Carbon molecular sieve production system and method
By using clay instead of coal, and combining improvements to the kneading powder machine and constant temperature storage tank, the problems of high energy consumption, noise pollution, and fire risk in carbon molecular sieve production have been solved, achieving high-quality and stable carbon molecular sieve production.
Patent Information
- Application Number
- CN202410040634.3
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-01-11
- Publication Date
- 2026-02-06
- Estimated Expiration
- 2044-01-11
AI Technical Summary
Existing carbon molecular sieve production processes suffer from problems such as high energy consumption, severe noise pollution, high fire risk, and unstable product quality. Furthermore, raw material coal is a non-renewable resource, making pore size control difficult.
Using floral clay or floral clay scraps as raw materials, coarse and fine grinding is carried out using a kneading powder machine. Combined with improvements to the constant temperature storage tank and vacuum feeding machine, the motor power is reduced, static electricity and high temperature are prevented, and the temperature of the raw materials is ensured to be consistent. The pore size is optimized through multiple testing and deposition processes.
It reduces energy consumption and noise pollution, decreases fire risk, improves the quality stability and pore size control capability of carbon molecular sieves, and avoids resource waste and environmental pollution.
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Figure CN118005007B_ABST
Abstract
Description
TECHNICAL FIELD
[0001] The present application belongs to the technical field of carbon molecular sieve production, and relates to a carbon molecular sieve production system and method. BACKGROUND
[0002] Carbon molecular sieve is a new type of adsorbent developed in the 1970s, which is a kind of excellent non-polar carbon material. Carbon molecular sieve for nitrogen production (CMS) is used for separating oxygen and nitrogen in air, and finally the separated nitrogen is applied to the industries of corrosion prevention, explosion prevention and combustion prevention, such as aerospace, medicine, electronics, coal mine, cruise ship, oil field and food processing.
[0003] The carbon molecular sieve for nitrogen production originally adopts a normal temperature and low pressure nitrogen production process. The raw material in the original production process is mainly coal, which is a non-renewable material. Not only the non-renewable resources are consumed, but also the atmosphere environment is not friendly in the production process.
[0004] In addition, due to the limitation of the inherent characteristics of raw materials such as coal, there is a technical difficulty in controlling the pore size. Therefore, the pore size of most of the carbon molecular sieve for nitrogen production is distributed in 0.3-1nm, that is, the quality of the carbon molecular sieve for nitrogen production is medium and low grade.
[0005] The normal temperature and low pressure nitrogen production process provided by the prior art adopts a ball mill to coarsely grind the raw material, and a ball mill to finely grind the raw material after coarse grinding and drying. The motor power of the ball mill is large. It is understood that the motor of the coarse grinding process is at least 37KW, and the motor of the fine grinding process is generally not less than 55KW. Moreover, the ball grinding time is generally 35-40 hours, so there is a problem of large power consumption. Moreover, the noise pollution generated by the large power motor and the steel balls used for grinding in the ball mill during work is very serious, and the noise basically reaches 120 decibels.
[0006] The finely ground material is in nanometer level. When the material is sucked into the bin by vacuum, the vacuum material suction machine often does not stop when the material suction is finished. At this time, the idling causes the machine to heat. Or when production is stopped for a period of time and then started again, static electricity is accumulated due to the accumulation of raw materials at the pipe bend. These situations often cause fire, and the fire is difficult to extinguish. SUMMARY
[0007] The purpose of the present application is to provide a carbon molecular sieve production system and method for reducing the energy consumption of carbon molecular sieve production and improving the quality of carbon molecular sieve.
[0008] In a first aspect, the present application provides a carbon molecular sieve production system, comprising:
[0009] A feeding device for supplying the flower mud base to the next process;
[0010] A rubbing powder machine is designed and manufactured based on the rubbing principle, arranged at the coarse crushing station, used for receiving the flower mud base input by the feeding device, and after rubbing and crushing, the coarse crushed material meeting the first preset particle size is transported to the coarse crushed material bin by airflow with the first preset intensity;
[0011] A drying device receives the coarse crushed material of the preset weight input by the coarse crushed material bin, bakes the coarse crushed material according to the preset baking temperature and time, and transports the baked coarse crushed material meeting the requirements to the temporary storage bin after detection;
[0012] A rubbing powder machine is designed and manufactured based on the rubbing principle, arranged at the fine crushing station, used for receiving the coarse crushed material input by the temporary storage bin, and after rubbing and crushing, the fine powder material meeting the second preset particle size is transported to the fine crushed material bin by airflow with the second preset intensity, and the fine crushed material bin is a constant temperature bin;
[0013] A kneading mixer adds the fine powder material stored at constant temperature, resin and coal tar into the kneading mixer according to the preset mass ratio, and kneads to form the raw material in the kneading mixer;
[0014] An extruding machine is configured with a constant temperature storage tank, and the raw material is temporarily stored in the constant temperature storage tank; the constant temperature raw material output by the constant temperature storage tank is transported to the extruding barrel and the extruding screw arranged in the extruding barrel of the extruding machine, and the raw material is extruded to form the raw material strip by the extruding screw;
[0015] A screening machine receives the raw material strip output by the extruding machine, screens out the raw material strip meeting the preset size by the screening machine, and cools it to the first preset temperature;
[0016] A carbonization furnace receives the raw material strip output by the screening machine, completes carbonization at the preset carbonization temperature to form the carbonized strip, and cools it to the second preset temperature, and nitrogen is introduced into the carbonization furnace during the carbonization process;
[0017] A deposition furnace receives the carbonized strip output by the carbonization furnace, and uses the deposition furnace to perform deposition to form the deposited strip; during the deposition process, the aperture modulation solution is added multiple times, and nitrogen is introduced at the same time; after adding the aperture modulation solution each time, the deposited strip is sampled and detected, and the detection parameters at least include the tail gas amount of the deposited strip in the nitrogen making machine, the nitrogen purity and the hardness of the deposited strip; the deposited strip meeting the requirements is transported to the next process after the detection result reaches the requirements, and the deposited strip not meeting the requirements is deposited again until the detection result reaches the requirements; the deposited strip meeting the requirements is formed into the carbon molecular sieve after screening ash treatment.
[0018] As a possible implementation manner, the rubbing powder machine comprises a crushing box, a coarse crushing assembly, a fine crushing assembly, a motor and a transmission assembly.
[0019] The side wall of the crushing box is provided with adjacent feeding ports and air inlets, and the top wall of the crushing box is provided with a discharging port; the coarse crushing assembly is arranged in the crushing box and close to the feeding port; the coarse crushing assembly comprises a cylindrical first hollow rotating part extending from one side wall of the crushing box to the other side wall, and a plurality of first threaded rods arranged outside the cylindrical first hollow rotating part and extending from one side wall of the crushing box to the other side wall; the cylindrical first hollow rotating part and the first threaded rods have gaps therebetween.
[0020] The fine crushing assembly is arranged in the crushing box close to the air inlet; the fine crushing assembly comprises a cylindrical second hollow rotating part extending from one side wall of the crushing box to the other side wall, and a plurality of second threaded rods arranged outside the cylindrical second hollow rotating part and extending from one side wall of the crushing box to the other side wall; the second hollow rotating part and the second threaded rods have gaps therebetween; the second hollow rotating part and the first hollow rotating part rotate in opposite directions; the coarse crushing assembly and the fine crushing assembly are adjacent and through.
[0021] The motor is arranged at one end outside the crushing box.
[0022] The power input end of the transmission assembly is connected with the power output end of the motor, and the power output ends of the transmission assembly are connected with the first hollow rotating part and the second hollow rotating part.
[0023] As a possible implementation manner, the gap between the cylindrical first hollow rotating part and the first threaded rods is D1, the gap between the second hollow rotating part and the second threaded rods is D2, and D1>D2.
[0024] As a possible implementation manner, the rubbing powder machine further comprises a discharging cylinder arranged at the discharging port; the length of the discharging cylinder is determined according to the particle size of the crushed material, that is, the particle size of the crushed material is positively correlated with the length of the discharging cylinder; the discharging cylinder of the rubbing powder machine arranged at the coarse crushing station is H1, and the discharging cylinder of the rubbing powder machine arranged at the fine crushing station is H2, and H2>H1.
[0025] As a possible implementation manner, the drying device comprises:
[0026] The drying machine comprises a detachable inner container.
[0027] An electronic hanging scale is arranged above the drying machine and used for weighing the tare weight of the inner container.
[0028] The inner container after the tare weight is determined is displaced to the platform scale through the electronic sling scale, and the inner container is ensured to be located below the coarse crushing bin; the inner container receives the coarse crushing material input by the coarse crushing bin, and whether the coarse crushing material filled in the inner container reaches the preset weight is measured by the platform scale.
[0029] As a possible implementation, a vacuum suction machine is used to transport the fine powder material meeting the second preset particle size to the fine crushing bin; each bend of the pipeline included in the vacuum suction machine is grounded; a temperature detector and a temperature alarm are arranged on the vacuum pump included in the vacuum suction machine, and the temperature alarm is triggered to alarm when the working temperature of the vacuum pump detected by the temperature detector exceeds the preset temperature; the vacuum suction machine is also configured with a protective gas supply device, which absorbs the protective gas while absorbing the fine powder material.
[0030] In a second aspect, the present application also provides a carbon molecular sieve production method, comprising the following steps:
[0031] S10. The flower mud base material is provided by the feeding device;
[0032] S11. The rubbing powder machine is arranged at the coarse crushing station to receive the flower mud base material input by the feeding device, and the coarse crushing material meeting the first preset particle size is transported to the coarse crushing bin by using the airflow with the first preset intensity after rubbing and crushing;
[0033] S12. The drying device receives the coarse crushing material of the preset weight input by the coarse crushing bin, and bakes the coarse crushing material according to the preset baking temperature and the preset time; the coarse crushing material meeting the requirements after baking and detection is transported to the temporary storage bin;
[0034] S13. The rubbing powder machine is arranged at the fine crushing station to receive the coarse crushing material input by the temporary storage bin, and the fine powder material meeting the second preset particle size is transported to the fine crushing bin by using the airflow with the second preset intensity after rubbing and crushing, and the fine crushing bin is a constant-temperature bin;
[0035] S14. The kneading mixer is arranged at the kneading mixing station, and the constant-temperature stored fine powder material, the resin and the coal tar are added into the kneading mixer according to the preset mass ratio, and the raw material is formed by kneading in the kneading mixer;
[0036] S15. The extruding machine is arranged at the extruding station, and the constant-temperature storage tank is arranged for the extruding machine, and the raw material is temporarily stored in the constant-temperature storage tank; the constant-temperature raw material output by the constant-temperature storage tank is transported to the extruding cylinder included in the extruding machine and the extruding screw arranged in the extruding cylinder, and the raw material is extruded to form the raw material strip by using the extruding screw;
[0037] S16. A screening machine is arranged at a screening station to receive the green strips output by the strip extruder, screen the green strips to obtain green strips meeting the preset size, and cool the green strips to a first preset temperature;
[0038] S17. A carbonization furnace is arranged at a carbonization station to receive the green strips output by the screening machine, complete carbonization at a preset carbonization temperature to form carbonized strips, and cool the carbonized strips to a second preset temperature, and nitrogen is introduced into the carbonization furnace during the carbonization process;
[0039] S18. A deposition furnace is arranged at a deposition station to receive the carbonized strips output by the carbonization furnace, and the deposition furnace is used to perform deposition to form deposited strips. In the deposition process, the aperture modulation solution is added multiple times, and nitrogen is introduced at the same time. The deposited strips are sampled and detected each time the aperture modulation solution is added. The detection parameters include at least the tail gas amount of the deposited strips in the nitrogen generator, the nitrogen purity, and the hardness of the deposited strips. The deposited strips meeting the requirements are transported to the next process after the detection results meet the requirements. The deposited strips not meeting the requirements are deposited again until the detection results meet the requirements. The deposited strips meeting the requirements are processed by a screening machine to form carbon molecular sieves.
[0040] As a possible implementation manner, the kneading and dividing machine in the first aspect of the kneading powder machine, the crushing method of the kneading powder machine comprises:
[0041] S20. The motor is started to drive the first hollow rotating part in the coarse crushing assembly and the second hollow rotating part in the fine crushing assembly to relatively rotate through the transmission assembly, and the air blowing to the discharge port is generated in the relatively rotating process
[0042] S21. The flower mud base or coarse crushed material is transported to the crushing box through the feeding port, and the rotating first hollow rotating part makes the flower mud base or coarse crushed material reciprocate and impact at each position of the inner wall of the hollow rotating part to crush the flower mud base or coarse crushed material with a large size;
[0043] S22. After crushing, the crushed material falls into the gap between the first hollow rotating part and the first threaded rod; at this time, the friction between the rotating first hollow rotating part and the crushed material and the first threaded rod further crushes the crushed material;
[0044] S23. The relatively rotating first hollow rotating part drives the crushed and kneaded crushed material into the fine crushing assembly to form an 8-shaped kneading path, and finally, the flower mud base or coarse crushed material is kneaded by the coarse crushing assembly and the fine crushing assembly to a corresponding particle size and is blown out of the discharge port by the air.
[0045] As a possible implementation manner, in the case that the first preset intensity is equal to the second preset intensity and the first preset granularity is greater than the second preset granularity, the discharge cylinder of the rubbing powder machine arranged at the coarse crushing station is H1, and the discharge cylinder of the rubbing powder machine arranged at the fine crushing station is H2, and H2>H1.
[0046] As a possible implementation manner, the fine powder meeting the second preset granularity is transported to the fine crushing bin by the following method:
[0047] The fine powder meeting the second preset granularity is transported to the fine crushing bin by a vacuum suction machine; each bend of the pipeline included in the vacuum suction machine is grounded; a temperature detector and a temperature alarm are arranged on the vacuum pump included in the vacuum suction machine, and when the working temperature of the vacuum pump detected by the temperature detector exceeds a preset temperature, the temperature alarm is triggered to alarm; the vacuum suction machine is further configured with a protective gas supply device, and the protective gas is absorbed at the same time when the fine powder is absorbed by the vacuum suction machine.
[0048] As a possible implementation manner, S12 specifically includes the following steps:
[0049] S120. The inner container of the drying machine is taken out, and the tare weight of the inner container is weighed by an electronic overhead scale arranged above the drying machine;
[0050] S121. The inner container is placed on a weight machine, and it is ensured that the inner container is located below the coarse crushing bin;
[0051] S121. The discharge valve of the coarse crushing bin is opened to transport the coarse crushing material to the inner container, and at the same time, the weight of the coarse crushing material added to the inner container is acquired in real time by the weight machine, and when the measured weight of the coarse crushing material is equal to the preset weight, the discharge valve is closed;
[0052] S122. The inner container containing the coarse crushing material with the preset weight is placed into the drying machine again;
[0053] S123. The preset drying temperature of the drying machine is set to 200-400 DEG C, the preset time is set to 120-180 minutes, and the drying machine is started to roast the coarse crushing material.
[0054] Compared with the prior art, the present application has the following advantages:
[0055] First, the flower mud material or the flower mud leftover is used as the raw material for preparing nitrogen-carbon molecules to replace the coal raw material used in the prior art. The flower mud material or the flower mud leftover contains abundant large pores, medium pores, micropores and other pore structures, especially a large amount of micropores and submicropores required for carbon molecular sieve adsorption (in practical application, the large pores and small pores are often used as the channel for gas transmission, and the micropores and submicropores are used as the pore for containing oxygen. Nitrogen is difficult to enter the micropores and submicropores, and thus is isolated outside the carbon molecular sieve to achieve the separation of oxygen and nitrogen. That is, the flower mud material or the flower mud leftover is equivalent to an abundant "pore bank". Compared with the coal raw material, the self characteristics of the flower mud material or the flower mud leftover make the control of the carbon molecular sieve pore size easy. Therefore, the quality of the carbon molecular sieve prepared by using the flower mud material or the flower mud leftover can be effectively improved. In addition, the flower mud material or the flower mud leftover is a non-renewable material, and there is no problem of overconsumption of limited resources. Moreover, there is no problem of air pollution in the production process.
[0056] Second, the kneading powder machine is used in the rough grinding and fine grinding processes. In practical application, the motor is started to drive the first hollow rotating part in the rough crushing assembly and the second hollow rotating part in the fine crushing assembly to relatively rotate through the transmission assembly. In the process of relative rotation, the wind blowing to the discharge port can be generated. Based on this, the waste material such as the head material and the leftover can be conveyed to the crushing box through the feeding port. The rotating first hollow rotating part can make the waste material reciprocally impact at each position of the inner wall of the hollow rotating part to crush the waste material with a large size. After crushing, the waste material falls through the hollow position of the first hollow rotating part into the gap between the first threaded rod. At this time, the friction between the rotating first hollow rotating part and the crushed material and the first threaded rod can further knead and crush the crushed material.
[0057] The relatively rotating first hollow rotating part drives the kneaded and crushed material into the fine crushing assembly to form an 8-shaped kneading path. Finally, the waste material is kneaded by the rough crushing assembly and the fine crushing assembly to the corresponding particle size and is blown out from the discharge port by the wind.
[0058] From the above application process, it can be known that the kneading powder machine provided by the present application mainly utilizes the impact force and the kneading friction in the process of crushing the waste material. Compared with the ball mill which utilizes the mutual impact between the steel balls, the kneading powder machine can effectively reduce the adverse effects of noise on the working environment and the health of the personnel. In addition, the power of the motor used in the kneading powder machine can be reduced to 10KW, and the power consumption per hour can be reduced to 10 degrees / hour. Compared with the ball mill (the motor used in the ball mill is 55KW, and the power consumption is 55 degrees / hour) and the rough crusher (the motor used in the rough crusher is 37KW, and the power consumption is 37 degrees / hour) in the prior art, the kneading powder machine has the advantages of energy saving and consumption reduction. Moreover, the kneading powder machine provided by the present application also has the advantages of simple structure, small size, convenience and the like.
[0059] Third, after the fine grinding process, the fine grinding material is stored in the bin by vacuum suction. The elbow of each pipeline of the bin is grounded to effectively release the static electricity generated by the accumulated fine material at the elbow, thereby avoiding the risk of fire caused by static electricity. In addition, a temperature probe is installed on the vacuum pump to realize alarm when the temperature exceeds the set temperature, thereby avoiding high-temperature operation. Furthermore, protective gas such as nitrogen is injected during vacuum suction to reduce the risk of fire.
[0060] Fourth, a constant temperature storage tank is added beside the kneader to store raw materials, so as to ensure that the temperature of the raw materials is the same. Cooling devices are installed on the extrusion cylinder and screw of the extruder to avoid the problem that the temperature of the equipment is too high during extrusion, so that the strip cannot be extruded or the quality of the extruded strip is inconsistent. That is, the changes of climate / environmental temperature and storage time, etc. cause the kneading efficiency of this process and the extrusion effect of the subsequent process to be poor, etc. Finally, the quality of the carbon molecular sieve produced in different batches is basically consistent, that is, the product quality stability of the carbon molecular sieve is high. BRIEF DESCRIPTION OF DRAWINGS
[0061] The drawings described herein are used to provide further understanding of the present application, and form a part of the present application. The illustrative embodiments of the present application and their descriptions are used to explain the present application, and do not constitute an improper limitation on the present application. In the drawings:
[0062] Figure 1 A carbon molecular sieve production system diagram is provided for the embodiments of the present application;
[0063] Figure 2 A schematic diagram of the overall structure of the kneading powder machine is provided for the embodiments of the present application;
[0064] Figure 3 A schematic diagram of the structure of the transmission assembly in the kneading pulverizer is provided for the embodiments of the present application;
[0065] Figure 4 A schematic diagram of the structure of the coarse crushing assembly and the fine crushing assembly in the kneading pulverizer is provided for the embodiments of the present application;
[0066] Figure 5 A schematic diagram of the principle of generating convection wind in the kneading pulverizer is provided for the embodiments of the present application;
[0067] Figure 6 A carbon molecular sieve production process flow diagram is provided for the embodiments of the present application;
[0068] Figure 7 A carbon molecular sieve production method flow diagram is provided for the embodiments of the present application;
[0069] Figure 8 The water content of the carbon molecular sieve obtained by the carbon molecular sieve production method provided by the embodiments of the present application;
[0070] Figure 9 Ash content of the carbon molecular sieve obtained by the carbon molecular sieve production method provided by the embodiment of the present application;
[0071] Figure 10 Volatile content of the carbon molecular sieve obtained by the carbon molecular sieve production method provided by the embodiment of the present application;
[0072] Figure 11 Yield of the carbon molecular sieve obtained by the carbon molecular sieve production method provided by the embodiment of the present application.
[0073] Reference signs:
[0074] 1 - feeding device, 2 - kneading powder machine, 3 - coarse crushing bin, 4 - drying device, 5 - fine crushing bin, 6 - kneading mixer, 7 - extruding machine, 8 - screening machine, 9 - carbonization furnace, 10 - deposition furnace, 11 - screening and ashing device, 12 - packaging barrel;
[0075] 20 - crushing box, 21 - coarse crushing assembly, 22 - fine crushing assembly, 23 - motor, 24 - transmission assembly, 25 - discharge cylinder;
[0076] 200 - feeding port, 201 - air inlet;
[0077] 210 - first hollow rotating part, 211 - first threaded rod, 212 - blocking plate;
[0078] 220 - second hollow rotating part, 221 - second threaded rod;
[0079] 240 - driving sprocket, 241 - first driven sprocket, 242 - second driven sprocket, 243 - transmission chain, 244 - adjusting sprocket, 245 - lifting assembly. DETAILED DESCRIPTION
[0080] In order to make the technical problems to be solved by the present application, technical solutions and beneficial effects more clearly understood, the present application will be further described in detail below in combination with the drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain the present application and are not used to limit the present application.
[0081] It should be noted that when an element is referred to as being "fixed to" or "disposed on" another element, it can be directly on the other element or indirectly on the other element. When an element is referred to as being "connected to" another element, it can be directly connected to the other element or indirectly connected to the other element.
[0082] In addition, the terms "first", "second", "third", etc. are used only for descriptive purposes and are not to be construed as indicating or implying relative importance or an ordered sequence. Thus, features referring to "first", "second" or "third" features can include one or more of the features, explicitly or implicitly. In the description of the application, the meaning of "a plurality of" is two or more, unless explicitly specified otherwise. The meaning of "several" is one or more, unless explicitly specified otherwise.
[0083] In the description of the application, it should be understood that the terms "upper", "lower", "front", "back", "left", "right", etc. indicate the orientation or positional relationship shown in the drawings, and are only for the convenience of describing the application and simplifying the description, and do not indicate or imply that the devices or elements referred to must have a particular orientation, be constructed and operated in a particular orientation, and therefore cannot be understood as a limitation on the application.
[0084] In the description of the application, it should be noted that unless otherwise specified and limited, the terms "mounting", "connection", "connection" should be understood broadly, for example, it can be fixedly connected, or it can be detachably connected, or integrally connected; it can be mechanically connected, or it can be electrically connected; it can be directly connected, or it can be indirectly connected through an intermediate medium; it can be the internal communication of two elements or the interaction relationship between two elements. For those skilled in the art, the specific meaning of the above terms in the application can be understood according to the specific circumstances.
[0085] The fine material ground by the prior art is vacuumed into the bin, and then the fine material is transported from the bin to the kneader for mixing. The mixed material at least includes phenolic resin and coal tar. The viscosity and activity of phenolic resin and coal tar change with the change of climate / environmental temperature and the length of storage time, etc., which leads to the poor kneading efficiency of this process and the poor extrusion effect of the subsequent process, and finally makes the quality of carbon molecular sieve produced in different batches inconsistent, i.e. the product quality of carbon molecular sieve is unstable.
[0086] In view of the technical problems existing in the prior art, the embodiments of the present application provide a carbon molecular sieve production system and method for reducing the energy consumption of carbon molecular sieve production and improving the quality of carbon molecular sieve.
[0087] In a first aspect, referring to Figure 1 The carbon molecular sieve production system provided by the embodiments of the present application comprises a feeding device 1, a rubbing powder machine 2, a drying device 4, a rubbing powder machine 2, a kneading mixer 6, an extruder 7, a screening machine 8, a carbonization furnace 9 and a deposition furnace 10.
[0088] The feeding device 1 is used to supply the flower mud base material to the next process. The feeding device 1 can be any feeding device 1 provided by the prior art, for example, a conveying belt, a conveying cylinder or manual conveying. The flower mud base material can be a head material, a corner material or the like. The flower mud material or the corner material is used as a raw material for preparing the nitrogen-carbon molecule to replace the coal raw material used in the prior art. The flower mud material or the corner material contains abundant large pores, medium pores and micro pores, especially a large amount of micro pores and sub-micro pores required by the carbon molecular sieve adsorption (in actual application, the large pores and small pores are often used as channels for gas transmission, and the micro pores and sub-micro pores are used as pores for containing oxygen. Nitrogen is difficult to enter the micro pores and sub-micro pores, and thus is isolated outside the carbon molecular sieve to realize the separation of oxygen and nitrogen. ), that is, the flower mud material or the corner material is equivalent to an abundant “pore bank”. Compared with the coal raw material, the self characteristics of the flower mud material or the corner material make the control of the carbon molecular sieve pore size easy, and thus the quality of the carbon molecular sieve prepared by using the flower mud material or the corner material can be effectively improved. In addition, the flower mud material or the corner material is a non-renewable material, and there is no problem of excessive consumption of limited resources. In addition, there is no problem of air pollution in the production process.
[0089] The rubbing powder machine 2 is designed and manufactured based on the rubbing principle, is arranged at the coarse crushing station, is used to receive the flower mud base material input by the feeding device 1, rubs and crushes the flower mud base material, and then uses the airflow with the first preset strength to convey the coarse crushed material meeting the first preset particle size to the coarse crushed material bin 3.
[0090] The drying device 4 receives the coarse crushed material of the preset weight input by the coarse crushed material bin 3, and dries the coarse crushed material according to the preset drying temperature and the preset time; the dried coarse crushed material that meets the requirements after detection is transported to the temporary storage bin. As an example, the drying device 4 can specifically include a drying machine, the inner container of which is a detachable inner container; an electronic overhead scale is arranged above the drying machine and is used to weigh the tare weight of the inner container; a weighbridge, after the tare weight of the inner container is determined, the inner container is displaced to the weighbridge, and it is ensured that the inner container is located below the coarse crushed material bin 3; the inner container receives the coarse crushed material input by the coarse crushed material bin 3, and whether the coarse crushed material contained in the inner container reaches the preset weight is measured by the ground scale. In actual application, the inner container of the drying machine is taken out, and the tare weight of the inner container is weighed by the electronic overhead scale arranged above the drying machine. The inner container is placed on the weighbridge, and it is ensured that the inner container is located below the coarse crushed material bin 3. The discharge valve of the coarse crushed material bin 3 is opened to transport the coarse crushed material to the inner container, and at the same time, the weight of the coarse crushed material added to the inner container is obtained in real time by the weighbridge, and when the measured weight of the coarse crushed material is equal to the preset weight, the discharge valve is closed. The inner container containing the coarse crushed material of the preset weight is placed in the drying machine again.
[0091] In the above technical solution, the measuring instrument (i.e., the electronic overhead scale and the weighbridge) is arranged in the drying process, so that the contained amount of the coarse crushed material can be kept consistent. In the case that the preset drying temperature and the preset time arranged each time are basically consistent, the drying effect of different batches of coarse crushed material can be basically kept consistent. Therefore, the subsequent process can be stabilized, and the instability of the quality of the carbon molecular sieve can be reduced.
[0092] As an example, laboratory tests are performed on the dried coarse crushed material of each batch, mainly to test the moisture content and volatile matter indicators of the dried coarse crushed material, so as to ensure that the moisture content is 4%-6% and the volatile matter is 40%-45%.
[0093] The rubbing powder machine 2 is designed and manufactured based on the rubbing principle, is arranged at the fine crushing station, receives the coarse crushed material input by the temporary storage bin, rubs and crushes the coarse crushed material, and transports the fine powder meeting the second preset particle size to the fine crushed material bin 5 by using the airflow with the second preset intensity. The fine crushed material bin 5 is a constant-temperature bin.
[0094] As a possible implementation, the fine powder meeting the second preset granularity is transported to the fine crushing bin 5 by using a vacuum suction machine; each bend of the pipeline included in the vacuum suction machine is grounded; a temperature detector and a temperature alarm are arranged on the vacuum pump included in the vacuum suction machine; when the working temperature of the vacuum pump detected by the temperature detector exceeds a preset temperature, the temperature alarm is triggered to alarm; the vacuum suction machine is also configured with a protective gas supply device, which absorbs protective gas while absorbing the fine powder.
[0095] In practical application, it is found that the vacuum powder suction process is prone to fire problems. To solve this problem, the embodiment of the present application has the following solutions: 1. Grounding at all bends of the pipeline to release static electricity and avoid fire caused by static electricity accumulation. 2. Installing a temperature detector on the vacuum pump to realize alarm when the temperature exceeds the set temperature and avoid high-temperature operation. 3. Delivering nitrogen gas together with the vacuum powder suction, which greatly reduces the possibility of fire during the whole powder suction process.
[0096] The kneading mixer 6 is used to add the fine powder, resin and coal tar stored at constant temperature into the kneading mixer 6 according to a preset mass ratio, and to knead the materials in the kneading mixer 6 to form the raw material.
[0097] In practical application, it is found that the raw materials do not have a constant temperature device before being fed into the kneader, and the viscosity and activity of the phenolic resin and coal tar in the raw materials will change with the temperature change and storage time, which leads to unstable product quality of different batches. Especially, the change of the viscosity of the raw materials due to different climate temperatures will directly affect the kneading time and the effect of the extrusion, which will also cause instability in the subsequent processes and finally lead to unstable product quality.
[0098] To solve the above technical problems, the embodiment of the present application provides a possible implementation, which adds a constant temperature storage tank beside the kneader to store the raw materials and ensure that the raw materials have the same temperature. The cooling device is installed on the extrusion cylinder and screw of the extruder 7 to avoid the situation that the raw material cannot be extruded or the quality of the extruded raw material is inconsistent due to the high temperature of the equipment during extrusion.
[0099] The extruder 7 is configured with a constant temperature storage tank, and the raw material is temporarily stored in the constant temperature storage tank; the constant temperature raw material output from the constant temperature storage tank is transported to the extrusion cylinder included in the extruder 7 and the extrusion screw arranged in the extrusion cylinder, and the raw material is extruded to form a raw material strip by using the extrusion screw. As an example, the cooling device of the extrusion cylinder and screw starts to work after the extruder 7 works for 20-30 minutes.
[0100] The screening machine 8 receives the raw material strip output from the extruder 7, screens the raw material strip meeting the preset size by using the screening machine 8, and cools the raw material strip to a first preset temperature. The extruded raw material strip is put into the screening machine 8 for screening and ash screening, and finally the selected raw material strip is put into a basket for cooling.
[0101] Carbonization furnace 9 receives raw material strips output from screen bar machine 8, carbonizes them at a preset carbonization temperature to form carbonized strips, and cools them to a second preset temperature. Nitrogen gas is introduced into carbonization furnace 9 during the carbonization process. The cooled raw material strips are then loaded into carbonization furnace 9, and nitrogen gas is added simultaneously for electric heating carbonization at 700-900℃ to form carbonized strips. The carbonized strips are then allowed to cool statically.
[0102] The deposition furnace 10 receives the carbonized strips output from the carbonization furnace 9 and deposits them to form deposited strips. During the deposition process, a pore size modulation solution is added multiple times while nitrogen gas is introduced. After each addition of the pore size modulation solution, the deposited strips are sampled and tested. The test parameters include at least the amount of exhaust gas from the deposited strip in the nitrogen generator, the purity of the nitrogen gas, and the hardness of the deposited strip. Deposited strips that meet the test requirements are conveyed to the next process. Deposited strips that do not meet the test requirements are deposited again until the test results meet the requirements. After the deposited strips that meet the test requirements are screened, they form carbon molecular sieves.
[0103] The carbon molecular sieve production system provided in this embodiment of the invention also includes a sieving and crushing device 11. After the qualified carbon molecular sieve is cooled to a certain temperature (generally not lower than 70°C), it is sieved by the sieving and crushing device 11 and then bagged (the bag is put into the packaging barrel 12 in advance). At the same time, nitrogen gas is filled for protection. After the set weight is filled, the nitrogen gas pipe is pulled out and the plastic bag is tied tightly and sealed. Finally, the lid of the packaging barrel 12 is closed, a sealing label and product label are inserted, and it is put into storage.
[0104] See Figures 2 to 5As a possible implementation, the kneading powder machine 2 comprises a crushing box 20, a coarse crushing assembly 21, a fine crushing assembly 22, a motor 23 and a transmission assembly 24. The side wall of the crushing box 20 is provided with adjacent feed inlet 200 and air inlet 201, and the top wall of the crushing box 20 is provided with discharge outlet; the coarse crushing assembly 21 is arranged in the crushing box 20 and close to the feed inlet 200; the coarse crushing assembly 21 comprises a cylindrical first hollow rotating part 210 extending from one side wall to the other side wall of the crushing box 20, and a plurality of first threaded rods 211 arranged outside the cylindrical first hollow rotating part 210, the plurality of first threaded rods 211 are arranged at intervals and extend from one side wall to the other side wall of the crushing box 20; there is a gap between the cylindrical first hollow rotating part 210 and the first threaded rods 211. The fine crushing assembly 22 is arranged in the crushing box 20 close to the air inlet 201; the fine crushing assembly 22 comprises a cylindrical second hollow rotating part 220 extending from one side wall to the other side wall of the crushing box 20, and a plurality of second threaded rods 221 arranged outside the cylindrical second hollow rotating part 220, the plurality of second threaded rods 221 are arranged at intervals and extend from one side wall to the other side wall of the crushing box 20; there is a gap between the second hollow rotating part 220 and the second threaded rods 221; the second hollow rotating part 220 and the first hollow rotating part 210 rotate in opposite directions; the coarse crushing assembly 21 and the fine crushing assembly 22 are adjacent and through. The motor 23 is arranged at one end outside the crushing box 20. The power input end of the transmission assembly 24 is connected with the power output end of the motor 23, and the power output end of the transmission assembly 24 is connected with the first hollow rotating part 210 and the second hollow rotating part 220 respectively.
[0105] In the above technical solution, the coarse grinding and fine grinding processes adopt the kneading powder machine 2. In actual application, the motor 23 is started, and the first hollow rotating part 210 in the coarse crushing assembly 21 and the second hollow rotating part 220 in the fine crushing assembly 22 are driven to rotate in opposite directions by the transmission assembly 24, and air is blown to the discharge outlet during the relative rotation. Based on this, waste materials such as head materials and corner materials can be transported into the crushing box 20 through the feed inlet 200, and the rotating first hollow rotating part 210 can make the waste materials reciprocate and impact on the inner wall of the hollow rotating part at various positions to crush the waste materials with large size. After crushing, the waste materials fall into the gap between the first threaded rods 211 through the hollow positions of the first hollow rotating part 210. At this time, the friction between the rotating first hollow rotating part 210 and the crushed materials and the first threaded rods 211 further crushes the materials.
[0106] The relative rotation of the first hollow rotating part 210 drives the crushed materials to the fine crushing assembly 22, forming an 8-shaped kneading path, and finally, the waste materials are kneaded by the coarse crushing assembly 21 and the fine crushing assembly 22 to the corresponding particle size and then blown out of the discharge outlet by the air.
[0107] From the above application process, it can be known that the rubbing powder machine 2 provided by the application mainly utilizes the impact force and rubbing friction force in the process of crushing waste materials, and compared with the mutual impact between steel balls in the ball mill, the rubbing powder machine 2 can effectively reduce the adverse effects of noise on the working environment and the health of personnel. In addition, the power of the motor 23 used by the rubbing powder machine 2 provided by the application can be reduced to 10 KW, and the power consumption per hour can be reduced to 10 degrees / hour, which has the advantages of energy saving and consumption reduction compared with the ball mill (the motor 23 used by the ball mill is 55 KW, and the power consumption is 55 degrees / hour) and the coarse crusher (the motor 23 used by the coarse crusher is 37 KW, and the power consumption is 37 degrees / hour). Moreover, the rubbing powder machine 2 provided by the application also has the advantages of simple structure, small size, convenience and the like.
[0108] As a possible implementation manner, in the case that the first preset strength is equal to the second preset strength and the first preset particle size is greater than the second preset particle size, the discharge cylinder 25 of the rubbing powder machine 2 arranged on the coarse crushing station is H1, the discharge cylinder 25 of the rubbing powder machine 2 arranged on the fine crushing station is H2, and H2>H1. It needs to be further explained that the rubbing crushed crushed materials are blown out of the discharge cylinder 25 by the convection generated by the relatively rotating first and second hollow rotating parts 210. Therefore, when the length of the discharge cylinder 25 is relatively short, the crushed materials with a larger particle size can also be blown out. When the length of the discharge cylinder 25 is relatively long, the weight of the crushed materials downward is greater than the blowing force upward, at this time, the crushed materials with a larger particle size are not easy to be blown out of the discharge cylinder 25, but fall back to the coarse crushing assembly 21 and / or the fine crushing assembly 22 to continue to be rubbed. In view of this, when it is needed to rub the waste materials to the crushed materials with a smaller particle size, the length of the discharge cylinder 25 can be designed to be relatively long, and when it is needed to rub the waste materials to the crushed materials with a larger particle size, the length of the discharge cylinder 25 can be designed to be relatively short.
[0109] As a possible implementation manner, the first hollow rotating part 210 includes a face-shaped end cover, a ring-shaped end cover and a plurality of coarse crushing plates. The face-shaped end cover is arranged on the inner side of one side wall of the crushing box 20 close to the transmission assembly 24. The ring-shaped end cover is arranged on the inner side of the other side wall opposite to the above-mentioned side wall. Both ends of each coarse crushing plate are connected to the face-shaped end cover and the ring-shaped end cover, respectively, and the plurality of coarse crushing plates are combined in a circular ring shape. It needs to be further explained that the face-shaped end cover and the ring-shaped end cover mainly bear the plurality of coarse crushing plates, and the opening of the ring-shaped end cover is arranged opposite to the feeding port 200 to ensure that the waste materials can smoothly enter into the interior of the first hollow rotating part 210 through the feeding port 200 and the opening of the ring-shaped end cover. The interior here refers to the interior region enclosed by the face-shaped end cover and the plurality of coarse crushing plates.
[0110] As a possible implementation manner, the second hollow rotating part 220 comprises a face-shaped end cover, a ring-shaped end cover and a plurality of fine crushing plates. The face-shaped end cover is arranged on the inner side of one side wall of the crushing box 20 close to the transmission assembly 24. The ring-shaped end cover is arranged on the inner side of the other side wall opposite to the above-mentioned side wall. Two ends of each fine crushing plate are connected to the face-shaped end cover and the ring-shaped end cover respectively, and the plurality of coarse crushing plates are combined in a circular ring shape. The specific structure of the second hollow rotating part 220 is basically the same as that of the first hollow rotating part 210, and the difference between the two is that the number of the fine crushing plates is greater than that of the coarse crushing plates. That is, the distribution of the fine crushing plates is more dense than that of the coarse crushing plates.
[0111] As a possible implementation manner, the transmission assembly 24 is any one of a chain transmission assembly 24 or a belt transmission assembly 24.
[0112] As a possible implementation manner, the transmission assembly 24 is a chain transmission assembly 24, which comprises: a driving sprocket 240 connected to the output shaft of the motor 23. A first driven sprocket 241 and a first driven sprocket 241 shaft connected to the face-shaped end cover included in the first hollow rotating part 210. A second driven sprocket 242 and a second driven sprocket 242 shaft connected to the face-shaped end cover included in the second hollow rotating part 220. A transmission chain 243, the inner ring of the transmission chain 243 is sleeved on the driving sprocket 240 and the second driven sprocket 242, and the outer ring of the transmission chain 243 is engaged with the first driven sprocket 241.
[0113] As a possible implementation manner, the chain transmission assembly 24 further comprises: an adjusting sprocket 244 arranged between the driving sprocket 240 and the first driven sprocket 241 and located below the two. An adjusting sprocket 244 shaft connected to the adjusting sprocket 244. A bearing connected to the end of the adjusting sprocket 244 shaft. A lifting assembly 245, the execution end of the lifting assembly 245 is connected to the bearing, driving the bearing, the adjusting sprocket 244 shaft and the adjusting sprocket 244 to move upward or downward.
[0114] As a possible implementation manner, the lifting assembly 245 comprises: a support plate connected to the outer side of the side wall of the crushing box 20 close to the transmission assembly 24, and a threaded hole is arranged at the position close to the suspended end of the support plate. An adjusting rod, one end of the adjusting rod connected to the support plate has an external thread segment; the other end of the adjusting rod is connected to the bearing through a transfer rod.
[0115] As a possible implementation manner, the side of the first hollow rotating part 210 away from the second hollow rotating part 220 is provided with a blocking plate 212 extending from one side wall to the other side wall of the crushing box 20, and the blocking plate 212 does not interfere with the first hollow rotating part 210.
[0116] As a possible implementation manner, the crushing box 20 comprises: two side walls arranged oppositely, an end wall connected with the same end of the two side walls, a coarse crushing barrel arranged between the two side walls, the coarse crushing barrel having an end opening communicated with the feeding port 200, a fine crushing barrel arranged between the two side walls, the fine crushing barrel having an end opening communicated with the air inlet 201; the opposite walls of the coarse crushing barrel and the fine crushing barrel are provided with side openings communicated with each other, and the discharging port is arranged between the coarse crushing barrel and the fine crushing barrel.
[0117] As a possible implementation manner, the plurality of first threaded rods 211 are arranged at intervals on the inner wall of the coarse crushing barrel; and the plurality of second threaded rods 221 are arranged at intervals on the inner wall of the fine crushing barrel.
[0118] In a second aspect, referring to Figure 6 and Figure 7 The present application also provides a carbon molecular sieve production method, comprising the following steps:
[0119] S10. Providing a clay base;
[0120] S11. The kneading powder machine 2 is arranged at a coarse crushing station to receive the clay base input by the feeding device 1, and after being crushed and kneaded, the coarse crushing material meeting the first preset particle size is conveyed to the coarse crushing bin 3 by using air flow with the first preset strength.
[0121] S12. The drying device 4 receives the coarse crushing material of the preset weight input by the coarse crushing bin 3, and bakes the coarse crushing material according to the preset baking temperature and the preset time; after the baking is completed and the coarse crushing material meeting the requirements is detected, the coarse crushing material is conveyed to the temporary storage bin.
[0122] S13. The kneading powder machine 2 is arranged at a fine crushing station to receive the coarse crushing material input by the temporary storage bin, and after being crushed and kneaded, the fine powder material meeting the second preset particle size is conveyed to the fine crushing bin 5 by using air flow with the second preset strength, and the fine crushing bin 5 is a constant-temperature bin.
[0123] S14. The constant-temperature stored fine powder material, the resin and the coal tar are added into the kneading mixer 6 according to the preset mass ratio, and the raw material is formed by kneading in the kneading mixer 6.
[0124] S15. The extruding machine 7 is arranged at an extruding station, and the constant-temperature storage tank is arranged for the extruding machine 7, and the raw material is temporarily stored in the constant-temperature storage tank; the constant-temperature raw material output by the constant-temperature storage tank is conveyed to the extruding barrel included in the extruding machine 7 and the extruding screw arranged in the extruding barrel, and the raw material is extruded to form the raw material strip by using the extruding screw.
[0125] S16. The screening machine 8 is arranged at a screening station to receive the raw material strip output by the extruding machine 7, and the raw material strip meeting the preset size is screened by using the screening machine 8 and is cooled to the first preset temperature.
[0126] S17. A carbonization furnace 9 is arranged at the carbonization station to receive the raw material strip output by the strip screening machine 8, complete carbonization at a preset carbonization temperature to form carbonized strips, and cool the carbonized strips to a second preset temperature, and nitrogen is introduced into the carbonization furnace 9 during the carbonization process;
[0127] S18. A deposition furnace 10 is arranged at the deposition station to receive the carbonized strips output by the carbonization furnace 9, and deposition is performed by using the deposition furnace 10 to form deposition strips. The aperture modulation solution is added multiple times during the deposition process, and nitrogen is introduced at the same time. The deposition strips are sampled and detected each time the aperture modulation solution is added, and the detection parameters at least include the tail gas amount of the deposition strips in the nitrogen generator, the purity of the nitrogen, and the hardness of the deposition strips. The deposition strips that meet the requirements are transported to the next process after the detection results meet the requirements, and the deposition strips that do not meet the requirements are deposited again until the detection results meet the requirements. The deposition strips that meet the requirements form carbon molecular sieves after being screened by the ash screening device.
[0128] As a possible implementation manner, the crushing method of the kneading powder machine 2 includes:
[0129] S20. The motor 23 is started to drive the first hollow rotating part 210 in the coarse crushing assembly 21 and the second hollow rotating part 220 in the fine crushing assembly 22 to relatively rotate by the transmission assembly 24, and the wind blowing to the discharge port is generated during the relative rotation
[0130] S21. The flower mud base or coarse crushed material is transported to the crushing box 20 through the feeding port 200, and the rotating first hollow rotating part 210 makes the flower mud base or coarse crushed material reciprocate and impact at various positions on the inner wall of the hollow rotating part to crush the flower mud base or coarse crushed material with a large size.
[0131] S22. After crushing, the crushed material falls into the gap between the first hollow rotating part 210 and the first threaded rod 211 through the hollow position of the first hollow rotating part 210. At this time, the friction between the rotating first hollow rotating part 210 and the crushed material and the first threaded rod 211 further crushes the crushed material.
[0132] S23. The relatively rotating first hollow rotating part 210 drives the crushed material to the fine crushing assembly 22 to form an 8-shaped kneading path. Finally, the flower mud base or coarse crushed material is kneaded to a corresponding particle size by the coarse crushing assembly 21 and the fine crushing assembly 22, and is blown out of the discharge port by the wind.
[0133] As a possible implementation manner, in the S11 and S13 steps, in the case that the first preset intensity is equal to the second preset intensity and the first preset particle size is greater than the second preset particle size, the discharge cylinder 25 of the kneading powder machine 2 arranged at the coarse crushing station is H1, and the discharge cylinder 25 of the kneading powder machine 2 arranged at the fine crushing station is H2, and H2>H1.
[0134] As a possible implementation, the fine powder meeting the second preset granularity is transported to the fine crushing bin 5 by the following method:
[0135] The fine powder meeting the second preset granularity is transported to the fine crushing bin 5 by a vacuum suction machine; each bend of the pipeline included in the vacuum suction machine is grounded; a temperature detector and a temperature alarm are arranged on the vacuum pump included in the vacuum suction machine, and the temperature alarm is triggered to alarm when the working temperature of the vacuum pump detected by the temperature detector exceeds a preset temperature; the vacuum suction machine is further configured with a protective gas supply device, which absorbs protective gas while absorbing the fine powder.
[0136] As a possible implementation, S12 specifically includes the following steps:
[0137] S120. The inner container of the drying machine is taken out, and the tare weight of the inner container is weighed by an electronic overhead scale arranged above the drying machine;
[0138] S121. The inner container is placed on a weight machine, and it is ensured that the inner container is located below the coarse crushing bin 3;
[0139] S121. The discharge valve of the coarse crushing bin 3 is opened to transport the coarse crushing material to the inner container, and at the same time, the weight of the coarse crushing material added to the inner container is acquired in real time by the weight machine, and when the measured weight of the coarse crushing material is equal to the preset weight, the discharge valve is closed;
[0140] S122. The inner container containing the coarse crushing material with the preset weight is placed into the drying machine again;
[0141] S123. The preset drying temperature of the drying machine is set to 200-400℃, the preset time is set to 120-180 minutes, and the drying machine is started to roast the coarse crushing material.
[0142] In order to verify the superiority of the carbon molecular sieve production system and method provided by the present application relative to the prior art, the quality of the carbon molecular sieve is evaluated from moisture, ash content, volatile matter and grinding time, etc.
[0143] Referring to Figures 8 to 11 , the moisture content of the carbon molecular sieve is 20.43% on average, the ash content is 2.23% on average, and the volatile matter is 53.15% on average. The oven yield obtained in the actual production process (69.87% and 70.10% on average) is not only not low, but also higher than the yield (60%) of the production method provided by the prior art.
[0144] Those skilled in the art can understand that all or part of the steps of the methods in the above embodiments can be completed by instructing the relevant hardware through a program, the program is stored in a storage medium, and the program includes a plurality of instructions for enabling an apparatus (which can be a single-chip microcomputer, a chip, etc.) or a processor to perform all or part of the steps of the methods described in various embodiments of the present application. The foregoing storage medium includes but is not limited to a U disk, a mobile hard disk, a magnetic storage, an optical storage, and various storage media that can store program codes.
[0145] As can be seen from the above description, embodiments of the present application can be provided as a method, a system, or a computer program product. Therefore, the present application can take the form of a complete hardware embodiment, a complete software embodiment, or an embodiment combining software and hardware aspects. The above description is only a preferred embodiment of the present application, and the present application should not be limited to the content disclosed in the embodiment and the drawings. Any equivalent or modification made without departing from the disclosed spirit of the present application falls within the scope of the present application.
[0146] In the description of the above-described embodiments, specific features, structures, materials or characteristics can be combined in any one or more embodiments or examples in a suitable manner.
[0147] The above description is only a specific implementation of the present application, but the protection scope of the present application is not limited thereto. Any person skilled in the art can easily think of changes or replacements within the technical range disclosed in the present application, which should be covered within the protection scope of the present application. Therefore, the protection scope of the present application should be subject to the protection scope of the claims.
Claims
1. A carbon molecular sieve production system, characterized in that, include: Feeding device, kneading powder mill set in coarse crushing station, drying device, kneading powder mill set in fine crushing station, kneading and mixing machine, extruder, screener, carbonization furnace and sedimentation furnace; The kneading powder machine is designed and manufactured based on the kneading principle. The kneading powder machine set at the coarse crushing station is used to receive the flower foam base material input by the feeding device. After kneading and crushing, the coarse crushed material that meets the first preset particle size is transported to the coarse crushing silo by an airflow with a first preset intensity. The kneading powder machine set at the fine crushing station is used to receive the coarse crushed material input by the temporary storage silo. After kneading and crushing, the fine powder that meets the second preset particle size is transported to the fine crushing silo by an airflow with a second preset intensity. The fine crushing silo is a constant temperature silo. The kneading powder machine includes: a crushing box, a coarse crushing component, a fine crushing component, a motor, and a transmission component; The crushing chamber has adjacent feed inlets and air inlets on its side walls, and a discharge outlet on its top wall. The coarse crushing component is located inside the crushing chamber and near the feed inlet. The coarse crushing component includes a cylindrical first hollow rotating part extending from one side wall of the crushing chamber to the other side wall, and a plurality of first threaded rods disposed outside the cylindrical first hollow rotating part. The plurality of first threaded rods are spaced apart and extend from one side wall of the crushing chamber to the other side wall. There is a gap between the cylindrical first hollow rotating part and the first threaded rods. The fine crushing component is located near the air inlet of the crushing chamber; the fine crushing component includes a cylindrical second hollow rotating part extending from one side wall of the crushing chamber to the other side wall, and a plurality of second threaded rods disposed outside the cylindrical second hollow rotating part, the plurality of second threaded rods being spaced apart and extending from one side wall of the crushing chamber to the other side wall; there is a gap between the second hollow rotating part and the second threaded rods; the second hollow rotating part rotates relative to the first hollow rotating part; the coarse crushing component and the fine crushing component are connected on adjacent sides; The motor is located at one end outside the crushing chamber; The power input end of the transmission component is connected to the power output end of the motor, and the power output end of the transmission component is connected to the first hollowed-out rotating part and the second hollowed-out rotating part respectively.
2. The carbon molecular sieve production system according to claim 1, characterized in that, The feeding device is used to supply floral foam base material to subsequent processes; A drying device receives a preset weight of coarse crushed material input from the coarse crushing hopper and bakes the coarse crushed material at a preset drying temperature and for a preset time. After baking and passing inspection, the coarse crushed material is transported to a temporary storage silo. A kneading mixer is used to add fine powder, resin and coal tar stored at a constant temperature into the kneading mixer according to a preset mass ratio, and knead them in the kneading mixer to form raw material; The extruder is equipped with a constant temperature storage tank, and the raw material is temporarily stored in the constant temperature storage tank. The constant temperature raw material output from the constant temperature storage tank is transported to the extrusion cylinder and the extrusion screw installed in the extrusion cylinder of the extruder, and the extrusion screw is used to extrude the raw material into raw material strips. A screening machine receives raw strips output from the extruder, uses the screening machine to screen out raw strips that meet a preset size, and cools them to a first preset temperature; A carbonization furnace receives raw material strips output from a screening machine, carbonizes them at a preset carbonization temperature to form carbonized strips, and cools them to a second preset temperature. Nitrogen gas is introduced into the carbonization furnace during the carbonization process. A deposition furnace receives carbonized strips output from the carbonization furnace and deposits them to form deposited strips. During the deposition process, a pore size modulation solution is added multiple times while nitrogen gas is introduced. After each addition of the pore size modulation solution, the deposited strips are sampled and tested. The test parameters include at least the amount of exhaust gas from the deposited strip in the nitrogen generator, the purity of the nitrogen gas, and the hardness of the deposited strip. Deposited strips that meet the test requirements are conveyed to the next process, while those that do not meet the test requirements are deposited again until the test results meet the requirements. Deposition strips that meet the test requirements are sieved to form carbon molecular sieves.
3. The carbon molecular sieve production system according to claim 2, characterized in that, The gap between the first hollowed-out rotating part of the cylindrical shape and the first threaded rod is D1, and the gap between the second hollowed-out rotating part and the second threaded rod is D2, where D1 > D2; And / or: The kneading powder machine also includes a discharge cylinder, which is located at the discharge port. The length of the discharge cylinder is determined according to the particle size of the crushed material, that is, the particle size of the crushed material is positively correlated with the length of the discharge cylinder. The discharge cylinder of the kneading powder machine located at the coarse crushing station is H1, and the discharge cylinder of the kneading powder machine located at the fine crushing station is H2, where H2 > H1.
4. The carbon molecular sieve production system according to claim 1, characterized in that, The drying device includes: The dryer includes a removable inner liner; An electronic hanging scale is installed above the dryer to weigh the tare weight of the inner liner; After the tare weight is determined, the inner liner is moved onto the weighbridge via the electronic crane scale, ensuring that the inner liner is located below the coarse crushing bin. The inner liner receives the coarse crushed material input from the coarse crushing bin, and the weighbridge is used to measure whether the coarse crushed material contained in the inner liner has reached the preset weight.
5. The carbon molecular sieve production system according to claim 1, characterized in that, A vacuum feeder is used to transport fine powder that meets a second preset particle size to a fine crushing hopper; each bend in the pipeline included in the vacuum feeder is grounded; the vacuum pump included in the vacuum feeder is equipped with a temperature detector and a temperature alarm, and when the operating temperature of the vacuum pump detected by the temperature detector exceeds the preset temperature, the temperature alarm is triggered; the vacuum feeder is also equipped with a protective gas supply device, which absorbs protective gas while the vacuum feeder is absorbing fine powder.
6. A method for producing carbon molecular sieves using the carbon molecular sieve production system according to any one of claims 1 to 5, characterized in that, Includes the following steps: S10. Floral foam base material is provided by a feeding device; S11. A kneading powder mill is set up at the coarse crushing station to receive the flower foam base material input by the feeding device. After kneading and crushing, the coarse crushed material with the first preset particle size is transported to the coarse crushing silo by an airflow with a first preset intensity. S12. The drying device receives the coarse crushed material of a preset weight input from the coarse crushing hopper, and bakes the coarse crushed material at a preset drying temperature and a preset time; the coarse crushed material that has been baked and has been tested to meet the requirements is conveyed to the temporary storage hopper; S13. A kneading powder mill is set in the fine crushing station to receive the coarse crushed material input from the temporary storage silo. After kneading and crushing, the fine powder material that meets the second preset particle size is transported to the fine crushing silo by an airflow with a second preset intensity. The fine crushing silo is a constant temperature silo. S14. A kneading mixer is set up at the kneading and mixing station. Fine powder, resin and coal tar stored at a constant temperature are added to the kneading mixer according to a preset mass ratio, and kneaded in the kneading mixer to form raw material. S15. An extruder is configured at the extrusion station, and a constant temperature storage tank is configured for the extruder. The raw material is temporarily stored in the constant temperature storage tank. The constant temperature raw material output from the constant temperature storage tank is transported to the extrusion cylinder included in the extruder and the extrusion screw installed in the extrusion cylinder. The extrusion screw is used to extrude the raw material to form raw material strips. S16. A screen bar machine is configured at the screen bar station to receive the raw material strips output by the extruder, and the screen bar machine is used to screen out the raw material strips that meet the preset size and cool them to the first preset temperature; S17. A carbonization furnace is configured at the carbonization station to receive raw material strips output by the screen bar machine, carbonize them at a preset carbonization temperature to form carbonized strips, and cool them to a second preset temperature. Nitrogen gas is introduced into the carbonization furnace during the carbonization process. S18. A deposition furnace is configured at the deposition station to receive carbonized strips output from the carbonization furnace. The deposition furnace is used to deposit the carbonized strips to form deposition strips. During the deposition process, a pore size modulation solution is added multiple times while nitrogen gas is introduced. Each time the pore size modulation solution is added, the deposition strips are sampled and tested. The test parameters include at least the amount of exhaust gas from the deposition strip in the nitrogen generator, the purity of the nitrogen gas, and the hardness of the deposition strip. Deposition strips that meet the test requirements are transported to the next process. Deposition strips that do not meet the test requirements are deposited again until the test results meet the requirements. Deposition strips that meet the test requirements are sieved to form carbon molecular sieves.
7. The method for producing carbon molecular sieves according to claim 6, characterized in that, The pulverizing method of the kneading powder machine includes: S20. Start the motor, and drive the first hollow rotating part in the coarse crushing component and the second hollow rotating part in the fine crushing component to rotate relative to each other through the transmission component. During the relative rotation, air is generated and blown towards the discharge port. S21. The floral foam base material or coarse crushed material is fed into the crushing box through the feed inlet. The rotating first hollow rotating part causes the floral foam base material or coarse crushed material to repeatedly impact at various positions on the inner wall of the hollow rotating part in order to crush the larger floral foam base material or coarse crushed material. S22. After crushing, the material falls into the gap between the first hollowed-out rotating part and the first threaded rod through the hollowed-out position of the first hollowed-out rotating part; at this time, the friction between the rotating first hollowed-out rotating part and the crushed material, and between the crushed material and the first threaded rod, further crushes the crushed material. S23. The first hollow rotating part rotates relative to each other, driving the crushed material into the fine crushing component, forming an 8-shaped crushing path. Finally, the flower clay base material or coarse crushed material is crushed to the corresponding particle size by the coarse crushing component and the fine crushing component and then blown out from the outlet by the wind.
8. The method for producing carbon molecular sieves according to claim 6, characterized in that, In steps S11 and S13, when the first preset strength is equal to the second preset strength and the first preset particle size is greater than the second preset particle size, the discharge cylinder of the kneading powder machine set at the coarse crushing station is H1, and the discharge cylinder of the kneading powder machine set at the fine crushing station is H2, where H2 > H1.
9. The method for producing carbon molecular sieves according to claim 6, characterized in that, The following method is used to convey fine powder that meets the second preset particle size to the fine crushing silo: A vacuum feeder is used to transport fine powder that meets a second preset particle size to a fine crushing hopper; each bend in the pipeline included in the vacuum feeder is grounded; the vacuum pump included in the vacuum feeder is equipped with a temperature detector and a temperature alarm, and when the operating temperature of the vacuum pump detected by the temperature detector exceeds the preset temperature, the temperature alarm is triggered; the vacuum feeder is also equipped with a protective gas supply device, which absorbs protective gas while the vacuum feeder is absorbing fine powder.
10. The method for producing carbon molecular sieves according to claim 6, characterized in that, S12 specifically includes the following steps: S120. Remove the inner drum of the dryer and weigh the tare weight of the inner drum using an electronic crane scale located above the dryer; S121. Place the inner liner on the weighbridge, ensuring that the inner liner is located below the coarse crushing bin; S121. Open the discharge valve of the coarse crushing hopper to transport the coarse crushing material to the inner liner. At the same time, the weight of the coarse crushing material added to the inner liner is obtained in real time through the weighbridge. When the actual weight of the coarse crushing material is equal to the preset weight, close the discharge valve. S122. Place the inner liner containing the preset weight of coarse crushed material back into the dryer; S123. Set the preset drying temperature of the dryer to 200-400℃ and the preset time to 120-180 minutes, and start the dryer to bake the coarse crushed material.
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A kneading powder machine
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