Method for producing pig iron in electric smelting furnace and associated smelting furnace

Abstract

The invention relates to a method for producing pig iron in an electric smelting furnace 13 comprising a container 20, said method comprising the following sequential steps:-loading a DRI product into the container 20,-melting the DRI product to form a pig iron layer 14, the top of which is a slag layer 23, and-directly injecting a desulfurizing agent into the pig iron layer 14. The invention also relates to the production of steel from said pig iron and to a related electric smelting furnace 13.

Description

Technical Field

[0001] The present invention relates to a method of making pig iron (also called hot metal), and to a method of producing steel from such pig iron. Background Art

[0002] Steel can be produced by two main manufacturing routes. Today, the most commonly used production route, known as the "BF-BOF route", involves producing hot metal in a blast furnace by reducing iron oxides using a reducing agent (mainly coke), which is then converted into steel in a converter process or basic oxygen furnace (BOF). This route releases large amounts of CO both when producing coke from coal in a coking plant and when producing hot metal. 2 .

[0003] The second major route involves the so-called "direct reduction process". In these processes, sponge iron is produced in the form of HDRI (hot direct reduced iron), CDRI (cold direct reduced iron) or HBI (hot briquetted iron) by direct reduction of an iron oxide carrier. The sponge iron in the form of HDRI, CDRI and HBI undergoes further processing in an electric furnace to produce steel.

[0004] Therefore, the CO reduction options chosen by steel manufacturers 2 One of the main options for discharge is to switch from the BF-BOF route to the DRI route. However, the use of DRI products with ferrous scrap in a classic electric furnace has some limitations. In fact, the scrap contains a lot of impurities and the resulting steel will need to be further processed to produce high-quality steel grades. Therefore, investments in new steel treatment equipment will be necessary. Summary of the invention

[0005] It is therefore an object of the present invention to remedy the disadvantages of pig iron and steelmaking manufacturing by providing a new way to effectively minimize the environmental impact of such manufacturing routes without incurring large investments.

[0006] This problem is solved by a method for producing pig iron as specified in claim 1 .

[0007] Such a method may also comprise the optional features of claims 2 to 8 considered alone or in any possible technical combination.

[0008] The invention also relates to a method for producing steel according to claim 9 .

[0009] Such a method may further comprise the optional features of claim 10 .

[0010] The invention also relates to an electric smelting furnace as specified in claim 11. BRIEF DESCRIPTION OF THE DRAWINGS

[0011] Other characteristics and advantages of the invention will emerge clearly from the description of the invention, which is given below by way of indication and which is in no way limiting, with reference to the accompanying drawings, in which:

[0012] - Figure 1 shows the pig iron and steel making process according to the smelting / BOF route,

[0013] - Figure 2 shows a melting furnace,

[0014] - Figure 3 An embodiment of the method according to the invention is shown.

[0015] Elements in the drawings are illustrative and may not be drawn to scale. DETAILED DESCRIPTION

[0016] Figure 1 The steel production route according to the DRI route is shown, from the reduction of iron to the casting of steel into semi-finished products, such as slabs, billets, blooms or strips. Iron ore 10 is first reduced in a direct reduction facility 11. The direct reduction facility 11 can be designed to implement any kind of direct reduction technology, such as Technology or The direct reduction process may be, for example, a conventional natural gas-based or biogas-based process.

[0017] In a preferred embodiment, the DRI product used in the process according to the invention is produced using a reducing gas based on biogas from the combustion of biomass.

[0018] Biomass is a renewable organic material from plants and animals. Biomass sources include wood and wood processing waste (e.g., firewood, wood particles and wood chips, wood and furniture factory sawdust and waste), and black liquor from pulp and paper mills, agricultural crops and waste materials (e.g., corn, soybeans, sugar cane, switchgrass, woody plants and algae), and crop and food processing residues, and also include biogenic materials in municipal solid waste (e.g., paper, cotton and wool products), and food, yard and wood waste, animal manure and human filth. In the sense of the present invention, biomass can also encompass plastic residues, such as recycled waste plastics, such as solid refuse fuel (Solid Refuse Fuel) or SRF.

[0019] Whenever natural gas or biogas is used as the reducing gas, the carbon content of the DRI product can be set to a maximum of 3 wt %, and is typically set in the range of 2 wt % to 3 wt %.

[0020] In another preferred embodiment, the DRI product used in the process according to the invention is obtained by so-called H 2 -DRI process production, wherein the reducing gas contains more than 50% by volume, and preferably more than 60%, 70%, 80% or 90% by volume of hydrogen, or even consists entirely of hydrogen. 2 - The DRI product will contain carbon at levels much lower than natural gas or biogas DRI, and thus typically less than 1 wt %, or even lower. In a preferred embodiment, the hydrogen used in the DRI reducing gas is derived from the electrolysis of water, preferably partially or entirely from CO 2 Powered by neutral electricity. CO 2 Neutral electricity specifically includes electricity from renewable sources, which is defined as energy collected from renewable sources that replenish naturally on a human time scale (including sources like sunlight, wind, rain, tides, waves, and geothermal). In some embodiments, the use of electricity from nuclear sources can be used because it does not produce CO 2 emission.

[0021] Regardless of the DRI process used, the resulting direct reduced iron (DRI) product 12 is then charged to a smelting furnace 13 where reduction of the iron oxides is completed and the product is melted to produce pig iron.

[0022] The DRI product may be transferred to the smelting furnace in various forms. Preferably, the direct reduced iron product (DRI product) is fed to the smelting furnace in hot form as a HDRI product (so-called hot DRI), or in cold form as a CDRI product (so-called cold DRI), or in hot briquetted form as a HBI product (so-called hot briquetted iron) and / or in pelletized form (preferably having an average particle size of at most 10.0 mm, more preferably having an average particle size of at most 5.0 mm).

[0023] It is preferably loaded directly at the outlet of the direct reduction facility 11 as a hot product at a temperature of 500 to 700° C. This allows reducing the amount of energy required to melt it. When hot loading is not possible, for example if the direct reduction facility 11 and the smelting furnace 13 are not co-located, or if the smelting furnace 13 is out of operation for maintenance and the DRI product must therefore be stored, the DRI product can be loaded cold or a preheating step can be carried out.

[0024] The smelting furnace 13 utilizes electrical energy provided by a plurality of electrodes to melt the DRI product 12 and produce pig iron 14. In a preferred embodiment, part or all of the required electricity is derived from CO 2 Neutral power. Figure 2 A further detailed description of the smelting furnace is given.

[0025] The pig iron 14 can then be transferred to a converter 17. The converter essentially transforms liquid metal into molten steel by blowing oxygen through the liquid metal to decarburize it. It is often referred to as a basic oxygen furnace (BOF). Iron-containing scrap 18 from steel recovery can also be charged to the converter 17 to utilize the heat released by the exothermic reaction created by injecting oxygen into the pig iron.

[0026] The molten steel 19 thus formed can then be transferred to one or more secondary metallurgical equipment 20A, 20B, such as a ladle furnace, a RH (Ruhrstahl-Heareus) vacuum vessel, a vacuum tank degasser, an alloying and mixing station, etc., to be processed according to the steel grade to be produced to achieve the desired steel composition. The molten steel 21 with the desired composition can then be transferred to a casting facility 22, where it can be transformed into a solid product, such as a slab, billet, bloom or strip.

[0027] like Figure 2 As shown, the smelting furnace 13 is composed of a container 20 capable of containing molten iron. For example, the container 20 can have a circular or rectangular shape. The container 20 is closed by a top, which is provided with some holes to receive electrodes 22 to be inserted into the container 20, and is provided with other holes to allow raw materials to be loaded into the container 20.

[0028] Electrodes 22 provide the electrical energy required to melt the loaded raw materials and form pig iron. They are preferably Type electrode.

[0029] During melting of the raw material, two layers are formed, a layer of pig iron 14 which is the densest and therefore located at the bottom of the vessel 20, and a layer of slag 23 located above the pig iron 14. The slag layer 23 may be partially covered by a pile 24 of raw material waiting to be melted.

[0030] The vessel 20 is also provided with holes called tap holes 25, which are located in the lower part of the vessel 20 and which allow the pig iron 14 to be discharged while keeping most of the slag in the vessel 20. They can be located in the side walls of the vessel or in its bottom wall.

[0031] The smelting furnace 13 may be a SAF (Submerged-Arc Furnace) in which the electrodes are immersed in a slag layer 23, or an OSBF (open-slag bath furnace) in which the electrodes 22 are located above the slag layer 23. It is preferably an OSBF as shown in the drawings.

[0032] In the framework of the present invention, the desulphurizing agent is added to the smelting furnace 13, directly to the pig iron layer 14. This addition can be done by injection means.

[0033] The inventors have indeed observed that reducing conditions in the smelting furnace 13 are conducive to efficient sulphur removal.

[0034] Carrying out the desulfurization in the smelting furnace may allow suppressing the need for a desulfurization treatment between the smelting furnace 13 and the converter 17, or at least reducing such treatment.

[0035] The final sulfur content of the pig iron is preferably set to a maximum of 0.03 weight percent and preferably to a maximum of 0.004 weight percent.

[0036] In a preferred embodiment, the injection means is a lance 26 inserted in at least one tap hole 25 of the container 20. Such lance 26 opens in the pig iron layer 14 to allow direct addition.

[0037] The positioning of the injection lance 26 through the at least one tap hole 25 avoids injecting the desulphurization agent from the top of the smelting furnace 13 where the available space may be insufficient due to the presence of electrodes and loading means for the DRI product.

[0038] In a preferred embodiment, the desulfurizing agent is injected together with a carrier gas to avoid clogging of the injection device. This gas is preferably inert and can consist of nitrogen, argon, helium or carbon monoxide or any mixture of such gases.

[0039] In a preferred embodiment, silicon-containing materials can be injected into the pig iron layer 14 together with the desulfurizing agent. Silicon has a strong deoxidizing ability at high temperatures, and in particular about 1600° C., which is the temperature of molten steel in the converter. It reacts with oxygen and then helps to form slag when the pig iron is converted into molten steel. The reaction is exothermic and thus provides additional energy for the melting of scrap in the converter.

[0040] Such silicon can be added in different forms, such as metallic silicon Si, silicon carbide SiC, silicon manganese SiMn, calcium silicate SiCa or iron silicon alloy FeSi, such as FeSi75 or FeSi65.

[0041] The use of DRI products in the melting furnace 13 will result in an initial amount of silicon generally below 0.2 wt.-% or even below 0.1 wt.-%. The final silicon content of the pig iron is preferably set to a value of 0.1 wt.-% to 0.4 wt.-%, preferably 0.2 wt.-% to 0.4 wt.-%. If necessary, further addition of silicon can be carried out in the converter 17.

[0042] In a preferred embodiment, the carbonaceous material may also be injected along with the desulfurization agent with or without silicon addition.

[0043] The reaction of carbon with oxygen in the converter produces carbon monoxide gas, which provides an intense and efficient stirring of the liquid metal and thus improves the removal of impurities from the steel. The reaction is also exothermic and thus provides additional energy for the scrap melting. The more scrap is used, the smaller the environmental footprint of the process.

[0044] The carbon content of the pig iron 14 produced by the DRI route will generally be less than 3 wt%. However, in order to meet the requirements of the subsequent steelmaking process at the converter, the carbon content of the pig iron should preferably be as close as possible to 4.5 wt%, which is the saturation level. In a preferred embodiment, the carbon content of the pig iron is set in the range of 4.0 wt% to 4.5 wt% by adding carbonaceous materials.

[0045] The carbonaceous material can come from different sources. It can be selected from, for example, coke, anthracite, silicon carbide, calcium carbide or a mixture of any of those sources, but can also advantageously come from a renewable source, such as biomass, for part or all of the carbon load. In particular, biochar can be used. Adding calcium carbide is particularly advantageous because the calcium atoms can provide a desulfurization effect. Adding silicon carbide is also particularly advantageous because it allows the silicon content of the pig iron to be increased.

[0046] The particle size of the carbonaceous material to be injected by the injection device is preferably below 3 mm. In a preferred embodiment, the particle size of the material is less than or equal to 75 μm, and the particle size of the remaining particles is less than or equal to 2 mm.

[0047] In another embodiment, the carbonaceous material may also consist of a composite briquette in which an iron source is mixed with one or several of the aforementioned carbon sources.

[0048] In a preferred embodiment, the iron source may be selected from sludge from an electric furnace, a converter or a smelting furnace, slag from an electric furnace or from a converter, or any iron-rich waste from the steel production route.

[0049] It must be noted that the addition of calcium carbide is particularly advantageous, since carbide addition can also add carbon to the pig iron in addition to desulfurization. Adding a mixture of calcium carbide and silicon carbide is even more advantageous, since it provides carbon and silicon addition while ensuring desulfurization.

Claims

1. A method for producing pig iron in an electric smelting furnace (13) comprising a vessel (20), the method comprising the following sequential steps: - loading the container (20) with a DRI product, - melting the DRI product to form a pig iron layer (14) topped by a slag layer (23), and - Directly injecting desulfurizing agent material into the pig iron layer (14).

2. A method according to claim 1, wherein the smelting furnace (13) includes at least one tap hole (25) arranged on such a container (20), and a lance (26) is inserted through the at least one tap hole (25), and the lance is used as an injection device to directly inject the desulfurization agent into the pig iron layer (14).

3. A method according to claim 1 or 2, wherein the desulfurizing agent is injected in an amount sufficient to achieve a final sulfur content of less than 0.02% by weight in the pig iron layer (14).

4. The method according to any one of claims 1 to 3, wherein the desulfurization agent is injected together with a carrier gas.

5. The method according to any one of claims 1 to 4, wherein the desulfurization agent is selected from sodium carbonate, lime, calcium carbide, magnesium or a mixture of any of those materials.

6. The method according to any one of claims 1 to 5, wherein the injected desulfurization agent has particles with a particle size below 3 mm.

7. The method according to any one of claims 1 to 6, wherein the DRI product is produced using a reducing gas comprising at least 50% by volume of hydrogen before the DRI product is charged into the smelting furnace (13).

8. The method according to any one of claims 1 to 7, wherein silicon-containing material and / or carbon-containing material are added to the desulfurization agent to be injected into the pig iron layer (14).

9. A method for manufacturing steel, wherein the pig iron manufactured according to any one of claims 1 to 8 is transferred from the melting furnace (13) to a converter (17), wherein the carbon content of the pig iron is then reduced to a value below 2.1 weight percent by blowing oxygen to obtain molten steel.

10. The method for manufacturing steel according to claim 9, wherein iron-containing scrap is added to the pig iron in the converter (17) and melted.

11. An electric smelting furnace (13) for producing pig iron (14), the furnace (13) comprising a container (20), the container (20) comprising at least one tapping hole (25) arranged on such container (20), through which a lance (26) is inserted, the lance being designed to inject a desulfurizing agent directly into a pig iron layer (14) contained in the container (20).

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