INVERT LIQUID EMULSION WITH A FILM-FORMING SILICONE POLYMER, OPTIONALLY A TITANIUM DIOXIDE-BASED PIGMENT AND BORON NITRIDE PARTICLES

Abstract

Title: INVERSE LIQUID EMULSION WITH A SILICONE FILM-FORMING POLYMER, OPTIONALLY A TITANIUM DIOXIDE-BASED PIGMENT AND BORON NITRIDE PARTICLES The present invention relates to a liquid cosmetic composition in the form of a water-in-oil emulsion, comprising: a) at least one non-volatile oil; b) at least one silicone film-forming polymer; c) boron nitride particles, in a content of at least 3% by weight, relative to the total weight of the composition; d) optionally titanium dioxide as pigment in a content such that the weight ratio [boron nitride / titanium dioxide] is at least 65 / 35. It also relates to a makeup process, in which this composition is applied to said keratin materials.

Description

Title of the invention: INVERT LIQUID EMULSION WITH A FILM-FORMING SILICONE POLYMER, OPTIONALLY A TITANIUM DIOXIDE-BASED PIGMENT AND BORON NITRIDE PARTICLES

[0001] The present invention relates to liquid cosmetic compositions in the form of water-in-oil emulsions, comprising a non-volatile oil, a silicone film-forming polymer, boron nitride particles and optionally pigment particles comprising titanium dioxide, as well as a makeup process using said composition, in particular makeup of the skin and / or lips.

[0002] The present invention relates to the field of makeup of the skin and / or lips, and more particularly of the lips, using fluid compositions.

[0003] The development of fluid compositions dedicated to lip makeup, such as liquid lipsticks, which are stable and have satisfactory properties in terms of application (sliding on application, ease of spreading, fineness of deposit), but also in terms of the makeup effect of the deposit on the lips, such as for example coverage, absence of migration of the deposit, preferably without developing stickiness, is a permanent objective.

[0004] All kinds of liquid makeup compositions are now available on the market, from anhydrous forms to direct (oil in water) or inverse (water in oil) emulsions which have appeared more recently on the market. As indicated above, the present invention relates more particularly to liquid compositions in the form of water in oil emulsions.

[0005] In the field of makeup, more specifically of the lips, applications WO2014 / 154701 and WO2017 / 167668 describe fluid inverse emulsions comprising at least one non-volatile oil, at least one silicone film-forming polymer and coloring materials. These compositions make it possible to obtain very fine deposits, almost imperceptible on the lips, with good resistance over time. It may however be interesting to further improve the transfer resistance of such compositions, in particular for compositions comprising titanium dioxide among the pigments present.

[0006] This aim and others are achieved by the present invention which therefore has as its subject a liquid cosmetic composition in the form of a water-in-oil emulsion, comprising: (a) at least one non-volatile oil; b) at least one silicone film-forming polymer (c) boron nitride particles at a content of at least 3% by weight, relative to the total weight of the composition; (d) optionally titanium dioxide as pigment in a content such that the weight ratio [boron nitride / titanium dioxide] is at least 65 / 35 (expressed as a percentage).

[0007] The present invention also relates to a method for making up the skin and / or the lips, preferably the lips, using the composition according to the invention.

[0008] The composition according to the invention makes it possible to improve transfer resistance compared to compositions which lack it, without degrading the other advantageous properties of such compositions. In particular, the composition according to the invention is stable, is easily applied in a precise, non-sticky deposit, with good resistance over time, which does not migrate and also has very good coverage. The deposit is also comfortable and in certain cases, depending on the nature of the applicator used for example, can lead to an almost imperceptible deposit.

[0009] But other advantages of the present invention will appear on reading the description and the examples which follow.

[0010] As indicated previously, the composition according to the invention is in the form of an inverse emulsion, in other words, the continuous phase is the lipophilic phase and the aqueous phase is dispersed within this lipophilic phase.

[0011] Furthermore, the composition according to the invention is in liquid form.

[0012] By “liquid” is meant a fluid texture whose viscosity at 25°C is more particularly between 0.005 and 12 Pa.s, preferably between 0.01 and 10 Pa.s and even more advantageously between 0.05 and 8 Pa.s.

[0013] Preferably, the viscosity at 25°C of a composition according to the invention is between 0.1 and 6 Pa.s. Protocol for viscosity measurement:

[0014] The viscosity measurement is generally carried out at 25°C, using a RHEOMAT RM 180 viscosimeter equipped with a spindle no. 2 or 3, the measurement being carried out after 10 minutes of rotation of the spindle within the formula, at a shear of 200 revolutions / min (rpm). BORON NITRIDE

[0015] The composition according to the invention comprises boron nitride particles.

[0016] More particularly, it has a volume average equivalent diameter (D50) of between 0.3 and 6 pm, more particularly between 0.3 and 4 pm.

[0017] The diameter of the sphere which would behave as an "equivalent diameter" is called identically during the chosen granulometric analysis operation.

[0018] Particle size can be measured by static light scattering using a commercial granulometer of the MasterSizer 2000 type from Malvem. The data are processed on the basis of Mie scattering theory. This theory, which is accurate for isotropic particles, makes it possible to determine, in the case of non-spherical particles, an "effective" particle diameter. This theory is described in particular in the publication by Van de Hulst, HC, "Light Scattering by Small Particles", Chapters 9 and 10, Wiley, New York, 1957.

[0019] Preferably, the boron nitride is in the form of platelets.

[0020] By "platelet-shaped particle" is meant a particle having a length greater than its width and a width greater than its thickness.

[0021] It advantageously does not have any surface treatment.

[0022] Advantageously, the specific surface area per unit mass of the boron nitride used in the context of the present invention is between 10 and 30 m2 / g. The specific surface area per unit mass can be determined by the nitrogen absorption method called the BET method (BRUNAUER - EMMET - TELLER) described in "The journal of the American Chemical Society", vol. 60, page 309, February 1938 and corresponding to the international standard ISO 5794 / 1 (annex D). The BET specific surface area corresponds to the total specific surface area of ​​the particles considered.

[0023] Furthermore, the packed density of the boron nitride particles suitable for carrying out the present invention is advantageously between 0.1 and 0.4 g / cm3. In the context of the invention, the packed density, p, can be assessed according to the following protocol: 40 g of powder are poured into a graduated cylinder; the graduated cylinder is then placed on a Stav 2003 machine from Stampf Volumeter; the graduated cylinder is then subjected to a series of 2500 packing movements (this operation is repeated until the difference in volume between two consecutive tests is less than 2%); the final volume Vf of packed powder is then measured directly on the graduated cylinder. The packed density is determined by the ratio w / Vf, in this case 40 / Vf (Vf being expressed in cm3 and w in g).

[0024] Boron nitride particles of this size may be prepared, for example, from commercially available boron nitride powder agglomerates (having sizes greater than 1 micron) by sonication of a liquid suspension of BN in water and a surfactant in an ultrasonic bath. This type of process is described in particular in application EPI829522.

[0025] Boron nitride powders are for example commercially available such as SP1, SP2 boron nitride, boron nitrides from the Très BN range from Saint Gobain Ceramics, boron nitrides from the Softouch range from Momentive Performance Materials.

[0026] As indicated above, the boron nitride content is at least 3% by weight, relative to the total weight of the composition. More particularly, it represents from 3 to 20% by weight, in particular from 3.5 to 15% by weight, and preferably from 3.5 to 12% by weight, relative to the total weight of the composition. TITANIUM DIOXIDE

[0027] The composition according to the invention may also comprise titanium dioxide particles as pigment. More particularly, the titanium dioxide used in the present invention is a pigment corresponding to the reference CI77891 (Color Index Classification) (also called pigmentary titanium dioxide in the remainder of the description).

[0028] By titanium dioxide pigment particles is meant more particularly particles whose volume average size (D50) is greater than or equal to 0.7 pm, more particularly greater than or equal to 1 pm. The size is determined according to the method mentioned above. The size is also indicated in average equivalent diameter.

[0029] The pigmented titanium dioxide may optionally have been surface-treated, in particular with at least one lipophilic (or hydrophobic) compound.

[0030] The coating may also comprise at least one additional non-lipophilic compound.

[0031] For the purposes of the invention, “coating” titanium dioxide generally designates the total or partial surface treatment of said compound with a surface agent, absorbed, adsorbed or grafted onto said compound.

[0032] Surface-treated titanium dioxides can be prepared according to surface treatment techniques of a chemical, electronic, chemical-mechanical or mechanical nature well known to those skilled in the art. Commercial products can also be used.

[0033] The surfactant can be absorbed, adsorbed or grafted onto the pigments by solvent evaporation, chemical reaction and creation of a covalent bond.

[0034] According to one variant, the surface treatment consists of coating the particles.

[0035] The coating may represent from 0.1% to 20% by weight, and in particular from 0.5% to 5% by weight of the total weight of coated titanium dioxide.

[0036] The coating can be carried out for example by adsorption of a liquid surface agent on the surface of the solid particles by simple mixing with stirring of the particles and said surface agent, optionally hot, prior to the incorporation of the particles into the other ingredients of the makeup or care composition.

[0037] The coating can be carried out for example by chemical reaction of a surfactant with the surface of the solid particles of titanium dioxide and creation of a covalent bond between the surfactant and the particles. This method is notably described in US patent 4,578,266.

[0038] The chemical surface treatment may consist of diluting the surfactant in a volatile solvent, dispersing the particles in this mixture, and then slowly evaporating the volatile solvent, so that the surfactant is deposited on the surface of the particles.

[0039] According to a particular embodiment of the invention, the pigmentary titanium dioxide may be coated with at least one compound chosen from silicone surfactants; fluorinated surfactants; fluoro-silicone surfactants; metallic soaps; N-acylated amino acids or their salts; lecithin and its derivatives; isopropyl trisostearyl titanate; isostearyl sebacate; natural plant or animal waxes; polar synthetic waxes; fatty esters; phospholipids; and mixtures thereof. It may also have been surface-treated with at least one inorganic compound such as alumina, silica, or mixtures thereof. The combination of these two treatment methods is also conceivable.

[0040] Furthermore, according to the invention, composites comprising combinations of titanium dioxide with at least one other mineral compound such as, for example, mica, natural or synthetic, borosilicates, do not fall within the definition of pigmentary titanium dioxide. It is indicated that by "composite materials", we do not designate simple mixtures of titanium dioxide particles with another mineral compound, but composites more particularly obtained by sol-gel, CVD (Chemical Vapor Deposition), PVD (Physical Vapor Deposition) type processes, for example.

[0041] As indicated previously, if the composition comprises it, then the content of pigmentary titanium dioxide is such that the weight ratio [boron nitride / titanium dioxide] is at least 65 / 35 (in percentage). Preferably, when the composition comprises pigmentary titanium dioxide, the weight ratio is between 65 / 35 and 99 / 1, preferably at least 75 / 25; more particularly at least 80 / 20, and even more especially at least 90 / 10. It should be noted that when the pigmentary titanium dioxide used is in a surface-treated form, the entire particle (therefore the titanium dioxide with its coating) is taken into account for the calculation of said ratio. NON-VOLATILE OILS

[0042] The composition according to the invention firstly comprises at least one non-volatile oil.

[0043] The oil or oils may be chosen from non-volatile oils, silicone oils, hydrocarbon oils, and mixtures thereof.

[0044] By “oil” is meant a fatty substance which is liquid at room temperature (25°C) and atmospheric pressure (760 mm Hg or 1,013.105 Pa.

[0045] For the purposes of the present invention, the term “silicone oil” means an oil comprising at least one silicon atom, and in particular at least one Si-O group, and more particularly an organopolysiloxane.

[0046] The expression “non-phenylated silicone oil” designates a silicone oil not containing phenyl substituents.

[0047] The term “hydrocarbon oil” means an oil containing mainly hydrogen and carbon atoms and optionally one or more functions chosen from hydroxyl, ester, ether and carboxylic functions. These oils are therefore distinct from silicone oils.

[0048] By "non-volatile oil" is meant an oil remaining on the skin at room temperature and atmospheric pressure for at least several hours. In particular, these oils have a vapor pressure of less than 2.66 Pa, preferably less than 0.13 Pa. For example, the vapor pressure can be measured using the static method or by the isothermal thermogravimetry effusion method, according to the vapor pressure (OECD standard 104).

[0049] The total non-volatile oil content advantageously represents at least 8% by weight, relative to the total weight of the composition. Preferably, the total non-volatile oil content represents from 8 to 20% by weight, relative to the total weight of the composition. Non-volatile silicone oils

[0050] Among the non-volatile silicone oils, mention may be made of non-phenylated silicones, and phenylated silicones carrying or not a dimethicone fragment.

[0051] Note that the terms "dimethicone fragment" designate a divalent siloxane group whose silicon atom carries two methyl radicals, this group not being found at the ends of the molecule. It can be represented by the following formula: -(Si(CH3)2-O)-.

[0052] More particularly, said silicone oils are free of (poly)alkoxylated groups such as in particular (poly)ethoxylated or (poly)propoxylated groups, or (poly)glycerolated groups.

[0053] In particular, the non-phenylated silicones can be chosen from the following non-volatile oils: - polydimethylsiloxanes (PDMS or Dimethicone (INCI name)), for example products from the Belsil DM ranges from Wacker; XiameterPMX-200 from Dow Corning, - alkyldimethicones comprising aliphatic groups, in particular alkyl or alkoxy, which are pendant and / or at the end of the silicone chain; these groups each comprising from 2 to 24 carbon atoms. By way of example, mention may be made of Cetyl Dimethicone (INCI name) marketed under the commercial reference AB IL WAX 9801 from Evonik Goldschmidt, - their mixtures.

[0054] Preferably, these non-volatile non-phenylated silicone oils are chosen from polydimethylsiloxanes.

[0055] As regards phenylated silicones, mention may be made of trimethyl pentaphenyl trisiloxane, tetramethyl tetraphenyl trisiloxane, diphenyl dimethicone, trime-thylsiloxyphenyl dimethicone, phenyltrimethicone, diphenylsiloxy phenyl tri-methicone, as well as their mixtures.

[0056] These products are notably marketed under the names PH-1555 HRI Cosmetic Fluid (Trimethyl Pentaphenyl Trisiloxane), Dow Corning 556 Cosmetic Grade Fluid (Phenyltrimethicone) by Dow Corning; Diphenyl Dimethicone such as the products KF-54, KF54HV, KF-50-300CS, KF-53 d, KF-50-100CS or Diphenylsiloxy Phenyl Trimethicone KF56 A marketed by Shin Etsu, marketed by Shin Etsu; the products Belsil PDM 1000, Belsil PDM 20 marketed by Wacker Chemie (Trimethylsiloxy Phenyl Dimethicone), alone or in mixtures. The values ​​in parentheses represent the viscosities at 25°C (ASTM D-445 standard).

[0057] Preferably, the composition comprises at least one non-volatile silicone oil chosen from polydimethylsiloxanes, from phenylated silicone oils, preferably not comprising a dimethicone fragment, as well as mixtures thereof. According to an even more advantageous embodiment, the non-volatile silicone oil is chosen from phenylated silicone oils, preferably not comprising a dimethicone fragment.

[0058] According to a particular embodiment of the invention, the content of non-volatile silicone oil(s), more particularly phenylated, and preferably not having a dimethicone fragment, varies from 1 to 8% by weight, preferably from 1.5 to 5% by weight, relative to the weight of the composition. Polar non-volatile hydrocarbon oils

[0059] By "polar hydrocarbon oil" is meant an oil containing mainly hydrogen and carbon atoms and also comprising at least one oxygen atom. More particularly, such an oil comprises one or more functions chosen from hydroxyl, ester, ether, carboxylic, carbonate and preferably hydroxyl, ester functions, or combinations thereof.

[0060] The composition according to the invention may comprise one or more non-volatile hydrocarbon oils, in particular chosen from:

[0061] - Cm-C^ alcohols, preferably monoalcohols;

[0062] More particularly, the C10-C26 alcohols are saturated or unsaturated, branched or unbranched, and comprise from 10 to 26 carbon atoms. Preferably, the C10-C26 alcohols are fatty alcohols, preferably branched when they comprise at least 16 carbon atoms.

[0063] As non-limiting examples of such alcohols, mention may be made of lauryl, isostearyl, oleyl alcohol, 2-butyloctanol, 2-undecyl pentadecanol, 2-hexyldecyl alcohol, isocetyl alcohol, octyldodecanol and mixtures thereof, and very particularly octyldodecanol.

[0064] - monoesters, diesters. triesters. optionally hydroxylated. of an acid mono or polycarboxylic acid C^-Cr and a C2-C8 alcohol.

[0065] In particular:

[0066] * monoesters of a C2-C8 carboxylic acid and a C2-C8 alcohol, optional ally hydroxylated,

[0067] * diesters of a C2-C8 dicarboxylic acid and a C2-C8 alcohol, optional ally hydroxylated; such as diisopropyl adipate, 2-diethylhexyl adipate, dibutyl adipate, or diisostearyl adipate, 2-diethylhexyl succinate,

[0068] * triesters of a C2-C8 tricarboxylic acid and a C2-C8 alcohol, optional ally hydroxylated, such as citric acid esters, such as trioctyl citrate, triethylcitrate, acetyltributyl citrate, tributyl citrate, acetyltributyl citrate,

[0069] - esters of a C2-C8 polyol and of one or more C2-C8 carboxylic acids, such as diesters of glycol and monoacids, such as neopentylglycol diheptanoate, or triesters of glycol and monoacids such as triacetin.

[0070] - esters, in particular having between 18 and 80 carbon atoms.

[0071] As examples, mention may be made of mono-, di- or triesters, optionally hydroxylated or not.

[0072] Thus, the ester can be chosen for example from:

[0073] * monoesters comprising between 18 and 40 carbon atoms in total, in particular monoesters, of formula RiCOOR2 in which Ri represents the residue of a linear or branched or aromatic fatty acid containing from 4 to 40 carbon atoms, saturated or unsaturated, and R2 represents a hydrocarbon chain, in particular a branched chain, containing from 4 to 40 carbon atoms provided that Ri + R2 is >18, such as, for example, Purcellin oil (cetostearyl octanoate), isononyl isononanoate, C12 to C15 alcohol benzoate, 2-ethylhexyl palmitate, octyldodecyl neopentanoate, 2-octyldodecyl stearate, 2-octyldodecyl erucate, isostearyl isostearate, 2-octyldodecyl benzoate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, 2-ethylhexyl palmitate, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyldodecyl myristate.

[0074] Preferably, these are esters of formula RiCOOR2 in which Ri represents the residue of a linear or branched fatty acid comprising from 4 to 40 carbon atoms and R2 represents a hydrocarbon chain, in particular branched, containing from 4 to 40 carbon atoms, Ri and R2 being such that Ri + R2 is >18. Even more particularly, The ester has between 18 and 40 carbon atoms in total.

[0075] As preferred monoesters, mention may be made of isononyl isononanoate, oleyl erucate and / or octyl-2-docecyl neopentanoate;

[0076] * fatty acid monoesters, in particular of 18 to 22 carbon atoms, and including lanolic acid, oleic acid, lauric acid, stearic acid, and diols, such as propylene glycol monoisostearate.

[0077] * diesters, in particular comprising between 18 and 60 carbon atoms in total, in in particular between 18 and 50 carbon atoms in total. It is possible in particular to use diesters of dicarboxylic acid and monoalcohols, such as preferably dii-sostearyl malate, or diesters of glycol and monocarboxylic acids, such as neopentyl glycol diheptanoate, propylene glycol dioctanoate, diethylene glycol diisononanoate, or polyglyceryl-2 diisostearate (in particular such as the compound sold under the commercial reference DERMOL DGDIS by the company Alzo);

[0078] * hydroxylated monoesters and diesters, preferably having a total number of carbon ranging from 18 to 70, such as polyglyceryl-3 diisostearate, isostearyl lactate, octylhydroxystearate, octyldodecyl hydroxystearate, diisostearyl malate, glycerin stearate;

[0079] * triesters, in particular comprising between 35 and 70 carbon atoms in total, in particular such as tricarboxylic acid triesters, such as triisostearyl citrate, or tridecyl trimellitate, or glycol monocarboxylic acid triesters such as polyglycerol-2 triisostearate;

[0080] * tetraesters, in particular having a total number of carbons ranging from 35 to 80, such as than tetraesters of penthaerythritol or polyglycerol and a monocarboxylic acid, for example such as pentaerythrityl tetrapelargonate, pentaerythrityl tetraisostearate, pentaerythrityl tetraisononanoate, glyceryl tri-2-decyl tetradecanoate, polyglyceryl-2-tetraisostearate or pentaerythrityl tetra-2-decyl tetradecanoate;

[0081] * polyesters obtained by condensation of fatty acid dimer and / or trimer unsaturated and diol such as those described in patent application FR853634, such as in particular dilinoleic acid and 1,4-butanediol. In this respect, we can notably mention the polymer marketed by Biosynthis under the name Viscoplast 14436H (INCI name: dilinoleic acid / butanediol copolymer), or copolymers of polyols and diacid dimers, and their esters, such as Hailuscent ISDA;

[0082] * esters and polyesters of dimer diol and mono- or dicarboxylic acid, such as dimer diol fatty acid esters and dimer diol dimer dicarboxylic acid esters, in particular obtainable from a dimer dicarboxylic acid derived in particular from the dimerization of an unsaturated fatty acid in particular C8 to C34, in particular C12 to C22, in particular C16 to C20, and more by particularly in C[8, such as esters of dilinoleic diacids and di-linoleic diol dimers, for example such as those marketed by the company NIPPON FINE CHEMICAL under the trade name LUSPLAN DD-DA5® and DD-DA7®;

[0083] * triglycerides consisting of fatty acid esters and glycerol, in particular of which the fatty acids may have chain lengths varying from C4 to C36, and in particular from C18 to C36, these oils being able to be linear or branched, saturated or unsaturated; as well as vegetable oils. Examples of such compounds include vegetable oils such as wheat germ, sunflower, grape seed, sesame, corn, apricot, castor, shea, avocado, olive, soybean, sweet almond, palm, rapeseed, cotton, hazelnut, macadamia, jojoba, alfalfa, poppy, pumpkin, squash, blackcurrant, evening primrose, millet, barley, quinoa, rye, safflower, candlenut, passionflower, and musk rose; shea oil; or caprylic / capric acid triglycerides such as those sold by the company Stéarineries Dubois or those sold under the names Miglyol 810®, 812® and 818® by the company Dynamit Nobel, as well as their mixtures.

[0084] - di-alkyl carbonates. the 2 alkyl chains may be identical or different different, such as dicaprylyl carbonate marketed under the name Cetiol CC®, by Cognis.

[0085] - and mixtures thereof.

[0086] Preferably, at least one fatty alcohol comprising from 20 to 26 carbon atoms, and in particular octyldodecanol, is used as the polar non-volatile hydrocarbon oil.

[0087] Preferably, the content of non-volatile polar hydrocarbon oil(s) is between 5 and 15% by weight, preferably between 6 and 12% by weight, relative to the weight of the composition.

[0088] According to a particularly advantageous variant of the invention, the composition comprises several non-volatile oils, at least one of which is chosen from polar hydrocarbon non-volatile oils, and at least the other is chosen from phenylated silicone non-volatile oils, preferably free of di-methicone fragment.

[0089] NON-VOLATILE APOLAR HYDROCARBON ADDITIONAL OILS

[0090] The composition according to the invention may also comprise at least one additional non-volatile apolar hydrocarbon oil.

[0091] These oils can be of vegetable, mineral or synthetic origin.

[0092] By “apolar hydrocarbon oil” within the meaning of the present invention, we mean an oil comprising in its structure only carbon and hydrogen atoms.

[0093] More particularly, non-volatile apolar hydrocarbon oils are chosen among linear or branched hydrocarbons, of mineral, vegetable or synthetic origin such as: - paraffin oil or its derivatives (mineral oil), - squalane, preferably of plant origin, - isoeicosane, - mixtures of linear, saturated hydrocarbons, more particularly in C15-C28, such as mixtures whose INCI names are for example the following: alkane C15-19 Alkane (INCI name), alkane C18-C21 Alkane (INCI name), alkane C21-C28 Alkane (INCI name), such as for example the products Gemseal 40, Gemseal 60, Gemseal 120 marketed by Total, Emogreen L19 marketed by SEPPIC - polybutenes such as for example LTNDOPOL H-100, LTNDOPOL H- 300, LTNDOPOL H-1500 marketed by the company AMOCO, - polyisobutenes, hydrogenated polyisobutenes such as Parléam® marketed by NIPPON OIL FATS, PANALANE H-300 E marketed by AMOCO, VISEAL 20000 marketed by SYNTEAL, REWOPAL PIB 1000 marketed by WITCO, or PARLEAM LITE marketed by NOF Corporation, - decene / butene copolymers, polybutene / polyisobutene copolymers, in particular Indopol L-14, - polydecenes and hydrogenated polydecenes such as: PURESYN 10, PURESYN 150 or PURESYN 6 marketed by the company EXXONMOBIL CHEMICALS, - and their mixtures.

[0094] If they are present in the composition used, then their content is preferably such that the total content of non-volatile oils (in other words polar or apolar hydrocarbon oils, or silicone oils, phenylated or non-phenylated, having or not having at least one dimethicone fragment) varies between 6 and 20% by weight, preferably between 6 and 15% by weight, relative to the weight of the composition, VOLATILE OILS

[0095] According to a particular embodiment of the invention, the composition comprises at least one volatile oil.

[0096] The volatile oil(s) may be chosen from hydrocarbon oils, silicone oils, fluorinated oils and mixtures thereof.

[0097] The volatile hydrocarbon oils are preferably chosen from apolar hydrocarbon oils and in particular can be chosen from volatile oils hydrocarbons having from 8 to 16 carbon atoms and their mixtures, and in particular: - branched C8-Ci6 alkanes such as C8-Ci6 isoalkanes (also called isoparaffins), isododecane, isodecane, isohexadecane, and for example oils sold under the trade names Isopars or Permetyls, - linear alkanes, for example such as n-dodecane (C12) and n-tetradecane (C14) sold by Sasol respectively under the references PARAFOL 12-97 and PARAFOL 14-97, as well as their mixtures, the undecane-tridecane mixture (Cetiol UT), the mixtures of n-undecane (Cl 1) and n-tridecane (C13) obtained in examples 1 and 2 of application WO2008 / 155059 from Cognis, and - their mixtures.

[0098] The volatile silicone oils may be chosen from silicone oils having a flash point ranging from 40°C to 102°C, preferably having a flash point greater than 55°C and less than or equal to 95°C, and preferentially ranging from 65°C to 95°C.

[0099] As volatile silicone oils which can be used in the invention, mention may be made of linear or cyclic silicones having a viscosity at 25°C of less than 8 centistokes (cSt) (8 x 10 6m2 / s), and having, in particular, from 2 to 10 silicon atoms, and in particular, from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups having from 1 to 10 carbon atoms.

[0100] As volatile silicone oil(s) which can be used in the invention, mention may be made, in particular, of dimethicone with a viscosity of 2, 5 and 6 cSt, octamethyl cyclotetrasiloxane, decamethyl cyclopentasiloxane, dodecamethyl cyclohexasiloxane, heptamethyl hexyltrisiloxane, heptamethyloctyl trisiloxane, hexamethyl disiloxane, octamethyl trisiloxane, decamethyl tetrasiloxane, dodecamethyl pentasiloxane, and mixtures thereof.

[0101] Preferably, the composition according to the invention comprises at least one volatile oil, more particularly chosen from apolar volatile hydrocarbon oils, from volatile silicone oils, alone or in mixtures.

[0102] According to a particular embodiment, the composition comprises at least one volatile oil in a content ranging from 5 to 45% by weight, in particular from 10 to 30% by weight, relative to the total weight of said composition. FILMOGENIC AGENT

[0103] Furthermore, the composition according to the invention comprises at least one film-forming agent chosen more particularly from silicone film-forming polymers. Advantageously, the film-forming polymer(s) are chosen from silicone resins, silicone acrylate polymers with carbosiloxane dendrimer units, silicone acrylate copolymers, as well as mixtures thereof.

[0104] More particularly, the content of film-forming agent(s) represents from 0.5 to 30% in weight of active material, preferably from 1 to 20% by weight, relative to the total weight of the composition. Silicone resins

[0105] More generally, the term "resin" means a compound whose structure is three-dimensional. Thus, for example, within the meaning of the present invention, a polydimethylsiloxane is not a silicone resin, within the meaning of the present invention.

[0106] The nomenclature of silicone resins (also called siloxane resins or silicone resins) is known as "MDTQ", the resin being described according to the different siloxane monomeric units that it comprises, each of the letters "MDTQ" characterizing a type of unit.

[0107] The letter “M” represents the Monofunctional unit of formula RlR2R3SiOl / 2, the silicon atom being linked to a single oxygen atom in the polymer comprising this unit.

[0108] The letter “D” means a Difunctional unit RlR2SiO2 / 2 in which the silicon atom is linked to two oxygen atoms

[0109] The letter “T” represents a Trifunctional unit of formula RlSiO3 / 2.

[0110] Such resins are described for example in “Encyclopedia of Polymer Science and Engineering, vol. 15, John and Wiley and Sons, New York, (1989), p. 265-270, and US 2,676,182, US 3,627,851, US 3,772,247, US 5,248,739 or even US 5,082,706, US 5,319,040, US 5,302, 685 and US 4,935,484.

[0111] In the M, D, T units defined above, Ri, namely RI, R2 and R3, identical or different, represent a hydrocarbon radical (in particular alkyl) having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or even a hydroxyl group.

[0112] Finally, the letter "Q" signifies a Tetrafunctional SiO4 / 2 unit in which the silicon atom is linked to four oxygen atoms themselves linked to the rest of the polymer.

[0113] Various silicone resins with different properties can be obtained from these different units, the properties of these polymers varying according to the type of monomers (or units), the nature and number of the radical(s) Ri, the length of the polymer chain, the degree of branching and the size of the pendant chains.

[0114] As silicone resins which can be used in the compositions according to the invention, it is possible to use, for example, silicone resins of the MQ type, of the T type or of the MQT type. MQ Resins

[0115] As an example of MQ type silicone resins, mention may be made of siloxysilicate type resins such as alkyl siloxysilicates, aryl siloxysilicates or alkylaryl siloxy-silicates, of formula [(Rl)3SiOi / 2]x(SiO4 / 2)y (MQ units) in which x and y are integers ranging for example from 50 to 80, and such that the RI group represents a radical as defined above, and preferably is an alkyl group having from 1 to 8 carbon atoms, or a hydroxyl group, preferably a methyl group,

[0116] The silicone resin can be used alone or in the form of a mixture in an oil, which can in particular be chosen from the first and second oil(s) as well as their combinations.

[0117] Examples of MQ type silicone resins of Trimethylsiloxysilicate type (INCI name) include those marketed under the reference SR 1000 by the company General Electric, under the reference TMS 803 by the company Wacker, or mixtures comprising it such as the products marketed under the names KF-7312J (in cyclopentasiloxane) by the company Shin-Etsu, "Silsoft 74 Fluid (in isododecane) by the company Momentive, Dowsil RSN-749 resin (in cyclopentasiloxane), Dowsil 593 Fluid (in a dimethicone) by the company Dow Corning.

[0118] As silicone resins comprising MQ siloxysilicate units, mention may also be made of phenylalkylsiloxysilicate resins, such as phenylpropyl-dimethylsiloxysilicate (INCI name; Silshine 151 marketed by the company General Electric). The preparation of such resins is described in particular in patent US5817302. T resins

[0119] As examples of T-type silicone resins, mention may be made of polysilsesquioxanes comprising mainly units of formula (RSiO3 / 2)x (T units) in which x is greater than 100 and such that the R group is an alkyl group having from 1 to 10 carbon atoms, said polysilsesquioxanes being able to further comprise Si-OH end groups. Thus, these resins comprise, for example, at least 80 mol% of T units.

[0120] Mention may be made of polymethylsilsesquioxanes which are polysilsesquioxanes in which none of the methyl radicals is substituted by another group. Such polymethylsilsesquioxanes are described for example in document US 5,246,694.

[0121] Preferably, it is possible to use Polymethylsilsesquioxane resins (INCI name) in which R represents a methyl group, such as for example those marketed by the company Wacker under the reference Resin MK such as Belsil PMS MK by the company Shin-Etsu under the references KR-220L, or even under the reference KR-251.

[0122] Among the silsesquioxane resins which can be used in the present invention, mention may also be made of those corresponding to homopolymers and / or copolymers of silsesquioxane having an average siloxane unit of general formula Rln SiO(4-n) / 2, wherein each RI is a propyl group, wherein more than 80 mol% of RI represents a C3 to C10 alkyl group, n is a value of 1.0 to 1.4, and more than 60 mol% of the copolymer comprises RlSiO3 / 2 units. Since each RI is a propyl group, these polymers are called polypropylsilsesquioxane resins (INCI name) or “t-propyl” silsesquioxane resins. These resins and their manufacturing processes are described, for example, in US8586013, US2012 / 0301415 and US2006 / 0292096.

[0123] Among the polypropylsilsesquioxane resins suitable for use in the present invention, mention may be made of those marketed by Dow Corning under the names Dowsil 670 Fluid or Dowsil 680 ID Fluid, which are mixtures of Polypropylsilsesquioxane respectively with cyclopentasiloxane or with isosodecane. MQT resins

[0124] As a resin comprising MQT units, those cited in document US 5110890 are known in particular.

[0125] A preferred form of MQT type resins are MQT-propyl resins (also called MQTPr). Such resins which can be used in the compositions according to the invention are in particular those described and prepared in application WO 2005 / 075542, the content of which is incorporated herein by reference.

[0126] The MQ-T-propyl resin preferably comprises the units: (i) (Rl3SiO1 / 2)a (ii) (R22SiO2 / 2)b (iii) (R3SiO3 / 2)c and (iv) (SiO4 / 2)d with RI, R2 and R3 independently representing a hydrocarbon radical (in particular alkyl) having from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or even a hydroxyl group and preferably an alkyl radical having from 1 to 8 carbon atoms or a phenyl group, a, b, c and d being molar fractions, a being between 0.05 and 0.5, b being between zero and 0.3, c being greater than zero, d being between 0.05 and 0.6, a + b + c + d = 1, provided that more than 40 mol% of the R3 groups of the siloxane resin are propyl groups.

[0127] Preferably, the siloxane resin comprises the units: (i) (Rl3SiO1 / 2)a (iii) (R3SiO3 / 2)c and (iv) (SiO4 / 2)davec RI and R3 independently representing an alkyl group having from 1 to 8 carbon atoms, RI preferably being a methyl group and R3 preferably being a propyl group, a being between 0.05 and 0.5, preferably between 0.15 and 0.4, c being greater than zero, preferably between 0.15 and 0.4, d being between 0.05 and 0.6, preferably between 0.2 and 0.6, or between 0.2 and 0.55, a + b + c + d = 1, eta, b, cetd being molar fractions, provided that more than 40 mol% of the R3 groups of the siloxane resin are propyl groups.

[0128] The siloxane resins which can be used according to the invention can be obtained by a process comprising the reaction of: A) an MQ resin comprising at least 80 mol% of (Rl3SiOi / 2)a and (SiO 4 / 2)d units - RI representing an alkyl group having from 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group, - a and d being greater than zero, - the ratio a / d being between 0.5 and 1.5; and B) a propyl resin T comprising at least 80 mol% of (R3SiO3 / 2)c units, - R3 representing an alkyl group having from 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group, - c being greater than zero, provided that at least 40 mol% of the R3 groups are propyl groups, where the mass ratio A / B is between 95:5 and 15:85, preferably the mass ratio A / B is 30:70.

[0129] Advantageously, the mass ratio A / B is between 95:5 and 15:85, preferably, the ratio A / B is less than or equal to 70:30.

[0130] Preferably, the composition according to the invention comprises, as silicone resin, at least one resin of type MQ, of type T, and even more preferably at least one resin of type MQ, as described above. In particular, the silicone resin is a siloxysilicate resin, preferably a trimethylsiloxysilicate resin.

[0131] Vinyl polymer comprising at least one carbosiloxane dendrimer unit

[0132] According to another particular embodiment, the composition may comprise at least one vinyl polymer comprising at least one unit derived from carbosiloxane dendrimer.

[0133] This type of vinyl polymer has in particular a backbone and at least one side chain, which comprises a carbosiloxane dendrimer-derived unit having a carbosiloxane dendrimer structure.

[0134] In particular, vinyl polymers comprising at least one carbosiloxane dendrimer unit may be used as described in applications WO03 / 045337 and EP 963 751 from the company Dow Corning.

[0135] The term "carbosiloxane dendrimer structure" in the context of the present invention represents a molecular structure having branched groups having high molecular weights, said structure having high regularity in the radial direction starting from the bond to the backbone. Such carbosiloxane dendrimer structures are described as a highly branched siloxane-silylalkylene copolymer in Japanese Laid-Open Patent Application Kokai 9-171 154.

[0136] A vinyl polymer having at least one carbosiloxane dendrimer-derived unit has a side molecular chain containing a carbosiloxane dendrimer structure, and may be derived from the polymerization:

[0137] (A) from 0 to 99.9 parts by weight of a vinyl monomer; and

[0138] (B) from 100 to 0.1 parts by weight of a carbosiloxane dendrimer containing a group organic polymerizable using radicals, represented by the general formula

[0139] [Chem.l] | Y—If "PO—If—X L.L.

[0140] in which Y represents an organic group polymerizable using radicals, RI represents an aryl group or an alkyl group having from 1 to 10 carbon atoms, and Xi represents a silylalkyl group which, when i = 1, is represented by the formula:

[0141] [Chem.2] (œ3! T a "1 ! i " Yes :î [ R' | 3-8?

[0142] wherein RI is as defined above, R2 represents an alkylene group having from 2 to 10 carbon atoms, R3 represents an alkyl group having from 1 to 10 carbon atoms, Xi+1 represents a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, an aryl group, or the silylalkyl group defined above with i = i + 1; i is an integer from 1 to 10 which represents the generation

[0143]

[0144]

[0145]

[0146]

[0147]

[0148]

[0149]

[0150] said silylalkyl group, and ai is an integer from 0 to 3; wherein said radical-polymerizable organic group contained in component (A) is selected from *organic groups containing a methacrylic group or an acrylic group and which are represented by the formulas: CH2=C-(R4)-COO-R5- and CH2=C(R4)-CO-NH-R5-; in which R4 represents a hydrogen atom or an alkyl group, R5 represents an alkylene group having from 1 to 10 carbon atoms; and *organic groups containing a styryl group and which are represented by the formula: [Chem. 3] wherein R6 represents a hydrogen atom or an alkyl group, R7 represents an alkyl group having from 1 to 10 carbon atoms, R8 represents an alkylene group having from 1 to 10 carbon atoms, b is an integer from 0 to 4, and c is 0 or 1, such that if c is 0, -(R8)c- represents a bond. The vinyl-type monomer which is component (A) in the vinyl polymer is a vinyl-type monomer which contains a radically polymerizable vinyl group. There is no particular limitation with respect to such a monomer. The following are examples of this vinyl-type monomer: methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, isopropyl methacrylate, or a lower alkyl methacrylate analog; glycidyl methacrylate; butyl methacrylate, butyl acrylate, n-butyl methacrylate, isobutyl methacrylate, tert-butyl acrylate, tert-butyl methacrylate, n-hexyl methacrylate, cyclohexyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, octyl methacrylate, lauryl methacrylate, stearyl acrylate, stearyl methacrylate, or a higher methacrylate analog; vinyl acetate, vinyl propionate, or a lower fatty acid ester thereof; vinyl caproate, vinyl 2-ethylhexoate, vinyl laurate, vinyl stearate, or a higher fatty acid ester thereof;styrene, vinyl toluene, benzyl methacrylate, phenoxyethyl methacrylate, vinyl pyrrolidone, or analogous aromatic vinyl monomers; methacrylamide, N-methylolmethacrylamide, N-methoxymethylmethacrylamide, isobutoxymethoxymethacrylamide, N,N dimethylmethacrylamide, or analogous vinyl-type monomers that contain amide groups; me; hydroxyethyl acrylate, hydroxypropyl alcohol methacrylate, or analogous vinyl-type monomers that contain hydroxyl groups; acrylic acid, methacrylic acid, itaconic acid, crotonic acid, fumaric acid, maleic acid, or analogous vinyl-type monomers that contain a carboxylic acid group; tetrahydrofurfuryl methacrylate, butoxyethyl methacrylate, ethoxydiethylene glycol methacrylate, polyethylene glycol methacrylate, polypropylene glycol monomethacrylate, hydroxybutyl vinyl ether, cetyl vinyl ether, 2-ethylhexyl vinyl ether, or an analogous vinyl-type monomer with ether linkages;methacryloxypropyltrimethoxysilane, polydimethylsiloxane having a methacrylic group on one of its molecular ends, polydimethylsiloxane having a styryl group on one of its molecular ends, or a similar silicone compound having unsaturated groups; butadiene; vinyl chloride; vinylidene chloride; methacrylonitrile; dibutyl fumarate; anhydrous maleic acid; anhydrous succinic acid; methacryl glycidyl ether; an organic salt of an amine, an ammonium salt, and an alkali metal salt of methacrylic acid, itaconic acid, crotonic acid, maleic acid, or fumaric acid; an unsaturated monomer polymerizable with radicals having a sulfonic acid group such as a styrene sulfonic acid group; a quaternary ammonium salt derived from methacrylic acid such as 2-hydroxy-3-methacryloxypropyltrimethylammonium chloride;and a methacrylic acid ester of an alcohol having a tertiary amine group such as a methacrylic acid ester of diethylamine. ;

[0151] Multifunctional vinyl-type monomers can also be used.

[0152] The following are examples of such compounds: trimethylolpropane trimethacrylate, pentaerythritol trimethacrylate, ethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, 1,4-butanediol dimethacrylate, 1,6-hexanediol dimethacrylate, neopentyl glycol dimethacrylate, trimethylolpropanetrioxyethylmethacrylate, tris-(2-hydroxyethyl)isocyanurate dimethacrylate, tris-(2-hydroxyethyl)isocyanurate trimethacrylate, styryl-capped polydimethylsiloxane having divinylbenzene groups on both ends, or analogous silicone compounds having unsaturated groups.

[0153] To facilitate the preparation of the mixture of the raw material of cosmetic products, the number average molecular weight of the vinyl polymer which contains a carbosiloxane dendrimer, can be chosen in the range between 3000 g / mol and 2000000 g / mol, preferably between 5000 g / mol and 800000 g / mol. It can be a liquid, a gum, a paste, a solid, a powder, or any other form. The forms preferred are solutions constituted by the dilution in solvents such as a silicone oil or an organic oil, of a dispersion, or of a powder.

[0154] According to a preferred embodiment, a vinyl polymer suitable for the invention may be one of the polymers described in the examples of application EP963751.

[0155] According to a preferred embodiment, a vinyl polymer grafted with a carbosiloxane dendrimer can be obtained from the polymerization:

[0156] (A) from 0.1 to 99 parts by weight of one or more acrylate or me monomer(s) acrylate; and

[0157] B) from 100 to 0.1 parts by weight of an acrylate or methacrylate monomer of a tri[tri(trimethylsiloxy)silylethyl dimethylsiloxy]silylpropyl carbosiloxane dendrimer.

[0158] According to one embodiment, a vinyl polymer having at least one carbosiloxane dendrimer-derived unit may comprise a tri[tri(trimethylsiloxy)silylethyl dimethylsiloxy]silylpropyl carbosiloxane dendrimer-derived unit corresponding to one of the formulas:

[0159] [Chem.4] CH. CH / | i ".......K! A...... 1 1 ?. 1 K ? J 1 I 1 O [ CH, 1 CH, | § "vi 3

[0160] or

[0161] [Chem.5] r, / ... i ÇMq | ÇH, t 1 t * O CK.. CH, )

[0162] According to a preferred embodiment, a vinyl polymer having at least one carbosiloxane dendrimer-derived unit used in the invention comprises at least one butyl acrylate monomer.

[0163] According to one embodiment, a vinyl polymer may further comprise at least one fluorinated organic group. A fluorinated vinyl polymer may be one of the polymers described in the examples of application WO 03 / 045337.

[0164] According to a preferred embodiment, a grafted vinyl polymer within the meaning of the present invention may be carried in an oil or a mixture of oil(s), preferably volatile oil(s) in particular, chosen from silicone oils and hydrocarbon oils and their mixtures.

[0165] According to a particular embodiment, a silicone oil suitable for the invention may be cyclopentasiloxane.

[0166] According to another particular embodiment, a hydrocarbon oil suitable for the invention may be isododecane.

[0167] Preferably, the vinyl polymer grafted with at least one carbosiloxane dendrimer-derived unit usable in a composition of the invention is a copolymer with the INCI name Acrylates / Polytrimethylsiloxymethacrylate Copolymer, and in particular sold under the names FA 4002 ID Silicone Acrylate, FA 4001 CM Silicone Acrylate, by the company Dow Corning, and preferably that marketed in isododecane under the name Dow Corning FA 4002 ID silicone acrylate. Silicone acrylate copolymers

[0168] According to another particular embodiment, the composition comprises at least one copolymer comprising carboxylate groups and polydimethylsiloxane groups.

[0169] By “copolymer comprising carboxylate groups and polydimethylsiloxane groups” is meant in the present application, a copolymer obtained from (a) one or more carboxylic monomers (acid or ester), and (b) one or more polydimethylsiloxane (PDMS) chains.

[0170] In the present application, the term "carboxylic monomer" means both carboxylic acid monomers and carboxylic acid ester monomers. Thus, the monomer (a) may be chosen, for example, from acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, their esters and mixtures of these monomers. As esters, the following monomers may be mentioned: acrylate, methacrylate, maleate, fumarate, itaconoate and / or crotonoate. According to a preferred embodiment of the invention, the monomers in the form of esters are more particularly chosen from linear or branched alkyl acrylates and methacrylates, preferably C1-C24 and better still C1-C22, the alkyl radical being preferentially chosen from methyl, ethyl, stearyl, butyl, ethyl-2-hexyl radicals, and mixtures thereof.

[0171] Thus, according to a particular embodiment of the invention, the copolymer comprises as carboxylate groups, at least one group chosen from acrylic acid, methacrylic acid, methyl, ethyl, stearyl, butyl, ethyl-2-hexyl acrylates or methacrylates, and mixtures thereof.

[0172] In the present application, the term "polydimethylsiloxanes" (also called organopolysiloxanes or, in abbreviation, PDMS), in accordance with general acceptance, is intended to denote any organosilicon polymer or oligomer with a linear structure, of variable molecular weight, obtained by polymerization and / or polycondensation of suitably functionalized silanes, and consisting essentially of a repetition of main units in which the silicon atoms are linked together by oxygen atoms (siloxane bond °Si-O-Si°), comprising trimethyl radicals directly linked via a carbon atom to said silicon atoms. The PDMS chains which can be used to obtain the copolymer used according to the invention comprise at least one polymerizable radical group, preferably located on at least one of the ends of the chain, that is to say that the PDMS can have for example a polymerizable radical group on both ends of the chain or have a polymerizable radical group on one end of the chain and a trimethylsilyl terminal group on the other end of the chain. The polymerizable radical group can be in particular an acrylic or methacrylic group, in particular a group

[0173] CH2 = CRI - CO - O - R2, where RI represents a hydrogen or a methyl group, and R2 represents -CH2-, -(CH2)n- with n = 3, 5, 8 or 10, -CH2-CH(CH3)-CH2-, -CH2-CH2-O-CH2-CH2-, -CH2-CH2-O-CH2-CH2-CH(CH3)-CH2-, -CH2-CH2-O-CH2CH2-O-CH2-CH2-CH2-.

[0174] The copolymers used in the composition of the invention are generally obtained according to the usual polymerization and grafting methods, for example by radical polymerization (A) of a PDMS comprising at least one polymerizable radical group (for example on one of the ends of the chain or on both) and (B) of at least one carboxylic monomer, as described for example in documents US-A-5,061,481 and US-A-5,219,560.

[0175] The copolymers obtained generally have a molecular weight ranging from approximately 3,000 g / mol to 200,000 g / mol and preferably from approximately 5,000 g / mol to 100,000 g / mol.

[0176] The copolymer used in the composition of the invention may be present as such or in dispersed form in a solvent such as lower alcohols containing from 2 to 8 carbon atoms, such as isopropyl alcohol, or oils such as volatile silicone oils (for example cyclopentasiloxane).

[0177] As copolymers which can be used in the composition of the invention, mention may be made, for example, of copolymers of acrylic acid and stearyl acrylate with polydimethylsiloxane grafts, copolymers of stearyl methacrylate with polydimethylsiloxane grafts, copolymers of acrylic acid and stearyl methacrylate with polydimethylsiloxane grafts, copolymers of methyl methacrylate, butyl methacrylate, 2-ethylhexyl acrylate and stearyl methacrylate with polydimethylsiloxane grafts.Mention may in particular be made, as copolymers which can be used in the composition of the invention, of the copolymers marketed by the company SHIN-ETSU under the names KP-561 (CTFA name: acrylates / dimethicone), KP-541 where the copolymer is dispersed at 60% by weight in isopropyl alcohol (CTFA name: acrylates / dimethicone and Isopropyl alcohol), KP-545 where the copolymer is dispersed at 30% in cyclopentasiloxane (CTFA name: acrylates / dimethicone and Cyclopenta- . siloxane). According to a preferred embodiment of the invention, KP561 is preferably used; this copolymer is not dispersed in a solvent, but is in waxy form, its melting point being approximately 30°C.

[0178] Mention may also be made of the graft copolymer of polyacrylic and dimethylpolysiloxane dissolved in isododecane marketed by the company Shin Etsu under the name KP-550.

[0179] Preferably, the composition comprises at least one film-forming polymer chosen from the compounds with the following INCI names: trimethylsiloxysilicate, polypropylsilsesquioxane, polymethylsilsesquioxane, acrylates / polytrimethylsiloxymethacrylate copolymer, as well as mixtures thereof, and preferably acrylates / polytrimethylsiloxymethacrylate copolymer.

[0180] According to one embodiment, the composition according to the present invention comprises at least one film-forming polymer in an active material content of from 0.5% to 20% by weight, in particular from 1% to 15% by weight, more particularly from 1.5% to 10% by weight, and preferably from 3% to 5% by weight, relative to the total weight of said composition. SURFACTANTS

[0181] According to a particular embodiment of the invention, the composition comprises at least one surfactant.

[0182] A surfactant or a mixture of surfactants may be present from 0.05 to 20% by weight and preferably from 0.5 to 10% by weight, relative to the total weight of the composition.

[0183] More particularly, suitable surfactants are chosen from non-ionic surfactants. It is preferred not to use ionic (anionic, cationic or amphoteric) surfactants.

[0184] For the choice of these surfactants, one can refer to the document “Encyclopedia of Chemical Technology, KIRK-OTHMER”, volume 22, pages 333-432, 3rd edition, 1979, WILEY, for the definition of the properties and functions (emulsifier) ​​of the surfactants, in particular to pages 347-377 of this reference, for anionic and non-ionic surfactants.

[0185] Non-ionic, hydrocarbon or silicone surfactants, or mixtures thereof, are preferably used.

[0186] In particular, at least one surfactant may be used which has at 25°C an HLB (hydrophilic-lipophilic balance) in the sense of GRIFFIN, less than 8. The HLB value according to GRIFFIN is defined in J. Soc. Cosm. Chem. 1954 (volume 5), pages 249-256.

[0187] One could also optionally use an additional surfactant having at 25°C an HLB balance (hydrophilic-lipophilic balance) in the sense of GRIFFIN, greater than or equal to 8.

[0188] As surfactants which can be used for the preparation of water-in-oil (W / O) emulsions, mention may be made, for example, of sorbitan alkyl esters or ethers; silicone surfactants such as dimethicone copolyols such as the mixture of cyclomethicone and dimethicone copolyol, sold under the name "DC 5225 C" by the company Dow Corning, and alkyl-dimethicone copolyols such as Laurylmethicone copolyol sold under the name "Dow Corning 5200 Formulation Aid" by the company Dow Corning; Cetyl dimethicone copolyol such as the product sold under the name Abil EM 90R by the company Goldschmidt and the mixture of cetyl dimethicone copolyol, polyglycerol isostearate (4 moles) and hexyl laurate sold under the name ABIL WE 09 by the company Goldschmidt, or phosphate surfactants.

[0189] One or more co-emulsifiers may also be added, which, advantageously, may be chosen from the group comprising polyol alkyl esters.

[0190] As alkylated polyol esters, mention may in particular be made of polyethylene glycol esters such as PEG-30 Dipolyhydroxystearate such as the product marketed under the name Arlacel P135 by the company ICI;

[0191] It is also possible to use as surfactants for W / O emulsions a crosslinked solid elastomeric organopolysiloxane comprising at least one oxyalkylenated group, such as those obtained according to the procedure of examples 3, 4 and 8 of document US-A-5,412,004 and the examples of document US-A-5,811,487, in particular the product of example 3 (synthesis example) of patent US-A-5,412,004 and such as that marketed under the reference KSG 21 by the company Shin Etsu.

[0192] According to a particularly preferred embodiment, an emulsion according to the invention, in particular a W / O emulsion, comprises at least one silicone surfactant, and more particularly chosen from dimethicone copolyols.

[0193] A dimethicone copolyol that can be used according to the invention is an oxypropylenated and / or oxyethylenated polydimethyl methyl siloxane.

[0194] Dimethicone copolyols may be used as those corresponding more particularly to the following formula (II):

[0195] [Chem.6]

[0196] in which:

[0197] - Rb R2, R3, independently of each other, represent a Ci - alkyl radical C6 or a radical -(CH2)X - (OCH2CH2)y - (OCH2CH2CH2)Z - OR4, at least one radical R 1, R2 or R3 not being an alkyl radical; R4 being a hydrogen, a C1-C3 alkyl radical or a C2-C4 acyl radical;

[0198] - A is an integer ranging from 0 to 200;

[0199] - B is an integer ranging from 0 to 50; provided that A and B are not equal to zero at the same time;

[0200] - x is an integer ranging from 1 to 6;

[0201] - y is an integer ranging from 1 to 30; and

[0202] - z is an integer ranging from 0 to 30, preferably 20.

[0203] According to a preferred embodiment, in the compound of formula (II), Ri = R3 = methyl radical, x is an integer ranging from 2 to 6 and y is an integer ranging from 4 to 30. R4 is in particular hydrogen.

[0204] Examples of compounds of formula (II) that may be mentioned are compounds of formula (III):

[0205] [Chem.7] (CH3)3SiO - [(CH3)2SiO]A - ((CH^SiO)B - Si{CH3)3 (Mi) (CH2)2-(OCH2CH2)y-OH in which A is an integer from 20 to 105, B is an integer from 2 to 10 and y is an integer from 10 to 20.

[0206] Examples of silicone compounds of formula (II) that may also be mentioned are compounds of formula (IV):

[0207] [Chem 8]

[0208] HO - (OCH2CH2)y-(CH2)3 - [(CH3)2SiO]A - (CH2)3 - (OCH2CH2)y - OH (IV)

[0209] in which A' and y are integers ranging from 10 to 20.

[0210] Dimethicone copolyols that can be used are those sold under the names DC 5329, DC 7439-146, DC 2-5695, Q4-3667 by the company Dow Corning; KF-6013, KF-6015, KF-6016, KF-6017, KF-6028, KF-6050 L by the company Shin-Etsu.

[0211] Compounds DC 5329, DC 7439-146, DC 2-5695 are compounds of formula (III) where respectively A is 22, B is 2 and y is 12; A is 103, B is 10 and y is 12; A is 27, B is 3 and y is 12.

[0212] According to a particular embodiment, the silicone surfactant may be PEG-9 Polydimethylsiloxyethyl Dimethicone, notably marketed by the company Shin-Etsu under the reference KF-6028, PEG-10 dimethicone notably marketed by the company Shin-Etsu under the reference KF-6017, and their mixtures.

[0213] The surfactant may also be chosen from non-ionic surfactants of the type mono- or polyglycerolated fatty alcohols which can be represented by the following formula (V):

[0214] [Chem.9] RC<

[0215] in which:

[0216] R represents a saturated or unsaturated, linear or branched radical, comprising from 8 to 40 carbon atoms and preferably from 10 to 30 carbon atoms;

[0217] m represents a number ranging from 1 to 10.

[0218] As compounds of this type, mention may be made of lauryl alcohol containing 4 moles of glycerol, isostearyl alcohol containing 4 moles of glycerol, lauryl alcohol containing 1.5 moles of glycerol, oleyl alcohol containing 4 moles of glycerol, oleyl alcohol containing 2 moles of glycerol, cetearyl alcohol containing 2 moles of glycerol, cetearyl alcohol containing 6 moles of glycerol, oleocetyl alcohol containing 6 moles of glycerol, and octadecanol containing 6 moles of glycerol.

[0219] Fatty alcohol can represent a mixture of fatty alcohols in the same way that the value of m represents a statistical value, which means that in a commercial product several species of polyglycerolated fatty alcohols can coexist in the form of a mixture. AQUEOUS PHASE

[0220] The composition according to the invention comprises water and optionally at least one water-soluble solvent (the whole constituting the aqueous phase).

[0221] For the purposes of the present invention, the term "water-soluble solvent" means a liquid compound, at 25°C and ambient pressure, and miscible with water (miscibility in water greater than 50% by weight at 25°C and atmospheric pressure).

[0222] Among the water-soluble solvents which can be used in the compositions in accordance with the invention, mention may in particular be made of monoalcohols having from 1 to 5 carbon atoms, such as preferably ethanol, isopropanol; glycols having from 2 to 8 carbon atoms, such as ethylene glycol, propylene glycol, 1,3-butylene glycol and dipropylene glycol; C3 and C4 ketones and C2-C4 aldehydes.

[0223] The composition according to the invention preferably comprises at least 20% by weight of aqueous phase (water + water-soluble solvent(s)), in particular from 20 to 60% by weight, and in particular from 25 to 50% by weight, relative to the total weight of the composition.

[0224] The composition according to the invention preferably comprises at least 15% by weight of water, in particular from 20 to 60% by weight, and in particular from 25 to 50% by weight, relative to the total weight of the composition.

[0225] According to one embodiment, the composition may comprise at least 60% in weight of water, preferably at least 70% by weight, and in particular at least 75% by weight, relative to the total weight of the aqueous phase.

[0226] According to a preferred embodiment, the composition comprises a total content of aqueous phase and volatile oil(s) greater than or equal to 50% by weight, in particular greater than or equal to 60% by weight, relative to the total weight of the composition. COLORING MATTER

[0227] According to a particular embodiment of the invention, the composition comprises at least one coloring material, synthetic, natural or of natural origin, different from the boron nitride and pigmentary titanium dioxide, mentioned previously.

[0228] More particularly, the content of coloring matter(s) in the composition is at least 0.01% by weight, more particularly between 0.05 and 30% by weight, in particular between 0.1 and 25% by weight, relative to the total weight of the composition.

[0229] The coloring material(s) may be chosen from coated or uncoated pigments, water-soluble dyes, fat-soluble dyes, and mixtures thereof. Pigments

[0230] The term “pigments” means white or colored particles, mineral or organic, insoluble in the medium of the composition, intended to color and / or opacify the composition and / or the resulting deposit.

[0231] According to a particular embodiment, the pigments used are chosen from mineral pigments.

[0232] By "mineral pigment" is meant any pigment that meets the definition of the Ullmann encyclopedia in the inorganic pigment chapter. Among the mineral pigments useful in the present invention, mention may be made of zirconium or cerium oxides, as well as zinc, iron (black, yellow or red) or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue, metal powders such as aluminum powder and copper powder. The following mineral pigments may also be used: TiO, ZrO2, CeO2.

[0233] The size of the pigment useful in the context of the present invention is generally greater than 100 nm and can range up to 10 qm, preferably from 200 nm to 5 qm, and more preferably from 300 nm to 1 qm.

[0234] According to a particular form of the invention, the pigments have a size characterized by a D

[50] greater than 100 nm and which can range up to 10 qm, preferably from 200 nm to 5 qm, and more preferably from 300 nm to 1 qm.

[0235] The sizes are measured by static light scattering using a commercial granulometer of the MasterSizer 3000® type from Malvem, making it possible to understand the granulometric distribution of all the particles over a wide area. range from 0.01 pm to 1000 pm. The data are processed on the basis of classical Mie scattering theory. This theory is most suitable for size distributions ranging from submicron to multi-micron, it allows the determination of an "effective" particle diameter. This theory is notably described in the work of Van de Hulst, HC, "Light Scattering by Small Particles", Chapters 9 and 10, Wiley, New York, 1957.

[0236] D

[50] represents the maximum size that 50% by volume of the particles has.

[0237] In the context of the present invention, the mineral pigments are more particu mainly iron oxide and / or titanium dioxide. For example, mention may be made more particularly of titanium dioxides and iron oxides, coated with aluminum stearoyl glutamate, for example marketed under the reference NAI® by the company MIYOSHI KASEI.

[0238] As mineral pigments which can be used in the invention, mention may also be made of nacres.

[0239] By “mother-of-pearl” is meant colored particles of any shape, iridescent or not, in particular, produced by certain molluscs in their shell or synthesized and which present a color effect by optical interference.

[0240] The nacres may be chosen from pearlescent pigments, such as titanium mica coated with iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with an organic dye, as well as pearlescent pigments based on bismuth oxychloride. They may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic coloring materials.

[0241] Examples of mother-of-pearls that may also be mentioned include natural mica coated with titanium oxide, iron oxide, natural pigment or bismuth oxychloride.

[0242] The mother-of-pearls can more particularly have a yellow, pink, red, bronze, orange, brown, gold and / or coppery color or reflection.

[0243] Among the pigments that can be used according to the invention, mention may also be made of those with an optical effect different from a simple conventional tint effect, that is to say unified and stabilized as produced by conventional coloring materials, such as, for example, monochromatic pigments. For the purposes of the invention, "stabilized" means devoid of any effect of variability of the color with the angle of observation or in response to a change in temperature.

[0244] For example, this material can be chosen from metallic reflective particles, goniochromatic coloring agents, diffracting pigments, thermochromic agents, optical brightening agents, as well as fibers, in particular interference fibers. Of course, these different materials can be combined in such a way as to provide the simultaneous manifestation of two effects, or even of a new effect in accordance with the invention.

[0245] According to a particular embodiment, the composition according to the invention comprises at least one uncoated pigment.

[0246] According to another particular embodiment, the composition according to the invention comprises at least one pigment coated with at least one lipophilic or hydrophobic compound.

[0247] This type of pigment is particularly advantageous. To the extent that they are treated with a hydrophobic compound, they exhibit a predominant affinity for an oily phase which can then carry them.

[0248] The coating may also comprise at least one additional non-lipophilic compound.

[0249] For the purposes of the invention, “coating” a pigment according to the invention generally designates the total or partial surface treatment of the pigment with a surface agent, absorbed, adsorbed or grafted onto said pigment.

[0250] The surface-treated pigments may be prepared according to surface treatment techniques of a chemical, electronic, mechanochemical or mechanical nature well known to those skilled in the art. Commercial products may also be used.

[0251] The surfactant can be absorbed, adsorbed or grafted onto the pigments by solvent evaporation, chemical reaction and creation of a covalent bond.

[0252] According to one variant, the surface treatment consists of a coating of the pigments.

[0253] The coating may represent from 0.1% to 20% by weight, and in particular from 0.5% to 5% by weight of the total weight of the coated pigment.

[0254] The coating can be carried out for example by adsorption of a liquid surface agent on the surface of the solid particles by simple mixing with stirring of the particles and said surface agent, optionally hot, prior to the incorporation of the particles into the other ingredients of the makeup or care composition.

[0255] The coating can be carried out for example by chemical reaction of a surfactant with the surface of the solid pigment particles and creation of a covalent bond between the surfactant and the particles. This method is notably described in US patent 4,578,266.

[0256] The chemical surface treatment may consist of diluting the surfactant in a volatile solvent, dispersing the pigments in this mixture, and then slowly evaporating the volatile solvent, so that the surfactant is deposited on the surface of the pigments.

[0257] When the pigment comprises a lipophilic or hydrophobic coating, the latter is preferably present in the fatty phase of the composition according to the invention.

[0258] According to a particular embodiment of the invention, the pigments can be coated according to the invention with at least one compound chosen from surface agents silicones; fluorinated surfactants; fluoro-silicone surfactants; metallic soaps; N-acylated amino acids or their salts; lecithin and its derivatives; isopropyl trisostearyl titanate; isostearyl sebacate; natural vegetable or animal waxes; polar synthetic waxes; fatty esters; phospholipids; and mixtures thereof.

[0259] According to a particular embodiment of the invention, the pigments can be coated with a hydrophilic compound.

[0260] According to another particular embodiment, the coloring matter is an organic, synthetic, natural or naturally occurring pigment.

[0261] By "organic pigment" is meant any pigment which meets the definition of the Ullmann encyclopedia in the organic pigment chapter. The organic pigment may in particular be chosen from nitroso, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal complex type, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane, quinophthalone compounds.

[0262] The organic pigment(s) may be chosen, for example, from carmine, carbon black, aniline black, melanin, azo yellow, quinacridone, phthalocyanine blue, sorghum red, the blue pigments codified in the Color Index under the references CI 42090, 69800, 69825, 73000, 74100, 74160, the yellow pigments codified in the Color Index under the references CI 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000, 47005, the green pigments codified in the Color Index under the references CI 61565, 61570, 74260, the orange pigments codified in the Color Index under the references CI 11725, 15510, 45370, 71105, the red pigments codified in the Color Index under the references CI 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915, 75470, and the pigments obtained by oxidative polymerization of indole derivatives,phenolics as described in patent FR 2 679 771.,

[0263] The pigments may also be in the form of composite pigments as described in patent EP 1 184 426. These composite pigments may be composed in particular of particles comprising an inorganic core covered at least partially with an organic pigment and at least one binder ensuring the fixing of the organic pigments on the core.

[0264] The pigment may also be a lake. By lake is meant insolubilized dyes adsorbed on insoluble particles, the whole thus obtained remaining insoluble during use.

[0265] The inorganic substrates on which the dyes are adsorbed are, for example, alumina, silica, calcium and sodium borosilicate or sodium borosilicate. calcium and aluminum, and aluminum.

[0266] Among the organic dyes, we can cite cochineal carmine. Other products known under the following names include: D&C Red 21 (CI 45 380), D&C Orange 5 (CI 45 370), D&C Red 27 (CI 45 410), D&C Orange 10 (CI 45 425), D&C Red 3 (CI 45 430), D&C Red 4 (CI 15 510), D&C Red 33 (CI 17 200), D&C Yellow 5 (CI 19 140), D&C Yellow 6 (CI 15 985), D&C Green (CI 61 570), D&C Yellow 1 O (CI 77 002), D&C Green 3 (CI 42 053), D&C Blue 1 (CI 42 090).

[0267] Examples of lacquers include the product known under the name D&C Red 7 (CI 15850:1).

[0268] The pigment(s) are preferably present in the composition at contents of at least 0.01% by weight, more particularly at least 1% by weight, and even more particularly at least 2% by weight, relative to the total weight of the composition. More particularly, the coloring matter content is less than 30% by weight, and more particularly between 0.05 and 30% by weight, and even better from 0.1 to 25% by weight relative to the total weight of the composition. Water-soluble or fat-soluble dyes

[0269] According to a particular embodiment of the invention, the coloring material is a water-soluble dye or a liposoluble dye.

[0270] By "water-soluble coloring matter", within the meaning of the invention, is meant any generally organic, natural or synthetic compound, soluble in an aqueous phase or water-miscible solvents and capable of coloring.

[0271] By "liposoluble coloring matter", within the meaning of the invention, is meant any generally organic, natural or synthetic compound, soluble in an oily phase or solvents miscible with the oily phase and capable of coloring.

[0272] As water-soluble dyes suitable for the invention, mention may in particular be made of synthetic or natural water-soluble dyes such as, for example, FDC Red 4, DC Red 6, DC Red 22, DC Red 28, DC Red 30, DC Red 33, DC Orange 4, DC Yellow 5, DC Yellow 6, DC Yellow 8, FDC Green 3, DC Green 5, FDC Blue 1.

[0273] Among the natural water-soluble colorants, we can cite anthocyanins.

[0274] As liposoluble dyes suitable for the invention, mention may in particular be made of liposoluble dyes such as, for example, DC Red 17, DC Red 21, DC Red 27, DC Green 6, DC Yellow 11, DC Violet 2, DC Orange 5, Sudan red, Sudan brown.

[0275] As an illustration of natural fat-soluble colorants, we can particularly cite carotenes such as [3-carotene, α-carotene, lycopene; quinoline yellow; xanthophylls such as astaxanthin, antheraxanthin, citranaxanthin, cryp- toxanthin, canthaxanthin, diatomoxanthin, flavoxanthin, fucoxanthin, lutein, rhodoxanthin, rubixanthin, siphonaxanthin, violaxanthin, zeaxanthin; annatto; curcumin; quinizarin (Ceres Green BB, D&C Green No. 6, CI 61565, 1,4-Di-p-Toluidinoanthraquinone, Green No. 202, Quinzaine Green SS) and chlorophylls.

[0276] The water-soluble or fat-soluble colorant(s) are preferably present in the composition at contents of less than 4% by weight, or even less than 2% by weight, more preferably ranging from 0.01 to 2% by weight, and even better from 0.02 to 1.5% by weight relative to the total weight of the composition. COMMON ADDITIVES

[0277] The composition according to the invention may further comprise any additive that a person skilled in the art will choose in such a way that the advantageous properties intrinsically attached to the compositions in accordance with the invention are not, or not substantially, altered by the addition(s) envisaged.

[0278] As additives which may be incorporated into the compositions in accordance with the invention, mention may in particular be made of hydrophilic thickeners, hydrophobic thickeners, fillers of organic or mineral nature, stabilizers, preservatives, sweeteners, cosmetic active ingredients, flavorings or perfumes, pigment dispersants, film-forming agents, other than those according to the invention.

[0279] Cosmetic active ingredients include sunscreens, vitamins A, E, C, B3, provitamins such as D-panthenol, soothing active ingredients such as α-bisabolol, aloe vera, allantoin, plant extracts or essential oils, protective or restructuring agents, freshness active ingredients such as menthol and its derivatives, emollients, moisturizers, anti-wrinkle active ingredients, essential fatty acids, and mixtures thereof. Hydrophilic thickeners

[0280] As examples of hydrophilic thickening polymers, we can cite more particularly: - homo- or copolymers of acrylic or methacrylic acids or their salts and esters and in particular the products sold under the names “VERSICOL F” or “VERSICOL K” by the company ALLIED COLLOID, “UTRAHOLD 8” by the company CIBA-GEIGY, polyacrylic acids of the SYNTHALEN K type, and salts, in particular sodium, of polyacrylic acid (corresponding to the INCI name sodium acrylate copolymer) and more particularly a crosslinked sodium polyacrylate (corresponding to the INCI name sodium acrylate copolymer (and) caprylic / capric triglyceride) sold under the name “LUVIGEL EM” by the company, - copolymers of acrylic acid and acrylamide sold in the form of their sodium salt under the names “RETEN” by the company HERCULES, sodium polymethacrylate sold under the name “DARVAN N°7” by the company VANDERBILT, sodium salts of polyhydroxycarboxylic acids sold under the name “HYDAGEN F” by the company HENKEL, - polyacrylic acid / alkyl acrylate copolymers, preferably modified or unmodified carboxyvinyl polymers, particularly with acrylate / Cio-C3O-alkylacrylate copolymers (INCI name Acrylates / C 10-30 Alkyl acrylate Crosspolymer) such as the products marketed by the company Lubrizol under the trade names PEMULEN TRI, PEMULEN TR2, CARBOPOL 1382, CARBOPOL EDT 2020 and even more preferably PEMULEN TR-2; - polyacrylamidomethyl propane sulfonic acid partially neutralized with ammonia and highly crosslinked) marketed by the company CLARIANT, - acrylamido propane sulfonic acid / acrylamide copolymers of the SEPIGEL or SIMULGEL type marketed by the company SEPPIC, - acrylamido propane sulfonic acid / polyoxyethylenated alkyl methacrylate copolymers (crosslinked or not) of the ARISTOFLEX HMS type marketed by the company CLARIANT, - copolymers of hydroxyalkyl acrylic acid or their salts and acryloyldimethyl taurate monomers of the type of SEPINOV EMT 10 products marketed by the company SEPPIC; - and their mixtures.

[0281] As other examples of hydrophilic gelling polymers, mention may be made of: - anionic, cationic, amphoteric or non-ionic chitin or chitosan polymers; - cellulose polymers, such as alkylcelluloses, such as hydroxyethylcellulose, hydroxypropylcellulose, hydroxymethylcellulose, ethylhydroxyethylcellulose, carboxymethylcellulose, as well as quaternized derivatives of cellulose; - vinyl polymers, such as polyvinylpyrrolidones, copolymers of methyl vinyl ether and malic anhydride, copolymer of vinyl acetate and crotonic acid, copolymers of vinylpyrrolidone and vinyl acetate; copolymers of vinylpyrrolidone and ca-prolactam; polyvinyl alcohol; - polymers of natural origin, possibly modified, such as galact- tomannans and their derivatives, such as Konjac gum, Gellan gum, Carob gum, Fennugreek gum, Karaya gum, Tragacanth gum, gum arabic, acacia gum, guar gum, hydroxypropyl guar, hydroxypropyl guar modified with sodium methylcarboxylate groups (Jaguar XC97-1, Rhodia), guar hydroxypropyl tri-methyl ammonium chloride, xanthan gum and its derivatives; - alginates and carrageenans; - muccopolysaccharides such as hyaluronic acid, - and their mixtures.

[0282] If the composition comprises it, the content of hydrophilic thickener varies from 0.01 to 3% by weight, preferably from 0.05 to 2% by weight, and more advantageously from 0.1 to 1% by weight, relative to the weight of the composition. Hydrophobic thickeners

[0283] As hydrophobic thickeners, mention may be made in particular of hydrophobic mineral thickeners such as modified clays, modified silicas, or mixtures thereof. Hydrophobic modified clays

[0284] Clays are silicates containing a cation which can be chosen from calcium, magnesium, aluminum, sodium, potassium, lithium cations, and mixtures thereof.

[0285] Examples of such products include clays from the smectite family, as well as from the vermiculite, stevensite and chlorite families. These clays may be of natural or synthetic origin.

[0286] Preferably, organophilic clays are used, more particularly modified clays, such as montmorillonite, bentonite, hectorite, attapulgite, sepiolite, and mixtures thereof. The clay is preferably a bentonite or a hectorite.

[0287] These clays are modified with a chemical compound chosen from quaternary amines, tertiary amines, amine acetates, imidazolines, amine soaps, fatty sulfates, alkyl aryl sulfonates, amine oxides, and mixtures thereof.

[0288] Mention may thus be made of hectorites modified by a quaternary amine, more precisely by a halide, such as a chloride, of ammonium of a C10 to C22 fatty acid, comprising or not an aromatic group; such as hectorite modified by a halide, preferably a chloride, of distearyl dimethyl ammonium (CTFA name: Disteardimonium hectorite), such as, for example, that marketed under the name Bentone 38V, Bentone 38V CG, Bentone EW CE, by the company ELEMENTIS; stearalkonium Hectorites such as in particular the product Bentone 27 V.

[0289] Mention may also be made of quatemium-18 bentonites such as those sold, among others, under the names Bentone 34 marketed by the company Elementis, Claytone 40, Tixogel VP by the company United catalyst by the company Southern Clay; stearalkonium bentonites such as those sold under the names Tixogel LG by the company United Catalyst, Claytone AF, Claytone APA by the company Southern Clay; quatemium-18 / benzalkonium bentonite such as those sold under the name Claytone HT by the company Southern Clay

[0290] According to a preferred embodiment, the thickening agent is chosen from organophilic modified clays, in particular organophilic modified hectorites, in particular by halides, in particular chlorides, of benzyldimethyl ammonium stearate, or of distearyl dimethyl ammonium. Modified silicas

[0291] Mention may also be made of surface-treated hydrophobic fumed silica, the particle size of which is advantageously less than 1 μm. It is in fact possible to chemically modify the surface of the silica, by chemical reaction generating a reduction in the number of silanol groups present on the surface of the silica. In particular, silanol groups can be substituted by hydrophobic groups: a hydrophobic silica is then obtained. The hydrophobic groups may be: - trimethylsiloxyl groups, which are in particular obtained by treatment of fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are called “Silica silylate” according to the CTFA (6th edition, 1995). They are, for example, marketed under the references Aerosil R812® by the company DEGUSSA, CAB-O-SIL TS-530® by the company CABOT, - dimethylsilyloxyl or polydimethylsiloxane groups, which are obtained in particular by treating fumed silica in the presence of polydimethylsiloxane, for example hexamethyldisiloxane, or dimethyldichlorosilane. Silicas treated in this way are called “Silica dimethyl silylate” according to the CTFA (6th edition, 1995). They are, for example, marketed under the references Aerosil R972® and Aerosil R974® by the company DEGUSSA, CAB-O-SIL TS-610® and CAB-O-SIL TS-720® by the company CABOT.

[0292] The hydrophobic pyrogenic silica has in particular a particle size which can be nanometric to micrometric, for example ranging from approximately 5 to 200 nm.

[0293] The composition according to the invention may also comprise at least silica aerogel particles.

[0294] Silica aerogels are porous materials obtained by replacing (by drying) the liquid component of a silica gel with air.

[0295] They are generally synthesized by sol-gel process in liquid medium and then usually dried by extraction of a supercritical fluid, the most commonly used being supercritical CO2. This type of drying makes it possible to avoid contraction of the pores and the material. The sol-gel process and the different drying processes are described in detail in Brinker CL, and Scherer GW, Sol-Gel Science: New York: Academie Press, 1990.

[0296] The hydrophobic silica aerogel particles suitable for implementing the invention have a specific surface area per unit mass (SM) ranging from 500 to 1500 m2 / g, preferably from 600 to 1200 m2 / g and better still from 600 to 800 m2 / g, and a size expressed as volume average diameter (D[0.5]) ranging from 1 to 1500 pm, better still from 1 to 1000 pm, preferably from 1 to 100 pm, in particular from 1 to 30 pm, more preferably from 5 to 25 pm, better still from 5 to 20 pm and even better still from 5 to 15 pm.

[0297] According to an advantageous embodiment, the hydrophobic silica aerogel particles used in the present invention have a specific surface area per unit mass (MS) ranging from 600 to 800 m2 / g and a size expressed as volume average diameter (D[0.5]) ranging from 5 to 20 pm and even better from 5 to 15 pm.

[0298] The specific surface area per unit mass can be determined by the nitrogen absorption method called the BET (BRUNAUER - EMMET - TELLER) method described in "The journal of the American Chemical Society", vol. 60, page 309, February 1938 and corresponding to the international standard ISO 5794 / 1 (annex D). The BET specific surface area corresponds to the total specific surface area of ​​the particles considered.

[0299] The sizes of silica aerogel particles can be measured by static light scattering using a commercial granulometer of the MasterSizer 2000 type from Malvern. The data are processed on the basis of Mie scattering theory. This theory, which is accurate for isotropic particles, makes it possible to determine, in the case of non-spherical particles, an "effective" particle diameter. This theory is described in particular in the work of Van de Hulst, HC, "Light Scattering by Small Particles," Chapters 9 and 10, Wiley, New York, 1957.

[0300] According to a preferred embodiment, the hydrophobic silica aerogel particles used in the present invention have a specific surface area per unit volume Svallant of 5 to 60 m2 / cm3, preferably of 10 to 50 m2 / cm3 and better still of 15 to 40 m2 / cm3.

[0301] The aerogels used according to the present invention are hydrophobic silica aerogels, preferably silylated silica (INCI name silica silylate).

[0302] Concerning the preparation of hydrophobic silica aerogel particles modified on the surface by silylation, reference may be made to document US 7,470,725.

[0303] Particles of hydrophobic silica aerogels modified on the surface by trimethylsilyl groups will preferably be used.

[0304] As hydrophobic silica aerogels which can be used in the invention, mention may be made, for example, of the aerogel marketed under the name VM-2260 (INCI name Silica silylate), by the company Dow Corning, the particles of which have an average size of approximately 1000 microns and a specific surface area per unit of mass ranging from 600 to 800 m2 / g.

[0305] Mention may also be made of the aerogels marketed by the company Cabot under the references Aerogel TLD 201, Aerogel OGD 201, Aerogel TLD 203, Enova® Aerogel MT 1100, Enova Aerogel MT 1200.

[0306] Preferably, the aerogel marketed under the name VM-2270 (INCI name Silica silylate), by the company Dow Corning, will be used, the particles of which have an average size ranging from 5-15 microns and a specific surface area per unit mass ranging from 600 to 800 m2 / g.

[0307] Preferably, the mineral thickeners are chosen from organophilic clays, in particular modified hectorites; hydrophobically treated pyrogenic silica; hydrophobic silica aerogels, or mixtures thereof, and even more precisely at least one organophilic modified clay or at least one hydrophobic modified silica, in particular an organophilic modified clay.

[0308] More particularly, if the composition contains it, the content of mineral thickener(s) represents from 0.2 to 2.5% by weight, expressed as active material, preferably 0.5 to 2% by weight, relative to the weight of the composition. PACKAGING AND APPLICATORS

[0309] The composition according to the invention may be packaged in a container delimiting at least one compartment which comprises said composition, said container being closed by a closing element.

[0310] The container may be in any suitable form. It may in particular be in the form of a bottle, a tube, a pot, a case.

[0311] The closing element may be in the form of a removable stopper, a lid, a cover, in particular of the type comprising a body fixed to the container and a cap hinged to the body. It may also be in the form of an element ensuring the selective closing of the container, in particular a pump, a valve, or a flap.

[0312] The container may be associated with an applicator, for example in the form of a brush (as described for example in patent FR2722380), in the form of an element, deformable or not, made of foam or elastomer, flocked or not. According to a particular embodiment, the applicator head comprises at least one flocked distal end, in particular a flocked outer periphery, more particularly extending according to a flocked band, for example in the general shape of an O, a V or a U. As an example, we can refer to French patent FR3026281.

[0313] The applicator may also be free (sponge) or integral with a rod carried by the closure element, as described for example in patent US5492426. The applicator may be integral with the container, as described for example in patent FR2761959.

[0314] The product may be contained directly in the container, or indirectly.

[0315] The closure element may be coupled to the container by screwing. Alternatively, the coupling between the closure element and the container is achieved by means other than screwing, in particular via a bayonet mechanism, by snap-fastening, or by tightening. By "snap-fastening" is meant in particular any system involving the crossing of a bead or cord of material by elastic deformation of a portion, in particular of the closure element, then by return to the non-elastically stressed position of said portion after crossing the bead or cord.

[0316] The container may be at least partly made of thermoplastic material. Examples of thermoplastic materials include polypropylene or polyethylene.

[0317] The container may have rigid walls or deformable walls, in particular in the form of a tube or a tube bottle.

[0318] The container may comprise means for causing or facilitating the dispensing of the composition. For example, the container may have deformable walls so as to cause the composition to exit in response to an overpressure inside the container, which overpressure is caused by elastic (or non-elastic) crushing of the walls of the container.

[0319] The container may be equipped with a wiper arranged in the vicinity of the opening of the container. Such a wiper makes it possible to wipe the applicator and possibly the rod to which it may be attached. Such a wiper is described for example in patent FR2792618.

[0320] Throughout the description, including the claims, the expression "comprising a" should be understood as being synonymous with "comprising at least one", unless otherwise specified.

[0321] The expressions “between... and...” and “ranging from... to...” must be understood inclusively, unless otherwise specified.

[0322] Furthermore, the sum of the quantities of the ingredients of the composition represents 100% by weight of the composition.

[0323] The invention is illustrated in more detail by the examples presented below.

[0324] Unless otherwise indicated, the quantities indicated are expressed as a mass percentage.

[0325] The following examples are presented for illustrative and non-limiting purposes of the invention. EXAMPLES Examples 1

[0326] 1. Compositions

[0327] The following compositions in accordance with the invention are prepared, the ingredients of which are listed in the table below; the quantities are expressed in quantity by weight of raw material:

[0328] [Tables 1] Phase Ingrédient Compositio n 1 Composition 2 Composition 3 A Cetyl PEG / PPG-10 / 1 Dimethicone (Abil EM 90, Evonik Goldschmidt) 2,9 3,1 3,1 Polyglyceryl-4 Isostearate (Isolan GI34, Evonik Goldschmidt) 1 1 1 PEG / PPG-18 / 18 Dimethicone (KF6050L, Shin Etsu) 1 1,1 1,1 Isododécane 2,7 2,8 2,9 Dodécaméthylpentasiloxane (Xiameter PMX-200 Silicone Fluid 2CS ; Dow Corning) 8,9 9,4 9,5 Trimethyl Pentaphenyl Trisiloxane (Dow Corning PH-1555 HRI Cosmetic Fluid ; Dow Corning) 2,2 2,3 2,3 Octyl-2 dodécanol 10 10 10 Acrylates / Polytrimethylsiloxy-me-thacrylate Copolymer (Dow Corning FA 4002 ID silicone acrylate Dow Corning, en mélange à 40% pds dans l’isododécane) 9,8 10,3 10,5 B Disteardimonium Hectorite 1 1 1 Propylene Carbonate 0,3 0,3 0,3 Dodécaméthylpentasiloxane (Xiameter PMX-200 Silicone Fluid 2CS ; Dow Corning) 2,7 2,8 2,8 c Iron Oxides (and) Disodium Stearoyl Glutamate (and) Aluminum Hydroxide (NAI-C33-8001-10, Myioshi) 1 0.1 1.8 Iron Oxides (and) Disodium Stearoyl Glutamate (and) Aluminum Hydroxide (NAI-C33-7001-10, myishi) 0.1 0.8 - Iron Oxides (and) Disodium Stearoyl Glutamate (and) Aluminum Hydroxide (NAI-C33-9001-10, Myioshi) 0.3 - - Synthetic Fluorphlogopite 0.2 0.1 0.2 Red 28 Lake - 0.1 - Red 27 Lake - - 0.7 Blue 1 Lake - 0.1 - Red 7 - 0.4 - Boron nitride 11.3 7.2 3.2 D Water QsplOO QsplOO QsplOO Butylene glycol 5.9 6.3 6.2 Magnesium sulfate 0.7 0.7 0.7 Ethanol 4.4 4.6 4.6 Phenoxyethanol 0.5 0.5 0.5 1. Preparation

[0329] First, the pigments are mixed into a portion of the dodecamethylpenta-siloxane from phase A (in an Exakt three-cylinder machine).

[0330] Separately, the aqueous phase D is prepared using a magnetic bar.

[0331] Separately, the ingredients of phase B are mixed using a Rayneri stirrer.

[0332] The ingredients of phase A, the pigment / dodecamethyl-cyclopentasiloxane mixture previously obtained, are then mixed, with Moritz stirring, for 20 minutes, at room temperature.

[0333] Once mixture A is smooth and homogeneous and phase B is well homogeneous, the emulsion is prepared at room temperature by pouring aqueous phase D onto phase A, at using a Moritz stirrer.

[0334] Once the mixture has been prepared, stirring is continued until a homogeneous product is obtained and the whole is packaged in a container equipped with an immersion stirrer. 1. Evaluation

[0335] Transfer evaluation protocol:

[0336] - Apply the composition to the lips in a homogeneous deposit (make up the lip upper lip without intermediate refill of product; then make up the lower lip without intermediate refill of product), - wait 2 minutes,

[0337] - Apply the mouth with light pressure on a BIODY support from Beaulax Cheek Skin model #W in white color,

[0338] - the residual coloration is evaluated according to the table below:

[0339] [Tables2] Note Appearance / coloration of the support in contact with the deposit 5 Very intense coloration, mouth shape fully defined 4 Intense coloration, mouth shape visible 3 Medium coloration, mouth shape perceptible 2 Slight coloration, some visible traces 1 No coloration or barely visible coloration

[0340] A score lower than 3 corresponds to a composition which is considered to transfer little, very little or almost not at all.

[0341] A score of at least 3 corresponds to a composition whose transfer is more significant and considered to be outside the invention. Results :

[0342] A fluid, homogeneous, stable composition is obtained.

[0343] The composition is easily applied in a covering, homogeneous, non-sticky deposit.

[0344] The deposit obtained is fine, comfortable, and does not migrate.

[0345] Each of the compositions gives a score of 2 for the transfer test detailed above. Comparative examples 2

[0346] 1. Compositions

[0347] The following comparative compositions are prepared according to the protocol detailed in examples 1, the ingredients of which are listed in the table below; the quantities are expressed in weight quantity of raw material: Phase Ingrédient Cl C2 C3 C4 A Cetyl PEG / PPG-10 / 1 Dimethicone (Abil EM 90, Evonik Goldschmidt) 3,2 3,2 3,2 3,2 Polyglyceryl-4 Isostearate (Isolan GI34, Evonik Goldschmidt) 1,1 1,1 1,1 1,1 PEG / PPG-18 / 18 Dimethicone (KF6050L, Shin Etsu) 1,1 1,1 1,1 1,1 Isododécane 2,9 2,9 2,9 2,9 Dodécaméthylpentasiloxane (Xiameter PMX-200 Silicone Fluid 2CS ; Dow Corning) 9,9 9,9 9,9 9,9 Trimethyl Pentaphenyl Trisiloxane (Dow Corning PH-1555 HRI Cosmetic Fluid ; Dow Corning) 2,3 2,3 2,3 2,3 Octyl-2 dodécanol 10,0 10,0 10,0 10,0 Acrylates / Polytrimethylsiloxy-methacrylate Copolymer (Dow Corning FA 4002 ID silicone acrylate Dow Corning, en mélange à 40% pds dans l’isododécane) 10,5 10,5 10,5 10,5 B Disteardimonium Hectorite 1,1 1,1 1,1 1,1 Propylene Carbonate 0,4 0,4 0,4 0,4 Dodécaméthylpentasiloxane (Xiameter PMX-200 Silicone Fluid 2CS ; Dow Corning) 2,9 2,9 2,9 2,9 c Iron Oxides (and) Disodium Stearoyl Glutamate (and) Aluminum Hydroxide (NALC33-7001-10, myioshi) 0.1 0.1 0.1 0.1 Iron Oxides (and) Disodium Stearoyl Glutamate (and) Aluminum Hydroxide (NALC33-9001-10, Myioshi) 0.8 0.8 0.8 0.8 Red 28 Lake 0.1 0.1 0.1 0.1 Blue 1 Lake 0.1 0.1 0.1 0.1 Red 7 0.4 0.4 0.4 0.4 White pigment based on titanium dioxide, hydrophobic treatment (disodium stearoyl glutamate) (*) 2.5 2.5 - 5 Boron nitride SP1 2.8 - 2.8 3.1 D Water qsp 100 qsp 100 qsp 100 qsp 100 Butylene glycol 6.3 6.3 6.3 6.3 Magnesium sulfate 0.7 0.7 0.7 0.7 Ethanol 4.7 4.7 4.7 4.7 Phenoxyethanol 0.5 0.5 0.5 0.5 BN / TiO2 ratio 53 / 47 0 - 62 / 38

[0349] (*) for the calculation of the ratio, the content of coated titanium dioxide is taken into consideration deration 1. Evaluation

[0350] A fluid, homogeneous, stable composition is obtained.

[0351] The composition is easily applied in a covering, homogeneous, non-sticky deposit.

[0352] The deposit obtained is fine, comfortable, and does not migrate.

[0353] On the other hand, the mark obtained after the transfer evaluation is 4. Examples 3

[0354] 1. Compositions

[0355] The following compositions in accordance with the invention are prepared according to the protocol detailed in Example 1, the ingredients of which are listed in the table below; the quantities are expressed in quantity by weight of raw material: Phase Ingrédient Composition 4 Composition 5 A Cetyl PEG / PPG-10 / 1 Dimethicone (Abil EM 90, Evonik Goldschmidt) 3,1 3,08 Polyglyceryl-4 Isostearate (Isolan GI34, Evonik Goldschmidt) 1,0 1,03 PEG / PPG-18 / 18 Dimethicone (KF6050L, Shin Etsu) 1,1 1,1 Isododécane 2,8 2,8 Dodécaméthylpentasiloxane (Xiameter PMX-200 Silicone Fluid 2CS ; Dow Corning) 9,8 9,48 Trimethyl Pentaphenyl Trisiloxane (Dow Corning PH-1555 HRI Cosmetic Fluid ; Dow Corning) 2,3 2,28 Octyl-2 dodécanol 10,0 10,0 Acrylates / Polytrimethylsiloxy-me-thacrylate Copolymer (Dow Corning FA 4002 ID silicone acrylate Dow Corning, en mélange à 40% pds dans l’isododécane) 10,4 10,29 B Disteardimonium Hectorite 1,0 1,03 Propylene Carbonate 0,3 0,34 Dodécaméthylpentasiloxane (Xiameter PMX-200 Silicone Fluid 2CS ; Dow Corning) 2,8 2,8 c Iron Oxides (and) Disodium Stearoyl Glutamate (and) Aluminum Hydroxide (NAI-C33-7001-10, myishi) 0.1 0.14 Iron Oxides (and) Disodium Stearoyl Glutamate (and) Aluminum Hydroxide (NAI-C33-9001-10, Myioshi) 0.8 0.81 Red 28 Lake 0.1 0.13 Blue 1 Lake 0.1 0.38 Red 7 0.4 0.04 White pigment based on titanium dioxide, hydrophobically treated (disodium stearoyl glutamate) 2.1 - Boron nitride (SP1) 4.3 7.2 D Water qsp 100 qsp 100 Butylene glycol 6.2 6.17 Magnesium sulfate 0.7 0.72 Ethanol 4.7 4.63 Phenoxyethanol 0.5 0.51 BN / TiO2 ratio 67 / 33 100 1. Evaluation

[0357] Each time a fluid, homogeneous, stable composition is obtained.

[0358] The compositions are easily applied. The deposits are covering, homogeneous, non-sticky.

[0359] The deposits obtained are fine, comfortable, and do not migrate.

[0360] After evaluating the transfer according to the protocol detailed previously, each deposit obtains a score of 2.

Claims

Claims

1. Liquid cosmetic composition in the form of a water-in-oil emulsion, comprising: a) at least one non-volatile oil; b) at least one silicone film-forming polymer; c) boron nitride particles, in a content of at least 3% by weight, relative to the total weight of the composition; d) optionally titanium dioxide as pigment in a content such that the weight ratio [boron nitride / titanium dioxide] is at least 65 / 35 (in percentage).

2. Cosmetic composition according to the preceding claim, characterized in that the boron nitride has a volume average equivalent diameter (D50) of between 0.3 and 6 pm, more particularly between 0.3 and 4 pm.

3. Cosmetic composition according to the preceding claim, characterized in that the boron nitride is in the form of platelets.

4. Cosmetic composition according to the preceding claim, characterized in that the boron nitride has a specific surface area of ​​between 10 and 30 m2 / g.

5. Composition according to any one of the preceding claims, characterized in that the boron nitride content represents from 3 to 20% by weight, more particularly from 3.5 to 15% by weight, and preferably from 3.5 to 12% by weight relative to the total weight of the composition.

6. Composition according to any one of the preceding claims, characterized in that the pigmentary titanium dioxide has a Color Index number CI 77891.

7. Composition according to any one of the preceding claims, characterized in that the weight ratio [boron nitride / titanium dioxide] is between 65 / 35 and 99 / 1, preferably at least 75 / 25; more particularly at least 80 / 20, and even more especially at least 90 / 10.

8. Composition according to any one of the preceding claims, characterized in that the non-volatile oil is chosen from silicone oils, polar hydrocarbon oils, as well as their mixtures, preferably chosen from polydimethylsiloxanes, phenylated silicones, from C10-C26 alcohols, monoesters, diesters, triesters, optionally hydroxylated, of a mono or polycar- C2-C8 carboxylic acid and a C2-C8 alcohol, monoesters, diesters, triesters, optionally hydroxylated, of a C2-C8 mono or polycarboxylic acid and a C2-C8 alcohol, esters of a C2-C8 polyol and one or more C2-C8 carboxylic acids, esters, in particular having between 18 and 80 carbon atoms, dialkyl carbonates, the 2 alkyl chains possibly being identical or different, and mixtures thereof and preferably among C10-C26 alcohols; preferably C20-C26.

9. Composition according to any one of the preceding claims, characterized in that the content of non-volatile oil(s) is at least 8% by weight, preferably between 8 and 20% by weight, relative to the total weight of the composition.

10. Composition according to any one of the preceding claims, characterized in that the film-forming polymer is chosen from silicone resins, silicone acrylate type copolymers, as well as their mixtures, and in particular chosen from the compounds with the following INCI names: trimethylsiloxysilicate, polypropylsilsesquioxane, polymethyl-silsesquioxane, acrylates / polytrimethylsiloxy-methacrylate copolymer, acrylates / dimethicone, even more particularly the film-forming polymers with the following INCI name: acrylates / polytrimethylsiloxy-me-thacrylate copolymer.

11. Composition according to any one of the preceding claims, characterized in that the content of film-forming polymer represents from 0.5 to 30% by weight, expressed as weight of active material, preferably from 1 to 20% by weight, even more particularly between 3 and 10% by weight, relative to the total weight of the composition.

12. Composition according to any one of the preceding claims, characterized in that the water content varies from 20 to 60% by weight, relative to the total weight of the composition.

13. Composition according to any one of the preceding claims, characterized in that the composition comprises at least one volatile oil.

14. Composition according to any one of the preceding claims, characterized in that the content of volatile oil(s) represents from 5 to 45% by weight, preferably 10 to 30% by weight, relative to the weight of the composition.

15. Method for making up human keratin materials, such as skin and / or lips, in particular lips, in which the composition according to any one of the preceding claims.