Fluorine-containing wastewater pretreatment device

By extending the hydraulic retention time through multi-stage reaction units and baffle structures, combined with chemical chelation reactions and inclined tube sedimentation, the leakage and clogging problems of fluoride-containing wastewater treatment devices were solved, improving treatment efficiency and achieving sludge reduction and resource recycling.

CN224186005UActive Publication Date: 2026-05-01JIANGSU SAFELY ENVIRONMENT ENG
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Patent Information

Application Number
CN202520920381.9
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2025-05-12
Publication Date
2026-05-01
Estimated Expiration
2035-05-12

AI Technical Summary

Technical Problem

In existing technologies, fluoride-containing wastewater treatment devices suffer from gel leakage and clogging of subsequent TMF devices, resulting in low treatment efficiency.

Method used

The system employs multi-stage reaction units and baffle structures to extend the hydraulic retention time, combined with chelation reactions of iron/aluminum salts, and works in conjunction with inclined tube sedimentation and activated carbon filtration. Sludge reduction and resource recycling are achieved through sludge pyrolysis.

Benefits of technology

It improved the removal rate of fluoride, extended the hydraulic retention time, enhanced the treatment efficiency, and achieved sludge reduction and resource recycling.

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Abstract

The utility model discloses a fluorine-containing wastewater pretreatment device which comprises a series system consisting of a wastewater regulating tank, a multi-stage reaction unit, an inclined tube sedimentation tank, a treatment tank, a TMF (Tetramethylbenzidine) circulating unit and an activated carbon filter tank. The innovation points are as follows: the multi-stage reaction unit adopts the volume gradient design of a first-stage reaction tank and a second-stage reaction tank in a ratio of 1: 1.2-1.5, and is provided with a continuous turn-back type deflection baffle, so that the hydraulic retention time is prolonged by 40-60%, and the chelation reaction of fluorine ions and ferric salt / aluminum salt is enhanced. 50-60-degree hexagonal honeycomb filler is adopted in the inclined tube sedimentation tank to improve the floccule interception efficiency, a gel growth tank with an online particle size detection function is additionally arranged between the treatment tank and the TMF unit, and PAC is accurately added through 80-150-micrometer floccule particle size threshold value control. The matched sludge treatment system converts the fluorine-containing sludge into activated carbon through oxygen-controlled carbonization at 400-600 DEG C, so that the hazardous waste is reduced, and the adsorption capacity of the filter tank is improved. According to the device, through the multi-stage synergistic effect, the fluorine removal rate is increased, and meanwhile, the problem of blockage of the TMF membrane assembly is effectively avoided.
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