Hydrogenation catalyst, process for its preparation and use

By introducing an amine complex of Fe and Mn into the hydrogenation catalyst and passing CO2 through it, the problem of catalyst carbon deposition is solved, the service life is extended and the activity is improved, making it suitable for the hydrogenation treatment of secondary processed oils with high unsaturated hydrocarbon content.

CN120571635BActive Publication Date: 2026-06-02CHINA PETROLEUM & CHEMICAL CORP +1

Patent Information

Authority / Receiving Office
CN Β· China
Patent Type
Patents(China)
Current Assignee / Owner
CHINA PETROLEUM & CHEMICAL CORP
Filing Date
2024-03-01
Publication Date
2026-06-02

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Abstract

The application discloses a hydrogenation catalyst, a preparation method and application thereof. The catalyst comprises a sulfided hydrogenation catalyst and a complex of auxiliary metals Fe and Mn, wherein the complex of auxiliary metals Fe and Mn contains two or more amine groups and / or imine groups. The preparation method of the hydrogenation catalyst comprises the following steps: (1) preparing a sulfided hydrogenation catalyst; (2) preparing an impregnation solution by mixing a Fe source and a Mn source with a complexing agent; and (3) impregnating the sulfided hydrogenation catalyst in step (1) with the impregnation solution in step (2), and drying to obtain the hydrogenation catalyst. The catalyst can realize reverse conversion of carbon deposition precursors to a certain extent, and is particularly suitable for a hydrogenation treatment process of secondary processing oil containing relatively high unsaturated hydrocarbons.
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