Magnesium-based hydrogen storage material based on magnesium dihydride and copper vanadate and method for producing same
CN118419855BActive Publication Date: 2026-08-28CHONGQING UNIV +2
Patent Information
- Application Number
- CN202410670564.X
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-05-28
- Publication Date
- 2026-08-28
- Estimated Expiration
- 2044-05-28
AI Technical Summary
Technical Problem
[0006]Cu3(VO4)2是一种典型的双金属氧化物,目前还没有出现Cu3(VO4)2对镁基储氢材料催化改性的相关研究和报道
Benefits of technology
[0024]本发明的有益效果在于:本发明公开了一种基于二氢化镁和钒酸铜的镁基储氢材料,主要是通过球磨将Cu3(VO4)2粉末包覆在MgH2粉末表面,利用Cu3(VO4)2双金属氧化物对Mg/MgH2体系进行协同催化改性,显著提升了MgH2的吸放氢速率,获得了低温储氢性能优异的复合储氢材料,同时达到了吸氢动力学和吸放氢总量的共同优化改善。相对于单一金属氧化物以及其他形式添加的双金属元素,本发明的镁基储氢材料能够通过引入新相进一步优化提升催化改善效果,为新型镁基复合储氢材料的设计提供了有效策略。本发明提供的镁基储氢材料是为了解决MgH2吸放氢温度高、动力学缓慢等问题,实现中温下的快速吸放氢动力学,即实现在低温条件下(100℃)吸氢,并能在较低的放氢温度下(例如225℃,250℃)具备快速的放氢动力学。
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Abstract
The present application relates to a magnesium-based hydrogen storage material based on magnesium dihydride and copper vanadate and a preparation method thereof, and belongs to the technical field of hydrogen storage material preparation. The present application mainly coats Cu3(VO4)2 powder on the surface of MgH2 powder through ball milling, and uses Cu3(VO4)2 bimetallic oxide to synergistically catalyze and modify the Mg / MgH2 system, significantly improves the hydrogen absorption and desorption rate of MgH2, obtains a composite hydrogen storage material with excellent low-temperature hydrogen storage performance, and simultaneously achieves the common optimization and improvement of hydrogen absorption kinetics and the total amount of hydrogen absorption and desorption. Compared with single metal oxides and other forms of added bimetallic elements, the present application is to solve the problems of high hydrogen absorption and desorption temperature and slow kinetics of MgH2, realize fast hydrogen absorption and desorption kinetics at medium temperature, that is, realize hydrogen absorption at low temperature (100 DEG C), and have fast hydrogen desorption kinetics at a relatively low hydrogen desorption temperature (for example, 225 DEG C, 250 DEG C).
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Citation Information
Patent Citations
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