Lightweight safety energy-saving composite hollow glass and manufacturing method thereof

Abstract

The application relates to a manufacturing method of light-weight safe energy-saving composite hollow glass, and belongs to the field of building materials. A middle interlayer product is formed by bonding a nanometer ATO film between two layers of transparent PMMA organic modified materials; a plurality of round holes are formed near the periphery of the middle interlayer product to obtain a middle interlayer finished product; a first square frame is bonded between the T-DLs180 ultra-low radiation glass film surface of the first layer and the middle interlayer finished product; a second square frame is bonded between the middle interlayer finished product and the TXITNO189 glass film surface of the fourth layer; a cross-row type non-metal rigid displacement prevention reinforcing device is arranged between the middle interlayer finished product and the fourth layer, and the long ends of a plurality of cylinders are correspondingly inserted into the round holes; structural sealant is filled into annular grooves between the T-DLs180 glass, the middle interlayer finished product and the outer circumferential surface of the first square frame, and between the TXITNO189 glass, the middle interlayer finished product and the outer circumferential surface of the second square frame; and inert gas is filled into the cavities of the two square frames. The hollow glass is used for preparing building doors and windows.

Description

TECHNICAL FIELD

[0001] The present application belongs to the technical field of building materials, and particularly relates to a light-weight safe energy-saving composite hollow glass and a manufacturing method thereof. BACKGROUND

[0002] Hollow glass has been used in the field of construction for more than a hundred years, and has the characteristics of good transparency, sound insulation and heat preservation. The specific gravity of glass is 2500 kg / m³. In order to save energy and heat preservation, three single-layer glasses are usually used to form a hollow glass. Taking a glass thickness of 6 mm as an example, the weight of 1 square meter of three-layer hollow glass is 45 kg (the weight of the spacer and the sealant is not included). The weight of the glass itself has a high requirement on the frame material and hardware of the door and window, and increases the weight of the door and window and the load of the building, which is not conducive to the reasonable saving and carbon reduction of building materials.

[0003] Glass is a fragile product. Even if it is tempered glass or laminated glass, its safety cannot be guaranteed. Under the action of external force, tempered glass and laminated glass can be easily penetrated, which is not conducive to safety, theft prevention and anti-impact.

[0004] The current mainstream application of energy-saving glass on the market is LOW-E tempered hollow glass. The spacer layer of the hollow glass plays a role in blocking convection and reducing heat conduction. LOW-E is realized by magnetron sputtering silver on the inner surface of the outer glass to reflect infrared rays, so it has the characteristics of heat insulation and heat preservation. However, the LOW-E tempered hollow glass only blocks the heat of radiation, and the glass itself has a large thermal conductivity coefficient. The coating does not change the heat conduction performance of the glass, which is also a defect of the hollow glass in energy saving.

[0005] Therefore, it is an urgent problem to study a light-weight safe energy-saving composite hollow glass. SUMMARY

[0006] The purpose of the present application is to overcome the defects of the prior art, and to provide a light-weight safe energy-saving composite hollow glass and a manufacturing method thereof.

[0007] Compared with the existing hollow glass, the hollow glass of the present application reduces the weight of the glass and strengthens the safety and anti-impact function of the glass, and solves the problem of heat transmission caused by conduction of the hollow glass.

[0008] The technical scheme adopted by the present application is as follows:

[0009] The application discloses a light-weighted safe energy-saving composite hollow glass, which is a four-layer two-cavity structure, wherein: the first layer is used as the outermost layer and adopts T-DLs180 ultra-low radiation glass; the second layer and the third layer are used as the intermediate layers and both adopt transparent PMMA organic modified material, and a nano ATO film is bonded between the two layers of transparent PMMA organic modified material to form an intermediate laminated layer product, a plurality of round holes are processed near the outer edge of the intermediate laminated layer product, and the intermediate laminated layer product is obtained; the fourth layer is used as the innermost layer and adopts T-XITNO189 Low-E glass; a first square frame is bonded between the film surface of the first layer and the intermediate laminated layer product, a second square frame is bonded between the film surface of the fourth layer and the intermediate laminated layer product, a cross-row type non-metal rigid displacement prevention reinforcing device is arranged between the intermediate laminated layer product and the fourth layer, and the long ends of a plurality of cylinders of the cross-row type non-metal rigid displacement prevention reinforcing device are inserted into the round holes in a one-to-one correspondence; structural sealant is filled in annular grooves formed between the T-DLs180 ultra-low radiation glass and the outer circumferential surface of the intermediate laminated layer product and the first square frame and between the TXITNO189 Low-E glass and the outer circumferential surface of the intermediate laminated layer product and the second square frame; and inert gas is filled in the inner cavities of the first square frame and the second square frame.

[0010] Further, the thickness of the T-DLs180 ultra-low radiation glass of the first layer is 5 mm, 6 mm or 8 mm; the thickness of the transparent PMMA organic modified material of the second layer and the third layer is 1.5-3 mm; the thickness of the T-XITNO189 Low-E glass of the fourth layer is 5 mm, 6 mm or 8 mm; and the thickness of the nano ATO film is 0.5-1.0 mm.

[0011] Further, the transparent PMMA organic modified material is made of the following raw materials in parts by weight: ABS 5-10 parts, HIPS 7-15 parts, ultraviolet absorber 0.2-1.0 part, infrared barrier 0.4-1.2 part, carbon fiber 0.5-1.0 part and transparent PMMA material 85-90 parts.

[0012] Further, the nano ATO film is made of the following raw materials in parts by weight: cesium tungsten bronze 0.2-2 parts, tin antimony oxide 0.2-2 parts, tackifier 5-10 parts, antioxidant 3-7 parts and thermoplastic resin base 82-90 parts.

[0013] Further, the cross-row type non-metal rigid displacement prevention reinforcing device comprises a long rod and a plurality of cylinders, the long rod is fixed with the plurality of cylinders penetrating out at equal intervals, the two ends of the plurality of cylinders are flush respectively, the lengths of the plurality of cylinders penetrating out of the long rod are different, one end is a long end and the length of the long end penetrating out of the long rod is 4 mm; the other end is a short end and the length of the short end penetrating out of the long rod is 3 mm, and the center distance between adjacent two cylinders is 100-150 mm.

[0014] Further, the cross-arrangement type non-metal rigid displacement prevention reinforcing device is made of polytetrafluoroethylene material.

[0015] A manufacturing method of a light-weight safe energy-saving composite hollow glass, the manufacturing method comprising the following steps:

[0016] Step one: preparing an intermediate adhesive layer product;

[0017] Step two: according to the size of the produced hollow glass, processing several Φ2.5-3.0mm round holes at a distance of 5-7mm from the outer edge of the intermediate adhesive layer product, to obtain an intermediate adhesive layer finished product;

[0018] Step three: cleaning two pieces of glass of the same size with a cleaning machine, the two pieces of glass being T-DLs180 ultra-low emissivity glass and TXITNO189 Low-E glass respectively;

[0019] Step four: bending a rigid warm edge spacer into two square frame bodies, the four corners of the square frame bodies being 90°, each square frame body being filled with molecular sieve desiccant, and the length of the four sides of the square frame body being 7mm shorter than the corresponding length of the glass; the two square frame bodies being a first square frame body and a second square frame body respectively;

[0020] Step five: uniformly applying butyl sealant to both sides of the two square frame bodies;

[0021] Step six: vertically placing the T-DLs180 ultra-low emissivity glass cleaned in step three on a vertical hollow glass assembling machine, with the film facing inwards, bonding one side of the first square frame body to the film surface of the T-DLs180 ultra-low emissivity glass, and the length and width directions of the first square frame body corresponding to and centrally bonded to the length and width directions of the T-DLs180 ultra-low emissivity glass respectively;

[0022] Step seven: centrally bonding the intermediate adhesive layer finished product prepared in step two to the other side of the first square frame body in alignment with the four sides;

[0023] Step eight: bonding one side of the second square frame body to the other side of the intermediate adhesive layer finished product, and the length and width directions of the second square frame body corresponding to and centrally bonded to the length and width directions of the intermediate adhesive layer finished product respectively;

[0024] Step nine: according to the length of the glass, reducing 7mm from both ends of the cross-arrangement type non-metal rigid displacement prevention reinforcing device, and inserting the plurality of cylinders into the round holes in the intermediate adhesive layer finished product, so that the cylinders are parallel to the corresponding side frames of the square frame bodies;

[0025] Step ten: align the TXITNO189 Low-E glass with the T-DLs180 ultra-low emissivity glass four sides, the film surface of the TXITNO189 Low-E glass is bonded to the other side of the second frame body, the long and wide directions of the second frame body are respectively corresponding to and centered bonded to the long and wide directions of the TXITNO189 Low-E glass, and a glass semi-finished product is prepared;

[0026] Step eleven: send the glass semi-finished product into a heat sealing machine, and realize sealing of each contact surface through a hot press forming process;

[0027] Step twelve: fill structural sealant into the annular grooves formed between the T-DLs180 ultra-low emissivity glass and the intermediate laminated layer product and the first frame body, and between the TXITNO189 Low-E glass and the intermediate laminated layer product and the second frame body, and make the surface of the filled structural sealant flush with the corresponding end surface of the glass;

[0028] Step thirteen: fill more than 90% of inert gas into the cavities of the two frame bodies to prepare a glass finished product.

[0029] Further, in step one, the specific steps for preparing the intermediate laminated layer product are as follows:

[0030] Step 11: cut two pieces of transparent PMMA organic modified material and a nanoscale ATO film into the same size according to the length and width, and place them in a silica gel bag, and place the nanoscale ATO film between the two pieces of transparent PMMA organic modified material;

[0031] Step 12: after sealing the silica gel bag, use a vacuum pump to extract the air in the silica gel bag, and cold extraction for 15-25 min at room temperature, and the vacuum degree is between -98 and -100.8 kPa;

[0032] Step 13: place the vacuumized silica gel bag in a lamination furnace, heat the lamination furnace to 50-70℃, and keep for 20-30 min; then heat the lamination furnace to 105-110℃, and keep for 45-60 min;

[0033] Step 14: take out the silica gel bag from the lamination furnace, and after reducing the temperature to room temperature, open the silica gel bag, and take out the intermediate laminated layer product.

[0034] Further, in step 11, the thickness of the two pieces of transparent PMMA organic modified material is 1.5-3.0 mm, and the thickness of the nanoscale ATO film is 0.5-1.0 mm.

[0035] Further, in step nine, the cross-shaped array type non-metal rigid displacement prevention reinforcing device includes a long rod and a plurality of cylinders, the long rod is fixed with the plurality of cylinders penetrating out at equal intervals, the two ends of the plurality of cylinders are flush respectively, the lengths of the plurality of cylinders penetrating out of the long rod are different, one end is a long end, the length of the long end penetrating out is 4mm; the other end is a short end, the length of the short end penetrating out is 3mm, the center distance of adjacent two cylinders is 100-150mm.

[0036] The beneficial effects of the present application are:

[0037] 1. The present application provides a light-weight, safe and energy-saving composite hollow glass, aiming to realize the light-weight of building glass and reduce the weight load of door and window frame materials, door and window hardware, and building foundation.

[0038] 2. It has the safety performance of anti-theft, anti-smashing, anti-falling and difficult to be penetrated by external force.

[0039] 3. It improves the solar heat gain coefficient SHGC (also known as g value), reduces the heat transfer coefficient K value, and reduces noise and other special functions.

[0040] 4. The T-DLs180 ultra-low emissivity glass adopts an internationally advanced reflective nano thermal insulation coating, which weakens and filters out infrared radiation through the nano thermal insulation coating, successfully solving the difficult problem of coexistence of high light transmittance and low K value.

[0041] 5. The nano coating of TXITNO189 Low-E glass does not contain metal silver ions, the light transmittance is ≥87%, the solar heat gain coefficient is improved, and the solar heat gain coefficient SHGC=0.75.

[0042] 6. The intermediate laminated layer finished product processed by the lamination process is made of modified transparent PMMA organic modified material and nano ATO film, and is processed by an EVA lamination furnace.

[0043] 7. Carbon fibers are added to the transparent PMMA raw material to improve the mechanical strength; ABS is added to improve the bending modulus and heat resistance; HIPS is added to improve the impact toughness and improve the surface finish.

[0044] 8. The specific gravity of the transparent PMMA organic modified material is 1200kg / m³, the specific gravity of the glass is 2500kg / m³, the weight ratio of the transparent PMMA organic modified material to the glass with the same thickness is 1.2:2.5, and the weight is reduced by more than 50%, that is, the intermediate laminated layer finished product processed by the lamination process has obvious light weight performance.

[0045] 9. The nano ATO film (thickness of 0.5-1.0mm) contains cesium tungsten bronze, tin oxide antimony and other infrared blockers, which can block 70-75% of infrared rays. BRIEF DESCRIPTION OF DRAWINGS

[0046] Figure 1 is a schematic view of the structure of the intermediate laminated product.

[0047] Figure 2 is a schematic view of the structure of the intermediate laminated product.

[0048] Figure 3 is a schematic view of the structure of the cross-row type non-metal rigid displacement prevention reinforcing device.

[0049] Figure 4 is a top view of a lightweight, safe and energy-saving composite hollow glass according to the present application. DETAILED DESCRIPTION

[0050] The following examples are implemented on the premise of the technical solutions of the present application, and detailed implementation modes and specific operation processes are given, but the protection scope of the present application is not limited to the following examples. The methods used in the following examples are all conventional methods unless otherwise specified. EXAMPLE

[0051] As shown in Figures 1-4 , a lightweight, safe and energy-saving composite hollow glass, the hollow glass is a four-layer two-cavity structure, wherein: the first layer 1 as the outermost layer adopts T-DLs180 ultra-low emissivity glass (this glass is a prior art); the second layer 2 and the third layer 3 as the intermediate layer both adopt transparent PMMA organic modified material, and a nano ATO film 4 is glued between the two layers of transparent PMMA organic modified material to form an intermediate laminated product 5, a plurality of Φ2-2.5mm round holes 6 are processed at a distance of 5-7mm from the outer edge of the four sides of the intermediate laminated product 5, the center distance t1 of adjacent round holes 6 is 100-150mm, and an intermediate laminated product 7 is obtained; the fourth layer 8 as the innermost layer adopts T-XITNO189Low-E glass (this glass is a prior art); a first square frame body 11 is glued between the film surface of the first layer 1 and the intermediate laminated product 7, a second square frame body 12 is glued between the film surface of the fourth layer 8 and the intermediate laminated product 7, and a cross-row type non-metal rigid displacement prevention reinforcing device 9 is placed between the intermediate laminated product 7 and the fourth layer 8, the long ends 10 of a plurality of cylinders of the cross-row type non-metal rigid displacement prevention reinforcing device 9 are inserted into the round holes 6 one by one; the annular grooves formed between the T-DLs180 ultra-low emissivity glass and the outer circumferential surface of the intermediate laminated product 7 and the first square frame body 11, and the annular grooves formed between the TXITNO189Low-E glass and the outer circumferential surface of the intermediate laminated product 7 and the second square frame body 12 are filled with structural sealant; and the inner cavities of the first square frame body 11 and the second square frame body 12 are filled with inert gas.

[0052] Further, the thickness of the T-DLs 180 ultra-low emissivity glass of the first layer 1 is 5 mm, 6 mm or 8 mm; the thickness of the transparent PMMA organic modified material of the second layer 2 and the third layer 3 is 1.5-3 mm (for example, the thickness of the transparent PMMA organic modified material is 1.5 mm, 2.0 mm, 2.5 mm or 3.0 mm); the thickness of the T-XIT NO 189 Low-E glass of the fourth layer 8 is 5 mm, 6 mm or 8 mm; the thickness of the nanoscale ATO film 4 is 0.5-1.0 mm (for example, the thickness of the nanoscale ATO film 4 is 0.5 mm or 1.0 mm).

[0053] Further, the transparent PMMA organic modified material is made of the following raw materials by weight: ABS 5-10 parts, HIPS 7-15 parts, ultraviolet absorber 0.2-1.0 parts, infrared barrier 0.4-1.2 parts, carbon fiber 0.5-1.0 parts, and transparent PMMA material 85-90 parts.

[0054] Further, the nanoscale ATO film 4 is made of the following raw materials by weight: cesium tungsten bronze 0.2-2 parts, tin antimony oxide 0.2-2 parts, tackifier 5-10 parts, antioxidant 3-7 parts, and thermoplastic resin base 82-90 parts.

[0055] Further, the cross-row type non-metallic rigid displacement prevention reinforcing device 9 includes a long rod 13 and a plurality of cylinders, the long rod 13 is fixed with a plurality of cylinders penetrating out at equal intervals, the two ends of the plurality of cylinders are flush respectively, the lengths of the plurality of cylinders penetrating out of the long rod 13 are different, one end is a long end 10, the length L1 penetrating out of the long end 10 is 4 mm; the other end is a short end 14, the length L2 penetrating out of the short end 14 is 3 mm, the center distance t2 of adjacent two cylinders is 100-150 mm.

[0056] Further, the cross-row type non-metallic rigid displacement prevention reinforcing device 9 is made of polytetrafluoroethylene material. Embodiment

[0057] As shown in Figures 1-4 A manufacturing method of a lightweight, safe, energy-saving and composite type hollow glass, the manufacturing method comprises the following steps (intermediate laminated product 5→ intermediate laminated product 7→ cleaning→ bonding→ upper piece (T-DLs 180 ultra-low emissivity glass)→ bonding→ insertion→ upper piece (TXIT NO 189 Low-E glass)→ glue injection→ inert gas filling→ glass product):

[0058] Step one: preparing the intermediate laminated product 5;

[0059] Step two: according to the size of the hollow glass produced, a number of Φ2.5-3.0mm round holes 6 are drilled in the middle interlayer product 5 at a distance of 5-7mm from the outer edge 5, the center distance t1 between adjacent round holes 6 is 100-150mm, and the middle interlayer finished product 7 is obtained;

[0060] Step three: two pieces of glass of the same size are cleaned with a cleaning machine, and the two pieces of glass are T-DLs180 ultra-low emissivity glass and TXITNO189 Low-E glass (the thickness of the two pieces of glass is 5mm, 6mm or 8mm);

[0061] Step four: a rigid warm edge spacer strip (a professional name in the field) with a width of 12-18mm is bent into two square boxes, the four corners of the square box are 90°, molecular sieve desiccant is filled in each square box, and the length of the four sides of the square box is 7mm shorter than the corresponding length of the glass; the two square boxes are a first square box 11 and a second square box 12;

[0062] Step five: the two sides of the two square boxes are uniformly coated with butyl sealant;

[0063] Step six: the T-DLs180 ultra-low emissivity glass cleaned in step three is placed vertically on a vertical hollow glass combining machine, the film surface faces inwards, one side of the first square box 11 is bonded to the film surface of the T-DLs180 ultra-low emissivity glass, and the length and width directions of the first square box 11 correspond to and are centrally bonded to the length and width directions of the T-DLs180 ultra-low emissivity glass;

[0064] Step seven: the middle interlayer finished product 7 prepared in step two is centrally bonded to the other side of the first square box 11 in alignment with the four sides;

[0065] Step eight: one side of the second square box 12 is bonded to the other side of the middle interlayer finished product 7, and the length and width directions of the second square box 12 correspond to and are centrally bonded to the length and width directions of the middle interlayer finished product 7;

[0066] Step nine: the cross-row type non-metallic rigid displacement prevention reinforcing device 9 is reduced by 7mm at both ends according to the length of the glass, and a number of cylindrical long ends 10 are inserted into the round holes 6 of the middle interlayer finished product 7 (the insertion length is 4mm), so that the cylinders are parallel to the corresponding edge frames of the square boxes;

[0067] Step ten: the TXITNO189 Low-E glass is aligned with the four sides of the T-DLs180 ultra-low emissivity glass, the film surface of the TXITNO189 Low-E glass is bonded to the other side of the second square box 12, and the length and width directions of the second square box 12 correspond to and are centrally bonded to the length and width directions of the TXITNO189 Low-E glass, thereby obtaining a glass semi-finished product.

[0068] Step eleven: send the glass semi-finished product into a heat sealing machine, and realize the sealing of the contact surfaces by a heat compression molding process (which is prior art);

[0069] Step twelve: fill the structural sealant into the annular grooves formed between the T-DLs 180 ultra-low emissivity glass and the intermediate laminated glass product 7 and the outer circumferential surface of the first square frame 11, and between the TXITNO 189 Low-E glass and the intermediate laminated glass product 7 and the outer circumferential surface of the second square frame 12, and make the surface of the filled structural sealant flush with the corresponding end surface of the glass;

[0070] Step thirteen: fill more than 90% of inert gas in the cavities of the two square frames to make the glass product.

[0071] Further, in step one, the specific steps for preparing the intermediate laminated glass product 5 (cutting → stacking → vacuumizing → first heat treatment → second heat treatment → cooling → intermediate laminated glass product 5 → drilling to make the intermediate laminated glass product 7) are as follows:

[0072] Step 11: cut two pieces of transparent PMMA organic modified material and the nanoscale ATO film 4 to the same length and width, and put them into a silica gel bag, and place the nanoscale ATO film 4 between the two pieces of transparent PMMA organic modified material;

[0073] Step 12: after sealing the silica gel bag, use a vacuum pump to extract the air in the silica gel bag, and cold extract for 15-25 minutes at room temperature, with a vacuum degree of -98 to -100.8 kPa;

[0074] Vacuumizing makes the three layers of materials completely free of air;

[0075] Step 13: place the vacuumized silica gel bag in a laminated glass furnace, heat the laminated glass furnace to 50-70℃, and keep for 20-30 minutes; then heat the laminated glass furnace to 105-110℃, and keep for 45-60 minutes (the holding time can be appropriately prolonged if the thickness of the film or the number of intermediate laminated layers increases);

[0076] Step 14: take the silica gel bag out of the laminated glass furnace, and after reducing the temperature to room temperature (using a fan), open the silica gel bag, and take out the intermediate laminated glass product 5.

[0077] Further, in step 11, the thickness of the two pieces of transparent PMMA organic modified material is 1.5-3.0 mm (such as 1.5, 2.0, 2.5 or 3.0 mm), and the thickness of the nanoscale ATO film 4 is 0.5-1.0 mm (such as 0.5 or 1.0 mm).

[0078] Further, in step nine, the cross-row type non-metal rigid displacement prevention reinforcing device 9 includes a long rod 13 and a plurality of cylinders, the long rod 13 is fixed with the plurality of cylinders penetrating out at equal intervals, two ends of the plurality of cylinders are flush respectively, lengths of the plurality of cylinders penetrating out of the long rod 13 are different, one end is a long end 10, a length L1 penetrating out of the long end 10 is 4 mm; the other end is a short end 14, a length L2 penetrating out of the short end 14 is 3 mm, a center distance t2 between adjacent two cylinders is 100-150 mm.

[0079] The specific embodiments of the present application are further described below with reference to the accompanying drawings:

[0080] The organic modified material is processed by the EVA sandwiching process, has good heat insulation performance, and can significantly reduce the heat transfer coefficient K value of the glass. The intermediate sandwiching layer product processed by the EVA sandwiching process has higher strength, and is difficult to be broken and penetrated by a blunt instrument, has strong safety, high light transmittance, and plays a positive role in reducing the thermal conductivity and the heat transfer coefficient K value. After the transparent PMMA organic modified material and the nanoscale ATO film are processed by the EVA sandwiching process, the thermal conductivity λ is 0.11 W / (m.K), the light transmittance is greater than or equal to 80%, the solar heat gain coefficient SHGC (also referred to as g value) is greater than or equal to 0.68, and the EVA sandwiching process is the existing process.

[0081] The long end (4 mm end) of the cross-row type non-metal rigid displacement prevention reinforcing device is inserted into the round hole of the intermediate sandwiching layer product, and after structure sealant adhesion curing, the cross-row type non-metal rigid displacement prevention reinforcing device, the rigid warm edge spacing strip (square box), the intermediate sandwiching layer product and the TXITNO189 Low-E glass form a firm whole, which avoids the separation of the rigid warm edge spacing strip and the intermediate sandwiching layer product due to the action of external force, and makes the insulating glass have firmness and safety.

[0082] The above only describes the preferred embodiments of the present application, but the protection scope of the present application is not limited to this. Any person skilled in the art can make equivalent replacement, change or modification according to the technical scheme and the inventive concept of the present application within the technical range disclosed by the present application, which should be covered in the protection scope of the present application.

Claims

1. A lightweight, safe, and energy-saving composite insulating glass, characterized in that: The hollow glass is a four-layer two-cavity structure, wherein: the first layer (1) as the outermost layer adopts T-DLs180 ultra-low emissivity glass; the second layer (2) and the third layer (3) as the intermediate layer both adopt transparent PMMA organic modified material, and a nano ATO film (4) is bonded between the two layers of transparent PMMA organic modified material to form an intermediate laminated layer product (5), a plurality of round holes (6) are processed near the outer edge of the intermediate laminated layer product (5), and an intermediate laminated layer finished product (7) is obtained; the fourth layer (8) as the innermost layer adopts T-XITNO189 Low-E glass; the first square frame (11) is centrally bonded between the film surface of the first layer (1) and the intermediate laminated layer finished product (7); the second square frame (12) is centrally bonded between the film surface of the intermediate laminated layer finished product (7) and the fourth layer (8); and the cross-row type non-metal rigid displacement prevention reinforcing device (9) is placed between the intermediate laminated layer finished product (7) and the fourth layer (8); The cross-row type non-metal rigid displacement prevention reinforcing device (9) comprises a long rod (13) and a plurality of cylinders, the long rod (13) is fixed with a plurality of cylinders penetrating out at equal intervals, the two ends of the plurality of cylinders are flush respectively, and the lengths of the plurality of cylinders penetrating out of the long rod (13) are different, wherein one end is a long end (10), the length (L1) of the long end (10) penetrating out is 4mm; the other end is a short end (14), the length (L2) of the short end (14) penetrating out is 3mm, and the center distance (t2) of adjacent two cylinders is 100-150mm; The long end (10) of the plurality of cylinders of the cross-row type non-metal rigid displacement prevention reinforcing device (9) is inserted into the round hole (6) one by one; the annular groove formed between the T-DLs180 ultra-low emissivity glass and the outer circumferential surface of the intermediate laminated layer finished product (7) and the first square frame (11) and the annular groove formed between the T-XITNO189 Low-E glass and the outer circumferential surface of the intermediate laminated layer finished product (7) and the second square frame (12) are filled with structural sealant; and the inner cavities of the first square frame (11) and the second square frame (12) are filled with inert gas; After the long end of the cross-row type non-metal rigid displacement prevention reinforcing device is inserted into the round hole of the intermediate laminated layer finished product and is bonded and solidified by the structural sealant, the cross-row type non-metal rigid displacement prevention reinforcing device, the second square frame, the intermediate laminated layer finished product and the T-XITNO189 Low-E glass form a firm whole.

2. The light-weighted safety and energy-saving composite insulating glass according to claim 1, characterized in that: The thickness of the T-DLs180 ultra-low emissivity glass of the first layer (1) is 5mm, 6mm or 8mm; the thickness of the transparent PMMA organic modified material of the second layer (2) and the third layer (3) is 1.5-3mm; the thickness of the T-XITNO189 Low-E glass of the fourth layer (8) is 5mm, 6mm or 8mm; and the thickness of the nano ATO film (4) is 0.5-1.0mm.

3. The light-weighted safety and energy-saving composite insulating glass according to claim 1, characterized in that: The transparent PMMA organic modified material is made of the following raw materials in parts by weight: ABS 5-10 parts, HIPS 7-15 parts, ultraviolet absorber 0.2-1.0 parts, infrared barrier 0.4-1.2 parts, carbon fiber 0.5-1.0 parts, and transparent PMMA material 85-90 parts.

4. The light-weighted safety and energy-saving composite insulating glass according to claim 1, characterized in that: The nanometer ATO film (4) is made of the following raw materials in parts by weight: cesium tungsten bronze 0.2-2 parts, tin antimony oxide 0.2-2 parts, tackifier 5-10 parts, antioxidant 3-7 parts, and thermoplastic resin base 82-90 parts.

5. The light-weighted safety and energy-saving composite insulating glass according to claim 1, characterized in that: The cross-row type non-metallic rigid displacement prevention reinforcing device (9) is made of polytetrafluoroethylene material.

6. A method of manufacturing the light-weighted safety energy-saving composite-type hollow glass according to any one of claims 1 to 5, characterized by: The manufacturing method comprises the following steps: Step one: preparing an intermediate adhesive layer product (5); Step two: according to the size of the produced hollow glass, processing several Φ2.5-3.0 mm round holes (6) at a distance of 5-7 mm from the outer edge of the intermediate adhesive layer product (5), to obtain an intermediate adhesive layer finished product (7); Step three: cleaning two pieces of glass of the same size with a cleaning machine, and the two pieces of glass are T-DLs180 ultra-low emissivity glass and T-XITNO189 Low-E glass respectively; Step four: bending the rigid warm edge spacer into two square frames, the four corners of the square frame are 90°, each square frame is filled with molecular sieve desiccant, and the length of the four sides of the square frame is 7 mm shorter than the corresponding length of the glass; the two square frames are a first square frame (11) and a second square frame (12) respectively; Step five: uniformly applying butyl sealant on both sides of the two square frames; Step six: placing the T-DLs180 ultra-low emissivity glass cleaned in step three vertically on a vertical hollow glass bonding machine, with the film facing inwards, bonding one side of the first square frame (11) to the film surface of the T-DLs180 ultra-low emissivity glass, and the length and width of the first square frame (11) correspond to and are centrally bonded to the length and width of the T-DLs180 ultra-low emissivity glass respectively; Step seven: aligning and centrally bonding the other four sides of the intermediate adhesive layer finished product (7) obtained in step two to the other side of the first square frame (11); Step eight: bonding one side of the second square frame (12) to the other side of the intermediate adhesive layer finished product (7), and the length and width of the second square frame (12) correspond to and are centrally bonded to the length and width of the intermediate adhesive layer finished product (7) respectively; Step nine: according to the length of the glass, reducing 7 mm from both ends of the cross-row type non-metallic rigid displacement prevention reinforcing device (9), and inserting the plurality of cylindrical long ends (10) into the round holes (6) in the intermediate adhesive layer finished product (7), so that the cylinders are parallel to the corresponding side frames of the square frame; Step ten: aligning the four sides of the T-XITNO189 Low-E glass with the T-DLs180 ultra-low emissivity glass, bonding the film surface of the T-XITNO189 Low-E glass to the other side of the second square frame (12), and the length and width of the second square frame (12) correspond to and are centrally bonded to the length and width of the T-XITNO189 Low-E glass respectively, to obtain a glass semi-finished product. Step eleven: send the glass semi-finished product into the heat sealing machine, and realize the sealing of the contact surfaces through the heat compression molding process; Step twelve: fill the structural sealant into the annular groove formed between the T-DLs180 ultra-low emissivity glass and the intermediate laminated layer product (7) and the outer peripheral surface of the first square box (11), and the annular groove formed between the T-XITNO189 Low-E glass and the intermediate laminated layer product (7) and the outer peripheral surface of the second square box (12), and make the surface of the filled structural sealant flush with the corresponding end surface of the glass; Step thirteen: fill more than 90% of inert gas in the cavities of the two square boxes to make the glass product.

7. The production method according to claim 6, wherein: In step one, the specific steps for preparing the intermediate laminated layer product (5) are as follows: Step 11: cut two pieces of transparent PMMA organic modified material and nanoscale ATO film (4) to the same length and width size, and put them into a silica gel bag, and place the nanoscale ATO film (4) between the two pieces of transparent PMMA organic modified material; Step 12: after sealing the silica gel bag, use a vacuum pump to extract the air in the silica gel bag, and cold extract for 15-25 min at room temperature, with a vacuum degree of -98 to -100.8 kPa; Step 13: place the vacuumized silica gel bag in a lamination oven, heat the lamination oven to 50-70℃, and keep for 20-30 min; then heat the lamination oven to 105-110℃, and keep for 45-60 min; Step 14: take out the silica gel bag from the lamination oven, and after reducing the temperature to room temperature, open the silica gel bag, and take out the intermediate laminated layer product (5).

8. The production method according to claim 7, characterized by: In step 11, the thickness of the two pieces of transparent PMMA organic modified material is 1.5-3.0 mm, and the thickness of the nanoscale ATO film (4) is 0.5-1.0 mm.

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