Unsaturated polyester resin button bubble-free production device and method

CN118144135BActive Publication Date: 2026-09-04GAOFAN (ZHEJIANG) INFORMATION TECH CO LTD
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Patent Information

Application Number
CN202410309433.9
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-03-19
Publication Date
2026-09-04
Estimated Expiration
2044-03-19

AI Technical Summary

Technical Problem

[0003]不饱和聚酯树脂纽扣在生产加工过程中,会添加色料、促进剂等多种不同添加剂,为混合均匀还需要进行搅拌,而在搅拌作用下,不饱和聚酯树脂混合液内便会存在较多的气泡,而且不饱和聚酯树脂混合液液面上,还易于堆积有泡沫,为了保证凝胶、固化后的不饱和聚酯树脂板或棒内不存在或仅有少量的气泡,现有技术中,一般是通过在不饱和聚酯树脂混合液内添加消泡剂,但在不饱和聚酯树脂混合液液面上堆积有较多泡沫时,仅依靠在不饱和聚酯树脂混合液内所添加的消泡剂进行消除气泡、泡沫,其耗时较久,效率较低,会影响连续化生产加工的效率,为此,发明一种不饱和聚酯树脂纽扣无气泡生产装置及方法是亟须解决的问题

Benefits of technology

[0032] 1) This invention uses a moving component to move a foam pusher along the inside of the pool to push the foam on the surface of the unsaturated polyester resin mixture towards the collection frame. Both the foam pusher and the collection frame can spray defoamer into the pool. The pushing component operates under the pushing action of the foam pusher to move the collection frame containing the foam upwards to align with the receiving frame. The moving component then moves a pusher plate to push the foam out of the collection frame and onto the receiving frame. The moving component then moves the foam pusher back to the initial position. This cycle repeats. With the combined action of foam capture and defoamer spraying, the bubbles in the unsaturated polyester resin mixture are quickly eliminated.

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Abstract

The present application relates to a kind of unsaturated polyester resin button bubble-free production device and method, the production device includes tank, further includes, support frame, the support frame is located tank periphery;Push foam piece, the push foam piece is used to collect.The present application is moved by moving assembly one to drive push foam piece along tank interior to move to push the foam on the liquid level of unsaturated polyester resin mixed solution in tank interior to the direction of collection frame, push foam piece and collection frame can be sprayed defoaming agent to tank interior, push assembly runs under the pushing action of push foam piece to drive collection frame with foam to move to align with receiving frame, by moving assembly two to drive push plate two to move to push the foam in collection frame out of collection frame and fall on receiving frame, moving assembly one again drives push foam piece to move to initial position, so on cycle, under the double cooperation of fishing foam and defoaming agent spraying, it is convenient to quickly eliminate the bubble of unsaturated polyester resin mixed solution.
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Description

Technical Field

[0001] This invention belongs to the field of resin button production technology, specifically relating to a bubble-free production device and method for unsaturated polyester resin buttons. Background Technology

[0002] Unsaturated polyester resin buttons are made from unsaturated polyester resin as the main raw material, with the addition of appropriate additives. They are gelled and cured into pearlescent or non-pearlescent sheets or rods in specific equipment and molds, and then mechanically processed. Unsaturated polyester resin buttons are an emerging international garment accessory. They are resistant to acids and alkalis and do not deform after high-temperature washing and ironing. In addition, unsaturated polyester resin buttons have rich color variations, strong simulation, and excellent physical and chemical properties, and have become the leading button product for clothing.

[0003] During the production and processing of unsaturated polyester resin buttons, various additives such as colorants and accelerators are added. Stirring is required to ensure uniform mixing. However, this stirring action results in numerous air bubbles in the unsaturated polyester resin mixture, which easily accumulates on the surface. To ensure that the gelled and cured unsaturated polyester resin sheets or rods contain little or no air bubbles, existing technologies typically involve adding defoamers to the unsaturated polyester resin mixture. However, when a significant amount of foam accumulates on the surface, relying solely on defoamers to eliminate bubbles is time-consuming and inefficient, impacting the efficiency of continuous production. Therefore, inventing a bubble-free production device and method for unsaturated polyester resin buttons is an urgent problem to be solved. Summary of the Invention

[0004] The purpose of this invention is to provide an apparatus and method for producing bubble-free unsaturated polyester resin buttons in order to solve the above-mentioned problems.

[0005] The present invention achieves the above objectives through the following technical solutions:

[0006] A bubble-free production apparatus for unsaturated polyester resin buttons includes a material tank and further includes...

[0007] The support frame is located around the material pool.

[0008] A foam pusher, used to collect and push the foam on the surface of the unsaturated polyester resin mixture in the pool;

[0009] A first moving component is provided on a support frame to drive the foam pusher to move back and forth along the material pool;

[0010] A collection frame for receiving foam propelled by a foam pusher;

[0011] A pushing component, which, under the pushing of the foam pushing component, causes the collecting frame to move upward;

[0012] Push plate two, which is located above the collection frame, and after the collection frame is moved upward, push plate two is located inside the collection frame;

[0013] Movable component two, which is used to drive push plate two to move so as to push the foam collected in the collection box out of the collection box;

[0014] A receiving frame, which is used to receive the foam pushed out of the collection frame by the pusher plate two.

[0015] As a further optimization of the present invention, the foam pushing component includes a push plate, a spraying chamber opened inside the push plate, a plurality of spraying pipes for conveying defoamer inside the spraying chamber, and a plurality of liquid outlets opened at the bottom of the spraying chamber.

[0016] Both sides of the push plate are downward sloped and the bottom is horizontal. Two side plates are symmetrically provided on the side of the push plate near the collection frame to form a collection cavity with the push plate.

[0017] At least two mesh plates are provided on both sides of the push plate, and several spiked rollers are provided between two adjacent mesh plates.

[0018] As a further optimization of the present invention, the collection frame includes a frame body, a fixing plate disposed on the upper part of the frame body, a mesh plate II disposed on the lower part of the frame body, a guide plate disposed between the mesh plate II and the bottom of the frame body, a plurality of spray pipes II disposed between the mesh plate II and the guide plate, a plurality of liquid outlets II opened on the bottom of the frame body, and a conveying pipe connected to the collection frame and extending into the unsaturated polyester resin mixture.

[0019] The frame has openings on the top and the side near the foam pusher, and several discharge channels are provided on the two side walls of the frame adjacent to the side near the foam pusher.

[0020] As a further optimization of the present invention, the pushing component includes two sets of symmetrically arranged push rod assemblies, a support plate connected to the support frame, several springs disposed between the fixed plate and the support plate, and several guide rods disposed on the fixed plate and located inside each spring for limiting and guiding the springs. The top of the guide rods passes through the support plate and is provided with a baffle.

[0021] The push rod assembly includes a hinge seat that is slidably connected to the material pool, and a push rod that is rotatably connected to the hinge seat and the side wall of the frame.

[0022] At least one groove is provided on the inner wall of the material pool for the hinge seat to slide horizontally.

[0023] As a further optimization of the present invention, the support plate is slidably connected to the support frame, and a first telescopic member is provided between the support frame and the support plate;

[0024] A second telescopic component is provided between the foam-propelling component and the moving component.

[0025] As a further optimization of the present invention, a roller shutter structure is installed on the side of the frame near the foam pusher.

[0026] A method for producing bubble-free unsaturated polyester resin buttons using a bubble-free unsaturated polyester resin button production device, the specific steps of which are as follows:

[0027] Step 1: The moving component drives the foam pusher to move along the inside of the pool to push the foam on the surface of the unsaturated polyester resin mixture towards the collection frame. The collection frame receives the foam pushed by the foam pusher. The foam pusher and the collection frame spray defoamer into the pool.

[0028] Step 2: When the foam pusher moves to contact the pushing component, the foam pusher drives the pushing component to move, causing the collection box to move upward and align with the receiving box, and causing the pusher plate 2 to extend into the collection box.

[0029] Step 3: Move push plate 2 by moving component 2 to push the foam inside the collection box out of the collection box and into the receiving box;

[0030] Step 4: Repeat steps 1 to 3 until the bubbles and foam in and on the surface of the unsaturated polyester resin mixture are removed.

[0031] The beneficial effects of this invention are as follows:

[0032] 1) This invention uses a moving component to move a foam pusher along the inside of the pool to push the foam on the surface of the unsaturated polyester resin mixture towards the collection frame. Both the foam pusher and the collection frame can spray defoamer into the pool. The pushing component operates under the pushing action of the foam pusher to move the collection frame containing the foam upwards to align with the receiving frame. The moving component then moves a pusher plate to push the foam out of the collection frame and onto the receiving frame. The moving component then moves the foam pusher back to the initial position. This cycle repeats. With the combined action of foam capture and defoamer spraying, the bubbles in the unsaturated polyester resin mixture are quickly eliminated.

[0033] 2) In this invention, the foam pusher can not only push the foam on the surface of the unsaturated polyester resin mixture to move, but also serve as a power source to drive the pusher component to move, thereby driving the moving component two to move upward. They cooperate with each other and are easy to use.

[0034] 3) The present invention can adjust the height of the pushing component relative to the material pool by means of the first telescopic component, so as to adjust the height of the collecting frame, the pushing component, the second push plate, the second moving component and the receiving frame. The height of the foam pushing component relative to the material pool can be adjusted by means of the second telescopic component, so as to adapt to different liquid level heights and foam thicknesses of the unsaturated polyester resin mixture inside the material pool. Attached Figure Description

[0035] Figure 1 This is a front sectional view of the overall structure of the present invention.

[0036] Figure 2 This is a top view of part of the structure of the present invention.

[0037] Figure 3 This is a schematic diagram of the foam-expelling component of the present invention.

[0038] Figure 4 This is a front sectional view of a portion of the structure of the present invention.

[0039] Figure 5 This is a front sectional view of the collection frame of the present invention.

[0040] Figure 6 This is a top view of the collecting frame, pushing component, push plate II, moving component II, and receiving frame of the present invention.

[0041] Figure 7 This is a schematic diagram of the structure of the frame, guide plate, and liquid outlet II of the present invention.

[0042] In the diagram: 1. Material tank; 2. Support frame; 3. Foam pusher; 31. Push plate one; 32. Side plate; 33. Spraying chamber; 34. Spraying pipe one; 35. Liquid outlet one; 36. Mesh plate one; 37. Spike roller; 4. Moving component one; 41. Lead screw one; 42. Nut seat one; 43. Drive component one; 5. Collection frame; 51. Frame body; 52. Fixing plate; 53. Mesh plate two; 54. Spraying pipe two; 55. Guide plate; 56. Second outlet; 57. Discharge channel; 6. Pushing assembly; 61. Hinge seat; 62. Push rod; 63. Support plate; 64. Guide rod; 65. Spring; 66. Baffle; 7. Second push plate; 8. Second moving assembly; 81. Fixing frame; 82. Second lead screw; 83. Second nut seat; 84. Second driving component; 9. Receiving frame; 10. First telescopic component; 11. Second telescopic component. Detailed Implementation

[0043] The present application will now be described in further detail with reference to the accompanying drawings. It should be noted that the following specific embodiments are only used to further illustrate the present application and should not be construed as limiting the scope of protection of the present application. Those skilled in the art can make some non-essential improvements and adjustments to the present application based on the above application content.

[0044] Example 1

[0045] like Figure 1-7 As shown, a bubble-free production apparatus for unsaturated polyester resin buttons includes a material tank 1, and further includes...

[0046] Support frame 2, which is located around the material pool 1;

[0047] Foam pusher 3, which is used to collect and push the foam on the surface of the unsaturated polyester resin mixture in the material tank 1;

[0048] Movable component 4, which is mounted on support frame 2 to drive foam pusher 3 to reciprocate along material pool 1;

[0049] Collection frame 5, the collection frame 5 is used to receive foam pushed by foam pusher 3;

[0050] The pushing component 6, under the pushing of the foam pushing component 3, drives the collecting frame 5 to move upward;

[0051] Push plate 2 7 is located above collection frame 5. After collection frame 5 is moved upward, push plate 2 7 is located inside collection frame 5.

[0052] Movable component 2 8, which is used to drive push plate 2 7 to move so as to push the foam collected in collection frame 5 out of the collection frame 5.

[0053] The receiving frame 9 is used to receive the foam pushed out of the collection frame 5 by the pusher plate 2 7.

[0054] Preferably, the foam pusher 3 includes a pusher plate 31, a spraying chamber 33 opened inside the pusher plate 31, a plurality of spraying pipes 34 arranged inside the spraying chamber 33 for conveying defoamer, and a plurality of liquid outlets 35 opened at the bottom of the spraying chamber 33. The defoamer is sprayed out through the foam pusher 3, and the liquid outlets 35 are designed to facilitate the leakage of defoamer.

[0055] Both sides of the push plate 31 are downward sloped and the bottom is horizontal. Two side plates 32 are symmetrically provided on the side of the push plate 31 near the collection frame 5 to form a collection cavity with the push plate 31. During the movement of the push plate 31, the foam can be collected through the collection cavity, thereby pushing the foam towards the collection frame 5.

[0056] At least two mesh plates 36 are provided on both sides of the push plate 31, and several puncturing rollers 37 are provided between two adjacent mesh plates 36. The foam pusher 3 is used to puncture the air bubbles in the unsaturated polyester resin mixture.

[0057] In this embodiment, the moving component 4 includes two symmetrically arranged lead screws 41, a nut seat 42 connected to the lead screws 41 via a ball nut pair, and a driving component 43 that drives the two lead screws 41 to rotate. The lead screws 41 are rotatably connected to the support frame 2.

[0058] The drive component 43 includes a servo motor connected to one of the lead screws 41, two synchronous pulleys respectively sleeved on the lead screws 41, and a synchronous belt located between the two synchronous pulleys. The servo motor, the synchronous pulleys, and the synchronous belt drive the two lead screws 41 to rotate synchronously, and the nut seat 42 moves back and forth along the lead screws 41, thereby driving the foam pusher 3 to move back and forth.

[0059] Preferably, the collection frame 5 includes a frame 51, a fixing plate 52 disposed on the upper part of the inside of the frame 51, a mesh plate 53 disposed on the lower part of the inside of the frame 51, a guide plate 55 disposed between the mesh plate 53 and the bottom of the inside of the frame 51, a plurality of spray pipes 54 disposed between the mesh plate 53 and the guide plate 55, a plurality of liquid outlets 56 opened on the bottom of the inside of the frame 51, and a conveying pipe connected to the collection frame 5 and extending into the unsaturated polyester resin mixture. The frame 51 receives the foam pushed by the foam pusher 3, and the mesh plate 53 is used to allow the unsaturated polyester resin mixture to leak out. The leaked unsaturated polyester resin mixture falls to the top of the guide plate 55 and is guided to the liquid outlets 56 for delivery.

[0060] The frame 51 has openings on the top and on the side near the foam pusher 3. Several discharge channels 57 are provided on the two side walls of the frame 51 adjacent to the side near the foam pusher 3. Under the push of the pusher plate 7, the foam inside the frame 51 leaks out through the discharge channels 57.

[0061] Preferably, the pushing component 6 includes two sets of symmetrically arranged push rod assemblies, a support plate 63 connected to the support frame 2, a plurality of springs 65 disposed between the fixed plate 52 and the support plate 63, and a plurality of guide rods 64 disposed on the fixed plate 52 and respectively located inside each spring 65 for limiting and guiding the spring 65. The top of the guide rod 64 passes through the support plate 63 and is provided with a baffle 66.

[0062] The push rod assembly includes a hinge seat 61 that is slidably connected to the material pool 1, and a push rod 62 that is rotatably connected to the hinge seat 61 and the side wall of the frame 51.

[0063] At least one groove is provided on the inner wall of the material pool 1 for the hinge seat 61 to slide horizontally.

[0064] The hinge seat 61 moves horizontally along the slide groove under the push of the push plate 31 and the mesh plate 36, and compresses the spring 65, so that the collecting frame 5 moves up and aligns with the receiving frame 9. When the foam pusher 3 moves away from the collecting frame 5, the collecting frame 5 can move down and return to the initial position under the elastic force of the spring 65.

[0065] Preferably, the number of push plates 7 is at least one, and the moving component 8 includes a fixed frame 81 disposed at the bottom of the support plate 63, a lead screw 82 rotatably connected to the fixed frame 81, a nut seat 83 connected to the lead screw 82 through a ball bearing pair, and a driving component 84 for driving the lead screw 82 to rotate. The push plates 7 and the nut seats 83 correspond one-to-one and are connected to each other.

[0066] In this embodiment, when there is only one lead screw 82, the second driving component 84 includes a second servo motor connected to the second lead screw 82;

[0067] When there are two or more lead screws 82, each lead screw 82 includes a servo motor 2 connected to one of the driving components 84, several synchronous pulleys 2 respectively sleeved on each lead screw 82, and several synchronous belts 2 for driving the synchronous pulleys 2 to rotate synchronously.

[0068] The driving component 2 84 drives the lead screw 2 82 to rotate, so that the nut seat 2 83 drives the push plate 2 7 to move along the lead screw 2 82. The push plate 2 7 pushes the foam inside the frame 51 to be output from the frame 51 and fall into the receiving frame 9.

[0069] A method for producing bubble-free unsaturated polyester resin buttons using a bubble-free unsaturated polyester resin button production device, the specific steps of which are as follows:

[0070] Step 1: The foam pusher 3 is moved along the inside of the material tank 1 by the moving component 4 to push the foam on the surface of the unsaturated polyester resin mixture in the material tank 1 toward the collection frame 5. The collection frame 5 receives the foam pushed by the foam pusher 3. The foam pusher 3 and the collection frame 5 spray defoamer into the material tank 1.

[0071] Step 2: When the foam pusher 3 moves to contact the pusher component 6, the foam pusher 3 drives the pusher component 6 to move the collection frame 5 upward to align with the receiving frame 9, and causes the pusher plate 2 7 to extend into the collection frame 5.

[0072] Step 3: Move the pusher plate 7 by moving component 2 8 to push the foam inside the collection box 5 out of the collection box 5 and let it fall into the receiving box 9;

[0073] Step 4: Repeat steps 1 to 3 until the bubbles and foam in and on the surface of the unsaturated polyester resin mixture are removed.

[0074] Furthermore, the material tank 1 is equipped with a stirring structure (not shown in the figure) for mixing saturated polyester resin mixture and defoamer. The stirring structure is a conventional technical solution and will not be described in detail here.

[0075] It should be noted that, in this embodiment, the addition of defoamer into the material tank 1 can also be done in accordance with conventional techniques, by adding it together with various additives such as colorants and accelerators, and then mixing it evenly in the unsaturated polyester resin mixture through the stirring structure. That is, the defoamer sprayed by the foam pusher 3 and the collection frame 5 and the defoamer added by conventional techniques are used in combination.

[0076] Example 2

[0077] like Figure 1-7 As shown, a bubble-free production device for unsaturated polyester resin buttons differs from Embodiment 1 in that, in this embodiment, the support plate 63 and the support frame 2 are slidably connected vertically, and a first telescopic member 10 is provided between the support frame 2 and the support plate 63.

[0078] A second telescopic component 11 is provided between the foam-propelling component 3 and the moving component 4.

[0079] In this embodiment, the receiving frame 9 is disposed on the support plate 63.

[0080] The height of the pushing component 6 relative to the material pool 1 can be adjusted by the first telescopic component 10, so as to adjust the height of the collection frame 5, the pushing component 6, the second push plate 7, the second moving component 8, and the receiving frame 9.

[0081] The height of the foam pusher 3 relative to the material tank 1 can be adjusted by the second telescopic member 11 to adapt to different liquid level heights and foam thicknesses of the unsaturated polyester resin mixture inside the material tank 1.

[0082] It should be noted that in this embodiment, the height of the hinge seat 61 is adjusted by snapping it into different height slides. The installation and disassembly of the hinge seat 61 into different slides are conventional technical means, and will not be described in detail here.

[0083] Furthermore, to ensure that the foam inside the collection frame 5 is discharged from the discharge channel 57 as much as possible, a roller shutter structure is installed on the side of the frame 51 near the foam pusher 3. The roller shutter structure consists of a drive motor, a winding roller, and a winding door panel on the winding roller. The winding door panel is slidably connected to the frame 51. After the frame 51 moves upward, the roller shutter structure lowers to form a shield. After the frame 51 moves downward, the roller shutter structure retracts to facilitate foam collection.

[0084] The embodiments described above are merely examples of several implementations of the present invention, and while the descriptions are relatively specific and detailed, they should not be construed as limiting the scope of the present invention. It should be noted that those skilled in the art can make various modifications and improvements without departing from the concept of the present invention, and these modifications and improvements all fall within the scope of protection of the present invention.

Claims

1. A bubble-free production apparatus for unsaturated polyester resin buttons, comprising a material tank (1), characterized in that: It also includes, Support frame (2), the support frame (2) is located around the material pool (1); Foaming component (3), the foaming component (3) is used to collect and push the foam on the surface of the unsaturated polyester resin mixture in the material pool (1); Moving component 1 (4), which is mounted on support frame (2) to drive foam pusher (3) to move back and forth along material pool (1); Collection box (5), the collection box (5) is used to receive foam pushed by foam pusher (3); The pushing component (6) drives the collecting frame (5) to move upward under the pushing of the foam pushing component (3); Push plate two (7), the push plate two (7) is located above the collection frame (5), and the collection frame (5) is moved up so that the push plate two (7) is located inside the collection frame (5); The second moving component (8) is used to drive the second pusher (7) to move so as to push the foam collected in the collection box (5) out of the collection box (5); The receiving frame (9) is used to receive the foam pushed out of the collection frame (5) by the pusher plate (7); The foaming component (3) includes a push plate (31), a spraying chamber (33) opened inside the push plate (31), a number of spraying pipes (34) arranged inside the spraying chamber (33) for conveying defoamer, and a number of liquid outlets (35) opened at the bottom of the spraying chamber (33). The push plate (31) has downward slopes on both sides and horizontal bottom. The push plate (31) has two side plates (32) symmetrically arranged on the side near the collection frame (5) to form a collection cavity with the push plate (31). At least two mesh plates (36) are provided on both sides of the push plate (31), and several spiked rollers (37) are provided between two adjacent mesh plates (36). The collection frame (5) includes a frame (51), a fixing plate (52) located inside the upper part of the frame (51), a mesh plate (53) located inside the lower part of the frame (51), a guide plate (55) located between the mesh plate (53) and the bottom of the frame (51), several spray pipes (54) located between the mesh plate (53) and the guide plate (55), several liquid outlets (56) located at the bottom of the frame (51), and a delivery pipe connected to the collection frame (5) and extending into the unsaturated polyester resin mixture; The frame (51) has openings on the top and on the side near the foam pusher (3). Several discharge channels (57) are provided on the two side walls of the frame (51) adjacent to the side near the foam pusher (3). The pushing assembly (6) includes two sets of symmetrically arranged push rod assemblies, a support plate (63) connected to the support frame (2), several springs (65) disposed between the fixed plate (52) and the support plate (63), and several guide rods (64) disposed on the fixed plate (52) and located inside each spring (65) for limiting and guiding the spring (65). The top of the guide rod (64) passes through the support plate (63) and is provided with a baffle (66). The push rod assembly includes a hinge seat (61) slidably connected to the material pool (1) and a push rod (62) rotatably connected to the hinge seat (61) and the side wall of the frame (51). At least one groove is provided on the inner wall of the material pool (1) for the hinge seat (61) to slide horizontally.

2. The bubble-free production apparatus for unsaturated polyester resin buttons according to claim 1, characterized in that: The support plate (63) is slidably connected to the support frame (2) in the upper and lower parts, and a first telescopic member (10) is provided between the support frame (2) and the support plate (63). A second telescopic component (11) is provided between the foam pushing component (3) and the moving component (4).

3. The bubble-free production apparatus for unsaturated polyester resin buttons according to claim 2, characterized in that: A roller shutter structure is installed on the side of the frame (51) near the pusher (3).

4. A method for producing bubble-free unsaturated polyester resin buttons using the production apparatus described in any one of claims 1-3, characterized in that: The specific steps are as follows: Step 1: The foam pusher (3) is moved along the inside of the material tank (1) by the moving component (4) to push the foam on the surface of the unsaturated polyester resin mixture inside the material tank (1) toward the collection frame (5). The collection frame (5) receives the foam pushed by the foam pusher (3). The foam pusher (3) and the collection frame (5) spray defoamer into the material tank (1). Step 2: When the foam pusher (3) moves to contact the pusher (6), the foam pusher (3) drives the pusher (6) to run so that the collection box (5) moves up to align with the receiving box (9) and the pusher plate (7) extends into the collection box (5). Step 3: Move push plate 2 (7) by moving component 2 (8) to push the foam inside collection box (5) out of collection box (5) and into receiving box (9); Step 4: Repeat steps 1 to 3 until the bubbles and foam in and on the surface of the unsaturated polyester resin mixture are removed.

Citation Information

Patent Citations

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