Method for producing pig iron in a production line equipped with an electric smelting furnace

Abstract

The present invention is a method for producing pig iron in a smelting furnace 13 provided with a container 20, comprising the following successive steps: - loading the container 20 with a DRI product, - melting the DRI product to form a pig iron layer 14 covered with a slag layer 23, - transferring the pig iron 14 to the desulphurization station 15, and - injecting a silicon-containing material into the pig iron 14 at the desulphurization station 15. The present invention also deals with the production of steel from said pig iron.

Description

Technical Field

[0001] The present invention relates to a method for producing pig iron, also called hot metal, and a method for producing steel from such pig iron.

Background Art

[0002] Currently, steel can be produced through two main manufacturing routes. Today, the most commonly used manufacturing route, called the "BF-BOF route", consists of producing hot metal in a blast furnace by reducing iron oxide using a reducing agent, mainly coke, and then converting the hot metal into steel in a converter process or a basic oxygen furnace (BOF). This route emits a significant amount of CO2 both in the production of coke from coal in the coke plant and in the production of hot metal.

[0003] The second main route includes the so-called "direct reduction process". Among them, there are methods such as those by brands MIDREX (registered trademark), FINMET (registered trademark), ENERGIRON (registered trademark) / HYL, COREX (registered trademark), FINEX (registered trademark), etc., where sponge iron is produced from the direct reduction of an iron oxide carrier in the form of HDRI (hot direct reduced iron), CDRI (cold direct reduced iron) or HBI (hot briquetted iron). Sponge iron in the form of HDRI, CDRI and HBI is further processed in an electric furnace to produce steel.

[0004] Therefore, one of the main options for steelmakers to reduce CO2 emissions is to switch from the BF-BOF route to the DRI route. However, there are some limitations to using DRI products in a classical electric furnace together with iron scrap. In fact, scrap contains many impurities and the resulting molten steel needs to be further processed to produce high-quality steel grades. Therefore, investment in new molten steel treatment tools is required.

Summary of the Invention

Problems to be Solved by the Invention

[0005] Therefore, an object of the present invention is to improve the drawbacks of the manufacturing routes for pig iron and steel by providing a new route that efficiently minimizes the impact on such manufacturing environments.

Means for Solving the Problem

[0006] This problem is solved by a method for manufacturing pig iron as detailed in claim 1.

[0007] Such a method can also include the optional features of claims 2 to 7, considered separately or in any possible technical combination.

[0008] The present invention also addresses a method for manufacturing steel as described in claim 8.

[0009] Such a method can also include the optional feature of claim 9.

[0010] Other features and advantages of the present invention will become apparent from the description of the present invention, which is given below by way of indication and with reference to the accompanying drawings and is in no way limiting.

Brief Description of the Drawings

[0011]

Figure 1

Figure 2

Modes for Carrying Out the Invention

[0012] The elements in the figures are illustrative and may not be drawn to scale.

[0013] Figure 1 shows a steel manufacturing route by the DRI route from the reduction of iron to the casting of steel into semi-finished products such as slabs, billets, blooms or strips. Iron ore 10 is first reduced in the direct reduction plant 11. This direct reduction plant 11 can be designed to implement any type of direct reduction technology such as MIDREX (registered trademark) technology or Energiron (registered trademark). The direct reduction process may be, for example, a process based on traditional natural gas or biogas.

[0014] In a preferred embodiment, the DRI product used in the method according to the invention is produced using a reducing gas based on biogas resulting from the combustion of biomass.

[0015] Biomass is a renewable organic material derived from plants and animals. Biomass sources include, in particular, wood and wood processing waste such as sawdust, wood pellets and wood chips, sawdust and waste from sawmills and furniture factories, and black liquor from pulp and paper mills, crops and agricultural waste such as corn, soybeans, sugarcane, switchgrass, woody plants and algae, and crop and food processing residues, but also municipal solid waste such as paper, cotton and wool products, and food, yard and wood waste, animal excrement and biological materials in domestic sewage. In the context of the present invention, biomass may also include plastic residues such as recycled waste plastics such as solid waste fuel or SRF.

[0016] Whenever natural gas or biogas is used as the reducing gas, the carbon content of the DRI product can be set to a maximum of 3 wt%, usually in the range of 2 - 3 wt%.

[0017] In another preferred embodiment, the DRI product used in the method according to the invention is produced by a so-called H2-DRI process in which the reducing gas contains more than 50% by volume, preferably more than 60, 70, 80 or 90% by volume of hydrogen, or consists entirely of hydrogen. H2-DRI products contain much lower levels of carbon, typically less than 1% by weight or even lower, than natural gas or biogas DRI. In a preferred embodiment, the hydrogen used in the DRI reducing gas is derived from the electrolysis of water, which is preferably powered in part or in whole by CO2-neutral electricity. CO2-neutral electricity is defined in particular as electricity from renewable sources, which are naturally replenished on the human time scale, including sources such as sunlight, wind, rain, tides, waves and geothermal energy. In some embodiments, the use of electricity from nuclear sources can be used because it does not emit the CO2 being produced.

[0018] Regardless of the DRI process used, the resulting direct reduced iron (DRI) product 12 is then charged into a smelting furnace 13 where the reduction of the iron oxide is completed and the product is melted to produce pig iron.

[0019] DRI products can be transferred to the smelting furnace in various forms. Preferably, the directly reduced iron product (DRI product) is in a hot form as an HDRI product (so-called Hot DRI), or in a room temperature form as a CDRI product (so-called Cold DRI), or in a hot formed form as an HBI product (so-called hot briquette iron), and / or preferably in a particulate form having an average particle size of up to 10.0 mm, more preferably up to 5.0 mm, and is supplied to the smelting furnace.

[0020] This is preferably charged directly as a hot product having a temperature of 500°C to 700°C at the outlet of the direct reduction plant 11. Thereby, the amount of energy required for melting can be reduced. When hot charging is not possible, for example, when the direct reduction plant 11 and the steelmaking furnace 13 are not in the same location, or when the steelmaking furnace 13 is stopped for maintenance and thus the DRI product has to be stored, the DRI product may be charged at room temperature or a preheating step may be carried out.

[0021] The steelmaking furnace 13 uses the electrical energy provided by several electrodes to melt the DRI product 12 and produce hot metal 14. In a preferred embodiment, some or all of the required electric power is derived from CO2-neutral power. A more detailed description of the steelmaking furnace will be given hereinafter with reference to FIG. 2.

[0022] The hot metal 14 is then transferred to a hot metal ladle through at least one tap hole 25 provided with at least one runner 26. Such tap holes 25 are arranged at the lower part of the container 20. They may be arranged in the side wall or the bottom wall of the container. Usually, there are the same number of auxiliary runners as tap holes, and the runners intersect to form a main runner, guiding the extracted hot metal to the hot metal ladle.

[0023] This hot metal ladle may be a simple ladle or a torpedo ladle.

[0024] Pig iron 14 is sent to a desulfurization station 15 to carry out a desulfurization step. This desulfurization step can be carried out directly in a dedicated container or, preferably, in a pig iron ladle in order to avoid the transfer of the molten metal and the associated heat losses. This desulfurization step is necessary for the production of steel grades that require a low sulfur content, for example set at a maximum of 0.03 wt%. Desulfurization under oxidizing conditions is not effective and is therefore preferably carried out either on the pig iron before oxygen refining or in the steel ladle after steel deoxidation. For very low sulfur contents, for example less than 0.004 wt%, deoxidation and desulfurization are combined for overall higher performance. Thus, low sulfur grades benefit from carrying out pig iron desulfurization before the conversion step.

[0025] Desulfurization of the pig iron can be carried out by adding reagents based on calcium or magnesium compounds, such as sodium carbonate, lime, calcium carbide and / or magnesium, in particular, into the pig iron. This can be done, for example, by injecting these reagents into the pig iron ladle. The desulfurized pig iron 16 has a sulfur content of preferably less than 0.03 wt%, preferably less than 0.004 wt%.

[0026] The desulfurized pig iron 16 can then be transferred into a converter 17. The converter basically converts the molten metal into molten steel by blowing oxygen into the molten metal to decarburize it. This is generally called a basic oxygen furnace (BOF). Iron scrap 18 resulting from the recycling of steel can also be charged into the converter 17 in order to benefit from the heat released by the exothermic reaction resulting from the injection of oxygen into the pig iron.

[0027] Next, the molten steel 19 thus formed can be transferred at any time as required to one or more secondary metallurgy tools 20A, 20B, such as ladle furnaces, RH (Ruhrstahl-Heareus) vacuum vessels, vacuum tank degassing devices, alloying and stirring stations, etc., and processed to reach the steel composition required according to the steel grade to be manufactured. Then, the molten steel having the required composition 21 can be transferred to the casting plant 22, where it can be converted into solid products such as slabs, billets, blooms or strips.

[0028] As shown in FIG. 2, the smelting furnace 13 is composed of a container 20 that can accommodate hot metal. The container 20 may be, for example, circular or rectangular. This container 20 is closed by a roof 21 provided with several openings for receiving the electrodes 22 inserted into the container 20 and other openings for enabling the charging of raw materials into the container 20.

[0029] The electrodes 22 provide the electrical energy necessary to melt the charged raw materials to form pig iron. These are preferably Söderberg type electrodes.

[0030] During the melting of the raw materials, two layers are formed: a layer of pig iron 14, which is the densest and thus located at the bottom of the container 20, and a slag layer 23 located above the pig iron 14. The slag layer 23 can be partially covered by a pile of raw materials 24 waiting to be melted.

[0031] The container 20 also has openings called tap holes 25 located at its lower part, which enable the discharge of the pig iron 14 while retaining most of the slag inside the container 20. They may be arranged on the side wall or the bottom wall of the container.

[0032] The smelting furnace 13 may be a SAF (Submerged-Arc Furnace) in which the electrodes are immersed in the slag layer 23 or an OSBF (Open Slag Bath Furnace) in which the electrodes 22 are located above the slag layer 23. This is preferably an OSBF as shown in the figure.

[0033] In the mechanism of the present invention, the silicon-containing material is added to the pig iron at the desulfurization station 15. This addition can be carried out through an injection device. Silicon has a strong deoxidizing ability at high temperatures, particularly at about 1600 °C, which is the temperature of the molten steel in the converter. Silicon reacts with oxygen and then contributes to the formation of slag in the converter. This reaction is exothermic and thus provides additional energy for scrap melting. The more scrap is used, the smaller the environmental footprint of the process.

[0034] It has been observed by the inventors that injecting silicon into the pig iron at that stage enables complete dissolution of silicon with good yield before the pig iron reaches the converter 17. Furthermore, this addition improves the efficiency of the desulfurization process by maintaining strong local deoxidation conditions.

[0035] In a preferred embodiment, the injection is carried out using a lance commonly used for injecting desulfurization reagents. Then, a carrier gas is added to this. This gas is preferably inert and can be made of nitrogen, argon, helium or carbon monoxide, or any mixture of such gases.

[0036] Such silicon can be added in different forms. The silicon may be metallic silicon Si, silicon carbide SiC, silicomanganese SiMn, calcium silicate SiCa, or a ferrosilicon alloy FeSi such as FeSi75 or FeSi65.

[0037] When using DRI products in the smelting furnace 13, a natural amount of silicon of usually less than 0.2% by weight, and further less than 0.1% by weight, is brought about. The final silicon content of the pig iron is preferably set to a value of 0.1 - 0.4% by weight, preferably 0.2 - 0.4% by weight. If necessary, further addition of silicon can be carried out in the converter 17.

[0038] In a preferred embodiment, the carbon-containing material may be injected in the desulfurization station 15 together with the silicon-containing material.

[0039] As described above, the carbon content of the pig iron 14 produced via the DRI route is generally less than 3% by weight. However, in order to meet the requirements of the subsequent steelmaking process in the converter, the pig iron should preferably have a carbon content as close as possible to the saturation level of 4.5% by weight. In a preferred embodiment, the carbon content of the pig iron is in the range of 4.0 - 4.5% by weight.

[0040] In fact, carbon is necessary for the steelmaking process carried out in the converter 17 by oxygen blowing. This is because the reaction between carbon and oxygen produces carbon monoxide gas, which brings about strong and efficient stirring of the molten metal, and thus improves the removal of impurities from the steel. This reaction is exothermic and thus provides additional energy for melting iron scrap, making it possible to incorporate such iron scrap resulting from steel recycling in larger quantities. The more iron scrap is used, the smaller the environmental footprint of the steelmaking process.

[0041] The carbon-containing material can be derived from different sources. This can be selected, for example, from among coke, anthracite, silicon carbide, calcium carbide or any mixture of these sources, but can also advantageously be obtained from renewable sources such as biomass for part or all of the carbon load. In particular, biochar can be used. Adding calcium carbide is particularly advantageous because calcium atoms can provide a desulfurization effect.

[0042] In another embodiment, the carbon-containing material may also be made of a composite briquette in which an iron source is mixed with one or some of the aforementioned carbon sources.

[0043] In a preferred embodiment, the iron source can be selected from among sludge from an electric furnace, a converter or a smelter, slag from an electric furnace or a converter, or any waste rich in iron from a steel manufacturing route.

[0044] Adding silicon carbide is particularly advantageous because it enables an increase in the carbon content of pig iron after adding silicon. Adding a mixture of calcium carbide and silicon carbide is even more advantageous because it provides the addition of carbon and silicon while ensuring desulfurization.

Claims

1. A method for producing pig iron in a production line comprising an electric smelting furnace (13) and a desulfurization station (15) including a container (20), the method comprising the following consecutive steps: - loading a DRI product into the container (20); - melting the DRI product to form a pig iron layer (14) covered with a slag layer (23); - transferring the pig iron (14) to the desulfurization station (15); and - injecting a silicon-containing material into the pig iron (14) at the desulfurization station (15). A method comprising the above steps.

2. The method according to claim 1, wherein the silicon-containing material is injected in an amount sufficient to reach a final silicon content of 0.1 to 0.4 wt% in the pig iron (14).

3. The method according to claim 1 or 2, wherein the silicon-containing material is injected together with a carrier gas.

4. The method according to any one of claims 1 to 3, wherein the silicon-containing material is selected from metallic silicon Si, silicon carbide SiC, silicomanganese SiMn, calcium silicate SiCa, ferrosilicon alloy FeSi, or a mixture of any of these materials.

5. The method according to any one of claims 1 to 4, wherein the injected silicon-containing material has particles with a particle size of less than 3 mm.

6. The method according to any one of claims 1 to 5, wherein the DRI product is produced using a reducing gas containing at least 50% by volume of hydrogen before being loaded into the smelting furnace (13).

7. The method according to any one of claims 1 to 6, wherein a carbon-containing material is added to the silicon-containing material and injected into the pig iron (14).

8. A method for producing steel, wherein the pig iron produced according to any one of claims 1 to 7 is transferred from the smelting furnace (13) to a converter (17), and then the carbon content of the pig iron is reduced to a value of less than 2.1 wt% by oxygen blowing to obtain molten steel.

9. The method for producing steel according to claim 8, wherein iron scrap is added to and melted with the pig iron in the converter (17).

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