Phosphogypsum on-line monitoring system

By designing an online monitoring system for phosphogypsum and using automated detection technology, the problems of long detection cycle and integrity risks in the existing technology are solved, and the effect of real-time monitoring of product quality and environmental risks is achieved.

CN120142681APending Publication Date: 2025-06-13YUNNAN ZHONGHUAN ZHENGHAO ENVIRONMENTAL TECH CO LTD
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Patent Information

Application Number
CN202510071110.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-01-16
Publication Date
2025-06-13

AI Technical Summary

Technical Problem

Existing phosphogypsum modification testing requires manual sampling and laboratory testing, resulting in a long testing cycle, unable to monitor product quality and environmental risks in real time, and there is a risk of integrity in sample cheating.

Method used

Design a phosphogypsum online monitoring system, including the device main body, phosphogypsum quantizer, deionized water quantizer, robot, operating table, ultra-pure water machine, horizontal oscillator, automatic suction filter, water sample distribution machine and characteristic value measurement machine, to realize the automatic detection of phosphogypsum.

Benefits of technology

It realizes automated detection of phosphogypsum, improves detection efficiency, can monitor product quality and environmental risks in real time, and reduces the drawbacks and integrity risks of manual testing.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention relates to the technical field of ardealite online monitoring, in particular to an ardealite online monitoring system. The device consists of a device main body, an ardealite batcher, a deionized water batcher, a manipulator, an operation table, an ultrapure water machine, a horizontal oscillator, an automatic suction filter, a water sample distributor and a characteristic value determinator, wherein the ardealite batcher is arranged in the device main body. By adopting a series of structures such as the device main body, the ardealite batcher, the deionized water batcher, the manipulator, the operation table, the ultrapure water machine, the horizontal oscillator, the automatic suction filter, the water sample distributor and the characteristic value measuring machine, automatic detection of ardealite can be realized, the detection efficiency is ensured, and the product quality and the environmental risk can be controlled in real time; the defects of manual detection are overcome, and the detection efficiency is improved.
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Description

Technical Field

[0001] The present invention relates to the technical field of on-line monitoring of phosphogypsum, and particularly relates to an on-line monitoring system for phosphogypsum. Background Art

[0002] Phosphogypsum is the residue of phosphate rock after phosphoric acid production and belongs to acidic substances. The main components are calcium sulfate (CaSO 4 ), attached water (H 2 O), water-soluble phosphorus pentoxide (P 2 O 5 ), water-soluble fluoride ion (F - ), water-soluble magnesium oxide (MgO), heavy metals, etc. Before modification, phosphogypsum was classified as Class II general industrial solid waste and could not be utilized as a resource.

[0003] According to the current regulations, after modification, phosphogypsum meets the relevant requirements of Class I general industrial solid waste specified in the "Pollution Control Standards for Storage and Landfill of General Industrial Solid Wastes" (GB18599-2020), and meets the screening value standard for the second type of land use in the "Soil Environmental Quality Risk Control Standards for Soil Pollution of Construction Land (Trial)" (GB36600-2018), and can be comprehensively utilized as an industrial product.

[0004] The modification of phosphogypsum mainly takes the compliance of pollution characteristic values such as pH, water-soluble phosphorus, water-soluble fluorine, and heavy metals as the main basis for meeting the requirements of Class I general industrial solid waste. For the detection of phosphogypsum, manual sampling is required and the samples are sent to the testing laboratory, and the experiment preparation and operation are carried out manually according to the horizontal oscillation method. From sampling to the laboratory issuing data, it takes at least two days and at most one week, and the product quality and environmental risks cannot be controlled in real time. During the detection period, there is an environmental risk of a large amount of pollutants overflowing due to quality problems of a large number of products. At the same time, sample cheating is likely to occur during manual sampling, and there is a relatively high integrity risk.

[0005] Therefore, in view of the above problems, an on-line monitoring system for phosphogypsum is now developed. Summary of the Invention

[0006] In order to overcome the shortcomings that the existing modification of phosphogypsum requires manual sampling and delivery to the testing laboratory, and the experiment preparation and operation are carried out manually according to the "Horizontal Oscillation Method for the Leaching Toxicity of Solid Wastes", from sampling to the laboratory issuing data, it takes at least two days and at most one week, and the product quality and environmental risks cannot be controlled in real time. During the detection period, there is an environmental risk of a large amount of pollutants overflowing due to quality problems of a large number of products. At the same time, sample cheating is likely to occur during manual sampling, and there is a relatively high integrity risk, the present invention provides an on-line monitoring system for phosphogypsum.

[0007] The technical implementation solution of the present invention is: a phosphogypsum online monitoring system, which includes a device main body, a phosphogypsum quantifier, a deionized water quantifier, a manipulator, an operation console, an ultrapure water machine, a horizontal oscillator, an automatic suction filter, a water sample dispenser, and an eigenvalue detector. A phosphogypsum quantifier is arranged inside the device main body. The device main body is configured with a system feed inlet, a temperature and humidity regulator, a video monitoring system, an access control system, a lighting system, an automatic control system, and a data collector. The phosphogypsum quantifier is connected to the system feed inlet through a pipeline. A deionized water quantifier is arranged on one side of the phosphogypsum quantifier. The operation console is located inside the device main body. A manipulator is fixedly arranged on the lower surface inside the device main body. An ultrapure water machine is arranged on one side of the operation console. A horizontal oscillator is arranged on one side of the ultrapure water machine. An automatic suction filter is arranged on the side of the horizontal oscillator away from the ultrapure water machine. A water sample dispenser is arranged on the side of the automatic suction filter away from the horizontal oscillator.

[0008] Optionally, the phosphogypsum quantifier is composed of a hose, a primary storage tank, a first electric valve, a quantitative feeding belt, a secondary quantitative tank, a second electric valve, a quantitative tank weighing sensor, a fixed bracket, and a storage tank weighing sensor. The hose is connected to the system feed inlet. The other end of the hose is provided with a primary storage tank. A first electric valve is arranged below the primary storage tank. A quantitative feeding belt is arranged below the first electric valve. A secondary quantitative tank is arranged at the discharge port of the quantitative feeding belt. A second electric valve is arranged at the discharge port below the secondary quantitative tank. The fixed bracket is located on the side of the quantitative feeding belt and is used to connect the phosphogypsum quantifier to the device main body. The primary storage tank is equipped with a storage tank weighing sensor, and the secondary quantitative tank is equipped with a quantitative tank weighing sensor.

[0009] Optionally, the deionized water quantifier is composed of a quantitative water tank, a third electric valve, a quantitative water weighing sensor, a peristaltic tube, and a peristaltic pump. A third electric valve is arranged at the water outlet of the quantitative water tank. The quantitative water tank is equipped with a quantitative water weighing sensor. A peristaltic tube is arranged between the peristaltic pump and the quantitative water tank.

[0010] Optionally, it further includes that the manipulator is composed of a fixed seat, a robotic arm, a tooling plate, clamping fingers, and a suction cup. The fixed seat is fixedly connected to the lower surface inside the device main body. The robotic arm is movably connected to the fixed seat. A tooling plate is arranged at one end of the robotic arm away from the fixed seat. Clamping fingers and a suction cup are respectively arranged on both sides of the tooling plate.

[0011] Optionally, it further includes that the operation table includes a box body, an extraction bottle main body is arranged on the upper surface of the box body, an installation box is arranged on one side of the box body, a hot air dryer and a cleaning faucet are arranged inside the installation box, a placement rack is arranged on the side of the installation box away from the box body, a cap screwing storage magazine is arranged above the placement rack, a cap screwing main body is arranged inside the cap screwing storage magazine, an extraction bottle main body is arranged inside the placement rack, an extraction bottle fixing tooling is arranged on one side of the placement rack, an extraction bottle main body is arranged inside the extraction bottle fixing tooling, and a cap screwing fixing tooling is arranged below the cap screwing storage magazine.

[0012] Optionally, it further includes that the extraction bottle fixing tooling includes a fixed chuck, a movable chuck and a driving air cylinder, and the movable chuck is fixed on the cylinder head of the driving air cylinder and moves synchronously with the cylinder head.

[0013] Optionally, it further includes that the automatic suction filter is composed of an air shaft, a movable sealing head, a filter membrane roll, a winding and unwinding motor, a filter residue recovery box, a suction filter tank and a vacuum system. The filter membrane of the filter membrane roll is a 0.45μm microporous filter membrane. The movable sealing head is driven by an air cylinder. The winding and unwinding motor winds and unwinds the filter membrane roll at a fixed length. The air shaft is used for radially clamping the inner core of the filter membrane roll. The filter residue recovery box is used for recovering the filter residue filtered out after suction filtration.

[0014] It should be noted that: the accuracy of the quantitative water weighing sensor is not less than ±0.01g.

[0015] The accuracy of the quantitative tank weighing sensor and the storage tank weighing sensor is not less than ±0.01g.

[0016] In addition, the detection method of the present invention is: the modification of phosphogypsum mainly takes the compliance of pollution characteristic values such as pH, water-soluble phosphorus, water-soluble fluorine, and heavy metals as the main basis for meeting the requirements of Class I general industrial solid waste. The detection method is carried out in accordance with the National Environmental Protection Standard of the People's Republic of China "Solid Waste Leaching Toxicity Leaching Method Horizontal Oscillation Method" (HJ557-2009).

[0017] The present invention has the following advantages:

[0018] The present invention can realize the automatic detection of phosphogypsum by adopting a series of structures such as a device main body, a phosphogypsum quantifier, a deionized water quantifier, a manipulator, an operation table, an ultrapure water machine, a horizontal oscillator, an automatic suction filter, a water sample dispenser, and a characteristic value detector, ensuring the detection efficiency, and can real-time control the product quality and environmental risks, solving the drawbacks of manual detection and improving the detection efficiency. BRIEF DESCRIPTION OF THE DRAWINGS

[0019] Figure 1 It is a schematic diagram of the overall structure of Embodiment 2 of the present invention;

[0020] Figure 2 Internal structure schematic diagram of Embodiment 2 of the present invention;

[0021] Figure 3 Structural schematic of Embodiment 1 of the present invention Figure 1 ;

[0022] Figure 4 Structural schematic of Embodiment 1 of the present invention Figure 2 ;

[0023] Figure 5 Structural schematic diagram of the phosphogypsum quantifier in the present invention;

[0024] Figure 6 Structural schematic diagram of the deionized water quantifier in the present invention;

[0025] Figure 7 Structural schematic diagram of the manipulator in the present invention;

[0026] Figure 8 Structural schematic diagram of the operating table in the present invention;

[0027] Figure 9 Structural schematic diagram of the extraction bottle fixing tooling in the present invention;

[0028] Figure 10 Structural schematic diagram of the cap screwing fixing tooling in the present invention;

[0029] Figure 11 Connection schematic diagram of the cap screwing main body and the extraction bottle in the present invention;

[0030] Figure 12 Structural schematic diagram of the automatic suction filter in the present invention;

[0031] Figure 13 Pouring schematic diagram of the extraction bottle main body in the present invention;

[0032] Figure 14 Drying schematic diagram of the extraction bottle main body in the present invention;

[0033] Figure 15 Cleaning schematic diagram of the extraction bottle main body in the present invention;

[0034] Figure 16 Structural schematic diagram of Embodiment 3 of the present invention;

[0035] Figure 17 Phosphogypsum test flow chart of the present invention;

[0036] Figure 18 Preparation and test flow chart of the leaching agent in the present invention;

[0037] Figure 19This is the diagram for detecting data flow and storage in the present invention.

[0038] Meanings of the reference numerals in the figure: 1. Device main body; 101. Feed inlet; 102. Temperature and humidity regulator; 2. Phosphogypsum quantifier; 201. Hose; 202. Primary storage tank; 203. First electric valve; 204. Quantitative feeding belt; 205. Secondary quantitative tank; 206. Second electric valve; 207. Quantitative tank weighing sensor; 208. Fixed bracket; 209. Storage tank weighing sensor; 3. Deionized water quantifier; 301. Quantitative water tank; 302. Third electric valve; 303. Quantitative water weighing sensor; 304. Peristaltic tube; 305. Peristaltic pump; 4. Manipulator; 401. Fixed seat; 402. Robot arm; 403. Tooling plate; 404. Gripping finger; 405. Suction cup; 5. Operating table; 501. Extraction bottle main body; 502. Box body; 503. Hot air dryer; 504. Installation box; 505. Cleaning faucet; 506. Placing rack; 507. Cap storage magazine; 508. Cap main body; 509. Cap fixing tooling; 510. Extraction bottle fixing tooling; 5101. Fixed chuck; 5102. Movable chuck; 5103. Driving cylinder; 6. Ultra-pure water machine; 7. Horizontal oscillator; 8. Automatic suction filter; 801. Air shaft; 802. Movable sealing head; 803. Filter membrane roll; 804. Rewinding motor; 805. Filter residue recovery box; 9. Water sample dispenser; 10. Eigenvalue measuring machine. Detailed implementation manners

[0039] To make the objectives, technical solutions and advantages of the present invention clearer, the present invention will be further described in detail below with reference to the accompanying drawings. It is hereby declared that the upper, lower, left, right, front, rear, inner, outer and other orientation terms that appear or will appear in the present invention are only based on the drawings of the present invention, and they do not specifically limit the present invention.

[0040] Example 1

[0041] As Figure 3 - Figure 15As shown in the figure, a phosphogypsum on-line monitoring system includes a device main body 1, a phosphogypsum quantifier 2, a deionized water quantifier 3, a manipulator 4, an operation console 5, an ultrapure water machine 6, a horizontal oscillator 7, an automatic suction filter 8, a water sample distributor 9, and an eigenvalue detector 10. Inside the device main body 1, there is a phosphogypsum quantifier 2. The device main body 1 is equipped with a system feed inlet 101, a temperature and humidity regulator 102, a video monitoring system, an access control system, a lighting system, an automatic control system, and a data collector. The phosphogypsum quantifier 2 is connected to the system feed inlet 101 through a pipeline. On one side of the phosphogypsum quantifier 2, there is a deionized water quantifier 3. The operation console 5 is located inside the device main body 1. On the lower surface inside the device main body, there is a fixed manipulator 4. On one side of the operation console 5, there is an ultrapure water machine 6. On one side of the ultrapure water machine 6, there is a horizontal oscillator 7. On the side of the horizontal oscillator 7 away from the ultrapure water machine 6, there is an automatic suction filter 8. On the side of the automatic suction filter 8 away from the horizontal oscillator 7, there is a water sample distributor 9. The device main body 1 is a laboratory.

[0042] As Figure 5 shown in the figure, the phosphogypsum quantifier 2 consists of a flexible hose 201, a primary storage tank 202, a first electric valve 203, a quantitative feeding belt 204, a secondary quantitative tank 205, a second electric valve 206, a quantitative tank weighing sensor 207, a fixed bracket 208, and a storage tank weighing sensor 209. The flexible hose 201 is connected to the system feed inlet 101. At the other end of the flexible hose 201, there is a primary storage tank 202. Below the primary storage tank 202, there is a first electric valve 203. Below the first electric valve 203, there is a quantitative feeding belt 204. At the discharge port of the quantitative feeding belt 204, there is a secondary quantitative tank 205. At the lower discharge port of the secondary quantitative tank 205, there is a second electric valve 206. The fixed bracket 208 is located on the side of the quantitative feeding belt 204 for connecting the phosphogypsum quantifier 2 to the device main body 1. The primary storage tank 202 is equipped with a storage tank weighing sensor 209, and the secondary quantitative tank 205 is equipped with a quantitative tank weighing sensor 207.

[0043] The phosphogypsum first enters the primary storage tank 202, and the weight is measured by the storage tank weighing sensor 209. The first electric valve 203 is opened, and the phosphogypsum is metered according to the weight loss algorithm and falls onto the quantitative feeding belt 204. The phosphogypsum is transported by the quantitative feeding belt 204 to the secondary quantitative tank 205, and the secondary quantitative tank 205 accurately measures by the weight gain method. After the phosphogypsum in the secondary quantitative tank 205 reaches the preset phosphogypsum quality, the first electric valve 203 is closed, and the quantitative feeding belt 204 is stopped. After the manipulator 4 places the extraction bottle at the designated position below the discharge port, the second electric valve 206 is opened, and the metered phosphogypsum is loaded into the extraction bottle. Then, the manipulator 4 places the extraction bottle filled with phosphogypsum at the designated position below the water outlet of the deionized water quantifier 3.

[0044] As shown Figure 6 As shown in the figure, the deionized water quantifier 3 is composed of a quantitative water tank 301, a third electric valve 302, a weighing sensor, a peristaltic tube 304, and a peristaltic pump 305. A third electric valve 302 is provided at the water outlet of the quantitative water tank 301. The quantitative water tank 301 is equipped with a quantitative water weighing sensor 303. A peristaltic tube 304 is provided between the peristaltic pump 305 and the quantitative water tank 301.

[0045] It should be noted that the peristaltic pump 305 quantitatively pumps the deionized water produced by the ultrapure water machine 6 into the quantitative water tank 301 through the peristaltic tube 304. The quantitative water tank 301 accurately measures by the weight gain method. After the quantitative water weighing sensor 303 measures that the deionized water in the quantitative water tank 301 reaches the set mass, the peristaltic pump 305 is turned off, and the third electric valve 302 is opened, and the quantitative deionized water flows into the extraction bottle containing phosphogypsum.

[0046] As shown Figure 7 - Figure 15 As shown in the figure, the manipulator 4 is composed of a fixed seat 401, a robotic arm 402, a tooling plate 403, clamping fingers 404, and a suction cup 405. The fixed seat 401 is fixedly connected to the lower surface inside the device main body 1. The robotic arm 402 is movably connected to the fixed seat 401. A tooling plate 403 is provided at one end of the movable arm away from the fixed seat 401. Clamping fingers 404 and a suction cup 405 are respectively provided on both sides of the tooling plate 403. The operation table 5 includes a box body 502. The upper surface of the box body 502 is provided with an extraction bottle main body 501. An installation box 504 is provided on one side of the box body 502. A hot air dryer 503 and a cleaning faucet 505 are provided inside the installation box 504. A placement rack 506 is provided on the side of the installation box 504 away from the box body 502. A cap storage magazine 507 is provided above the placement rack 506. A cap main body 508 is provided inside the cap storage magazine 507. An extraction bottle main body 501 is provided inside the placement rack 506. An extraction bottle fixing tooling 510 is provided on one side of the placement rack 506. An extraction bottle main body 501 is provided inside the extraction bottle fixing tooling 510. A cap fixing tooling 509 is provided below the cap storage magazine 507. The extraction bottle fixing tooling 510 includes a fixed chuck 5101, a movable chuck 5102, and a driving cylinder 5103. The movable chuck 5102 is fixed on the cylinder head of the driving cylinder 5103 and moves synchronously with the cylinder head.

[0047] It should be noted that the extraction bottle fixing tooling 510 is composed of a fixed chuck 5101, a movable chuck 5102, and a driving cylinder 5103. The movable chuck 5102 is fixed on the cylinder head of the driving cylinder 5103 and moves synchronously with the cylinder head. The movable chuck 5102 has two working positions. When in the clamping position, the fixed chuck 5101 and the movable chuck 5102 jointly clamp the extraction bottle.

[0048] After the manipulator 4 places the extraction bottle into the extraction bottle fixing tooling 510, it uses the suction cup 405 to pick up the inner cap from the inner cap storage magazine and press it onto the extraction bottle. Then, the manipulator 4 uses the suction cup 405 to grab the screw cap from the screw cap storage magazine and places the screw cap onto the screw cap fixing tooling 509. After the manipulator 4 replaces the clamping fingers 404, it clamps the screw cap, and the robotic arm 402 moves to screw the screw cap tightly onto the extraction bottle, completing the work of extracting the inner cap and the screw cap of the extraction bottle.

[0049] After the extraction bottle cap is tightened, the extraction bottle fixing tooling 510 resets to the loose state. The manipulator 4 places the extraction bottle into the horizontal oscillator 7 for horizontal oscillation. After the horizontal oscillation is completed, the manipulator 4 takes out the extraction bottle from the horizontal oscillator 7 and places it into the extraction bottle static rack. The extraction bottle static rack can be used as the static position after horizontal oscillation and also as the storage position for empty extraction bottles.

[0050] When the static time of the extraction bottle after horizontal oscillation arrives, the manipulator 4 places the extraction bottle into the extraction bottle fixing tooling 510. After the extraction bottle fixing tooling 510 clamps the extraction bottle, the manipulator 4 completes the work of unscrewing the screw cap and sucking away the inner cap. Both the screw cap and the inner cap are cleaned by the manipulator 4 in cooperation with the cleaning faucet 505 and the hot air dryer 503, and then put back into their respective magazines after cleaning.

[0051] As Figure 8 shown, the automatic suction filter 8 consists of an air shaft 801, a movable sealing head 802, a filter membrane roll 803, a winding and unwinding motor 804, a filter residue recovery box 805, a suction filter tank and a vacuum system. The filter membrane of the filter membrane roll 803 is a 0.45μm microporous filter membrane. The movable sealing head 802 is driven by a cylinder. The winding and unwinding motor 804 winds and unwinds the filter membrane roll 803 at a fixed length. The air shaft 801 is used to radially clamp the inner core of the filter membrane roll 803. The filter residue recovery box 805 is used to recover the filter residue filtered out after suction filtration.

[0052] It should be noted that the aforementioned extraction bottle is grabbed by the manipulator 4 above the suction filter port of the automatic suction filter 8. The filter membrane is a 0.45μm microporous filter membrane. The movable sealing head 802 is driven by a cylinder. The winding and unwinding motor 804 winds and unwinds the filter membrane roll 803 at a fixed length. Each time after suction filtration, a fixed length of clean filter membrane is released. Before winding and unwinding the filter membrane, the movable sealing head 802 opens to allow the filter membrane to pass through. After winding and unwinding the filter membrane is completed, the movable sealing head 802 closes, and the sealing ring on the sealing head presses the filter membrane tightly. The filter residue filtered out after the previous suction filtration is automatically poured into the filter residue recovery box 805 through winding and unwinding. The air shaft 801 is used to radially clamp the inner core of the filter membrane roll 803 to limit the non-working degrees of freedom of the filter membrane roll 803 during the working process.

[0053] The manipulator 4 pours the phosphogypsum and the leaching solution in the extraction bottle into the automatic suction filter 8. The automatic suction filter 8 filters out the leaching solution and pumps the leaching solution to the water sample dispenser 9. The water sample dispenser 9 distributes the leaching solution to each characteristic value detector 10 for characteristic value detection.

[0054] The manipulator 4 grips and extracts the bottle and cooperates with the cleaning faucet 505 and the hot air dryer 503 for cleaning, and then places the cleaned empty extraction bottle into the extraction bottle static rack.

[0055] The eigenvalue data detected by each eigenvalue detector 10, the corresponding sampling, the entire process video data of the test, and the data of the operation of each device are packaged together. After packaging, they are transmitted by the data acquisition instrument to the local data storage system and the cloud storage system. The cloud storage system classifies and transmits the data to each authorized terminal data receiving device in real time as needed.

[0056] The above-mentioned phosphogypsum quantizer 2, automatic suction filter 8, water sample dispenser 9, eigenvalue detector 10 and all working pipelines are all designed with self-cleaning functions.

[0057] When in use, as Figure 17 shown, a negative pressure suction sampling device is set at the discharge conveyor or the storage yard of the phosphogypsum modification production line to negatively and quantitatively suck the phosphogypsum to be inspected. The phosphogypsum to be inspected is pneumatically conveyed to the cyclone dryer, and after drying, it is pneumatically conveyed to the system feed port 101.

[0058] Example 2

[0059] As Figure 1 and Figure 2 shown, the structure of this example is basically the same as that of Example 1, and the difference is that the device main body 1 adopts a container.

[0060] Example 3

[0061] As Figure 16 shown, the structure of this embodiment is basically the same as that of Example 1, and the difference is that the device main body 1 adopts a vehicle-mounted container.

[0062] The above has described the embodiments of the present invention in detail with reference to the drawings. However, the present invention is not limited to the above embodiments, and various changes can be made without departing from the spirit of the present invention within the knowledge of those skilled in the art.

Claims

1. A phosphogypsum online monitoring system, comprising a device body (1), a phosphogypsum dosing device (2), a deionized water dosing device (3), a manipulator (4), an operating table (5), an ultrapure water machine (6), a horizontal oscillator (7), an automatic suction filter (8), a water sample distributor (9), and a characteristic value measuring device (10), wherein the phosphogypsum dosing device (2) is arranged inside the device body (1), and the device body (1) is equipped with a system feed port (101), a temperature and humidity regulator (102), a video monitoring system, an access control system, a lighting system, an automatic control system, and a data acquisition device, wherein the phosphogypsum dosing device (2) and The system feed ports (101) are connected by pipelines, a deionized water doser (3) is arranged on one side of the phosphogypsum doser (2), the operating table (5) is located inside the device body (1), a manipulator (4) is fixedly arranged on the lower surface inside the device body (1), an ultrapure water machine (6) is arranged on one side of the operating table (5), a horizontal oscillator (7) is arranged on one side of the ultrapure water machine (6), an automatic suction filter (8) is arranged on the side of the horizontal oscillator (7) away from the ultrapure water machine (6), and a water sample dispenser (9) is arranged on the side of the automatic suction filter (8) away from the horizontal oscillator (7).

2. A phosphogypsum online monitoring system according to claim 1, characterized in that: The phosphogypsum dosing device (2) is composed of a hose (201), a primary storage tank (202), a first electric valve (203), a quantitative feeding belt (204), a secondary quantitative tank (205), a second electric valve (206), a quantitative tank weighing sensor (207), a fixing bracket (208), and a storage tank weighing sensor (209). The hose (201) is connected to the system feed port (101). The other end of the hose (201) is provided with a primary storage tank (202). The first electric valve (203) is provided below the primary storage tank (202). A quantitative feeding belt (204) is arranged below the electric valve (203); a secondary quantitative tank (205) is arranged at the discharge port of the quantitative feeding belt (204); a second electric valve (206) is arranged at the discharge port below the secondary quantitative tank (205); the fixed bracket (208) is located on the side of the quantitative feeding belt (204) and is used to connect the phosphogypsum doser (2) to the device body (1); the primary storage tank (202) is equipped with a storage tank weighing sensor (209); and the secondary quantitative tank (205) is equipped with a quantitative tank weighing sensor (207).

3. The phosphogypsum online monitoring system according to claim 1 is characterized in that: The deionized water doser (3) is composed of a dosing water tank (301), a third electric valve (302), a dosing water weighing sensor (303), a peristaltic tube (304), and a peristaltic pump (305). The third electric valve (302) is arranged at the water outlet of the dosing water tank (301). The dosing water tank (301) is equipped with a dosing water weighing sensor (303). A peristaltic tube (304) is arranged between the peristaltic pump (305) and the dosing water tank (301).

4. The phosphogypsum online monitoring system according to claim 1 is characterized in that: The manipulator (4) is composed of a fixed seat (401), a mechanical arm (402), a tooling plate (403), a clamping finger (404) and a suction cup (405); the fixed seat (401) is fixedly connected to the lower surface inside the device body (1); the mechanical arm (402) is movably connected to the fixed seat (401); a tooling plate (403) is provided at one end of the movable arm away from the fixed seat (401); and clamping fingers (404) and a suction cup (405) are respectively provided on both sides of the tooling plate (403).

5. The phosphogypsum online monitoring system according to claim 1 is characterized in that: The operating table (5) comprises a box body (502), an extraction bottle body (501) is arranged on the upper surface of the box body (502), an installation box (504) is arranged on one side of the box body (502), a hot air dryer (503) and a cleaning faucet (505) are arranged inside the installation box (504), a placement rack (506) is arranged on the side of the installation box (504) away from the box body (502), and a rotary A cover storage magazine (507) is provided with a cover body (508) inside the cover storage magazine (507), an extraction bottle body (501) is provided inside the placement rack (506), an extraction bottle fixing tool (510) is provided on one side of the placement rack (506), an extraction bottle body (501) is provided inside the extraction bottle fixing tool (510), and a cover fixing tool (509) is provided below the cover storage magazine (507).

6. A phosphogypsum online monitoring system according to claim 5, characterized in that: The extraction bottle fixing tool (510) comprises a fixed chuck (5101), a movable chuck (5102) and a driving cylinder (5103), wherein the movable chuck (5102) is fixed on the cylinder head of the driving cylinder (5103) and moves synchronously with the cylinder head.

7. A phosphogypsum online monitoring system according to claim 1, characterized in that: The automatic suction filter (8) is composed of an air expansion shaft (801), a movable sealing head (802), a filter membrane roll (803), a reeling and unreeling motor (804), a filter residue recovery box (805), a suction filter tank and a vacuum system. The filter membrane of the filter membrane roll (803) is a 0.45 μm microporous filter membrane. The movable sealing head (802) is driven by an air cylinder. The reeling and unreeling motor (804) reels and unreels the filter membrane roll (803) at a fixed length. The air expansion shaft (801) is used to radially clamp the inner core of the filter membrane roll (803). The filter residue recovery box (805) is used to recover the filter residue filtered out after suction filtration.