A composite coating for a piston rod in a marine environment and a method of making the same

By preparing a FeCoNiCrMo high-entropy alloy-based composite coating on the surface of a piston rod in a marine environment, and utilizing laser cladding technology and slow cooling treatment, a dense FCC structure and a carbide-reinforced system are formed, which solves the problem of insufficient corrosion resistance of coatings in marine environments and achieves long-term corrosion resistance.

CN122400554APending Publication Date: 2026-07-17GUANGDONG YUEKE NEW MATERIALS TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
GUANGDONG YUEKE NEW MATERIALS TECH CO LTD
Filing Date
2026-06-03
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing marine piston rod coatings lack sufficient corrosion resistance in high salt spray and high chloride ion environments. Traditional coatings are easily penetrated by chloride ions, leading to corrosion and peeling, and cannot meet the requirements for long-term use.

Method used

A composite powder consisting of FeCoNiCrMo high-entropy alloy powder, WC powder, Ti powder, graphite powder, and CeO2 powder is used to form a composite coating on the piston rod surface through a coaxial powder feeding laser cladding process. Combined with substrate preheating and slow cooling treatment, a dense FCC structure high-entropy solid solution and TiC and WC carbide reinforcement system are formed to block chloride ion corrosion.

Benefits of technology

It significantly improves the long-term corrosion resistance of piston rod coatings in marine environments. Through the synergistic effect of the passivation film of high-entropy alloy, dense coating structure and carbide reinforcement phase, it blocks chloride ion penetration, avoids coating peeling, and achieves long-term structural stability in high salt spray and high chloride ion environments.

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Abstract

本申请提供了一种用于海洋环境活塞杆的复合涂层及其制备方法,属于涂层领域。该方法包括:将FeCoNiCrMo高熵合金粉、WC粉、Ti粉、石墨粉、Mo粉和CeO2粉混合得复合粉末;对活塞杆基体进行除油、喷砂粗化及预热处理;采用同轴送粉激光熔覆工艺将复合粉末熔覆于预处理基体表面,后缓冷至室温。本申请通过Ti与石墨原位生成TiC及(Ti,W)C硬质颗粒,结合高熵合金优异的抗氯离子腐蚀能力,获得物相包括FCC高熵固溶体、TiC、(Ti,W)C及WC颗粒的复合涂层。涂层显微硬度HV1为1100~1300,孔隙率≤0.3%,与基体冶金结合,大幅提升了涂层在海洋环境下的长效耐腐蚀性能。
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