Coated glass and vehicle

Abstract

The invention provides coated glass and a vehicle. The coated glass comprises a glass substrate and a coating structure arranged on the glass substrate, the coating structure comprises a reflection increasing layer and a functional lamination layer, and the functional lamination layer comprises at least two functional layers and a middle layer arranged between the two functional layers; the coated glass is provided with an outer surface and an inner surface which are opposite to each other, the reflection increasing layer is closer to the outer surface than the functional laminated layer, the reflectivity of the outer surface is greater than that of the inner surface, the total solar transmittance Tts of the coated glass is less than or equal to 10%, and the transmittance Lab1 value of the coated glass meets the following conditions:-3 < = a1 < = 1,-13 < = b1 < =-2. The reflection increasing layer and the functional lamination layer are matched with each other, so that the coated glass has low in-vehicle reflectivity and neutral perspective color, passengers can observe a more natural scene outside the vehicle, the coated glass has low solar total transmittance, more heat can be reflected, radiation of sunlight in the vehicle is reduced, reflection of heat outside the vehicle is realized, and the service life of the vehicle is prolonged. And overheating in the vehicle in summer is avoided.

Description

Technical Field

[0001] This application belongs to the field of coated glass technology, specifically relating to coated glass and vehicles. Background Technology

[0002] One-way glass, due to its one-way visibility function, is often used in car sunroofs. However, when traditional one-way glass is used inside a car, the excessive reflectivity of the interior affects the passenger experience and the one-way function. Not only is the reflectivity of the glass unacceptable, but it also fails to consider the visibility of colors. The view through the sunroof glass often appears with an orange "filter," causing discomfort to passengers and affecting the vehicle's aesthetics. Summary of the Invention

[0003] In view of this, the first aspect of this application provides a coated glass, the coated glass including a glass substrate and a coating structure disposed on the glass substrate, the coating structure including an anti-reflection layer and a functional stack layer stacked thereon, the functional stack layer including at least two functional layers and an intermediate layer disposed between the two functional layers; The coated glass has an outer surface and an inner surface, the anti-reflective layer is closer to the outer surface than the functional stack, the reflectivity of the outer surface is greater than the reflectivity of the inner surface, the total solar transmittance Tts of the coated glass is ≤10%, and the transmittance Lab1 value of the coated glass satisfies: -3≤a1≤1, -13≤b1≤-2.

[0004] Wherein, the reflectivity of the outer surface is ≥60%, and the Lab2 value of the outer surface reflection of the coated glass satisfies: -7≤a2≤0, -1≤b2≤1.

[0005] Wherein, the reflectivity of the inner surface is ≤8%, and the Lab3 value of the inner surface reflection of the coated glass satisfies: -1≤a3≤1, -1≤b3≤1.

[0006] The material of the functional layer is selected from at least one of Ag, Au, Cu, Al and their alloys; And / or, the material of the intermediate layer is selected from oxides, nitrides or oxynitrides of at least one element selected from Si, Zn, Mg, Sn, Ti, Nb, Zr, In and Al.

[0007] The ratio between the total thickness of the functional layers and the total thickness of the intermediate layers in the coating structure is 0.4 to 1.2. And / or, the total thickness of the functional layers in the coating structure is 20nm~70nm; And / or, the total thickness of the intermediate layer in the coating structure is 20nm~140nm.

[0008] The at least two functional layers include a first functional layer and a second functional layer, and the intermediate layer includes a first intermediate layer, which is disposed between the first functional layer and the second functional layer.

[0009] The first functional layer is closer to the enhancement and reflection layer than the second functional layer. The thickness ratio of the first functional layer to the second functional layer is 1 to 5. And / or, the thickness ratio of the first functional layer to the first intermediate layer is 0.2 to 1.1.

[0010] The at least two functional layers include a first functional layer, a second functional layer, and a third functional layer. The intermediate layer includes a first intermediate layer and a second intermediate layer. The first intermediate layer is located between the first functional layer and the second functional layer, and the second intermediate layer is located between the second functional layer and the third functional layer.

[0011] Wherein, the first functional layer is closer to the enhancement and reflection layer than the second functional layer, and the second functional layer is closer to the enhancement and reflection layer than the third functional layer; The thickness of the first functional layer is d1, the thickness of the second functional layer is d2, the thickness of the third functional layer is d3, the thickness of the first intermediate layer is d4, the thickness of the second intermediate layer is d5, and the functional stack satisfies at least one of the following conditions: 3≤(d1+d2) / d3≤10; And / or, 0.5≤d4 / d5≤1.8; And / or, 0.6≤(d1+d2) / d5≤2.5.

[0012] The at least two functional layers include a first functional layer, a second functional layer, a third functional layer, and a fourth functional layer, and the intermediate layer includes a first intermediate layer, a second intermediate layer, and a third intermediate layer. The first intermediate layer is disposed between the first functional layer and the second functional layer, the second intermediate layer is disposed between the second functional layer and the third functional layer, and the third intermediate layer is disposed between the third functional layer and the fourth functional layer.

[0013] The anti-reflection layer includes at least one anti-reflection stack, and each anti-reflection stack includes a high refractive index layer and a low refractive index layer.

[0014] The high refractive index layer has a refractive index of 1.98 to 2.72, and the low refractive index layer has a refractive index of 1.45 to 1.65. And / or, the material of the high refractive index layer is selected from oxides of at least one element selected from Zn, Sn, Nb, Ti, Cr, Ta and Zr, or includes one or more nitrides and oxynitrides of at least one element selected from Si, Zr and Al; And / or, the material of the low refractive index layer is selected from oxides of at least one element selected from Si, Al and B, or fluorides including at least one element selected from Mg, Al and Ba; And / or, the total thickness of the high refractive index layer in the antireflection layer is 30 nm to 110 nm; And / or, the total thickness of the low-refractive-index layer in the antireflective layer is 40nm~180nm.

[0015] The anti-reflection layer includes two anti-reflection stacks: a first anti-reflection stack and a second anti-reflection stack, wherein the second anti-reflection stack is closer to the outer surface than the first anti-reflection stack. The thickness ratio of the high-refractive-index layer in the first anti-reflection layer to the high-refractive-index layer in the second anti-reflection layer is 0.7 to 1.6. And / or, the thickness ratio of the low-refractive-index layer in the first anti-stack layer to the low-refractive-index layer in the second anti-stack layer is 0.7~1; And / or, the ratio of the total thickness of the low-refractive-index layer in the first anti-stack layer and the second anti-stack layer to the total thickness of the high-refractive-index layer in the first anti-stack layer and the second anti-stack layer is 1 to 2.3.

[0016] The coating structure further includes a dielectric layer, which is disposed between the antireflective layer and the functional layer, and / or between the functional layer and the intermediate layer; The material of the dielectric layer is selected from at least one of AZO, Ti alloy, NbOx, TiOx, NiCr, NiCrOx, ZnAlOx, ZnOx, and SnOx, wherein x in SnOx satisfies: 1 < x ≤ 3; And / or, the thickness of the dielectric layer is 0.5 nm to 20 nm.

[0017] The coating structure further includes a protective layer, which is the film layer in the coating structure furthest from the glass substrate. The material of the protective layer is selected from oxides, nitrides or oxynitrides of at least one element selected from Si, Zn, Mg, Sn, Ti, Nb, Zr, In and Al. And / or, the thickness of the protective layer is 30nm~70nm; And / or, the coating structure further includes a dielectric layer disposed between the functional layer and the protective layer.

[0018] The coating structure further includes an adhesion layer, which is disposed on the side of the functional stack away from the antireflective layer and contacts the surface of the glass substrate. The material of the adhesion layer is selected from oxides, nitrides or nitrogen oxides of at least one element selected from Si, Zn, Mg, Sn, Ti, Nb, Zr, In and Al. And / or, the thickness of the adhesion layer is 30nm~70nm; And / or, the coating structure further includes a dielectric layer disposed between the functional layer and the adhesion layer.

[0019] The glass substrate is a single piece of glass, and the coating structure is disposed on one side of the single piece of glass.

[0020] The glass substrate includes a first glass plate, an intermediate adhesive layer and a second glass plate stacked in sequence. The side of the first glass plate facing away from the intermediate adhesive layer is the outer surface, and the side of the second glass plate facing away from the intermediate adhesive layer is the inner surface. The coating structure is disposed on the surface of the first glass plate facing the intermediate adhesive layer, or on the surface of the second glass plate facing the intermediate adhesive layer.

[0021] The coated glass further includes an infrared reflective layer, which is disposed on the surface of the second glass plate facing the intermediate adhesive layer or on the surface of the second glass plate away from the intermediate adhesive layer, and the emissivity E of the infrared reflective layer is ≤0.15.

[0022] And / or, the first glass plate is anti-glare glass.

[0023] The second aspect of this application provides a vehicle including a body and coated glass as provided in the first aspect of this application, the coated glass being disposed on the body.

[0024] This application provides coated glass and vehicles. By designing anti-reflective layers and functional layers in combination, the coated glass not only has low interior reflectivity and neutral color perception, making the outside scene observed by passengers more natural, but also has low total solar transmittance, which can reflect more heat, reduce the radiation of sunlight inside the vehicle, and reflect the heat from outside the vehicle, thus avoiding overheating inside the vehicle in summer. Attached Figure Description

[0025] To more clearly illustrate the technical solutions in the embodiments of this application, the accompanying drawings used in the embodiments of this application will be described below.

[0026] Figure 1 This is a schematic diagram of the structure of the coated glass provided in one embodiment of this application.

[0027] Figure 2 This is a schematic diagram of the structure of a coated glass provided in another embodiment of this application.

[0028] Labeling Explanation: Coated Glass 1, First Glass Plate 11, Intermediate Adhesive Layer 12, Second Glass Plate 13, First Functional Layer 21, Second Functional Layer 22, Third Functional Layer 23, First Intermediate Layer 31, Second Intermediate Layer 32, First Anti-overlap Layer 41, First High Refractive Index Layer 411, First Low Refractive Index Layer 412, Second Anti-overlap Layer 42, Second High Refractive Index Layer 421, Second Low Refractive Index Layer 422, Adhesive Layer 50, Protective Layer 60, Infrared Reflective Layer 70, First Dielectric Layer 81, Second Dielectric Layer 82, Third Dielectric Layer 83, Fourth Dielectric Layer 84, Fifth Dielectric Layer 85, Sixth Dielectric Layer 86. Detailed Implementation

[0029] The following are preferred embodiments of this application. It should be noted that, for those skilled in the art, several improvements and modifications can be made without departing from the principles of this application, and these improvements and modifications are also considered to be within the scope of protection of this application.

[0030] Unless otherwise stated or in case of conflict, the terms or phrases used in this application shall have the following meanings: In this application, "at least one" means any one, any two, or more of the listed items.

[0031] The value of x in the chemical formula: If it is clearly defined, the defined range shall prevail. If it is not clearly defined, it can be determined according to the stoichiometric, substoichiometric, or superstoichiometric deposition methods used in the magnetron sputtering process.

[0032] Refractive index: The refractive index measured at a wavelength of 550 nm.

[0033] To solve the above problems, please refer to the following: Figures 1-2 This embodiment provides a coated glass 1, which includes a glass substrate and a coating structure disposed on the glass substrate. The coating structure includes an anti-reflective layer and a functional stack layer stacked on top of each other. The functional stack layer includes at least two functional layers and an intermediate layer disposed between the two functional layers.

[0034] The coated glass 1 has an outer surface and an inner surface, the anti-reflective layer is closer to the outer surface than the functional stack, the reflectivity of the outer surface is greater than the reflectivity of the inner surface, the total solar transmittance Tts of the coated glass 1 is ≤10%, and the transmittance Lab1 value of the coated glass 1 satisfies: -3≤a1≤1, -13≤b1≤-2.

[0035] The outer surface of the coated glass 1 is in contact with the external environment of the vehicle, and the inner surface of the coated glass 1 is in contact with the internal environment of the vehicle.

[0036] The coating structure is disposed on a glass substrate. In one embodiment, the glass substrate is a monolithic glass, and the coating structure is disposed on one side of the monolithic glass. Optionally, the monolithic glass is selected from at least one of soda-lime glass, high-alumina glass, lithium aluminum glass, or borosilicate glass. Optionally, the monolithic glass is transparent glass or colored glass.

[0037] In another embodiment, the glass substrate includes a first glass plate 11, an intermediate adhesive layer 12 and a second glass plate 13 stacked in sequence, wherein the side of the first glass plate 11 facing away from the intermediate adhesive layer 12 is the outer surface and the side of the second glass plate 13 facing away from the intermediate adhesive layer 12 is the inner surface.

[0038] The coating structure is disposed on the surface of the first glass plate 11 facing the intermediate adhesive layer 12, or on the surface of the second glass plate 13 facing the intermediate adhesive layer 12. In this case, the coated glass 1 can also be understood as laminated glass.

[0039] Specifically, the first glass plate 11 serves as the outer glass plate of the laminated glass. The first glass plate 11 has a first surface and a second surface. The first surface is away from the intermediate adhesive layer 12 and in contact with the external environment of the vehicle, while the second surface is close to the intermediate adhesive layer 12. The second glass plate 13 serves as the inner glass plate of the laminated glass. The second glass plate 13 has a third surface and a fourth surface. The third surface is close to the intermediate adhesive layer 12, while the fourth surface is away from the intermediate adhesive layer 12 and in contact with the internal environment of the vehicle. The coating structure is located on either the second surface or the third surface.

[0040] The first glass plate 11 and the second glass plate 13 are either transparent glass or tinted glass, respectively. The thickness of the first glass plate 11 and the second glass plate 13 is 0.7 mm to 4 mm, respectively, and the visible light transmittance of the first glass plate 11 and the second glass plate 13 is greater than or equal to 80%. For example, the first glass plate 11 can be a 2.1 mm thick transparent glass with a visible light transmittance of 89%, and the second glass plate 13 can be a 1.6 mm thick green glass with a visible light transmittance of 83%, or a 2.1 mm thick green glass with a visible light transmittance of 80%.

[0041] The intermediate adhesive layer 12 is a transparent adhesive layer or a colored adhesive layer. The intermediate adhesive layer 12 is a thermoplastic polymer film, and its thickness is 0.38 mm to 2.28 mm, specifically, examples include 0.38 mm, 0.76 mm, 1.14 mm, 1.52 mm, 1.9 mm, or 2.28 mm. The visible light transmittance of the intermediate adhesive layer 12 is greater than or equal to 85%, specifically, examples include 85%, 90%, or 95%. The haze of the intermediate adhesive layer 12 is less than or equal to 1%, specifically, examples include 1%, 0.8%, 0.6%, or 0.4%. The material of the thermoplastic polymer film can be selected from at least one of polyvinyl butyral (PVB), polyurethane (PU), ethylene-vinyl acetate copolymer (EVA), and ionomer polymer (SGP). The colored thermoplastic polymer film can be a gray thermoplastic polymer film, a green thermoplastic polymer film, or a blue thermoplastic polymer film.

[0042] For example, the intermediate adhesive layer 12 can be a single-layer or multi-layer structure. Examples of multi-layer structures include double-layer, triple-layer, quadruple-layer, and five-layer structures. The intermediate adhesive layer 12 can also have other functions, such as providing at least one colored area as a shaded zone to reduce sunlight interference with the human eye, adding infrared absorbers to provide sun protection or heat insulation, adding ultraviolet absorbers to provide ultraviolet protection, or having at least one layer of the multi-layer structure with a higher plasticizer content to provide sound insulation.

[0043] The coated glass 1 can be used independently as vehicle window glass, or it can be made into laminated glass and used as vehicle window glass. Optionally, the coated glass 1 can be used as sunroof glass, rear windshield glass, side window glass, corner window glass, etc. of a vehicle.

[0044] The reflectivity of the outer surface is ≥60%, specifically, examples include 60%, 65%, 70%, 75%, 80%, 85%, or 90%, etc. Preferably, the reflectivity of the outer surface is ≥70%. More preferably, the reflectivity of the outer surface is ≥80%.

[0045] The Lab2 reflectance value of the outer surface of the coated glass 1 satisfies: -7≤a2≤0, -1≤b2≤1. The Lab2 reflectance value refers to the Lab value obtained by observing the color characteristics of the light reflected from the outer surface of the coated glass 1.

[0046] Specifically, a2 can be exemplified as -7, -6, -5, -4, -3, -2, -1, or 0, etc. Preferably, the Lab2 value of the outer surface reflection of the coated glass 1 satisfies: -5 ≤ a2 ≤ 0. More preferably, the Lab2 value of the outer surface reflection of the coated glass 1 satisfies: -3 ≤ a2 ≤ 0.

[0047] Specifically, b2 can be exemplified as -1, -0.8, -0.6, -0.4, -0.2, 0, 0.2, 0.4, 0.6, 0.8, or 1, etc. Preferably, the Lab2 value of the outer surface reflection of the coated glass 1 satisfies: -0.5 ≤ b2 ≤ 1. More preferably, the Lab2 value of the outer surface reflection of the coated glass 1 satisfies: -0.5 ≤ b2 ≤ 0.5.

[0048] The reflectivity of the inner surface is ≤8%, specifically, examples include 8%, 7.5%, 7%, 6.5%, 6%, 5.5%, 5%, 4.5%, 4%, 3.5%, 3%, 2.5%, 2%, 1.5%, or 1%, etc. Preferably, the reflectivity of the inner surface is ≤6%. More preferably, the reflectivity of the inner surface is ≤4%.

[0049] The Lab3 reflection value of the inner surface of the coated glass satisfies: -1≤a3≤1, -1≤b3≤1. The Lab3 reflection value refers to the Lab value obtained by observing the color characteristics of the light reflected from the inner surface of the coated glass 1.

[0050] Specifically, a3 can be exemplified as -1, -0.8, -0.6, -0.4, -0.2, 0, 0.2, 0.4, 0.6, 0.8, or 1, etc. Preferably, the Lab3 value of the inner surface reflection of the coated glass 1 satisfies: -0.5 ≤ a3 ≤ 1. More preferably, the Lab3 value of the inner surface reflection of the coated glass 1 satisfies: -0.5 ≤ a3 ≤ 0.5.

[0051] Specifically, b3 can be exemplified as -1, -0.8, -0.6, -0.4, -0.2, 0, 0.2, 0.4, 0.6, 0.8, or 1, etc. Preferably, the Lab3 value of the inner surface reflection of the coated glass 1 satisfies: -0.5 ≤ b3 ≤ 1. More preferably, the Lab3 value of the inner surface reflection of the coated glass 1 satisfies: -0.5 ≤ b3 ≤ 0.5.

[0052] The total solar transmittance (Tts) of the coated glass is ≤10%, specifically, examples include 10%, 9%, 8%, 7%, 6%, 5%, 4%, 3%, 2%, or 1%, etc. Preferably, the total solar transmittance (Tts) of the coated glass is ≤8%. More preferably, the total solar transmittance (Tts) of the coated glass is ≤6%.

[0053] The transmittance Lab1 value refers to the Lab value obtained by measuring the color characteristics of light after it passes through the coated glass 1. The transmittance Lab1 value of the coated glass 1 satisfies: -3≤a1≤1, -13≤b1≤-2.

[0054] Specifically, a1 can be exemplified as -3, -2.5, -2, -1.5, -1, -0.5, 0, 0.5, or 1, etc. Preferably, the transmittance Lab1 value of the coated glass 1 satisfies: -2 ≤ a1 ≤ 1. More preferably, the transmittance Lab1 value of the coated glass 1 satisfies: -1 ≤ a1 ≤ 0.

[0055] Specifically, b1 can be exemplified as -13, -12, -11, -10, -9, -8, -7, -6, -5, -4, -3, or -2, etc. Preferably, the transmittance Lab1 value of the coated glass 1 satisfies: -10 ≤ b1 ≤ -2. More preferably, the transmittance Lab1 value of the coated glass 1 satisfies: -8 ≤ b1 ≤ -4.

[0056] Specifically, the functional layers are used to reflect infrared light and reduce the emissivity inside the vehicle. Preferably, the number of functional layers is two to four.

[0057] The material of the functional layer is selected from at least one of Ag, Au, Cu, Al and their alloys.

[0058] The intermediate layer is used to reduce reflectivity and adjust the side angle color and transmitted color. The material of the intermediate layer is selected from oxides, nitrides or oxynitrides of at least one element selected from Si, Zn, Mg, Sn, Ti, Nb, Zr, In and Al.

[0059] In one embodiment, the at least two functional layers include a first functional layer 21 and a second functional layer 22, and the intermediate layer includes a first intermediate layer 31, which is disposed between the first functional layer 21 and the second functional layer 22.

[0060] Furthermore, the first functional layer 21 is closer to the augmentation layer than the second functional layer 22.

[0061] The thickness ratio of the first functional layer 21 to the second functional layer 22 is 1 to 5, specifically for example, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, or 5, etc.

[0062] And / or, the thickness ratio of the first functional layer 21 to the first intermediate layer 31 is 0.2 to 1.1, specifically for example, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, or 1.1, etc.

[0063] In another embodiment, the at least two functional layers include a first functional layer 21, a second functional layer 22, and a third functional layer 23, and the intermediate layer includes a first intermediate layer 31 and a second intermediate layer 32, wherein the first intermediate layer 31 is disposed between the first functional layer 21 and the second functional layer 22, and the second intermediate layer 32 is disposed between the second functional layer 22 and the third functional layer 23.

[0064] like Figures 1-2 As shown, for example, the coating structure consists of "reflective layer / first functional layer 21 / first intermediate layer 31 / second functional layer 22 / second intermediate layer 32 / third functional layer 23".

[0065] The first functional layer 21 is closer to the reflection layer than the second functional layer 22, and the second functional layer 22 is closer to the reflection layer than the third functional layer 23.

[0066] The thickness of the first functional layer 21 is d1, the thickness of the second functional layer 22 is d2, the thickness of the third functional layer 23 is d3, the thickness of the first intermediate layer 31 is d4, the thickness of the second intermediate layer 32 is d5, and the functional stack satisfies at least one of the following conditions: 3≤(d1+d2) / d3≤10, and specific examples include 3, or 4, or 5, or 6, or 7, or 8, or 9, or 10, etc.

[0067] And / or, 0.5≤d4 / d5≤1.8, specifically for example, 0.5, or 0.6, or 0.7, or 0.8, or 0.9, or 1, or 1.1, or 1.2, or 1.3, or 1.4, or 1.5, or 1.6, or 1.7, or 1.8, etc.

[0068] And / or, 0.6≤(d1+d2) / d5≤2.5, specifically for example, 0.6, or 0.7, or 0.8, or 0.9, or 1, or 1.2, or 1.4, or 1.6, or 1.8, or 2, or 2.1, or 2.2, or 2.3, or 2.4, or 2.5, etc.

[0069] In another embodiment, the at least two functional layers include a first functional layer 21, a second functional layer 22, a third functional layer 23, and a fourth functional layer, and the intermediate layer includes a first intermediate layer 31, a second intermediate layer 32, and a third intermediate layer.

[0070] The first intermediate layer 31 is disposed between the first functional layer 21 and the second functional layer 22, the second intermediate layer 32 is disposed between the second functional layer 22 and the third functional layer 23, and the third intermediate layer is disposed between the third functional layer 23 and the fourth functional layer.

[0071] For example, the coating structure consists of "reflective layer / first functional layer 21 / first intermediate layer 31 / second functional layer 22 / second intermediate layer 32 / third functional layer 23 / third intermediate layer / fourth functional layer".

[0072] Specifically, the ratio between the total thickness of the functional layer and the total thickness of the intermediate layer in the coating structure is 0.4 to 1.2, and can be exemplified by 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1, 1.1, or 1.2, etc.

[0073] And / or, the total thickness of the functional layer in the coating structure is 20nm~70nm, specifically for example, 20nm, 25nm, 30nm, 35nm, 40nm, 45nm, 50nm, 55nm, 60nm, 65nm, or 70nm, etc.

[0074] And / or, the total thickness of the intermediate layer in the coating structure is 20nm~140nm, specifically for example, 20nm, 30nm, 40nm, 50nm, 60nm, 70nm, 80nm, 90nm, 100nm, 110nm, 120nm, 130nm, or 140nm, etc.

[0075] The antireflective layer is used to increase the reflectivity of the coated glass 1, while also increasing the adhesion between the film and the glass substrate. In one embodiment, the antireflective layer includes at least one antireflective stack, each of the antireflective stacks including a high refractive index layer and a low refractive index layer.

[0076] Optionally, the high refractive index layer is closer to the outer surface than the low refractive index layer; or, the high refractive index layer is closer to the inner surface than the low refractive index layer. Preferably, the number of anti-reflection layers is two to four.

[0077] like Figures 1-2 As shown, for example, the anti-reflection layer is composed of "a first high refractive index layer 411 / a first low refractive index layer 412 / a second high refractive index layer 421 / a second low refractive index layer 422". Among them, the first high refractive index layer 411 and the first low refractive index layer 412 form a first anti-reflection stack 41, and the second high refractive index layer 421 and the second low refractive index layer 422 form a second anti-reflection stack 42.

[0078] Furthermore, the refractive index of the high refractive index layer is 1.98~2.72, and the refractive index of the low refractive index layer is 1.45~1.65.

[0079] Examples of refractive indices for high-refractive-index layers include 1.98, 2, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, and 2.72.

[0080] Examples of refractive indices for low-refractive-index layers include 1.45, 1.5, 1.55, 1.6, and 1.65.

[0081] And / or, the material of the high refractive index layer is selected from oxides of at least one element selected from Zn, Sn, Nb, Ti, Cr, Ta and Zr, or includes one or more nitrides and oxynitrides of at least one element selected from Si, Zr and Al.

[0082] And / or, the material of the low refractive index layer is selected from oxides of at least one element selected from Si, Al and B, or fluorides including at least one element selected from Mg, Al and Ba.

[0083] And / or, the total thickness of the high refractive index layer in the antireflection layer is 30nm~110nm, specifically for example, 30nm, 40nm, 50nm, 60nm, 70nm, 80nm, 90nm, 100nm, or 110nm, etc.

[0084] And / or, the total thickness of the low refractive index layer in the antireflection layer is 40nm~180nm, specifically for example, 40nm, 50nm, 60nm, 70nm, 80nm, 90nm, 100nm, 110nm, 120nm, 130nm, 140nm, 150nm, 160nm, 170nm, or 180nm, etc.

[0085] The anti-reflection layer includes two anti-reflection stacks: a first anti-reflection stack 41 and a second anti-reflection stack 42, wherein the second anti-reflection stack 42 is closer to the outer surface than the first anti-reflection stack 41. The thickness ratio of the high refractive index layer in the first anti-stacking layer 41 to the high refractive index layer in the second anti-stacking layer 42 is 0.7 to 1.6. For example, it can be 0.7, 0.75, 0.8, 0.85, 0.9, 0.95, 1, 1.05, 1.1, 1.15, 1.2, 1.25, 1.3, 1.35, 1.4, 1.45, 1.5, 1.55, or 1.6.

[0086] And / or, the thickness ratio of the low refractive index layer in the first anti-stack layer 41 to the low refractive index layer in the second anti-stack layer 42 is 0.7 to 1, specifically for example, 0.7, 0.75, 0.8, 0.85, 0.9, 0.95, or 1, etc.

[0087] And / or, the ratio of the total thickness of the low-refractive-index layer in the first anti-reflection stack 41 and the second anti-reflection stack 42 to the total thickness of the high-refractive-index layer in the first anti-reflection stack 41 and the second anti-reflection stack 42 is 1 to 2.3. Specifically, examples include 1, 1.1, 1.2, 1.3, 1.4, 1.5, 1.6, 1.7, 1.8, 1.9, 2, 2.1, 2.2, 2.3, etc.

[0088] Furthermore, the anti-reflective layer is positioned closer to the outer surface than the functional stack, ensuring that the side of the coating structure with high reflectivity faces outwards and the side with low reflectivity faces inwards. This results in the outer surface having a higher reflectivity than the inner surface, making the view of the outside world more natural for passengers.

[0089] like Figure 1 As shown, for example, the coating structure consists of "first glass plate 11 / intermediate adhesive layer 12 / second anti-overlap layer 42 / first anti-overlap layer 41 / first functional layer 21 / first intermediate layer 31 / second functional layer 22 / second intermediate layer 32 / third functional layer 23 / second glass plate 13". The coating structure is located on the third surface.

[0090] like Figure 2 As shown, for example, the coating structure consists of "first glass plate 11 / second anti-overlay layer 42 / first anti-overlay layer 41 / first functional layer 21 / first intermediate layer 31 / second functional layer 22 / second intermediate layer 32 / third functional layer 23 / intermediate adhesive layer 12 / second glass plate 13". The coating structure is located on the second surface.

[0091] In summary, this embodiment, through the design of a combination of reflective and functional layers, not only enables the coated glass 1 to have low in-vehicle reflectivity and neutral transparent color, making the outside scene observed by passengers more natural, but also enables the coated glass 1 to have low total solar transmittance, reflecting more heat, reducing the radiation of sunlight inside the vehicle, and reflecting the heat from outside the vehicle, thus avoiding overheating inside the vehicle in summer.

[0092] In one implementation, such as Figures 1-2 As shown, the coating structure further includes a dielectric layer, which is disposed between the antireflective layer and the functional layer, and / or between the functional layer and the intermediate layer.

[0093] The dielectric layer is used to protect the functional layer from oxidation.

[0094] like Figure 1As shown, for example, the coating structure consists of "first glass plate 11 / intermediate adhesive layer 12 / second anti-overlap layer 42 / first anti-overlap layer 41 / first dielectric layer 81 / first functional layer 21 / second dielectric layer 82 / first intermediate layer 31 / third dielectric layer 83 / second functional layer 22 / fourth dielectric layer 84 / second intermediate layer 32 / fifth dielectric layer 85 / third functional layer 23 / sixth dielectric layer 86 / second glass plate 13". The coating structure is located on the third surface.

[0095] like Figure 2 As shown, for example, the coating structure consists of "first glass plate 11 / second anti-overlay layer 42 / first anti-overlay layer 41 / first dielectric layer 81 / first functional layer 21 / second dielectric layer 82 / first intermediate layer 31 / third dielectric layer 83 / second functional layer 22 / fourth dielectric layer 84 / second intermediate layer 32 / fifth dielectric layer 85 / third functional layer 23 / sixth dielectric layer 86 / intermediate adhesive layer 12 / second glass plate 13". The coating structure is located on the second surface.

[0096] Furthermore, the material of the dielectric layer is selected from at least one of AZO, Ti alloy, NbOx, TiOx, NiCr, NiCrOx, ZnAlOx, ZnOx, and SnOx, wherein x in SnOx satisfies: 1 < x ≤ 3.

[0097] And / or, the thickness of the dielectric layer is 0.5nm to 20nm, specifically for example, 0.5nm, or 1nm, or 2nm, or 3nm, or 4nm, or 5nm, or 6nm, or 7nm, or 8nm, or 9nm, or 10nm, or 11nm, or 12nm, or 13nm, or 14nm, or 15nm, or 16nm, or 17nm, or 18nm, or 19nm, or 20nm, etc.

[0098] In another embodiment, such as Figure 2 As shown, the coating structure further includes a protective layer 60, which is the film layer furthest from the glass substrate in the coating structure.

[0099] The protective layer 60 is used to improve the overall film's resistance to environmental and mechanical properties. For example, the protective layer 60 is disposed on the side of the functional stack away from the antireflective layer, and the protective layer 60 is the film layer in the coating structure that is furthest from the glass substrate in contact with the antireflective layer.

[0100] like Figure 2As shown, for example, the coating structure consists of "first glass plate 11 / second anti-overlay layer 42 / first anti-overlay layer 41 / first dielectric layer 81 / first functional layer 21 / second dielectric layer 82 / first intermediate layer 31 / third dielectric layer 83 / second functional layer 22 / fourth dielectric layer 84 / second intermediate layer 32 / fifth dielectric layer 85 / third functional layer 23 / sixth dielectric layer 86 / protective layer 60 / intermediate adhesive layer 12 / second glass plate 13". The coating structure is located on the second surface.

[0101] Furthermore, the material of the protective layer 60 is selected from oxides, nitrides or oxynitrides of at least one element selected from Si, Zn, Mg, Sn, Ti, Nb, Zr, In and Al.

[0102] And / or, the thickness of the protective layer 60 is 30nm~70nm, specifically for example, 30nm, 35nm, 40nm, 45nm, 50nm, 55nm, 60nm, 65nm, or 70nm, etc.

[0103] And / or, the coating structure further includes a dielectric layer disposed between the functional layer and the protective layer.

[0104] In yet another implementation, such as Figure 1 As shown, the coating structure further includes an adhesion layer 50, which is disposed on the side of the functional stack away from the antireflective layer and contacts the surface of the glass substrate.

[0105] The adhesion layer 50 is used to increase the adhesion between the film layer and the glass substrate.

[0106] like Figure 1 As shown, for example, the coating structure consists of "first glass plate 11 / intermediate adhesive layer 12 / second anti-overlap layer 42 / first anti-overlap layer 41 / first dielectric layer 81 / first functional layer 21 / second dielectric layer 82 / first intermediate layer 31 / third dielectric layer 83 / second functional layer 22 / fourth dielectric layer 84 / second intermediate layer 32 / fifth dielectric layer 85 / third functional layer 23 / sixth dielectric layer 86 / adhesion layer 50 / second glass plate 13". The coating structure is located on the third surface.

[0107] Furthermore, the material of the adhesion layer 50 is selected from oxides, nitrides or oxynitrides of at least one element selected from Si, Zn, Mg, Sn, Ti, Nb, Zr, In and Al.

[0108] And / or, the thickness of the adhesion layer 50 is 30nm~70nm, specifically for example, 30nm, 35nm, 40nm, 45nm, 50nm, 55nm, 60nm, 65nm, or 70nm, etc.

[0109] And / or, the coating structure further includes a dielectric layer disposed between the functional layer and the adhesion layer.

[0110] In another embodiment, the coated glass 1 further includes an infrared reflective layer 70, which is disposed on the surface of the second glass plate 13 facing the intermediate adhesive layer 12 or on the surface of the second glass plate 13 away from the intermediate adhesive layer 12.

[0111] The infrared reflective layer 70 can be disposed on the third or fourth surface. Optionally, the infrared reflective layer 70 is selected from a double silver film system, a triple silver film system, or an ITO film system.

[0112] An example of a double silver film structure is as follows: ZnSnO3 / AZO / Ag / AZO / ZnSnO3 / AZO / Ag / AZO / ZnSnO3 / SiNx.

[0113] An example of a three-silver film structure is as follows: ZnSnO3 / AZO / Ag / AZO / ZnSnO3 / AZO / Ag / AZO / ZnSnO3 / AZO / Ag / AZO / ZnSnO3 / SiNx.

[0114] An example of an ITO film structure is as follows: SiNx / SiO2 / ITO / SiNx / ITO / SiNx / ITO / SiO2.

[0115] like Figure 2 As shown, for example, the coating structure consists of "first glass plate 11 / second anti-overlay layer 42 / first anti-overlay layer 41 / first dielectric layer 81 / first functional layer 21 / second dielectric layer 82 / first intermediate layer 31 / third dielectric layer 83 / second functional layer 22 / fourth dielectric layer 84 / second intermediate layer 32 / fifth dielectric layer 85 / third functional layer 23 / sixth dielectric layer 86 / protective layer 60 / intermediate adhesive layer 12 / infrared reflective layer 70 / second glass plate 13". The infrared reflective layer 70 is located on the third surface, and the coating structure is located on the second surface.

[0116] Further, the emissivity E of the infrared reflective layer 70 is ≤0.15, specifically, examples include 0.15, 0.14, 0.13, 0.12, 0.11, 0.10, 0.09, 0.08, 0.07, 0.06, 0.05, 0.04, 0.03, 0.02, or 0.01, etc. Preferably, the emissivity E of the infrared reflective layer 70 is ≤0.10. More preferably, the emissivity E of the infrared reflective layer 70 is ≤0.05.

[0117] Therefore, by adding an infrared reflective layer 70, this embodiment can further reduce the total solar transmittance of the coated glass 1, further reflect more heat, further reduce the radiation of sunlight inside the vehicle, and reflect the heat outside the vehicle to avoid overheating inside the vehicle in summer.

[0118] In yet another embodiment, the first glass plate 11 is anti-glare glass.

[0119] Anti-glare glass, also known as AG glass, refers to glass whose surface is specially treated by physical or chemical means such as etching, corrosion, nano-imprinting, coating, sandblasting, or polishing to form a diffuse reflection structure. In this embodiment, by using anti-glare glass for the first glass plate 11, when light shines on the outer surface of the coated glass 1, it is no longer specular reflection, but diffuse reflection. On the one hand, it scatters the sunlight entering the vehicle, reducing the transmittance of sunlight; on the other hand, it reduces glare from concentrated reflections, avoids light pollution from the roof, further improves the user's visual comfort, further improves the vehicle's aesthetics, and further improves the user's experience.

[0120] Sunlight received by glass can generally be divided into the following components: Reflection (R) + Transmission (T) + Absorption (D) = 100%. Sunroof glass with related technologies often achieves approximately 20% Reflection (R), 15% Transmission (T), and 65% Absorption (D) by using a gray PVB interlayer or a heat-absorbing NiCr film. However, due to the excessively high absorption (D), secondary radiation occurs, radiating heat into the vehicle's interior. Furthermore, the excessive absorption (D) causes the sunroof glass to become extremely hot to the touch in summer.

[0121] However, by using the coated glass 1 provided in this application, the coated glass 1 reflects most of the heat away by setting functional layers. For example, the reflection R of the double functional layer is ≥65%, and the reflection R of the triple functional layer is ≥75%, which avoids the sunroof glass from radiating heat into the car and greatly alleviates the problem of the sunroof glass getting too hot in summer.

[0122] Meanwhile, this application also makes the first glass plate 11 an anti-glare glass, which serves as the outer glass plate, converting specular reflection into diffuse reflection, thus avoiding the problem of light pollution.

[0123] This application provides a vehicle, the vehicle including a body and coated glass as described above, the coated glass being disposed on the body.

[0124] The vehicle provided in this application uses the coated glass described above. The coated glass, through the design of anti-reflective layers and functional layers, not only has low interior reflectivity and neutral color perception, making the view of the outside scene more natural for passengers, but also has low total solar transmittance, which can reflect more heat, reduce the radiation of sunlight inside the vehicle, and reflect the heat from outside the vehicle, thus preventing the vehicle interior from overheating in summer.

[0125] To make the objectives and advantages of this application clearer, the effects of the coated glass of this application will be further explained in detail below with reference to specific embodiments.

[0126] In Comparative Example 1 and Examples 1-8, examples are illustrated by applying a coating structure to a glass substrate. The specific film materials and thicknesses of the coating structure and the glass substrate are shown in Tables 1-4. Furthermore, the following parameters of the coated glass in Comparative Example 1 and Examples 1-8 were measured respectively: (1) The reflectivity of the outer surface of the coated glass, in %; (2) Lab2 values ​​of the outer surface reflection of coated glass: a2 value and b2 value; (3) The reflectivity of the inner surface of the coated glass, in %; (4) Lab3 value of inner surface reflection of coated glass: a3 value and b3 value; (5) Visible light transmittance of coated glass, in %; (6) Transmittance Lab1 value of coated glass: a1 value and b1 value; The specific index data of Comparative Example 1 and Examples 1-8 are shown in Tables 1 to 4.

[0127] Table 1. Coating materials, thicknesses, and performance parameters of the coated glass in Comparative Example 1 and Examples 1-2.

[0128] Table 2. Coating materials, thicknesses, and performance parameters of the coated glass in Examples 3-4

[0129] Table 3. Coating materials, thicknesses, and performance parameters of the coated glass in Examples 5-6

[0130] Table 4. Coating materials, thicknesses, and performance parameters of the coated glass in Examples 7-8

[0131] Comparative Example 1 uses a conventional anti-reflection structure. Although the reflectivity of the outer surface is greatly improved, the reflectivity of the inner surface is as high as 21.2%, the reflection a3 value is -1.1, the reflection b3 value is -2.1, and the transmittance Lab1 value is a1 value of 7.6 and b1 value of 2.6. The field of view observed through the coated glass is "filtered" with an orange color, making it unsuitable for use in automotive sunroof products.

[0132] Example 1 uses a conventional dual-functional layer structure + anti-reflection layer, which not only greatly improves the reflectivity of the outer surface, but also the reflectivity of the inner surface is only 4.9%. Furthermore, the Lab1 value has a value of a1=0.4 and a value of b1=-2.8, and the field of view observed through the coated glass is a natural neutral color, which is suitable for use in automotive sunroof products.

[0133] Example 2 uses a conventional dual-functional layer structure + a double-layer anti-reflective layer, which not only greatly improves the reflectivity of the outer surface, but also the reflectivity of the inner surface is only 4.7%. Furthermore, the Lab1 value has a value of a1=0.5 and a value of b1=-4.0, and the field of view observed through the coated glass is a natural neutral color, which is suitable for use in automotive sunroof products.

[0134] Example 3 uses a conventional three-functional layer structure plus an anti-reflective layer, which not only greatly improves the reflectivity of the outer surface, but also reduces the reflectivity of the inner surface to only 4.5%. Furthermore, the Lab1 values ​​show a1=0.4 and b1=-9.4, and the field of view observed through the coated glass is light blue, making it suitable for automotive sunroof products.

[0135] Example 4 uses a conventional three-functional layer structure + double anti-reflective layer, which not only greatly improves the reflectivity of the outer surface, but also the reflectivity of the inner surface is only 4.8%. Furthermore, the Lab1 value has a value of a1=0.6 and a value of b1=-11.7, and the field of view observed through the coated glass is light blue, making it suitable for automotive sunroof products.

[0136] Example 5 uses a conventional dual-functional layer structure plus an anti-reflective layer. Compared with Example 1, the film structure is inverted. Not only is the reflectivity of the outer surface greatly improved, but the reflectivity of the inner surface is also 5.0%. Furthermore, the transmittance Lab1 values ​​are a1=-2.6 and b1=-9.9, and the field of view observed through the coated glass is light blue, making it suitable for automotive sunroof products.

[0137] Among them, the inverted film structure means that the reflective layer is closer to the outer surface than the functional stack, so that the side of the coating structure with high reflectivity faces outward and the side with low reflectivity faces inward. This makes the reflectivity of the outer surface greater than that of the inner surface, making the scene outside the vehicle more natural for passengers.

[0138] Example 6 uses a conventional dual-functional layer structure plus a dual-layer anti-reflective layer. Compared with Example 2, the film structure is inverted. Not only is the reflectivity of the outer surface greatly improved, but the reflectivity of the inner surface is also 4.7%. Furthermore, the transmittance Lab1 values ​​are a1=-0.3 and b1=-11.3, and the field of view observed through the coated glass is light blue, making it suitable for automotive sunroof products.

[0139] Example 7 uses a conventional three-functional layer structure plus an anti-reflective layer. Compared with Example 3, the film structure is inverted. Not only is the reflectivity of the outer surface greatly improved, but the reflectivity of the inner surface is only 3.7%. Furthermore, the transmittance Lab1 values ​​are a1=-1.3 and b1=-6.4, resulting in a neutral color field of view when viewed through the coated glass, making it suitable for automotive sunroof products.

[0140] Example 8 uses a conventional three-functional layer structure plus a double-layer anti-reflective layer. Compared with Example 4, the film structure is inverted. Not only is the reflectivity of the outer surface greatly improved, but the reflectivity of the inner surface is only 4.5%. Furthermore, the transmittance Lab1 values ​​are a1=-2.8 and b1=-9.5, and the field of view observed through the coated glass is light blue, making it suitable for automotive sunroof products.

[0141] In Comparative Examples 2-5 and Examples 9-16, examples are illustrated by applying a coating structure to laminated glass. The specific film materials and thicknesses of the coating structure and the glass substrate are shown in Tables 5-8. Furthermore, the following parameters of the coated glass in Comparative Examples 2-5 and Examples 9-16 were measured respectively: (1) The reflectivity of the outer surface of the coated glass, in %; (2) The reflectivity of the inner surface of the coated glass, in %; (3) Total solar transmittance Tts of coated glass, in %; The specific index data of Comparative Examples 2-5 and Examples 9-16 are shown in Tables 5-8.

[0142] Table 5. Coating materials, thicknesses, and performance parameters of the coated glass in Comparative Examples 2-4.

[0143] Table 6. Coating materials, thicknesses, and performance parameters of the coated glass in Comparative Example 5 and Examples 9-10.

[0144] Table 7. Coating materials, thicknesses, and performance parameters of the coated glass in Examples 11-13

[0145] Table 8. Coating materials, thicknesses, and performance parameters of the coated glass in Examples 14-16

[0146] In the above embodiments, the three-silver film system structure is formed by depositing the following film layers on a 2.1 mm white glass substrate: ZnSnO3(43.5nm) / AZO(10nm) / Ag(10.7nm) / AZO(10nm) / ZnSnO3(53nm) / AZO(10nm) / Ag(14.2nm) / AZO(10 nm) / ZnSnO3(60.2nm) / AZO(10nm) / Ag(16.4nm) / AZO(10nm) / ZnSnO3(15nm) / SiNx(22.5nm), its resistance value is 1.32Ω.

[0147] In the above embodiments, the ITO film system structure is formed by depositing the following film layer on a 2.1 mm gray glass substrate: The structure is SiNx (24.2nm) / SiO2 (33.2nm) / ITO (30nm) / SiNx (32.6nm) / ITO (143.1nm) / SiNx (60nm) / ITO (200nm) / SiO2 (74.4nm), with a resistance of 7.4Ω.

[0148] Comparative Example 2 shows a standard three-silver film sunroof combination, with a Tts of 36%, indicating significant heat transmission and poor heat insulation in summer. Comparative Example 3 uses gray PVB to block heat, with a Tts of 27.4%, still relatively high and unfavorable for summer heat insulation. Furthermore, the gray PVB absorbs most of the heat, causing secondary radiation into the car and resulting in the sunroof glass becoming "hot to the touch." Comparative Example 4 uses a double-gray glass ITO heat insulation film system, with a Tts of 28.1%, still relatively high and unfavorable for summer heat insulation. Additionally, the gray glass absorbs most of the heat, causing secondary radiation into the car and resulting in the sunroof glass becoming "hot to the touch."

[0149] Comparative Example 5 uses a common triple silver film system for the first glass plate, while the second glass plate uses the film system of Example 1. The intermediate adhesive layer uses common PVB, and it can be seen that its Tts is 18.8%, which is not conducive to heat insulation in summer.

[0150] Example 9 uses 2.1mm clear glass as the first glass plate and the film system of Example 1 as the second glass plate. The intermediate adhesive layer is ordinary PVB. It can be seen that its Tts is 8.7%, which is greatly reduced.

[0151] Example 10 uses 2.1mm AG glass as the first glass plate and the film system of Example 2 as the second glass plate. The intermediate adhesive layer is ordinary PVB. It can be seen that its Tts is 6.6%, which is greatly reduced.

[0152] Example 11 uses ordinary clear glass as the first glass plate and the film system of Example 3 as the second glass plate. The intermediate adhesive layer is ordinary PVB. It can be seen that its Tts is 8.6%, which is greatly reduced.

[0153] Example 12 uses 2.1mm AG glass as the first glass plate and the film system of Example 4 as the second glass plate. The intermediate adhesive layer is ordinary PVB, and the fourth surface is coated with an ITO film system. It can be seen that its Tts is 5.4%, which is greatly reduced.

[0154] Example 13 uses the film system of Example 5 for the first glass plate and 2.1mm clear glass for the second glass plate. The intermediate adhesive layer is ordinary PVB. It can be seen that its Tts is 8.5%, which is greatly reduced.

[0155] Example 14 uses the film system of Example 6 for the first glass plate and 2.1mm clear glass for the second glass plate. The intermediate adhesive layer is ordinary PVB. It can be seen that its Tts is 7.5%, which is greatly reduced.

[0156] Example 15 involves depositing the film system of Example 7 on a 2.1mm AG glass first glass plate. The second glass plate uses ordinary white glass, and the intermediate adhesive layer uses gray PVB. It can be seen that its Tts is 7.2%, which is greatly reduced.

[0157] Example 16 involves depositing the film system of Example 8 on a 2.1mm AG glass first glass plate, using triple silver glass as the second glass plate, depositing an ITO film system on the fourth surface, and using ordinary PVB as the intermediate bonding layer. It can be seen that its Tts is 5.5%, which is greatly reduced.

[0158] In summary, this application, through the design of a combination of anti-reflective layer and functional stacked layer, along with an infrared reflective layer, not only enables the coated glass to have low interior reflectivity and neutral color perception, making the outside scene observed by passengers more natural, but also enables the coated glass to have low total solar transmittance, reflecting more heat, reducing the radiation of sunlight inside the vehicle, and reflecting the heat from outside the vehicle, thus preventing the vehicle interior from overheating in summer.

[0159] Unless otherwise stated or in case of conflict, the terms or phrases used in this application shall have the following meanings: In this application, terms such as "first" and "second" are used for descriptive purposes only and should not be construed as indicating or implying relative importance or implicitly specifying the number of technical features indicated. Therefore, a feature defined with "first" or "second" may explicitly or implicitly include at least one of that feature.

[0160] In this application, "one or more" refers to any one, any two, or any two or more of the listed items. "Several" refers to any two or more.

[0161] In this application, it should be understood that the terms "center," "longitudinal," "lateral," "length," "width," "thickness," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," "clockwise," and "counterclockwise," etc., indicate the orientation or positional relationship based on the orientation or positional relationship shown in the accompanying drawings. They are used only for the convenience of describing this application and simplifying the description, and do not indicate or imply that the device or element referred to must have a specific orientation, or be constructed and operated in a specific orientation. Therefore, they should not be construed as limitations on this application.

[0162] In this application, unless otherwise expressly specified and limited, the terms "installation," "connection," "linking," and "fixing," etc., should be interpreted broadly. For example, they can refer to a fixed connection, a detachable connection, or an integral part. They can refer to a mechanical connection or an electrical connection. They can refer to a direct connection or an indirect connection through an intermediate medium, or the internal communication of two components or the interaction between two components. For those skilled in the art, the specific meaning of the above terms in this application can be understood according to the specific circumstances.

[0163] In this application, the terms "embodiment" and "implementation" mean that a specific feature, structure, or characteristic described in connection with an embodiment can be included in at least one embodiment of this application. The appearance of these phrases in various locations throughout the specification does not necessarily refer to the same embodiment, nor are they independent or alternative embodiments mutually exclusive with other embodiments. Those skilled in the art will understand, explicitly and implicitly, that the embodiments described in this application can be combined with other embodiments. Furthermore, it should be understood that the features, structures, or characteristics described in the various embodiments of this application can be arbitrarily combined to form yet another embodiment that does not depart from the spirit and scope of the technical solution of this application, provided there is no contradiction between them.

[0164] The above description represents some embodiments of this application. It should be noted that those skilled in the art can make various improvements and modifications without departing from the principles of this application, and these improvements and modifications are also considered to be within the scope of protection of this application.

Claims

1. A coated glass, characterized in that, The coated glass includes a glass substrate and a coating structure disposed on the glass substrate. The coating structure includes a reflective layer and a functional stack layer stacked together. The functional stack layer includes at least two functional layers and an intermediate layer disposed between the two functional layers. The coated glass has an outer surface and an inner surface, the anti-reflective layer is closer to the outer surface than the functional stack, the reflectivity of the outer surface is greater than the reflectivity of the inner surface, the total solar transmittance Tts of the coated glass is ≤10%, and the transmittance Lab1 value of the coated glass satisfies: -3≤a1≤1, -13≤b1≤-2.

2. The coated glass as described in claim 1, characterized in that, The reflectivity of the outer surface is ≥60%, and the Lab2 value of the outer surface reflection of the coated glass satisfies: -7≤a2≤0, -1≤b2≤1.

3. The coated glass as described in claim 1, characterized in that, The reflectivity of the inner surface is ≤8%, and the Lab3 value of the inner surface reflection of the coated glass satisfies: -1≤a3≤1, -1≤b3≤1.

4. The coated glass as described in claim 1, characterized in that, The material of the functional layer is selected from at least one of Ag, Au, Cu, Al and their alloys; And / or, the material of the intermediate layer is selected from oxides, nitrides or oxynitrides of at least one element selected from Si, Zn, Mg, Sn, Ti, Nb, Zr, In and Al.

5. The coated glass as described in claim 1, characterized in that, The ratio between the total thickness of the functional layer and the total thickness of the intermediate layer in the coating structure is 0.4 to 1.

2. And / or, the total thickness of the functional layers in the coating structure is 20nm~70nm; And / or, the total thickness of the intermediate layer in the coating structure is 20nm~140nm.

6. The coated glass as described in claim 1, characterized in that, The at least two functional layers include a first functional layer and a second functional layer, and the intermediate layer includes a first intermediate layer, which is disposed between the first functional layer and the second functional layer.

7. The coated glass as described in claim 6, characterized in that, The first functional layer is closer to the enhancement and reflection layer than the second functional layer; The thickness ratio of the first functional layer to the second functional layer is 1 to 5. And / or, the thickness ratio of the first functional layer to the first intermediate layer is 0.2 to 1.

1.

8. The coated glass as described in claim 1, characterized in that, The at least two functional layers include a first functional layer, a second functional layer, and a third functional layer. The intermediate layer includes a first intermediate layer and a second intermediate layer. The first intermediate layer is located between the first functional layer and the second functional layer, and the second intermediate layer is located between the second functional layer and the third functional layer.

9. The coated glass as described in claim 8, characterized in that, The first functional layer is closer to the enhancement and reflection layer than the second functional layer, and the second functional layer is closer to the enhancement and reflection layer than the third functional layer; The thickness of the first functional layer is d1, the thickness of the second functional layer is d2, the thickness of the third functional layer is d3, the thickness of the first intermediate layer is d4, the thickness of the second intermediate layer is d5, and the functional stack satisfies at least one of the following conditions: 3≤(d1+d2) / d3≤10; And / or, 0.5≤d4 / d5≤1.8; And / or, 0.6≤(d1+d2) / d5≤2.

5.

10. The coated glass as described in claim 1, characterized in that, The at least two functional layers include a first functional layer, a second functional layer, a third functional layer, and a fourth functional layer, and the intermediate layer includes a first intermediate layer, a second intermediate layer, and a third intermediate layer; The first intermediate layer is disposed between the first functional layer and the second functional layer, the second intermediate layer is disposed between the second functional layer and the third functional layer, and the third intermediate layer is disposed between the third functional layer and the fourth functional layer.

11. The coated glass as described in claim 1, characterized in that, The anti-reflection layer includes at least one anti-reflection stack, and each of the anti-reflection stacks includes a high refractive index layer and a low refractive index layer.

12. The coated glass as described in claim 11, characterized in that, The high refractive index layer has a refractive index of 1.98 to 2.72, and the low refractive index layer has a refractive index of 1.45 to 1.

65. And / or, the material of the high refractive index layer is selected from oxides of at least one element selected from Zn, Sn, Nb, Ti, Cr, Ta and Zr, or includes one or more nitrides and oxynitrides of at least one element selected from Si, Zr and Al; And / or, the material of the low refractive index layer is selected from oxides of at least one element selected from Si, Al and B, or fluorides including at least one element selected from Mg, Al and Ba; And / or, the total thickness of the high refractive index layer in the antireflection layer is 30 nm to 110 nm; And / or, the total thickness of the low-refractive-index layer in the antireflective layer is 40nm~180nm.

13. The coated glass as described in claim 11, characterized in that, The anti-reflection layer includes two anti-reflection stacks: a first anti-reflection stack and a second anti-reflection stack, wherein the second anti-reflection stack is closer to the outer surface than the first anti-reflection stack. The thickness ratio of the high-refractive-index layer in the first anti-reflection layer to the high-refractive-index layer in the second anti-reflection layer is 0.7 to 1.

6. And / or, the thickness ratio of the low-refractive-index layer in the first anti-stack layer to the low-refractive-index layer in the second anti-stack layer is 0.7~1; And / or, the ratio of the total thickness of the low-refractive-index layer in the first anti-stack layer and the second anti-stack layer to the total thickness of the high-refractive-index layer in the first anti-stack layer and the second anti-stack layer is 1 to 2.

3.

14. The coated glass as described in claim 1, characterized in that, The coating structure further includes a dielectric layer, which is disposed between the antireflective layer and the functional layer, and / or between the functional layer and the intermediate layer; The material of the dielectric layer is selected from at least one of AZO, Ti alloy, NbOx, TiOx, NiCr, NiCrOx, ZnAlOx, ZnOx, and SnOx, wherein x in SnOx satisfies: 1 < x ≤ 3; And / or, the thickness of the dielectric layer is 0.5 nm to 20 nm.

15. The coated glass as described in claim 1, characterized in that, The coating structure further includes a protective layer, which is the film layer in the coating structure that is furthest from the glass substrate. The material of the protective layer is selected from oxides, nitrides or oxynitrides of at least one element selected from Si, Zn, Mg, Sn, Ti, Nb, Zr, In and Al. And / or, the thickness of the protective layer is 30nm~70nm; And / or, the coating structure further includes a dielectric layer disposed between the functional layer and the protective layer.

16. The coated glass as described in claim 1, characterized in that, The coating structure further includes an adhesion layer, which is disposed on the side of the functional stack away from the antireflective layer and contacts the surface of the glass substrate; The material of the adhesion layer is selected from oxides, nitrides or nitrogen oxides of at least one element selected from Si, Zn, Mg, Sn, Ti, Nb, Zr, In and Al. And / or, the thickness of the adhesion layer is 30nm~70nm; And / or, the coating structure further includes a dielectric layer disposed between the functional layer and the adhesion layer.

17. The coated glass as described in claim 1, characterized in that, The glass substrate is a single piece of glass, and the coating structure is disposed on one side of the single piece of glass.

18. The coated glass as described in claim 1, characterized in that, The glass substrate includes a first glass plate, an intermediate adhesive layer and a second glass plate stacked in sequence. The side of the first glass plate facing away from the intermediate adhesive layer is the outer surface, and the side of the second glass plate facing away from the intermediate adhesive layer is the inner surface. The coating structure is disposed on the surface of the first glass plate facing the intermediate adhesive layer, or on the surface of the second glass plate facing the intermediate adhesive layer.

19. The coated glass as described in claim 18, characterized in that, The coated glass further includes an infrared reflective layer, which is disposed on the surface of the second glass plate facing the intermediate adhesive layer or on the surface of the second glass plate away from the intermediate adhesive layer, and the emissivity E of the infrared reflective layer is ≤0.

15. And / or, the first glass plate is anti-glare glass.

20. A vehicle, characterized in that, The vehicle includes a body and a coated glass as described in any one of claims 1-19, the coated glass being disposed on the body.

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