Eluting and regenerating device for uranium extraction material from seawater
By designing a seawater uranium extraction material elution and regeneration device, and using spacer and concentration treatment technology, the problems of low elution efficiency and large mechanical damage in seawater uranium extraction are solved, and efficient uranium recycling and regeneration are achieved, reducing solution processing volume and environmental impact.
Patent Information
- Application Number
- CN202411760722.7
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2024-12-03
- Publication Date
- 2025-03-18
AI Technical Summary
In the existing seawater uranium extraction technology, the uranium elution efficiency is low, the eluent and regeneration liquid are used, and the mechanical damage to adsorbent materials is great.
A seawater uranium extracting material elution and regeneration device is designed, including an elution and regeneration tank, an eluent collection flow path and a regeneration liquid collection flow path. A spacer is provided in the elution and regeneration tank, and the fiber material is placed in the spacer. The eluent and regeneration liquid are subjected to concentration-dividing treatment through the parallel collection tank to improve the elution and regeneration efficiency.
The mechanical damage to the fiber material is reduced through the spacer design, the utilization rate of eluent and recycled liquid is improved, the uranium recovery and regeneration effect is enhanced, and the solution processing volume and environmental impact are reduced.
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Figure CN119633787A_ABST
Abstract
Description
Technical Field
[0001] The invention relates to the technical field of uranium extraction from seawater, and in particular to a device for eluting and regenerating uranium extraction materials from seawater. Background Art
[0002] As a mature clean energy, nuclear energy has been actively and orderly developed in recent years under the premise of ensuring safety. At the same time, the consumption rate of uranium raw materials used in nuclear energy has also gradually increased.
[0003] It is known that the ocean contains about 4.5 billion tons of uranium resources, which is more than a thousand times the content of uranium mines on land. It has huge development potential, and the impact of uranium extraction from seawater on the ecological environment is much smaller than that of uranium mining on land.
[0004] The key steps of uranium extraction from seawater include: preparation of uranium extraction materials from seawater, adsorption of uranium by uranium extraction materials in seawater, material elution and regeneration, separation and recovery of uranium after elution, and other engineering designs.
[0005] At present, amidoxime-based fibrous seawater uranium extraction materials that have sea trial experience need to be eluted, regenerated and dehydrated after adsorbing uranium in seawater. However, in the traditional scheme, the uranium elution efficiency is low, the amount of eluent and regeneration liquid used is large, and the mechanical damage to the adsorption material is great.
[0006] Based on this, the inventor of the present application proposed a device for eluting and regenerating uranium materials from seawater in order to solve the above technical problems. Summary of the invention
[0007] The technical problem to be solved by the present invention is to overcome the defects of low uranium elution efficiency, large amount of eluent and regeneration liquid used, and great mechanical damage to adsorption materials in the process of uranium extraction from seawater in the prior art, and to provide a seawater uranium extraction material elution and regeneration device.
[0008] The present invention solves the above technical problems through the following technical solutions:
[0009] The present invention provides a device for eluting and regenerating uranium materials from seawater, which is characterized in that it comprises:
[0010] The elution regeneration tank has at least two compartments disposed therein, and the adjacent compartments are interconnected, and the fiber materials after uranium adsorption are respectively placed in the compartments at intervals;
[0011] An eluent collecting flow path, the inlet end and the outlet end of which are respectively connected to the elution regeneration tank, and the eluent collecting flow path is provided with at least two parallel eluent collecting tanks to collect eluents of different concentrations flowing through the spacer;
[0012] The regeneration liquid collecting flow path has an inlet end and an outlet end respectively connected to the elution regeneration tank. The regeneration liquid collecting flow path is provided with at least two parallel regeneration liquid collecting tanks. The regeneration liquid collecting tanks are used to collect regeneration liquids of different concentrations flowing through the interval area for treatment and discharge or return to the elution regeneration tank for reuse.
[0013] According to one embodiment of the present invention, an inlet is provided on the elution regeneration tank, and the eluent or the regeneration liquid enters the elution regeneration tank through the inlet or is discharged from the elution regeneration tank to the outside;
[0014] A plurality of partitions are provided in the elution regeneration tank, and the partitions divide the interior of the elution regeneration tank into a plurality of the partition areas;
[0015] At least one flow hole is formed on the partition.
[0016] According to one embodiment of the present invention, the plurality of partitions are arranged in a honeycomb shape in the elution regeneration tank.
[0017] According to one embodiment of the present invention, the partition is provided with at least two flow holes spaced vertically along the elution regeneration tank.
[0018] According to one embodiment of the present invention, a rotating mechanism is further provided at the bottom of the elution regeneration tank for driving the elution regeneration tank to rotate.
[0019] According to one embodiment of the present invention, the elution regeneration tank is provided with at least one liquid inlet and at least one liquid outlet;
[0020] The liquid inlet and the liquid outlet are arranged on two opposite sides of the elution regeneration tank.
[0021] According to one embodiment of the present invention, one end of the eluent collecting flow path is connected to the liquid outlet and is divided into at least two first branches, each of which is provided with an eluent collecting tank, and a first regulating valve is provided on opposite sides of the eluent collecting tank;
[0022] The other end of the eluent collection flow path is connected to the liquid inlet.
[0023] According to one embodiment of the present invention, the eluent collection flow path is provided with a second regulating valve upstream of the eluent collection tank;
[0024] The eluent collecting flow path is provided with an eluent filter and an eluent pump downstream of the eluent collecting tank, which are used for filtering and conveying the eluent respectively;
[0025] The eluent collecting flow path is further provided with a third regulating valve between the eluent filter and the eluent collecting tank.
[0026] According to one embodiment of the present invention, a uranium recovery flow path is further provided on the eluent collection flow path for collecting eluent with a high uranium content, and a fourth regulating valve is provided on the uranium recovery flow path.
[0027] According to one embodiment of the present invention, one end of the regeneration liquid collection flow path is connected to the liquid outlet and is divided into at least two second branches, each of the second branches is provided with a regeneration liquid collection tank, and a fifth regulating valve is provided on opposite sides of the regeneration liquid collection tank;
[0028] The other end of the regeneration liquid collecting tank is connected to the liquid inlet.
[0029] According to one embodiment of the present invention, the regeneration liquid collection flow path is provided with a sixth regulating valve upstream of the regeneration liquid collection tank;
[0030] The regeneration liquid collecting flow path is provided with a regeneration liquid filter and a regeneration liquid pump downstream of the regeneration liquid collecting tank, which are used for filtering and conveying the regeneration liquid respectively.
[0031] According to one embodiment of the present invention, the regeneration liquid collection flow path is also provided with a discharge flow path for discharging low-concentration regeneration liquid;
[0032] A seventh regulating valve is provided on the discharge flow path.
[0033] The positive and progressive effects of the present invention are:
[0034] The uranium material elution and regeneration device for extracting uranium from seawater of the present invention has a separation zone in the elution and regeneration tank, and the fiber materials adsorbing uranium are respectively arranged in the separation zone for separation, thereby avoiding the fiber materials from being disturbed during the elution, regeneration and dehydration processes, and reducing the mechanical damage to the fiber materials.
[0035] At least two parallel eluent collecting tanks are arranged on the eluent collecting flow path. The eluent can be processed according to concentration. The part with the highest uranium concentration can directly enter the uranium recovery section, while the eluent with a lower uranium concentration can be reused to improve the elution efficiency of the eluent and reduce the solution processing volume of the uranium recovery section.
[0036] At least two parallel regeneration liquid collection tanks are arranged on the regeneration liquid collection flow path. The regeneration liquid can be treated according to concentration. The regeneration liquid with low concentration can be discharged after being treated to meet the standards, and the regeneration liquid with higher concentration can be returned to the elution regeneration tank for reuse, thereby improving the utilization rate of the regeneration liquid while ensuring the regeneration effect. BRIEF DESCRIPTION OF THE DRAWINGS
[0037] The above and other features, properties and advantages of the present invention will become more apparent through the following description in conjunction with the accompanying drawings and embodiments, in which:
[0038] Figure 1 This is a schematic diagram of the structure of the device for eluting and regenerating uranium from seawater according to the present invention;
[0039] Figure 2 It is a structural schematic diagram of the elution regeneration tank of the present invention;
[0040] Figure 3 It is a top view of the elution regeneration tank of the present invention.
[0041] 1. elution regeneration tank; 11. spacing zone; 111. partition; 112. flow hole; 12. liquid inlet; 13. liquid outlet; 14. rotating mechanism; 15. inlet;
[0042] 2. eluent collection flow path; 21. eluent collection tank; 22. first branch; 221. first regulating valve; 23. second regulating valve; 24. eluent filter; 25. eluent pump; 26. third regulating valve; 27. uranium recovery flow path; 271. fourth regulating valve;
[0043] 3. Regeneration liquid collecting flow path; 31. Regeneration liquid collecting tank; 32. Second branch; 321. Fifth regulating valve; 33. Sixth regulating valve; 34. Regeneration liquid filter; 35. Regeneration liquid pump; 36. Discharge flow path; 361. Seventh regulating valve. DETAILED DESCRIPTION
[0044] The present invention is further described below in conjunction with specific embodiments and drawings. More details are elaborated in the following description to facilitate a full understanding of the present invention. However, the present invention can obviously be implemented in a variety of other ways different from the description herein. Those skilled in the art can make similar generalizations and deductions based on actual application situations without violating the connotation of the present invention. Therefore, the protection scope of the present invention should not be limited by the content of this specific embodiment.
[0045] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by technicians in the technical field to which this application belongs; the terms used herein are only for the purpose of describing specific embodiments and are not intended to limit this application; the terms "including" and "having" in the specification and claims of this application and the above-mentioned figure descriptions and any variations thereof are intended to cover non-exclusive inclusions.
[0046] Please refer to Figure 1 The present invention provides a uranium extraction material elution and regeneration device from seawater, comprising an elution and regeneration tank 1, an eluent collecting flow path 2 and a regeneration liquid collecting flow path 3. At least two spacer areas 11 are arranged inside the elution and regeneration tank 1, and adjacent spacer areas 11 are interconnected. The fiber materials after uranium adsorption are placed in the spacer areas 11 at intervals.
[0047] At present, the seawater uranium extraction test materials are amidoxime-based fibrous materials. The fibrous seawater uranium extraction materials that adsorb uranium from real sea areas need to be fully in contact with eluent and regeneration liquid. The seawater uranium extraction materials have the characteristics of low mechanical strength, fibrous material, easy entanglement and knotting, and relatively low reuse rate.
[0048] Based on this, the present invention sets at least two spacing areas 11 in the elution regeneration tank 1, and the fiber materials can be placed in the spacing areas 11 at intervals for spacing.
[0049] The inlet and outlet ends of the eluent collecting flow path 2 are respectively connected to the elution regeneration tank 1 . The eluent collecting flow path 2 is provided with at least two parallel eluent collecting tanks 21 to collect eluents of different concentrations flowing through the spacer 11 .
[0050] That is, since the subsequent process needs to recover the eluted uranium from the eluent, the uranium concentration of the eluent is increased and the volume of the solution is reduced, thereby improving the processing efficiency of the uranium recovery process.
[0051] The present invention is provided with at least two elution regeneration tanks 1, and the elution regeneration tanks 1 can be divided into A, B, C and the like according to the concentration of recovered uranium, so that the eluent with high uranium concentration can directly enter the uranium recovery process section, and the uranium-containing eluent in the medium concentration and low concentration sections can be returned to the elution regeneration tank 1 for repeated elution, so as to improve the elution efficiency of the eluent and reduce the solution processing volume of the uranium recovery section.
[0052] Specifically, the inlet and outlet ends of the regeneration liquid collecting flow path 3 are respectively connected to the elution regeneration tank 1, and at least two parallel regeneration liquid collecting tanks 31 are provided on the regeneration liquid collecting flow path 3. The regeneration liquid collecting tanks 31 are used to collect regeneration liquids of different concentrations flowing through the interval area 11 for treatment and discharge or return to the elution regeneration tank 1 for reuse.
[0053] It can be seen that at least two parallel regeneration liquid collection tanks 31 are set, and the regeneration liquid in the low-concentration regeneration liquid collection tank 31 is discharged after being treated to meet the standards, and the regeneration liquid in the medium- and high-concentration regeneration liquid collection tanks 31 can be returned to the elution regeneration tank 1 for reuse, so as to improve the utilization rate of the regeneration liquid while ensuring the regeneration effect. The regeneration liquid can be treated as a secondary pollutant and then discharged.
[0054] Compared with the design of adding the same volume of regeneration liquid in a single batch, the recycling and batch collection of the regeneration liquid can reduce the discharge of the regeneration liquid after use by nearly 60%, thereby greatly improving the environmental friendliness.
[0055] Moreover, the amount of uranium-containing solution treated in the subsequent uranium processing section was reduced by nearly 60%, and the uranium concentration in the uranium-containing solution was increased by at least three times.
[0056] Please refer to Figure 2 and Figure 3 An inlet 15 is provided on the elution regeneration tank 1, and the eluent or regeneration liquid enters the elution regeneration tank 1 through the inlet 15; a plurality of partitions 111 are provided in the elution regeneration tank 1, and the partitions 111 divide the interior of the elution regeneration tank 1 into a plurality of partition areas 11; at least one flow hole 112 is provided on the partition 111.
[0057] Please refer to 1 and Figure 2 The top of the elution regeneration tank 1 can be designed to be open, and the open opening corresponds to the inlet 15. The eluent or regeneration liquid can be injected into the elution regeneration tank 1 from the top opening. At the same time, the inlet 15 also serves as the discharge port of the eluent or regeneration liquid.
[0058] In some other embodiments, the inlet 15 may also be opened at other positions, such as the side of the elution regeneration tank 1, and the specific position is not limited here.
[0059] Optionally, the plurality of partitions 111 are arranged in a honeycomb shape in the elution regeneration tank 1 .
[0060] The multiple honeycomb-shaped spacing areas 11 can place fiber materials at intervals, which is beneficial to increase the amount of fiber materials placed, thereby improving the utilization rate of the elution and regeneration tank 1.
[0061] It should be noted that the partition 111 is provided with at least two flow holes 112 at intervals along the elution regeneration tank 1. Moreover, the multiple partitions 111 can be integrally formed into a honeycomb shape and then directly placed in the elution regeneration tank 1; or, one end of the honeycomb partition 111 is clamped or welded to the bottom of the elution regeneration tank 1, etc., which is not limited here.
[0062] Thus, the eluent or regeneration liquid can flow through each spacing zone 11 in sequence and fully contact with the fiber material.
[0063] Furthermore, a rotating mechanism 14 is provided at the bottom of the elution and regeneration tank 1 for driving the elution and regeneration tank 1 to rotate.
[0064] Rotating the elution regeneration tank 1 during the elution or regeneration process is beneficial to increasing the flow rate of the eluent or regeneration liquid in the spacing zone 11, thereby increasing the contact probability and contact amount between the eluent or regeneration liquid and the fiber material, which is beneficial to improving the elution or regeneration efficiency.
[0065] Please continue to refer to Figure 1 and Figure 2 The elution regeneration tank 1 is provided with at least one liquid inlet 12 and at least one liquid outlet 13 ; the liquid inlet 12 and the liquid outlet 13 are arranged on opposite sides of the elution regeneration tank 1 .
[0066] For example, the liquid inlet 12 is located at the top of the elution regeneration tank 1 or at a side portion close to the top; the liquid outlet 13 is opened at the bottom of the elution regeneration tank 1 .
[0067] Alternatively, the liquid inlet 12 and the liquid outlet 13 are opened on the side of the elution regeneration tank 1 and are arranged correspondingly, thereby improving the flow path of the eluent or regeneration liquid in the elution regeneration tank, so that the eluent or regeneration liquid is fully in contact with the fiber material.
[0068] The liquid inlet 12 and the liquid outlet 13 are disposed on opposite sides of the elution regeneration tank 1, thereby allowing the eluent or regeneration liquid to flow through each spacer 11 to a greater extent, thereby improving the elution efficiency or regeneration efficiency.
[0069] It can be seen that a liquid inlet 12 and a liquid outlet 13 can be provided on the elution regeneration tank 1, and the eluent collection flow path 2 and the regeneration liquid collection flow path 3 can be connected and used in sequence, thereby satisfying the operation of the eluent and regeneration liquid circulation flow paths. Or,
[0070] Two liquid inlets 12 and two liquid outlets 13 may also be provided on the elution regeneration tank 1, and the eluent collection flow path 2 and the regeneration liquid collection flow path 3 are each independently connected to a liquid inlet 12 and a liquid outlet 13, both methods are acceptable and are not limited here.
[0071] Alternatively, the inlet 15 at the top of the elution regeneration tank 1 can be used as the liquid inlet 12 and the liquid outlet 13, that is, the inlet 15, the liquid inlet 12 and the liquid outlet 13 are the same opening. The above three methods are all possible and are not limited here.
[0072] Specifically, one end of the eluent collecting flow path 2 is connected to the liquid outlet 13 and is divided into at least two first branches 22, each first branch 22 is provided with an eluent collecting tank 21, and a first regulating valve 221 is provided on each opposite side of the eluent collecting tank 21; the other end of the eluent collecting flow path 2 is connected to the liquid inlet 12.
[0073] The two first regulating valves 221 are arranged on opposite sides of the eluent collecting tank 21. By controlling the on and off of the first regulating valves 221, the flow direction of the eluent in the eluent collecting tank 21 can be controlled, so that the high-concentration eluent can flow to the uranium recovery section, and the medium and low-concentration eluent can return to the elution regeneration tank 1 for reuse.
[0074] Furthermore, the eluent collecting flow path 2 is provided with a second regulating valve 23 upstream of the eluent collecting tank 21; the eluent collecting flow path 2 is provided with an eluent filter 24 and an eluent pump 25 downstream of the eluent collecting tank 21, which are respectively used for filtering and transporting the eluent; the eluent collecting flow path 2 is also provided with a third regulating valve 26 between the eluent filter 24 and the eluent collecting tank 21.
[0075] The second regulating valve 23 can adjust the flow rate of the eluent flowing out of the elution regeneration tank 1. The specific flow rate can be adjusted according to actual needs and is not limited here.
[0076] The eluent filter 24 can filter impurities in the eluent of medium and low concentrations, and the eluent pump 25 is used to provide power for conveying the liquid from the eluent collecting tank 21 to the elution regeneration tank 1.
[0077] The third regulating valve 26 is used to control the flow direction of the eluent discharged from the eluent collecting tank 21, for example, it can flow to the elution regeneration tank 1, or it can flow to the uranium recovery section.
[0078] Specifically, a uranium recovery flow path 27 is further provided on the eluent collection flow path 2 for collecting eluent with a high uranium content, and a fourth regulating valve 271 is provided on the uranium recovery flow path 27 .
[0079] Here, three eluent collecting tanks 21 are taken as an example for description, namely, the eluent collecting tank 21A, the eluent collecting tank 21B, and the eluent collecting tank 21C.
[0080] In actual application, a certain amount of eluent is first introduced into the elution regeneration tank 1, and discharged into the eluent collecting tank 21A after elution; then a certain amount of eluent is introduced into the elution regeneration tank 1 again, and discharged into the eluent collecting tank 21B after elution. Secondly, a certain amount of eluent is introduced into the elution regeneration tank 1 again, and discharged into the eluent collecting tank 21C after elution. At this time, the uranium concentration of the eluent in the eluent collecting tank 21A, the eluent collecting tank 21B, and the eluent collecting tank 21C decreases in sequence, and the eluent in the eluent collecting tank 21A has the highest uranium concentration, which can be directly discharged to the uranium recovery section. The uranium concentration of the eluent in the eluent collecting tank 21B and the eluent collecting tank 21C is sampled and tested. If the concentration is too low, it is returned to the elution regeneration tank 1 for repeated cleaning in sequence.
[0081] It can be seen that if the uranium concentration of the eluent in the eluent collecting tank 21C is very low and the concentration does not change much after repeated elution, new fiber material can be replaced and then injected into the eluent collecting tank 21C as a new eluent for elution.
[0082] Please continue to refer to Figure 1 One end of the regeneration liquid collecting flow path 3 is connected to the liquid outlet 13 and is divided into at least two second branches 32. Each second branch 32 is provided with a regeneration liquid collecting tank 31, and a fifth regulating valve 321 is provided on each opposite side of the regeneration liquid collecting tank 31; the other end of the regeneration liquid collecting tank 31 is connected to the liquid inlet 12.
[0083] The number of the regeneration liquid collecting tanks 31 can be two, three, or more, which is not limited here. Here, three are taken as an example for description, which is not limited here.
[0084] After the elution is completed, the elution regeneration tank 1 is in a liquid-free state and then the regeneration liquid is injected into the elution regeneration tank 1. Each time the regeneration liquid is circulated, it can be discharged to different regeneration liquid collection tanks 31 in turn, and the concentration of the regeneration liquid is sampled and tested. If the concentration is too high, it is returned to the elution regeneration tank 1 for further treatment. If the concentration is too low, it is discharged after treatment.
[0085] Compared with the design of adding the same volume of regeneration liquid once, the recycling and batch collection of the regeneration liquid can reduce the discharge of the regeneration liquid after use by nearly 60%, which can greatly improve the environmental friendliness.
[0086] Furthermore, the regeneration liquid collecting flow path 3 is provided with a sixth regulating valve 33 upstream of the regeneration liquid collecting tank 31; the regeneration liquid collecting flow path 3 is provided with a regeneration liquid filter 34 and a regeneration liquid pump 35 downstream of the regeneration liquid collecting tank 31, which are used for filtering and transporting the regeneration liquid respectively.
[0087] The regeneration liquid filter 34 is used to filter impurities, and the regeneration liquid pump 35 is used to provide the power for conveying the regeneration liquid.
[0088] Furthermore, a discharge flow path 36 is provided on the regeneration liquid collecting flow path 3 for discharging low-concentration regeneration liquid; a seventh regulating valve 361 is provided on the discharge flow path 36 .
[0089] When the concentration of the regeneration liquid in the regeneration liquid collecting tank 31 is lower than the target value, the seventh regulating valve 361 can be opened to discharge the regeneration liquid.
[0090] Since the adsorption sites of the seawater uranium extraction material are occupied by the solvent during the elution and regeneration process, it is not conducive to the seawater uranium extraction material to adsorb uranium again. Therefore, in order to improve the secondary adsorption capacity of the material, the material needs to be dehydrated.
[0091] Before replacing the fiber material, the fiber material needs to be dehydrated, and the process is: turn on the rotating mechanism 14 to dehydrate the fiber material by centrifugal force.
[0092] In summary, in the elution and regeneration device for extracting uranium from seawater of the present invention, a partition area 11 is provided in the elution and regeneration tank 1, and the fiber materials adsorbing uranium are respectively arranged in the partition area 11 for separation, thereby avoiding disturbance of the fiber materials during the elution, regeneration and dehydration processes, and reducing mechanical damage to the fiber materials.
[0093] At least two parallel eluent collecting tanks 21 are provided on the eluent collecting flow path 2. The eluent can be processed according to concentration. The eluent with higher uranium concentration can directly enter the uranium recovery section, while the eluent with lower uranium concentration can be repeatedly eluted, so as to improve the elution efficiency of the eluent and reduce the solution processing volume of the uranium recovery section.
[0094] At least two parallel regeneration liquid collecting tanks 31 are arranged on the regeneration liquid collecting flow path 3. The regeneration liquid can be treated according to concentration. The regeneration liquid with low concentration can be discharged after being treated to meet the standards, and the regeneration liquid with higher concentration can be returned to the elution regeneration tank 1 for reuse, thereby improving the utilization rate of the regeneration liquid while ensuring the regeneration effect.
[0095] In the description of the embodiments of the present application, unless otherwise clearly specified and limited, technical terms such as "install", "connect", "connect", "fixed" and the like should be understood in a broad sense. For example, it can be a fixed connection, a detachable connection, or an integral connection; it can also be a mechanical connection. For ordinary technicians in this field, the specific meanings of the above terms in the embodiments of the present application can be understood according to the specific circumstances.
[0096] The present application uses specific words to describe the embodiments of the present application. For example, "one embodiment", "an embodiment", and / or "some embodiments" refer to a certain feature, structure or characteristic related to at least one embodiment of the present application. Therefore, it should be emphasized and noted that "one embodiment" or "an embodiment" or "an alternative embodiment" mentioned twice or multiple times in different positions in this specification does not necessarily refer to the same embodiment. In addition, some features, structures or characteristics in one or more embodiments of the present application can be appropriately combined.
[0097] Although the present invention is disclosed as above with preferred embodiments, it is not intended to limit the present invention. Any person skilled in the art may make possible changes and modifications without departing from the spirit and scope of the present invention. Therefore, any modification, equivalent change and modification made to the above embodiments according to the technical essence of the present invention without departing from the content of the technical solution of the present invention shall fall within the protection scope defined by the claims of the present invention.
Claims
1. A device for eluting and regenerating uranium from seawater, characterized in that: include: The elution regeneration tank has at least two compartments disposed therein, and the adjacent compartments are interconnected, and the fiber materials after uranium adsorption are respectively placed in the compartments at intervals; An eluent collecting flow path, the inlet end and the outlet end of which are respectively connected to the elution regeneration tank, and the eluent collecting flow path is provided with at least two parallel eluent collecting tanks to collect eluents of different concentrations flowing through the spacer; The regeneration liquid collecting flow path has an inlet end and an outlet end respectively connected to the elution regeneration tank. The regeneration liquid collecting flow path is provided with at least two parallel regeneration liquid collecting tanks. The regeneration liquid collecting tanks are used to collect regeneration liquids of different concentrations flowing through the interval area for treatment and discharge or return to the elution regeneration tank for reuse.
2. The device for eluting and regenerating uranium from seawater according to claim 1, characterized in that: The elution regeneration tank is provided with an inlet, through which the eluent or the regeneration liquid enters the elution regeneration tank or is discharged from the elution regeneration tank; A plurality of partitions are provided in the elution regeneration tank, and the partitions divide the interior of the elution regeneration tank into a plurality of the partition areas; At least one flow hole is formed on the partition.
3. The device for eluting and regenerating uranium from seawater according to claim 2, characterized in that: The plurality of partitions are arranged in a honeycomb shape in the elution regeneration tank.
4. The device for eluting and regenerating uranium from seawater according to claim 2, characterized in that: The partition plate is provided with at least two flow holes spaced vertically along the elution regeneration tank.
5. The device for eluting and regenerating uranium from seawater according to claim 1, characterized in that: A rotating mechanism is also provided at the bottom of the elution and regeneration tank for driving the elution and regeneration tank to rotate.
6. The device for eluting and regenerating uranium from seawater according to claim 1, characterized in that: The elution regeneration tank is provided with at least one liquid inlet and at least one liquid outlet; The liquid inlet and the liquid outlet are arranged on opposite sides of the elution regeneration tank.
7. The device for eluting and regenerating uranium from seawater according to claim 6, characterized in that: One end of the eluent collecting flow path is connected to the liquid outlet and is divided into at least two first branches, each of which is provided with an eluent collecting tank, and a first regulating valve is provided on opposite sides of the eluent collecting tank; The other end of the eluent collection flow path is connected to the liquid inlet.
8. The device for eluting and regenerating uranium from seawater according to claim 7, characterized in that: The eluent collecting flow path is provided with a second regulating valve upstream of the eluent collecting tank; The eluent collecting flow path is provided with an eluent filter and an eluent pump downstream of the eluent collecting tank, which are used for filtering and conveying the eluent respectively; The eluent collecting flow path is further provided with a third regulating valve between the eluent filter and the eluent collecting tank.
9. The device for eluting and regenerating uranium from seawater according to claim 6, characterized in that: The eluent collecting flow path is also provided with a uranium recovery flow path for collecting eluent with high uranium content, and the uranium recovery flow path is provided with a fourth regulating valve.
10. The device for eluting and regenerating uranium from seawater according to claim 6, characterized in that: One end of the regeneration liquid collection flow path is connected to the liquid outlet and is divided into at least two second branches, each of the second branches is provided with a regeneration liquid collection tank, and a fifth regulating valve is respectively provided on two opposite sides of the regeneration liquid collection tank; The other end of the regeneration liquid collecting tank is connected to the liquid inlet.
11. The device for eluting and regenerating uranium from seawater according to claim 10, characterized in that: The regeneration liquid collection flow path is provided with a sixth regulating valve upstream of the regeneration liquid collection tank; The regeneration liquid collecting flow path is provided with a regeneration liquid filter and a regeneration liquid pump downstream of the regeneration liquid collecting tank, which are used for filtering and conveying the regeneration liquid respectively.
12. The device for eluting and regenerating uranium from seawater according to claim 11, characterized in that: The regeneration liquid collection flow path is also provided with a discharge flow path for discharging low-concentration regeneration liquid; A seventh regulating valve is provided on the discharge flow path.
Citation Information
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