Plate net type electrolytic bath for preparing sodium perchlorate

Abstract

The invention relates to the technical field of sodium perchlorate preparation, and discloses a plate net type electrolytic bath for sodium perchlorate preparation, the plate net type electrolytic bath comprises an electrolytic bath body and two top covers, the top covers on the two sides are clamped to the top of the electrolytic bath body, and air outlet pipes are fixedly connected to the middles of the top covers on the two sides; a bubble uniform precipitation triggering assembly used for uniformly regulating and controlling gas precipitated from the cathode and the anode is arranged in the electrolytic bath body; an anode protection adjusting assembly used for releasing the concentration of chlorine around the anode in real time is arranged in the side, close to the anode, of the gas outlet pipe; the positions and forms of hydrogen and chlorine generated in the cathode chamber and the anode chamber are detected through the ultrasonic sensor, the distance between the cathode plate and the anode plate is adjusted, heat in the electrolytic bath is neutralized, bubble aggregation of two gases in the cathode chamber and the anode chamber is avoided, uniform separation of the gases is facilitated, and the production efficiency is improved. And meanwhile, meshes of the nickel wire meshes on the two sides are treated through linkage adjustment, and normal proceeding of the subsequent electrolysis process is guaranteed.

Description

Technical Field

[0001] The invention relates to the technical field of sodium perchlorate preparation, in particular to a plate-net type electrolytic cell for preparing sodium perchlorate. Background Art

[0002] The plate-net electrolytic cell adopts a plate-net electrode structure. The electrolytic cell plays a key role in the preparation of sodium perchlorate. The principle of electrolysis is used to convert electrical energy into chemical energy or thermal energy, so that an oxidation reaction occurs at the interface between the anode and the solution, and a reduction reaction occurs at the interface between the cathode and the solution to produce the desired sodium perchlorate product. The design of the plate-net electrolytic cell helps to increase the working surface area of ​​the electrode, improve the electrolysis efficiency, and facilitate the escape of bubbles, thereby reducing the bubble effect.

[0003] Since certain gases (such as hydrogen, chlorine, etc.) are generated during the electrolysis process, if the current density is unevenly distributed on the anode and cathode surfaces during this process, it will lead to uneven gas precipitation at the anode and cathode, which will cause uneven local heat distribution in the electrolytic cell and bubble aggregation of the precipitated gas, resulting in a decrease in the reaction rate of sodium perchlorate preparation and a decrease in product quality. In addition, during the electrolysis process, due to the gas, precipitate and other impurities generated in the electrolysis reaction, a layer of dirt or sediment will form on the surface of the nickel wire mesh, which will affect its conductivity and electrolysis efficiency. In order to avoid accumulation, the staff needs to remove the cover plate and then reach into the inside of the electrolytic cell for cleaning, which has a large range of motion and low cleaning efficiency.

[0004] In addition, the preparation process of sodium perchlorate generally involves an electrolysis reaction. During the electrolysis of the sodium chlorate solution, the anode chlorine ions are discharged to mainly generate chlorate ions, and some chlorine ions directly generate chlorine gas, while the cathode is discharged with hydrogen ions to generate hydrogen gas. However, during the generation of chlorine gas in the anode chamber, when the concentration is high, the anode plate is easily corroded, thereby reducing the service life of the anode plate.

[0005] Therefore, a plate-net type electrolytic cell for preparing sodium perchlorate is proposed. Summary of the invention

[0006] The object of the present invention is to provide a plate-net type electrolytic cell for preparing sodium perchlorate to solve the problems raised in the above-mentioned background technology.

[0007] To achieve the above object, the present invention provides the following technical solution: a plate-net type electrolytic cell for preparing sodium perchlorate, comprising an electrolytic cell body and two top covers, the top covers on both sides are clamped and arranged on the top of the electrolytic cell body, the middle parts of the top covers on both sides are fixedly connected with gas outlet pipes, the interior of the electrolytic cell body is provided with a bubble uniform precipitation trigger component for uniformly regulating the gas precipitation of the positive and negative electrodes, and the interior of the gas outlet pipe close to the anode is provided with an anode protection adjustment component for real-time release of chlorine concentration around the anode, wherein:

[0008] The bubble uniform precipitation trigger assembly includes two guide rails, the guide rails on both sides are fixedly connected to the upper inner wall of the electrolytic cell body, a diaphragm is fixedly connected to the middle of the inner wall of the electrolytic cell body, an ultrasonic sensor is installed in the middle of the diaphragm, propellers are rotatably connected to the middle of both sides of the diaphragm, a pair of pulleys are rotatably connected to the outer walls on both sides of the diaphragm, the pulleys on both sides are connected by connecting belts, the lower pulleys are fixedly connected to the propellers on both sides, and four main bevel gears are rotatably connected from left to right in the vertical direction inside the electrolytic cell body, two of which are rotatably connected to the middle of the diaphragm and fixedly connected to the upper pulleys.

[0009] Preferably, three auxiliary bevel gears are rotatably connected in sequence from left to right in the horizontal direction inside the electrolytic cell body, one of which is meshingly connected to the main bevel gears on both sides of the middle part and rotatably connected to the top of the diaphragm, and a transmission gear is fixedly connected to the top of the auxiliary bevel gear, and racks are meshingly connected on both sides of the transmission gear.

[0010] Preferably, an anode chamber and a cathode chamber are respectively provided on both sides of the electrolytic cell body, and an anode plate and a cathode plate are respectively provided inside the anode chamber and the cathode chamber, and the anode plate and the cathode plate are both slidably connected to the outer walls of the guide rails on both sides.

[0011] Preferably, one end of the racks on both sides away from the transmission gear is fixedly connected to the anode plate and the cathode plate respectively, and the main bevel gears on the other two sides are meshedly connected to the other two auxiliary bevel gears respectively, and the inside of the anode chamber and the cathode chamber are rotatably connected with reciprocating screws, and the reciprocating screws on both sides are fixedly connected to the main bevel gears on both sides respectively.

[0012] Preferably, the interior of the anode chamber and the cathode chamber are fixedly connected to limit rods located on the sides of the reciprocating screw, and rollers are threadedly connected to the outer walls of the reciprocating screws on both sides, and the rollers on both sides are respectively slidably connected to the outer walls of the limit rods on both sides, and nickel wire meshes are provided on both sides of the inner wall of the electrolytic cell body, and the rollers on both sides are respectively slidably connected to the outer walls of the nickel wire meshes on both sides.

[0013] Preferably, the anode protection adjustment component includes a chlorine gas detector, which is fixedly connected to the inner wall of the anode chamber, and the insides of the air outlet pipes on both sides are fixedly connected with gas collecting hoods, and the insides of the gas collecting hoods on both sides are fixedly connected with fans, and the top of the gas collecting hood close to the anode chamber is fixedly connected with a multi-slot hollow column, and the inside of the multi-slot hollow column is fixedly connected with an electric telescopic rod, and the driving end of the electric telescopic rod is fixedly connected with a movable block, and the movable block is slidably connected to the inner wall of the multi-slot hollow column, and the outer wall of the movable block is evenly rotated around a circle and connected with a plurality of adjustment rods.

[0014] Preferably, a three-pronged cavity plate is fixedly connected to the inner wall of one side of the outlet pipe close to the anode chamber, a plurality of rectangular holes are evenly opened on the bottom of the three-pronged cavity plate, one end of the adjusting rod away from the movable block is slidably connected to the inner walls of the rectangular holes, one end of the adjusting rod away from the movable block is fixedly connected to a fan-shaped plate, and the fan-shaped plate is slidably connected to the inner wall of the three-pronged cavity plate.

[0015] Preferably, the bottom of the electrolytic cell body is located directly below the anode chamber and the cathode chamber and is fixedly connected to a valve, and the outer wall of the electrolytic cell body is fixedly connected to a control panel, and the control panel is electrically connected to the valve, ultrasonic sensor, propeller, chlorine gas detector, fan and electric telescopic rod.

[0016] Compared with the prior art, the present invention has the following beneficial effects:

[0017] 1. Ultrasonic sensors are set up to detect the position and form of hydrogen and chlorine generated in the cathode chamber and the anode chamber. When abnormal gas accumulation is detected, the ultrasonic sensor transmits an electrical signal, so that the control panel controls the rotation of the propellers on both sides, and the main bevel gears on both sides can be driven to rotate with the cooperation of the pulley groups on both sides, and then the transmission gear is driven to rotate through the secondary bevel gear meshed at the top. With the help of the limit of the guide rails on both sides, the cathode plate and the anode plate are moved in the cathode chamber and the anode chamber through the racks on both sides meshed with the transmission gear, and the distance between the cathode plate and the anode plate is adjusted, so as to neutralize the heat in the electrolytic cell, avoid the accumulation of hydrogen and chlorine bubbles in the cathode chamber and the anode chamber, and facilitate the uniform precipitation of the gas;

[0018] 2. By neutralizing and regulating the electrolytic heat in the cathode chamber and the anode chamber, the bevel gear sets arranged at both ends are synchronously driven to drive the reciprocating screws on both sides to rotate inside the cathode chamber and the anode chamber, and with the cooperation of the limit rods on both sides, the rollers threadedly connected to the outer wall of the reciprocating screw on both sides can slide up and down on the outer wall of the nickel wire mesh on both sides, thereby cleaning the dirty impurities adhering to and accumulating on the nickel wire mesh, ensuring the normal progress of the subsequent electrolysis process;

[0019] 3. By setting a chlorine detector on the inner wall of the anode chamber, the chlorine generation concentration in the anode chamber is monitored in real time. When the chlorine concentration exceeds the set maximum threshold, the control panel controls the operation of the electric telescopic rod to drive the movable block to retract downward, and each fan-shaped plate is retracted to the inner wall of the three-way cavity plate through each adjustment rod, so that the inner wall aperture of the chlorine outlet pipe can be adjusted, the output speed of chlorine can be accelerated, the overall gas concentration can be reduced, and its accumulation around the anode plate can be reduced, so that the anode plate can be protected from the corrosion of chlorine and the service life of the anode plate can be extended. BRIEF DESCRIPTION OF THE DRAWINGS

[0020] Figure 1 It is a three-dimensional schematic diagram of the overall device of the present invention;

[0021] Figure 2 It is a side view schematic diagram of the overall device of the present invention;

[0022] Figure 3 It is a schematic top view of the interior of the electrolytic cell of the present invention;

[0023] Figure 4 For the present invention Figure 3 The enlarged schematic diagram of point A in the middle;

[0024] Figure 5 It is a vertical cross-sectional schematic diagram of the electrolytic cell body of the present invention;

[0025] Figure 6 It is a schematic diagram of the internal structure of the electrolytic cell of the present invention;

[0026] Figure 7 For the present invention Figure 6 The enlarged schematic diagram of point B in the middle;

[0027] Figure 8 It is a vertical cross-sectional schematic diagram of the air outlet pipes on both sides of the present invention;

[0028] Fig. 9 This is a schematic diagram of the internal structure of the anode gas outlet pipe of the present invention;

[0029] Fig.10 Schematic diagram of a vertical section of the anode gas outlet pipe of the present invention;

[0030] Fig.11 It is a partial structural schematic diagram of the anode plate protection and adjustment assembly of the present invention;

[0031] Fig.12 For the present invention Fig.11 Enlarged schematic diagram of point C in the middle.

[0032] In the figure:

[0033] 1. Electrolytic cell body; 2. Top cover; 3. Exhaust pipe; 4. Control panel; 5. Valve; 6. Nickel wire mesh; 7. Anode plate; 8. Cathode plate; 9. Anode chamber; 10. Cathode chamber; 11. Diaphragm;

[0034] The bubble uniform precipitation triggering assembly includes: 121, guide rail; 122, ultrasonic sensor; 123, propeller; 124, pulley; 125, connecting belt; 126, main bevel gear; 127, auxiliary bevel gear; 128, transmission gear; 129, rack; 1210, reciprocating screw rod; 1211, limit rod; 1212, roller;

[0035] The anode protection adjustment component includes: 131, chlorine gas detector; 132, gas collecting hood; 133, fan; 134, multi-slot hollow column; 135, electric telescopic rod; 136, movable block; 137, adjustment rod; 138, three-branch cavity plate; 139, rectangular hole; 1310, fan plate. DETAILED DESCRIPTION

[0036] The following will be combined with the drawings in the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0037] See also Figures 1 to 12 , is an embodiment provided by the present invention: a plate-net type electrolytic cell for preparing sodium perchlorate, comprising an electrolytic cell body 1 and two top covers 2, both top covers 2 on both sides are clamped and arranged on the top of the electrolytic cell body 1, and the middle of both top covers 2 on both sides are fixedly connected with an outlet pipe 3, and the inside of the electrolytic cell body 1 is provided with a bubble uniform precipitation trigger component for uniformly regulating the gas precipitation of the positive and negative electrodes, and the inside of the outlet pipe 3 close to the anode side is provided with an anode protection adjustment component for real-time release of chlorine concentration around the anode, wherein:

[0038] The bubble uniform precipitation trigger assembly includes two guide rails 121, both side guide rails 121 are fixedly connected to the upper inner wall of the electrolytic cell body 1, both sides of the inner part of the electrolytic cell body 1 are provided with an anode chamber 9 and a cathode chamber 10, respectively, the inner parts of the anode chamber 9 and the cathode chamber 10 are provided with an anode plate 7 and a cathode plate 8, respectively, the anode plate 7 and the cathode plate 8 are slidably connected to the outer walls of the guide rails 121 on both sides, a diaphragm 11 is fixedly connected to the middle of the inner wall of the electrolytic cell body 1, an ultrasonic sensor 122 is installed in the middle of the diaphragm 11, and the diaphragm 11 is provided with an ultrasonic sensor 122. The middle of both sides of the membrane 11 are rotatably connected with a propeller 123, and the outer walls of both sides of the diaphragm 11 are rotatably connected with a pair of pulleys 124, the pulleys 124 on both sides are connected by connecting belts 125, and the lower pulleys 124 are fixedly connected to the propellers 123 on both sides, and four main bevel gears 126 are rotatably connected from left to right in the vertical direction inside the electrolytic cell body 1, wherein two main bevel gears 126 are rotatably connected to the middle of the diaphragm 11 and are fixedly connected to the upper pulleys 124 respectively;

[0039] Wherein: the inner wall of the top end of the air outlet pipe 3 is clamped with a sealing plug, and the vertical section of the guide rail 121 is L-shaped;

[0040] Better: inject the sodium chlorate solution to be electrolyzed into the electrolytic cell body 1, and energize the positive and negative electrodes through the power supply, so that the sodium chlorate solution undergoes electrolysis reaction in the cathode chamber 10 and the anode chamber 9 through the cathode plate 8 and the anode plate 7, and arrange an ultrasonic sensor 122 in the middle of the diaphragm 11 to monitor the precipitated gas in the anode chamber 9 and the cathode chamber 10 in real time, and analyze its position and morphology. When uneven gas precipitation is detected and bubbles gather, the ultrasonic sensor 122 transmits this abnormal situation through an electrical signal, controls the rotation of the propellers 123 on both sides through the control panel 4, and transmits the rotational force through the pulley 124 and the connecting belt 125, so that the main bevel gears 126 connected to the diaphragm 11 on both sides rotate synchronously.

[0041] The inside of the electrolytic cell body 1 is horizontally connected with three auxiliary bevel gears 127 which are rotatably connected from left to right in sequence. One of the auxiliary bevel gears 127 is meshedly connected with the main bevel gears 126 on both sides of the middle part and is rotatably connected to the top of the diaphragm 11. The top of the auxiliary bevel gear 127 is fixedly connected with a transmission gear 128. Both sides of the transmission gear 128 are meshedly connected with racks 129. The ends of the racks 129 on both sides away from the transmission gear 128 are fixedly connected with the anode plate 7 and the cathode plate 8 respectively. The main bevel gears 126 on the other two sides are meshedly connected with the other two auxiliary bevel gears 127 respectively. The inside of the anode chamber 9 and the cathode chamber 10 are both rotatably connected with a reciprocating screw rod 1210, and the reciprocating screw rods 1210 on both sides are fixedly connected to the main bevel gears 126 on both sides. The inside of the anode chamber 9 and the cathode chamber 10 are located next to the reciprocating screw rod 1210 and are fixedly connected to the limiting rod 1211. The outer walls of the reciprocating screw rods 1210 on both sides are threadedly connected with rollers 1212, and the rollers 1212 on both sides are respectively slidably connected to the outer walls of the limiting rods 1211 on both sides. Nickel wire meshes 6 are provided on both sides of the inner wall of the electrolytic cell body 1, and the rollers 1212 on both sides are respectively slidably connected to the outer walls of the nickel wire meshes 6 on both sides;

[0042] Wherein: the auxiliary bevel gear 127 and the main bevel gears 126 on both sides are rotatably connected to the middle of the diaphragm 11 and are arranged in a convex shape, and the material of the roller 1212 is sponge;

[0043] Better: With the rotation of the main bevel gears 126 on both sides, the meshing auxiliary bevel gears 127 are driven to rotate in the middle of the diaphragm 11, so that the transmission gear 128 fixedly connected to the auxiliary bevel gear 127 can rotate with it. With the auxiliary support of the guide rails 121 on both sides, the meshing racks 129 on both sides can be driven to move closer to or away from each other in the horizontal direction through the rotation of the transmission gear 128, thereby driving the anode plate 7 and the cathode plate 8 to slide on the outer walls of the guide rails 121 on both sides, so that the heat in the electrolytic cell body 1 can be neutralized by adjusting the distance between the cathode plate 8 and the anode plate 7. , avoiding the accumulation of hydrogen and chlorine bubbles in the cathode chamber 10 and the anode chamber 9, which is conducive to the uniform precipitation of the gas. At the same time, with the rotation of two of the main bevel gears 126, the other two main bevel gears 126 arranged on both sides of the inner wall of the electrolytic cell body 1 can also rotate along, and respectively drive the reciprocating screws 1210 on both sides to rotate inside the cathode chamber 10 and the anode chamber 9 through the corresponding sub-bevel gears 127 meshing with them, and further, with the assistance of the limiting rods 1211 on both sides, the rollers 1212 on both sides threadedly connected to the outer wall of the reciprocating screw 1210 can be driven to move up and down to clean the outer wall mesh of the nickel wire mesh 6 on both sides.

[0044] The anode protection adjustment component includes a chlorine gas detector 131, which is fixedly connected to the inner wall of the anode chamber 9. The insides of the air outlet pipes 3 on both sides are fixedly connected with gas collecting covers 132, and the insides of the air collecting covers 132 on both sides are fixedly connected with fans 133. The top of the air collecting cover 132 close to the anode chamber 9 is fixedly connected with a multi-slot hollow column 134, and the inside of the multi-slot hollow column 134 is fixedly connected with an electric telescopic rod 135. The driving end of the electric telescopic rod 135 is fixedly connected with a movable block 136, and the movable block 136 is slidably connected to the inner wall of the multi-slot hollow column 134. The outer wall of the movable block 136 is evenly rotated around a circle and connected with a plurality of adjusting rods 137. The inner wall of the air outlet pipe 3 close to the anode chamber 9 is fixedly connected to the inner wall of the multi-slot hollow column 134. A three-way cavity plate 138 is connected, and a plurality of rectangular holes 139 are evenly opened at the bottom of the three-way cavity plate 138. The end of the adjusting rod 137 away from the movable block 136 is slidably connected to the inner wall of the rectangular hole 139, and the end of the adjusting rod 137 away from the movable block 136 is fixedly connected to a fan-shaped plate 1310, and the fan-shaped plate 1310 is slidably connected to the inner wall of the three-way cavity plate 138. The bottom of the electrolytic cell body 1 is located directly below the anode chamber 9 and the cathode chamber 10, and a valve 5 is fixedly connected. The outer wall of the electrolytic cell body 1 is fixedly connected to a control panel 4, and the control panel 4 is electrically connected to the valve 5, the ultrasonic sensor 122, the propeller 123, the chlorine gas detector 131, the fan 133 and the electric telescopic rod 135.

[0045] The slots of the multi-slot hollow column 134 correspond to the shapes of the movable block 136, the material of the sector plate 1310 is rubber, and the cavity shape of the three-branch cavity plate 138 corresponds to the shape of the sector plate 1310;

[0046] Preferably: during the electrolysis process, the gas outlet pipes 3 on both sides are kept in a sealed state, and the chlorine concentration generated during the electrolysis of the sodium chlorate solution in the anode chamber 9 is monitored in real time by the chlorine detector 131. When the chlorine concentration in the anode chamber 9 reaches the set maximum threshold, the chlorine detector 131 transmits an over-limit signal to the control panel 4, and the control panel 4 controls the operation of the electric telescopic rod 135 to drive the movable block 136 to retract downward, and then, under the cooperation of each adjusting rod 137 and the rectangular hole 139, each sector plate 1310 can be driven to move closer to the inner wall of the three-way cavity plate 138, so that each sector plate 13 10 maintains a certain gap with the inner wall of the outlet pipe 3 so that the outlet pipe 3 remains unobstructed. At this time, the output end of the outlet pipe 3 is connected to the relevant collecting container, and the control panel 4 controls the operation of the fan 133 to pump the chlorine gas upward through the gas collecting hood 132, and pump the high-concentration chlorine gas into the container to avoid polluting the external environment, thereby finally completing the monitoring and adjustment of the chlorine concentration inside the anode chamber 9. While the electrolysis process maintains a sealed and stable operating environment, it can also be adjusted according to special circumstances to ensure the balance of the chlorine concentration in the anode chamber 9, avoid excessive chlorine molecules from contacting the anode plate 7 to cause corrosion to it, and extend its service life.

[0047] The above implementation works as follows:

[0048] The initialization steps are as follows:

[0049] The dissolved sodium chlorate solution is injected into the anode chamber 9 and the cathode chamber 10 in the electrolytic cell body 1, and the power supply is turned on so that the anode plate 7 and the cathode plate 8 are energized;

[0050] The working steps are as follows:

[0051] like Figure 1 - Figure 7As shown, the sodium chlorate solution undergoes electrolytic reaction in the cathode chamber 10 and the anode chamber 9 through the cathode plate 8 and the anode plate 7, and an ultrasonic sensor 122 is arranged in the middle of the diaphragm 11 to monitor the precipitated gas in the anode chamber 9 and the cathode chamber 10 in real time, and analyze its position and morphology. When uneven gas precipitation is detected and bubbles gather, the ultrasonic sensor 122 transmits the abnormal situation through an electrical signal, controls the rotation of the propellers 123 on both sides through the control panel 4, and transmits the rotational force through the pulley 124 and the connecting belt 125, so that the main bevel gears 126 connected to the diaphragm 11 on both sides rotate synchronously, and with the rotation of the main bevel gears 126 on both sides, the meshing and connected auxiliary bevel gears 127 are driven to rotate in the middle of the diaphragm 11. The transmission gear 128 fixedly connected to the secondary bevel gear 127 can rotate accordingly. With the auxiliary support of the guide rails 121 on both sides, the rotation of the transmission gear 128 can drive the meshing racks 129 on both sides to move closer to or away from each other in the horizontal direction, thereby driving the anode plate 7 and the cathode plate 8 to slide on the outer walls of the guide rails 121 on both sides. By adjusting the spacing between the anode plate 7 and the cathode plate 8, the heat distribution generated during the electrolysis process can be affected. The appropriate spacing can make the current pass through the electrolyte solution more evenly and reduce local overheating. Therefore, the heat in the electrolytic cell body 1 can be neutralized by adjusting the distance between the cathode plate 8 and the anode plate 7 to avoid the accumulation of hydrogen and chlorine bubbles in the cathode chamber 10 and the anode chamber 9. , which is conducive to the uniform precipitation of gas. According to the bubble aggregation state and position information detected by the ultrasonic sensor 122, after increasing the distance between the anode plate 7 and the cathode plate 8 to the maximum, the control panel 4 can be used to control the propellers 123 on both sides to stop rotating, thereby reducing the efficiency of the electrolysis of the sodium chlorate solution, so that the bubble precipitation rate is reduced, which is convenient for the uniform precipitation of gas. Correspondingly, when the electrolysis efficiency of the sodium chlorate solution is low, the distance between the anode plate 7 and the cathode plate 8 can be adjusted to be closer, and the electrolysis operation can be flexibly adjusted. At the same time, with the rotation of two of the main bevel gears 126, the other two main bevel gears 126 arranged on both sides of the inner wall of the electrolytic cell body 1 can also rotate with it, and drive the reciprocating screw rods 12 on both sides through the corresponding secondary bevel gears 127 meshing with them. 10 rotates inside the cathode chamber 10 and the anode chamber 9, and further, with the assistance of the limiting rods 1211 on both sides, it can drive the rollers 1212 on both sides that are threadedly connected to the outer wall of the reciprocating screw rod 1210 to move up and down, so as to clean the outer wall meshes of the nickel wire meshes 6 on both sides. During the electrolysis of the sodium chlorate solution, the chloride ions and the hydroxide ions therein will react during the electrolysis process to produce precipitates or bubbles, which will block the meshes of the nickel wire meshes 6 on both sides over time. The roller 1212 is arranged to reciprocate up and down on the outer wall of the nickel wire mesh 6 while adjusting the heat distribution during the electrolysis of the sodium chlorate solution, so that the meshes of the nickel wire mesh 6 can be cleaned regularly to ensure the patency of the meshes, and to ensure that the current passes through the entire electrolysis surface evenly.Ensuring effective contact between the solution and the electrode is beneficial to improving electrolysis efficiency and reducing energy loss;

[0052] like Figure 6 , Figure 8 - Fig.12 As shown, during the electrolysis process, the gas outlet pipes 3 on both sides are kept in a sealed state, and the chlorine concentration generated during the electrolysis of the sodium chlorate solution in the anode chamber 9 is monitored in real time by the chlorine detector 131. When the chlorine concentration in the anode chamber 9 reaches the set maximum threshold, the chlorine detector 131 transmits an over-limit signal to the control panel 4, and the control panel 4 controls the operation of the electric telescopic rod 135 to drive the movable block 136 to retract downward, and then, with the cooperation of each adjusting rod 137 and the rectangular hole 139, each sector plate 1310 can be driven to move closer to the inner wall of the three-way cavity plate 138, so that each sector plate 1310 can maintain a certain gap with the inner wall of the gas outlet pipe 3, so that the gas outlet pipe 3 remains unobstructed, and at this time, the output end of the gas outlet pipe 3 is connected to a related collection container (such as a gas cylinder or a gas collection tank). Then, at the same time, the control panel 4 controls the operation of the fan 133 to discharge the chlorine gas upward through the gas collecting hood 132, and the high-concentration chlorine is extracted and output into the container to avoid polluting the external environment, thereby finally completing the monitoring and adjustment of the chlorine concentration inside the anode chamber 9. While the electrolysis process maintains the sealed and stable operating environment, it can also be adjusted according to special circumstances to ensure the balance of the chlorine concentration in the anode chamber 9, avoid excessive chlorine molecules from contacting the anode plate 7 and causing corrosion to it, thereby extending its service life. Finally, after the electrolysis treatment, the sodium perchlorate solution is evaporated and concentrated to increase the concentration of the solution, and the concentrated solution is cooled to a certain temperature to precipitate and crystallize the sodium perchlorate, and the precipitated sodium perchlorate crystals are dried by air flow to remove residual moisture to obtain the final product, and finally the valve 5 is opened to obtain the prepared sodium perchlorate product.

[0053] It should be noted that, in this article, relational terms such as first and second, etc. are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply any such actual relationship or order between these entities or operations. Moreover, the terms "include", "comprise" or any other variants thereof are intended to cover non-exclusive inclusion, so that a process, method, article or device including a series of elements includes not only those elements, but also other elements not explicitly listed, or also includes elements inherent to such process, method, article or device. In the absence of further restrictions, the elements defined by the sentence "comprise a ..." do not exclude the existence of other identical elements in the process, method, article or device including the elements.

[0054] Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the present invention, and that the scope of the present invention is defined by the appended claims and their equivalents.

Claims

1. A plate-net electrolytic cell for preparing sodium perchlorate, characterized in that: The invention comprises an electrolytic cell body (1) and two top covers (2), wherein the top covers (2) on both sides are clamped and arranged on the top of the electrolytic cell body (1), and the middle parts of the top covers (2) on both sides are fixedly connected with gas outlet pipes (3), and the inside of the electrolytic cell body (1) is provided with a bubble uniform precipitation trigger component for uniformly regulating the gas precipitation of the positive and negative electrodes, and the inside of the gas outlet pipe (3) close to the anode side is provided with an anode protection adjustment component for real-time release of chlorine gas concentration around the anode, wherein: The bubble uniform precipitation triggering assembly comprises two guide rails (121), the guide rails (121) on both sides are fixedly connected to the upper part of the inner wall of the electrolytic cell body (1), a diaphragm (11) is fixedly connected to the middle of the inner wall of the electrolytic cell body (1), an ultrasonic sensor (122) is installed in the middle of the diaphragm (11), propellers (123) are rotatably connected to the middle of both sides of the diaphragm (11), and a pair of leather blades are rotatably connected to the outer walls of both sides of the diaphragm (11). Pulleys (124), the pulleys (124) on both sides are connected by connecting belts (125), the pulleys (124) on the lower side are fixedly connected to the propellers (123) on both sides, and four main bevel gears (126) are rotatably connected from left to right in the vertical direction inside the electrolytic cell body (1), wherein two of the main bevel gears (126) are rotatably connected to the middle part of the diaphragm (11) and are fixedly connected to the pulleys (124) on the upper side.

2. The expanded metal electrolytic cell for preparing sodium perchlorate according to claim 1, characterized in that: Three auxiliary bevel gears (127) are rotatably connected in sequence from left to right in the horizontal direction inside the electrolytic cell body (1), one of the auxiliary bevel gears (127) is meshedly connected to the main bevel gears (126) on both sides of the middle part and is rotatably connected to the top of the diaphragm (11), and a transmission gear (128) is fixedly connected to the top of the auxiliary bevel gear (127), and racks (129) are meshedly connected to both sides of the transmission gear (128).

3. A expanded metal electrolytic cell for preparing sodium perchlorate according to claim 2, characterized in that: An anode chamber (9) and a cathode chamber (10) are respectively provided on both sides of the electrolytic cell body (1), and an anode plate (7) and a cathode plate (8) are respectively provided inside the anode chamber (9) and the cathode chamber (10), and the anode plate (7) and the cathode plate (8) are both slidably connected to the outer walls of the guide rails (121) on both sides.

4. The expanded metal electrolytic cell for preparing sodium perchlorate according to claim 3, characterized in that: One end of the racks (129) on both sides away from the transmission gear (128) is fixedly connected to the anode plate (7) and the cathode plate (8), respectively, and the main bevel gears (126) on the other two sides are meshedly connected to the other two auxiliary bevel gears (127), and the insides of the anode chamber (9) and the cathode chamber (10) are rotatably connected with reciprocating screws (1210), and the reciprocating screws (1210) on both sides are fixedly connected to the main bevel gears (126) on both sides.

5. The expanded metal electrolytic cell for preparing sodium perchlorate according to claim 4, characterized in that: The inside of the anode chamber (9) and the cathode chamber (10) are fixedly connected to limit rods (1211) located beside the reciprocating screw rod (1210), and rollers (1212) are threadedly connected to the outer walls of the reciprocating screw rods (1210) on both sides, and the rollers (1212) on both sides are slidably connected to the outer walls of the limit rods (1211) on both sides, and nickel wire meshes (6) are provided on both sides of the inner wall of the electrolytic cell body (1), and the rollers (1212) on both sides are slidably connected to the outer walls of the nickel wire meshes (6) on both sides.

6. The expanded metal electrolytic cell for preparing sodium perchlorate according to claim 3, characterized in that: The anode protection adjustment component comprises a chlorine gas detector (131), the chlorine gas detector (131) is fixedly connected to the inner wall of the anode chamber (9), the inside of the gas outlet pipes (3) on both sides are fixedly connected to gas collecting covers (132), the inside of the gas collecting covers (132) on both sides are fixedly connected to fans (133), the top of the gas collecting cover (132) close to the anode chamber (9) is fixedly connected to a multi-slot hollow column (134), the inside of the multi-slot hollow column (134) is fixedly connected to an electric telescopic rod (135), the driving end of the electric telescopic rod (135) is fixedly connected to a movable block (136), the movable block (136) is slidably connected to the inner wall of the multi-slot hollow column (134), and the outer wall of the movable block (136) is evenly rotated and connected to a plurality of adjustment rods (137).

7. The expanded metal electrolytic cell for preparing sodium perchlorate according to claim 6, characterized in that: A three-way cavity plate (138) is fixedly connected to the inner wall of one side of the outlet pipe (3) close to the anode chamber (9), and a plurality of rectangular holes (139) are evenly opened at the bottom of the three-way cavity plate (138). One end of the adjustment rod (137) away from the movable block (136) is slidably connected to the inner wall of the rectangular hole (139), and one end of the adjustment rod (137) away from the movable block (136) is fixedly connected to a fan-shaped plate (1310), and the fan-shaped plate (1310) is slidably connected to the inner wall of the three-way cavity plate (138).

8. The expanded metal electrolytic cell for preparing sodium perchlorate according to claim 7, characterized in that: The bottom of the electrolytic cell body (1) is located directly below the anode chamber (9) and the cathode chamber (10), and is fixedly connected to a valve (5). The outer wall of the electrolytic cell body (1) is fixedly connected to a control panel (4). The control panel (4) is electrically connected to the valve (5), the ultrasonic sensor (122), the propeller (123), the chlorine gas detector (131), the fan (133), and the electric telescopic rod (135).

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