Preparation method of wear-resistant noise-reducing material suitable for brake pad of two-wheeled vehicle
By preparing a combination of Ni-Fe alloy powder, hard phase reinforcement particles, solid lubricants and microfibers, the problems of low-speed noise, wear resistance and friction stability of two-wheeled vehicle friction materials were solved, and efficient braking performance and noise reduction effects were achieved.
Patent Information
- Application Number
- CN202511183965.3
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2025-08-22
- Publication Date
- 2025-10-10
AI Technical Summary
Existing friction materials for two-wheeled vehicles produce high-frequency braking noise at low speeds, have unsatisfactory wear resistance, and unstable friction performance. In particular, the friction coefficient decreases under high temperature conditions. There is a lack of technical solutions to simultaneously optimize wear resistance, friction stability, and noise reduction.
A wear-resistant and noise-reducing material is prepared by mixing, pressing and hot-pressing sintering a combination of Ni-Fe alloy powder, hard phase reinforcement particles, solid lubricant, microfiber and organic binder. A microporous damping structure is introduced to form stable friction performance.
It significantly reduces braking noise, improves friction coefficient and wear resistance, and adapts to the braking needs of high-speed and low-speed two-wheeled vehicles.
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Figure BDA0005561591460000101
Abstract
Description
Technical Field
[0001] The invention relates to the field of friction brake materials, in particular to a method for preparing a wear-resistant noise-reducing material suitable for a two-wheeled vehicle brake pad. Background Art
[0002] Two-wheeled vehicle braking systems (such as motorcycles and electric vehicles) widely use non-asbestos organic friction materials, semi-metallic materials, or ceramic-reinforced friction materials. Although these materials have certain braking performance, they are prone to the following problems in actual use:
[0003] Prominent brake noise: Especially during low-speed coasting, the initial braking phase, or wet conditions, a high-frequency "squealing" noise, also known as brake squeal, is easily generated between the friction pad and the brake disc. Prior art research has proposed reducing brake noise through coatings or surface treatments. For example, patent US11655864B2 reduces friction-induced vibration noise by applying a graphite-containing thermosetting resin coating to the friction pad surface.
[0004] Poor wear resistance: Two-wheeled vehicles often experience frequent starts and stops, and high braking frequency, which can lead to rapid wear of friction materials. While some improved materials improve wear resistance, this often sacrifices friction coefficient stability and noise control.
[0005] Unstable friction performance: Particularly under high-temperature or thermal decay conditions, the friction coefficient of some metal-based friction materials decreases significantly, making them unsuitable for high-speed braking. For example, patent US11635120B2 states that using Ni or Ni-Fe as a metal matrix, incorporating oxide or nitride particles and solid lubricants, can improve high-temperature stability and friction performance, but lacks systematic optimization for noise control.
[0006] In the prior art, some have proposed using organic fillers (such as cashew nut shell powder and rubber particles) as friction modifiers to improve chemical stability, reduce noise, and enhance wear resistance. For example, Nisshinbo Industries' patent proposes that by adding 2–20 vol% cashew nut shell powder, 10–25 vol% rubber particles, and a small amount of solid lubricant, the braking static friction coefficient can be increased and noise can be suppressed, but it is not specifically designed for the vibration characteristics of two-wheeled vehicles. Another Japanese patent, JP2014251547, also points out that the use of straight novolak-type phenolic resin can effectively suppress low-frequency noise, and its lower elastic modulus helps to reduce the stick-slip phenomenon.
[0007] In summary, although the existing two-wheeled vehicle friction material technology has made progress in some aspects, it still has the following shortcomings:
[0008] There is little suppression of high-frequency brake noise generated by two-wheeled vehicles at low speeds; existing patents mostly focus on passenger cars or heavy-duty vehicles; there is a lack of systematic technical solutions that can coordinate the design of hard phase reinforcement, solid lubricants and organic fillers to balance wear resistance, friction stability and noise reduction performance; in particular, there is a lack of methods for preparing friction materials that introduce fiber or microporous structures to improve damping and reduce noise based on the vibration characteristics of two-wheeled vehicles. Summary of the Invention
[0009] Based on the above-mentioned technical status, the present invention proposes a preparation method of a wear-resistant and noise-reducing material suitable for two-wheeled vehicle brake pads. By rationally selecting metal matrix powder, hard phase reinforcement material, solid lubricant, organic filler and microfiber, they work together to improve friction performance, wear resistance and noise control, and have better performance in working stability and adaptability to extreme conditions.
[0010] The technical solution is as follows:
[0011] A method for preparing a wear-resistant and noise-reducing material suitable for a two-wheeled vehicle brake pad comprises the following steps:
[0012] 1) Ingredients stage, by mass
[0013] Ni-Fe alloy powder: 40-60 parts;
[0014] Hard phase reinforcement particles: 18-35 parts;
[0015] Solid lubricant: 4-12 parts;
[0016] Microfiber reinforcement: 4-10 parts;
[0017] Organic binder: 10-20 parts;
[0018] Lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive: 0.5-2 parts;
[0019] Filler / damping agent: the rest up to a total of 145 parts;
[0020] 2) Mixing process
[0021] All ingredients are mixed evenly in a ball mill or V-type mixer for 10-30 minutes;
[0022] 3) Press molding
[0023] Press the mixture onto the metal backing plate with a certain pressure and hold it for 30-60 seconds;
[0024] 4) Hot pressing sintering / curing
[0025] If hot pressing sintering is used: set the temperature to 200-300℃ and keep warm for 1-3 hours;
[0026] If compression curing is used: temperature 130-160°C, pressure 20-50 MPa, hold pressure for 2-8 minutes
[0027] 5) Post-processing stage
[0028] Post-cure at set temperature for 1-2 hours to perfect the bonding network.
[0029] Preferably, the hard phase reinforcement particles are a mixture of ZrO2, TiO2, and mullite, with ZrO2: 6-14 parts, TiO2: 6-14 parts, and mullite: 6-14 parts.
[0030] Preferably, the solid lubricant comprises 15-35wt% of MoS2, 5-15wt% of BN, 5-15wt% of FeS, and the rest is graphite.
[0031] Preferably, the microfiber reinforcement material is selected from aramid fibers or microcellulose fibers.
[0032] Preferably, the organic binder is selected from phenolic resin, epoxy-modified phenolic resin, polyvinyl acetal-modified phenolic resin or cashew nut shell oil-modified phenolic resin.
[0033] Preferably, the filler / damping agent is selected from rubber powder, graphite powder, and talc powder.
[0034] Preferably, the preparation method of the lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive is:
[0035] According to parts by mass, 20-30 parts of cashew nut shell liquid-modified phenolic resin and 6-10 parts of 5-carboxyindazole are added to 30-40 parts of toluene, 1-3 parts of zinc chloride are added as a catalyst, and an acylation reaction is carried out at a temperature of 80-90°C. After a period of reaction, the system is cooled, 0.03-0.08 parts of La(NO3)3·6H2O are added, and the reaction is continued for 2-5 hours. After post-treatment, a lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive is obtained.
[0036] Preferably, the rotation speed in the mixing process is 60-150 rpm.
[0037] Preferably, the pressure during the compression molding is 100-200 MPa.
[0038] Preferably, the curing temperature is 300-350°C.
[0039] Reaction mechanism: 5-carboxyindazole is grafted onto the molecular chain of cashew nut shell oil phenolic resin through acylation reaction, which enhances the rigidity and thermal stability of the resin; La 3+It coordinates with indazole and other groups to form a stable chemical structure, which can form a uniform transfer film during the friction process and improve the friction performance.
[0040] Technical effect:
[0041] The composite friction material produced by the preparation method described herein, through hard phase reinforcement, lubricant ratio, and microfiber-introduced microporous damping structure, not only improves friction coefficient and wear resistance, but also effectively suppresses braking noise. It is particularly suitable for braking applications on high- and low-speed two-wheeled vehicles. DETAILED DESCRIPTION
[0042] In order to further explain the technical solution of the present invention, the following is a detailed description of the embodiment 1.
[0043] 1. Batching stage (by mass, total 145kg)
[0044] Ni-Fe alloy powder: 40kg;
[0045] Hard phase reinforcement particles: 18 kg (ZrO2: 6 kg, TiO2: 6 kg, mullite: 6 kg, total 18 kg);
[0046] Solid lubricant: 4 kg (MoS2 accounts for 15 wt%, i.e., 0.6 kg; BN accounts for 5 wt%, i.e., 0.2 kg; FeS accounts for 5 wt%, i.e., 0.2 kg; the rest is graphite, i.e., 4-0.6-0.2-0.2=3 kg);
[0047] Microfiber reinforcement material: 4kg (selected from aramid fibers);
[0048] Organic binder: 10kg (selected from phenolic resin);
[0049] Lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive: 0.5 kg (preparation method: 20 kg cashew nut shell oil-modified phenolic resin and 6 kg 5-carboxyindazole are added to 30 kg toluene, 1 kg zinc chloride is added as a catalyst, and an acylation reaction is carried out at 80°C for 2 hours; then the system is cooled to 50°C, 0.03 kg La(NO3)3·6H2O is added, and the reaction is continued for 2 hours; after the reaction is completed, the mixture is filtered and the filter cake is vacuum dried at 80°C for 4 hours to obtain the additive);
[0050] Filler / damping agent: 145-(40+18+4+4+10+0.5)=68.5kg (selected from rubber powder).
[0051] 2. Mixing process
[0052] Add the above-mentioned Ni-Fe alloy powder, hard phase reinforcement particles, solid lubricant, organic binder, additives, filler / damping agent (powder type) and microfiber reinforcement material (fiber type) into a V-type mixer, set the speed to 60 rpm, and mix for 10 minutes to ensure that the materials are evenly dispersed.
[0053] 3. Pressing
[0054] The evenly mixed material is pressed onto the metal backing plate at a pressure of 100 MPa for 30 seconds to ensure the initial bonding between the material and the backing plate.
[0055] 4. Hot pressing sintering / curing
[0056] The hot pressing sintering process is adopted: the temperature is set to 200℃, kept warm for 1 hour, and the sintering molding is completed.
[0057] 5. Post-processing stage
[0058] Post-curing is performed at a set temperature of 300°C for 1 hour to improve the cross-linking network of the organic binder and enhance the bonding strength of the material.
[0059] Example 2
[0060] 1. Batching stage (by mass, total 145kg)
[0061] Ni-Fe alloy powder: 48 kg (8 kg higher than in Example 1, in the range of 40-60 kg);
[0062] Hard phase reinforcement particles: 24kg (ZrO2: 8kg, TiO2: 8kg, mullite: 8kg, total 24kg);
[0063] Solid lubricant: 7 kg (MoS2 accounts for 22 wt%, i.e., 1.54 kg; BN accounts for 8 wt%, i.e., 0.56 kg; FeS accounts for 8 wt%, i.e., 0.56 kg; the remainder is graphite, i.e., 7-1.54-0.56-0.56=4.34 kg);
[0064] Microfiber reinforcement material: 6 kg (selected from microcellulose fibers, 2 kg more than in Example 1);
[0065] Organic binder: 14 kg (selected from epoxy-modified phenolic resin, 4 kg more than that in Example 1);
[0066] Lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive: 1 kg (preparation method: 24 kg cashew nut shell oil-modified phenolic resin and 7 kg 5-carboxyindazole were added to 33 kg toluene, and 1.5 kg zinc chloride was added as a catalyst. The acylation reaction was carried out at 83°C for 2.5 hours; then the temperature was lowered to 55°C, 0.05 kg La(NO3)3·6H2O was added, and the reaction was continued for 3 hours; after filtering, the filter cake was vacuum dried at 85°C for 4.5 hours to obtain the additive);
[0067] Filler / damping agent: 145-(48+24+7+6+14+1)=44kg (selected from graphite powder).
[0068] 2. Mixing process
[0069] Add all materials to the ball mill, set the speed to 90 rpm, and mix for 18 minutes to ensure that the fiber and powder are fully mixed without agglomeration.
[0070] 3. Pressing
[0071] The material is pressed onto the metal backing plate at a pressure of 130 MPa for 40 seconds to increase the density of the material.
[0072] 4. Hot pressing sintering / curing
[0073] The molding curing process is adopted: temperature 140℃, pressure 30MPa, holding pressure for 4 minutes to complete the curing molding.
[0074] 5. Post-processing stage
[0075] Post-curing at 320 °C for 1.3 hours further optimized the internal structure of the material.
[0076] Example 3
[0077] 1. Batching stage (by mass, total 145kg)
[0078] Ni-Fe alloy powder: 55 kg (close to the upper limit of 40-60 kg, 7 kg higher than Example 2);
[0079] Hard phase reinforcement particles: 30kg (ZrO2: 12kg, TiO2: 12kg, mullite: 6kg, total 30kg);
[0080] Solid lubricant: 10 kg (MoS2 accounts for 30 wt%, i.e., 3 kg; BN accounts for 12 wt%, i.e., 1.2 kg; FeS accounts for 12 wt%, i.e., 1.2 kg; the remainder is graphite, i.e., 10-3 - 1.2 - 1.2 = 4.6 kg);
[0081] Microfiber reinforcement material: 8 kg (selected from aramid fiber, 2 kg more than in Example 2);
[0082] Organic binder: 18 kg (selected from polyvinyl acetal modified phenolic resin, close to the upper limit of 10-20 kg);
[0083] Lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive: 1.5 kg (preparation method: 28 kg cashew nut shell oil-modified phenolic resin and 9 kg 5-carboxyindazole are added to 38 kg toluene, 2.5 kg zinc chloride is added as a catalyst, and an acylation reaction is carried out at 88°C for 3 hours; after cooling to 60°C, 0.07 kg La(NO3)3·6H2O is added and the reaction is continued for 4 hours; after filtering, the filter cake is vacuum dried at 90°C for 5 hours to obtain the additive);
[0084] Filler / damping agent: 145-(55+30+10+8+18+1.5)=22.5 kg (selected from talc).
[0085] 2. Mixing process
[0086] Add the material to the V-type mixer, set the speed to 130 rpm, and mix for 25 minutes to ensure that a high ratio of powder and fiber is evenly mixed.
[0087] 3. Pressing
[0088] The material is pressed onto the metal backing plate at a pressure of 180 MPa and maintained for 50 seconds to further improve the density of the material and the bonding strength with the backing plate.
[0089] 4. Hot pressing sintering / curing
[0090] The hot pressing sintering process is adopted: temperature 280℃, heat preservation for 2.5 hours, taking into account both sintering efficiency and material performance.
[0091] 5. Post-processing stage
[0092] Post-curing at 340°C for 1.8 hours fully completes the bonding network.
[0093] Example 4
[0094] 1. Batching stage (by mass, total 145kg)
[0095] Ni-Fe alloy powder: 60kg (reaching the upper limit of 40-60kg);
[0096] Hard phase reinforcement particles: 35kg (ZrO2: 14kg, TiO2: 14kg, mullite: 7kg, total 35kg);
[0097] Solid lubricant: 12 kg (MoS2 accounts for 35 wt%, i.e., 4.2 kg; BN accounts for 15 wt%, i.e., 1.8 kg; FeS accounts for 15 wt%, i.e., 1.8 kg; the remainder is graphite, i.e., 12 - 4.2 - 1.8 - 1.8 = 4.2 kg);
[0098] Microfiber reinforcement: 10 kg (selected from microcellulose fibers, reaching an upper limit of 4-10 kg);
[0099] Organic binder: 20 kg (selected from cashew nut shell liquid modified phenolic resin, reaching the upper limit of 10-20 kg);
[0100] Lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive: 2 kg (preparation method: 30 kg cashew nut shell oil-modified phenolic resin and 10 kg 5-carboxyindazole are added to 40 kg toluene, 3 kg zinc chloride is added as a catalyst, and an acylation reaction is carried out at 90°C for 3.5 hours; after cooling to 65°C, 0.08 kg La(NO3)3·6H2O is added and the reaction is continued for 5 hours; after filtering, the filter cake is vacuum dried at 95°C for 6 hours to obtain the additive);
[0101] Filler / damping agent: 145-(60+35+12+10+20+2)=6kg (selected from rubber powder and graphite powder mixed in a ratio of 1:1, i.e. 3kg each).
[0102] 2. Mixing process
[0103] Add the materials into the ball mill, set the speed to 150 rpm, and mix for 30 minutes to ensure that the high viscosity organic binder is fully dispersed with other materials.
[0104] 3. Pressing
[0105] The material is pressed onto the metal backing plate at a pressure of 200 MPa and maintained for 60 seconds to reach the upper limit of the pressing pressure and time to maximize the density of the material.
[0106] 4. Hot pressing sintering / curing
[0107] The molding curing process is adopted: temperature 160℃ (reaching the upper limit of 130-160℃), pressure 50MPa (reaching the upper limit of 20-50MPa), holding pressure for 8 minutes (reaching the upper limit of 2-8 minutes) to complete efficient curing.
[0108] 5. Post-processing stage
[0109] Post-curing at 350°C (reaching the upper limit of 300-350°C) for 2 hours (reaching the upper limit of 1-2 hours) finally improves the material bonding network and performance.
[0110] Comparative Example 1
[0111] 1. Batching stage (by mass, total 145kg)
[0112] Ni-Fe alloy powder: 40kg;
[0113] Hard phase reinforcement particles: 18 kg (ZrO2: 6 kg, TiO2: 6 kg, mullite: 6 kg, total 18 kg);
[0114] Solid lubricant: 4 kg (MoS2 accounts for 15 wt%, i.e., 0.6 kg; BN accounts for 5 wt%, i.e., 0.2 kg; FeS accounts for 5 wt%, i.e., 0.2 kg; the rest is graphite, i.e., 4-0.6-0.2-0.2=3 kg);
[0115] Microfiber reinforcement material: 4kg (selected from aramid fibers);
[0116] Organic binder: 10kg (selected from phenolic resin);
[0117] Filler / damping agent: 145-(40+18+4+4+10)=69kg (selected from rubber powder).
[0118] 2. Mixing process
[0119] Add the above-mentioned Ni-Fe alloy powder, hard phase reinforcement particles, solid lubricant, organic binder, additives, filler / damping agent (powder type) and microfiber reinforcement material (fiber type) into a V-type mixer, set the speed to 60 rpm, and mix for 10 minutes to ensure that the materials are evenly dispersed.
[0120] 3. Pressing
[0121] The evenly mixed material is pressed onto the metal backing plate at a pressure of 100 MPa for 30 seconds to ensure the initial bonding between the material and the backing plate.
[0122] 4. Hot pressing sintering / curing
[0123] The hot pressing sintering process is adopted: the temperature is set to 200℃, kept warm for 1 hour, and the sintering molding is completed.
[0124] 5. Post-processing stage
[0125] Post-curing is performed at a set temperature of 300°C for 1 hour to improve the cross-linking network of the organic binder and enhance the bonding strength of the material.
[0126] Comparative Example 2
[0127] 1. Batching stage (by mass, total 145kg)
[0128] Ni-Fe alloy powder: 40kg;
[0129] Hard phase reinforcing particles: 18 kg (ZrO2: 6 kg, TiO2: 6 kg, mullite: 6 kg, total 18 kg);
[0130] Solid lubricant: 4 kg (MoS2: 15 wt%, i.e. 0.6 kg; BN: 5 wt%, i.e. 0.2 kg; FeS: 5 wt%, i.e. 0.2 kg; the rest is graphite, i.e. 4-0.6-0.2-0.2 = 3 kg);
[0131] Micro-fiber reinforcing material: 4 kg (selected from aramid fiber);
[0132] Organic binder: 10 kg (selected from phenolic resin);
[0133] Lanthanum (III)-indazolyl-kernel oil phenolic resin additive: 0.5 kg (preparation method: 20 kg of kernel oil modified phenolic resin is added to 30 kg of toluene, 1 kg of zinc chloride is added as catalyst, and acylation reaction is carried out at 80°C for 2 hours; then the system is cooled to 50°C, 0.03 kg of La(NO3)3·6H2O is added, and the reaction is continued for 2 hours; after the reaction is completed, filtration is carried out, the filter cake is dried at 80°C under vacuum for 4 hours, and the additive is obtained);
[0134] Filling / damping agent: 145-(40+18+4+4+10+0.5) = 68.5 kg (selected from rubber powder).
[0135] 2. Mixing process
[0136] The above Ni-Fe alloy powder, hard phase reinforcing particles, solid lubricant, organic binder, additive, filling / damping agent (powder type) and micro-fiber reinforcing material (fiber type) are added to a V-type mixer, the rotating speed is set to 60 rpm, and mixing is carried out for 10 minutes to ensure uniform dispersion of the materials.
[0137] 3. Press forming
[0138] The uniformly mixed materials are pressed on a metal back plate at a pressure of 100 MPa, and maintained for 30 seconds to ensure preliminary bonding of the materials to the back plate.
[0139] 4. Hot pressing sintering / curing
[0140] The hot pressing sintering process is adopted: the temperature is set to 200°C, and the sintering is completed after maintaining for 1 hour.
[0141] 5. Post-treatment stage
[0142] Post-curing is carried out at a temperature of 300°C for 1 hour to perfect the crosslinking network of the organic binder and improve the bonding strength of the material.
[0143] Comparative Example 3
[0144] 1. Batching stage (by mass, total 145kg)
[0145] Ni-Fe alloy powder: 40kg;
[0146] Hard phase reinforcement particles: 18 kg (ZrO2: 6 kg, TiO2: 6 kg, mullite: 6 kg, total 18 kg);
[0147] Solid lubricant: 4 kg (MoS2 accounts for 15 wt%, i.e., 0.6 kg; BN accounts for 5 wt%, i.e., 0.2 kg; FeS accounts for 5 wt%, i.e., 0.2 kg; the rest is graphite, i.e., 4-0.6-0.2-0.2=3 kg);
[0148] Microfiber reinforcement material: 4kg (selected from aramid fibers);
[0149] Organic binder: 10kg (selected from phenolic resin);
[0150] Lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive: 0.5 kg (preparation method: 20 kg of cashew nut shell oil-modified phenolic resin and 6 kg of 5-carboxyindazole are added to 30 kg of toluene, and 1 kg of zinc chloride is added as a catalyst. The acylation reaction is carried out at 80°C for 2 hours; after the reaction is completed, the mixture is filtered and the filter cake is vacuum dried at 80°C for 4 hours to obtain the additive);
[0151] Filler / damping agent: 145-(40+18+4+4+10+0.5)=68.5kg (selected from rubber powder).
[0152] 2. Mixing process
[0153] Add the above-mentioned Ni-Fe alloy powder, hard phase reinforcement particles, solid lubricant, organic binder, additives, filler / damping agent (powder type) and microfiber reinforcement material (fiber type) into a V-type mixer, set the speed to 60 rpm, and mix for 10 minutes to ensure that the materials are evenly dispersed.
[0154] 3. Pressing
[0155] The evenly mixed material is pressed onto the metal backing plate at a pressure of 100 MPa for 30 seconds to ensure the initial bonding between the material and the backing plate.
[0156] 4. Hot pressing sintering / curing
[0157] The hot pressing sintering process is adopted: the temperature is set to 200℃, kept warm for 1 hour, and the sintering molding is completed.
[0158] 5. Post-processing stage
[0159] Post-curing is performed at a set temperature of 300°C for 1 hour to improve the cross-linking network of the organic binder and enhance the bonding strength of the material.
[0160] Test method:
[0161] 1. Friction coefficient and wear rate test
[0162] The friction coefficient (μ) and wear rate tests were carried out according to QC / T654-2005 motorcycle and moped brake bench test method.
[0163] The sample was mounted on a standard motorcycle disc brake test bench and 50 braking cycles were performed at different braking stages (low speed, medium speed, and high speed). The friction force and normal force were measured to calculate the μ average value.
[0164] The friction plate is accurately weighed before and after the test to calculate the wear mass.
[0165] 2. Noise test
[0166] The NVH test method is based on the SAE J2521 standard and is carried out on a brake test rig in the acoustic laboratory.
[0167] The sound pressure level (dBA) during each braking process was collected, with particular attention paid to the high frequency range (>1kHz). The average of 20 tests was calculated to represent the noise level.
[0168] Test results:
[0169] Table 1 Test results
[0170]
[0171]
[0172] The above test method and results demonstrate the beneficial effects of the method through the indicators of friction coefficient, wear rate and noise value.
[0173] The above description of the disclosed embodiments is intended to enable one skilled in the art to implement or use the present invention. Various modifications to these embodiments will be readily apparent to one skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the present invention. Therefore, the present invention is not limited to the embodiments shown herein but is intended to conform to the widest scope consistent with the principles and novel features disclosed herein.
Claims
1. A method for preparing a wear-resistant and noise-reducing material suitable for two-wheeled vehicle brake pads, characterized in that: The following steps are involved: 1) Ingredients stage, by mass Ni-Fe alloy powder: 40-60 parts; Hard phase reinforcement particles: 18-35 parts; Solid lubricant: 4-12 parts; Microfiber reinforcement: 4-10 parts; Organic binder: 10-20 parts; Lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive: 0.5-2 parts; Filler / damping agent: the rest up to a total of 145 parts; 2) Mixing process All ingredients are mixed evenly in a ball mill or V-type mixer for 10-30 minutes; 3) Press molding Press the mixture onto the metal backing plate with a certain pressure and hold it for 30-60 seconds; 4) Hot pressing sintering / curing If hot pressing sintering is used: set the temperature to 200-300℃ and keep warm for 1-3 hours; If compression curing is used: temperature 130-160°C, pressure 20-50 MPa, hold pressure for 2-8 minutes 5) Post-processing stage Post-cure at set temperature for 1-2 hours to perfect the bonding network; The lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive is prepared by reacting cashew nut shell oil-modified phenolic resin, 5-carboxy indazole, zinc chloride and La(NO3)3·6H2O.
2. The method for preparing a wear-resistant and noise-reducing material suitable for a two-wheeled vehicle brake pad according to claim 1, characterized in that: The hard phase reinforcement particles are a mixture of ZrO2, TiO2 and mullite, with ZrO2 being 6-14 parts, TiO2 being 6-14 parts and mullite being 6-14 parts.
3. The method for preparing a wear-resistant and noise-reducing material suitable for a two-wheeled vehicle brake pad according to claim 1, characterized in that: The solid lubricant comprises 15-35 wt% of MoS2, 5-15 wt% of BN, 5-15 wt% of FeS, and the remainder is graphite.
4. The method for preparing a wear-resistant and noise-reducing material suitable for a two-wheeled vehicle brake pad according to claim 1, characterized in that: The microfiber reinforcement material is selected from aramid fibers or microcellulose fibers.
5. The method for preparing a wear-resistant and noise-reducing material suitable for a two-wheeled vehicle brake pad according to claim 1, characterized in that: The organic binder is selected from phenolic resin, epoxy-modified phenolic resin, polyvinyl acetal-modified phenolic resin or cashew nut shell oil-modified phenolic resin.
6. The method for preparing a wear-resistant and noise-reducing material suitable for a two-wheeled vehicle brake pad according to claim 1, characterized in that: The filler / damping agent is selected from rubber powder, graphite powder and talc powder.
7. The method for preparing a wear-resistant and noise-reducing material suitable for a two-wheeled vehicle brake pad according to claim 1, characterized in that: The preparation method of the lanthanum (III)-indazole-cashew nut shell oil phenolic resin auxiliary agent: According to parts by mass, 20-30 parts of cashew nut shell liquid-modified phenolic resin and 6-10 parts of 5-carboxyindazole are added to 30-40 parts of toluene, 1-3 parts of zinc chloride are added as a catalyst, and an acylation reaction is carried out at a temperature of 80-90°C. After a period of reaction, the system is cooled, 0.03-0.08 parts of La(NO3)3·6H2O are added, and the reaction is continued for 2-5 hours. After post-treatment, a lanthanum (III)-indazole-cashew nut shell oil phenolic resin additive is obtained.
8. The method for preparing a wear-resistant and noise-reducing material suitable for a two-wheeled vehicle brake pad according to claim 1, characterized in that: The rotation speed in the mixing process is 60-150 rpm.
9. The method for preparing a wear-resistant and noise-reducing material suitable for a two-wheeled vehicle brake pad according to claim 1, characterized in that: The pressure during the compression molding is 100-200 MPa.
10. The method for preparing a wear-resistant and noise-reducing material suitable for a two-wheeled vehicle brake pad according to claim 1, characterized in that: The curing temperature is 300-350°C.
Citation Information
Patent Citations
friction material
JP5953362B2