Compositions for caring for keratin materials and masks comprising same

Abstract

The present invention relates to a composition for caring for keratin materials and a mask comprising the same. The invention also relates to a non-therapeutic method for caring for keratin materials using said composition or mask.

Description

Technical Field

[0001] The present invention relates to a cosmetic composition and a mask comprising the same. In particular, the present invention relates to a composition for caring for keratin materials and a mask comprising the same, and a non-therapeutic method for caring for keratin materials using the composition or the mask. Background Art

[0002] The skin is the body's protective barrier. It protects the body's interior from physical damage (such as trauma) and biological damage (such as bacteria, viruses or fungi).

[0003] Skin aging is part of the aging process of the human body, which is not only related to age itself, but also closely related to external factors such as sunlight exposure. Light-induced skin aging ("photoaging") is mainly caused by sunlight exposure, and as the depletion of the ozone layer increases, the photoaging of the skin becomes more and more serious, which affects the appearance of the skin.

[0004] The development of formulations dedicated to the care of the skin is a permanent endeavour.

[0005] There are many challenges in formulating cosmetic compositions. Some active ingredients, such as retinoids, are unstable. To be commercially acceptable, the active ingredients contained in a cosmetic product must be stable over a certain period of time. No matter how effective a product is, if the product deteriorates under storage conditions before it is sold, it will not be commercially acceptable.

[0006] Furthermore, some lipophilic active ingredients such as retinoids are not effectively delivered into the skin.

[0007] Therefore, it remains a goal to develop cosmetic products that can effectively deliver retinoids into the skin and in which the retinoids contained are stable for a relatively long period of time. Summary of the invention

[0008] It is an object of the present invention to develop cosmetic products in which the retinoids contained are stable over a relatively long period of time, for example at least two months.

[0009] Another object of the present invention is to develop cosmetic products that can effectively deliver retinoids into the skin.

[0010] Thus, according to a first aspect, the present invention provides a composition for caring for keratin materials, said composition comprising:

[0011] a) at least one retinoid; and

[0012] b) Combination of the following antioxidants

[0013] i) ascorbic acid or its derivatives,

[0014] ii) tocopherol or a derivative thereof, and

[0015] iii) at least one hydroxyhydrocinnamate antioxidant.

[0016] According to a second aspect, the present invention provides a mask for caring for keratin materials, the mask comprising:

[0017] A) Hydrophilic film towel, and

[0018] B) The composition according to the invention impregnated into the film-covered towel.

[0019] According to a third aspect, the invention also provides a non-therapeutic method for caring for keratin materials, in particular the skin, comprising the step of applying a composition or a mask according to the invention to the keratin material.

[0020] The inventors have discovered that retinoids are stable over relatively long periods of time and can be effectively delivered into the skin.

[0021] Other subjects and features, aspects and advantages of the invention will emerge even more clearly on reading the detailed description and examples which follow. DETAILED DESCRIPTION OF THE INVENTION

[0023] As used herein, unless otherwise indicated, the limits of a numerical range are included within that range, particularly in the expressions "between... and..." and "... to...".

[0024] As used herein, the term "comprising" should be interpreted as including all the specifically mentioned features as well as optional, additional, unspecified features.

[0025] As used herein, use of the term "comprising" also discloses embodiments in which features other than those specifically mentioned are absent (ie, "consisting of.").

[0026] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by those skilled in the art to which the invention belongs. When the definition of a term in this specification conflicts with the meaning commonly understood by those skilled in the art to which the invention belongs, the definition described herein shall apply.

[0027] Unless otherwise indicated, all numerical values ​​expressing quantities of ingredients and the like used in the specification and claims are to be understood as modified by the term “about.” Accordingly, unless indicated to the contrary, the numerical values ​​and parameters set forth herein are approximations that can vary depending upon the desired properties desired to be obtained.

[0028] As used herein, the expression "at least one" used in this specification is equivalent to the expression "one or more".

[0029] For the purposes of the present invention, the term "keratin material" is intended to encompass the skin. According to the present invention, facial skin and eye skin are most particularly contemplated.

[0030] As used herein, "stable" means that the retinol or its derivative contained in the film will not substantially decompose for at least 2 months.

[0031] The composition for caring for keratin materials according to the invention comprises:

[0032] a) at least one retinoid; and

[0033] b) Combination of the following antioxidants

[0034] i) ascorbic acid or its derivatives,

[0035] ii) tocopherol or a derivative thereof, and

[0036] iii) at least one hydroxyhydrocinnamate antioxidant.

[0037] Retinoids

[0038] According to a first aspect, a composition according to the invention comprises at least one retinoid.

[0039] The retinoids according to the invention include, in particular, retinol (vitamin A), retinal (vitamin A aldehyde), retinoic acid (vitamin A acid), or retinol and C2-C 20 Esters of acids such as propionate, acetate, linoleate or palmitate (retinyl palmitate) of retinol.

[0040] Thus, in some embodiments, the retinoid is selected from retinol, retinal, retinoic acid, retinol and C2-C 20 Esters of acids, and combinations thereof.

[0041] Among the retinoids, mention may be made more particularly of retinol, retinal, retinoic acid, in particular all-trans retinoic acid and 13-cis retinoic acid, retinol derivatives, for example retinyl acetate, retinyl propionate or retinyl palmitate, and the retinoids described in the following patent applications: FR 2 370 377, EP 0 199 636, EP 0 325 540 and EP 0 402 072.

[0042] Preferably, the retinoid is retinol or pro-retinol.

[0043] The term "retinol" is intended to refer to all isomers of retinol, ie, all-trans-retinol, 13-cis-retinol, 11-cis-retinol, 9-cis-retinol, and 3,4-didehydroretinol.

[0044] As a representative of pro-retinol, mention may in particular be made of retinyl palmitate (palmitic acid ester of retinol).

[0045] Preferably, the retinoid is selected from retinol, retinyl palmitate, and combinations thereof.

[0046] Thus, in some preferred embodiments, the compositions according to the present invention comprise retinol and / or retinyl palmitate.

[0047] Advantageously, the retinoid is present in an amount ranging from 0.1% to 5% by weight, preferably from 0.1% to 2% by weight and more preferably from 0.15% to 1% by weight relative to the total weight of the composition.

[0048] Antioxidants

[0049] According to a first aspect, a composition according to the invention comprises a combination of the following antioxidants: i) ascorbic acid or a derivative thereof, ii) tocopherol or a derivative thereof, and iii) at least one hydroxyhydrocinnamate antioxidant.

[0050] Ascorbic acid and its derivatives

[0051] As used herein, ascorbic acid derivatives include, among others, aminopropanol ascorbyl phosphate, ascorbic acid polypeptide, ascorbyl dipalmitate, ascorbyl glucoside, ascorbyl linoleate, ascorbyl methylsilanol pectinate, ascorbyl palmitate, ascorbyl tetraisopalmitate, trisodium ascorbyl palmitate phosphate, disodium ascorbyl sulfate, calcium ascorbate, methylsilanol ascorbate, sodium ascorbate, sodium ascorbyl phosphate, sodium ascorbyl / cholesteryl phosphate, tetrahexyldecyl ascorbyl phosphate, magnesium ascorbyl phosphate.

[0052] Therefore, in some embodiments, the composition according to the present invention comprises one or more of aminopropanol ascorbyl phosphate, ascorbic acid polypeptide, ascorbyl dipalmitate, ascorbyl glucoside, ascorbyl linoleate, ascorbyl methylsilanol pectinate, ascorbyl palmitate, ascorbyl tetraisopalmitate, trisodium ascorbyl palmitate phosphate, disodium ascorbyl sulfate, calcium ascorbate, methylsilanol ascorbate, sodium ascorbate, sodium ascorbyl phosphate, sodium ascorbyl / cholesteryl phosphate, tetrahexyldecyl ascorbyl ester, and magnesium ascorbyl phosphate.

[0053] Preferably, the composition according to the invention comprises ascorbic acid and / or ascorbyl glucoside.

[0054] Advantageously, ascorbic acid or a derivative thereof is present in an amount ranging from 0.05% to 3% by weight, preferably from 0.1% to 2% by weight and more preferably from 0.15% to 1% by weight relative to the total weight of the composition.

[0055] Tocopherol and its derivatives

[0056] As used herein, tocopherol derivatives include, among others, tocopheryl acetate, tocopheryl linoleate, tocopheryl linoleate / oleate, tocopheryl nicotinate, tocopheryl retinoate, sodium tocopheryl phosphate, dioleyl tocopheryl methylsilanol.

[0057] Thus, in some embodiments, the compositions according to the present invention comprise one or more of tocopherol, tocopheryl acetate, tocopheryl linoleate, tocopheryl linoleate / oleate, tocopheryl nicotinate, tocopheryl retinoate, sodium tocopheryl phosphate and dioleyl tocopheryl methylsilanol.

[0058] Preferably, the composition according to the invention comprises tocopherol.

[0059] Advantageously, tocopherol or a derivative thereof is present in an amount ranging from 0.05% to 3% by weight, preferably from 0.1% to 2% by weight and more preferably from 0.15% to 1% by weight relative to the total weight of the composition.

[0060] Hydroxyhydrocinnamate antioxidant

[0061] Preferably, the hydroxyhydrocinnamate antioxidant is selected from pentaerythritol tetra-di-tert-butyl hydroxyhydrocinnamate, octadecyl di-tert-butyl-4-hydroxyhydrocinnamate, tetra-dibutyl pentaerythritol hydroxyhydrocinnamate, and combinations thereof.

[0062] Advantageously, the hydroxyhydrocinnamate antioxidant is present in an amount ranging from 0.05% to 3% by weight, preferably from 0.1% to 2% by weight, more preferably from 0.15% to 1% by weight relative to the total weight of the composition.

[0063] Water Phase

[0064] The compositions of the present invention may comprise an aqueous phase.

[0065] The aqueous phase comprises water.

[0066] Optionally, the aqueous phase comprises an organic solvent miscible with water (at room temperature 25° C.) to provide hydration, the organic solvent being selected from diols and polyols having 2 to 20 carbon atoms, preferably 2 to 10 carbon atoms, and preferably 2 to 6 carbon atoms, such as glycerol, propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, caprylyl glycol, dipropylene glycol, diethylene glycol; and combinations thereof.

[0067] Advantageously, the aqueous phase is present in the composition according to the invention in an amount ranging from 50% to 95% by weight and preferably from 60% to 85% by weight relative to the total weight of the composition.

[0068] oil phase

[0069] The compositions of the invention may comprise an oily phase.

[0070] The oil phase contains at least one oil.

[0071] Oils can be volatile or non-volatile.

[0072] The term "oil" refers to a water-immiscible, non-aqueous compound that is liquid at room temperature (25° C.) and atmospheric pressure (760 mmHg). The term "non-volatile oil" refers to a compound that can remain on keratin materials for at least several hours at room temperature and atmospheric pressure and, in particular, has a volatile organic compound of less than 10 3 Non-volatile oils may also be defined as oils having a vapor pressure of less than 0.07 mg / cm2 under the aforementioned conditions after 30 minutes. 2 evaporation rate.

[0073] These oils may be of vegetable, mineral or synthetic origin.

[0074] The oil may be selected from hydrocarbon-based oils, silicone oils or fluorinated oils.

[0075] The term "hydrocarbon-based oil" refers to an oil that is essentially formed from carbon and hydrogen atoms and optionally O and N atoms, or even consists of carbon and hydrogen atoms and optionally O and N atoms, and does not contain Si and F heteroatoms. Such oils may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

[0076] The term "silicone oil" refers to an oil containing at least one silicon atom, especially containing Si-O groups.

[0077] The term "fluorinated oil" refers to an oil containing at least one fluorine atom.

[0078] Preferably, the oil is selected from hydrocarbon-based oils.

[0079] Advantageously, the oily phase is present in the composition according to the invention in an amount ranging from 1% to 20% by weight and preferably from 2% to 10% by weight relative to the total weight of the composition.

[0080] Additional cosmetic active ingredients

[0081] Depending on the end purpose, the compositions according to the invention may comprise one or more additional cosmetic active ingredients.

[0082] As cosmetic active ingredients that may be used in the composition according to the invention, examples that may be mentioned include, inter alia: enzymes; flavonoids; humectants (eg biosaccharide gum-1, mannose, sodium hyaluronate); tensioning agents; soothing agents.

[0083] It is easy for a person skilled in the art to adjust the amount of the additional cosmetic active ingredient based on the end use of the composition according to the invention.

[0084] Additional adjuvants or additives

[0085] The composition of the present invention may contain conventional cosmetic adjuvants or additives, such as fragrances, surfactants (e.g., nonionic surfactants), chelating agents (e.g., trisodium ethylenediamine disuccinate), preservatives (e.g., chlorphenesin and phenoxyethanol) and bactericides (e.g., hydroxyacetophenone), thickeners (e.g., xanthan gum, ammonium polyacryloyldimethyltaurate), pH adjusters (e.g., sodium citrate), and combinations thereof.

[0086] A person skilled in the art can select the amount of additional adjuvants or additives so as not to negatively affect the end use of the composition according to the invention.

[0087] According to a preferred embodiment, the present invention provides a composition for caring for keratin materials, the composition comprising, relative to the total weight of the composition:

[0088] a) 0.15% to 1% by weight of retinol and / or retinyl palmitate; and

[0089] b) Combination of the following antioxidants

[0090] i) 0.15% to 1% by weight of ascorbic acid or ascorbyl glucoside,

[0091] ii) 0.15% to 1% by weight of tocopherol, and

[0092] iii) 0.15 to 1 wt% of at least one hydroxyhydrocinnamate antioxidant selected from pentaerythritol tetra-di-tert-butyl hydroxyhydrocinnamate, octadecyl di-tert-butyl-4-hydroxyhydrocinnamate, tetra-dibutyl pentaerythritol hydroxyhydrocinnamate, and combinations thereof.

[0093] Galenic form

[0094] The composition of the present invention may be in the form of a gel, lotion or emulsion.

[0095] Film

[0096] The composition according to the present invention can be impregnated into a film-forming towel to form a film.

[0097] According to a second aspect, the present invention relates to a mask for caring for keratin materials, comprising:

[0098] A) Hydrophilic film towel, and

[0099] B) The composition according to the invention impregnated into the film-covered towel.

[0100] Hydrophilic film towel

[0101] According to a first aspect, a film coating according to the present invention comprises a hydrophilic film coating towel.

[0102] Preferably, the film wrap is water insoluble.

[0103] For purposes of the present invention, the term "water-insoluble" means that the film wrap does not dissolve in water and does not break apart when immersed in water.

[0104] Those skilled in the art can select a suitable film-forming towel and the weight ratio of the film-forming towel to the composition according to the present invention based on the properties of the composition.

[0105] The compress material can be a woven or nonwoven fabric.

[0106] Preferably, the film-covering wipe is an alginate wipe.

[0107] Alginate towels are known in the art and are described in WO2020001069A1.

[0108] For example, the alginate towel may comprise a water-insoluble alginate selected from calcium alginate, strontium alginate, zinc alginate, copper alginate, manganese alginate, or a combination thereof, preferably calcium alginate, preferably in an amount of 20 to 100 wt % relative to the total weight of the towel.

[0109] Preferably, when the film-forming wipe is an alginate wipe, the composition according to the present invention comprises a pH regulator in an amount of 0.01% to 1.0% by weight, preferably 0.05% to 0.45% by weight, more preferably 0.15% to 0.3% by weight, relative to the total weight of the composition according to the present invention, and the pH regulator is selected from sodium acetate, sodium citrate, sodium tartrate, and combinations thereof.

[0110] The film-wrapped towel can be composed of one or more layers. If a multi-layer towel is used, the materials of the layers can be the same or different from each other. The multi-layer towel can be prepared by laminating multiple layers made of the above-mentioned materials.

[0111] The film wrap can have a variety of shapes depending on the desired use and characteristics of the film.

[0112] The film wipes are usually designed to fit the area of ​​the skin to which the topical application is desired. For example, when the film is applied to the face, the film wipes are designed to correspond to the shape of the face, avoiding the eyes, nostrils and mouth areas as needed.

[0113] Preferably, the weight ratio of the water-insoluble substrate to the composition is from 1:3 to 1:20. More preferably, the weight ratio of the water-insoluble substrate to the composition is from 1:10 to 1:18.

[0114] use

[0115] The composition or mask according to the invention is intended for topical application and can be used in particular for caring for keratin materials, and in particular the skin.

[0116] In particular, the composition according to the invention can be used for combating wrinkles.

[0117] According to a third aspect, the present invention provides a non-therapeutic method for caring for keratin materials, in particular the skin, comprising the step of applying to the keratin material a composition or a mask as defined above.

[0118] In particular, the keratin material is facial skin and / or eye skin.

[0119] In some embodiments, the present invention provides a non-therapeutic method for caring for keratin materials, in particular the skin, comprising:

[0120] applying a film according to the invention to a keratin material;

[0121] allowing the film to remain on the keratin material for a period of time; and

[0122] The film is removed from the keratin material.

[0123] The invention is illustrated in greater detail by the following examples, which are given purely as non-limiting illustrations. Example

[0124] The main raw materials used, their trade names and their suppliers are listed in Table 1.

[0125] Table 1

[0126]

[0127]

[0128] Inventive Example 1 and Comparative Examples 1-4

[0129] Compositions according to Inventive Example (IE.) 1 and Comparative Examples (CE.) 1-4 were prepared with the ingredients listed in Table 2 (unless otherwise stated, the contents are expressed as weight percentages of active material relative to the total weight of each composition):

[0130] Table 2

[0131]

[0132]

[0133] The composition of Inventive Example 1 is representative of a composition according to the present invention.

[0134] The composition of Comparative Example 1 did not include an antioxidant.

[0135] The composition of Comparative Example 2 does not contain ascorbic acid or its derivatives.

[0136] The composition of Comparative Example 3 does not contain ascorbic acid or its derivatives, and hydroxyhydrocinnamate antioxidant.

[0137] The composition of Comparative Example 4 does not contain ascorbic acid or its derivatives, and tocopherol or its derivatives.

[0138] Preparation process:

[0139] Taking the composition of Inventive Example 1 as an example, each composition was prepared as follows:

[0140] 1). Add water (40% by weight of the total amount of water), xanthan gum, citric acid and sodium citrate into a mixer and heat to 75°C under stirring;

[0141] 2). Add dicaprylyl ether, PEG-6 caprylic / capric glyceride, pentaerythrityl tetra-di-tert-butyl hydroxyhydrocinnamate, dicaprylyl carbonate, PPG-6-decyltetradecyl polyether-30, octyldodecanol and glyceryl isostearate into a mixer, heat until mixed, and heat to 75°C under stirring;

[0142] 3). Adding tocopherol into a mixer to obtain an emulsion;

[0143] 4). Water (39.5% by weight of the total amount of water) was added to the mixer to dilute the emulsion;

[0144] 5). Add ammonium polyacryloyldimethyltaurate to the mixer to gel the emulsion;

[0145] 6) cooling the obtained system to 30° C.;

[0146] 7) Add ascorbyl glucoside into the mixer under stirring;

[0147] 8) cooling the obtained system to 30° C.; and

[0148] 9) Add retinyl palmitate under stirring to obtain a homogenous composition and then drain it through an 80 mesh filter.

[0149] Evaluate:

[0150] The compositions of Inventive Example 1 and Comparative Examples 1-4 were tested for retinyl palmitate content after preparation (T0) and after one week at 55°C (T1W).

[0151] Table 3

[0152]

[0153] As can be seen from Table 3, the retinyl palmitate in the composition of Inventive Example 1 is more stable than the compositions of Comparative Examples 1-4.

[0154] Inventive Examples 2-4 and Comparative Example 5

[0155] Inventive Examples 2-4 and Comparative Example 5 were conducted to investigate the delivery capabilities of retinyl palmitate using different film-wrapped tissues. The compositions listed in Table 4 were used in each of Inventive Examples 2-4 and Comparative Example 5.

[0156] Table 4

[0157]

[0158]

[0159] *: The indicated amounts are based on the total amount of the composition.

[0160] In Inventive Example (IE.) 2, 20 g of the composition in Table 4 was immersed in a towel for 12 hours, the towel comprising 20 wt % of alginate fibers derived from seaweed and 80 wt % of Tencel fibers relative to the total weight of the towel, wherein the weight ratio of the towel to the composition was 1:13.5. The towel was then squeezed, and the composition squeezed out of the towel was dissolved in isopropanol. The obtained solution was stirred for 0.5 hour, filtered for ultra-high performance liquid chromatography (UPLC) analysis, and retinyl palmitate was quantified by standard methods to determine the content of retinyl palmitate in the squeezed composition.

[0161] In Inventive Example (IE.) 3, 20 g of the composition in Table 4 was impregnated into a towel material for 12 hours, the towel material comprising 50% by weight of alginate fibers derived from seaweed and 50% by weight of Tencel fibers relative to the total weight of the towel material, wherein the weight ratio of the towel material to the composition was 1:13.5. The content of retinyl palmitate in the extruded composition was then determined according to the procedure of Inventive Example 2.

[0162] In Inventive Example (IE.) 4, 20 g of the composition in Table 4 was immersed in a towel material for 12 hours, the towel material comprising 100 wt % of alginate fibers derived from seaweed relative to the total weight of the towel material, wherein the weight ratio of the towel material to the composition was 1:13.5. The content of retinyl palmitate in the extruded composition was then determined according to the procedure of Inventive Example 2.

[0163] In Comparative Example (CE.) 5, 20 g of the composition in Table 4 was impregnated into a towel made of viscose fiber, wherein the weight ratio of the water-insoluble substrate to the composition was 1:13.5. The content of retinyl palmitate in the extruded composition was then determined according to the procedure of Inventive Example 2.

[0164] The content of retinyl palmitate in each of the compositions extruded in Inventive Examples 2-4 and Comparative Example 5 is summarized in Table 5.

[0165] Table 5

[0166]

[0167]

[0168] As can be seen from Table 5, the content of retinyl palmitate is higher when impregnated into alginate towels compared to towels made from viscose fibers, and the dosage will become higher as the composition of alginate fibers in the towel increases.

Claims

1. A composition for caring for keratin materials, comprising: a) at least one retinoid; and b) Combination of the following antioxidants i) ascorbic acid or its derivatives, ii) tocopherol or a derivative thereof, and iii) at least one hydroxyhydrocinnamate antioxidant.

2. The composition according to claim 1, wherein the retinoid is selected from retinol, retinal, retinoic acid, retinol and C2-C 20 Esters of acids, and combinations thereof, preferably, the retinoid is selected from retinol, retinyl palmitate, and combinations thereof.

3. The composition according to claim 1 or 2, wherein the retinoid is present in an amount of 0.1 wt% to 5 wt%, preferably 0.1 wt% to 2 wt%, more preferably 0.15 wt% to 1 wt%, relative to the total weight of the composition.

4. The composition according to any one of claims 1 to 3, comprising one or more of aminopropanol ascorbyl phosphate, ascorbic acid polypeptide, ascorbyl dipalmitate, ascorbyl glucoside, ascorbyl linoleate, ascorbyl methylsilanol pectinate, ascorbyl palmitate, ascorbyl tetraisopalmitate, trisodium ascorbyl palmitate phosphate, disodium ascorbyl sulfate, calcium ascorbate, methylsilanol ascorbate, sodium ascorbate, sodium ascorbyl phosphate, sodium ascorbyl phosphate / cholesterol phosphate, tetrahexyldecyl ascorbyl and magnesium ascorbyl phosphate, preferably, the composition comprises ascorbic acid and / or ascorbyl glucoside.

5. The composition according to any one of claims 1 to 4, wherein ascorbic acid or a derivative thereof is present in an amount of 0.05 to 3 wt. %, preferably 0.1 to 2 wt. %, more preferably 0.15 to 1 wt. %, relative to the total weight of the composition.

6. The composition according to any one of claims 1 to 5, comprising one or more of tocopherol, tocopherol acetate, tocopherol linoleate, tocopherol linoleate / oleate, tocopherol nicotinate, tocopherol retinoate, sodium tocopherol phosphate and dioleyl tocopheryl methylsilanol, preferably, the composition comprises tocopherol.

7. A composition according to any one of claims 1 to 6, wherein tocopherol or a derivative thereof is present in an amount of 0.05 to 3 wt. %, preferably 0.1 to 2 wt. %, more preferably 0.15 to 1 wt. %, relative to the total weight of the composition.

8. The composition of any one of claims 1 to 7, wherein the hydroxyhydrocinnamate antioxidant is selected from pentaerythritol tetra-di-tert-butyl hydroxyhydrocinnamate, octadecyl di-tert-butyl-4-hydroxyhydrocinnamate, tetra-dibutyl pentaerythritol hydroxyhydrocinnamate, and combinations thereof.

9. The composition according to any one of claims 1 to 8, wherein the hydroxyhydrocinnamate antioxidant is present in an amount of 0.05 to 3 wt%, preferably 0.1 to 2 wt%, more preferably 0.15 to 1 wt%, relative to the total weight of the composition.

10. The composition according to claim 1, comprising, relative to the total weight of the composition: a) 0.15% to 1% by weight of retinol and / or retinyl palmitate; and b) Combination of the following antioxidants i) 0.15% to 1% by weight of ascorbic acid or ascorbyl glucoside, ii) 0.15% to 1% by weight of tocopherol, and iii) 0.15 to 1 wt% of at least one hydroxyhydrocinnamate antioxidant selected from pentaerythritol tetra-di-tert-butyl hydroxyhydrocinnamate, octadecyl di-tert-butyl-4-hydroxyhydrocinnamate, tetra-dibutyl pentaerythritol hydroxyhydrocinnamate, and combinations thereof.

11. A mask for caring for keratin materials, the mask comprising: A) Hydrophilic film towel, and B) A composition according to any one of claims 1 to 10 impregnated into the film-applying towel.

12. The film according to claim 11, wherein the water-insoluble film towel is an alginate towel, the alginate towel contains water-insoluble alginate, the water-insoluble alginate is selected from calcium alginate, strontium alginate, zinc alginate, copper alginate, manganese alginate, or a combination thereof, preferably calcium alginate, preferably in an amount of 20 wt % to 100 wt %, preferably 20 wt % to 50 wt % relative to the total weight of the towel.

13. A non-therapeutic method for caring for keratin materials, comprising the step of applying a composition according to any one of claims 1 to 10 or a mask according to claim 11 or 12 to the keratin materials.

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