Three-in-one synthesis furnace and process for byproduct steam hydrochloric acid

Abstract

The invention belongs to the technical field of industrial hydrochloric acid preparation, particularly relates to a three-in-one synthesis furnace and process for byproduct steam hydrochloric acid, and aims to solve the problem of energy and process waste caused by the fact that electrolyzed chlorine needs a complicated drying procedure during hydrochloric acid synthesis in the prior art. Comprising a main barrel structure which is consistent in upper diameter and lower diameter and integrally of a cylindrical structure, the main barrel structure comprises a sealing base plate, a combustion bottom barrel with a downward opening is fixed to the upper surface of the sealing base plate, a gas gathering cover is embedded in the middle of the top of the combustion bottom barrel, and a combustor is fixed to the middle of the combustion bottom barrel; a middle barrel is fixed to the top end of the combustion bottom barrel, and an annular partition strip is reserved in the position, close to the bottom, of the circumferential inner wall of the middle barrel. According to the invention, chlorine dried by dilute sulfuric acid is pressurized, then is introduced into the sulfuric acid drying barrel for final drying, and then is introduced into the burner at the bottom, so that dry and pure chlorine can be obtained, and the reaction efficiency is improved.

Description

Technical Field

[0001] The invention relates to the technical field of industrial hydrochloric acid preparation, and in particular to a three-in-one synthesis furnace and process for by-product steam hydrochloric acid. Background Art

[0002] Hydrochloric acid is the common name for aqueous solution of hydrogen chloride, which is a monobasic inorganic strong acid and an extremely important industrial raw material. When synthesizing industrial hydrochloric acid, firstly, hydrogen and chlorine generated after electrolysis are passed through a quartz burner in a hydrochloric acid synthesis furnace and ignited to generate hydrogen chloride gas, which is then absorbed by water after cooling to become hydrochloric acid. During the hydrochloric acid synthesis process in a hydrochloric acid synthesis furnace, there is often a certain amount of moisture in the chlorine after electrolysis. If it is directly passed into the mixed combustion, it will not only lead to incomplete combustion, but also cause certain safety hazards.

[0003] After searching, it is found that in the prior art, a drying tower is usually required to dry the chlorine before it is passed into the combustion section for combustion. However, water vapor in the air is everywhere, and the chlorine gas coming out of the drying tower still has a distance to reach the combustion section. Therefore, we propose a new industrial hydrochloric acid synthesis furnace that integrates heating, drying, generation, cooling and absorption to improve synthesis efficiency and energy consumption. Summary of the invention

[0004] In view of the technical problem in the prior art that the chlorine after electrolysis in the synthesis of hydrochloric acid requires a complicated drying procedure, resulting in waste of energy and process, the present invention adopts the following technical solution: A three-in-one synthesis furnace for hydrochloric acid with by-product steam comprises a main barrel structure with consistent upper and lower diameters and an overall cylindrical structure, the main barrel structure comprises a sealed bottom plate, a combustion bottom barrel with an opening downward is fixed on the upper surface of the sealed bottom plate, a gas gathering hood is embedded in the middle of the top of the combustion bottom barrel, a burner is fixed in the middle of the combustion bottom barrel, an intermediate barrel is fixed on the top of the combustion bottom barrel, and an annular baffle strip is reserved on the circumferential inner wall of the intermediate barrel near the bottom, and a fixed support plate is sealed and fixed on the upper surface of the annular baffle strip, a sulfuric acid drying barrel is fixed on the upper surface of the fixed support plate, and a piston gas barrel extending into the top of the gas gathering hood is provided on the right side of the intermediate barrel below the annular baffle strip, a three-way air intake valve pipe is fixed on the circumferential outer wall of the piston gas barrel near the bottom of the barrel, and two inlets of the three-way air intake valve pipe are fixed with two spiral air pipes twisted together. , one end of the spiral air pipe away from the piston air barrel is plugged and connected to the side wall of the gas gathering hood; the top of the combustion bottom barrel and the lower surface of the fixed support plate form a closed cold water-deficient chamber; a three-way air outlet valve pipe is fixed at the bottom of the piston air barrel, and the two air outlet holes of the three-way air outlet valve pipe are fixed with connecting pipes inserted into the bottom of the hydrochloric acid synthesis barrel and connected with the inside of the hydrochloric acid synthesis barrel; a semicircular support plate is fixed to the inner wall of the circumference of the intermediate barrel near the top third, and a sulfuric acid drying barrel is fixed on the upper surface of the semicircular support plate, the sulfuric acid drying barrel is filled with concentrated sulfuric acid, and the upper and lower ends of the sulfuric acid drying barrel are respectively plugged with a second conveying pipe and an air delivery pipe 1; a top barrel is fixed to the top of the intermediate barrel, a dilute sulfuric acid drying mechanism is arranged inside the top barrel, and an L-shaped charging mechanism is embedded in the bottom of the top barrel, and a raw material chlorine gas inlet pipe is plugged into the side of the top barrel near the top.

[0005] Preferably, a spoke rod is fixed to the outer wall of the burner, and one end of the spoke rod away from the burner is fixed on the circumferential inner wall of the combustion bottom barrel; a hydrogen pipe is arranged on the side of the burner close to the second delivery pipe; and the hydrogen pipe has the same diameter as the second delivery pipe, and one end of the second delivery pipe away from the sulfuric acid drying barrel is inserted into the combustion bottom barrel and connected to the input end of the burner; by arranging the burner at the bottom, the second delivery pipe is prevented from being empty, ensuring that there is a continuous supply of dried chlorine gas in the second delivery pipe, and ensuring that the reaction continues.

[0006] Preferably, a circular hole with a diameter matching the outer diameter of the piston cylinder is opened below the intermediate cylinder near the annular spacer strip, and a piston disk is slidably connected in the piston cylinder, and a reciprocating push rod is fixed to the middle side of the piston disk away from the bottom of the barrel; and a reciprocating propulsion mechanism is provided on the outer wall of the intermediate cylinder near the barrel mouth of the piston cylinder, and a water pipe hole is opened near the bottom end of the intermediate barrel near the rear side for inserting a cooling water circulation pipe.

[0007] Preferably, a baffle cover is provided at the top of the hydrochloric acid synthesis barrel, and a sliding bearing is embedded in the middle of the baffle cover, a long rotating shaft extending vertically to the bottom of the hydrochloric acid synthesis barrel is rotatably connected in the sliding bearing, and a sealed rotating partition is fixed to the outer wall of the long rotating shaft, the sealed rotating partition divides the interior of the hydrochloric acid synthesis barrel into two, and a finished hydrochloric acid discharge pipe is provided at the bottom of the hydrochloric acid synthesis barrel away from the two connecting pipes; the two connecting pipes and the finished hydrochloric acid discharge pipe are not in the same semicircle, and a water supply pipe is provided directly above the hydrochloric acid synthesis barrel on the same side as the finished hydrochloric acid discharge pipe.

[0008] Preferably, an angle pointer is fixed near the top of the circumferential outer wall of the long rotating shaft, and the direction of the angle pointer is consistent with the direction of the sealed rotating baffle, a driven pulley is fixed to the top of the long rotating shaft, and a double belt through hole at the same height as the driven pulley is opened near the middle of the rear side of the intermediate cylinder, an insulating motor seat is fixed above the outer wall of the intermediate cylinder near the double belt through hole, and a servo motor is fixed on the surface of the insulating motor seat, and a driving pulley is fixed to the top of the output shaft of the servo motor, and the same driving belt is wound between the driving pulley and the driven pulley; the remote control solution replacement can be realized by setting the driving belt.

[0009] Preferably, an observation window is provided near the middle of the front side of the intermediate cylinder, and the position of the observation window is between the semicircular support plate and the baffle cover, so as to more clearly confirm the position of the angle pointer, and then obtain the rotation angle of the sealing rotating partition, so as to ensure that the discharge and filling of hydrochloric acid are more accurate.

[0010] Preferably, the dilute sulfuric acid drying mechanism further comprises a top cover fixed to the top of the top barrel, and a sealed bearing is embedded in the middle of the top cover, a vertical transmission pipe is rotatably connected in the sealed bearing, and the top of the transmission pipe is connected to the dilute sulfuric acid inlet pipe; the bottom end of the transmission pipe is fixedly connected to a swinging sprayer extending horizontally toward the circumferential edge of the top barrel, and a connecting driving plate is fixed to one end of the swinging sprayer close to the rotation center, and a nozzle is fixed to the bottom end of the connecting driving plate, and a connecting hose is connected between the nozzle and the pipe opening of the raw material chlorine inlet pipe; a swing gear is fixedly sleeved at the top of the transmission pipe, and a swing driving box matched with the swing gear is provided on the upper surface of the top cover; an externally threaded pipe connected to the sulfuric acid drying barrel below is screwed to the bottom of the top barrel, and a plurality of support rods are provided at the top of the externally threaded pipe, and the same cap is fixed to the top of the support rod, and a packing layer is provided at the top of the cap, so that the dilute sulfuric acid can be oscillated and sprayed in the top barrel for full contact during use, thereby improving the initial drying efficiency of the chlorine.

[0011] Preferably, a second circular hole is formed at the bottom of the top barrel away from the external threaded tube, and a secondary perforation matching the second circular hole is formed on the right side of the middle barrel near the top, a rubber clamp is clamped in the secondary perforation, and the same L-shaped curved barrel is inserted between the rubber clamp and the second circular hole, the opening of the L-shaped curved barrel faces downward, and the L-shaped inflation mechanism also includes an annular bamboo hat sleeved on the top of the L-shaped curved barrel, a plurality of one-way air intake valves are embedded near the top of the circumferential outer wall of the L-shaped curved barrel, and the one-way air intake valve includes an inclined outer tube, a spring stopper is fixed in the middle of the inner part of the outer tube, a reset spring is fixed to the top of the spring stopper, and a sealing stopper for sealing the top tube opening of the outer tube is fixed to the top of the reset spring. The inner wall of the straight tube at the top of the L-shaped curved barrel is slidably connected with an anti-twist piston disc, and a push-in spring for pushing and pulling is fixed to the bottom end of the anti-twist piston disc, a push-in spring is fixed to the bottom end of a push-in spring, and two symmetrical windproof and anti-skid bumps are fixed to the outer wall of the push-in spring, a guide rail matched with the anti-skid bumps is fixed to the inner wall of the straight tube at the bottom of the L-shaped curved barrel, a buffer block is arranged on the inner wall at the corner of the L-shaped curved barrel to assist the push-in spring in pushing, and a steel wire is also arranged between the lower surface of the anti-twist piston disc and the second push-in rod; and a one-way air outlet valve is arranged at the top of the L-shaped curved barrel, and the end of the air supply pipe away from the sulfuric acid drying barrel is plugged into the top of the one-way air outlet valve.

[0012] Preferably, the interior of the sulfuric acid drying barrel is provided with a zigzag partition with cross-engaging distribution points, the end of the air delivery pipe one away from the L-shaped curved barrel is inserted above the bottom last zigzag partition, the side wall of the intermediate barrel is provided with a sulfuric acid replenishing pipe plug hole near the rear side, and the sulfuric acid replenishing pipe plug hole is plugged with a sulfuric acid replenishing pipe extending to the bottom end of the sulfuric acid drying barrel; the reciprocating propulsion mechanism also includes a conveying frame fixed to the outer wall of the intermediate barrel and located between the L-shaped curved barrel and the piston gas barrel, and the conveying frame is in an "I"-shaped structure as a whole, and conveying wheels are arranged at the four corners of the conveying frame, and the same toothed conveyor belt is wound between the four conveying wheels, and the toothed conveyor belt is fixedly connected to the reciprocating push rod one and the push rod two at the same time, and forms movement in opposite directions, and a connecting rod and a reduction motor are arranged on the side of the toothed conveyor belt away from the intermediate barrel, and a propulsion wheel that is rotatably connected to the connecting rod is fixed to the top end of the output shaft of the reduction motor.

[0013] A three-in-one synthesis process of by-product steam hydrochloric acid comprises the following steps: S1: When in use, the chlorine obtained by electrolysis is introduced into the top barrel through the raw chlorine inlet pipe at the top for preliminary dilute sulfuric acid spray drying. Fillers are placed in the top barrel. At this time, the raw chlorine is spread under the action of the moving swing sprayer and is dried in contact with a large amount of dilute sulfuric acid; At this time, the reduction motor in the reciprocating propulsion mechanism is started again, and the L-shaped charging mechanism is used to form a power to pump and pressurize the chlorine gas that has been dried for the first time. At this time, the chlorine gas that has been sprayed and dried by dilute sulfuric acid is passed through the gas pipe 1 to the sulfuric acid drying barrel for full drying, and then enters the burner at the bottom through the second delivery pipe connected to the top, and is mixed and burned with the hydrogen gas that enters together; S2: The HCL gas generated after combustion is temporarily stored in the gas collecting hood, and the HCL gas is drawn into the spiral gas pipe under the rapid extraction of the piston, and passes through the cooling water area to be cooled to the optimal temperature, and then introduced into the hydrochloric acid synthesis barrel; Before the synthesis, the sealing rotating baffle is rotated in a forward and backward direction to ensure that the outlets of the two connecting pipes are on the same side of the sealing rotating baffle; S3: When the concentration of hydrochloric acid reaches the set value, start the servo motor on the rear side to rotate the pure water to the upper position of the two connecting pipes. At this time, the hydrochloric acid that has reached the standard concentration can be easily pushed to the finished hydrochloric acid discharge pipe, and then the valve can be opened to discharge it. After discharge, fill it with pure water for next use. The whole process can release the finished product and add pure water without stopping the machine.

[0014] The beneficial effects of the present invention are: 1. Through the L-shaped charging mechanism, the chlorine gas dried by dilute sulfuric acid can be pressurized and then passed into the sulfuric acid drying barrel for final drying, and then passed into the burner at the bottom to obtain dry and pure chlorine gas, thereby improving the reaction efficiency.

[0015] 2. Through the sealed rotating baffle, when the hydrochloric acid reaches the required concentration during use, the pure water can be rotated to the upper position of the two connecting pipes. At this time, the hydrochloric acid that has reached the standard concentration can be easily pushed to the finished hydrochloric acid discharge pipe, and then the valve can be opened to discharge it. After discharge, it can be filled with pure water for the next use. The whole process can be released without stopping the machine and pure water can be added.

[0016] 3. By controlling the reciprocating advance of the second push rod, the chlorine gas sucked into the anti-twist piston disc can be continuously pressurized, and then the chlorine gas can be continuously introduced into the sulfuric acid drying barrel; in conjunction with the toothed conveyor belt, the L-shaped charging mechanism and the piston gas barrel can be driven to operate synchronously, and then power output can be provided for the operation of the internal chlorine gas and HCL gas. BRIEF DESCRIPTION OF THE DRAWINGS

[0017] Figure 1 This is a schematic diagram of the overall structure of a three-in-one synthesis furnace for hydrochloric acid with by-product steam proposed by the present invention; Figure 2 A side view of a three-in-one hydrochloric acid synthesis furnace with by-product steam proposed by the present invention; Figure 3 A three-in-one synthesis furnace for hydrochloric acid with by-product steam proposed by the present invention Figure 2 Schematic diagram of the cross-sectional structure along line AA; Figure 4 This is a schematic structural diagram of a hydrochloric acid synthesis barrel and a sulfuric acid drying barrel inside a three-in-one synthesis furnace for hydrochloric acid with by-product steam proposed by the present invention; Figure 5 It is a schematic cross-sectional view of the structure of a one-way air inlet valve 1 in a three-in-one synthesis furnace for hydrochloric acid with by-product steam proposed by the present invention; Figure 6 A schematic diagram of a half-cut three-dimensional structure of a main barrel structure of a three-in-one synthesis furnace for hydrochloric acid with by-product steam proposed by the present invention; Figure 7 This is a schematic cross-sectional view of the sulfuric acid drying barrel of a three-in-one synthesis furnace for hydrochloric acid with by-product steam proposed by the present invention; Figure 8 It is a cross-sectional structural schematic diagram of an L-shaped charging mechanism in a three-in-one synthesis furnace for hydrochloric acid with by-product steam proposed by the present invention; Fig. 9 A schematic diagram of the top view of the hydrochloric acid synthesis mechanism in a three-in-one synthesis furnace for hydrochloric acid with by-product steam proposed by the present invention; Fig.10 The present invention provides a schematic cross-sectional structural diagram of a hydrochloric acid synthesis mechanism of a three-in-one synthesis furnace for hydrochloric acid with by-product steam.

[0018] In the figure: 1. Sealed bottom plate; 2. Combustion bottom barrel; 3. Hydrogen pipe; 4. Intermediate barrel; 401. Secondary perforation; 402. Double belt perforation; 403. Round hole one; 404. Water pipe hole; 405. Annular baffle strip; 406. Sulfuric acid supplement pipe jack; 5. Second delivery pipe; 6. Observation window; 7. Gas delivery pipe one; 8. Swinging gear; 9. Dilute sulfuric acid inlet pipe; 10. Top cover; 11. Raw material chlorine inlet pipe; 12. Top barrel; 1201. Round hole two; 13. Rubber snap ring; 14. L-shaped inflation mechanism; 141. Annular bamboo hat; 142. One-way air inlet valve one; 143. Spring stopper; 144. Reset tension spring; 145. Sealed stopper; 146. Push rod two; 147. Buffer block; 148. Push spring; 149. Anti-twist piston disc; 15 , guide rail; 16, toothed conveyor belt; 17, conveyor frame; 18, connecting rod; 19, propulsion wheel; 20, reduction motor; 21, reciprocating push rod; 22, piston gas cylinder; 2201, connecting pipe; 23, cooling water circulation pipe; 24, finished hydrochloric acid discharge pipe; 25, swing drive box; 26, servo motor; 27, driving belt; 28, gas hood; 29, spiral air pipe; 30, fixed support plate; 31, connecting hose; 32, swing sprayer; 33, cap; 34, external threaded pipe; 35, semicircular support plate; 36, sulfuric acid drying barrel; 361, sulfuric acid replenishment pipe; 362, zigzag partition; 37, sealed rotating partition; 38, long rotating shaft; 3801, angle pointer; 39, burner; 40, hydrochloric acid synthesis barrel; 41, baffle. DETAILED DESCRIPTION

[0019] The technical solutions in the embodiments of the present invention will be described clearly and completely below in conjunction with the drawings in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, rather than all the embodiments.

[0020] In the present invention, reference is made to Figure 1-10A three-in-one synthesis furnace for by-product steam hydrochloric acid, comprising a main barrel structure with the same upper and lower diameters and an overall cylindrical structure, the main barrel structure comprising a sealed bottom plate 1 fixed horizontally to the ground and an overall disc-shaped structure, a combustion bottom barrel 2 with an opening downward is sealed and fixed on the upper surface of the sealed bottom plate 1, a gas collecting hood 28 with an opening downward is embedded in the middle of the top of the combustion bottom barrel 2, and a burner 39 is fixed in the middle of the combustion bottom barrel 2; it is used to burn mixed hydrogen and chlorine, an intermediate barrel 4 is fixed on the top of the combustion bottom barrel 2, and an annular baffle strip 405 is reserved on the circumferential inner wall of the intermediate barrel 4 near the bottom at one-third of the height, and the upper surface of the annular baffle strip 405 A fixed support plate 30 is sealed and fixed, a sulfuric acid drying barrel 36 is fixed on the upper surface of the fixed support plate 30, and a piston gas barrel 22 is arranged on the right side of the middle cylinder 4 below the annular baffle strip 405, which extends horizontally into the top of the gas hood 28. A three-way air intake valve pipe is fixed to the circumferential outer wall of the piston gas barrel 22 near the bottom of the barrel, and two inlets of the three-way air intake valve pipe are fixed with two twisted spiral air pipes 29, and one end of the spiral air pipe 29 away from the piston gas barrel 22 is plugged and connected to the side wall of the gas hood 28; the top of the combustion bottom barrel 2 and the lower surface of the fixed support plate 30 form a closed cold water-deficient chamber; it is used to keep the combusted gas away from the cold for a long time. After being fully cooled, the piston cylinder 22 is contacted with water and then melted into water at the optimal temperature to improve the synthesis efficiency. A three-way air outlet valve pipe is fixed at the bottom of the piston cylinder 22, and the two air outlet holes of the three-way air outlet valve pipe are fixed with a connecting pipe 2201 inserted into the bottom of the hydrochloric acid synthesis barrel 40 and connected to the inside of the hydrochloric acid synthesis barrel 40; controlling the operation of the piston cylinder 22 can accelerate the gas generated in the gas hood 28 to be transported into the hydrochloric acid synthesis barrel 40, thereby accelerating the dissolution of hydrochloric acid gas and water and improving the fusion efficiency; a semicircular support plate 35 is fixed to the inner wall of the circumference of the intermediate cylinder 4 near the top one-third, and a sulfuric acid dry The drying barrel 36 is filled with concentrated sulfuric acid, and the upper and lower ends of the sulfuric acid drying barrel 36 are respectively connected with a second conveying pipe 5 and a gas conveying pipe 7; a top barrel 12 is fixed to the top of the intermediate cylinder 4, and a dilute sulfuric acid drying mechanism is arranged inside the top barrel 12, and an L-shaped charging mechanism 14 is embedded at the bottom of the top barrel 12, and a raw material chlorine gas inlet pipe 11 is connected to the side of the top barrel 12 near the top; through the L-shaped charging mechanism 14, the chlorine gas dried by dilute sulfuric acid can be pressurized and then introduced into the sulfuric acid drying barrel 36 for final drying, and then introduced into the burner 39 at the bottom to obtain dry and pure chlorine gas, thereby improving the reaction efficiency.

[0021] Reference Figure 3A spoke rod is fixed to the outer wall of the burner 39, and one end of the spoke rod away from the burner 39 is fixed to the circumferential inner wall of the combustion bottom barrel 2; a hydrogen pipe 3 is arranged on the side of the burner 39 close to the second delivery pipe 5; and the hydrogen pipe 3 has the same diameter as the second delivery pipe 5, and one end of the second delivery pipe 5 away from the sulfuric acid drying barrel 36 is inserted into the combustion bottom barrel 2 and connected to the input end of the burner 39; by setting the burner 39 at the bottom, the second delivery pipe 5 is prevented from being empty, ensuring that the second delivery pipe 5 can have a continuous supply of dried chlorine gas to ensure the continuous reaction.

[0022] Reference Figure 3 and Figure 6 A circular hole 403 with a diameter matching the outer diameter of the piston cylinder 22 is opened below the middle cylinder 4 near the annular baffle strip 405, and a piston disk is slidably connected in the piston cylinder 22, and a reciprocating push rod 21 is fixed to the middle side of the piston disk away from the bottom of the barrel; and a reciprocating propulsion mechanism is provided on the outer wall of the middle cylinder 4 near the barrel mouth of the piston cylinder 22, and a water pipe hole 404 is opened near the bottom end of the middle barrel 4 near the rear side for inserting the cooling water circulation pipe 23.

[0023] Reference Figure 3 , Figure 4 and Fig.10 A stop cover 41 is provided at the top of the hydrochloric acid synthesis barrel 40, and a sliding bearing is embedded in the middle of the stop cover 41. A long rotating shaft 38 extending vertically to the bottom of the hydrochloric acid synthesis barrel 40 is rotatably connected in the sliding bearing, and a sealed rotating partition 37 is fixed to the outer wall of the long rotating shaft 38. The sealed rotating partition 37 divides the interior of the hydrochloric acid synthesis barrel 40 into two parts, and a finished hydrochloric acid discharge pipe 24 is provided at the bottom of the hydrochloric acid synthesis barrel 40 away from the two connecting pipes 2201; the two connecting pipes 2201 are not in the same In a semicircle, a water supply pipe is arranged above the hydrochloric acid synthesis barrel 40 on the same side as the finished hydrochloric acid discharge pipe 24; by means of the sealed rotating baffle 37, when in use, after the hydrochloric acid reaches the required concentration, the pure water can be rotated to the upper position of the two connecting pipes 2201. At this time, the hydrochloric acid that has reached the standard concentration can be easily pushed to the finished hydrochloric acid discharge pipe 24, and then the valve can be opened to discharge it. After discharge, it can be filled with pure water for next use. The whole process can be released and pure water can be added without stopping the machine.

[0024] Reference Figure 4 , Fig. 9 and Fig.10An angle pointer 3801 is fixed near the top of the circumferential outer wall of the long rotating shaft 38, and the direction of the angle pointer 3801 is consistent with the direction of the sealed rotating partition 37. A driven pulley is fixed to the top of the long rotating shaft 38, and a double belt through hole 402 with the same height as the driven pulley is opened near the middle of the rear side of the intermediate cylinder 4. An insulating motor seat is fixed above the outer wall of the intermediate cylinder 4 near the double belt through hole 402, and a servo motor 26 is fixed on the surface of the insulating motor seat, and a driving pulley is fixed to the top of the output shaft of the servo motor 26, and the same driving belt 27 is wound between the driving pulley and the driven pulley; the remote control solution replacement can be realized by setting the driving belt 27.

[0025] Reference Figure 1 and Figure 3 and Figure 4 An observation window 6 is provided near the middle of the front of the intermediate cylinder 4, and the position of the observation window 6 is between the semicircular support plate 35 and the blocking cover 41, so as to more clearly confirm the position of the angle pointer 3801, and then obtain the rotation angle of the sealing rotating partition 37, so as to ensure that the discharge and filling of hydrochloric acid are more accurate.

[0026] Reference Figure 2 and Figure 3 The dilute sulfuric acid drying mechanism also includes a top cover 10 fixed to the top of the top barrel 12, and a sealed bearing is embedded in the middle of the top cover 10, a vertical transmission pipe is rotatably connected in the sealed bearing, and the top of the transmission pipe is connected to the dilute sulfuric acid inlet pipe 9; the bottom end of the transmission pipe is fixedly connected to a swinging sprayer 32 extending horizontally toward the circumferential edge of the top barrel 12, and a connecting driving plate is fixed to one end of the swinging sprayer 32 close to the rotation center, and a nozzle is fixed to the bottom end of the connecting driving plate, and a connecting nozzle is connected to the nozzle and the pipe mouth of the raw material chlorine gas inlet pipe 11. Hose 31; a swing gear 8 is fixedly sleeved on the top of the transmission pipe, and a swing driving box 25 matched with the swing gear 8 is provided on the upper surface of the top cover 10; an external threaded pipe 34 connected to the sulfuric acid drying barrel 36 below is screwed on the bottom of the top barrel 12, and a plurality of support rods are provided on the top of the external threaded pipe 34, and a cap 33 is fixed on the top of the support rod, and a packing layer is provided on the top of the cap 33, so that dilute sulfuric acid can be swung and sprayed into the top barrel 12 for full contact during use, thereby improving the initial drying efficiency of chlorine.

[0027] Reference Figure 5-6 and Figure 8A second circular hole 1201 is formed at the bottom of the top barrel 12 away from the external threaded tube 34, and a secondary perforation 401 matching the second circular hole 1201 is formed on the right side of the middle barrel 4 near the top, a rubber clamping ring 13 is clamped in the secondary perforation 401, and the same L-shaped curved barrel is inserted between the rubber clamping ring 13 and the second circular hole 1201, the opening of the L-shaped curved barrel faces downward, and the L-shaped inflation mechanism 14 also includes an annular bamboo hat 141 sleeved on the top of the L-shaped curved barrel, a plurality of one-way air intake valves 142 are embedded near the top of the circumferential outer wall of the L-shaped curved barrel, and the one-way air intake valve 142 includes an inclined outer tube, a spring stopper 143 is fixed in the middle of the inner part of the outer tube, a reset spring 144 is fixed to the top of the spring stopper 143, and a sealing stopper 145 for blocking the top pipe opening of the outer tube is fixed to the top of the reset spring 144; an anti-twist piston disc is slidably connected to the inner wall of the straight tube part at the top of the L-shaped curved barrel 149, and the bottom end of the anti-twist piston disc 149 is fixed with a push-in spring 148 for pushing and pulling, the bottom end of the push-in spring 148 is fixed with a push rod 146, and the outer wall of the push rod 146 is fixed with two mutually symmetrical windproof and anti-skid protrusions, the inner wall of the bottom straight tube of the L-shaped curved barrel is fixed with a guide rail 15 adapted to the anti-skid protrusions, and the inner wall at the corner of the L-shaped curved barrel is provided with a buffer block 147 to assist the push-in spring 148 in pushing, and a steel wire is also provided between the lower surface of the anti-twist piston disc 149 and the push rod 146; and a one-way air outlet valve 1 is provided at the top of the L-shaped curved barrel, and the end of the air supply pipe 17 away from the sulfuric acid drying barrel 36 is plugged into the top of the one-way air outlet valve 1; by controlling the reciprocating advancement of the push rod 146, the chlorine gas sucked into the top of the anti-twist piston disc 149 can be continuously pressurized, and then the chlorine gas is continuously introduced into the interior of the sulfuric acid drying barrel 36.

[0028] Reference Figure 1 , Figure 3 and Figure 7The interior of the sulfuric acid drying barrel 36 is provided with a zigzag partition 362 with cross-engaging distribution points, and the end of the gas transmission pipe 7 away from the L-shaped curved barrel is inserted above the bottom last zigzag partition 362, and the side wall of the intermediate barrel 4 is provided with a sulfuric acid replenishing pipe plug hole 406 near the rear side, and the sulfuric acid replenishing pipe plug hole 406 is plugged with a sulfuric acid replenishing pipe 361 extending to the bottom end of the sulfuric acid drying barrel 36; the reciprocating propulsion mechanism also includes a conveying frame 17 fixed to the outer wall of the intermediate barrel 4 and located between the L-shaped curved barrel and the piston gas barrel 22, and the conveying frame 17 is an "I"-shaped structure as a whole, and the conveying frame 17 Transmission wheels are arranged at the four corners, and the same toothed conveyor belt 16 is wound between the four transmission wheels. The toothed conveyor belt 16 is fixedly connected to the reciprocating push rod 1 21 and the push rod 2 146 at the same time, and forms opposite direction movement. A connecting rod 18 and a reduction motor 20 are arranged on the side of the toothed conveyor belt 16 away from the intermediate cylinder 4, and a propulsion wheel 19 is fixed on the top of the output shaft of the reduction motor 20 to form a rotation connection with the connecting rod 18; the toothed conveyor belt 16 can synchronously drive the L-shaped inflation mechanism 14 and the piston cylinder 22 to operate, thereby providing power output for the operation of the internal chlorine gas and HCL gas.

[0029] A three-in-one synthesis process of by-product steam hydrochloric acid comprises the following steps: S1: When in use, the chlorine obtained by electrolysis is introduced into the top barrel 12 through the raw chlorine inlet pipe 11 at the top for preliminary dilute sulfuric acid spray drying. A filler is placed in the top barrel 12. At this time, the raw chlorine is spread under the action of the moving swing sprayer 32 and is dried in contact with a large amount of dilute sulfuric acid; At this time, the reduction motor 20 in the reciprocating propulsion mechanism is started again, and the L-shaped charging mechanism 14 forms a power to pump and pressurize the chlorine gas that has been dried for the first time. At this time, the chlorine gas that has been sprayed and dried by dilute sulfuric acid is passed through the gas pipe 7 to the sulfuric acid drying barrel 36 for full drying, and then enters the burner 39 at the bottom through the second delivery pipe 5 connected to the top, and is mixed and burned with the hydrogen gas that enters together; S2: The HCL gas generated after combustion is temporarily stored in the gas collecting hood 28, and the HCL gas is sucked into the spiral gas pipe 29 under the rapid extraction of the piston 22, and passes through the cooling water area to be cooled to the optimal temperature, and then introduced into the hydrochloric acid synthesis barrel 40; Before the synthesis, the sealing rotating partition 37 is rotated in a forward and backward direction to ensure that the outlets of the two connecting pipes 2201 are on the same side of the sealing rotating partition 37; S3: When the concentration of hydrochloric acid reaches the set value, start the servo motor 26 on the rear side to rotate the pure water to the upper position of the two connecting pipes 2201. At this time, the hydrochloric acid that has reached the standard concentration can be easily pushed to the finished hydrochloric acid discharge pipe 24, and then the valve can be opened to discharge it. After discharge, fill it with pure water for next use. The whole process can release the finished product and add pure water without stopping.

[0030] The above description is only a preferred specific implementation manner of the present invention, but the protection scope of the present invention is not limited thereto. Any technician familiar with the technical field can make equivalent replacements or changes according to the technical scheme and inventive concept of the present invention within the technical scope disclosed by the present invention, which should be covered by the protection scope of the present invention.

Claims

1. A three-in-one synthesis furnace for hydrochloric acid with byproduct steam, comprising a main barrel structure with the same upper and lower diameters and an overall cylindrical structure, the main barrel structure comprising a sealed bottom plate (1), a combustion bottom barrel (2) with an opening facing downward fixed on the upper surface of the sealed bottom plate (1), a gas collecting hood (28) embedded in the middle of the top of the combustion bottom barrel (2), and a burner (39) fixed in the middle of the combustion bottom barrel (2); characterized in that: The top of the combustion bottom barrel (2) is fixed with an intermediate barrel (4), and an annular baffle strip (405) is reserved near the bottom of the circumferential inner wall of the intermediate barrel (4), and a fixed support plate (30) is sealed and fixed on the upper surface of the annular baffle strip (405), and a sulfuric acid drying barrel (36) is fixed on the upper surface of the fixed support plate (30), and a piston gas barrel (22) extending into the top of the gas gathering hood (28) is arranged on the right side of the intermediate barrel (4) below the annular baffle strip (405), and a three-way air intake valve pipe is fixed near the bottom of the circumferential outer wall of the piston gas barrel (22), and two inlets of the three-way air intake valve pipe are fixed with two twisted spiral air pipes (29), and one end of the spiral air pipe (29) away from the piston gas barrel (22) is plugged and connected to the side wall of the gas gathering hood (28); the top of the combustion bottom barrel (2) and the lower surface of the fixed support plate (30) form a closed cold water-deficient chamber; A three-way air outlet valve pipe is fixed at the bottom of the piston gas barrel (22), and two air outlet holes of the three-way air outlet valve pipe are fixed with a connecting pipe (2201) inserted into the bottom of the hydrochloric acid synthesis barrel (40) and connected to the inside of the hydrochloric acid synthesis barrel (40); a semicircular support plate (35) is fixed to the inner wall of the circumference of the intermediate barrel (4) near the top third, and a sulfuric acid drying barrel (36) is fixed on the upper surface of the semicircular support plate (35), the sulfuric acid drying barrel (36) is filled with concentrated sulfuric acid, and the upper and lower ends of the sulfuric acid drying barrel (36) are respectively plugged with a second delivery pipe (5) and a gas delivery pipe 1 (7); a top barrel (12) is fixed to the top of the intermediate barrel (4), a dilute sulfuric acid drying mechanism is arranged inside the top barrel (12), and an L-shaped charging mechanism (14) is embedded in the bottom of the top barrel (12), and a raw material chlorine gas inlet pipe (11) is plugged into the side of the top barrel (12) near the top.

2. A three-in-one synthesis furnace for hydrochloric acid with byproduct steam according to claim 1, characterized in that: A spoke rod is fixed to the outer wall of the burner (39), and one end of the spoke rod away from the burner (39) is fixed to the circumferential inner wall of the combustion bottom barrel (2); a hydrogen pipe (3) is arranged on the side of the burner (39) close to the second delivery pipe (5); and the hydrogen pipe (3) and the second delivery pipe (5) have the same diameter, and one end of the second delivery pipe (5) away from the sulfuric acid drying barrel (36) is inserted into the combustion bottom barrel (2) and connected to the input end of the burner (39).

3. A three-in-one synthesis furnace for hydrochloric acid with byproduct steam according to claim 2, characterized in that: A circular hole (403) having a diameter matching the outer diameter of the piston cylinder (22) is formed on the intermediate cylinder (4) below the annular spacer strip (405), and a piston disc is slidably connected to the piston cylinder (22), and a reciprocating push rod (21) is fixed to the middle side of the piston disc away from the bottom of the cylinder; a reciprocating propulsion mechanism is provided on the outer wall of the intermediate cylinder (4) near the barrel mouth of the piston cylinder (22), and a water pipe hole (404) is formed near the bottom end of the rear side of the intermediate cylinder (4) for inserting a cooling water circulation pipe (23).

4. A three-in-one synthesis furnace for hydrochloric acid with byproduct steam according to claim 3, characterized in that: A stop cover (41) is provided at the top of the hydrochloric acid synthesis barrel (40), and a sliding bearing is embedded in the middle of the stop cover (41). A long rotating shaft (38) extending vertically toward the bottom of the hydrochloric acid synthesis barrel (40) is rotatably connected to the sliding bearing, and a sealed rotating partition (37) is fixed to the outer wall of the long rotating shaft (38). The sealed rotating partition (37) divides the interior of the hydrochloric acid synthesis barrel (40) into two parts, and a finished hydrochloric acid discharge pipe (24) is provided at the bottom of the hydrochloric acid synthesis barrel (40) away from the two connecting pipes (2201); the two connecting pipes (2201) and the finished hydrochloric acid discharge pipe (24) are not in the same semicircle, and a water supply pipe is provided on the hydrochloric acid synthesis barrel (40) directly above the same side as the finished hydrochloric acid discharge pipe (24).

5. A three-in-one synthesis furnace for hydrochloric acid with byproduct steam according to claim 4, characterized in that: An angle pointer (3801) is fixed near the top of the circumferential outer wall of the long rotating shaft (38), and the direction of the angle pointer (3801) is consistent with the direction of the sealed rotating partition (37). A driven pulley is fixed at the top of the long rotating shaft (38), and a double belt through hole (402) is opened near the middle of the rear side of the intermediate cylinder (4) at the same height as the driven pulley. An insulating motor base is fixed above the double belt through hole (402) on the outer wall of the intermediate cylinder (4), and a servo motor (26) is fixed on the surface of the insulating motor base. A driving pulley is fixed at the top of the output shaft of the servo motor (26), and the same driving belt (27) is wound between the driving pulley and the driven pulley.

6. A three-in-one synthesis furnace for hydrochloric acid with byproduct steam according to claim 5, characterized in that: An observation window (6) is provided near the middle of the front side of the intermediate cylinder (4), and the observation window (6) is located between the semicircular support plate (35) and the blocking cover (41).

7. A three-in-one synthesis furnace for hydrochloric acid with byproduct steam according to claim 6, characterized in that: The dilute sulfuric acid drying mechanism further comprises a top cover (10) fixed to the top of the top barrel (12), and a sealed bearing is embedded in the middle of the top cover (10), a vertical transmission pipe is rotatably connected in the sealed bearing, and the top of the transmission pipe is connected to a dilute sulfuric acid inlet pipe (9); the bottom end of the transmission pipe is fixedly connected to a swinging sprayer (32) extending horizontally toward the circumferential edge of the top barrel (12), and a connecting driving plate is fixed to one end of the swinging sprayer (32) close to the rotation center, and a nozzle is fixed to the bottom end of the connecting driving plate, and the nozzle is connected to A connecting hose (31) is connected between the pipe openings of the raw material chlorine gas inlet pipe (11); a swing gear (8) is fixedly sleeved on the top of the transmission pipe, and a swing drive box (25) matched with the swing gear (8) is arranged on the upper surface of the top cover (10); an externally threaded pipe (34) connected to a sulfuric acid drying barrel (36) below is screwed to the bottom of the top barrel (12), and a plurality of support rods are arranged at the top of the externally threaded pipe (34), a cap (33) is fixed to the top of the support rods, and a packing layer is arranged at the top of the cap (33).

8. A three-in-one synthesis furnace for hydrochloric acid with byproduct steam according to claim 7, characterized in that: A second circular hole (1201) is formed at the bottom of the top barrel (12) away from the external threaded tube (34), and a secondary perforation (401) matching the second circular hole (1201) is formed on the right side of the middle barrel (4) near the top end, a rubber clamping ring (13) is clamped in the secondary perforation (401), and an L-shaped curved barrel is inserted between the rubber clamping ring (13) and the second circular hole (1201), the opening of the L-shaped curved barrel faces downward, and the L-shaped inflation mechanism (14) further includes an annular bamboo hat (141) sleeved on the top end of the L-shaped curved barrel, and a plurality of one-way air intake valves (142) are embedded on the circumferential outer wall of the L-shaped curved barrel near the top end, and the one-way air intake valves (142) include an inclined outer tube, and a spring stopper is fixed in the middle of the inner part of the outer tube. (143), the top of the spring stopper (143) is fixed with a reset spring (144), and the top of the reset spring (144) is fixed with a sealing stopper (145) for blocking the top end of the outer tube; the inner wall of the straight tube portion at the top of the L-shaped curved barrel is slidably connected with an anti-twist piston disc (149), and the bottom end of the anti-twist piston disc (149) is fixed with a push-in spring (148) for pushing and pulling, and the bottom end of the push-in spring (148) is fixed with a second push rod (146), and the outer wall of the second push rod (146) is fixed with two mutually symmetrical windproof and anti-skid protrusions, the inner wall of the straight tube at the bottom of the L-shaped curved barrel is fixed with a guide rail (15) adapted to the anti-skid protrusions, and a buffer block (147) is provided on the inner wall of the corner of the L-shaped curved barrel; A steel wire is further provided between the lower surface of the anti-twist piston disc (149) and the second push rod (146); and a one-way air outlet valve (1) is provided at the top of the L-shaped curved barrel, and the end of the air delivery pipe (1) (7) away from the sulfuric acid drying barrel (36) is plugged into the top of the one-way air outlet valve (1).

9. A three-in-one synthesis furnace for hydrochloric acid with byproduct steam according to claim 8, characterized in that: The interior of the sulfuric acid drying barrel (36) is provided with a zigzag partition (362) with cross-engaging distribution points, the end of the gas transmission pipe (7) away from the L-shaped curved barrel is inserted above the bottom last zigzag partition (362), the side wall of the intermediate barrel (4) is provided with a sulfuric acid replenishing pipe insertion hole (406) near the rear side, and the sulfuric acid replenishing pipe (361) extending to the bottom end of the sulfuric acid drying barrel (36) is inserted into the sulfuric acid replenishing pipe insertion hole (406); the reciprocating propulsion mechanism also includes a conveying frame fixed to the outer wall of the intermediate barrel (4) between the L-shaped curved barrel and the piston gas barrel (22) (17), and the overall structure of the conveyor frame (17) is in the shape of an "I" character, and conveyor wheels are arranged at the four corners of the conveyor frame (17), and the same toothed conveyor belt (16) is wound between the four conveyor wheels, and the toothed conveyor belt (16) is fixedly connected to the reciprocating push rod 1 (21) and the push rod 2 (146) at the same time, and forms movement in opposite directions, and the side of the toothed conveyor belt (16) away from the intermediate cylinder (4) is provided with a connecting rod (18) and a reduction motor (20), and the top end of the output shaft of the reduction motor (20) is fixed with a propulsion wheel (19) that is rotatably connected to the connecting rod (18).

10. A three-in-one synthesis process of by-product steam hydrochloric acid, comprising a three-in-one synthesis furnace of by-product steam hydrochloric acid as claimed in claim 9, characterized in that: The following steps are involved: S1: When in use, the chlorine gas obtained by electrolysis is introduced into the top barrel (12) through the raw material chlorine gas inlet pipe (11) at the top to perform preliminary dilute sulfuric acid spray drying. A filler is placed in the top barrel (12). At this time, the raw material chlorine gas is spread under the action of the moving swing sprayer (32) and is dried in contact with a large amount of dilute sulfuric acid; At this time, the reduction motor (20) in the reciprocating propulsion mechanism is started again, and the L-shaped gas charging mechanism (14) generates power to pump and pressurize the chlorine gas that has been dried for the first time. At this time, the chlorine gas that has been sprayed and dried by the dilute sulfuric acid is passed through the gas transmission pipe 1 (7) to the sulfuric acid drying barrel (36) for full drying, and then enters the burner (39) at the bottom end through the second transmission pipe (5) connected to the top end, and is mixed with the hydrogen gas that enters together and burns; S2: The HCL gas generated after combustion is temporarily stored in the gas collecting hood (28), and the HCL gas is sucked into the spiral gas pipe (29) under the rapid extraction of the piston through (22), and passes through the cooling water area to be cooled to the optimal temperature, and then introduced into the hydrochloric acid synthesis barrel (40); Before the synthesis, the sealing rotating baffle (37) is rotated in a forward and backward direction to ensure that the outlets of the two connecting pipes (2201) are on the same side of the sealing rotating baffle (37); S3: When the concentration of hydrochloric acid reaches the set value, the servo motor (26) on the rear side is started to rotate the pure water to the upper position of the two connecting pipes (2201). At this time, the hydrochloric acid that has reached the standard concentration can be easily pushed to the finished hydrochloric acid discharge pipe (24), and then the valve can be opened to discharge it. After discharge, it is filled with pure water for next use. The whole process can be released without stopping the machine and adding pure water.

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