Cylindrical honeycomb carrier and catalytic body
By setting up a reinforcement area, including a thickening area and a special-shaped compartment area, within the cross section of the cylindrical honeycomb carrier, the deformation or damage of the compartment caused by external force impact and heating is solved, and the strength and compressive resistance of the carrier are improved.
Patent Information
- Application Number
- CN202411710445.9
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2024-11-26
- Publication Date
- 2025-03-04
AI Technical Summary
When the cylindrical straight-through honeycomb carrier is impacted by external forces, the radial component of the external force may cause the square compartment to be deformed or damaged when passing through the right angle vertex angle, and the internal expansion stress caused by the rapid heating speed will also cause the compartment to be damaged.
A cylindrical honeycomb carrier is designed, with a reinforcement area and a non-reinforcement area in its cross section. The reinforcement area is located on the periphery, including a thickening area and a special-shaped compartment area. The wall thickness of the compartment in the thickening area is greater than that of the non-reinforcement area. The special-shaped compartment area has chamfers and inner convex parts, and the thickening area and the special-shaped compartment area are separated by a non-reinforcement area.
Through the design of the thickening zone and the special-shaped compartment zone, the overall strength and compressive resistance of the honeycomb carrier are improved, the influence of radial forces is reduced, the square compartment is prevented from deformation or damage, and the thermal stress is buffered during heating to prevent the compartment from being damaged.
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Figure CN119549201A_ABST
Abstract
Description
Technical Field
[0001] The invention relates to the technical field of honeycomb ceramic carriers, and in particular to a cylindrical honeycomb carrier and a catalytic body. Background Art
[0002] In the prior art, a straight-through honeycomb carrier with a wide range of applications is in the shape of a cylinder. The compartments of the cylindrical straight-through honeycomb carrier generally have a square cross-sectional shape, and the square compartments are arranged in a checkerboard pattern in the cylindrical straight-through honeycomb carrier. However, in these square compartments, when the outer wall of the carrier is impacted by external force, one of the outward-facing vertices in a group of diagonals whose diagonal direction is perpendicular or nearly perpendicular to the outer circumferential surface of the cylindrical carrier can be regarded as consisting of two components when the external force is transmitted inside the carrier: a "radial force" pointing to the inside of the carrier along the radial direction and a "circumferential force" along the circumferential direction of the cross section. Among them, the radial force is often a stronger component. When the radial force passes through the vertices, the right-angled vertices may cause deformation or even damage to the square compartment when bearing the radial force. Therefore, the right-angled vertices in this orientation become the weak link of the cylindrical straight-through carrier in the shape of a square compartment; when the diagonal direction of the right-angled vertices completely coincides with the radial direction of the cross section, the defect of the above-mentioned weak area is more obvious; therefore, the short-board effect leads to a reduction in the strength and pressure-bearing capacity of the entire cylindrical straight-through honeycomb carrier. In addition, the cracking at a forty-five-degree angle on the cross section of the honeycomb carrier, that is, the cracking in the diagonal direction, is not only affected by external forces. When the heating speed itself is too fast, the stress of the expansion of the honeycomb carrier will also be loaded onto the compartment walls in the form of radial force.
[0003] Therefore, when the cylindrical straight-through honeycomb carrier is impacted by external force and the external force is transmitted inside the carrier, especially when the radial component of the external force passes through the outward right-angled vertices, the square compartments may be deformed or even damaged. The internal expansion stress generated by the rapid heating of the honeycomb carrier may affect the compartment walls and cause damage. These problems have become urgent issues to be solved in this field. Summary of the invention
[0004] The purpose of the present invention is to provide a cylindrical honeycomb carrier and catalyst to solve the problem that when the cylindrical straight-through honeycomb carrier is impacted by external force, the external force is transmitted inside the carrier, especially the radial component of the external force passes through the outward right-angled vertices, which may cause the square compartments to deform or even break.
[0005] To achieve the above object, the present invention provides the following technical solutions:
[0006] A cylindrical honeycomb carrier, wherein a reinforced area and a non-reinforced area are distributed in the cross section of the honeycomb carrier;
[0007] Wherein, the reinforcement area is located at a peripheral position within the cross section of the honeycomb carrier;
[0008] The number of the reinforcement areas is at least two;
[0009] The reinforced area includes a thickened area, and the wall thickness of the cells in the thickened area is greater than the wall thickness of the cells in the non-reinforced area.
[0010] In some embodiments of the present invention, along the radial direction of the cross section of the honeycomb carrier, from the center of the cross section of the honeycomb carrier to the outer peripheral surface of the honeycomb carrier, the wall thickness of the compartments in the thickened area gradually increases.
[0011] In some embodiments of the present invention, the at least two reinforcement areas are centrally symmetric about the center of the honeycomb carrier.
[0012] In some embodiments of the present invention, a diagonal wall is provided in the partial square compartment, and the diagonal wall is arranged along the radial direction, or the diagonal wall is arranged perpendicular to the radial direction.
[0013] In some embodiments of the present invention, the reinforcement area further includes a special-shaped compartment area;
[0014] The cross-sectional shape of the cells in the special-shaped cell area has chamfers and / or inward protrusions.
[0015] In some embodiments of the present invention, the inner convex portion has a shape of an inner convex right angle, an inner convex rounded corner or an inner convex flower corner, and the inner convex right angle, inner convex rounded corner or inner convex flower corner are all configured to protrude toward the interior of the compartment where it is located.
[0016] In some embodiments of the present invention, the thickened area is arranged at the periphery of the special-shaped compartment area, and / or the special-shaped compartment area is arranged at the periphery of the thickened area.
[0017] In some embodiments of the present invention, the thickened area and the special-shaped compartment area are separated by the non-reinforced area.
[0018] In some embodiments of the present invention, the number of the reinforcement areas is four, and each reinforcement area has one thickening area and a special-shaped compartment area surrounding the thickening area;
[0019] Each of the thickened areas has a partial square compartment, and each of the special-shaped compartment areas is respectively arranged around the periphery of the thickened area corresponding thereto.
[0020] In some embodiments of the present invention, the cross-sectional shape of each reinforcement area is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 50° to 80°, and the ratio of the radial dimension of the fan-shaped ring in the cross-sectional area of the honeycomb carrier to the radius of the cross-sectional area of the honeycomb carrier is (0.2 to 0.35):1;
[0021] And / or, the cross-sectional shape of each of the thickened zones is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 20° to 40°, and the ratio of the radial dimension of the fan-shaped ring in the cross-section of the honeycomb carrier to the radius of the cross-section of the honeycomb carrier is (0.05 to 0.15):1.
[0022] In some embodiments of the present invention, each reinforcement zone is provided with a thickening zone and a special-shaped compartment zone surrounding the thickening zone, the reinforcement zone is radially symmetrical with respect to the cross-section of the carrier, the thickening zone is radially symmetrical with respect to the cross-section of the carrier, and the special-shaped compartment zone is radially symmetrical with respect to the cross-section of the carrier.
[0023] In some embodiments of the present invention, the reinforcement zone has a reference line, which coincides with a diagonal line of several square compartments and coincides with the radial direction of the cross section of the carrier. The reinforcement zone is symmetrical about the reference line, the thickening zone is symmetrical about the reference line, and the special-shaped compartment zone is symmetrical about the reference line.
[0024] In some embodiments of the present invention, the number of the reinforcement areas is four, and each reinforcement area has one thickening area and a special-shaped compartment area surrounding the thickening area;
[0025] Each of the thickened areas has a partial square compartment, and each of the special-shaped compartment areas is respectively arranged around the periphery of the thickened area corresponding thereto.
[0026] In some embodiments of the present invention, the cross-sectional shape of each reinforcement area is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 50° to 80°, and the ratio of the radial dimension of the fan-shaped ring in the cross-sectional area of the honeycomb carrier to the radius of the cross-sectional area of the honeycomb carrier is (0.2 to 0.35):1;
[0027] And / or, the cross-sectional shape of each of the thickened zones is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 20° to 40°, and the ratio of the radial dimension of the fan-shaped ring in the cross-section of the honeycomb carrier to the radius of the cross-section of the honeycomb carrier is (0.05 to 0.15):1.
[0028] In some embodiments of the present invention, each reinforcement zone is provided with a thickening zone and a special-shaped compartment zone surrounding the thickening zone, the reinforcement zone is radially symmetrical with respect to the cross-section of the carrier, the thickening zone is radially symmetrical with respect to the cross-section of the carrier, and the special-shaped compartment zone is radially symmetrical with respect to the cross-section of the carrier.
[0029] In some embodiments of the present invention, the reinforcement zone has a reference line, which coincides with a diagonal line of several square compartments and coincides with the radial direction of the cross section of the carrier. The reinforcement zone is symmetrical about the reference line, the thickening zone is symmetrical about the reference line, and the special-shaped compartment zone is symmetrical about the reference line.
[0030] In order to achieve the above object, the present invention also provides the following technical solutions:
[0031] A catalyst body, comprising:
[0032] The cellular carrier described above; and
[0033] A catalyst is coated on the wall surface of the cells of the honeycomb carrier.
[0034]
[0006] Areas of applicability will become apparent from the description provided in the present disclosure.
[0035] The description and specific examples in this summary are intended for purposes of illustration only and are not intended to limit the scope of the present disclosure.
[0036] Compared with the prior art, the technical solution provided by the present invention has the following beneficial effects:
[0037] The present invention provides a cylindrical honeycomb carrier and a catalyst body, wherein the cross section of the honeycomb carrier is provided with a reinforcement zone and a non-reinforcement zone; wherein the reinforcement zone is located at the peripheral position in the cross section of the honeycomb carrier; the number of the reinforcement zones is at least two; the reinforcement zone includes a thickening zone, and the wall thickness of the compartment in the thickening zone is greater than the wall thickness of the compartment in the non-reinforcement zone. The present invention solves the problem that when a cylindrical straight-through honeycomb carrier is impacted by an external force, the external force is transmitted inside the carrier, especially when the radial component of the external force passes through the right-angled apex facing outward, which may cause the square compartment to deform or even break, thereby improving the overall strength of the cylindrical straight-through honeycomb carrier with square compartments arranged in a checkerboard form. In addition, the cracking at a forty-five-degree angle on the cross section of the honeycomb carrier, that is, the cracking in the diagonal direction, is not only affected by the external force, but when the self-heating speed is too fast, the stress of the expansion of the honeycomb carrier will also be loaded on the compartment wall in the form of radial force. The technical solution provided by the present invention can also solve the problem that "the internal thermal stress generated by the excessively fast heating speed may cause damage to the compartment walls". BRIEF DESCRIPTION OF THE DRAWINGS
[0038] In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings required for use in the description of the embodiments will be briefly introduced below. Obviously, the drawings described below are only some implementation plans of the present invention. For those skilled in the art, other drawings can be obtained based on these drawings without paying any creative work.
[0039] Figure 1 A schematic structural diagram of a cross section of a honeycomb carrier provided in a first embodiment of the present invention;
[0040] Figure 2 for Figure 1 A local enlarged schematic diagram in FIG.
[0041] Figure 3 for Figure 1 Schematic diagram of the overall structure of the honeycomb carrier;
[0042] Figure 4 A schematic structural diagram of a cross section of a honeycomb carrier provided in a second embodiment of the present invention;
[0043] Figure 5 for Figure 4 A local enlarged schematic diagram in FIG.
[0044] Figure 6 for Figure 4 Schematic diagram of the overall structure of the honeycomb carrier;
[0045] Figure 7 A schematic structural diagram of a cross section of a honeycomb carrier provided in a third embodiment of the present invention;
[0046] Figure 8 for Figure 7 A local enlarged schematic diagram in FIG.
[0047] Fig. 9 for Figure 7 Schematic diagram of the overall structure of the honeycomb carrier;
[0048] Fig.10 A schematic structural diagram of a cross section of a honeycomb carrier provided in a fourth embodiment of the present invention;
[0049] Fig.11 for Fig.10 A local enlarged schematic diagram in FIG.
[0050] Fig.12 for Fig.10 Schematic diagram of the overall structure of the honeycomb carrier;
[0051] Fig.13 A schematic structural diagram of a cross section of a honeycomb carrier provided in a fifth embodiment of the present invention;
[0052] Fig.14 for Fig.13 A local enlarged schematic diagram in FIG.
[0053] Fig.15 for Fig.13 Schematic diagram of the overall structure of the honeycomb carrier;
[0054] Fig.16 It is a structural schematic diagram of a cross section of a honeycomb carrier in the prior art;
[0055] Fig.17 It is a schematic structural diagram of the cross section of another honeycomb carrier in the prior art.
[0056] Reference numerals
[0057] 1-thickening area; 2-special-shaped compartment area; 3-non-reinforced area; P-reference line. DETAILED DESCRIPTION
[0058] The technical solutions in the embodiments of the present invention are described clearly and completely below. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments in the present invention, all other embodiments obtained by those skilled in the art without creative work belong to the scope of protection of the present invention. It should be understood that the specific embodiments described herein are only used to illustrate and explain the present invention, and are not used to limit the present invention.
[0059] It should be noted that the "reinforced area" in the specification of the present invention refers to the area where the strength enhancement design is made for the compartment strength, and the "non-reinforced area" refers to the area where the strength enhancement design is not made for the compartment strength.
[0060] In addition, the "square compartment" in the present specification specifically includes a compartment with a square cross-section and a compartment with a rectangular cross-section.
[0061] First aspect
[0062] See also Figure 1 , Figure 4 , Figure 7 , Fig.10 , Fig.13 The present invention provides a cylindrical honeycomb carrier, wherein a reinforcement area and a non-reinforcement area 3 are distributed in the cross section of the honeycomb carrier; wherein the reinforcement area is located at the peripheral position in the cross section of the honeycomb carrier; the number of the reinforcement areas is at least two; the reinforcement area includes a thickening area 1, and the wall thickness of the compartment in the thickening area 1 is greater than the wall thickness of the compartment in the non-reinforcement area 3. It is worth noting that thickening the wall thickness in the crack-prone area improves the strength of the square format, helps to reduce the influence of radial force, and reduces the deformation or even damage of the square compartment.
[0063] As mentioned in the previous background technology, in a square compartment, one of the outward-facing vertices in a group of diagonals whose diagonal direction is perpendicular or nearly perpendicular to the outer circumferential surface of the cylindrical carrier, when the outer wall of the carrier is impacted by external force, the force can be regarded as consisting of two components when it is transmitted inside the carrier, namely, a "radial force" pointing to the inside of the carrier along the radial direction and a "circumferential force" along the circumferential direction of the cross section. Among them, in most application scenarios, the radial force is often a stronger component. When the radial force passes through the vertices, the right-angled vertices may cause the square compartment to deform or even break when bearing the radial force. Therefore, the right-angled vertices in this position become the weak link of the cylindrical straight-through carrier in the shape of a square compartment; wherein, when the diagonal direction of the right-angled vertices completely coincides with the radial direction of the cross section, the defects of the above-mentioned weak area are more obvious; therefore, the short-board effect leads to a reduction in the strength and pressure-bearing capacity of the entire cylindrical straight-through honeycomb carrier. Therefore, the present invention proposes the above solution, by setting a reinforcement zone and thickening the partition wall thickness of the compartment in the reinforcement zone, thereby enhancing the compressive strength and impact resistance of the partition wall and the compartment. In addition, on the cross section of the honeycomb carrier, the 45-degree cracking, that is, the diagonal cracking, is not only affected by external forces. When the heating speed of the honeycomb carrier is too fast, the stress of the expansion of the honeycomb carrier will also be loaded on the partition wall in the form of radial force. The above technical solution provided by the present invention can also solve the problem that "the internal thermal stress generated by the excessively fast heating speed will cause damage to the partition wall".
[0064] It is worth noting that the above-mentioned thickened partition wall concept provided by the present invention can be applied not only to the scenario of "cylindrical carrier + square compartment", but also to other carriers that are also designed as square or rectangular compartments but have other three-dimensional shapes, such as honeycomb carriers with elliptical cross-sections or various polyhedral prisms such as triangular prisms, quadrangular prisms, pentagonal prisms, hexagonal prisms, and octagonal prisms; because when these honeycomb carriers are designed to have square or rectangular compartments, the right-angled vertices in the compartments that are opposite to the center of the carrier cross section and facing the outer surface of the carrier will also directly face the radial component with greater force that is impacted by external forces. In other words, the inventive concept of thickening the compartment wall provided by the present invention has good versatility.
[0065] In some embodiments of the present invention, the wall thickness of the compartment in the thickened area 1 is 1.5 to 2.8 times the wall thickness of the compartment in the non-reinforced area 3, and can be any one of 1.6, 1.7, 1.8, 1.9, 2, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7 times, or any value within a range of values consisting of any two values, which can be selected and adjusted according to actual application scenarios and design standards. Figure 1 , Figure 4 , Figure 7 , Fig.10 , Fig.13 In some embodiments of the present invention, along the radial direction of the cross section of the honeycomb carrier, from the center of the cross section of the honeycomb carrier to the outer peripheral surface of the honeycomb carrier, the wall thickness of the compartment in the thickening zone 1 gradually increases. It is worth noting that in these embodiments, the average thickness of the wall thickness of the compartment in the thickening zone 1 is 1.5 to 2.8 times the wall thickness of the compartment in the non-reinforced zone 3, and can be any one of 1.6, 1.7, 1.8, 1.9, 2, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7 times or any value in the range of values composed of any two values, which can be selected and adjusted according to the actual application scenario and design standards; or, in these embodiments, the minimum thickness of the wall thickness of the compartment in the thickening zone 1 is at least 1.5 times the wall thickness of the compartment in the non-reinforced zone 3, and the maximum thickness is at most 2.8 times the wall thickness of the compartment in the non-reinforced zone 3. It is worth noting that thicker wall thickness will lead to higher stress between the thickened area 1 and the non-reinforced area 3. When internal stress is generated by external force or thermal expansion, the honeycomb ceramic is more likely to break at the junction of the thickened area 1 and the non-reinforced area 3, while thinner wall thickness will lead to insufficient support and easy breakage.
[0066] See also Figure 1 , Figure 4 , Figure 7 , Fig.10 , Fig.13 In some embodiments of the present invention, the at least two reinforcement areas are centrally symmetrical about the center of the honeycomb carrier. This makes it more convenient to make a mold and can completely include the crack-prone area.
[0067] In some embodiments of the present invention, the cells of the thickened region 1 include square cells, and some of the square cells are arranged in a manner that the diagonal lines coincide with the radial lines of the honeycomb carrier.
[0068] In some embodiments of the present invention, a diagonal wall is provided in the partial square compartment, and the diagonal wall is arranged along the radial direction. It is worth noting that the diagonal wall structure is equivalent to isolating a square compartment into two triangular compartments. Since the triangle has good structural stability and pressure bearing capacity, this solution can further improve the impact resistance and pressure bearing resistance of the honeycomb carrier.
[0069] See also Figure 1 , Figure 4 , Figure 7 , Fig.10 , Fig.13 In some embodiments of the present invention, the reinforcement area further includes a special-shaped compartment area 2; the cross-sectional shape of the compartment in the special-shaped compartment area 2 has a chamfer and / or an inner convex portion.
[0070] See also Figure 4-Figure 5 , Figure 7-Figure 8 , Figure 10-11 , Figure 13-14 In some embodiments of the present invention, the shape of the inner convex portion is an inner convex right angle, an inner convex rounded corner or an inner convex flower angle, and the inner convex right angle, inner convex rounded corner or inner convex flower angle are all configured to protrude inward relative to the interior of the compartment in which it is located.
[0071] See also Figures 10 to 15 In some embodiments of the present invention, the thickened area 1 is arranged around the periphery of the special-shaped compartment area 2.
[0072] See also Figures 4 to 9 In some embodiments of the present invention, the special-shaped compartment area 2 is arranged around the periphery of the thickened area 1.
[0073] In some embodiments of the present invention, the thickened area 1 and the special-shaped compartment area 2 are separated by the non-reinforced area 3 .
[0074] See also Figure 4 and Figure 7 In some embodiments of the present invention, the number of the reinforcement zones is four, each of which has a thickening zone 1 and a special-shaped compartment zone 2 surrounding the thickening zone 1; each thickening zone 1 has a partial square compartment, and each special-shaped compartment zone 2 is respectively surrounded by the corresponding thickening zone 1. The existence of the special-shaped compartment zone further transitions, and when the special-shaped transition zone is between the thickening zone and the ordinary compartment, it can buffer the stress between the thermal expansion of the two, making the honeycomb ceramic structure more stable.
[0075] See also Figure 4 and Figure 7 In some embodiments of the present invention, the cross-sectional shape of each reinforcement area is a fan ring, the central angle of the fan ring ranges from 50° to 80°, and the ratio of the radial dimension of the fan ring in the cross section of the honeycomb carrier to the radius of the cross section of the honeycomb carrier is (0.2-0.35): 1. The smaller fan ring area controls its angle and ring radius, so that the opening rate of the honeycomb ceramic end face changes less and the back pressure increase is smaller.
[0076] See also Figure 4 and Figure 7 In some embodiments of the present invention, the cross-sectional shape of each of the thickened areas 1 is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 20° to 40°, and the ratio of the radial dimension of the fan-shaped ring in the cross-section of the honeycomb carrier to the radius of the cross-section of the honeycomb carrier is (0.05 to 0.15):1.
[0077] See also Figure 4and Figure 7 In some embodiments of the present invention, each reinforcement zone is provided with a thickening zone 1 and a special-shaped compartment zone 2 surrounding the thickening zone 1, the reinforcement zone is radially symmetrical with respect to the cross-section of the carrier, the thickening zone is radially symmetrical with respect to the cross-section of the carrier, and the special-shaped compartment zone is radially symmetrical with respect to the cross-section of the carrier.
[0078] See also Figure 4 and Figure 7 In some embodiments of the present invention, the reinforcement zone has a reference line P, which coincides with a diagonal line of several square compartments and coincides with the radial direction of the cross section of the carrier. The reinforcement zone is symmetrical about the reference line P, the thickening zone is symmetrical about the reference line P, and the special-shaped compartment zone is symmetrical about the reference line P.
[0079] See also Fig.10 and Fig.13 In some embodiments of the present invention, the number of the reinforcement zones is four, each of the reinforcement zones has one of the special-shaped compartment zones 2 and a thickening zone 1 surrounding the periphery of the special-shaped compartment zone 2; each of the special-shaped compartment zones 2 has the partial square compartment, and each of the thickening zones 1 is respectively surrounded by the periphery of the special-shaped compartment zone 2 corresponding thereto.
[0080] See also Fig.10 and Fig.13 In some embodiments of the present invention, the cross-sectional shape of each reinforcement zone is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 50° to 80°, and the ratio of the radial dimension of the fan-shaped ring in the cross-section of the honeycomb carrier to the radius of the cross-section of the honeycomb carrier is (0.2 to 0.35):1.
[0081] See also Fig.10 and Fig.13 In some embodiments of the present invention, the cross-sectional shape of each of the special-shaped compartment areas 2 is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 20° to 40°, and the ratio of the radial dimension of the fan-shaped ring in the cross-section of the honeycomb carrier to the radius of the cross-section of the honeycomb carrier is (0.05 to 0.15):1.
[0082] See also Fig.10 and Fig.13 In some embodiments of the present invention, each reinforcement zone is provided with a thickening zone and a special-shaped compartment zone 2 surrounding the thickening zone, the reinforcement zone is radially symmetrical with respect to the cross-section of the carrier, the thickening zone is radially symmetrical with respect to the cross-section of the carrier, and the special-shaped compartment zone is radially symmetrical with respect to the cross-section of the carrier.
[0083] See also Fig.10 and Fig.13In some embodiments of the present invention, the reinforcement zone has a reference line P, which coincides with a diagonal line of several square compartments and coincides with the radial direction of the cross section of the carrier. The reinforcement zone is symmetrical about the reference line P, the thickening zone is symmetrical about the reference line P, and the special-shaped compartment zone is symmetrical about the reference line P.
[0084] See also Figures 1 to 3 The present invention provides a honeycomb carrier, the compartments of the honeycomb carrier are square, and a reinforcement area and a non-reinforcement area 3 are provided in the cross section of the carrier. The square compartments in the non-reinforcement area 3 can be regarded as conventional square compartments in the prior art, while the compartments in the reinforcement area adopt a wall thickening design, that is, the carrier provided in this embodiment is provided with a thickening area 1, and the wall thickness of the compartments in the thickening area 1 is greater than the wall thickness of the compartments in the non-reinforcement area 3, and the specific thickening multiple can be any value in the range of 1.5 to 2.8 times. The number of thickening areas 1 of the carrier provided in this embodiment is four, and the four thickening areas 1 are centrally symmetrically distributed about the center of the cross section of the cylindrical carrier, and the four thickening areas 1 are located in the peripheral area of the carrier cross section; and the four thickening areas 1 just include the "square compartments whose diagonal direction coincides or nearly coincides with the radial direction of the carrier cross section", because the compressive strength of the compartments in this distribution mode is relatively the most fragile, so the carrier provided by this embodiment of the present invention can enhance the compressive resistance of these compartments, thereby improving the overall compressive resistance of the carrier. It is worth mentioning that the concept of the reinforcement area provided by the present invention can be regarded as "at least two 'reinforcement ribs' or 'strengthening ribs' are set along the longitudinal direction of the cylindrical carrier" to "reinforce and strengthen" the pressure-bearing weak area of the carrier. Furthermore, the central angle of the thickening area 1 in the form of a fan ring is 30°, and the length ratio of the radial dimension of the fan ring to the radius of the carrier cross section is 0.15:1; the mesh number specification of the compartment density is 750 mesh.
[0085] See again Figures 1 to 3 The present invention also provides a honeycomb carrier, which, based on the aforementioned design concept of only the thickening zone 1, further integrates the concept of "gradual wall thickness design", that is: while setting the thickening zone 1, the wall thickness of the compartment in the thickening zone 1 is gradually thickened from the center of the carrier cross section to the outer wall of the carrier along the radial direction of the carrier cross section; at this time, the average wall thickness in each thickening zone 1 (the sum of the thickness of the thickest and thinnest parts of the wall thickness in the thickening zone 1 divided by two) can be any value between 1.5 and 2.8 times the wall thickness of the compartment in the non-reinforced zone 3; of course, the thickness at the thinnest part can also be at least 1.5 times the wall thickness of the compartment in the non-reinforced zone 3, and the thickness at the thickest part can be at most 2.8 times the wall thickness of the compartment in the non-reinforced zone 3.
[0086] See also Figures 4 to 6The present invention provides a honeycomb carrier, wherein the cross section of the carrier is distributed with two types of reinforcement areas, namely, a thickening area 1 and a special-shaped compartment area 2, wherein one set of diagonals in the compartment within the special-shaped compartment area 2 is chamfered, and the other set of diagonals in the same compartment is kept at right angles; in this scheme, there are a total of four thickening areas 1 and four special-shaped compartment areas 2, and each special-shaped compartment area 2 is respectively arranged around the periphery of a thickening area 1; this scheme is equivalent to integrating the two reinforcement concepts and applying them to the same honeycomb carrier to further enhance the strength of the honeycomb carrier. Furthermore, the central angle of the thickening area 1 in the form of a fan ring is 30°, and the length ratio of the radial dimension of the fan ring to the radius of the carrier cross section is 0.15:1; the mesh number specification of the compartment density is 750 meshes.
[0087] See also Figures 7 to 9 The present invention provides a honeycomb carrier, wherein the cross section of the carrier is distributed with two types of reinforcement areas, namely, a thickening area 1 and a special-shaped compartment area 2, wherein one set of diagonals in the compartment within the special-shaped compartment area 2 is an inward convex fillet, and the other set of diagonals in the same compartment is a right angle; in this scheme, there are a total of four thickening areas 1 and four special-shaped compartment areas 2, and each special-shaped compartment area 2 is respectively arranged around the periphery of a thickening area 1; this scheme is equivalent to integrating the two reinforcement concepts and applying them to the same honeycomb carrier to further enhance the strength of the honeycomb carrier. Furthermore, the central angle of the thickening area 1 in the form of a fan ring is 30°, and the length ratio of the radial dimension of the fan ring to the radius of the carrier cross section is 0.15:1; the mesh number specification of the compartment density is 750 meshes.
[0088] See also Figures 10 to 12 The present invention provides a honeycomb carrier, wherein the cross section of the carrier is distributed with two types of reinforcement areas, namely, a thickening area 1 and a special-shaped compartment area 2, wherein one set of diagonal angles in the compartment within the special-shaped compartment area 2 is chamfered, and the other set of diagonal angles in the same compartment is retained as a right angle; in this scheme, there are a total of four thickening areas 1 and four special-shaped compartment areas 2, and each thickening area 1 is respectively arranged around the periphery of a special-shaped compartment area 2; this scheme is equivalent to integrating the two reinforcement concepts and applying them to the same honeycomb carrier to further enhance the strength of the honeycomb carrier. Furthermore, the central angle of the thickening area 1 in the form of a fan ring is 30°, and the length ratio of the radial dimension of the fan ring to the radius of the carrier cross section is 0.15:1; the mesh number specification of the compartment density is 750 meshes.
[0089] See also Figures 13 to 15The present invention provides a honeycomb carrier, wherein the cross section of the carrier is distributed with two types of reinforcement areas, namely, a thickening area 1 and a special-shaped compartment area 2, wherein one set of diagonals in the compartment within the special-shaped compartment area 2 is an inward convex fillet, and the other set of diagonals in the same compartment is a right angle; in this scheme, there are a total of four thickening areas 1 and four special-shaped compartment areas 2, and each thickening area 1 is respectively arranged around the periphery of a special-shaped compartment area 2; this scheme is equivalent to integrating the two reinforcement concepts and applying them to the same honeycomb carrier to further enhance the strength of the honeycomb carrier. Furthermore, the central angle of the thickening area 1 in the form of a fan ring is 30°, and the length ratio of the radial dimension of the fan ring to the radius of the carrier cross section is 0.15:1; the mesh number specification of the compartment density is 750 meshes.
[0090] See also Fig.16 The present invention shows a honeycomb carrier of the prior art, which is also cylindrical and has square compartments arranged in a checkerboard pattern. However, the thickening area 1 of the carrier is arranged in a full circle outside the cross section of the carrier, and the ratio of the radial dimension of the annular area to the radius of the cross section of the carrier is 0.15:1, and the mesh number specification of the cell density is 750 meshes. In this honeycomb carrier of the prior art, there is no "thickness transition zone" between the thickening area 1 and the non-reinforced area 3, so the stress on the partition wall will have a sudden change, and the sudden change in wall thickness in the structure will make the extrusion speed uneven during the processing. During extrusion molding, the processing mold needs to be adjusted several times to successfully extrude the rough blank of the entire carrier; in addition, the area of the thickening area 1 of this honeycomb carrier accounts for a large proportion, but the area that actually needs to be reinforced is not so large, so there will be a certain degree of waste of raw materials.
[0091] See also Fig.17 The present invention shows a honeycomb carrier of the prior art, which is also cylindrical in shape and has square compartments arranged in a checkerboard pattern. However, the thickening area 1 of the carrier is of fan-shaped design. The fan-shaped thickening area 1 extends from the outer wall of the carrier to the central area of the carrier cross section. The central angle of the fan-shaped area is 30°, and the mesh number specification of the compartment density is 750 mesh. This kind of honeycomb carrier of the prior art does not have a "thickness transition zone" between the thickening area 1 and the non-reinforced area 3, so the stress on the partition wall will have a sudden change, and the sudden change in wall thickness in the structure will lead to uneven extrusion speed during processing. Conventional means cannot be used to adjust the extrusion speed between the compartments of the thickening area 1 and the compartments of the non-reinforced area 3 to be the same during the extrusion molding process; in addition, compared with Figures 1 to 3 Compared with the honeycomb carrier shown and provided by the present invention, the thickened region 1 of the honeycomb carrier of the prior art has a larger area proportion, but the area actually requiring reinforcement is not so large, so there will be a certain degree of waste of raw materials.
[0092] It is worth noting that the honeycomb carrier provided by the present invention may be made of ceramic or other materials such as metal, and no sole limitation is made on the material.
[0093] Example 1
[0094] 39.2% of flaky talc, 13.4% of flaky raw kaolin, 29.4% of calcined kaolin, 1% of silicon oxide, and 16.4% of aluminum oxide were put into a plow mixer and dry mixed for 15 minutes at a rotation speed of 95 rpm. After the dry mixing, 2% of the inorganic raw materials were added with lubricant, 8% of the binder, and 35% of water were wet mixed for 5 minutes at a rotation speed of 95 rpm. After wet mixing, the clay was kneaded and then extruded through a mold. The extrusion pressure was 12 MPa, the extrusion speed of the clay was 1 m / min, the pore density of the extruded body was 600 cpsi, the finished product had a diameter of 118.4 mm, and a length of 138 mm. After forming, it was cut, dried at 50°C, and then fired at 1400-1500°C and kept warm for 8 hours. After cooling, the finished honeycomb carrier was obtained.
[0095] See also Figures 1 to 3 The honeycomb carrier provided in this embodiment has four reinforcement areas, each of which has a thickening area 1 and a special-shaped compartment area 2 surrounded by the thickening area 1, wherein the compartments of the special-shaped compartment area 2 have chamfers in a flat-cut shape, and the wall thickness of the compartments in the thickening area 1 gradually thickens from the inside to the outside along the radial direction of the carrier cross section.
[0096] For further information, see Figures 1 to 3 In the honeycomb carrier provided in this embodiment, the projection shape of a single reinforcement area on the cross section of the carrier is a fan-shaped ring, the central angle of the fan-shaped ring is 60°, and the ratio of the radial dimension of the fan-shaped ring to the radius of the cross section of the carrier is 0.35:1; the projection shape of the thickening zone 1 on the cross section of the carrier is a fan-shaped ring, the central angle of the fan-shaped ring is 30°, and the ratio of the radial dimension of the fan-shaped ring to the radius of the cross section of the carrier is 0.15:1.
[0097] For further information, see Figures 1 to 3 In the honeycomb carrier provided in this embodiment, the average wall thickness of the compartment in the thickened zone 1 is 2.3 times the wall thickness of the compartment in the non-reinforced zone 3, the wall thickness of the compartment farthest from the carrier cross section in the thickened zone 1 is 3 times the wall thickness of the compartment in the non-reinforced zone 3, and the wall thickness of the compartment closest to the carrier cross section in the thickened zone 1 is 1.8 times the wall thickness of the compartment in the non-reinforced zone 3.
[0098] Example 2
[0099] 25.6% of flaky talc, 20% of flaky raw kaolin, 29.4% of calcined kaolin, 10% of silicon oxide, and 15% of aluminum oxide were put into a plow mixer for dry mixing for 15 minutes at a rotation speed of 95 rpm. After dry mixing, 5% of the inorganic raw materials were added with lubricant, 8% of the binder, and 35% of water for wet mixing for 5 minutes at a rotation speed of 95 rpm. After wet mixing, the clay was kneaded and then extruded through a mold. The extrusion pressure was 11.5 MPa, the extrusion speed of the clay was 1 m / min, the pore density of the extruded body was 750 cpsi, the finished product had a diameter of 132.1 mm, and a length of 138 mm. After forming, it was cut, dried at 50°C, and then fired at 1400-1500°C and kept warm for 8 hours. After cooling, the finished honeycomb carrier was obtained.
[0100] See also Figures 4 to 6 The honeycomb carrier provided in this embodiment has four reinforcement areas, each of which has a thickening area 1 and a special-shaped compartment area 2 surrounded by the thickening area 1, wherein the compartments of the special-shaped compartment area 2 have rounded inner convex corners, and the wall thickness of the compartments in the thickening area 1 gradually thickens from the inside to the outside along the radial direction of the carrier cross section.
[0101] For further information, see Figures 4 to 6 In the honeycomb carrier provided in this embodiment, the projection shape of a single reinforcement area on the cross section of the carrier is a fan-shaped ring, the central angle of the fan-shaped ring is 60°, and the ratio of the radial dimension of the fan-shaped ring to the radius of the cross section of the carrier is 0.35:1; the projection shape of the thickening zone 1 on the cross section of the carrier is a fan-shaped ring, the central angle of the fan-shaped ring is 30°, and the ratio of the radial dimension of the fan-shaped ring to the radius of the cross section of the carrier is 0.15:1.
[0102] For further information, see Figures 4 to 6 In the honeycomb carrier provided in this embodiment, the average wall thickness of the compartment in the thickened zone 1 is 2.3 times the wall thickness of the compartment in the non-reinforced zone 3, the wall thickness of the compartment farthest from the carrier cross section in the thickened zone 1 is 3 times the wall thickness of the compartment in the non-reinforced zone 3, and the wall thickness of the compartment closest to the carrier cross section in the thickened zone 1 is 1.8 times the wall thickness of the compartment in the non-reinforced zone 3.
[0103] Example 3
[0104] 50% of flaky talc, 10% of flaky raw kaolin, 15% of calcined kaolin, 5% of silicon oxide, and 20% of aluminum oxide were put into a plow mixer for dry mixing for 15 minutes at a rotation speed of 95 rpm. After dry mixing, 5% of the inorganic raw materials were added with lubricant, 10% of the binder, and 35% of water for wet mixing for 5 minutes at a rotation speed of 95 rpm. After wet mixing, the clay was kneaded and then extruded through a mold. The extrusion pressure was 12.1 MPa, the extrusion speed of the clay was 1 m / min, the pore density of the extruded body was 800 cpsi, the finished product had a diameter of 132.1 mm, and a length of 138 mm. After forming, it was cut, dried at 50°C, and then fired at 1400-1500°C and kept warm for 8 hours. After cooling, the finished honeycomb carrier was obtained.
[0105] See also Figures 7 to 9 The honeycomb carrier provided in this embodiment has four reinforcement areas, each of which has a special-shaped compartment area 2 and a thickening area 1 surrounding the special-shaped compartment area 2, wherein the compartments of the special-shaped compartment area 2 have chamfers in a flat-cut shape, and the wall thickness of the compartments in the thickening area 1 gradually thickens from the inside to the outside along the radial direction of the carrier cross section.
[0106] For further information, see Figures 7 to 9 In the honeycomb carrier provided in this embodiment, the projection shape of a single reinforcement area on the cross section of the carrier is a fan-shaped ring, the central angle of the fan-shaped ring is 60°, and the ratio of the radial dimension of the fan-shaped ring to the radius of the cross section of the carrier is 0.35:1; the projection shape of the special-shaped compartment area 2 on the cross section of the carrier is a fan-shaped ring, the central angle of the fan-shaped ring is 30°, and the ratio of the radial dimension of the fan-shaped ring to the radius of the cross section of the carrier is 0.15:1.
[0107] For further information, see Figures 7 to 9 In the honeycomb carrier provided in this embodiment, the average wall thickness of the compartment in the thickened zone 1 is 2.3 times the wall thickness of the compartment in the non-reinforced zone 3, the wall thickness of the compartment farthest from the carrier cross section in the thickened zone 1 is 3 times the wall thickness of the compartment in the non-reinforced zone 3, and the wall thickness of the compartment closest to the carrier cross section in the thickened zone 1 is 1.8 times the wall thickness of the compartment in the non-reinforced zone 3.
[0108] Example 4
[0109] 35.1% of flaky talc, 16.8% of flaky raw kaolin, 30.1% of calcined kaolin, 3.5% of silicon oxide, and 13.5% of aluminum oxide were put into a plow mixer and dry mixed for 15 minutes at a rotation speed of 95 rpm. After the dry mixing, 4% of the inorganic raw materials were added with lubricant, 7% of the binder, and 35% of water were wet mixed for 5 minutes at a rotation speed of 95 rpm. After wet mixing, the clay was kneaded and then extruded through a mold. The extrusion pressure was 11 MPa, the extrusion speed of the clay was 1 m / min, the pore density of the extruded body was 900 cpsi, the finished product had a diameter of 105.7 mm, and a length of 138 mm. After forming, it was cut, dried at 50°C, and then fired at 1400-1500°C and kept warm for 8 hours. After cooling, the finished honeycomb carrier was obtained.
[0110] See also Figures 10 to 12 The honeycomb carrier provided in this embodiment has four reinforcement areas, each of which has a special-shaped compartment area 2 and a thickening area 1 surrounding the special-shaped compartment area 2, wherein the compartments of the special-shaped compartment area 2 have rounded inner convex corners, and the wall thickness of the compartments in the thickening area 1 gradually thickens from the inside to the outside along the radial direction of the carrier cross section.
[0111] For further information, see Figures 10 to 12 In the honeycomb carrier provided in this embodiment, the projection shape of a single reinforcement area on the cross section of the carrier is a fan-shaped ring, the central angle of the fan-shaped ring is 60°, and the ratio of the radial dimension of the fan-shaped ring to the radius of the cross section of the carrier is 0.35:1; the projection shape of the special-shaped compartment area 2 on the cross section of the carrier is a fan-shaped ring, the central angle of the fan-shaped ring is 30°, and the ratio of the radial dimension of the fan-shaped ring to the radius of the cross section of the carrier is 0.15:1.
[0112] For further information, see Figures 10 to 12 In the honeycomb carrier provided in this embodiment, the average wall thickness of the compartment in the thickened zone 1 is 2.3 times the wall thickness of the compartment in the non-reinforced zone 3, the wall thickness of the compartment farthest from the carrier cross section in the thickened zone 1 is 3 times the wall thickness of the compartment in the non-reinforced zone 3, and the wall thickness of the compartment closest to the carrier cross section in the thickened zone 1 is 1.8 times the wall thickness of the compartment in the non-reinforced zone 3.
[0113] Example 5
[0114] 45% of flaky talc, 12.1% of flaky raw kaolin, 20.4% of calcined kaolin, 4.5% of silicon oxide, and 17.5% of aluminum oxide were put into a plow mixer for dry mixing for 15 minutes at a rotation speed of 95 rpm. After dry mixing, 5% of the inorganic raw materials were added with lubricant, 3% of binder, and 35% of water for wet mixing for 5 minutes at a rotation speed of 95 rpm. After wet mixing, the clay was kneaded and then extruded through a mold. The extrusion pressure was 10.9 MPa, the extrusion speed of the clay was 1 m / min, the pore density of the extruded body was 1200 cpsi, the finished product had a diameter of 101.6.1 mm, and a length of 138 mm. After forming, it was cut, dried at 50°C, and then fired at 1400-1500°C and kept warm for 8 hours. After cooling, the finished honeycomb carrier was obtained.
[0115] See also Figures 13 to 15 The honeycomb carrier provided in this embodiment has four reinforcement areas, each of which contains only a thickening area 1, and the wall thickness of the compartments in the thickening area 1 gradually increases from the inside to the outside along the radial direction of the carrier cross section.
[0116] For further information, see Figures 13 to 15 In the honeycomb carrier provided in this embodiment, the projection shape of a single reinforcement area on the carrier cross section is a fan-shaped ring, the central angle of the fan-shaped ring is 60°, and the ratio of the radial dimension of the fan-shaped ring to the radius of the carrier cross section is 0.35:1.
[0117] For further information, see Figures 13 to 15 In the honeycomb carrier provided in this embodiment, the average wall thickness of the compartment in the thickened zone 1 is 2.3 times the wall thickness of the compartment in the non-reinforced zone 3, the wall thickness of the compartment farthest from the carrier cross section in the thickened zone 1 is 3 times the wall thickness of the compartment in the non-reinforced zone 3, and the wall thickness of the compartment closest to the carrier cross section in the thickened zone 1 is 1.8 times the wall thickness of the compartment in the non-reinforced zone 3.
[0118] Comparative Example 1
[0119] 45% of flaky talc, 12.1% of flaky raw kaolin, 20.4% of calcined kaolin, 4.5% of silicon oxide, and 17.5% of aluminum oxide were put into a plow mixer and dry mixed for 15 minutes at a rotation speed of 95 rpm. After the dry mixing, 5% of the inorganic raw materials were added with lubricant, 3% of binder, and 35% of water for wet mixing for 5 minutes at a rotation speed of 95 rpm. After wet mixing, the clay was kneaded and then extruded through a mold. The extrusion pressure was 15 MPa, the extrusion speed of the clay was 1 m / min, the pore density of the extruded body was 600 cpsi, the finished product had a diameter of 118.4 mm, and a length of 138 mm. After forming, it was cut, dried at 50°C, and then fired at 1400-1500°C and kept warm for 8 hours. After cooling, the finished honeycomb carrier was obtained.
[0120] See also Fig.16 The honeycomb carrier provided in this embodiment has a reinforcement area which is only a thickened area 1 with thickened wall thickness. The distribution shape of the thickened area 1 is a full circle of circular ring outside the carrier cross section, and the wall thickness of the compartments in the thickened area 1 is uniform without a gradual transition design.
[0121] For further information, see Fig.16 In the honeycomb carrier provided in this embodiment, the ratio of the radial dimension of the thickened area 1 to the cross-sectional radius of the carrier is 0.15:1.
[0122] Comparative Example 2
[0123] 35.1% of flaky talc, 16.8% of flaky raw kaolin, 30.1% of calcined kaolin, 3.5% of silicon oxide, and 13.5% of aluminum oxide were put into a plow mixer and dry mixed for 15 minutes at a rotation speed of 95rpm. After dry mixing, 4% of the inorganic raw materials were added with lubricant, 7% of the binder, and 35% of water were wet mixed for 5 minutes at a rotation speed of 95rpm. After wet mixing, the clay was kneaded and then extruded through a mold. The extrusion pressure was 14.5MPa, the extrusion speed of the clay was 1m / min, the pore density of the extruded body was 750cpsi, the finished product had a diameter of 118.4mm, and a length of 138mm. After forming, it was cut, dried at 50℃, and then fired at 1400-1500℃ and kept warm for 8h. After cooling, the finished honeycomb carrier was obtained.
[0124] See also Fig.17 The honeycomb carrier provided in this embodiment has four reinforcement areas, each reinforcement area only contains a thickening area 1 with a wall thickening design, and the wall thickness of the compartments in the thickening area 1 is uniform without a gradual transition design.
[0125] For further information, see Fig.17 In the honeycomb carrier provided in this embodiment, the central angle of each thickened area 1 is 30°.
[0126] The yields in the following Table 1 refer to the statistics of the product yields of Examples 1 to 5 and Comparative Examples 1 to 2 under the same raw material ratio, extrusion pressure, extrusion speed, drying speed, sintering temperature and other conditions.
[0127] Table 1 Performance data of honeycomb carriers obtained in various embodiments and comparative examples
[0128]
[0129]
[0130] It can be seen from the data listed in Table 1 that, compared with Examples 1 and 2 and Examples 3 and 4, the thermal shock resistance of the product with chamfered wall thickness structure is 50°C higher; the A-axis compressive strength of the A-axis is increased by 1MPa; the isostatic pressure is increased by 2MPa; the transition structure of the special-shaped compartment area is conducive to the uniform distribution of the pressure of the molding mud on the mold, and the yield rate is about 5% higher.
[0131] Example 5 uses a full-circle wall thickness gradual reinforcement structure and no chamfered transition area, the thermal shock of the product is reduced, the pressure distribution of the molding mud on the mold is uneven, and the yield rate is about 7% lower than that of Examples 1 and 2.
[0132] Compared with Example 5, Comparative Example 1 has no gradual structure and the pressure unevenness is more obvious, resulting in a further decrease in the yield rate.
[0133] Comparative Example 2 has no gradual change in wall thickness and no transition area compared to Example 1, and its thermal shock resistance, compressive strength of A and B axes, and isostatic pressure are significantly reduced.
[0134] Second aspect
[0135] The present invention provides a catalytic body, which comprises: the honeycomb carrier mentioned above; and a catalyst coated on the wall surface of the compartment of the honeycomb carrier.
[0136] In some embodiments of the present invention, the catalytic body can be used to treat automobile exhaust gas, and the specific type and amount of the catalyst carried by the catalytic body can be selected and adjusted according to the actual application scenario or design standard.
[0137] Further areas of applicability will become apparent from the description provided in the present disclosure.
[0138] The above is only a specific implementation of the present invention, but the protection scope of the present invention is not limited thereto. Any technician familiar with the technical field can easily think of changes or substitutions within the technical scope disclosed by the present invention, which should be covered within the protection scope of the present invention. Therefore, the protection scope of the present invention shall be based on the protection scope of the claims. In addition, the specification uses specific examples to illustrate the principles and implementation methods of the present invention. The description of the above embodiments is only used to help understand the method of the present invention and its core idea. The content of this specification should not be understood as a limitation on the present invention.
Claims
1. A cylindrical honeycomb carrier, characterized in that: The cross section of the honeycomb carrier is provided with a reinforcement area and a non-reinforcement area; Wherein, the reinforcement area is located at a peripheral position within the cross section of the honeycomb carrier; The number of the reinforcement areas is at least two; The reinforced area includes a thickened area, and the wall thickness of the cells in the thickened area is greater than the wall thickness of the cells in the non-reinforced area.
2. The honeycomb carrier according to claim 1, characterized in that: Along the radial direction of the cross section of the honeycomb carrier, from the center of the cross section of the honeycomb carrier to the outer peripheral surface of the honeycomb carrier, the wall thickness of the compartments in the thickened area gradually increases.
3. The honeycomb carrier according to claim 1, characterized in that: The at least two reinforcement areas are centrally symmetrical about the center of the honeycomb carrier.
4. The honeycomb carrier according to claim 1, characterized in that: A diagonal wall is provided in the partial square compartment, and the diagonal wall is arranged along the radial direction, or the diagonal wall is arranged perpendicular to the radial direction.
5. The honeycomb carrier according to any one of claims 1 to 4, characterized in that: The reinforcement area also includes a special-shaped compartment area; The cross-sectional shape of the cells in the special-shaped cell area has chamfers and / or inward protrusions.
6. The honeycomb carrier according to claim 5, characterized in that: The shape of the inner convex portion is an inner convex right angle, an inner convex rounded corner or an inner convex flower corner, and the inner convex right angle, inner convex rounded corner or inner convex flower corner are all configured to protrude toward the inside of the compartment where the inner convex portion is located.
7. The honeycomb carrier according to claim 5, characterized in that: The thickened area is arranged at the periphery of the special-shaped compartment area, and / or the special-shaped compartment area is arranged at the periphery of the thickened area.
8. The honeycomb carrier according to claim 5, characterized in that: The thickened area and the special-shaped compartment area are separated by the non-reinforced area.
9. The honeycomb carrier according to claim 5, characterized in that: There are four reinforcement areas, each of which has one thickening area and a special-shaped compartment area surrounding the thickening area; Each of the thickened areas has a partial square compartment, and each of the special-shaped compartment areas is respectively arranged around the periphery of the thickened area corresponding thereto.
10. The honeycomb carrier according to claim 9, characterized in that: The cross-sectional shape of each reinforcement zone is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 50° to 80°, and the ratio of the radial dimension of the fan-shaped ring in the cross-sectional area of the honeycomb carrier to the radius of the cross-sectional area of the honeycomb carrier is (0.2 to 0.35):1; And / or, the cross-sectional shape of each of the thickened zones is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 20° to 40°, and the ratio of the radial dimension of the fan-shaped ring in the cross-section of the honeycomb carrier to the radius of the cross-section of the honeycomb carrier is (0.05 to 0.15):
1.
11. The honeycomb carrier according to claim 9, characterized in that: Each reinforcement zone is provided with a thickened zone and a shaped compartment zone surrounding the thickened zone. The reinforcement zone is radially symmetrical about the cross section of the carrier, the thickened zone is radially symmetrical about the cross section of the carrier, and the shaped compartment zone is radially symmetrical about the cross section of the carrier.
12. The honeycomb carrier according to claim 9, characterized in that: The reinforcement area has a reference line, which coincides with a diagonal line of several square compartments and the radial direction of the cross section of the carrier. The reinforcement area is symmetrical about the reference line, the thickening area is symmetrical about the reference line, and the special-shaped compartment area is symmetrical about the reference line.
13. The honeycomb carrier according to claim 5, characterized in that: There are four reinforcement areas, each of which has one thickening area and a special-shaped compartment area surrounding the thickening area; Each of the thickened areas has a partial square compartment, and each of the special-shaped compartment areas is respectively arranged around the periphery of the thickened area corresponding thereto.
14. The honeycomb carrier according to claim 13, characterized in that: The cross-sectional shape of each reinforcement zone is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 50° to 80°, and the ratio of the radial dimension of the fan-shaped ring in the cross-sectional area of the honeycomb carrier to the radius of the cross-sectional area of the honeycomb carrier is (0.2 to 0.35):1; And / or, the cross-sectional shape of each of the thickened zones is a fan-shaped ring, the central angle of the fan-shaped ring is in the range of 20° to 40°, and the ratio of the radial dimension of the fan-shaped ring in the cross-section of the honeycomb carrier to the radius of the cross-section of the honeycomb carrier is (0.05 to 0.15):
1.
15. The honeycomb carrier according to claim 13, characterized in that: Each reinforcement zone is provided with a thickened zone and a shaped compartment zone surrounding the thickened zone. The reinforcement zone is radially symmetrical about the cross section of the carrier, the thickened zone is radially symmetrical about the cross section of the carrier, and the shaped compartment zone is radially symmetrical about the cross section of the carrier.
16. The honeycomb carrier according to claim 13, characterized in that: The reinforcement area has a reference line, which coincides with a diagonal line of several square compartments and the radial direction of the cross section of the carrier. The reinforcement area is symmetrical about the reference line, the thickening area is symmetrical about the reference line, and the special-shaped compartment area is symmetrical about the reference line.
17. A catalyst, characterized in that: The catalyst body comprises: The cellular carrier according to any one of claims 1 to 16; and A catalyst is coated on the wall surface of the cells of the honeycomb carrier.
Citation Information
Patent Citations
Crack-resistant ceramic honeycomb structures
CN101443291A
Honeycomb structure
CN110496650A
Honeycomb structure and mold
CN111670098A
Honeycomb filter
CN111749758A
Honeycomb ceramic carrier, preparation method thereof and catalytic body containing honeycomb ceramic carrier
CN118976542A