted flow arrows.
[0052] Intermediate modes can also generally occur, for example, electrolysis can produce only 5% of the hydrogen required for an ammonia synthesis and the rest can be taken from the buffer storage used (see below) if the ammonia synthesis requires a minimum of 10%.
[0053] The process of Figures 1 and 2 is illustrated using an ammonia synthesis, although other embodiments can also be used to produce other synthesis products. The basic concepts are the same or essentially the same, although for other synthesis products, nitrogen is replaced by, for example, carbon dioxide and / or carbon monoxide (in the case of methane or methanol synthesis), and a conversion 30 takes place in a different, but known, form.
[0054] Part of the process 100 is an electrolysis 10 of any type, to which water is supplied in the form of a water stream 1. In the first process mode according to Figure 1, the water is decomposed by means of the electrolysis 10 using electrical current 2, which is obtained in particular from renewable sources, to form hydrogen and oxygen. The hydrogen can be freed of residual oxygen by means of a catalytic oxygen conversion unit (not shown) (so-called DeOxo) to form water, and the hydrogen can be further dried after the water formed has been separated off, for example by means of adsorptive processes. Typically, the electrolysis 10 consumes approximately 90% or more of the total electrical energy consumed by the plant.
[0055] A substantially dry hydrogen stream 3 is obtained. The amount of this hydrogen typically exceeds the minimum required for the formation of the synthesis product 6. The oxygen (not shown) can be used for other purposes or vented.
[0056] In the second process mode according to Figure 2, the electrolysis 10 is not in operation due to the lower power supply and therefore does not supply any hydrogen stream 3 or only supplies it in an amount that is below the minimum required for the formation of the synthesis product 6.
[0057] In parallel with the formation of the hydrogen stream 3 in the first process mode according to Figure 1, a nitrogen stream 4 is provided, for example by means of cryogenic air separation or other processes. This typically does not occur in the second process mode according to Figure 2.
[0058] The hydrogen stream 3 and the nitrogen stream 4 are mixed together in a ratio of three to one (mol / mol) in the first process mode according to Figure 1, for example using a mixing drum (not shown), wherein a mixing control can be carried out using a density measuring unit (not shown).
[0059] A reaction mixture 5 formed in this way is fed into the first process mode according to Figure 1 on the suction side by means of a compressor unit 40, for example, a four-stage centrifugal compressor. A first portion of the reaction mixture 5 is withdrawn from the compressor unit 40 via an intermediate withdrawal point, for example, between the third and fourth compressor stages viewed from the suction side, and temporarily stored in a storage unit 20 comprising, for example, several storage containers. This occurs at a pressure level referred to as the storage pressure level. A second portion of the reaction mixture 5 is withdrawn from the compressor unit on the pressure side and fed to a conversion 30 to form the desired process product 6, here ammonia.
[0060] This occurs at a pressure level known as the conversion pressure level.
[0061] In the second process mode according to Figure 2, the first portion of the reaction mixture 5, previously temporarily stored in the first process mode, is removed from the storage unit and fed to the suction side of the compressor unit 40. This occurs at the storage pressure level. The first portion of the reaction mixture 5 is then compressed in the compressor unit to the conversion pressure level and then fed to the conversion unit 30 to form the desired process product 6.
[0062] Some central aspects of embodiments of the invention are explained again below in other words.
[0063] Hydrogen 3 from a deoxo and drying unit, which is connected downstream of an electrolysis 10 and is not illustrated here, and nitrogen 4 from a suitable plant, for example an air separation plant, are mixed in the first process mode according to Figure 1 to obtain a reaction mixture 5 in a ratio of three to one (mol / mol), wherein a mixing drum can be used for homogenization, and finally passed to the suction side of the compressor unit 40.
[0064] The combined reaction mixture 5 is compressed, for example, to approximately 140 bar in the first, second, and third stages of an electrically driven centrifugal compressor, which forms the compressor unit 40. The ratio of hydrogen to nitrogen in the reaction mixture 5 fed to the compressor unit 40 is precisely controlled to ensure stable operation of the compressor unit 40 and the ammonia synthesis, i.e., the conversion 30. The ratio can be continuously monitored by a density measurement at the inlet of the compressor unit 40. The fourth compressor stage compresses to 150 bar. It serves to compress reaction mixture 5 and, if appropriate, a recycled reaction mixture 7 from the synthesis circuit of the conversion 30. The reaction mixture compressed here can be preheated to 170°C in a heat exchanger (not shown) before being fed to the conversion 30.During periods of low power availability, in which no or only small amounts of hydrogen 3 are produced, i.e., in the second process mode according to Figure 2, previously buffered reaction mixture 5 ("first portion" see above and immediately below) is fed from the storage unit 20 to the inlet of the compressor unit 40. The storage unit 20 can, for example, be operated in a pressure range of 30 to 140 bar.
[0065] During periods of high power availability, when hydrogen production exceeds the minimum requirement, i.e., in the first process mode according to Figure 1, the storage unit 20 is filled with the excess hydrogen (and nitrogen) produced, i.e., reaction mixture 5. The reaction mixture 5 ("first portion" of the reaction mixture 5) is, for example, extracted after the third stage of the four-stage centrifugal compressor forming the compressor unit 40 and passed into the storage unit 20 via an aftercooler (not shown).
Claims
Patent claims 1. A process (100) for producing a synthesis product (6), in which gaseous hydrogen (3) is provided by electrolysis (10) of water (1) and is subjected to a reaction (30) with one or more gaseous reactants (4) to form the synthesis product (6), wherein during a first process mode the hydrogen (3) and the one or more reactants (4) are mixed to obtain a gaseous reaction mixture (5), and the gaseous reaction mixture (5) or a portion thereof is stored under pressure in a storage unit (20), and wherein during a second process mode the gaseous reaction mixture (5) stored under pressure in the first process mode or a portion thereof is removed from the storage unit (20) and fed to the reaction (30) to form the synthesis product (6).
2. The process (100) according to claim 1, wherein, in a third process mode, the gaseous hydrogen (3) is provided by the electrolysis (10) of water (1) and is subjected to a reaction (30) with the one or more gaseous reactants (4) to form the synthesis product (6), wherein the hydrogen (3) and the one or more reactants (4) are mixed to obtain the reaction mixture (5), and the reaction mixture (5) or a portion thereof is fed to the reaction (30) to form the synthesis product (6), bypassing the storage unit (20).
3. The process (100) according to claim 1 or 2, wherein in the first process mode the reaction mixture (5) or its pressure-stored part is compressed to a storage pressure level before the pressure storage, and wherein in the second process mode the reaction mixture (5) pressure-stored in the first process mode or its part fed to the conversion (30) to the synthesis product (6) is removed at the storage pressure level of the storage unit (20) and compressed to a conversion pressure level before the conversion (30) to the synthesis product (6).
4. The method (100) according to claim 3, wherein the compression to the storage pressure level and the conversion pressure level is carried out using a multi-stage compressor unit (40).
5. The process (100) according to claim 4, wherein in the first process mode the reaction mixture (5) is fed to the compressor unit (40) on the suction side, from which a portion of the reaction mixture (5) is withdrawn at the storage pressure level via an intermediate withdrawal for introduction into the storage unit (20), and wherein in the second process mode the reaction mixture (5) stored under pressure in the first process mode or the portion thereof fed to the conversion (30) to form the synthesis product (6) is fed to the compressor unit (40) on the suction side and removed on the pressure side at the conversion pressure level.
6. The method (100) according to claim 4 or 5, wherein the storage pressure level is 30 to 210 bar and the conversion pressure level is 100 to 250 bar.
7. The process (100) according to claim 5, wherein a recycle stream (7) comprising unreacted reaction mixture (5) from the reaction (30) is fed back to the compressor unit (40) via an intermediate feed.
8. The method (100) according to any one of claims 4 to 7, wherein the compressor unit (40) comprises an axial and / or a radial turbocompressor and / or a piston compressor.
9. Method according to one of the preceding claims, in which the mixing to form the reaction mixture (5) is carried out using a mixing drum or using a static mixer and / or is monitored using a density measuring unit arranged on the suction side of the compressor unit (40).
10. The method (100) according to any one of the preceding claims, wherein the electrolysis (10) is carried out using regeneratively generated electrical current (2).
11. The method (100) according to any one of the preceding claims, wherein the first operating mode is performed during a period of higher power availability and wherein the second operating mode is performed during a period of lower power availability.
12. The process (100) according to any one of the preceding claims, wherein the synthesis product (6) is ammonia and the reactant is nitrogen.
13. The process (100) according to any one of claims 1 to 10, wherein the synthesis product (6) is synthetic methane or methanol and the reactant is carbon monoxide and / or carbon dioxide.
14. Plant for producing a synthesis product (6), which is designed to provide gaseous hydrogen (3) by electrolysis (10) of water (1) and to subject it to a reaction (30) with one or more gaseous reactants (4) to form the synthesis product (6), wherein the plant is further designed to mix the hydrogen (3) and the one or more reactants (4) to obtain a reaction mixture (5) during a first process mode and to pressure-store the reaction mixture (5) or a part thereof in a storage unit (20), and to remove the reaction mixture (5) or a part thereof pressure-stored in the first process mode from the storage unit (20) during a second process mode and to feed it to the reaction (30) to form the synthesis product (6).
15. Plant according to claim 14, which is arranged to carry out a method according to one of claims 1 to 13.
Citation Information
Patent Citations
Method and device for making power plants fueled with carbon-containing fuels more flexible by means of the production of carbon-containing energy carriers
DE102014105067A1
Method and fuel generation assembly for the carbon dioxide-neutral compensation of energy peaks and troughs in the generation of electrical energy and / or for producing a fuel containing hydrocarbons
EP2426236B1
Power supply system, in particular for the field of building technology
EP2751307B1
Flexibly operable power plant and method for the operation thereof
EP3019582B1
Method of storing chemical and electrical energy via thermodynamically reversible cycle processes
EP3310709B1