Process for separating nickel and magnesium and use thereof
CN112442605BActive Publication Date: 2026-08-28BOTREE CYCLING SCI &TECH CO LTD
Patent Information
- Application Number
- CN202011330247.1
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2020-11-24
- Publication Date
- 2026-08-28
- Estimated Expiration
- 2040-11-24
AI Technical Summary
Technical Problem
但是这种方法选用的萃取剂萃取镍的时候会带很多的锂上去,需要用大量的酸把锂洗下来,这样一来就造成了镍的萃取成本高,回收率低等不足,并且镍和锂的分离效率也有待提高
Benefits of technology
[0052]本发明提供的镍和镁的分离方法中,首先将包含特定结构的羧酸类化合物的萃取有机相进行皂化处理,得到皂化有机相,随后利用皂化有机相对镍镁料液进行萃取,将镍和镁分离,最后对萃取后含有镍的有机相进行反萃取,得到再生有机相和金属离子富集溶液,整个过程操作简便、酸耗低、对环境友好,并且本发明提供的分离方法不仅离子分离效果好,而且所使用的萃取试剂溶解度低,稳定,再生后可循环使用,有利于成本降低,可以应用于大批量工业化应用。
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Abstract
The application provides a method for separating nickel and magnesium and application thereof, and the separation method comprises the following steps: (1) configuring high-purity extractant and diluent into an extraction organic phase with a certain volume fraction, and then performing saponification reaction on the extraction organic phase with an alkaline compound to obtain a saponified organic phase; the extractant comprises a specific carboxylic acid compound BC197; (2) mixing, extracting and layering a nickel-magnesium feed liquid with the saponified organic phase obtained in step (1) to obtain a loaded organic phase and a raffinate aqueous phase; (3) performing back extraction on the loaded organic phase obtained in step (2) with a back extraction agent to obtain a metal ion enrichment solution and a regenerated organic phase; the whole separation process is simple in operation, low in acid consumption and friendly to the environment; the separation method has good separation effect on nickel and magnesium, is high in separation coefficient, low in back extraction acidity, and is low in water solubility of the used extraction reagent, stable, and recyclable after regeneration, so that the separation cost is reduced, and the method is suitable for large-scale application.
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Citation Information
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