High-temperature sintering and stretching all-in-one machine for PPS hydrogen energy diaphragm

Abstract

The invention discloses a PPS hydrogen energy diaphragm high-temperature sintering and stretching all-in-one machine which comprises a support, a U-shaped frame is fixedly installed on the upper surface of the support, a tubular furnace is fixedly installed on the upper surface of the U-shaped frame, a sintering extrusion mechanism is arranged in a heating groove of the tubular furnace, the sintering extrusion mechanism can be filled with PPS particle materials, and the PPS particle materials are extruded and bitten by a rolling forming mechanism. And the roll forming mechanism can pull the meshed diaphragm into a W shape for transmission, the diaphragm pulled into the W shape can be shored and stretched by the stretching mechanism in the transmission process, and the stretching mechanism is rotationally installed between the two sets of fastening plates and rotates in the U-shaped frame. Through the design of the rolling forming mechanism and the stretching mechanism, the extruded diaphragm can be rolled and stretched together, and proper rolling and stretching can promote regular arrangement of polyphenylene sulfide molecular chains and increase the crystallinity, so that the rigidity, heat resistance, chemical resistance and other properties of the material are improved.

Description

Technical Field

[0001] The present invention relates to the technical field of polyphenylene sulfide production, and particularly to a high-temperature sintering and stretching integrated machine for PPS hydrogen energy diaphragms. Background Art

[0002] Polyphenylene sulfide is a polymer containing repeating structural units of p-phenylene sulfide in its molecules and is a new type of functional engineering plastic. It has wide applications in the fields of electronics, automobiles, machinery, and chemicals. Polyphenylene sulfide is fully called polyphenyl sulfide and is a thermoplastic resin with phenylthio groups in the main chain of its molecules. Polyphenylene sulfide is a crystalline polymer. The as-spun fiber has a large amorphous region, with a crystallinity of about 5%. It undergoes exothermic crystallization at 125 °C, has a glass transition temperature of 150 °C, and a melting point of 281 °C. The drawn fiber generates partial crystallization during the drawing process, increasing to 20%. If the drawn fiber is heat-treated at a temperature of 130 to 230 °C, the crystallinity can be increased to 60 to 80%.

[0003] As disclosed in the Chinese patent with the publication number CN220903941U, a polyphenylene sulfide extruder includes an extrusion mechanism for extruding molten polyphenylene sulfide, a die for receiving the polyphenylene sulfide extruded by the extrusion mechanism, and a vibration defoaming mechanism for generating vibrations to discharge the bubbles in the polyphenylene sulfide in the die; the die is provided with a cavity for accommodating molten polyphenylene sulfide, and the extrusion end of the extrusion mechanism extends into the die; the die is arranged on the vibration defoaming mechanism. The vibration defoaming mechanism generates vibrations, and the bubbles in the molten polyphenylene sulfide are discharged by vibration. In this way, the bubbles contained in the polyphenylene sulfide are reduced, and the quality of the product is improved.

[0004] However, in the above-mentioned polyphenylene sulfide extruder, during the extrusion process of polyphenylene sulfide, it is not possible to roll and stretch the extruded polyphenylene sulfide at the same time, which makes it difficult to precisely control the crystallinity, resulting in unstable product performance, large differences between batches, and the produced products are more likely to crack or break when subjected to impact or bending. Summary of the Invention

[0005] The purpose of the present invention is to provide a high-temperature sintering and stretching integrated machine for PPS hydrogen energy diaphragms to solve the problems raised in the above background art.

[0006] To achieve the above purpose, the present invention provides the following technical solutions:

[0007] A PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine, comprising: a support, on the upper surface of which a U-shaped frame is fixedly installed; on the upper surface of the U-shaped frame, a tubular furnace is fixedly installed; a top cover is covered on the upper surface of the tubular furnace; one end of the top cover is fixedly installed with a connecting arm, the connecting arm is rotatably installed at one end of a support rod, the inner end of the connecting arm is rotatably connected to the piston rod of a second electric push rod, and the second electric push rod is rotatably installed on the upper surface of the support, so that the second electric push rod can push the top cover open by pushing the connecting arm; the support rod is fixedly installed on the upper surface of the support; a sintering and extrusion mechanism is arranged in the heating tank of the tubular furnace, the sintering and extrusion mechanism can be filled with PPS granular material, and can push it into the sintering and extrusion mechanism for high-temperature sintering and extrude it to be bitten by a roll-forming mechanism; the roll-forming mechanism is rotatably installed between two docking plates, the two docking plates are respectively fixedly installed at both ends of the U-shaped frame, and the two roll-forming mechanisms can make the bitten diaphragm be pulled into a W shape and drive between them;

[0008] Among them, the diaphragm pulled into a W shape will be supported and stretched by a stretching mechanism during the transmission process. The stretching mechanism is rotatably installed between two fastening plates and rotates inside the U-shaped frame, and the two fastening plates are fixedly installed on the lower surface of the U-shaped frame.

[0009] Preferably, one end of the tubular furnace is fixedly installed with a mounting plate, two U-shaped groove openings are formed on the lower surface of the mounting plate, and a winding column is placed and rotated in the two U-shaped groove openings. One end of the winding column is fixedly installed with a first gear, the first gear meshes with a second gear, the second gear is rotatably installed at one end of the U-shaped groove opening, one end of the second gear is fixedly installed with a first transmission disk, a transmission belt is sleeved on the outer surface of the first transmission disk, and the other end of the transmission belt is sleeved on one end of the roll-forming mechanism, so that while the roll-forming mechanism rolls the extruded diaphragm, it can synchronously drive the winding column to wind the diaphragm through the second gear.

[0010] Preferably, the sintering and extrusion mechanism includes a furnace tube, the furnace tube is placed in the heating tank of the tubular furnace, both ends of the furnace tube extend out of the heating tank of the tubular furnace, and a feeding hopper is connected and installed on the outer surface of the furnace tube extending out to the outer end of the furnace tube, and an extrusion nozzle is connected and installed at the lower end of the outer surface of the furnace tube at the other end.

[0011] Preferably, a spiral conveyor blade is rotatably installed in the furnace tube, one end of the spiral conveyor blade is fixedly connected to the output shaft of a first motor, and the first motor is fixedly installed on the upper surface of the mounting plate, so that the spiral conveyor blade can push the PPS granular material filled from the feeding hopper into the heating tank of the tubular furnace for high-temperature sintering, and then the sintered material can be pushed into the extrusion nozzle by the spiral conveyor blade to form a diaphragm and be extruded therefrom.

[0012] Preferably, the roll forming mechanism includes roll pressing columns which are rotatably installed in two groups of docking plates. There are three roll pressing columns rotatably installed in each two groups of docking plates, and third gears are fixedly installed at one ends of the three roll pressing columns and are meshed with each other.

[0013] Preferably, the second roll pressing column of the three roll pressing columns is fixedly connected to the output shaft of the second motor. The second motor is fixedly installed at one end of the docking plate, so that the second motor can drive the second roll pressing column to rotate counterclockwise. The counterclockwise rotating second roll pressing column can drive the first and third roll pressing columns to rotate clockwise through the meshing of the third gears, so as to bite the extruded diaphragm into a W shape and roll it into shape.

[0014] Preferably, a second transmission disc is fixedly installed at one end of one of the roll pressing columns. The outer surface of the second transmission disc is sleeved by the other end of the transmission belt. In this way, when the roll pressing column is driven to rotate, the second transmission disc will be driven by the transmission belt to drive the winding column to rotate in the two U-shaped grooves.

[0015] Preferably, the stretching mechanism includes two triangular plates which are respectively rotatably installed at both ends inside the U-shaped frame. Three guide rail grooves are respectively opened at the inner ends of the two triangular plates. Guide rail blocks are slidably installed in the three guide rail grooves, and a top support wheel is rotatably installed between every two vertically opposite guide rail blocks.

[0016] Preferably, push-pull rods are rotatably installed at the inner ends of the three guide rail blocks, and the other ends of the three push-pull rods are rotatably installed on the outer surface of the push plate. The push plate is rotatably installed on the outer surface of the piston rod of the first electric push rod. The first electric push rod is fixedly installed at one end of the U-shaped frame, so that the first electric push rod can drive the three push-pull rods to push or pull the three guide rail blocks to slide synchronously inwards or outwards in the three guide rail grooves by pushing or pulling the push plate, so as to realize the regulation of the top support distance of the top support wheels.

[0017] Preferably, a third motor is fixedly installed at one end of the U-shaped frame, and the output shaft of the third motor rotates through the U-shaped frame and is fixedly connected to one of the triangular plates.

[0018] Compared with the prior art, the beneficial effects of the present invention are:

[0019] 1. Through the design of the tubular furnace, sintering and extrusion mechanism, roll forming mechanism and stretching mechanism, during use, PPS granular materials can be poured into the sintering and extrusion mechanism. Then, the sintering and extrusion mechanism can push the PPS granular materials into the heating tank of the tubular furnace to be sintered and melted at high temperature. With the continuous pushing of the sintering and extrusion mechanism, the melted PPS material can be extruded from it and bitten by the roll forming mechanism for rolling. The two roll forming mechanisms can make the bitten diaphragm be pulled into a W shape and transmitted between them. The plastic diaphragm formed by rolling can be wound around the outer surface of the winding column. The winding column can be sleeved on the outer surface of the roll forming mechanism through the transmission belt sleeved on the outer surface of the second transmission disc. Thus, when the roll forming mechanism rolls the extruded diaphragm, it can simultaneously drive the winding column to wind the diaphragm. While winding the diaphragm, the stretching mechanism can be started simultaneously to continuously support the lower surface of the diaphragm to stretch it. Then, the stretched diaphragm can be wound by the winding column. Appropriate rolling and stretching can promote the regular arrangement of polyphenylene sulfide molecular chains, increase the crystallinity, thereby improving the properties such as the rigidity, heat resistance and chemical resistance of the material. During the whole production process, from the conveying, sintering and extrusion, roll forming, winding to stretching of the granular materials, each link cooperates with each other and has a high degree of automation. It not only reduces the workload and error of manual operation, but also improves the production stability and the consistency of product quality, which is conducive to large-scale industrial production.

[0020] 2. Through the design of the furnace tube, spiral conveyor blade, first motor and extrusion nozzle, during use, PPS granular materials can be poured into the feeding hopper opened at the upper end of the outer surface of the furnace tube. Subsequently, the first motor can be started to drive the spiral conveyor blade to push the poured PPS granular materials into the heating tank of the tubular furnace to be sintered at high temperature. Then, the sintered material can be pushed into the extrusion nozzle by the spiral conveyor blade to form a diaphragm and be extruded from it. And through the uniform rotation of the spiral conveyor blade, the conveying amount and conveying speed of the material can be accurately controlled, ensuring the continuity and stability of the material supply, which is conducive to the stable progress of the subsequent sintering and extrusion processes. And this precise extrusion and forming process helps to improve the consistency and yield rate of the product.

[0021] 3. Through the design of the second motor, the roller column, the second transmission disc and the third gear, the plastic diaphragm extruded by the extrusion nozzle can fall between the two groups of roller columns by the natural falling force, and the second group of roller columns can be driven to rotate by the second motor, so that the rotating second group of roller columns can engage the third gear of the other two groups of roller columns through the third gear, so that the other two groups of roller columns rotate clockwise, so that the two groups of relatively rotating roller columns can bite the extruded plastic diaphragm into the roller, and then the staff can guide it into the space between the second and third groups of roller columns to be bitten and driven out, and then the staff can again introduce the plastic diaphragm into the three groups of roller columns on the other side, so that the diaphragm segments between the three groups of roller columns on both sides can be pulled into a horizontal shape, and the diaphragm rolled out from the other side can be pulled into a horizontal shape. The film can be rolled up on the outer surface of the winding column, and the winding column can be meshed with the second gear through the first gear at one end, and the second gear can be driven to rotate by the transmission belt through the first transmission plate, and the other end of the transmission belt is set on the outer surface of the second transmission plate fixedly installed at one end of one group of roller columns, so that the roller column can be driven to rotate and the second transmission plate can be driven by the transmission belt to drive the winding column to rotate in the two groups of U-shaped grooves to roll up the diaphragm together, thereby avoiding the diaphragm being too long and causing wrinkles on the surface of the diaphragm. Multiple groups of roller columns rotate relative to each other and roll the plastic diaphragm in turn, which can make the diaphragm evenly stressed, better control the thickness and density of the diaphragm, ensure consistent performance everywhere, avoid problems such as uneven thickness and local density differences, and improve the overall quality and stability of the product.

[0022] 4. Through the design of the third motor, the triangular plate, the guide groove, the guide block, the supporting wheel, the push-pull rod and the first electric push rod, the third motor can be started after the diaphragm between the three groups of roller columns on both sides is pulled into a horizontal state, and the third motor can drive the supporting wheel rotatably installed between the triangular plates to rotate, so that the triangular plate can drive the supporting wheel to support the lower surface of the horizontal diaphragm, so as to realize the operation of supporting and stretching the diaphragm. In the process of supporting and stretching the diaphragm, the first electric push rod can be started to push or pull the push disk rotatably installed on the outer surface of the piston rod, so that The push-pull rod installed on the outer surface of the push disk pushes or pulls the three groups of guide blocks to slide outward or inward in the guide groove of the triangle plate synchronously to reduce or increase the distance between them, and there are support wheels installed rotatably between each two groups of vertically opposite guide blocks, which can drive the guide blocks to drive the support wheels installed rotatably to adjust the distance between them, and can allow the staff to adjust the degree to which the diaphragm is supported and stretched, so that the staff can flexibly adjust the stretching degree of the diaphragm according to actual production needs to meet different product specifications and performance requirements, and also improve the production flexibility and versatility of the equipment. BRIEF DESCRIPTION OF THE DRAWINGS

[0023] Figure 1 Schematic diagram of the overall structure of the present invention;

[0024] Figure 2 Schematic diagram of the structure of the mounting plate of the present invention;

[0025] Figure 3 Schematic diagram of the top cover of the present invention being pushed open by the second electric push rod;

[0026] Figure 4 Schematic diagram of the structure of the sintering and extrusion mechanism of the present invention;

[0027] Figure 5 Schematic diagram of the structure of the winding column of the present invention;

[0028] Figure 6 Schematic diagram of the structure of the first gear, second gear and first transmission disc of the present invention;

[0029] Figure 7 Schematic diagram of the structure of the roll forming mechanism of the present invention;

[0030] Figure 8 Schematic diagram of the structure of the stretching mechanism of the present invention.

[0031] In the figure: 1, support; 101, U-shaped frame; 102, tubular furnace; 103, top cover; 104, support rod; 105, connecting arm; 106, mounting plate; 107, U-shaped groove; 108, winding column; 109, second electric push rod; 110, first gear; 111, second gear; 112, first transmission disc; 113, docking plate; 114, transmission belt; 115, fastening plate; 2, sintering and extrusion mechanism; 201, first motor; 202, furnace tube; 203, feeding hopper; 204, spiral conveying blade; 205, extrusion nozzle; 3, roll forming mechanism; 301, second motor; 302, roll forming column; 303, second transmission disc; 304, third gear; 4, stretching mechanism; 401, third motor; 402, triangular plate; 403, guide rail groove; 404, guide rail block; 405, top support wheel; 406, push-pull rod; 407, push plate; 408, first electric push rod. Detailed implementation manners

[0032] Next, the technical solutions in the embodiments of the present invention will be clearly and completely described in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

[0033] Such as Figures 1 - 3As shown in the figure, this embodiment provides a PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine, including: a support 1, on the upper surface of the support 1, a U-shaped frame 101 is fixedly installed, on the upper surface of the U-shaped frame 101, a tubular furnace 102 is fixedly installed, on the upper surface of the tubular furnace 102, a top cover 103 is covered, at one end of the top cover 103, a connecting arm 105 is fixedly installed, the connecting arm 105 is rotatably installed at one end of a support rod 104, the inner end of the connecting arm 105 is rotatably connected to the piston rod of a second electric push rod 109, the second electric push rod 109 is rotatably installed on the upper surface of the support 1, so that the second electric push rod 109 can push the top cover 103 to turn it over by pushing the connecting arm 105, the support rod 104 is fixedly installed on the upper surface of the support 1, in the heating tank of the tubular furnace 102, a sintering and extrusion mechanism 2 is arranged, the sintering and extrusion mechanism 2 can be filled with PPS granular materials, and can push them into the sintering and extrusion mechanism 2 for high-temperature sintering and extrude them to be bitten by a roll-forming mechanism 3, the roll-forming mechanism 3 is rotatably installed between two docking plates 113, the two docking plates 113 are respectively fixedly installed at both ends of the U-shaped frame 101, and the two roll-forming mechanisms 3 can make the bitten diaphragm be pulled into a W shape and transmitted between them;

[0034] Among them, the diaphragm pulled into a W shape will be supported and stretched by a stretching mechanism 4 during the transmission process, the stretching mechanism 4 is rotatably installed between two fastening plates 115 and rotates within the U-shaped frame 101, and the two fastening plates 115 are fixedly installed on the lower surface of the U-shaped frame 101.

[0035] At one end of the tubular furnace 102, a mounting plate 106 is fixedly installed, on the lower surface of the mounting plate 106, two U-shaped groove openings 107 are formed, and a winding column 108 is rotatably placed and supported in the two U-shaped groove openings 107, at one end of the winding column 108, a first gear 110 is fixedly installed, the first gear 110 meshes with a second gear 111, the second gear 111 is rotatably installed at one end of the U-shaped groove opening 107, at one end of the second gear 111, a first transmission disc 112 is fixedly installed, on the outer surface of the first transmission disc 112, a transmission belt 114 is sleeved, the other end of the transmission belt 114 is sleeved at one end of the roll-forming mechanism 3, so that while the roll-forming mechanism 3 rolls the extruded diaphragm, it can synchronously drive the winding column 108 to wind the diaphragm through the second gear 111.

[0036] Through the design of the tube furnace 102, the sintering and extrusion mechanism 2, the roll pressing mechanism 3 and the stretching mechanism 4, during use, the PPS granular material can be poured into the sintering and extrusion mechanism 2, and the sintering and extrusion mechanism 2 can push the PPS granular material into the heating tank of the tube furnace 102 to be sintered and melted at high temperature. With the continuous pushing of the sintering and extrusion mechanism 2, the melted PPS material can be extruded from it and bitten by the roll pressing mechanism 3 for roll pressing. The two roll pressing mechanisms 3 can make the bitten diaphragm be pulled into a W shape and transmitted between them, and the formed plastic diaphragm can be wound around the outer surface of the winding column 108. The winding column 108 can be sleeved on the outer surface of the roll pressing mechanism 3 through the transmission belt 114 sleeved on the outer surface of the second transmission disk 303. Thus, when the roll pressing mechanism 3 rolls the extruded diaphragm, it can synchronously drive the winding column 108 to wind the diaphragm at the same time. While winding the diaphragm, the stretching mechanism 4 can be started simultaneously to continuously support and stretch the lower surface of the diaphragm, so that the stretched diaphragm can be wound by the winding column 108. Appropriate roll pressing and stretching can promote the regular arrangement of the polyphenylene sulfide molecular chains, increase the crystallinity, thereby improving the properties such as the rigidity, heat resistance and chemical resistance of the material. And during the whole production process, from the transportation of the granular material, sintering and extrusion, roll pressing and forming, winding to stretching, each link cooperates with each other, and the degree of automation is relatively high. It not only reduces the workload and error of manual operation, but also improves the production stability and the consistency of product quality, which is beneficial to large-scale industrial production.

[0037] As Figures 4 - 5 shown, the sintering and extrusion mechanism 2 includes a furnace tube 202. The furnace tube 202 is arranged in the heating tank of the tube furnace 102. Both ends of the furnace tube 202 extend out of the heating tank of the tube furnace 102, and a feeding hopper 203 is connected and installed on the outer surface of the furnace tube 202 extending to the outer end of the furnace tube 202. And a nozzle 205 is connected and installed at the lower end of the outer surface of the other end of the furnace tube 202.

[0038] A spiral conveyor blade 204 is rotatably installed in the furnace tube 202. One end of the spiral conveyor blade 204 is fixedly connected to the output shaft of the first motor 201. The first motor 201 is fixedly installed on the upper surface of the mounting plate 106, so that the spiral conveyor blade 204 can push the PPS granular material filled from the feeding hopper 203 into the heating tank of the tube furnace 102 to be sintered at high temperature. Then, the sintered material can be pushed into the nozzle 205 by the spiral conveyor blade 204 to form a diaphragm and be extruded from it.

[0039] Through the design of the furnace tube 202, the spiral conveyor blade 204, the first motor 201 and the extrusion nozzle 205, during use, the PPS granular material can be poured into the feeding hopper 203 opened at the upper end of the outer surface of the furnace tube 202. Subsequently, the first motor 201 can be started to drive the spiral conveyor blade 204 to push the poured PPS granular material into the heating tank of the tubular furnace 102 to be sintered at high temperature. Furthermore, the sintered material can be pushed into the extrusion nozzle 205 by the spiral conveyor blade 204 to form a diaphragm and be extruded therefrom. And through the uniform rotation of the spiral conveyor blade 204, the conveying amount and conveying speed of the material can be precisely controlled, ensuring the continuity and stability of the material supply, which is conducive to the stable progress of the subsequent sintering and extrusion processes. And this precise extrusion molding process helps to improve the consistency and yield rate of the product.

[0040] As Figures 6 - 7 shown, the roll forming mechanism 3 includes roll pressing columns 302. The roll pressing columns 302 are rotatably installed in two groups of docking plates 113. And there are three roll pressing columns 302 rotatably installed in each two groups of docking plates 113. And third gears 304 are fixedly installed at one ends of the three roll pressing columns 302 and are meshed with each other.

[0041] The second roll pressing column 302 of the three roll pressing columns 302 is fixedly connected to the output shaft of the second motor 301. The second motor 301 is fixedly installed at one end of the docking plate 113. Thus, the second motor 301 can drive the second roll pressing column 302 to rotate counterclockwise. And the counterclockwise rotating second roll pressing column 302 can drive the first and third roll pressing columns 302 to rotate clockwise through the meshing of the third gears 304. Thus, the extruded diaphragm can be bitten into a W shape and roll formed.

[0042] A second transmission disk 303 is fixedly installed at one end of one group of roll pressing columns 302. The outer surface of the second transmission disk 303 is sleeved by the other end of the transmission belt 114. In this way, when the roll pressing column 302 is driven to rotate, the second transmission disk 303 will be driven to rotate the winding column 108 in the two U-shaped grooves 107 through the transmission belt 114.

[0043] The second gear 303 of the second gear 304 is driven by the second motor 301 to rotate, thereby enabling the rotating second gear 302 to engage with the third gear 304 of the other two gears 302, so that the other two gears 302 can rotate clockwise, thereby enabling the two relatively rotating gears 302 to bite the extruded plastic diaphragm into the roller and then guide it between the second and third gears 302 to be bitten and driven out, and then the staff can again introduce the plastic diaphragm into the three groups of rollers 302 on the other side, thereby enabling the diaphragm segments between the three groups of rollers 302 on both sides to be pulled into a horizontal shape, and the diaphragm rolled out from the other side The film can be rolled up on the outer surface of the winding rod 108, and the winding rod 108 can be meshed with the second gear 111 through the first gear 110 at one end, and the second gear 111 can be driven to rotate by the transmission belt 114 through the first transmission plate 112, and the other end of the transmission belt 114 is set on the outer surface of the second transmission plate 303 fixedly installed at one end of one group of roller pressing rods 302, so that the roller pressing rod 302 can be driven to rotate together with the second transmission plate 303 through the transmission belt 114 to drive the winding rod 108 to rotate in the two groups of U-shaped slots 107 to roll up the diaphragm together, thereby avoiding the diaphragm being too long and causing wrinkles on the surface of the diaphragm. The multiple groups of roller pressing rods 302 rotate relative to each other and roll the plastic diaphragm in turn, so that the diaphragm is evenly stressed, and the thickness and density of the diaphragm can be better controlled, thereby ensuring consistent performance everywhere, avoiding problems such as uneven thickness and local density differences, and improving the overall quality and stability of the product.

[0044] like Figure 1 As shown, the stretching mechanism 4 includes two sets of triangular plates 402, which are rotatably mounted at both ends of the U-shaped frame 101, and three sets of guide rail grooves 403 are opened at one end of the inner side of the two sets of triangular plates 402. Guide rail blocks 404 are slidably mounted in the three sets of guide rail grooves 403, and a top support wheel 405 is rotatably mounted between each two sets of vertically opposite guide rail blocks 404.

[0045] One end of the inner side of each of the three groups of guide rail blocks 404 is rotatably installed with a push-pull rod 406, and the other ends of the three groups of push-pull rods 406 are rotatably installed on the outer surface of the push disk 407. The push disk 407 is rotatably installed on the outer surface of the piston rod of the first electric push rod 408. The first electric push rod 408 is fixedly installed at one end of the U-shaped frame 101, so that the first electric push rod 408 can drive the three groups of push-pull rods 406 to push or pull the three groups of guide rail blocks 404 to slide synchronously inward or outward in the three groups of guide rail grooves 403 by pushing or pulling the push disk 407, thereby realizing the adjustment of the top support distance of the top support wheels 405.

[0046] A third motor 401 is fixedly installed at one end of the U-shaped frame 101, and the output shaft of the third motor 401 rotates through the U-shaped frame 101 and is fixedly connected to one of the triangular plates 402.

[0047] Through the design of the third motor 401, the triangular plate 402, the guide rail groove 403, the guide rail block 404, the top support wheel 405, the push-pull rod 406 and the first electric push rod 408, after the diaphragm in the section between the three groups of roller pressing columns 302 on both sides is pulled into a horizontal shape, the third motor 401 can be started, and the third motor 401 can drive the top support wheels 405 rotatably installed between the triangular plates 402 to rotate. Furthermore, the triangular plate 402 can drive the top support wheels 405 to support the lower surface of the horizontal diaphragm, thereby realizing the operation of supporting and stretching the diaphragm. During the process of supporting and stretching the diaphragm, the first electric push rod 408 can be started to push or pull the push disk 407 rotatably installed on the outer surface of the piston rod. Furthermore, the push disk 407 can pull the push-pull rod 406 rotatably installed on the outer surface to push or pull the three groups of guide rail blocks 404 to slide outward or inward synchronously in the guide rail grooves 403 of the triangular plate 402 to reduce or increase the distance therebetween. And a top support wheel 405 is rotatably installed between every two vertically opposite guide rail blocks 404. Furthermore, the guide rail blocks 404 can drive the top support wheels 405 rotatably installed therebetween to adjust the distance therebetween, so that the staff can adjust the degree of the diaphragm being supported and stretched, and the staff can flexibly adjust the stretching degree of the diaphragm according to the actual production requirements to meet the requirements of different product specifications and performances, and also improve the flexibility of production and the versatility of the equipment.

[0048] In this embodiment, a crystallinity control system is integrated in the U-shaped frame 101, and this system executes the following dynamic crystallinity prediction equation:

[0049]

[0050] Parameter description:

[0051] X(t): Crystallinity (%) at time t;

[0052] X ∞:Maximum theoretical crystallinity (determined by material properties);

[0053] λ: Orientation factor (related to molecular chain rigidity, 0.8 - 1.2);

[0054] ε: Real-time strain rate (s -1 , feedback from the speed of the top support wheel);

[0055] vc: Critical strain rate threshold (1.2×10 -3 s -1 );

[0056] n: Stress response index (1.5 - 2.5, calibrated by DSC);

[0057] Ea: Activation energy (kJ / mol, related to the molecular weight of PPS);

[0058] R: Gas constant;

[0059] T(τ): Real-time temperature field (K, monitored by an infrared thermal imager);

[0060] Tg: Glass transition temperature (358K).

[0061] This crystallinity control system includes:

[0062] a) A distributed temperature sensor array embedded in the inner wall of the tube furnace 102 at a spacing of 5 mm;

[0063] b) A high-precision encoder for real-time monitoring of the displacement of the top support wheel 405 (accuracy ±0.01 mm);

[0064] c) An industrial PC for solving the crystallinity equation at a cycle of 1 ms;

[0065] d) A servo driver for converting the X(t) deviation value into a PID control signal for the first electric push rod 408.

[0066] For example, when the top support wheel moves in a sine wave mode (amplitude h = 50 mm, frequency f = 0.5 Hz), the strain rate is calculated by real-time acquisition of displacement data through the encoder:

[0067]

[0068] After substituting into the equation, the evolution curve of crystallinity over time can be predicted, which is used to optimize the combination of stretching parameters.

[0069] Technical effect verification table:

[0070] Process parameters Traditional method Optimization of this equation Performance improvement Tensile rate (mm / s) Constant 2.0 Dynamic 3.5 - 1.8 +18％ Top support amplitude (mm) Fixed 30 Gradient 40 - 25 +22％ Crystallinity (%) 62.3 74.8 +20％ Tensile strength (MPa) 85 102 +20％

[0071] This equation has been verified in real time through online Raman spectroscopy. Under the optimized parameters of f = 0.8 Hz and h = 45 mm, the crystallinity of the PPS separator was successfully stabilized at 72 ± 1.5%, a 19.3% improvement over conventional processes. The digital twin system established with this model enables the prediction of separator microstructural evolution without downtime, providing theoretical support for the reliability of hydrogen separators.

[0072] Summarize and sort out the working steps of this solution according to the above technical solution: When in use, the PPS granular material can be poured into the feeding hopper 203 opened at the upper end of the outer surface of the furnace tube 202. Subsequently, the first motor 201 can be started to drive the spiral conveying blade 204 to push the poured PPS granular material into the heating tank of the tubular furnace 102 to be sintered at high temperature. Furthermore, the sintered material can be pushed into the extrusion nozzle 205 by the spiral conveying blade 204 to form a diaphragm and be extruded therefrom. The plastic diaphragm extruded by the extrusion nozzle 205 can fall between two sets of roller columns 302 by the force of natural dropping. The second set of roller columns 302 can be driven to rotate by the second motor 301. Furthermore, the rotating second set of roller columns 302 can drive the third gears 304 of the other two sets of roller columns 302 through the third gear 304 to mesh and drive, so that the other two sets of roller columns 302 rotate clockwise. Furthermore, the two sets of relatively rotating roller columns 302 can bite and roll the extruded plastic diaphragm. Subsequently, the staff can guide it between the second and third sets of roller columns 302 to be bitten and driven out. Subsequently, the staff can introduce the plastic diaphragm into the three sets of roller columns 302 on the other side again. Furthermore, the diaphragm in the section between the three sets of roller columns 302 on both sides can be pulled into a horizontal shape. The diaphragm rolled out from the other side can be wound on the outer surface of the winding column 108. The horizontally pulled diaphragm can start the third motor 401, and the third motor 401 can drive the top support wheel 405 rotatably installed between the triangular plates 402 to rotate. Furthermore, the triangular plate 402 can drive the top support wheel 405 to support the lower surface of the horizontally shaped diaphragm, so as to realize the operation of supporting and stretching the diaphragm. During the process of supporting and stretching the diaphragm, the first electric push rod 408 can be started to push or pull the pushing disk 407 rotatably installed on the outer surface of the piston rod. Furthermore, the pushing disk 407 can pull the push rod 406 rotatably installed on the outer surface to push or pull the three guide rail blocks 404 to slide outward or inward synchronously in the guide rail groove 403 of the triangular plate 402 to reduce or increase the distance therebetween. A top support wheel 405 is rotatably installed between every two vertically opposite guide rail blocks 404. Furthermore, the guide rail blocks 404 can drive the top support wheel 405 rotatably installed therebetween to adjust the distance therebetween, so that the staff can adjust the degree of the diaphragm being supported and stretched. Furthermore, the diaphragm after being rolled and stretched can be wound on the outer surface of the winding column 108. One end of the winding column 108 can be meshed with the second gear 111 through the first gear 110. The second gear 111 can be driven to rotate by the transmission belt 114 through the first transmission disk 112. The other end of the transmission belt 114 is sleeved on the outer surface of the second transmission disk 303 fixedly installed at one end of one of the roller columns 302. Furthermore, when the roller column 302 is driven to rotate, it will drive the second transmission disk 303 through the transmission belt 114 to drive the winding column 108 to rotate in the two U-shaped grooves 107 to wind the diaphragm together.

[0073] In summary, the PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine can perform operations of rolling and stretching on the extruded diaphragm at the same time. Appropriate rolling and stretching can prompt the molecular chains of polyphenylene sulfide to be regularly arranged, increase the crystallinity, thereby improving the properties such as the rigidity, heat resistance and chemical resistance of the material. Moreover, in the whole production process, from the conveying of granular materials, sintering and extrusion, rolling forming, winding to stretching, each link cooperates with each other, and the degree of automation is relatively high. It not only reduces the workload and error of manual operation, but also improves the production stability and the consistency of product quality, which is conducive to large-scale industrial production.

[0074] Parts not involved in the present invention are the same as the prior art or can be implemented by using the prior art. Although the embodiments of the present invention have been shown and described, those of ordinary skill in the art can understand that various changes, modifications, substitutions and variations can be made to these embodiments without departing from the principle and spirit of the present invention. The scope of the present invention is defined by the appended claims and their equivalents.

Claims

1. A PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine, characterized in that Including: A support (1), on the upper surface of which a U-shaped frame (101) is fixedly installed. On the upper surface of the U-shaped frame (101), a tube furnace (102) is fixedly installed. A top cover (103) covers the upper surface of the tube furnace (102). One end of the top cover (103) is fixedly installed with a connecting arm (105). The connecting arm (105) is rotatably installed at one end of a support rod (104). The inner end of the connecting arm (105) is rotatably connected to the piston rod of a second electric push rod (109). The second electric push rod (109) is rotatably installed on the upper surface of the support (1), so that the second electric push rod (109) can push the connecting arm (105) to turn the top cover (103) open by pushing. The support rod (104) is fixedly installed on the upper surface of the support (1). A sintering and extrusion mechanism (2) is arranged in the heating tank of the tube furnace (102). The sintering and extrusion mechanism (2) can be filled with PPS granular material and can push it into the sintering and extrusion mechanism (2) for high-temperature sintering and extrude it to be bitten by a roll forming mechanism (3). The roll forming mechanism (3) is rotatably installed between two docking plates (113). The two docking plates (113) are respectively fixedly installed at both ends of the U-shaped frame (101). The two roll forming mechanisms (3) can drive the bitten diaphragm to be pulled into a W shape and transmit it therebetween. Among them, the diaphragm pulled into a W shape will be supported and stretched by a stretching mechanism (4) during the transmission process. The stretching mechanism (4) is rotatably installed between two fastening plates (115) and rotates within the U-shaped frame (101). The two fastening plates (115) are fixedly installed on the lower surface of the U-shaped frame (101).

2. The one PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine according to claim 1, characterized in that: One end of the tube furnace (102) is fixedly installed with a mounting plate (106). Two U-shaped grooves (107) are opened on the lower surface of the mounting plate (106). A winding column (108) is rotatably placed and supported in the two U-shaped grooves (107). One end of the winding column (108) is fixedly installed with a first gear (110). The first gear (110) meshes with a second gear (111). The second gear (111) is rotatably installed at one end of the U-shaped groove (107). One end of the second gear (111) is fixedly installed with a first transmission disc (112). The outer surface of the first transmission disc (112) is sleeved with a transmission belt (114). The other end of the transmission belt (114) is sleeved at one end of the roll forming mechanism (3), so that while the roll forming mechanism (3) rolls the extruded diaphragm, it can synchronously drive the winding column (108) to wind the diaphragm through the second gear (111).

3. A PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine according to claim 1, characterized in that: The sintering and extrusion mechanism (2) includes a furnace tube (202), the furnace tube (202) is arranged in the heating tank of the tubular furnace (102), both ends of the furnace tube (202) extend out of the heating tank of the tubular furnace (102), and a feeding hopper (203) is connected and installed on the outer surface of the furnace tube (202) at the outer end extending out of the furnace tube (202), and an extrusion nozzle (205) is connected and installed at the lower end of the outer surface of the other end of the furnace tube (202).

4. A PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine according to claim 3, characterized in that: A spiral conveyor blade (204) is rotatably installed in the furnace tube (202), one end of the spiral conveyor blade (204) is fixedly connected to the output shaft of the first motor (201), and the first motor (201) is fixedly installed on the upper surface of the mounting plate (106), so that the spiral conveyor blade (204) can push the PPS particle material filled from the feeding hopper (203) into the heating tank of the tubular furnace (102) to be sintered at high temperature, and then the sintered material can be pushed into the extrusion nozzle (205) by the spiral conveyor blade (204) to form a diaphragm and be extruded therefrom.

5. A high-temperature sintering and stretching integrated machine for PPS hydrogen energy diaphragm according to claim 1, characterized in that: The roll forming mechanism (3) includes roll pressing columns (302), the roll pressing columns (302) are rotatably installed in two groups of docking plates (113), and three roll pressing columns (302) are rotatably installed in each two groups of docking plates (113), and third gears (304) are fixedly installed at one ends of the three roll pressing columns (302) and are meshed with each other.

6. A PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine according to claim 5, characterized in that: The second roll pressing column (302) of the three roll pressing columns (302) is fixedly connected to the output shaft of the second motor (301), the second motor (301) is fixedly installed at one end of the docking plate (113), so that the second motor (301) can drive the second roll pressing column (302) to rotate counterclockwise, and the counterclockwise rotating second roll pressing column (302) can drive the first and third roll pressing columns (302) to rotate clockwise through the meshing of the third gears (304), so as to bite the extruded diaphragm into a W shape and roll it into shape.

7. A PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine according to claim 6, characterized in that: A second transmission disc (303) is fixedly installed at one end of one group of the roll pressing columns (302), and the other end of the transmission belt (114) is sleeved on the outer surface of the second transmission disc (303), so that when the roll pressing column (302) is driven to rotate, the second transmission disc (303) will be driven by the transmission belt (114) to drive the winding column (108) to rotate in the two U-shaped grooves (107).

8. A PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine according to claim 1, characterized in that: The stretching mechanism (4) includes two triangular plates (402), the two triangular plates (402) are respectively rotatably installed at both ends in the U-shaped frame (101), and three guide rail grooves (403) are opened at the inner ends of the two triangular plates (402), guide rail blocks (404) are slidably installed in the three guide rail grooves (403), and a top support wheel (405) is rotatably installed between each two vertically opposite guide rail blocks (404).

9. A PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine according to claim 8, characterized in that: One end of the inner side of each of the three groups of guide rail blocks (404) is rotatably installed with a push-pull rod (406), and the other ends of the three groups of push-pull rods (406) are rotatably installed on the outer surface of the push plate (407). The push plate (407) is rotatably installed on the outer surface of the piston rod of the first electric push rod (408). The first electric push rod (408) is fixedly installed at one end of the U-shaped frame (101), so that the first electric push rod (408) can drive the three groups of push-pull rods (406) to push or pull the three groups of guide rail blocks (404) to slide synchronously inwards or outwards in the three groups of guide rail grooves (403) by pushing or pulling the push plate (407), thereby realizing the adjustment of the top support distance of the top support wheel (405).

10. A PPS hydrogen energy diaphragm high-temperature sintering and stretching integrated machine according to claim 9, characterized in that: A third motor (401) is fixedly installed at one end of the U-shaped frame (101), and the output shaft of the third motor (401) rotates through the U-shaped frame (101) and is fixedly connected to one of the triangular plates (402).

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