Glass cat eye spike and preparation method thereof

By using specific raw materials and process treatment, the strength and reflectivity of glass cat eye studs are improved, solving the problem of insufficient strength and reflectivity of traditional products, and is suitable for use in advanced roads.

CN119263625APending Publication Date: 2025-01-07ZIBO ZHIGUO GLASS PROD PROCESSING FACTORY
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Patent Information

Application Number
CN202411526949.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-10-30
Publication Date
2025-01-07

AI Technical Summary

Technical Problem

Traditional glass cat eye lances have problems with poor strength and reflectivity during the manufacturing process, which is difficult to meet the alertness, comfort and safety needs of drivers on higher-level roads.

Method used

Use quartz sand, soda ash, sodium nitrate, calcium powder, borax, cobalt oxide, tin powder and feldspar for stirring and mixing, and then melted at high temperature and pressed into molding, and fire polishing, tempering, electroplating and spraying of external protective layer to enhance the product intensity and reflectivity.

Benefits of technology

It significantly improves the strength and reflectivity of glass cat eye studs, makes up for the shortcomings of the existing technology, improves the performance of the product, and is suitable for use in advanced roads.

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Abstract

The invention relates to a glass cat eye spike and a preparation method thereof, and relates to the technical field of glass cat eye spike preparation, the glass cat eye spike comprises the following raw materials by weight: 95-105 parts of quartz sand, 40-50 parts of soda ash, 12-20 parts of sodium nitrate, 15-25 parts of calcium powder, 20-30 parts of borax, 0.05-0.1 part of cobalt oxide, 0.05-0.1 part of tin powder, 15-20 parts of sodium nitrate, and 12-18 parts of feldspar. According to the glass cat eye spike provided by the invention, through the processes of mixing and melting the materials, pressing and forming, cooling, tempering and electroplating, spraying an outer protective layer and the like, the product strength and reflectance of the glass cat eye spike are remarkably improved, and the defects in the prior art are overcome.
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Description

Technical Field

[0001] The invention relates to the technical field of glass cat's eye road stud preparation, in particular to a glass cat's eye road stud and a preparation method thereof. Background Art

[0002] Road studs, also known as road studs, road signs, markings, reflective road studs, etc., are mainly used to distinguish lanes and provide warning functions, so that drivers can identify the scope, characteristics and direction of the road in a more comfortable situation. In the absence of road studs, the marking paint used to separate the roads will be covered with dust, dim lights or rain, and it will be difficult for drivers to distinguish the scope, characteristics and direction, which may cause confusion and fatigue, and even cause traffic accidents. Therefore, on higher-level roads, protruding road studs are usually installed to improve the driver's alertness, comfort and safety.

[0003] There are many types of road studs, which can be roughly divided into three categories: three-dimensional right-angle corner conic mirror retroreflection method, circular lens directional retroreflection method, and cat's eye lens omnidirectional retroreflection method. The materials of the reflective sheets and bases used are metal, ceramic, plastic and composite materials. Among them, the cat's eye lens omnidirectional retroreflective tempered glass road stud is composed of a glass body and a metal-coated reflective layer (coated around the disc and bottom surface of the lower half of the body). It has a 360-degree focusing and reflection effect, and can provide reflection functions in all directions. This is a unique feature that other road studs do not have. In addition, since the cat's eye road stud does not use plastic materials, it is only composed of a glass body and a metal-coated reflective layer, both of which are environmentally friendly materials, so it has environmental advantages. However, there are some challenges in the manufacturing process of traditional glass cat's eye road studs. For example, existing glass cat's eye road stud products have problems such as poor strength and reflectivity. Summary of the invention

[0004] In order to solve the above problems, the present invention provides a glass cat's eye road stud and a preparation method thereof.

[0005] In a first aspect, the present invention provides a glass cat's eye road stud, wherein the glass cat's eye road stud comprises the following raw materials in parts by weight:

[0006] 95-105 parts of quartz sand, 40-50 parts of soda ash, 12-20 parts of sodium nitrate, 15-25 parts of calcium powder, 20-30 parts of borax, 0.05-0.1 parts of cobalt oxide, 0.05-0.1 parts of tin powder, 15-20 parts of sodium nitrate, and 12-18 parts of feldspar.

[0007] Furthermore, the glass cat's eye road stud comprises the following raw materials in parts by weight:

[0008] 100 parts of quartz sand, 45 parts of soda ash, 16 parts of sodium nitrate, 20 parts of calcium powder, 25 parts of borax, 0.07 parts of cobalt oxide, 0.07 parts of tin powder, 16 parts of sodium nitrate, and 15 parts of feldspar. In a second aspect, the present invention provides a method for preparing the glass cat-eye road stud as described in any one of the first aspects, the preparation method comprising the following steps:

[0009] Stirring and mixing the raw materials in the glass cat-eye road stud to obtain a mixture;

[0010] Melting the mixture at high temperature to obtain molten glass;

[0011] The glass liquid is injected into a mold for compression molding to obtain a product intermediate;

[0012] The product intermediate is subjected to fire polishing and cooling to obtain a semi-finished glass cat-eye road stud;

[0013] The semi-finished glass cat-eye road stud is tempered, electroplated and sprayed with an outer protective layer to obtain the glass cat-eye road stud.

[0014] Furthermore, the working condition parameters of the high-temperature melting include: a temperature of 1450 to 1550° C. and a time of 45 to 50 hours.

[0015] Furthermore, the working condition parameters of the press forming include: using a 50-ton press for stamping.

[0016] Furthermore, the cooling working condition parameters include: the cooling time is 5 to 7 hours, and the temperature is cooled from 650 degrees to room temperature along with the furnace.

[0017] Furthermore, the tempering working condition parameters include: the tempering furnace temperature is 700-750° C., and the tempering time is 25-40 minutes.

[0018] Furthermore, the working condition parameters of the electroplating include: using electroplating wire, the electroplating temperature is 115-130° C., and the electroplating time is 25-40 minutes.

[0019] Furthermore, the working condition parameters of spraying the outer protective layer include: spraying the metal mixture by air pressure spraying, and then baking, the baking temperature is 220-225°C, and the baking time is 1-2 hours; the metal mixture is composed of aluminum powder, alcohol, epoxy resin and curing agent, the weight ratio of the aluminum powder, the alcohol, the epoxy resin and the curing agent is 10:1:40:1, and the curing agent is diethylenetriamine.

[0020] The above technical solution provided by the embodiment of the present invention has at least the following advantages compared with the prior art:

[0021] The embodiment of the present invention provides a glass cat's eye road stud and a preparation method thereof. The present invention provides a glass cat's eye road stud, which significantly improves the strength and reflectivity of the product through processes such as mixing and melting the above materials, pressing and molding, cooling, tempering, electroplating, and spraying an outer protective layer, thereby making up for the shortcomings of the prior art. DETAILED DESCRIPTION

[0022] In order to make the purpose, technical solution and advantages of the embodiments of the present invention clearer, the technical solution in the embodiments of the present invention will be clearly and completely described below. Obviously, the described embodiments are part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0023] Unless otherwise specified, various raw materials, reagents, instruments and equipment used in the present invention can be purchased from the market or prepared by existing methods.

[0024] In a first aspect, the present invention provides a glass cat's eye road stud, wherein the glass cat's eye road stud comprises the following raw materials in parts by weight:

[0025] 95-105 parts of quartz sand, 40-50 parts of soda ash, 12-20 parts of sodium nitrate, 15-25 parts of calcium powder, 20-30 parts of borax, 0.05-0.1 parts of cobalt oxide, 0.05-0.1 parts of tin powder, 15-20 parts of sodium nitrate, and 12-18 parts of feldspar.

[0026] The present invention provides a glass cat-eye road stud, which significantly improves the strength and reflectivity of the product through processes such as mixing and melting the above materials, pressing and molding, cooling, tempering, electroplating, and spraying an outer protective layer, thereby making up for the shortcomings of the prior art.

[0027] In some specific embodiments, the glass cat's eye road stud comprises the following raw materials in parts by weight:

[0028] 100 parts of quartz sand, 45 parts of soda ash, 16 parts of sodium nitrate, 20 parts of calcium powder, 25 parts of borax, 0.07 parts of cobalt oxide, 0.07 parts of tin powder, 16 parts of sodium nitrate, and 15 parts of feldspar.

[0029] In a second aspect, based on the same inventive concept, the present invention provides a method for preparing the glass cat-eye road stud as described in any one of the first aspects, the preparation method comprising the following steps:

[0030] Stirring and mixing the raw materials in the glass cat-eye road stud to obtain a mixture;

[0031] Melting the mixture at high temperature to obtain molten glass;

[0032] The glass liquid is injected into a mold for compression molding to obtain a product intermediate;

[0033] The product intermediate is subjected to fire polishing and cooling to obtain a semi-finished glass cat-eye road stud;

[0034] The semi-finished glass cat-eye road stud is tempered, electroplated and sprayed with an outer protective layer to obtain the glass cat-eye road stud.

[0035] In some specific embodiments, the working condition parameters of the high temperature melting include: a temperature of 1450-1550° C. and a time of 45-50 hours.

[0036] In some specific embodiments, the working condition parameters of the press forming include: using a 50-ton press for stamping.

[0037] In some specific embodiments, the cooling working condition parameters include: the cooling time is 5 to 7 hours, and the temperature is cooled from 650 degrees to room temperature in the furnace.

[0038] In some specific embodiments, the tempering working condition parameters include: the tempering furnace temperature is 700-750° C., and the tempering time is 25-40 minutes.

[0039] In some specific embodiments, the working condition parameters of the electroplating include: using electroplating wire, the electroplating temperature is 115-130° C., and the electroplating time is 25-40 minutes.

[0040] In some specific embodiments, the working condition parameters of spraying the outer protective layer include: spraying the metal mixture by air pressure spraying, and then baking, the baking temperature is 220-225°C, and the baking time is 1-2 hours; the metal mixture is composed of aluminum powder, alcohol, epoxy resin and curing agent, the weight ratio of the aluminum powder, the alcohol, the epoxy resin and the curing agent is 10:1:40:1, and the curing agent is diethylenetriamine.

[0041] It should be noted that the components and raw materials involved in the glass cat's eye road stud and the preparation method thereof provided in the embodiments of the present invention, unless otherwise specified or specified, can be directly commercially available products or homemade using existing public preparation methods; at the same time, the steps and parameters involved, unless otherwise specified or specified, can be carried out according to the existing processing technology of glass cat's eye road studs or directly using existing equipment, and the present invention document will not elaborate on them one by one.

[0042] The present invention will be further described below in conjunction with specific examples. It should be understood that these examples are intended only to illustrate the present invention and are not intended to limit the scope of the present invention. The experimental methods in the following examples that do not specify specific conditions are usually measured according to national standards. If there is no corresponding national standard, then the conditions recommended by the manufacturer are followed.

[0043] Example 1

[0044] This example provides a glass cat's eye road spike, which includes the following raw materials in parts by weight:

[0045] 100 parts of quartz sand, 45 parts of soda ash, 16 parts of sodium nitrate, 20 parts of calcium powder, 25 parts of borax, 0.07 parts of cobalt oxide, 0.07 parts of tin powder, 16 parts of sodium nitrate, and 15 parts of feldspar.

[0046] The preparation method of the above-mentioned glass cat's eye road stud comprises the following steps:

[0047] Stirring and mixing the raw materials in the glass cat-eye road stud to obtain a mixture;

[0048] The mixed material is melted at a high temperature of 1500° C. for 48 hours to obtain glass liquid;

[0049] The glass liquid is injected into a mold for pressing and forming, and a 50-ton press is used for stamping. The stamped product intermediate is then fire-polished and then put into a cooling furnace for 6 hours, and the temperature is gradually cooled from 650° C. to room temperature to obtain a semi-finished glass cat-eye road stud;

[0050] The semi-finished glass cat's eye road stud is tempered at a tempering furnace temperature of 720 degrees for 30 minutes, cooled for 30 minutes, and then electroplated with electroplating wire at a temperature of 120 degrees for 30 minutes. The electroplating is vacuum, and an outer protective layer is sprayed after the electroplating is completed. The protective layer is a metal mixture. The metal mixture is composed of aluminum powder, alcohol, epoxy resin and curing agent. The weight ratio of the aluminum powder, the alcohol, the epoxy resin and the curing agent is 10:1:40:1. The curing agent is diethylenetriamine. After air pressure spray painting, it is baked at a temperature of 220 degrees for 1.5 hours to obtain the glass cat's eye road stud.

[0051] The strength of the glass cat-eye road stud obtained in this example is 50 tons and the reflectivity is 53.

[0052] Various embodiments of the present invention may be presented in the form of a range; it should be understood that the description in the form of a range is only for convenience and brevity, and should not be understood as a rigid limitation on the scope of the present invention; therefore, the range description should be considered to have specifically disclosed all possible sub-ranges and single numerical values ​​within the range. For example, the range description from 1 to 6 should be considered to have specifically disclosed sub-ranges, such as from 1 to 3, from 1 to 4, from 1 to 5, from 2 to 4, from 2 to 6, from 3 to 6, etc., as well as single numbers within the range, such as 1, 2, 3, 4, 5 and 6, which apply regardless of the range. In addition, whenever a numerical range is indicated herein, it is meant to include any cited number (fractional or integer) within the indicated range.

[0053] The foregoing is merely a specific embodiment of the present invention, which enables those skilled in the art to understand or implement the present invention. Various modifications to these embodiments will be apparent to those skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the present invention. Therefore, the present invention will not be limited to the embodiments shown herein, but rather to the widest scope consistent with the principles and novel features claimed herein.

Claims

1. A glass cat-eye road stud, characterized in that: The glass cat's eye road stud comprises the following raw materials in parts by weight: 95-105 parts of quartz sand, 40-50 parts of soda ash, 12-20 parts of sodium nitrate, 15-25 parts of calcium powder, 20-30 parts of borax, 0.05-0.1 parts of cobalt oxide, 0.05-0.1 parts of tin powder, 15-20 parts of sodium nitrate, and 12-18 parts of feldspar.

2. The glass cat-eye road stud according to claim 1, characterized in that: The glass cat's eye road stud comprises the following raw materials in parts by weight: 100 parts of quartz sand, 45 parts of soda ash, 16 parts of sodium nitrate, 20 parts of calcium powder, 25 parts of borax, 0.07 parts of cobalt oxide, 0.07 parts of tin powder, 16 parts of sodium nitrate, and 15 parts of feldspar.

3. A method for preparing the glass cat-eye road stud according to any one of claims 1 to 2, characterized in that: The preparation method comprises the following steps: Stirring and mixing the raw materials in the glass cat-eye road stud to obtain a mixture; Melting the mixture at high temperature to obtain molten glass; The glass liquid is injected into a mold for compression molding to obtain a product intermediate; The product intermediate is subjected to fire polishing and cooling to obtain a semi-finished glass cat-eye road stud; The semi-finished glass cat-eye road stud is tempered, electroplated and sprayed with an outer protective layer to obtain the glass cat-eye road stud.

4. The method for preparing the glass cat-eye road stud according to claim 3, characterized in that: The working condition parameters of the high temperature melting include: a temperature of 1450 to 1550° C. and a time of 45 to 50 hours.

5. The method for preparing the glass cat-eye road stud according to claim 3, characterized in that: The working condition parameters of the compression molding include: using a 50-ton press for stamping.

6. The method for preparing the glass cat-eye road stud according to claim 3, characterized in that: The working condition parameters of the cooling include: the cooling time is 5 to 7 hours, and the temperature is cooled from 650 degrees to room temperature along with the furnace.

7. The method for preparing the glass cat-eye road stud according to claim 3, characterized in that: The working condition parameters of the tempering include: the tempering furnace temperature is 700-750° C., and the tempering time is 25-40 minutes.

8. The method for preparing the glass cat-eye road stud according to claim 3, characterized in that: The working condition parameters of the electroplating include: using electroplating wire, the electroplating temperature is 115-130° C., and the electroplating time is 25-40 minutes.

9. The method for preparing the glass cat-eye road stud according to claim 3, characterized in that: The working condition parameters for spraying the outer protective layer include: spraying the metal mixture by air pressure spraying, and then baking, the baking temperature is 220-225°C, and the baking time is 1-2 hours; the metal mixture is composed of aluminum powder, alcohol, epoxy resin and curing agent, the weight ratio of the aluminum powder, the alcohol, the epoxy resin and the curing agent is 10:1:40:1, and the curing agent is diethylenetriamine.