A device and method for efficiently recovering tungsten from tungsten-containing waste
CN116555594BActive Publication Date: 2026-08-28GANNAN NORMAL UNIV +2
Patent Information
- Application Number
- CN202310633654.7
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2023-05-31
- Publication Date
- 2026-08-28
- Estimated Expiration
- 2043-05-31
AI Technical Summary
Technical Problem
与直接回收法相比,化学回收法流程长,且消耗更多的能源和化学试剂;因此,应用化学法回收的含钨废料往往是杂质含量高、成分复杂,无法应用直接法或者熔炼法回收
Benefits of technology
(1)本发明的颗粒分层焙烧提高了高含钨废料的氧化效率,解决了致密钨氧化物膜层导致的高含钨废料氧化效率和氧化率低,以及氧化周期长的问题。传统焙烧方法处理致密钨颗粒废料存在氧化慢、升华慢、生产效率非常低的问题;例如,在使用转炉对高含钨废料进行氧化时,完全氧化的时间根据含钨废料颗粒粒径、通入气氛等通常需要15~40h,而在空气中自然氧化的情况下,高含钨废料完全氧化的时间则需要7~45天。本发明基于颗粒表面快速氧化和双室真空升华,可实现致密钨废料颗粒的快速氧化和氧化物的快速升华冷凝,将高含钨废料彻底氧化时间缩短至0.5~6h,缩短了回收工艺流程,极大程度提高了生产效率。
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Figure CN116555594B_ABST
Abstract
The application discloses a device and method for efficiently recovering tungsten from tungsten-containing waste, which comprises an oxidation device, a heat exchange-normal pressure condensation recovery device, a vacuum condensation recovery device, an oxidation detection device and a control device. The oxidation device is used for roasting and oxidizing the tungsten-containing waste. The heat exchange-normal pressure condensation recovery device is used for recovering the tungsten oxide and heat generated in the tail gas of the tungsten-containing waste. The vacuum condensation recovery device is used for sublimation and deposition of the tungsten oxide. When the tungsten on the surface of the tungsten-containing waste particles is completely oxidized according to the detection result of the oxidation detection device, the oxidation is stopped, the first valve is closed, and the oxidation furnace is sealed. Then, the second valve is opened, and after the sublimation and deposition of the tungsten oxide are completed, the second valve is closed. The roasting-condensation recovery cycle is repeated for multiple times. The application improves the oxidation efficiency of the tungsten-containing waste, and recovers the tungsten oxide product with high purity and fine granularity from the tungsten-containing waste.
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Citation Information
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