A pesticide preparation containing piperic acid derivatives

Abstract

The present invention belongs to the field of insecticides and relates to a pesticide preparation containing piperic acid derivatives. A pesticide preparation containing piperic acid derivatives, including active ingredients and agriculturally acceptable adjuvants and carriers, the pesticide preparation active component weight percentage is 1%-70%, wherein the active ingredient is active component A and active component B, active component A is selected from compound I-72, active component B is one or more of tetrachlorantraniliprole, chlorantraniliprole, and indoxacarb, and the weight ratio of active component A to active component B is 50:1-1:50. The preparation of the present invention can effectively block the interaction of two types of compounds when mixed with water for final application, thereby suppressing the incompatible self-defects of active material particles of two types of different structures, solving the problem of low suspension rate of mixed preparations existing in the prior art, making the suspension rate of the preparation qualified, product performance is guaranteed, and unexpected effects are achieved.

Description

Technical Field

[0001] The invention belongs to the field of pesticides and relates to a pesticide preparation containing a piperic acid derivative. Background Art

[0002] Chinese invention patent CN112457288 discloses a piperic acid derivative, among which compound I-72 has contact and stomach poison activity, good conduction activity, and can be used to control a variety of Lepidoptera, Hemiptera, Thysanoptera, Coleoptera and other pests. The compound has a novel structure, a broad insecticide spectrum, high activity, and no cross-resistance with other insecticides, and is expected to become an environmentally friendly agent for the control of resistant pests.

[0003] As mentioned in the aforementioned invention patent CN112457288, the use form of the compound can be a pesticide preparation, but the use form of the compound recorded in the patent is prepared in a known manner, for example, optionally in the presence of a surfactant, by diluting or dissolving the active substance with a solvent medium and / or a diluent, but the choice of the type of use of the compound known in the art depends on the specific application. At the same time, as a preparation composition of compound I-72 mixed with tetrachlorantraniliprole, chlorantraniliprole and indoxacarb, it is not involved. Moreover, in the actual development of pesticide preparation products, it is found that the form that can be prepared as a dosage form mentioned in the aforementioned patent is a generally applicable preparation, especially in the preparation technology problems that may occur during the mixing of two pesticides, and there is no clear research. In the process of our mixed preparation research, it was found that when compound I-72 was prepared as a preparation with tetrachlorantraniliprole, chlorantraniliprole and indoxacarb, the suspension rate of the product would be greatly reduced, and such problems would occur when the product is placed on the shelf.

[0004] Most pesticide formulations are diluted with water during actual application, and the active ingredients are suspended in water in a dispersed and dissolved state to exert their efficacy. The requirements for such suspension performance in mixed formulations are even more stringent. If the diluted product is not evenly dispersed and the suspension performance is poor, the suspension rate will be unqualified. According to the current suspension rate standard for formulations, the suspension rate must be no less than 90% to indicate that the formulation formula has been successfully developed. The suspension rate detection method of the formulation needs to be carried out in accordance with the national standard GB / T14825.

[0005] When compound I-72 is mixed with tetrachlorantraniliprole, chlorantraniliprole and indoxacarb, due to the different reactions of compounds with different structures in the adjuvant system, it will lead to a certain degree of poor particle suspension. Especially in the storage acceleration test, the two mixed particles may not be evenly dispersed and interfere with each other, which weakens the effects of some adjuvants, especially wetting and dispersing agents, and the suspension rate of the preparation will drop significantly, resulting in unqualified suspension rate, which ultimately affects the use of the preparation. Therefore, at this stage, there is an urgent need for a preparation type and a matching system that can solve the problem of low suspension rate. Summary of the invention

[0006] The present invention aims to provide a pesticide preparation containing a piperic acid derivative.

[0007] To achieve the above purpose, the present invention adopts the following technical solution:

[0008] A pesticide preparation containing a piperic acid derivative, comprising an active ingredient and an agriculturally acceptable adjuvant and a carrier, wherein the active ingredient of the pesticide preparation has a weight percentage of 1%-70%, wherein the active ingredient is an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from compound I-72, and the active ingredient B is one or more of tetrachlorantraniliprole, chlorantraniliprole, and indoxacarb, and the weight ratio of the active ingredient A to the active ingredient B is 50:1-1:50; and the active ingredient A has the following structure:

[0009]

[0010] The pesticide preparation is a granule, a tablet, an oil-dispersible powder, an emulsion, a water-dispersible granule, an emulsion, a water-dispersible tablet, a soluble powder, a soluble granule, a soluble tablet, an effervescent granule, an effervescent tablet, a soluble solution, a soluble gel, an oil, a film-spreading oil, a dispersible liquid, an ointment, an aqueous emulsion, an oil emulsion, a microemulsion, a suspension, a microcapsule suspension, an oil suspension, a dispersible oil suspension, a seed treatment agent, a seed treatment agent includes a seed treatment dry powder, a seed treatment dispersible powder, a seed treatment liquid, a seed treatment emulsion, a seed treatment suspension, an aerosol or an ultra-low solubility liquid.

[0011] The auxiliary agent is one or more of a wetting dispersant, a solvent, a warning color, an oil base, a carrier, and a capsule material.

[0012] The wetting and dispersing agent is one or more of lignin sulfonate, polyacrylic acid salt, polycarboxylate, carboxylate, carboxylic acid polymer copolymer, sulfonate, sulfate, phosphate, aryl ether phosphate, twin-structure amphiphilic surfactant complex, compound auxiliary agent of polyacrylate copolymer, special structure polymer surfactant, EO / PO block polyether, polymer, block copolymer, single comb polymer, sodium salt + block copolymer of alkylnaphthalenesulfonic acid condensate, Nongru T-20, Nongru 0201B, Nongru 0203B, Nongru 1601, sodium naphthalenesulfonate formaldehyde condensate, sodium salt of methylnaphthalenesulfonate formaldehyde condensate, polyvinyl alcohol, and chitosan.

[0013] Preferably, the wetting and dispersing agent is a mixture of lignin sulfonate and one or more of the following substances; wherein the following substances are polyacrylates, polycarboxylates, carboxylates, carboxylic acid polymer copolymers, sulfonates, sulfates, phosphates, aromatic ether phosphates, twin-structure amphiphilic surfactant complexes, compounded adjuvants of polyacrylate copolymers, special structure polymer surfactants, EO / PO block polyethers, polymers, block copolymers, single comb polymers, sodium salt + block copolymers of alkyl naphthalene sulfonic acid condensates, Nong Ru T-20, Nong Ru 0201B, Nong Ru 0203B, Nong Ru 1601, sodium naphthalene sulfonate formaldehyde condensates, sodium salt of methyl naphthalene sulfonate formaldehyde condensates, polyvinyl alcohol, and chitosan.

[0014] Or, the auxiliary agent also contains a stabilizer, which is decabromodiphenyl ether, and the added amount is 0%-5% of the mass of the preparation. At this time, the wetting agent is one or more of lignin sulfonate, polyacrylate, polycarboxylate, carboxylate, carboxylic acid polymer copolymer, sulfonate, sulfate, phosphate, aryl ether phosphate, gemini-structured amphiphilic surfactant complex, polyacrylate copolymer composite auxiliary agent, special structure polymer surfactant, EO / PO block polyether, polymer, block copolymer, single comb polymer, sodium salt + block copolymer of alkylnaphthalenesulfonic acid condensate, Nongru T-20, Nongru 0201B, Nongru 0203B, Nongru 1601, sodium naphthalenesulfonate formaldehyde condensate, sodium salt of methylnaphthalenesulfonate formaldehyde condensate, polyvinyl alcohol, and chitosan.

[0015] More preferably, when the wetting and dispersing agent is one or more of lignin sulfonate (SK-24N), a stabilizer is added, and the mass ratio of the stabilizer to the wetting and dispersing agent is 1:1.

[0016] The granules, by weight percentage, include 0.5%-70% active component A, 0.5%-70% active component B, 1-15% wetting and dispersing agent, 0%-5% stabilizer, and the balance is carrier;

[0017] The wettable powder comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-20% of wetting and dispersing agent, 0%-5% of stabilizer, and the balance being carrier;

[0018] The water dispersible granules, by weight percentage, include 0.5%-70% active component A, 0.5%-70% active component B, 1-20% wetting dispersant, 0%-5% stabilizer, and the balance is carrier;

[0019] The suspending agent comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-30% of wetting and dispersing agent, 0%-5% of stabilizer, and the balance is deionized water.

[0020] The dispersible oil suspension comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-30% of wetting dispersant, 0%-5% of stabilizer, and the balance being dispersed phase oil base.

[0021] The microcapsule suspension comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-20% of wetting dispersant, 1%-5% of capsule material, 0%-5% of stabilizer, and the balance being dispersed phase oil base.

[0022] The suspoemulsion comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 2%-30% of solvent, 1%-30% of wetting and dispersing agent, 0%-5% of stabilizer, and the balance is deionized water.

[0023] The soluble agent comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-30% of wetting and dispersing agent, 0%-5% of stabilizer, and the balance being solvent.

[0024] The seed treatment suspending agent comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-30% of wetting and dispersing agent, 1%-20% of warning color, 0%-5% of stabilizer, and the balance is deionized water.

[0025] The aqueous emulsion comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 2%-30% of solvent, 1%-30% of wetting and dispersing agent, 0%-5% of stabilizer, and the balance is deionized water.

[0026] The microemulsion comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 2%-30% of solvent, 1%-30% of wetting and dispersing agent, 0%-5% of stabilizer, and the balance is deionized water.

[0027] The emulsifiable concentrate comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-30% of wetting and dispersing agent, 0%-5% of stabilizer, and the balance being solvent.

[0028] The dry suspension concentrate comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 5%-70% of wetting and dispersing agent, 0.01%-5% of suspending agent, 0%-5% of stabilizer, and the balance is carrier;

[0029] The water-dispersible tablet comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1-20% of wetting and dispersing agent, 0.01-5% of suspending agent, 2-20% of tableting aid, 0%-5% of stabilizer, and the balance is carrier;

[0030] The soluble granules, by weight percentage, include 0.5%-70% active component A, 0.5%-70% active component B, 1-20% wetting and dispersing agent, 0.01-5% suspending agent, 0%-5% stabilizer, and the balance is carrier;

[0031] The soluble powder comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1-20% of wetting and dispersing agent, 0.01-5% of suspending agent, 0%-5% of stabilizer, and the balance is carrier;

[0032] The emulsifiable powder comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1-40% of wetting and dispersing agent, 0.01-5% of suspending agent, 0%-5% of stabilizer, and the balance is carrier;

[0033] The emulsifiable granules contain, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1-40% of wetting and dispersing agent, 0.01-5% of suspending agent, 0%-5% of stabilizer, and the balance is carrier.

[0034] When the stabilizer is 0, the wetting and dispersing agent can be lignin sulfonate

[0035] further,

[0036] The granules, by weight percentage, include 5%-40% active component A, 5%-40% active component B, 1-15% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is carrier;

[0037] The wettable powder comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1-15% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is carrier;

[0038] The water dispersible granules, by weight percentage, include 5%-40% active component A, 5%-40% active component B, 1-15% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is carrier;

[0039] The suspending agent comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is deionized water.

[0040] The dispersible oil suspension comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1%-30% of wetting dispersant, 0.2%-5% of stabilizer, and the balance being dispersed phase oil base.

[0041] The microcapsule suspension comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1%-20% of wetting dispersant, 1%-5% of capsule material, 0.2%-5% of stabilizer, and the balance is dispersed phase oil base.

[0042] The suspoemulsion comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 2%-30% of solvent, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is deionized water.

[0043] The soluble solution comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance being solvent.

[0044] The seed treatment suspending agent comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1%-30% of wetting and dispersing agent, 1%-20% of warning color, 0.2%-5% of stabilizer, and the balance is deionized water.

[0045] The aqueous emulsion comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 2%-30% of solvent, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is deionized water.

[0046] The microemulsion comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 2%-30% of solvent, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is deionized water.

[0047] The emulsifiable concentrate comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance being solvent.

[0048] The dry suspension concentrate comprises, by weight percentage, 5%-40% active component A, 5%-40% active component B, 5%-70% wetting and dispersing agent, 0.01%-5% suspending agent, 0.2%-5% stabilizer, and the balance is carrier;

[0049] The water-dispersible tablet comprises, by weight percentage, 5%-40% active component A, 5%-40% active component B, 1-20% wetting and dispersing agent, 0.01-5% suspending agent, 2-20% tableting aid, 0.2%-5% stabilizer, and the balance is carrier;

[0050] The soluble granules, by weight percentage, include 5%-40% active component A, 5%-40% active component B, 1-20% wetting and dispersing agent, 0.01-5% suspending agent, 0.2%-5% stabilizer, and the balance is carrier;

[0051] The soluble powder comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1-20% of wetting and dispersing agent, 0.01-5% of suspending agent, 0.2%-5% of stabilizer, and the balance is carrier;

[0052] The emulsifiable powder comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1-40% of wetting and dispersing agent, 0.01-5% of suspending agent, 0.2%-5% of stabilizer, and the balance is carrier;

[0053] The emulsifiable granules include, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1-40% of wetting and dispersing agent, 0.01-5% of suspending agent, 0.2%-5% of stabilizer, and the balance is carrier.

[0054] The wetting and dispersing agent is one or more of various salt surfactants, polymer copolymers, polyether surfactants, modified surfactants, polyvinyl alcohol, and chitosan; specifically, it includes but is not limited to lignin sulfonate (SK-24N), polyacrylic acid salt (SD-811), polycarboxylate (SD816, SD819, Emulson 14105, SP-2750, D800, ULTRASURF 7023A, D-205 or D-305), carboxylate (SD815, SK-25CH or TANEMUL DA2880), carboxylic acid polymer copolymer (Atlox 4913), sulfonate (SK-20TX, SK-24R), sulfate (YUS-FS7PG), phosphate (YUS-FS3000), aryl ether phosphate (SK-33SC), twin-structure amphiphilic surfactant complex (SP-SC3 or SP-SC29), natural polymer modified (Lamfix SO), compound additives of polyacrylate copolymer (FS981), special structure polymer surfactant (SP-27001), EO / PO block polyether (D800 or Atlas G5000), polymer (PVA), block copolymer (DB08, AMS303 or XA265), polymer surfactant with "ABA" regular structure (SP-2836), TWEEN L 1505-LQ-(AP), TWEEN L 0515-LQ-(AP), TWEEN L 1010-LQ-(AP), ATPLUS245-LQ-(TH), ATPLUS UEP 100LQ(CQ), Greenwet 7600, hydroxy polyethylene oxide block copolymer (Agrilan 788 or Ethylan NS-500LQ), single comb polymer (Agrilan 755), sodium salt of alkyl naphthalene sulfonic acid polycondensate + block copolymer (Morwet D500), one or more of Nong Ru T-20, Nong Ru 0201B, Nong Ru 0203B, Nong Ru 1601, sodium naphthalene sulfonate formaldehyde condensate, and sodium salt of methyl naphthalene sulfonate formaldehyde condensate.

[0055] The solvent is one or more of toluene, xylene, solvent oil, fatty acid methyl ester, methyl oleate, liquid paraffin, epoxidized soybean oil, N,N-dimethylformamide, N,N-dimethyldecylamide, sec-butyl acetate, cyclohexanone and dimethyl sulfoxide.

[0056] The oil base is one or more of mineral oils, vegetable oils and esters thereof.

[0057] The warning color is a dye or a pigment (including toner and color paste); such as 1211-S and RED131.

[0058] The carrier may be one or more of, but not limited to, clay, rock powder, chalk, quartz, clay, montmorillonite, sodium sulfate, silicon dioxide, diatomaceous earth, pumice, gypsum, talc, bentonite, kaolin, attapulgite, light calcium carbonate, clay, montmorillonite, magnesium aluminum silicate, activated clay, white carbon black, ammonium sulfate, benzofuran resin, superphosphate, alumina, calcite, marble, pumice, etc. Preferably, it is one or more of, clay, rock powder, diatomaceous earth, bentonite, kaolin, attapulgite, light calcium carbonate, montmorillonite, activated clay, and white carbon black.

[0059] Thickening substances may also be included, which may be one or more of xanthan gum, gelatin, gum arabic, polyvinyl acetate, polyvinyl pyrrolidone, magnesium aluminum silicate, polyethylene glycol, phenolic resin, sodium polyacrylate, polyurea prepolymer, styrene maleic anhydride copolymer, shellac, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose and sodium alginate, which may improve the stability of the preparation to a certain extent.

[0060] If required by the application, a defoaming agent may be added. The defoaming agent may be one or more of SAG1522, silicones, C8-10 fatty alcohols, phosphates, C10-20 saturated fatty acids (such as capric acid) and amides or others.

[0061] If it is necessary to store it for a long time, a preservative may be added, which may be one or more of sodium benzoate, kason (2-methyl-4-isothiazoline-3-one and (B) 5-chloro-2-methyl-4-isothiazoline-3-one), potassium sorbate, sodium dehydroacetate or others.

[0062] The capsule material for preparing microcapsule suspension can be, but is not limited to, urea-formaldehyde prepolymer.

[0063] The tableting aid may be starch, modified starch, cellulose, modified cellulose, various resins, polyvinyl pyrrolidone, etc., and the filler refers to a mixture of one or more fillers.

[0064] The pesticide preparation also includes some commonly used ingredients known to the industry, such as pH regulators, antifreeze agents, preservatives, quartz sand, polyvinyl alcohol, glucose, ammonium sulfate, etc. The preparation process of the preparation can be the conventional method.

[0065] Application of a pesticide preparation containing a piperic acid derivative, and application of the preparation in the field of agricultural insecticides.

[0066] The insecticide pesticide preparation of the present invention can be diluted by the user before use or directly added with water for spraying.

[0067] The technical solution of the present invention also includes a method for controlling pests: applying the insecticide suspension of the present invention to the pests or their growth medium.

[0068] The insecticide suspension of the present invention can be used for the prevention and control of agricultural pests, forestry pests or non-therapeutic sanitary pests, and can effectively prevent and control pests such as the striped stem borer, corn borer, armyworm, diamondback moth, beet armyworm larvae, etc.

[0069] The advantages of the present invention are:

[0070] The present invention uses compounds as active substance A and active substance B as effective components, and is prepared as a pesticide preparation, and relates to a dosage form that can be prepared as a pesticide preparation that can be applied. The various types of pesticide preparations obtained solve the problems that the existing dosage forms under the conditions specified by the national standard for shelf life have various forms of particles that are uneven due to the compounding of two active substances in the same system, and the suspension rate of active substance A decreases when diluted and applied in water. On the one hand, this problem will make the preparation product not meet the national standards and be an unqualified product. On the other hand, it will affect the performance of insecticidal activity after biological activity determination. Further, the present invention adds decabromodiphenyl ether as a stabilizer in the preparation with a suitable wetting dispersant system under the conditions of selecting and matching a suitable auxiliary agent system, and gives a specific addition amount, which can effectively improve the suspension rate of the preparation. Decabromodiphenyl ether is added to the system as a flame retardant. When mixed with water and finally applied, it can effectively block the interaction between the two types of compounds, thereby suppressing the incompatibility of the two types of active substance particles of different structures. The problem of low suspension rate of mixed preparations in the prior art is solved, so that the suspension rate of the preparation is qualified, the product performance is guaranteed, and unexpected effects are achieved. DETAILED DESCRIPTION

[0071] The following specific examples are used to further illustrate the present invention in detail, but the present invention is by no means limited to these examples, and methods well known to those skilled in the art are all included in the scope of the present invention.

[0072] The insecticide preparation of the present invention adopts the combination of the auxiliary agent system and the interaction of the two active substances, so that during the conventional shelf life of the preparation, the suspension performance of the active component A is greatly improved through the combination of the auxiliary agent system and the addition of the stabilizing substance, and the suspension rate is qualified.

[0073] The percentages and parts in the following formula are all by weight. The active component A is prepared according to the prior art (content 93-99%) and added in a 100% dosage. The proportions of each component are by weight. Other raw materials are commercially available.

[0074] The active component A has the following structure:

[0075]

[0076] It can be prepared according to the Chinese invention patent CN112457288.

[0077] Preparation formula example

[0078] Comparative Example 1.51% Compound I-72·Indoxacarb Granules

[0079] According to the formula requirements, 50% of compound I-72, 1% of indoxacarb, and 8% of diatomaceous earth are mixed to obtain a mother powder, and then 5% of PVA is added and mixed with quartz sand to obtain 51% of compound I-72·indoxacarb granules.

[0080] Example 1-1.51% Compound I-72·Indoxacarb Granules

[0081] According to the formula requirements, 50% of compound I-72, 1% of indoxacarb, 5% of decabromodiphenyl ether, and 8% of diatomaceous earth are mixed to obtain a mother powder, and then 5% of PVA is added and mixed with quartz sand to obtain 51% of compound I-72·indoxacarb granules.

[0082] Example 1-2. 51% Compound I-72·Indoxacarb Granules

[0083] According to the formula requirements, 50% of compound I-72, 1% of indoxacarb, 5% of decabromodiphenyl ether, 5% of SK-24N, and 8% of diatomaceous earth are mixed to obtain a mother powder, and then 5% of PVA is added and mixed with quartz sand to obtain 51% of compound I-72·indoxacarb granules.

[0084] Comparative Example 2.21% Compound I-72·Indoxacarb dispersible oil suspension

[0085] According to the formula requirements, 20% of compound I-72, 1% of indoxacarb, 10% of agricultural milk T-20, 10% of Ethylan NS-500LQ, 2% of white carbon black, and methyl oleate to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 21% compound I-72·indoxacarb dispersible oil suspension.

[0086] Example 2-1.21% Compound I-72·Indoxacarb Dispersible Oil Suspension

[0087] According to the formula requirements, 20% of compound I-72, 1% of indoxacarb, 10% of agricultural milk T-20, 10% of Ethylan NS-500LQ, 2% of decabromodiphenyl ether, 2% of white carbon black, and methyl oleate to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 21% compound I-72·indoxacarb dispersible oil suspension.

[0088] Example 2-2. 21% Compound I-72·Indoxacarb Dispersible Oil Suspension

[0089] According to the formula requirements, 20% of compound I-72, 1% of indoxacarb, 10% of agricultural milk T-20, 10% of Ethylan NS-500LQ, 2% of decabromodiphenyl ether, 2% of SK-24N, 2% of white carbon black, and methyl oleate to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 21% compound I-72·indoxacarb dispersible oil suspension.

[0090] Comparative Example 3.32% Compound I-72·Indoxacarb Suspension Emulsion

[0091] According to the formula requirements, 30% of compound I-72, 2% of indoxacarb, 10% of D305, 10% of SD-811, 0.1% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 32% compound I-72·indoxacarb suspoemulsion.

[0092] Example 3-1.32% Compound I-72·Indoxacarb Suspension Emulsion

[0093] According to the formula requirements, 30% of compound I-72, 2% of indoxacarb, 10% of D305, 10% of SD-811, 1% of decabromodiphenyl ether, 0.1% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 32% compound I-72·indoxacarb suspoemulsion.

[0094] Example 3-2.32% Compound I-72·Indoxacarb Suspension Emulsion

[0095] According to the formula requirements, 30% of compound I-72, 2% of indoxacarb, 10% of D305, 10% of SD-811, 1% of decabromodiphenyl ether, 1% of SK-24N, 0.1% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 32% compound I-72·indoxacarb suspoemulsion.

[0096] Comparative Example 4.44% Compound I-72·Indoxacarb EC

[0097] According to the formula requirements, compound I-72 40%, indoxacarb 4%, Nongru 0201B 10%, Nongru 1601 10%, S150 is added to 100%, stirred and mixed evenly, and heated in a hot water bath to dissolve if necessary, to obtain 44% compound I-72·indoxacarb emulsifiable concentrate.

[0098] Comparative Example 5.30% Compound I-72·Indoxacarb Microcapsule Suspension

[0099] According to the formula requirements, 25% of compound I-72, 5% of indoxacarb, and 20% of S150 were stirred evenly, and an aqueous solution containing 10% of YUS-FS7PG was added thereto and stirred to obtain an O / W stable emulsion. The capsule material urea-formaldehyde prepolymer was added thereto to wrap the oil phase material, and a 30% compound I-72·indoxacarb microcapsule suspension was obtained.

[0100] Example 5-1. 30% Compound I-72·Indoxacarb Microcapsule Suspension

[0101] According to the formula requirements, 25% of compound I-72, 5% of indoxacarb, and 20% of S150 were stirred evenly, and an aqueous solution containing 10% of YUS-FS7PG and 0.5% of decabromodiphenyl ether were added thereto, and stirred to obtain an O / W stable emulsion. The capsule material urea-formaldehyde prepolymer was added thereto to wrap the oil phase material, and a 30% compound I-72·indoxacarb microcapsule suspension was obtained.

[0102] Example 5-2. 30% Compound I-72·Indoxacarb Microcapsule Suspension

[0103] According to the formula requirements, 25% of compound I-72, 5% of indoxacarb, and 20% of S150 were stirred evenly, and an aqueous solution containing 10% of YUS-FS7PG, 0.5% of decabromodiphenyl ether, and 0.5% of SK-24N were added thereto, and stirred to obtain an O / W stable emulsion. The capsule material urea-formaldehyde prepolymer was added thereto to wrap the oil phase material, and a 30% compound I-72·indoxacarb microcapsule suspension was obtained.

[0104] Comparative Example 6.30% Compound I-72·Indoxacarb dispersible liquid

[0105] According to the formula requirements, 25% of compound I-72, 5% of indoxacarb, 30% of methyl oleate, 10% of Nongru 0201B, and 10% of D800 were stirred and mixed uniformly to obtain a 30% compound I-72·indoxacarb dispersible liquid.

[0106] Example 6-1. 30% Compound I-72·Indoxacarb Dispersible Liquid

[0107] According to the formula requirements, 25% of compound I-72, 5% of indoxacarb, 30% of methyl oleate, 10% of Nongru 0201B, 10% of D800, and 0.5% of decabromodiphenyl ether are stirred and mixed uniformly to obtain a 30% compound I-72·indoxacarb dispersible liquid.

[0108] Example 6-2. 30% Compound I-72·Indoxacarb Dispersible Liquid

[0109] According to the formula requirements, 25% of compound I-72, 5% of indoxacarb, 30% of methyl oleate, 10% of Nongru 0201B, 10% of D800, 0.5% of decabromodiphenyl ether, and 0.5% of SK-24N are stirred and mixed evenly to obtain a 30% compound I-72·indoxacarb dispersible liquid.

[0110] Comparative Example 7.30% Compound I-72·Indoxacarb Suspension

[0111] According to the formula requirements, 20% of compound I-72, 10% of indoxacarb, 10% of SK-20TX, 10% of SP27001, 0.12% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·indoxacarb suspension.

[0112] Example 7-1.30% Compound I-72·Indoxacarb Suspension

[0113] According to the formula requirements, 20% of compound I-72, 10% of indoxacarb, 10% of SK-20TX, 10% of SP27001, 0.12% of xanthan gum, 0.3% of decabromodiphenyl ether, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·indoxacarb suspension.

[0114] Example 7-2. 30% Compound I-72·Indoxacarb Suspension

[0115] According to the formula requirements, 20% of compound I-72, 10% of indoxacarb, 10% of SK-20TX, 10% of SP27001, 0.12% of xanthan gum, 0.3% of SK-24N, and water to 100% are sequentially added into a mixing tank for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·indoxacarb suspension.

[0116] Example 7-3. 30% Compound I-72·Indoxacarb Suspension

[0117] According to the formula requirements, 20% of compound I-72, 10% of indoxacarb, 10% of SK-20TX, 10% of SP27001, 0.12% of xanthan gum, 0.3% of decabromodiphenyl ether, 0.3% of SK-24N, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·indoxacarb suspension.

[0118] Comparative Example 8.20% Compound I-72·Indoxacarb Suspension

[0119] According to the formula requirements, 10% of compound I-72, 10% of indoxacarb, 10% of SK-20TX, 10% of SP27001, 0.12% of xanthan gum, and water to 100% are sequentially added into a mixing tank for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 20% compound I-72·indoxacarb suspension.

[0120] Example 8-1.20% Compound I-72·Indoxacarb Suspension

[0121] According to the formula requirements, 10% of compound I-72, 10% of indoxacarb, 10% of SK-33SC, 10% of SP27001, 0.12% of xanthan gum, 0.2% of decabromodiphenyl ether, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 20% compound I-72·indoxacarb suspension.

[0122] Example 8-2. 20% Compound I-72·Indoxacarb Suspension

[0123] According to the formula requirements, 10% of compound I-72, 10% of indoxacarb, 10% of SK-33SC, 10% of SP27001, 0.12% of xanthan gum, 0.2% of SK-24N, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 20% compound I-72·indoxacarb suspension.

[0124] Example 8-3. 20% Compound I-72·Indoxacarb Suspension

[0125] According to the formula requirements, 10% of compound I-72, 10% of indoxacarb, 10% of SK-33SC, 10% of SP27001, 0.12% of xanthan gum, 0.2% of decabromodiphenyl ether, 0.2% of SK-24N, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 20% compound I-72·indoxacarb suspension.

[0126] Comparative Example 9.10% Compound I-72·Indoxacarb Solution

[0127] According to the formula requirements, compound I-72 5%, indoxacarb 5%, 14105 10%, Nongru 1601 10%, S150 is added to 100%, and the mixture is stirred and mixed to obtain a 10% compound I-72·indoxacarb soluble solution.

[0128] Comparative Example 10.20% Compound I-72·Indoxacarb seed treatment suspension

[0129] According to the formula requirements, 10% of compound I-72, 10% of indoxacarb, 10% of SK-20TX, 10% of SPSC3, 0.10% of xanthan gum, 5% of RED131, and water to 100% are sequentially added into a mixing tank for mixing, firstly subjected to high shearing for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 20% compound I-72·indoxacarb seed treatment suspension.

[0130] Example 10-1. 20% Compound I-72·Indoxacarb Seed Treatment Suspension Concentrate

[0131] According to the formula requirements, 10% of compound I-72, 10% of indoxacarb, 10% of SK-20TX, 10% of SPSC3, 0.10% of xanthan gum, 5% of RED131, 0.2% of decabromodiphenyl ether, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 20% compound I-72·indoxacarb seed treatment suspension.

[0132] Example 10-2. 20% Compound I-72·Indoxacarb Seed Treatment Suspension Concentrate

[0133] According to the formula requirements, 10% of compound I-72, 10% of indoxacarb, 10% of SK-20TX, 10% of SPSC3, 0.10% of xanthan gum, 5% of RED131, 0.2% of decabromodiphenyl ether, 0.2% of SK-24N, and water supplemented to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 20% compound I-72·indoxacarb seed treatment suspension.

[0134] Comparative Example 11.30% Compound I-72·Indoxacarb Suspension

[0135] According to the formula requirements, 10% of compound I-72, 20% of indoxacarb, 10% of Atlox, 10% of DB08, 0.15% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·indoxacarb suspension.

[0136] Example 11-1.30% Compound I-72·Indoxacarb Suspension

[0137] According to the formula requirements, 10% of compound I-72, 20% of indoxacarb, 10% of Atlox, 10% of DB08, 0.15% of xanthan gum, 0.4% of decabromodiphenyl ether, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·indoxacarb suspension.

[0138] Example 11-2. 30% Compound I-72·Indoxacarb Suspension

[0139] According to the formula requirements, 10% of compound I-72, 20% of indoxacarb, 10% of Atlox, 10% of DB08, 0.15% of xanthan gum, 0.4% of SK-24N, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·indoxacarb suspension.

[0140] Example 11-3. 30% Compound I-72·Indoxacarb Suspension

[0141] According to the formula requirements, 10% of compound I-72, 20% of indoxacarb, 10% of Atlox, 10% of DB08, 0.15% of xanthan gum, 0.4% of decabromodiphenyl ether, 0.4% of SK-24N, and water to 100% are sequentially added into a mixing tank for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·indoxacarb suspension.

[0142] Comparative Example 12.44% Compound I-72·Indoxacarb water dispersible granules

[0143] According to the formula requirements, compound I-72 4%, indoxacarb 40%, Agrilan 755 2%, SK-20TX 3%, soluble starch 10%, sodium sulfate 8%, bentonite is added to 100%, and 44% compound I-72·indoxacarb water dispersible granules can be obtained.

[0144] Example 12 - 1.44% Compound I-72·Indoxacarb Water Dispersible Granules

[0145] According to the formula requirements, compound I-72 4%, indoxacarb 40%, Agrilan 755 2%, SK-20TX 3%, soluble starch 10%, sodium sulfate 8%, decabromodiphenyl ether 3%, bentonite is added to 100%, and 44% compound I-72·indoxacarb water dispersible granules can be obtained.

[0146] Example 12-2.44% Compound I-72·Indoxacarb Water Dispersible Granules

[0147] According to the formula requirements, compound I-72 4%, indoxacarb 40%, Agrilan 755 2%, SK-20TX 3%, soluble starch 10%, sodium sulfate 8%, decabromodiphenyl ether 3%, SK-24N 3%, bentonite is supplemented to 100%, and 44% compound I-72·indoxacarb water dispersible granules can be obtained.

[0148] Comparative Example 13.51% Compound I-72·Indoxacarb wettable powder

[0149] According to the formula requirements, 1% of compound I-72, 50% of indoxacarb, 5% of D205, 3% of D500, 5% of white carbon black, and light calcium carbonate are added to 100% to obtain 51% of compound I-72·indoxacarb wettable powder.

[0150] Example 13 - 1.51% Compound I-72·Indoxacarb Wettable Powder

[0151] According to the formula requirements, compound I-72 1%, indoxacarb 50%, D205 5%, D500 3%, white carbon black 5%, decabromodiphenyl ether 4%, and light calcium carbonate are added to 100%, and 51% compound I-72·indoxacarb wettable powder can be obtained.

[0152] Example 13-2.51% Compound I-72·Indoxacarb Wettable Powder

[0153] According to the formula requirements, compound I-72 1%, indoxacarb 50%, D205 5%, D500 3%, white carbon black 5%, decabromodiphenyl ether 4%, SK-24N 4%, and light calcium carbonate are added to 100%, and 51% compound I-72·indoxacarb wettable powder can be obtained.

[0154] Comparative Example 14.51% Compound I-72·Chlorantraniliprole Granules

[0155] According to the formula requirements, 50% of compound I-72, 1% of chlorantraniliprole, and 8% of diatomaceous earth are mixed to obtain a mother powder, and then 5% of PVA is added and mixed with quartz sand to obtain 51% compound I-72·chlorantraniliprole granules with good physical properties.

[0156] Example 14 - 1.51% Compound I-72·Chlorantraniliprole Granules

[0157] According to the formula requirements, 50% of compound I-72, 1% of chlorantraniliprole, 5% of decabromodiphenyl ether, and 8% of diatomaceous earth are mixed to obtain a mother powder, and then 5% of PVA is added and mixed with quartz sand to obtain 51% of compound I-72·chlorantraniliprole granules with good physical properties.

[0158] Example 14-2.51% Compound I-72·Chlorantraniliprole Granules

[0159] According to the formula requirements, 50% of compound I-72, 1% of chlorantraniliprole, 5% of decabromodiphenyl ether, 5% of SK-24N, and 8% of diatomaceous earth are mixed to obtain a mother powder, and then 5% of PVA is added and mixed with quartz sand to obtain 51% of compound I-72·chlorantraniliprole granules with good physical properties.

[0160] Comparative Example 15.21% Compound I-72·Chlorantraniliprole Microcapsule Suspension

[0161] According to the formula requirements, 20% of compound I-72, 1% of chlorantraniliprole, and 20% of S150 were stirred evenly, and an aqueous solution containing 10% of YUS-FS3000 was added thereto and stirred to obtain an O / W stable emulsion. The capsule material urea-formaldehyde prepolymer was added thereto to wrap the oil phase material, and a 21% compound I-72·chlorantraniliprole microcapsule suspension was obtained.

[0162] Example 15-1.21% Compound I-72·Chlorantraniliprole Microcapsule Suspension

[0163] According to the formula requirements, 20% of compound I-72, 1% of chlorantraniliprole, 20% of S150, and 4% of decabromodiphenyl ether are stirred evenly, and an aqueous solution containing 10% of YUS-FS3000 is added thereto, and stirred to obtain an O / W stable emulsion. The capsule material urea-formaldehyde prepolymer is added thereto to wrap the oil phase material, and a 21% compound I-72·chlorantraniliprole microcapsule suspension is obtained.

[0164] Example 15-2. 21% Compound I-72·Chlorantraniliprole Microcapsule Suspension

[0165] According to the formula requirements, 20% of compound I-72, 1% of chlorantraniliprole, 20% of S150, 4% of decabromodiphenyl ether, and 4% of SK-24N are stirred evenly, and an aqueous solution containing 10% of YUS-FS3000 is added thereto, and stirred to obtain an O / W stable emulsion. The capsule material urea-formaldehyde prepolymer is added thereto to wrap the oil phase material, and a 21% compound I-72·chlorantraniliprole microcapsule suspension is obtained.

[0166] Comparative Example 16.66% Compound I-72·Chlorantraniliprole dispersible oil suspension

[0167] According to the formula requirements, 60% of compound I-72, 6% of chlorantraniliprole, 10% of Nongru 0203B, 10% of Ethylan NS-500LQ, 2% of white carbon black, and methyl oleate to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 66% compound I-72·chlorantraniliprole dispersible oil suspension.

[0168] Example 16 - 1.66% Compound I-72·Chlorantraniliprole Dispersible Oil Suspension

[0169] According to the formula requirements, 60% of compound I-72, 6% of chlorantraniliprole, 10% of Nongru 0203B, 10% of Ethylan NS-500LQ, 3% of decabromodiphenyl ether, 2% of white carbon black, and methyl oleate to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 66% compound I-72 chlorantraniliprole dispersible oil suspension.

[0170] Example 16 - 2.66% Compound I-72·Chlorantraniliprole Dispersible Oil Suspension

[0171] According to the formula requirements, 60% of compound I-72, 6% of chlorantraniliprole, 10% of Nongru 0203B, 10% of Ethylan NS-500LQ, 3% of decabromodiphenyl ether, 3% of SK-24N, 2% of white carbon black, and methyl oleate to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 66% compound I-72·chlorantraniliprole dispersible oil suspension.

[0172] Comparative Example 17.6% Compound I-72·Chlorantraniliprole Dispersible Liquid

[0173] According to the formula requirements, 5% of compound I-72, 1% of chlorantraniliprole, 30% of methyl oleate, 10% of Nongru 0203B, and 10% of SD815 are stirred and mixed evenly to obtain a 6% compound I-72·chlorantraniliprole dispersible liquid.

[0174] Example 17-1.6% Compound I-72·Chlorantraniliprole Dispersible Liquid

[0175] According to the formula requirements, 5% of compound I-72, 1% of chlorantraniliprole, 30% of methyl oleate, 10% of Nongru 0203B, 10% of SD815, and 0.2% of decabromodiphenyl ether are stirred and mixed evenly to obtain a 6% compound I-72·chlorantraniliprole dispersible liquid.

[0176] Example 17-2.6% Compound I-72·Chlorantraniliprole Dispersible Liquid

[0177] According to the formula requirements, 5% of compound I-72, 1% of chlorantraniliprole, 30% of methyl oleate, 10% of Nongru 0203B, 10% of SD815, 0.2% of decabromodiphenyl ether, and 0.2% of SK-24N are stirred and mixed evenly to obtain a 6% compound I-72·chlorantraniliprole dispersible liquid.

[0178] Comparative Example 18.24% Compound I-72·Chlorantraniliprole Suspension Concentrate

[0179] According to the formula requirements, 18% of compound I-72, 6% of chlorantraniliprole, 10% of SD811, 10% of SP27001, and 0.16% of xanthan gum are added to a mixing tank in sequence and mixed. They are first coarsely crushed and homogenized by high shear, and then pumped into a sand mill for fine grinding to obtain a 24% compound I-72·chlorantraniliprole suspension.

[0180] Example 18-1.24% Compound I-72·Chlorantraniliprole Suspension Concentrate

[0181] According to the formula requirements, 18% of compound I-72, 6% of chlorantraniliprole, 10% of SD811, 10% of SP27001, 0.16% of xanthan gum, 0.4% of decabromodiphenyl ether, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 24% compound I-72·chlorantraniliprole suspension.

[0182] Example 18-2.24% Compound I-72·Chlorantraniliprole Suspension Concentrate

[0183] According to the formula requirements, 18% of compound I-72, 6% of chlorantraniliprole, 10% of SD811, 10% of SP27001, 0.16% of xanthan gum, and 0.4% of SK-24N are added to a mixing tank in sequence for mixing, first subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 24% compound I-72·chlorantraniliprole suspension.

[0184] Example 18-3.24% Compound I-72·Chlorantraniliprole Suspension Concentrate

[0185] According to the formula requirements, 18% of compound I-72, 6% of chlorantraniliprole, 10% of SD811, 10% of SP27001, 0.16% of xanthan gum, 0.4% of decabromodiphenyl ether, and 0.4% of SK-24N are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 24% compound I-72·chlorantraniliprole suspension.

[0186] Comparative Example 19.16% Compound I-72·Chlorantraniliprole Soluble Solution

[0187] According to the formula requirements, compound I-72 12%, chlorantraniliprole 4%, AMS303 10%, Nongru 1601 10%, S150 is added to 100%, and stirred to mix evenly to obtain a 16% compound I-72·chlorantraniliprole soluble solution.

[0188] Comparative Example 20.28% Compound I-72·Chlorantraniliprole seed treatment suspension

[0189] According to the formula requirements, 21% of compound I-72, 7% of chlorantraniliprole, 10% of SK-25CH, 10% of SP27001, 0.10% of xanthan gum, 5% of RED131, and water supplemented to 100% are added to a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 28% compound I-72·chlorantraniliprole seed treatment suspension.

[0190] Example 20-1.28% Compound I-72·Chlorantraniliprole Seed Treatment Suspension Concentrate

[0191] According to the formula requirements, 21% of compound I-72, 7% of chlorantraniliprole, 10% of SK-25CH, 10% of SP27001, 1% of decabromodiphenyl ether, 0.10% of xanthan gum, 5% of RED131, and water supplemented to 100% are added to a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 28% compound I-72·chlorantraniliprole seed treatment suspension.

[0192] Example 20-2.28% Compound I-72·Chlorantraniliprole Seed Treatment Suspension Concentrate

[0193] According to the formula requirements, 21% of compound I-72, 7% of chlorantraniliprole, 10% of SK-25CH, 10% of SP27001, 1% of decabromodiphenyl ether, 1% of SK-24N, 0.10% of xanthan gum, 5% of RED131, and water supplemented to 100% are added to a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 28% compound I-72·chlorantraniliprole seed treatment suspension.

[0194] Comparative Example 21.30% Compound I-72·Chlorantraniliprole Suspension Concentrate

[0195] According to the formula requirements, 15% of compound I-72, 15% of chlorantraniliprole, 10% of G5000, 10% of DB08, 0.11% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·chlorantraniliprole suspension.

[0196] Example 21-1.30% Compound I-72·Chlorantraniliprole Suspension Concentrate

[0197] According to the formula requirements, 15% of compound I-72, 15% of chlorantraniliprole, 10% of G5000, 10% of DB08, 2% of decabromodiphenyl ether, 0.11% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·chlorantraniliprole suspension.

[0198] Example 21-2. 30% Compound I-72·Chlorantraniliprole Suspension Concentrate

[0199] According to the formula requirements, 15% of compound I-72, 15% of chlorantraniliprole, 10% of G5000, 10% of DB08, 2% of SK-24N, and 0.11% of xanthan gum are added in sequence into a mixing tank for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·chlorantraniliprole suspension.

[0200] Example 21-3. 30% Compound I-72·Chlorantraniliprole Suspension Concentrate

[0201] According to the formula requirements, 15% of compound I-72, 15% of chlorantraniliprole, 10% of G5000, 10% of DB08, 2% of decabromodiphenyl ether, 2% of SK-24N, 0.11% of xanthan gum, and water supplemented to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72·chlorantraniliprole suspension.

[0202] Comparative Example 22.40% Compound I-72·Chlorantraniliprole Suspension Emulsion

[0203] According to the formula requirements, 10% of compound I-72, 30% of chlorantraniliprole, 10% of D205, 10% of D800, 0.1% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 40% compound I-72·chlorantraniliprole suspoemulsion.

[0204] Example 22-1. 40% Compound I-72·Chlorantraniliprole Suspension Emulsion

[0205] According to the formula requirements, 10% of compound I-72, 30% of chlorantraniliprole, 10% of D205, 10% of D800, 0.1% of xanthan gum, 2% of decabromodiphenyl ether, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 40% compound I-72·chlorantraniliprole suspoemulsion.

[0206] Example 22-2. 40% Compound I-72·Chlorantraniliprole Suspension Emulsion

[0207] According to the formula requirements, 10% of compound I-72, 30% of chlorantraniliprole, 10% of D205, 10% of D800, 0.1% of xanthan gum, 2% of decabromodiphenyl ether, 2% of SK-24N, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 40% compound I-72·chlorantraniliprole suspoemulsion.

[0208] Comparative Example 23.3% Compound I-72·Chlorantraniliprole EC

[0209] According to the formula requirements, compound I-72 0.5%, chlorantraniliprole 2.5%, Nongru 0203B 10%, D800 10%, S150 is added to 100%, stirred and mixed evenly, and heated in a hot water bath to dissolve if necessary, to obtain 3% compound I-72·chlorantraniliprole emulsifiable concentrate.

[0210] Comparative Example 24.44% Compound I-72·Chlorantraniliprole Water Dispersible Granules

[0211] According to the formula requirements, compound I-72 4%, chlorantraniliprole 40%, SP2750 2%, SK-20TX 3%, soluble starch 15%, sodium sulfate 6%, and bentonite is supplemented to 100% to obtain 44% compound I-72·chlorantraniliprole water dispersible granules.

[0212] Example 24-1.44% Compound I-72·Chlorantraniliprole Water Dispersible Granules

[0213] According to the formula requirements, compound I-72 4%, chlorantraniliprole 40%, SP2750 2%, SK-20TX 3%, soluble starch 15%, sodium sulfate 6%, decabromodiphenyl ether 3%, and bentonite is supplemented to 100% to obtain 44% compound I-72·chlorantraniliprole water dispersible granules.

[0214] Example 24-2.44% Compound I-72·Chlorantraniliprole Water Dispersible Granules

[0215] According to the formula requirements, compound I-72 4%, chlorantraniliprole 40%, SP2750 2%, SK-20TX 3%, soluble starch 15%, sodium sulfate 6%, decabromodiphenyl ether 3%, SK-24N 3%, and bentonite is supplemented to 100% to obtain 44% compound I-72·chlorantraniliprole water dispersible granules.

[0216] Comparative Example 25.51% Compound I-72·Chlorantraniliprole Wettable Powder

[0217] According to the formula requirements, compound I-72 1%, chlorantraniliprole 50%, D305 5%, NS-500LQ 3%, white carbon black 8%, and light calcium carbonate are added to 100% to obtain 51% compound I-72·chlorantraniliprole wettable powder.

[0218] Example 25-1.51% Compound I-72·Chlorantraniliprole Wettable Powder

[0219] According to the formula requirements, compound I-72 1%, chlorantraniliprole 50%, D305 5%, NS-500LQ 3%, white carbon black 8%, decabromodiphenyl ether 4%, and light calcium carbonate are added to 100% to obtain 51% compound I-72·chlorantraniliprole wettable powder.

[0220] Example 25-2.51% Compound I-72·Chlorantraniliprole Wettable Powder

[0221] According to the formula requirements, compound I-72 1%, chlorantraniliprole 50%, D305 5%, NS-500LQ 3%, white carbon black 8%, decabromodiphenyl ether 4%, SK-24N 4%, and light calcium carbonate are added to 100% to obtain 51% compound I-72·chlorantraniliprole wettable powder.

[0222] Comparative Example 26.51% Compound I-72·Tetrachloranil Granules

[0223] According to the formula requirements, 50% of compound I-72, 1% of tetrachlorantraniliprole, and 8% of diatomaceous earth are mixed to obtain a mother powder, and then 5% of PVA is added and mixed with quartz sand to obtain 51% compound I-72·tetrachlorantraniliprole granules with good physical properties.

[0224] Example 26-1.51% Compound I-72·Tetrachlorantraniliprole Granules

[0225] According to the formula requirements, 50% of compound I-72, 1% of tetrachlorantraniliprole, 5% of decabromodiphenyl ether, and 8% of diatomaceous earth are mixed to obtain a mother powder, and then 5% of PVA is added and mixed with quartz sand to obtain 51% of compound I-72·tetrachlorantraniliprole granules with good physical properties.

[0226] Example 26-2.51% Compound I-72·Tetrachlorantraniliprole Granules

[0227] According to the formula requirements, 50% of compound I-72, 1% of tetrachlorantraniliprole, 5% of decabromodiphenyl ether, 5% of SK-24N, and 8% of diatomaceous earth are mixed to obtain a mother powder, and then 5% of PVA is added and mixed with quartz sand to obtain 51% of compound I-72·tetrachlorantraniliprole granules with good physical properties.

[0228] Comparative Example 27.21% Compound I-72·Tetrachloranil Microcapsule Suspension

[0229] According to the formula requirements, 20% of compound I-72, 1% of tetrachlorantraniliprole, and 20% of S150 are stirred evenly, and an aqueous solution containing 10% of YUS-FS3000 is added thereto and stirred to obtain an O / W stable emulsion. The capsule material urea-formaldehyde prepolymer is added thereto to wrap the oil phase material, and a 21% compound I-72 tetrachlorantraniliprole microcapsule suspension can be obtained.

[0230] Example 27-1.21% Compound I-72·Tetrachlorantraniliprole Microcapsule Suspension

[0231] According to the formula requirements, 20% of compound I-72, 1% of tetrachlorantraniliprole, 20% of S150, and 4% of decabromodiphenyl ether are stirred evenly, and an aqueous solution containing 10% of YUS-FS3000 is added thereto, and stirred to obtain an O / W stable emulsion. The capsule material urea-formaldehyde prepolymer is added thereto to wrap the oil phase material, and a 21% compound I-72 tetrachlorantraniliprole microcapsule suspension can be obtained.

[0232] Example 27-2.21% Compound I-72·Tetrachlorantraniliprole Microcapsule Suspension

[0233] According to the formula requirements, 20% of compound I-72, 1% of tetrachlorantraniliprole, 20% of S150, 4% of decabromodiphenyl ether, and 4% of SK-24N are stirred evenly, and an aqueous solution containing 10% of YUS-FS3000 is added thereto, and stirred to obtain an O / W stable emulsion. The capsule material urea-formaldehyde prepolymer is added thereto to wrap the oil phase material, and a 21% compound I-72 tetrachlorantraniliprole microcapsule suspension can be obtained.

[0234] Comparative Example 28.66% Compound I-72·Tetrachloranil dispersible oil suspension

[0235] According to the formula requirements, 60% of compound I-72, 6% of tetrachlorantraniliprole, 10% of agricultural milk 0203B, 10% of Ethylan NS-500LQ, 2% of white carbon black, and methyl oleate to 100% are added to a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 66% compound I-72 tetrachlorantraniliprole dispersible oil suspension.

[0236] Example 28-1.66% Compound I-72·Tetrachloranil dispersible oil suspension

[0237] According to the formula requirements, 60% of compound I-72, 6% of tetrachlorantraniliprole, 10% of agricultural milk 0203B, 10% of Ethylan NS-500LQ, 3% of decabromodiphenyl ether, 2% of white carbon black, and methyl oleate to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 66% compound I-72 tetrachlorantraniliprole dispersible oil suspension.

[0238] Example 28-2.66% Compound I-72·Tetrachloranil dispersible oil suspension

[0239] According to the formula requirements, 60% of compound I-72, 6% of tetrachlorantraniliprole, 10% of agricultural milk 0203B, 10% of Ethylan NS-500LQ, 3% of decabromodiphenyl ether, 3% of SK-24N, 2% of white carbon black, and methyl oleate to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 66% compound I-72 tetrachlorantraniliprole dispersible oil suspension.

[0240] Comparative Example 29.6% Compound I-72·Tetrachlorantraniliprole Dispersible Liquid

[0241] According to the formula requirements, 5% of compound I-72, 1% of tetrachlorantraniliprole, 30% of methyl oleate, 10% of Nongru 0203B, and 10% of SD815 are stirred and mixed evenly to obtain a 6% compound I-72·tetrachlorantraniliprole dispersible liquid.

[0242] Example 29-1.6% Compound I-72·Tetrachlorantraniliprole Dispersible Liquid

[0243] According to the formula requirements, 5% of compound I-72, 1% of tetrachlorantraniliprole, 30% of methyl oleate, 10% of Nongru 0203B, 10% of SD815, and 0.2% of decabromodiphenyl ether are stirred and mixed evenly to obtain a 6% compound I-72·tetrachlorantraniliprole dispersible liquid.

[0244] Example 29-2.6% Compound I-72·Tetrachlorantraniliprole Dispersible Liquid

[0245] According to the formula requirements, compound I-72 5%, tetrachlorantraniliprole 1%, methyl oleate 30%, Nongru 0203B 10%, SD815 10%, decabromodiphenyl ether 0.2%, SK-24N 0.2% are stirred and mixed evenly to obtain a 6% compound I-72 tetrachlorantraniliprole dispersible liquid.

[0246] Comparative Example 30.30% Compound I-72·Tetrachloranil Suspension Concentrate

[0247] According to the formula requirements, 20% of compound I-72, 10% of tetrachlorantraniliprole, 10% of SD811, 10% of SP27001, and 0.16% of xanthan gum are added to a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72 tetrachlorantraniliprole suspension.

[0248] Example 30-1.30% Compound I-72·Tetrachlorantraniliprole Suspension Concentrate

[0249] According to the formula requirements, 20% of compound I-72, 10% of tetrachlorantraniliprole, 10% of SD811, 10% of SP27001, 0.16% of xanthan gum, 0.4% of decabromodiphenyl ether, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72 tetrachlorantraniliprole suspension.

[0250] Example 30-2. 30% Compound I-72·Tetrachlorantraniliprole Suspension Concentrate

[0251] According to the formula requirements, 20% of compound I-72, 10% of tetrachlorantraniliprole, 10% of SD811, 10% of SP27001, 0.16% of xanthan gum, 0.4% of SK-24N, and water supplemented to 100% are added to a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72 tetrachlorantraniliprole suspension.

[0252] Example 30-3. 30% Compound I-72·Tetrachlorantraniliprole Suspension Concentrate

[0253] According to the formula requirements, 20% of compound I-72, 10% of tetrachlorantraniliprole, 10% of SD811, 10% of SP27001, 0.16% of xanthan gum, 0.4% of decabromodiphenyl ether, and 0.4% of SK-24N are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72 tetrachlorantraniliprole suspension.

[0254] Comparative Example 31.18% Compound I-72·Tetrachlorantraniliprole Soluble Solution

[0255] According to the formula requirements, compound I-72 12%, tetrachlorantraniliprole 6%, AMS303 10%, Nongru 1601 10%, S150 is added to 100%, and stirred and mixed evenly to obtain 18% compound I-72 tetrachlorantraniliprole soluble solution.

[0256] Comparative Example 32.21% Compound I-72·Tetrachlorantraniliprole Seed Treatment Suspension Agent

[0257] According to the formula requirements, 14% of compound I-72, 7% of tetrachlorantraniliprole, 10% of SK-25CH, 10% of SP27001, 0.10% of xanthan gum, 5% of RED131, and water supplemented to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 21% compound I-72·tetrachlorantraniliprole seed treatment suspension.

[0258] Example 32-1.21% Compound I-72·Tetrachlorantraniliprole Seed Treatment Suspension Concentrate

[0259] According to the formula requirements, 14% of compound I-72, 7% of tetrachlorantraniliprole, 10% of SK-25CH, 10% of SP27001, 1% of decabromodiphenyl ether, 0.10% of xanthan gum, 5% of RED131, and water supplemented to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 21% compound I-72·tetrachlorantraniliprole seed treatment suspension.

[0260] Example 32-2.21% Compound I-72·Tetrachlorantraniliprole Seed Treatment Suspension Concentrate

[0261] According to the formula requirements, 14% of compound I-72, 7% of tetrachlorantraniliprole, 10% of SK-25CH, 10% of SP27001, 1% of decabromodiphenyl ether, 1% of SK-24N, 0.10% of xanthan gum, 5% of RED131, and water supplemented to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 21% compound I-72·tetrachlorantraniliprole seed treatment suspension.

[0262] Comparative Example 33.30% Compound I-72·Tetrachloranil Suspension Concentrate

[0263] According to the formula requirements, 15% of compound I-72, 15% of tetrachlorantraniliprole, 10% of G5000, 10% of DB08, 0.11% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72 tetrachlorantraniliprole suspension.

[0264] Example 33-1.30% Compound I-72·Tetrachlorantraniliprole Suspension Concentrate

[0265] According to the formula requirements, 15% of compound I-72, 15% of tetrachlorantraniliprole, 10% of G5000, 10% of DB08, 2% of decabromodiphenyl ether, 0.11% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72 tetrachlorantraniliprole suspension.

[0266] Example 33-2. 30% Compound I-72·Tetrachlorantraniliprole Suspension Concentrate

[0267] According to the formula requirements, 15% of compound I-72, 15% of tetrachlorantraniliprole, 10% of G5000, 10% of DB08, 2% of SK-24N, and 0.11% of xanthan gum are added in sequence into a mixing tank for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72 tetrachlorantraniliprole suspension.

[0268] Example 33-3. 30% Compound I-72·Tetrachlorantraniliprole Suspension Concentrate

[0269] According to the formula requirements, 15% of compound I-72, 15% of tetrachlorantraniliprole, 10% of G5000, 10% of DB08, 2% of decabromodiphenyl ether, 2% of SK-24N, 0.11% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 30% compound I-72 tetrachlorantraniliprole suspension.

[0270] Comparative Example 34.20% Compound I-72·Tetrachloranilamide Suspension Emulsion

[0271] According to the formula requirements, 10% of compound I-72, 10% of tetrachlorantraniliprole, 10% of D205, 10% of D800, 0.1% of xanthan gum, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 20% compound I-72·tetrachlorantraniliprole suspoemulsion.

[0272] Example 34-1.20% Compound I-72·Tetrachlorantraniliprole Suspension Emulsion

[0273] According to the formula requirements, 10% of compound I-72, 10% of tetrachlorantraniliprole, 10% of D205, 10% of D800, 0.1% of xanthan gum, 2% of decabromodiphenyl ether, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 20% compound I-72·tetrachlorantraniliprole suspoemulsion.

[0274] Example 34-2. 20% Compound I-72·Tetrachlorantraniliprole Suspension Emulsion

[0275] According to the formula requirements, 10% of compound I-72, 10% of tetrachlorantraniliprole, 10% of D205, 10% of D800, 0.1% of xanthan gum, 2% of decabromodiphenyl ether, 2% of SK-24N, and water to 100% are added into a mixing tank in sequence for mixing, firstly subjected to high shear for coarse crushing and homogenization, and then pumped into a sand mill for fine grinding to obtain a 20% compound I-72·tetrachlorantraniliprole suspoemulsion.

[0276] Comparative Example 35.3% Compound I-72·Tetrachlorantraniliprole emulsifiable concentrate

[0277] According to the formula requirements, compound I-72 0.5%, tetrachlorantraniliprole 2.5%, Nongru 0203B 10%, D800 10%, S150 is added to 100%, stirred and mixed evenly, and heated in a hot water bath to dissolve if necessary, to obtain 3% compound I-72 tetrachlorantraniliprole emulsifiable concentrate.

[0278] Comparative Example 36.44% Compound I-72·Tetrachlorantraniliprole Water Dispersible Granules

[0279] According to the formula requirements, compound I-72 4%, tetrachlorantraniliprole 40%, SP2750 2%, SK-20TX 3%, soluble starch 15%, sodium sulfate 6%, and bentonite is supplemented to 100% to obtain 44% compound I-72 tetrachlorantraniliprole water-dispersible granules.

[0280] Example 36-1.44% Compound I-72·Tetrachlorantraniliprole Water Dispersible Granules

[0281] According to the formula requirements, compound I-72 4%, tetrachlorantraniliprole 40%, SP2750 2%, SK-20TX 3%, soluble starch 15%, sodium sulfate 6%, decabromodiphenyl ether 3%, and bentonite is supplemented to 100% to obtain 44% compound I-72 tetrachlorantraniliprole water-dispersible granules.

[0282] Example 36-2.44% Compound I-72·Tetrachlorantraniliprole Water Dispersible Granules

[0283] According to the formula requirements, compound I-72 4%, tetrachlorantraniliprole 40%, SP2750 2%, SK-20TX 3%, soluble starch 15%, sodium sulfate 6%, decabromodiphenyl ether 3%, SK-24N 3%, and bentonite is supplemented to 100% to obtain 44% compound I-72 tetrachlorantraniliprole water-dispersible granules.

[0284] Comparative Example 37.51% Compound I-72·Tetrachlorantraniliprole Wettable Powder

[0285] According to the formula requirements, compound I-72 1%, tetrachlorantraniliprole 50%, D305 5%, NS-500LQ 3%, white carbon black 8%, and light calcium carbonate are added to 100% to obtain 51% compound I-72 tetrachlorantraniliprole wettable powder.

[0286] Example 37-1.51% Compound I-72·Tetrachlorantraniliprole Wettable Powder

[0287] According to the formula requirements, compound I-72 1%, tetrachlorantraniliprole 50%, D305 5%, NS-500LQ 3%, white carbon black 8%, decabromodiphenyl ether 4%, and light calcium carbonate are added to 100% to obtain 51% compound I-72 tetrachlorantraniliprole wettable powder.

[0288] Example 37-2.51% Compound I-72·Tetrachlorantraniliprole Wettable Powder

[0289] According to the formula requirements, compound I-72 1%, tetrachlorantraniliprole 50%, D305 5%, NS-500LQ 3%, white carbon black 8%, decabromodiphenyl ether 4%, SK-24N 4%, and light calcium carbonate are added to 100% to obtain 51% compound I-72 tetrachlorantraniliprole wettable powder.

[0290] The above-mentioned embodiment is subjected to the suspension rate determination, and the determination is based on the method mentioned in the national standard GB / T14825. The specific method is to accurately weigh 1.5g of the preparation sample (accurate to 0.0002g), and determine it according to "Method 1" in GB / T14825. The remaining 25mL of suspension and sediment are transferred to a 100mL volumetric flask, washed twice with 10mL of methanol each time, and the washing liquid is added to the volumetric flask, and then fixed to volume with methanol, degassed in an ultrasonic bath for 10min, and cooled until the liquid level returns to the scale. Centrifugal separation, take the supernatant, use high performance liquid chromatography to determine the mass of the effective ingredient, and calculate the suspension rate X (see Table 2). The suspension rate formula is as follows:

[0291]

[0292] Where, m1 is the mass of the active ingredient in the sample taken to prepare the suspension, g;

[0293] m2—the mass of the active ingredient in the 25 mL suspension remaining at the bottom of the measuring cylinder, g;

[0294] Table 1 Results of determination of suspension rate of compound I-72·indoxacarb preparation

[0295]

[0296] Table 2 Results of determination of suspension rate of compound I-72·chlorantraniliprole preparation

[0297]

[0298]

[0299] Table 3 Results of determination of suspension rate of compound I-72·tetrachlorantraniliprole preparation

[0300]

[0301] It can be seen from Tables 1 to 3 that, since the two substances are compounded to prepare the preparation, they are difficult to be compatible when diluted in water, and the particles are uneven in shape, resulting in problems such as a decrease in the suspension rate of active substance A when the active ingredient is diluted in water. In the comparative example, decabromodiphenyl ether was added separately, and it was found that the suspension rate of active substance A was significantly improved. Especially under the condition of adding lignin sulfonate adjuvant SK-24N, compounding with decabromodiphenyl ether, that is, compounding with a suitable wetting and dispersing agent, the suspension rate is greatly improved. This problem can be effectively solved, and the compatibility problem in the dilution and application link of pesticide preparations can be effectively solved, which brings practical application significance.

[0302] Biologically active examples

[0303] Example 38. Insecticide Activity Indoor Efficacy Test

[0304] Test target: Diamondback moth (Plutella xylostella), 3rd instar larvae, susceptible strain reared indoors.

[0305] Test conditions: temperature: 25-27°C, humidity: RH 60%, light: L:D=14:10.

[0306] Test agents: Example 8, Comparative Example 8-1, Comparative Example 8-2, Comparative Example 8-3, Example 18, Example 18-1, Example 18-2, Example 18-3, Example 30, Example 30-1, Example 30-2, Example 30-3.

[0307] Test method: leaf dipping method (NY / T1154.14-2008), punch the cabbage leaves cultured in the greenhouse into leaf discs of about 3 cm with a hole puncher, and immerse them in the prepared solution for 10 seconds according to the designed test dose (4mg / L, 2mg / L, 1mg / L, 0.5mg / L, 0.25mg / L, 0.125mg / L) from low to high, take them out and put them into a culture dish with a diameter of 7 cm padded with filter paper, and inoculate the 3rd instar larvae of Spodoptera exigua after natural shade drying. Each treatment is repeated 3 times, and 10 insects are inoculated in each repeat. There are also clear water treatment and blank control. The treated test materials are placed in an observation room with certain conditions, and the number of dead and alive insects is investigated for 72 hours, and the mortality rate is calculated. The toxicity regression equation, LC50 value and 95% confidence limit and other indicators are calculated using DPS software.

[0308] Table 4 Indoor activity test results of the preparation samples against Spodoptera plutellae

[0309]

Claims

1. A pesticide preparation containing a piperic acid derivative, comprising an active ingredient and an agriculturally acceptable adjuvant and carrier, characterized in that: The active component weight percentage of the pesticide preparation is 1%-70%, wherein the active ingredients are active component A and active component B, the active component A is selected from compound I-72, the active component B is one or more of tetrachlorantraniliprole, chlorantraniliprole, and indoxacarb, and the weight ratio of active component A to active component B is 50:1-1:50; the active component A has the following structure: Compound I-72; The additive contains a stabilizer, the stabilizer is decabromodiphenyl ether, and the added amount is 0.2%-5% of the preparation mass.

2. The pesticide formulation containing piperic acid derivatives according to claim 1, characterized in that: The pesticide preparation is a granule, a tablet, an oil-dispersible powder, an emulsion, a water-dispersible granule, an emulsion, a water-dispersible tablet, a soluble powder, a soluble granule, a soluble tablet, an effervescent granule, an effervescent tablet, a soluble solution, a soluble gel, an oil, a film-spreading oil, a dispersible liquid, an ointment, an aqueous emulsion, an oil emulsion, a microemulsion, a suspension, a microcapsule suspension, an oil suspension, a dispersible oil suspension, a seed treatment agent, a seed treatment agent includes a seed treatment dry powder, a seed treatment dispersible powder, a seed treatment liquid, a seed treatment emulsion, a seed treatment suspension, an aerosol or an ultra-low solubility liquid.

3. The pesticide formulation containing piperic acid derivatives according to claim 1, characterized in that: The auxiliary agent is one or more of a wetting and dispersing agent, a solvent, a warning color, an oil base, a carrier, and a capsule material.

4. The pesticide formulation containing piperic acid derivatives according to claim 3, characterized in that: The wetting and dispersing agent is one or more of lignin sulfonate, polyacrylic acid salt, polycarboxylate, carboxylate, carboxylic acid polymer copolymer, sulfonate, sulfate, phosphate, aryl ether phosphate, twin-structure amphiphilic surfactant complex, compound auxiliary agent of polyacrylate copolymer, special structure polymer surfactant, EO / PO block polyether, polymer, block copolymer, single comb polymer, sodium salt + block copolymer of alkylnaphthalenesulfonic acid condensate, Nongru T-20, Nongru 0201B, Nongru 0203B, Nongru 1601, sodium naphthalenesulfonate formaldehyde condensate, sodium salt of methylnaphthalenesulfonate formaldehyde condensate, polyvinyl alcohol, and chitosan.

5. The pesticide formulation containing piperic acid derivatives according to claim 4, characterized in that: The wetting and dispersing agent is a mixture of lignin sulfonate and one or more of the following substances; the following substances are polyacrylates, polycarboxylates, carboxylates, carboxylic acid polymer copolymers, sulfonates, sulfates, phosphates, aryl ether phosphates, twin-structure amphiphilic surfactant complexes, compounded additives of polyacrylate copolymers, special structure polymer surfactants, EO / PO block polyethers, polymers, block copolymers, single comb polymers, sodium salt + block copolymers of alkyl naphthalene sulfonic acid condensates, Nong Ru T-20, Nong Ru 0201B, Nong Ru 0203B, Nong Ru 1601, sodium naphthalene sulfonate formaldehyde condensates, sodium salt of methyl naphthalene sulfonate formaldehyde condensates, polyvinyl alcohol, and chitosan.

6. The pesticide formulation containing piperic acid derivatives according to claim 4, characterized in that: When the wetting and dispersing agent is lignin sulfonate SK-24N, the mass ratio of the stabilizer to the wetting and dispersing agent is 1:

1.

7. A pesticide formulation containing a piperic acid derivative according to any one of claims 1 to 6, characterized in that: The granules, by weight percentage, include 0.5%-70% active component A, 0.5%-70% active component B, 1-15% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is carrier; The wettable powder comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1-20% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is carrier; The water dispersible granules, by weight percentage, include 0.5%-70% active component A, 0.5%-70% active component B, 1-20% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is carrier; The suspending agent, by weight percentage, comprises 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is deionized water; The dispersible oil suspension comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance being dispersed phase oil base; The microcapsule suspension comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-20% of wetting and dispersing agent, 1%-5% of capsule material, 0.2%-5% of stabilizer, and the balance is dispersed phase oil base; The suspoemulsion comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 2%-30% of solvent, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is deionized water; The soluble solution comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance being solvent; The seed treatment suspension comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-30% of wetting and dispersing agent, 1%-20% of warning color, 0.2%-5% of stabilizer, and the balance is deionized water; The aqueous emulsion comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 2%-30% of solvent, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is deionized water; The microemulsion comprises, by weight percentage, 0.5%-70% active component A, 0.5%-70% active component B, 2%-30% solvent, 1%-30% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is deionized water; The emulsifiable concentrate comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance being solvent; The dry suspension concentrate comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 5%-70% of wetting and dispersing agent, 0.01%-5% of suspending agent, 0.2%-5% of stabilizer, and the balance is carrier; The water-dispersible tablet comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1-20% of wetting and dispersing agent, 0.01-5% of suspending agent, 2-20% of tableting aid, 0.2%-5% of stabilizer, and the balance is carrier; The soluble granules, by weight percentage, include 0.5%-70% active component A, 0.5%-70% active component B, 1-20% wetting and dispersing agent, 0.01-5% suspending agent, 0.2%-5% stabilizer, and the balance is carrier; The soluble powder comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1-20% of wetting and dispersing agent, 0.01-5% of suspending agent, 0.2%-5% of stabilizer, and the balance is carrier; The emulsifiable powder comprises, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1-40% of wetting and dispersing agent, 0.01-5% of suspending agent, 0.2%-5% of stabilizer, and the balance is carrier; The emulsifiable granules include, by weight percentage, 0.5%-70% of active component A, 0.5%-70% of active component B, 1-40% of wetting and dispersing agent, 0.01-5% of suspending agent, 0.2%-5% of stabilizer, and the balance being carrier.

8. The pesticide formulation containing piperic acid derivatives according to claim 7, characterized in that: The granules, by weight percentage, include 5%-40% active component A, 5%-40% active component B, 1-15% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is carrier; The wettable powder comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1-15% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is carrier; The water dispersible granules, by weight percentage, include 5%-40% active component A, 5%-40% active component B, 1-15% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is carrier; The suspending agent, by weight percentage, comprises 5%-40% active component A, 5%-40% active component B, 1%-30% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is deionized water; The dispersible oil suspension comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance is dispersed phase oil base; The microcapsule suspension comprises, by weight percentage, 5%-40% active component A, 5%-40% active component B, 1%-20% wetting dispersant, 1%-5% capsule material, 0.2%-5% stabilizer, and the balance is dispersed phase oil base; The suspoemulsion comprises, by weight percentage, 5%-40% active component A, 5%-40% active component B, 2%-30% solvent, 1%-30% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is deionized water; The soluble solution comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance being solvent; The seed treatment suspension comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1%-30% of wetting and dispersing agent, 1%-20% of warning color, 0.2%-5% of stabilizer, and the balance is deionized water; The aqueous emulsion comprises, by weight percentage, 5%-40% active component A, 5%-40% active component B, 2%-30% solvent, 1%-30% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is deionized water; The microemulsion comprises, by weight percentage, 5%-40% active component A, 5%-40% active component B, 2%-30% solvent, 1%-30% wetting and dispersing agent, 0.2%-5% stabilizer, and the balance is deionized water; The emulsifiable concentrate comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1%-30% of wetting and dispersing agent, 0.2%-5% of stabilizer, and the balance being solvent; The dry suspension concentrate comprises, by weight percentage, 5%-40% active component A, 5%-40% active component B, 5%-70% wetting and dispersing agent, 0.01%-5% suspending agent, 0.2%-5% stabilizer, and the balance is carrier; The water-dispersible tablet comprises, by weight percentage, 5%-40% active component A, 5%-40% active component B, 1-20% wetting and dispersing agent, 0.01-5% suspending agent, 2-20% tableting aid, 0.2%-5% stabilizer, and the balance is carrier; The soluble granules, by weight percentage, include 5%-40% active component A, 5%-40% active component B, 1-20% wetting and dispersing agent, 0.01-5% suspending agent, 0.2%-5% stabilizer, and the balance is carrier; The soluble powder comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1-20% of wetting and dispersing agent, 0.01-5% of suspending agent, 0.2%-5% of stabilizer, and the balance is carrier; The emulsifiable powder comprises, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1-40% of wetting and dispersing agent, 0.01-5% of suspending agent, 0.2%-5% of stabilizer, and the balance is carrier; The emulsifiable granules include, by weight percentage, 5%-40% of active component A, 5%-40% of active component B, 1-40% of wetting and dispersing agent, 0.01-5% of suspending agent, 0.2%-5% of stabilizer, and the balance is carrier.

9. The use of the pesticide preparation containing piperic acid derivatives according to claim 1, characterized in that: The application of the preparation in the field of agricultural pesticides.

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