KERATINOUS MATERIAL CARE KIT

Abstract

Keratinous Material Care Kit The present invention relates to a kit, preferably for the care of keratinous materials, comprising: A) a first container comprising a substrate and an aqueous composition comprising at least one carboxyvinyl polymer; and B) a second container comprising an oily composition comprising at least one ion activator. The present invention also relates to a non-therapeutic method for the care of keratinous materials. Figure for the abstract: none

Description

Title of the invention: KERATINOUS MATERIAL CARE KIT technical field

[0001] The present invention relates to a kit, preferably for the treatment of keratinous materials. The present invention also relates to a non-therapeutic method for the treatment of keratinous materials. STATE OF THE ART

[0002] Among all the compositions for the care of keratinous materials, in particular of the skin, masks are known to have a high penetration efficiency on keratinous materials.

[0003] On the market, gel-type masks are popular because of their moisturizing effect and their affinity with the skin.

[0004] However, gel-type masks generally face production difficulties because it is difficult to pour the gels into sachets due to the high viscosity of the gels.

[0005] Efforts have been made to produce gel-type masks containing low-viscosity gels. However, it has been observed that a dripping problem exists with gel-type masks containing low-viscosity gel. When such masks are removed from the sachets, the gel drips very quickly from the mask substrate, which is unpleasant.

[0006] It will therefore be desirable to offer gel-type masks without production difficulties and without dripping problems. Summary of the invention

[0007] An object of the present invention is to offer gel-type masks without production difficulties and without dripping problems.

[0008] Another object of the present invention is to propose a non-therapeutic method for the treatment of keratinous materials.

[0009] Thus, according to a first aspect, the present invention proposes a kit, preferably for the care of keratinous materials, comprising: A. a first container comprising a substrate and an aqueous composition comprising at least one carboxyvinyl polymer; and B. a second container comprising an oily composition including at least one ion activator.

[0010] The inventors have discovered that the kit according to the present invention can be easily prepared, a gel-type mask without dripping problems can be formed from the kit according to the present invention.

[0011] The kit according to the present invention is suitable for use as a mask, in particular for the care of keratinous materials.

[0012] According to a second aspect, the present invention proposes a non-therapeutic method for treating keratinous materials with the kit according to the present invention, comprising: a. mixing the oily composition and the aqueous composition to form a mixed system on a substrate; and b. the application of the substrate with the mixed system onto keratinous materials.

[0013] Other subjects, features, aspects, and advantages of the present invention will be presented in the following description and will be partly evident from the description or may be learned through practice of the present invention. DETAILED DESCRIPTION OF THE INVENTION

[0014] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as that commonly accepted by a person skilled in the art of the present invention. Where the definition of a term in this description conflicts with the meaning commonly accepted by a person skilled in the art of the present invention, the definition given herein shall prevail.

[0015] As used herein, the use of the term "comprising" also discloses the embodiment in which no features other than the features specifically mentioned are present (i.e., * consisting of").

[0016] For the purposes of the present invention, the term "keratinous material" is understood to refer to the skin. Facial skin and the skin around the eyes are particularly considered in the context of the present invention. Substrates

[0017] According to the first aspect, the kit according to the present invention comprises at least one substrate.

[0018] Preferably, the substrate is insoluble in water.

[0019] For the purposes of the invention, the expression "insoluble in water" means that the substrate is not soluble in water and does not disintegrate when immersed in water.

[0020] More preferably, the substrate is a water-insoluble mask substrate.

[0021] The mask substrate can be a woven, knitted or non-woven fabric made of natural fibers such as cotton, paper pulp, bamboo, cellulose, alginate, collagen and proteins, of semi-natural fibers such as rayon viscose fibers or of synthetic fibers such as polyester fibers, fibers of polyethylene terephthalate, polyethylene fibers, and polypropylene fibers. Two or more fibers selected from the above may be used in combination.

[0022] The mask substrate may consist of one or more layers. If a multilayer substrate is used, the material of each layer may be identical or different from the others. The multilayer substrate may be prepared by layering multiple layers made from the materials mentioned above.

[0023] The mask substrate can have a wide variety of shapes, depending on the desired use and the characteristics of the mask.

[0024] The mask substrate is typically designed to adapt to the area on which topical application is desired. For example, when the mask is applied to the face, the mask substrate is designed to conform to the shape of the face, avoiding, if necessary, the areas of the eyes, nostrils, and mouth.

[0025] A person skilled in the art can determine the thickness and texture of the mask substrate based on the intended use. Aqueous composition

[0026] According to the first aspect, the kit according to the present invention comprises at least one aqueous composition.

[0027] Preferably, said aqueous composition comprises water.

[0028] Advantageously, water is present in the aqueous composition of the present invention in an amount ranging from 50% by weight to 99% by weight, preferably from 55% by weight to 97% by weight, more preferably from 60% by weight to 95% by weight, relative to the total weight of the aqueous composition.

[0029] Preferably, the aqueous composition comprises an organic solvent miscible with water (at room temperature 25 °C).

[0030] Preferably, the water-miscible organic solvent is chosen from ethanol, glycols and polyols having from 2 to 20 carbon atoms, preferably from 2 to 10 carbon atoms, and more preferably from 2 to 6 carbon atoms, as well as polyglycols.

[0031] More preferably, the water-miscible organic solvent is chosen from ethanol, glycerin, propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, caprylyl glycol, dipropylene glycol, diethylene glycol; polyethylene glycols with a degree of polymerization of 3 to 20, preferably 4 to 10, and mixtures thereof.

[0032] Advantageously, the water-miscible organic solvent is present in the aqueous composition of the present invention in an amount ranging from 0.5% by weight to 50% by weight, preferably from 1% by weight to 40% by weight, plus preferably from 2% by weight to 30% by weight, relative to the total weight of the aqueous composition.

[0033] Advantageously, the aqueous composition comprises at least one water-miscible organic solvent selected from glycerin, PEG-8, 1,3-propanediol, and combinations thereof, in an amount ranging from 2% by weight to 20% by weight, relative to the total weight of the aqueous composition. Carboxyvinyl polymers

[0034] According to the first aspect, the aqueous composition comprises at least one carboxyvinyl polymer.

[0035] Preferably, the carboxyvinyl polymer is chosen from i. copolymers resulting from the polymerization of at least one monomer (a) selected from α,[3-ethylenically unsaturated carboxylic acids or their esters, with at least one ethylenically unsaturated monomer (b) comprising a hydrophobic group; ii. homopolymers resulting from the polymerization of a monomer selected from α,[3-ethylenically unsaturated carboxylic acids and their esters; and their mixture.

[0036] The term "copolymer" refers both to copolymers obtained from two kinds of monomers and to those obtained from more than two kinds of monomers, such as terpolymers obtained from three kinds of monomers.

[0037] Preferably, the copolymers comprise at least one hydrophilic motif and at least one hydrophobic motif. The term "hydrophobic group" or "hydrophobic motif" means a radical having a saturated or unsaturated, linear or branched hydrocarbon chain, comprising at least 8 carbon atoms, preferably from 10 to 30 carbon atoms.

[0038] Preferably, the copolymers are chosen from among the copolymers resulting from polymerization:

[0039] - of at least one monomer of the following formula (1):

[0040] CH^CHtRjCOOH (1)

[0041] in which Ri designates H or CH3 or C2H5, that is to say the monomers of acrylic acid, methacrylic acid or ethacrylic acid, and

[0042] - of at least one monomer corresponding to the monomer of the following formula (2):

[0043] CH2=CH(R2)COOR3 (2)

[0044] in which R2 designates H or CH3 or C2H5 (i.e. acrylate, methacrylate or ethacrylate motifs, and preferably H (acrylate motifs) or CH3 (methacrylate motifs), and R3 is an alkyl radical having from 10 to 30 carbon atoms.

[0045] Preferably, the copolymer is cross-linked.

[0046] More specifically, among copolymers of this type, copolymers resulting from the polymerization of a mixture of monomers comprising:

[0047] - acrylic acid,

[0048] - a compound of formula (2) described above in which R2 denotes H or CH3 and R3 is an alkyl radical having 10 to 30 carbon atoms,

[0049] - a crosslinking agent, which is an unsaturated polyethylene monomer well-known copolymerizable, such as diallyl phthalate, allyl (meth)acrylate, divinylbenzene, (poly)ethylene glycol dimethacrylate and methylenebisacrylamide.

[0050] Examples of homopolymers may also be cited

[0051] - sodium polyacrylates, such as those sold under the name Cosmedia SP® containing 90% dry matter and 10% water, or Cosmedia SPL® in the form of an inverse emulsion containing approximately 60% dry matter, an oil (hydrogenated polydecene) and a surfactant (PPG-5 Laureth-5), both sold by BASF; and

[0052] - crosslinked (meth)acrylic acid homopolymers.

[0053] For the purposes of this patent application, the term "(meth)acrylic" means "acrylic or methacrylic".

[0054] More preferably, the carboxyvinyl polymer is chosen from crosslinked acrylic acid homopolymers, their esters and mixtures thereof.

[0055] In particular, Carbopol (CTFA name: carbomer), sold by Lubrizol, is one example of a carboxyvinyl polymer that can be used more specifically in the context of the present invention. Homopolymers of this type include those crosslinked with an allyl alcohol ether from the sugar range, such as, for example, the products sold under the names Carbopol 980, 981, 954, 2984 and 5984 by Lubrizol or the products sold under the names Synthalen®M and Synthalen®K by 3V.

[0056] Advantageously, the carboxyvinyl polymer is present in the aqueous composition of the present invention in an amount ranging from 0.05% by weight to 10% by weight, preferably from 0.05% by weight to 5% by weight, more preferably from 0.08% by weight to 2% by weight, even more preferably from 0.1% by weight to 1% by weight, most preferably from 0.12% by weight to 0.5% by weight, relative to the total weight of the aqueous composition. Oily composition

[0057] According to the first aspect, the kit according to the present invention comprises at least one oily composition.

[0058] Preferably, the oily composition comprises at least one oil.

[0059] Here “oil” means a fatty compound or a fatty substance which is in the form of a liquid at room temperature (25 °C) under atmospheric pressure (760 mmHg).

[0060] The oil can be chosen from vegetable oils, synthetic oils, and mixtures thereof.

[0061] Examples of vegetable oils include linseed oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, avocado oil, sasanqua oil, castor oil, safflower oil, jojoba oil, sunflower oil, almond oil, rapeseed oil, sesame oil, soybean oil, peanut oil, and mixtures thereof.

[0062] Examples of synthetic oils include ester oils, ether oils, hydrocarbon oils, fatty alcohols, and mixtures thereof.

[0063] Preferably, the oily composition according to the present invention further comprises at least one fatty alcohol oil.

[0064] Preferably, the fatty alcohol oil has a branched and / or unsaturated carbon-based chain containing 12 to 26 carbon atoms.

[0065] More preferably, the fatty alcohol oil is chosen from 2-octyldodecanol, isostearyl alcohol, oleyl alcohol, 2-hexyldecanol, 2-butyloctanol, 2-undecylpentadecanol, and one of their combinations.

[0066] Even more preferably, the composition according to the present invention comprises 2-octyldodecanol.

[0067] Advantageously, the oil is present in the oily composition according to the present invention in an amount ranging from 10% by weight to 50% by weight, preferably from 15% by weight to 45% by weight, more preferably from 20% by weight to 40% by weight, relative to the total weight of the oily composition. Ion activators

[0068] According to the first aspect, the oily composition includes at least one ion activator.

[0069] As used here, the expression "ion activator" refers to an agent that can react with the carboxyvinyl polymer to produce ions, so that the carboxyvinyl polymer begins to thicken the system comprising it.

[0070] In particular, in the sense of the present invention, after mixing the oily composition and the aqueous composition, the ion activator in the oily composition and the carboxyvinyl polymer in the aqueous composition react to produce ions, and the carboxyvinyl polymer begins to thicken the mixed system.

[0071] With the combination of the ion activator and the carboxyvinyl polymer, the mixed system obtained from the oily composition and the aqueous composition will not have any dripping problems.

[0072] Preferably, the ion activator is chosen from organic alkalis, inorganic alkalis, and their combinations.

[0073] More preferably, the ion activator is chosen from among the organic alkalis.

[0074] Even more preferably, the ion activator is chosen from among the alkanolamines, for example, monoethanolamine, diethanolamine, triethanolamine, monopropanolamine, dipropanolamine, tripropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-l-propanol, tromethamine and 2-amino-2-hydroxymethyl-l,3-propanediol, or a mixture thereof.

[0075] According to some preferred embodiments, the oily composition comprises triethanolamine.

[0076] Advantageously, the ion activator is present in the oily composition according to the present invention in an amount ranging from 0.01% by weight to 10% by weight, preferably from 0.3% by weight to 8% by weight, more preferably from 0.5% by weight to 5% by weight, even more preferably from 0.8% by weight to 4% by weight, relative to the total weight of the oily composition. Amphiphilic organic solvents

[0077] Preferably, the oily composition for the kit of the present invention comprises at least one amphiphilic organic solvent.

[0078] As used here, the expression "amphiphilic organic solvent" means that the solvent has a hydrophilic motif and a lipophilic motif.

[0079] The amphiphilic organic solvent is beneficial to the dispersion of the ion activator in the oily composition.

[0080] More preferably, the amphiphilic organic solvent is chosen from polypropylene glycol (PPG), polypropylene glycol alkyl esters, PPG alkyl ethers, and mixtures thereof.

[0081] Even more preferably, the non-ionic surfactant is chosen from dipropylene glycol, PPG-23 oleyl ether, PPG-36 oleate, and mixtures thereof.

[0082] Most preferably, the oily composition comprises dipropylene glycol.

[0083] Advantageously, the amphiphilic organic solvent is present in the oily composition according to the present invention in an amount ranging from 10% by weight to 85% by weight, preferably from 30% by weight to 80% by weight, more preferably from 50% by weight to 75% by weight, relative to the total weight of the oily composition. Non-ionic surfactants

[0084] Preferably, the oily composition for the kit of the present invention comprises at least one non-ionic surfactant.

[0085] More preferably, the non-ionic surfactant is chosen from among the sorbitol esters.

[0086] Even more preferably, the non-ionic surfactant is chosen from among the C12-C22 fatty acid esters of sorbitol.

[0087] The C12-C22 fatty acids used to prepare the C12-C22 fatty acid esters of sorbitol can be linear or branched, saturated or unsaturated.

[0088] Even more preferably, the non-ionic surfactant is chosen from sorbitan isostearate, sorbitan laurate, sorbitan stearate, sorbitan trioleate and mixtures thereof.

[0089] With the presence of the non-ionic surfactant, the mixed system obtained by mixing the aqueous composition and the oily composition can be in the form of an emulsion.

[0090] Advantageously, the anionic surfactant is present in the oily composition according to the present invention in an amount ranging from 0.1% by weight to 20% by weight, preferably from 0.5% by weight to 15% by weight, more preferably from 1% by weight to 10% by weight, relative to the total weight of the oily composition. cosmetic active ingredients

[0091] Depending on the end use, the kit according to the present invention may include one or more cosmetic active ingredients in the aqueous composition and / or the oily composition.

[0092] It is easy for a person skilled in the art to adjust the quantity of the cosmetic active ingredient based on the end use of the kit according to the present invention.

[0093] Advantageously, the weight ratio of the oily composition to the aqueous composition is 1:1 to 1:20, preferably 1:3 to 1:10. Additional adjuvants or additives

[0094] The kit of the present invention may include additional conventional cosmetic adjuvants or additives, for example, perfumes, chelating agents, and mixtures thereof in the aqueous and / or oily composition.

[0095] A person skilled in the art can choose the quantity of additional adjuvants or additives so as not to have a negative impact on the final use of the kit according to the present invention.

[0096] According to a preferred embodiment, the present invention provides a kit comprising A. a first container comprising a water-insoluble mask substrate and an aqueous composition comprising from 0.1% by weight to 0.5% by weight of at least one carboxyvinyl polymer selected from crosslinked (meth)acrylic acid homopolymers, their esters and mixtures thereof, relative to the total weight of the aqueous composition, B. a second container comprising at least one oily composition, comprising from 0.5% by weight to 5% by weight of triethanolamine, relative to the total weight of the oily composition. Preparation and use

[0097] The oily composition and the aqueous composition for the kit according to the present invention can be prepared by routine practice.

[0098] The kit according to the present invention can be used for topical application and can in particular be used for the care of keratinous materials, and in particular human skin.

[0099] According to the second aspect, the present invention proposes a non-therapeutic method for treating keratinous materials with the kit according to the present invention, comprising:

[0100] a) mixing the oily composition and the aqueous composition to form a mixed system on the substrate; and

[0101] b) the application of the substrate with the mixed system onto the keratinous materials.

[0102] In particular, keratinous materials are the skin of the face and / or the skin around eyes.

[0103] The mixed system formed by the oily composition and the aqueous composition for the kit according to the present invention does not present a dripping problem so that the mixed system will not flow rapidly from the substrate, for example at a rate of one or more drops per minute.

[0104] The application time of the remaining mixed system on keratinous materials can be determined based on the intended use. Examples

[0105] The present invention is illustrated in more detail by the examples described below, which are given by way of non-limiting illustrations.

[0106] The main raw materials used, their trade names and their suppliers are listed in Table 1.

[0107] [Tables] INCI name Trade name Supplier Carbomer (Carbomer) CARBOPOL 980 POLYME R LUBRIZOL PEG-8 PLURACARE E 400 BASF Propanediol 1,3-PROPANEDIOL ZHANGJIAGANG GLO RY CHEMICAL IND Inventive Example 1 and Comparative Examples 1-2

[0108] The oily compositions and aqueous compositions for the kits of inventive example (E1) 1 and comparative examples (CE) 1-2 were prepared according to the quantities of components given in Table 2. The quantity of each component is given as % by weight of the total weight of the oily composition or aqueous composition of each example.

[0109] [Tables2] Components El. 1 EC. 1 EC. 2 Oily Composition Triethanolamine 2.2 0 2.2 Octyldodecanol 30 30 30 Dipropylene glycol QS100 QS100 QS100 Sorbitan isostearate 6 6 6 Aqueous Composition Carbomer 0.25 0.25 0 PEG-8 2 2 2 Propanediol 3 3 3 Glycerin 3 3 3 Water QS100 QS100 QS100

[0110] The oily composition and the aqueous composition of inventive example 1 represent an oily composition and an aqueous composition for the kit of the present invention.

[0111] The oily composition of comparative example 1 does not include at least one ion activator.

[0112] The aqueous composition of comparative example 2 does not include at least one carboxyvinyl polymer. Preparation of compositions

[0113] The above oily compositions were prepared as follows:

[0114] 1) mixture of octyldodecanol, dipropylene glycol and triethanolamine (the case if necessary) in a tank A with stirring;

[0115] 2) introduction of sorbitan isostearate into tank A at a temperature of 75-80°C by shaking to obtain an oily composition.

[0116] The above aqueous compositions were prepared as follows: 1. Mixture of water, glycerin, PEG-8 and propanediol at 80 °C in a vessel B while stirring; and 2. Introduction of carbomer (if applicable) into vessel B with stirring to obtain aqueous compositions. Preparing the kits

[0117] The oily composition and the aqueous composition as well as a viscose fiber mask substrate were poured into different chambers of a double chamber sachet, one chamber containing the oily composition and one chamber containing the mask substrate and the aqueous composition, then the sachet was sealed.

[0118] The oily composition can be pushed into the chamber containing the mask substrate and the aqueous composition to be mixed with the aqueous composition so as to form an emulsion. Assessment

[0119] The kits of inventive example 1 and comparative examples 1-2 were evaluated as follows. Viscosity

[0120] The oily composition and the aqueous composition were mixed to form a uniform emulsion for each kit of inventive example 1 and comparative examples 1-2.

[0121] The viscosity of each emulsion for each kit of inventive example 1 and comparative examples 1-2 was measured using a Lamy Rheology Rheomat RM 200 viscometer with spindle no. 2 at a speed of 200 rpm, at room temperature (25 °C) and atmospheric pressure (760 mmHg). The values ​​were recorded at T = 10 minutes.

[0122] The results on the viscosity of the emulsions obtained from the kits of inventive example 1 and comparative examples 1-2 have been summarized in Table 3.

[0123] [Tables3] Properties El. 1 EC. 1 EC. 2 Viscosity (mPa-S) 2940 <336 <336

[0124] Table 3 shows that the uniform emulsion obtained from the kit of inventive example 1 has a suitable viscosity at room temperature (25 °C). Runoff problem

[0125] The oily composition was pushed into the chamber containing the mask substrate and the aqueous composition to be mixed with the aqueous composition so as to form a uniform emulsion by massaging for 1 minute for each kit of inventive example 1 and comparative examples 1-2.

[0126] Next, the mask substrates were taken from the sachets to determine the flow rate of the emulsions of the mask substrates.

[0127] If an emulsion flows from the corresponding mask substrate at a speed greater than 1 drop per second, the corresponding kit is then considered to have a flow problem.

[0128] The dripping problem of each kit of inventive example 1 and comparative examples (CE) 1-2 has been summarized in Table 4.

[0129] [Tables4] Properties El. 1 EC. 1 EC. 2 Spill Problem No Yes Yes

[0130] It can be seen in Table 4 that the kit of inventive example 1 does not present any dripping problems.

Claims

Demands

1. Kit, preferably for the care of keratinous materials, comprising: A) a first container comprising a substrate and an aqueous composition comprising at least one carboxyvinyl polymer; and B) a second container comprising an oily composition comprising at least one ion activator.

2. Kit according to claim 1, wherein the carboxyvinyl polymer is selected from i) copolymers resulting from the polymerization of at least one monomer (a) selected from α,[3-ethylenically unsaturated carboxylic acids or their esters, with at least one monomer (b) ethylenically unsaturated comprising a hydrophobic group; ii) homopolymers resulting from the polymerization of a monomer selected from α,[3-ethylenically unsaturated carboxylic acids and their esters, and mixtures thereof, preferably, the carboxyvinyl polymer is selected from crosslinked (meth)acrylic acid homopolymers, their esters and mixtures thereof.

3. Kit according to any one of claims 1 and 2, wherein the carboxyvinyl polymer is present in the aqueous composition in an amount from 0.05% by weight to 10% by weight, preferably from 0.05% by weight to 5% by weight, more preferably from 0.08% by weight to 2% by weight, even more preferably from 0.1% by weight to 1% by weight, most preferably from 0.12% by weight to 0.5% by weight, relative to the total weight of the aqueous composition.

4. Kit according to any one of claims 1 to 3, wherein the ion activator is selected from organic alkalis, inorganic alkalis, and combinations thereof, preferably selected from alkanolamines, more preferably selected from monoethanolamine, diethanolamine, triethanolamine, monopropanolamine, dipropanolamine, tripropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-1-propanol and 2-amino-2-hydroxymethyl-1,3-propanediol, or a mixture thereof.

5. Kit according to any one of claims 1 to 4, wherein the ion activator is present in the oily composition in a quantity ranging from 0.01% by weight to 10% by weight, preferably from 0.3% by weight to 8% by weight, more preferably from 0.5% by weight to 5% by weight, even more preferably from 0.8% by weight to 4% by weight, relative to the total weight of the oily composition.

6. Kit according to any one of claims 1 to 5, wherein the oily composition further comprises at least one amphiphilic organic solvent, preferably selected from polypropylene glycol (PPG), polypropylene glycol alkyl esters, PPG alkyl ethers, and mixtures thereof, more preferably selected from dipropylene glycol, PPG-23 oleyl ether, PPG-36 oleate, and mixtures thereof, even more preferably the oily composition comprises dipropylene glycol.

7. Kit according to any one of claims 1 to 6, wherein the oily composition further comprises at least one non-ionic surfactant, preferably the non-ionic surfactant is selected from sorbitol esters, more preferably selected from C12-C22 fatty acid esters of sorbitol, even more preferably selected from sorbitan isostearate, sorbitan laurate, sorbitan stearate, sorbitan trioleate, and mixtures thereof.

8. Kit according to claim 1, comprising A) a first container comprising a water-insoluble mask substrate and an aqueous composition comprising from 0.1% by weight to 0.5% by weight of at least one carboxyvinyl polymer selected from crosslinked (meth)acrylic acid homopolymers, their esters and mixtures thereof, relative to the total weight of the aqueous composition, B) a second container comprising at least one oily composition, comprising from 0.5% by weight to 5% by weight of triethanolamine, relative to the total weight of the oily composition.

9. Kit according to any one of claims 1 to 8, wherein the weight ratio of the oily composition to the aqueous composition is from 1:1 to 1:20, preferably from 1:3 to 1:

10.

10. A non-therapeutic method for treating keratinous materials with the kit according to any one of claims 1 to 9, comprising a) mixing the oily composition and the aqueous composition to form a mixed system on a substrate; and b) the application of the substrate with the mixed system onto the keratinous materials.