Method for producing hydrogen powder

By carbonizing specific plants with deep ocean water or water-soluble silicon, and firing coral powder under controlled conditions, the method enhances charcoal adsorption and produces hydrogen powder for effective hydrogen delivery, addressing the limitations of existing charcoal and coral powder.

JP7710124B2Active Publication Date: 2025-07-18SUMI PLUS CO LTD
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Patent Information

Application Number
JP2024147023
Authority / Receiving Office
JP · JP
Patent Type
Patents
Current Assignee / Owner
Filing Date
2024-08-28
Publication Date
2025-07-18
Estimated Expiration
2040-06-02

AI Technical Summary

Technical Problem

Existing charcoal and activated carbon adsorption characteristics are not optimal, and there is a need to enhance the ability of charcoal to carry hydrogen, while coral powder is rich in minerals but lacks effective hydrogen-carrying capabilities.

Method used

The method involves carbonizing plants like Japanese red pine, bamboo, and coconut husks at specific atmospheric pressures and temperatures, and using deep ocean water or water-soluble silicon to enhance adsorption. For hydrogen powder, coral powder is fired at controlled pressures and temperatures with deep ocean water or water-soluble silicon to facilitate hydrogen adsorption.

Benefits of technology

The method improves charcoal adsorption and enables the charcoal to carry a large amount of hydrogen, while the hydrogen powder can efficiently deliver hydrogen to the body and skin, offering health and beauty benefits.

✦ Generated by Eureka AI based on patent content.

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Abstract

To provide a production method of hydrogen powders using coral powders that can carry (adsorb) much hydrogen.SOLUTION: A production method of hydrogen powders that supplement an essential and minor mineral includes at least the steps of: setting an atmospheric pressure in a furnace to 1-6 atm to calcine coral powders at 50-200°C; and forming hydrogen carrying using ocean deep water or water-soluble silicon-containing water subjected to reduction processing by hydrogen. Instead of the coral powders, powders that contain the essential and minor mineral are used, the powders including at least one of powders impregnated with ocean deep water, hydroxyapatite derived from naturel organisms or minerals, ocean deep water powders, seaweed powders, efflorescent seashell calcium powders, oyster shell powders, scallop shell powders, margaritifera shell powders, fine particle silicon dioxide (silica), and water-soluble silicon (water-containing silica / water-containing silicate such as metasilicate or orthosilicate).SELECTED DRAWING: Figure 2
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Description

Technical Field

[0001] The present invention relates to a method for producing "functional edible charcoal" having a high adsorption function for food use and "high-concentration hydrogen-carrying powder" containing minerals for beauty use.

Background Art

[0002] Conventionally, edible charcoal suitable for adding to food has been known. For example, Patent Document 1 discloses a method for producing edible charcoal for adding to food. In Patent Document 1, a smoking treatment step of obtaining uncarbonized material obtained by smoking naturally dried bamboo at 50 to 60 ° C, a refining step of igniting this uncarbonized material, refining it at a kiln temperature of 800 to 1100 ° C and carbonizing it, and then slowly cooling it to obtain raw charcoal, a coarse pulverization step of coarsely pulverizing the obtained raw charcoal to obtain a powder having a particle size of 2 to 5 mm, and the powder obtained in this coarse pulverization step is pulverized into fine powder having a particle size of 10 to 30 μm, 20 to 40 μm using a vibration mill, or fine powder having a particle size of 0.5 to 9 μm using an air jet mill. And edible charcoal is produced through a fine pulverization step. By using bamboo charcoal fine powder having a particle size of 0.5 to 40 μm as edible charcoal, the texture is not impaired even when added to food, and furthermore, since it is bamboo charcoal fine powder having a stable product particle size, it is said to be easy to handle.

[0003] On the other hand, Patent Document 2 discloses a health food containing an Indian traditional medical material that enhances the efficacy of suppressing allergic symptoms. This health food is characterized in that the seeds of Kalijiri (scientific name: Vernonia Anthelmintica) are the main component, coral powder, and the bark of Ditah or the powder of the flower of Marigold (Tagetes erecta) are added as effect promoters, and furthermore, at least one of Tsukuboxa, sunflower seeds, fennel, grape skin extract and kelp is added as an effect promoter and the dried powder is granulated.

[0004] Recently, from the perspective of preventive medicine, the concept of "hydrogen medicine" that utilizes the excellent properties of hydrogen has been spreading. Since harmful reactive oxygen species are considered the root cause of all diseases, it is believed that taking in hydrogen on a daily basis and eliminating harmful reactive oxygen species may reduce the risk of getting sick. For this reason, taking hydrogen water or inhaling hydrogen gas has attracted attention as a means of incorporating hydrogen into the body.

[0005] Patent Document 3 discloses a technique in which coral calcium is adopted as a negative hydrogen ion releasing substance, and this coral calcium is subjected to two-stage firing of oxidation firing and reduction firing to be provided for consumption. In this technique, a mixture of coral calcium and wheat flour is molded, subjected to oxidation firing and reduction firing, and this fired body is made into a powder and formed into tablets or capsules to be negative hydrogen ions (H-).

Prior Art Documents

Patent Documents

[0006]

Patent Document 1

Patent Document 2

Patent Document 3

Summary of the Invention

Problems to be Solved by the Invention

[0007] However, the adsorption characteristics of charcoal and activated carbon still have room for improvement, and it is possible to further enhance the adsorption characteristics. In addition, coral is rich in minerals and has beneficial functions for the human body, and there is room to make it easier to carry (adsorb) hydrogen.

[0008] The present invention has been made in view of such circumstances, and an object thereof is to provide a method for producing functional edible charcoal with improved adsorption characteristics of charcoal and activated charcoal, and a method for producing hydrogen powder using coral powder capable of carrying (adsorbing) a large amount of hydrogen.

Means for Solving the Problems

[0009] (1) To achieve the above object, the present invention has taken the following means. That is, the method for producing functional edible charcoal of the present invention is a method for producing functional edible charcoal having a high adsorption function and intended for food use, comprising setting the atmospheric pressure in the furnace to 1 to 3 atmospheres, and carbonizing plants including Japanese red pine, bamboo, ume fruits or coconut husks, and oyster shells at 500°C to 1500°C, and a step of causing an activation reaction using "deep ocean water or water containing water-soluble silicon" that has been reduced by hydrogen.

[0010] (2) Further, the method for producing hydrogen powder of the present invention is a method for producing hydrogen powder that supplements essential and trace minerals, comprising setting the atmospheric pressure in the furnace to 1 to 6 atmospheres, and firing coral powder at 50°C to 200°C, and a step of causing hydrogen carrying (adsorption) using "deep ocean water or water containing water-soluble silicon" that has been reduced by hydrogen.

[0011] (3) Further, the method for producing hydrogen powder of the present invention is characterized in that, instead of the coral powder, a powder containing at least one of essential and trace minerals including powder impregnated with deep ocean water, natural biogenic or mineral-derived hydroxyapatite, deep ocean water powder, seaweed powder, weathered shell calcium powder, oyster shell powder, scallop shell powder, pearl oyster shell powder, fine silica, and water-soluble silicon (hydrated silica or hydrated silicic acid such as metasilicic acid or orthosilicic acid) is used.

Effects of the Invention

[0012] According to the present invention, the adsorption characteristics are improved, and a large amount of hydrogen can be carried (adsorbed).

Brief Description of the Drawings

[0013]

Figure 1

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Figure 3

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Figure 8

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Figure 10

Modes for Carrying Out the Invention

[0014] In this specification, the functional edible charcoal is referred to as "Super Cleanse Activated Carbon". The manufacturing method of the Super Cleanse Activated Carbon according to this embodiment includes at least a step of setting the atmospheric pressure in the furnace to 1 to 3 atmospheres and carbonizing plants including Japanese red pine, bamboo, ume fruits, or coconut shells and oak acorns at 500°C to 1500°C, and a step of causing an activation reaction using "deep ocean water or water containing water-soluble silicon" that has been reductively processed with hydrogen. Also, in this specification, the hydrogen powder according to this embodiment is referred to as "Reductive Mineral Hydrogen Powder". The manufacturing method of the Reductive Mineral Hydrogen Powder according to this embodiment includes at least a step of setting the atmospheric pressure in the furnace to 1 to 6 atmospheres and firing coral powder at 50°C to 200°C, and a step of causing an activation reaction using "deep ocean water or water containing water-soluble silicon" that has been reductively processed with hydrogen. Thus, in this embodiment, it is characterized in that an activation reaction is caused using "deep ocean water or water containing water-soluble silicon" that has been reductively processed with hydrogen.

[0015] Deep ocean water is generally understood to be seawater at a depth of 200 m or more, and has characteristics such as cleanliness, rich in inorganic nutrients, and low-temperature stability compared to surface water. That is, since deep ocean water is not affected by river water polluted by human wastewater, it is not contaminated by chemical substances, and since sunlight does not reach it and plankton does not grow, harmful bacteria and the like are also less than one-thousandth of surface water. Also, compared to surface water, it is rich in inorganic nutrients necessary for the growth of phytoplankton, and further has the characteristics that the water temperature and contained components hardly change and the water quality is stable. The Super Cleanse Activated Carbon and Reductive Mineral Hydrogen Powder according to this embodiment use deep ocean water reductively treated with hydrogen, and thus it is considered that treatment can be performed in a state where the ionization of minerals such as calcium and magnesium is promoted.

[0016] The inventors conducted tests on the function of "deep ocean water processed by reduction with hydrogen" (sometimes referred to as "reduced processed mineral super-concentrated solution") to eliminate alcohol and acetaldehyde. The equipment used was "Gas Chromatograph GC-2010AF / AOC: manufactured by Shimadzu Corporation", and the reagents used were "whiskey (Suntory Square Bottle)" and "acetaldehyde (manufactured by Wako Pure Chemical Industries, Ltd.)". The test method is as follows.

[0017] [Regarding alcohol] (a) Three drops of the sample were added to 100 ml of undiluted whiskey (40% alcohol), stirred, and after standing for 2 hours, the alcohol was measured. (b) Six drops of the sample were added to 100 ml of undiluted whiskey (40% alcohol), stirred, and after standing for 2 hours, the alcohol was measured.

[0018] [Regarding acetaldehyde] (a) Acetaldehyde (90%) was diluted 100-fold to make a 0.9% solution. (b) Three drops of the sample were added to 100 ml of the above (a), stirred, and after 30 minutes, the acetaldehyde concentration was measured. (c) Six drops of the sample were added to 100 ml of the above (a), stirred, and after 30 minutes, the acetaldehyde concentration was measured.

[0019] The results are as shown in the following table.

Table 1

[0020] Thus, it was confirmed that the "deep ocean water subjected to reduction processing with hydrogen" according to this embodiment exhibits the function of eliminating alcohol and acetaldehyde. Acetaldehyde is known to cause hangover and severe drunkenness and is an evil substance involved in "oxidation and glycation of the body". The "deep ocean water (reduced processed mineral concentrated solution) subjected to reduction processing with hydrogen" according to this embodiment has high acetaldehyde elimination activity, and thus is expected to suppress oxidation and glycation of the body.

[0021] As described above, by subjecting deep ocean water to hydrogen processing, it contains essential and trace minerals such as calcium, magnesium, and silicon, and can efficiently contain both or either hydrogen gas and hydrogen ions with electrons, and can be dissolved in water continuously for a long time. Regarding this "hydrogen ion with electrons", while a general hydrogen ion is "H+" lacking one electron, there exists a "negative hydrogen ion H-" with two electrons charged, and there are reports that research towards practical application is being advanced at Kyoto University and Tokyo Institute of Technology. If the reduced mineral hydrogen powder (calcined coral calcium hydrogen powder) using the "deep ocean water subjected to reduction processing with hydrogen" according to this embodiment is consumed orally or used for food, it can be expected to efficiently deliver hydrogen into the gastrointestinal tract, liver, and blood. By applying it to the skin and scalp, hydrogen can be efficiently delivered to cells directly related to beauty.

[0022] Next, silicon and its related substances will be described. Here, based on the International Atomic Weight Table (2010), the atomic weights are taken as "Si 28.0855", "H 1.00794", and "O 15.9994", and the third decimal place is rounded off. Silicon is represented by "Si" and has an atomic weight of 28.09. The amount of silicon required by the human body per day is "10 - 40 mg", and the recommended intake amount is used as the reference for silicon intake. Next, silica is also called silicon dioxide, represented by "SiO2", and its molecular weight is 60.09 (28.09 + 16.00 × 2 = 60.09). Although it is anhydrous and not water-soluble silicon, due to the pleasant sound of the word "silica", it is sometimes called "silica" as an alias for water-soluble silicon. However, water-soluble silicon (metasilicic acid, or hydrated silica / hydrated silicic acid such as orthosilicic acid) and silica (silicon dioxide) are different substances as shown in the following molecular formulas and molecular weights. Silica (silicon dioxide) hydrates and one molecule of H2O is added to form metasilicic acid, and further hydrates with one more molecule of H2O added to change into orthosilicic acid, which is more easily taken up by the living body and effectively utilized. Water-soluble silicon is hydrated silica (hydrated silicic acid), referring to substances in the form of metasilicic acid or orthosilicic acid. Insoluble silica (silicon dioxide) that makes up mountains and rocks combines with water H2O and dissolves out, changing into metasilicic acid. Further hydration proceeds (with the addition of H2O), changing into orthosilicic acid, which is more easily absorbed by the living body, reaching the ocean, being taken up by "phytoplankton diatoms", which are at the bottom of the food chain, and progressing in the utilization within the living body. Although it is repetitive, the "drinking silica (silicon) from hot springs and spring water" sold as mineral water refers to the inclusion of "water-soluble silicon" (hydrated silica / hydrated silicic acid such as metasilicic acid or orthosilicic acid), which dissolves out from rocks (silica / silicon dioxide / silicic acid / anhydrous silicic acid) and has been loved by hot spring visitors for many years as a beauty bath ingredient. By the way, "silicon / silica" = "28.09 / 60.09" = "0.47" times. Also, "silica / silicon" = "60.09 / 28.09" = "2.14" times. From these facts, silica (silicon dioxide, SiO2) = silicon (Si) × 1 / 0.47 = silicon (Si) × 2.14 (based on the conversion value used by the Japan Food Analysis Center).

[0023] In addition, as a hydrogen carrier, fine silica dioxide SiO2 has a structure in which two oxygen atoms O are bonded to silicon Si, and due to its adsorption characteristics, it can be expected to have the effect of incorporating hydrogen and extending the dissolved hydrogen time. Also, water-soluble silicon (hydrated silica or hydrated silicic acid such as metasilicic acid or orthosilicic acid) has a structure in which four hydroxyl groups OH are bonded to silicon Si in the case of orthosilicic acid Si(OH)4, and it can be expected to have a stronger effect of incorporating dissolved hydrogen.

[0024] Next, metasilicic acid is represented by "H2SiO3" and has a molecular weight of 78.1 (1×2 + 28.09 + 16.00×3 = 30.09 + 48.0 = 78.09). From this, it can be said that metasilicic acid is a substance formed by the hydration of silica (silicic acid, silicon dioxide) changing to "H2O + SiO2 = H2SiO3".

[0025] Also, the following relationships are found. "Silicon / Metasilicic acid" = "28.09 / 78.09" = "0.36" times "Metasilicic acid / Silicon" = "78.09 / 28.09" = "2.78" times "Silica / Metasilicic acid" = "60.09 / 78.09" = "0.77" times "Metasilicic acid / Silica" = "78.09 / 60.09" = "1.30" times

[0026] Next, orthosilicic acid is represented by "H4SiO4" and has a molecular weight of 78.1 (1×4 + 28.09 + 16.00×4 = 32.09 + 64.0 = 96.09). Compared with the molecular formula of the above metasilicic acid, it takes a form further hydrated with "H2O". Water-soluble silicon finally exists in the form of "orthosilicic acid (H4SiO4)", and its biogeochemical cycle is controlled by diatoms. This "orthosilicic acid (H4SiO4)" is "Si(OH)4", and with Si as the center, it has a "beautiful molecular structure in which 4 OH groups hold hands", and it is excellent in absorbability. Also, the following relationships are found. "Silicon / Orthosilicic acid" = "28.09 / 96.09" = "0.29" times "Orthosilicic acid / silicon" = "96.09 / 28.09" = "3.42" times "Silica / orthosilicic acid" = "60.09 / 96.09" = "0.63" times "Orthosilicic acid / silica" = "96.09 / 60.09" = "1.60" times

[0027] Here, the recommended daily intake will be explained. As described above, "silica / silicon" = "60.09 / 28.09" = "2.14" times, "metasilicic acid / silicon" = "78.09 / 28.09" = "2.78" times, "orthosilicic acid / silicon" = "96.09 / 28.09" = "3.42" times. Since the recommended daily intake of elemental silicon is "10 - 40 mg", the recommended daily intake when converted to silica, metasilicic acid, and orthosilicic acid is considered to be within the respective conversion value ranges from the silicon content. That is, as "silicon" constituting water-soluble silicon is "10 - 40 mg", as "silica" constituting water-soluble silicon is "21.4 - 85.6 mg (10 - 40 mg × 2.14 times)", as metasilicic acid which is water-soluble silicon is "27.8 - 111.2 mg (10 - 40 mg × 2.78 times)", and as orthosilicic acid which is water-soluble silicon is "34.2 - 136.8 mg (10 - 40 mg × 3.42 times)".

[0028] According to the literature "Biochemistry of Silicon and Related Problems (Nobel Foundation Symposia)" edited by "Gerd Bendz", it is stated that "the silicon content in the human aorta changes with age". As shown in Figure 3, for water-soluble silicon (hydrous silica and hydrous silicic acid such as metasilicic acid or orthosilicic acid), assuming the value in the body at birth is 100, it will decrease by about half by the age of 40, ignoring individual differences. Since humans cannot produce the necessary water-soluble silicon in their own bodies, it is important to actively intake water-soluble silicon to maintain beauty and health.

[0029] Water-soluble silicon (hydrated silica or hydrated silicic acid such as metasilicic acid or orthosilicic acid) is also contained in the human body and exists in hair, nails, blood vessels, bones, teeth, joints, cell walls, etc. Water-soluble silicon in the living body has the effect of binding collagen and is useful for the regeneration, reinforcement, and maintenance of bones, teeth, hair, nails, and collagen. It also affects skin moisturization. In addition, water-soluble silicon is contained in the skin (dermis layer), hair, nails, etc., binds collagen, ceramide, elastin, hyaluronic acid, chondroitin, etc., has the function of maintaining skin firmness and elasticity, and binding tissues to make them strong. Furthermore, it is known that excellent beauty and health effects can be obtained by combining ceramide or hyaluronic acid, lactic acid bacteria, and water-soluble silicon. That is, ceramide has the function of enhancing the skin's barrier function (especially the moisturizing effect) and suppressing the evaporation of epidermal moisture. Hyaluronic acid enhances the skin's water retention function to prevent dryness. Lactic acid bacteria have the function of increasing immunity and anti-allergic function along with the intestinal regulation function. Furthermore, water-soluble silicon promotes the synthesis of collagen in the skin (cutaneous) and has the function of being responsible for the adhesion and keratinization between collagen layers. Therefore, it is expected that the combination of these will exert beauty and health effects. Additionally, water-soluble silicon is absorbed from the intestinal wall and has the effect of solubilizing the deposits inside the blood vessels when passing through the blood vessels, and is also effective in preventing arteriosclerosis. Moreover, it has the function of promoting plant growth or strengthening the stems.

[0030] In the Framingham Offspring Study in the United States, it was found that there is a close relationship between the intake of silicon (contained in water-soluble silicon) and bone mineral density (BMD). In this study, 2,846 men and women aged from their 30s to 80s were divided into four groups according to the measurement results of "silicon intake" and compared in their diets. As a result, it was found that in men and pre-menopausal women, the higher the silicon intake, the higher the bone density of the femoral neck. Therefore, the effect of silicon in preventing osteoporosis is expected. Thus, since the importance of silicon has become clear, in Europe and the United States, health supplements and foods containing water-soluble silicon (hydrated silica or hydrated silicic acid such as metasilicic acid or orthosilicic acid), which is easily absorbed by the body, have been attracting attention for quite some time, and the market for silicon products in Europe and the United States has already reached an extremely large scale. Human bone is composed of about 70% hydroxyapatite and about 30% collagen, and water-soluble silicon runs through them to make the tissue strong. Therefore, by containing water-soluble silicon, hydroxyapatite, and collagen, a great synergistic effect due to the collaboration of these three components is expected.

[0031] Both plant-derived silicic acid and mineral-derived silicic acid can be processed using deep ocean water under the same conditions of temperature and pressure to obtain water-soluble silicon (hydrated silica or hydrated silicic acid such as metasilicic acid or orthosilicic acid), but the mineral balance contained in each other than silicon Since the sources are different, if one wishes to fully enjoy the bounty of the earth and plants, a synergistic effect can be expected by mixing concentrated solutions of plant-derived water-soluble silicon and mineral-derived water-soluble silicon. In addition to bamboo, it is also possible to use plants of the grass family such as rice (rice straw, rice husks), sasaya, foxtail millet, pampas grass, sugarcane, wheat, etc., as well as silicon-rich plants such as sawtooth oak and knotweed. Mineral-derived silicic acid such as quartz crystal can also be used. Silicic acid derived from natural water or hot spring water in Kirishima (Kirishima mountain range) or Hakone can also be blended. Additionally, by utilizing silicic acid eluted from Fuji lava marimo or powder, or combining it with the silicic acid abundantly contained in the spring water or hot spring water of Mount Fuji, a further synergistic effect of minerals other than silicic acid can be expected. It can be said that "the bounty of minerals in Mount Fuji" and "the bounty of minerals in deep ocean water" are precisely the bounty of high and low minerals, and the bounty of the balance of yin and yang minerals. Incidentally, "vanadium" is contained in the spring water, hot spring water, lava, etc. of Mount Fuji, and it is known that "vanadium" can be expected to have an effect on diabetes. Also in this embodiment, by containing "vanadium", an effect on diabetes can be expected.

[0032] Moreover, the production areas of mineral water rich in water-soluble silicon (such as metasilicic acid or hydrous silica / hydrous silicic acid like orthosilicic acid) are mainly distributed in the Fuji-Hakone region and the Kyushu region. The Kyushu region has world-renowned volcanoes and hot spring groups such as Aso, Unzen, Kirishima, Kusatsu, Sakurajima, and Beppu. The strata in this area contain a large amount of silicic acid, which is known to have changed into water-soluble silicon (such as metasilicic acid or hydrous silica / hydrous silicic acid like orthosilicic acid) over a long period of time and dissolved into the water. Regarding the hot spring water in Kirishima rich in water-soluble silicon, there is a myth that "a long time ago, Izanagi no Mikoto and Izanami no Mikoto put the weak-kneed Hiruko no Mikoto on a boat and had him undergo hot spring treatment at the 'Valley of Sorrow' where they arrived." Also in this embodiment, it is possible to utilize silicic acid derived from spring water or natural water in Kirishima or Sakurajima.

[0033] [First Embodiment] Next, a method for manufacturing the super lens activated carbon according to this embodiment will be described. FIG. 1 is a flowchart showing the manufacturing process of the super lens activated carbon according to this embodiment. First, plants including Japanese red pine, bamboo, ume fruits, or coconut shells and oak leaves are harvested (step S1), and the harvested plants are heat-treated in a charcoal kiln (step S2). This heat treatment is "carbonization", and the treatment conditions are, for example, the atmospheric pressure in the furnace is 1 to 3 atmospheres and the temperature is 500°C to 1500°C. Next, an activation reaction is caused using "deep ocean water or water containing water-soluble silicon" that has been reductively processed with hydrogen (step S3). In this way, when the carbonized raw material (charcoal of plants including Japanese red pine, bamboo, ume fruits, or coconut shells and oak leaves) and the mineral-containing water ("deep ocean water or water containing water-soluble silicon" that has been reductively processed with hydrogen) are reacted at a temperature of 500°C to 1500°C, micropores (diameter 5 to 200 angstroms) are generated by the partial reaction of carbon and minerals, and activated carbon is manufactured. Thereby, the adsorption characteristics of the super lens activated carbon are improved. The atmospheric pressure and temperature conditions are not uniform, and since the sizes of the conduits vary depending on each plant, it is necessary to find the optimal conditions for each plant and carbonize them.

[0034] [Verification Example 1] Here, since the inventors of the present invention have found that the super lens activated carbon is characterized in that in addition to temperature and pressure, it is carbonized "soft and fluffy" using reduced water, a test was conducted to prove that the polishing action that damages teeth is low. Since the glass surface is softer than the enamel of teeth, a polishing action test using an electric hub brush was conducted on the glass surface using "Ina Japanese red pine wonderful charcoal·coconut shell activated carbon granules (dispersion processing)". As a result, it was found that the glass surface was not damaged at all even after being polished with an electric hub brush with charcoal for 1 hour. Thereby, it was found that there is no problem with the polishing action on teeth by the super lens activated carbon.

[0035] Also, in this embodiment, not only deep ocean water but also "water obtained by concentrating minerals by passing spring water and hot spring water such as Fuji, Southern Alps, Central Alps, and Kirishima natural water through an activated carbon filter" that has been hydrogenated with reduced water may be used to cause an activation reaction.

[0036] [Verification Example 2] In addition, the present inventors conducted a "Red No. 2 adsorption test" using functional coconut shell activated carbon, Ina red pine charcoal, and Kamakura siliceous bamboo charcoal as the super lens activated carbon according to this embodiment through a third-party research institution. The test specimens were super lens activated carbon (functional coconut shell activated carbon powder, Kamakura siliceous bamboo charcoal powder, Ina red pine charcoal powder), activated carbon powder of another company with medical achievements, and bamboo charcoal powder (domestic). The test method was to add the sample to water colored with Red No. 2 (amaranth), stir it, and measure the absorbance of the filtered solution. The results are as shown in the following table and Figure 8.

Table 2

[0037] [Verification Example 3] In addition, the inventors of the present invention conducted an "odor adsorption test" using functional coconut shell activated carbon as the super lens activated carbon according to this embodiment through a public third-party institution. The test sample was super lens activated carbon (functional coconut shell activated carbon powder). The test method was as follows: (1) A sample with the test sample placed in a Tedlar bag (odor bag: 3L) was defined as "sample measurement", and a sample without the test sample was defined as "blank test". (2) Ten types of odor components adjusted for both were added, and the odor after standing for 30 minutes was measured. Each sample was measured three times, and the average value was used as the result. Here, the adsorption rate (%) is synonymous with the reduction rate (%), and is obtained by dividing (concentration of blank test) - (concentration of sample measurement) by (concentration of blank test) and multiplying by 100. The results are as shown in the following table and Figure 9. In the following table, "ammonia" has a characteristic strong pungent odor, "acetic acid" has a strong sour taste and pungent odor. "Methyl mercaptan" is a typical halitosis substance produced by the periodontal pathogen Porphyromonas gingivalis, and "hydrogen sulfide" has a rotten egg odor. "Acetaldehyde" has a unique odor and irritation, and is also an air pollutant derived from automobile exhaust, tobacco smoke, etc. "Pyridine" has an odor like rotten fish, and "trimethylamine" is a substance that causes the fishy smell. "Nonenal" has an oily and fishy smell, and its relationship with body odor has been studied. "Indole" has a fecal odor, and "isovaleric acid" has a pungent odor accompanied by discomfort such as the smell of cheese, sweat, feet, and halitosis due to aging. [Table 3] Thus, since the "super lens activated carbon (functional coconut shell activated carbon)" has been subjected to unique processing using minerals under high temperature and high pressure, fine pores are formed deep inside, and an extremely high adsorption rate has been confirmed for various types of odors.

[0038] [Verification Example 4] In addition, the inventors of the present invention conducted a "food oil adsorption test" using functional coconut shell activated carbon as the super-cleaning activated carbon according to this embodiment through a third-party research institution. The test specimens were super-cleaning activated carbon (functional coconut shell activated carbon powder), coconut shell activated carbon powder (produced in China), and commercially available bamboo charcoal powder (produced in the country). The test method was as follows: (1) Add food oil to hot water and stir until evenly mixed. (2) Add the sample and stir for 10 minutes. (3) Measure the filtered product. (4) Add the same amount of food oil as in (1) to hot water, filter after stirring, and use the filtered product as the stock solution for comparison. The results are as shown in the following table and Figure 10.

Table 4

[0039] [Verification Example 5] In addition, the inventors of the present invention conducted a "heavy metal adsorption test" using functional coconut shell activated carbon, Ina red pine charcoal, and Kamakura silica bamboo charcoal as the super-cleaning activated carbon according to this embodiment through a third-party research institution. The test specimens were super-cleaning activated carbon (functional coconut shell activated carbon powder, Ina red pine charcoal powder, Kamakura silica bamboo charcoal powder). The test method was as follows: (1) Dilute cadmium standard solution, lead standard solution, and mercury standard solution. (2) Add the test specimens to these diluted solutions, stir, and then filter the product, which was analyzed using an ICP (inductively coupled plasma) optical emission spectrometer. The adsorption rates are as shown in the following table.

Table 5

[0040] [Verification Example 6] Furthermore, the inventors conducted a "Nicotine Adsorption Test" using Functional Coconut Shell Activated Carbon, Ina Red Pine Wonderful Carbon, and Kamakura Silica Bamboo Carbon as the Super Cleanse Activated Carbon according to this embodiment through a third-party research institution. The test specimens were Super Cleanse Activated Carbon (Functional Coconut Shell Activated Carbon powder, Ina Red Pine Wonderful Carbon powder, Kamakura Silica Bamboo Carbon powder). The test method was as follows: (1) Dilute the nicotine standard solution, (2) Add the test specimens to these solutions, stir, and then filter the resulting solution, which was analyzed using GC-MS (Gas Chromatograph Mass Spectrometer). The adsorption rates are as shown in the following table.

Table 6

[0041] [Verification Example 7] Furthermore, the inventors conducted an "Indole and Skatole Adsorption Test" using Functional Coconut Shell Activated Carbon, Ina Red Pine Wonderful Carbon, and Kamakura Silica Bamboo Carbon as the Super Cleanse Activated Carbon according to this embodiment through a third-party research institution. The test specimens were Super Cleanse Activated Carbon (Functional Coconut Shell Activated Carbon powder, Ina Red Pine Wonderful Carbon powder, Kamakura Silica Bamboo Carbon powder). The test method was as follows: (1) Dissolve indole and skatole that emit fecal odor, (2) Add the test specimens to these solutions, stir for 10 minutes, and then filter the resulting solution, which was analyzed using GC-MS (Gas Chromatograph Mass Spectrometer). The adsorption rates are as shown in the following table.

Table 7

[0042] [Verification Example 8] In addition, the inventors conducted a "Tobacco Tar Dye Adsorption Test" using functional coconut shell activated carbon, Ina red pine wonderful carbon, and Kamakura silica bamboo carbon as the super cleanse activated carbon according to this embodiment through a third-party research institution. The test specimens were super cleanse activated carbon (functional coconut shell activated carbon powder, Ina red pine wonderful carbon powder, Kamakura silica bamboo carbon powder). The test method was as follows: (1) Take the leaves of commercially available tobacco in a beaker, and use the one boiled with hot water as the stock solution. (2) Add the test specimen to the stock solution, measure the absorbance after stirring and filtering. The adsorption rates are as shown in the following table.

Table 8

[0043] [Verification Example 9] In addition, the inventors conducted an "Edible Dye Adsorption Test" using functional coconut shell activated carbon, Ina red pine wonderful carbon, and Kamakura silica bamboo carbon as the super cleanse activated carbon according to this embodiment through a third-party research institution. The test specimens were super cleanse activated carbon (functional coconut shell activated carbon powder, Ina red pine wonderful carbon powder, Kamakura silica bamboo carbon powder). The test method was to add the test specimen to water colored with edible dye, measure the absorbance after stirring and filtering. The adsorption rates are as shown in the following table.

Table 9

[0044] [Verification Example 10] In addition, the inventors conducted a "Trihalomethane (Chloroform) Adsorption Test" using functional coconut shell activated carbon, Ina red pine wonderful carbon, and Kamakura silica bamboo carbon as the super cleanse activated carbon according to this embodiment through a third-party research institution. The test specimens were super cleanse activated carbon (functional coconut shell activated carbon powder, Ina red pine wonderful carbon powder, Kamakura silica bamboo carbon powder). The test method was as follows: (1) Prepare a chloroform solution, (2) Place the sample in a chromatographic column in layers, and gently pour the solution from (1) on top, and (3) Analyze the permeated liquid using GC-MS (Gas Chromatograph Mass Spectrometer). The adsorption rates are as shown in the following table.

Table 10

[0045] [Verification Example 11] In addition, the present inventors conducted a "residual chlorine adsorption test" using functional coconut shell activated carbon, Ina red pine charcoal, and Kamakura siliceous bamboo charcoal as the super lens activated carbon according to this embodiment through a third-party research institution. The test specimens were super lens activated carbon (functional coconut shell activated carbon powder, Ina red pine charcoal powder, Kamakura siliceous bamboo charcoal powder). The test method was as follows: (1) Dilute sodium hypochlorite. (2) Place filter paper on a funnel, put the test specimen in it, and pour 100 ml of the diluted solution prepared in (1) from above. (3) Measure the permeated liquid by a back test. The diluted solution in (1) was used as a filter paper blank and measured after passing through the filter paper. The adsorption rates are as shown in the following table.

Table 11

[0046] [Verification Example 12] In addition, the present inventors conducted an "arsenic adsorption test" using functional coconut shell activated carbon, Ina red pine charcoal, and Kamakura siliceous bamboo charcoal as the super lens activated carbon according to this embodiment through a third-party research institution. The test specimens were super lens activated carbon (functional coconut shell activated carbon powder, Ina red pine charcoal powder, Kamakura siliceous bamboo charcoal powder). The test method was as follows: (1) Dilute the arsenic standard solution. (2) Add the test specimen to the diluted solution prepared in (1) and stir with a magnetic stirrer. (3) Filter with Advantec 2B filter paper. (4) Measure the arsenic concentration. The adsorption rates are as shown in the following table.

Table 12

[0047] [Verification Example 13] In addition, the inventors of the present invention conducted an "aluminum adsorption test" using functional coconut shell activated carbon, Ina red pine charcoal, and Kamakura siliceous bamboo charcoal as the super lens activated carbon according to this embodiment through a third-party research institution. The test specimens were super lens activated carbon (functional coconut shell activated carbon powder, Ina red pine charcoal powder, Kamakura siliceous bamboo charcoal powder). The test method was as follows: (1) Dilute the aluminum standard solution, and (2) Add the test specimen to the diluted solution prepared in (1), stir, filter, and analyze the filtered solution using an ICP (inductively coupled plasma) optical emission spectrometer. The adsorption rates are as shown in the following table. [Table 13] Thus, since the "super lens activated carbon (functional coconut shell activated carbon, Ina red pine charcoal, Kamakura siliceous bamboo charcoal)" has been subjected to unique processing utilizing minerals under high temperature and high pressure, fine pores are generated deep inside, and a high adsorption rate for aluminum, particularly for Ina red pine charcoal, was confirmed.

[0048] [Verification Example 14] In addition, the inventors of the present invention conducted a "bacterial adsorption test" using functional coconut shell activated carbon, Ina red pine charcoal, and Kamakura siliceous bamboo charcoal as the super lens activated carbon according to this embodiment through a third-party research institution. The test specimens were super lens activated carbon (functional coconut shell activated carbon powder, Ina red pine charcoal powder, Kamakura siliceous bamboo charcoal powder). The test method was as follows: Using oral bacteria from a male suspected of having periodontal disease, (1) Dilute the saliva, which is the bacterial solution used, 10-fold with physiological saline, then filter using filter paper (Advantec filter paper No. 2), (2) Add 1 g of the specimen to 10 ml and mix for 3 minutes. (3) Wait for the charcoal to precipitate, collect 1 ml of the supernatant, dilute it, and inoculate it into the medium. The results are as follows. [Table 14] Thus, since the "super lens activated carbon (functional coconut shell activated carbon, Ina red pine charcoal, Kamakura siliceous bamboo charcoal)" has been subjected to unique processing utilizing minerals under high temperature and high pressure, fine pores are generated deep inside, and it has been clarified that it can adsorb oral bacteria with an adsorption rate close to 100%.

[0049] [Verification Example 15] In addition, the inventors conducted an "AGEs adsorption test" using functional coconut shell activated carbon, Ina red pine charcoal, and Kamakura siliceous bamboo charcoal as the super clean activated carbon according to this embodiment through a third-party research institution. The test specimens were super clean activated carbon (functional coconut shell activated carbon powder, Ina red pine charcoal powder, Kamakura siliceous bamboo charcoal powder). The test method was as follows: (1) Alanine and glucose were dissolved in water and heated, and after natural cooling, a diluted AGEs solution was prepared. (2) Each test specimen was added to the AGEs solution, stirred, filtered, and the absorbance was measured. The results are as follows. [Table 15]

[0050] Thus, since the "super clean activated carbon (functional coconut shell activated carbon, Ina red pine charcoal, Kamakura siliceous bamboo charcoal)" has been subjected to unique processing utilizing minerals under high temperature and high pressure, fine pores are generated deep inside, and it has been revealed that in particular, the functional coconut shell activated carbon can adsorb AGEs with an adsorption rate close to 100%. Also, although the commercially available charcoal products (1) and (2) are edible charcoal raw materials that claim high prices and high functionality, the superiority of the "super clean activated carbon (functional coconut shell activated carbon, Ina red pine charcoal, Kamakura siliceous bamboo charcoal)" has become apparent even in comparison with these. Furthermore, as described above, the AGEs adsorption test results show that the adsorption rate of the functional coconut shell activated carbon is 100%, and even considering the error, it is close to 100%, the Ina red pine charcoal is 56%, and the Kamakura siliceous bamboo charcoal is 51%, while the spherical activated carbon prescription drug (fine granule sub-packaging) is 17%. Therefore, the functional coconut shell activated carbon shows an adsorption rate 5.9 times that of this prescription drug, the Ina red pine charcoal shows an adsorption rate 3.3 times that of this prescription drug, and the Kamakura siliceous bamboo charcoal shows an adsorption rate 3.0 times that of this prescription drug. As a result, the superiority of the "super clean activated carbon (functional coconut shell activated carbon, Ina red pine charcoal, Kamakura siliceous bamboo charcoal)" over this prescription drug has become apparent.

[0051] [Verification Example 16] In addition, the inventors of the present invention conducted a "purine adsorption test" using functional coconut shell activated carbon, Ina red pine charcoal, and Kamakura silica bamboo charcoal as the super lens activated carbon according to this embodiment through a third-party research institution. The test specimens were super lens activated carbon (functional coconut shell activated carbon powder, Ina red pine charcoal powder, Kamakura silica bamboo charcoal powder). The test method was to use "adenine" as the purine substance, add 1 g of the carbon sample to a 50 ppm solution of the purine substance concentration in ordinary beer, stir, filter using filter paper, and measure the concentration with a liquid chromatograph. The measurement results are as follows. The measurement results are as follows.

Table 16

[0052] Thus, since the "super lens activated carbon (functional coconut shell activated carbon powder, Ina red pine charcoal powder, Kamakura silica bamboo charcoal powder)" has been subjected to unique processing using minerals under high temperature and high pressure, it has been revealed that fine pores are formed deep inside and it can adsorb purine substances with a high adsorption rate.

[0053] [Verification Example 17] Using the super lens activated carbon (functional coconut shell activated carbon powder, Ina red pine charcoal powder) according to this embodiment, an "acrylamide adsorption test" was conducted. The test specimens were super lens activated carbon (functional coconut shell activated carbon powder, Ina red pine charcoal powder). The test method was to add the specimens to an acrylamide aqueous solution respectively, stir and then centrifuge, and filter the supernatant with a filter. The results of measuring the concentration of this filtrate using a "TOC-V CSN (total organic carbon meter)" are as follows.

[0054]

Table 17

[0055] The super lens activated carbon (functional coconut shell activated carbon powder, Ina red pine excellent carbon powder) according to this embodiment has been found to be able to adsorb acrylamide with a high adsorption rate. In particular, the functional coconut shell activated carbon powder showed an adsorption rate exceeding 90%. Acrylamide is contained in instant coffee and potato chips and is known as a carcinogenic harmful substance. By using the super lens activated carbon according to this embodiment, acrylamide can be removed at a high rate.

[0056] [Verification Example 18] Next, a caffeine adsorption test was conducted on the super lens activated carbon (functional coconut shell activated carbon powder, Kishu Binchotan activated carbon powder) according to this embodiment. The test specimens were the super lens activated carbon (functional coconut shell activated carbon powder, Kishu Binchotan activated carbon powder). The test method was to add each specimen to an aqueous caffeine solution, stir, filter with filter paper, and measure the concentration with a liquid chromatograph. The results are as shown in the following table.

[0057]

Table 18

[0058] [Second Embodiment] Next, a method for manufacturing the reduced mineral hydrogen powder according to the present embodiment will be described. FIG. 2 is a flowchart showing the manufacturing process of the reduced mineral hydrogen powder according to the present embodiment. This reduced mineral hydrogen powder can generate hydrogen at a high concentration for a long time. First, coral powder is supplied into a furnace (step T1), and the coral powder is heat-treated in a kiln (step T2). These are the firing processes of coral, and the processing conditions are that the atmospheric pressure in the furnace is 1 to 6 atmospheres and the temperature is 50°C to 200°C. Next, hydrogen loading is caused using "deep ocean water or water-soluble silicon-containing water" that has been reduced by hydrogen (step T3). In this way, when the fired coral powder and the mineral-containing water ("deep ocean water or water-soluble silicon-containing water" that has been reduced by hydrogen) are reacted at a pressure of 1 to 6 atmospheres and a temperature of 50°C to 200°C, micropores (diameter 10 to 200 Å) are generated by the partial reaction between the coral powder and the mineral. As a result, a large amount of hydrogen can be carried (adsorbed) by the mineral in the micropores.

[0059] [Verification Example 19] The inventors commissioned a third-party organization (Japan Hydrogen Water Promotion Association) to measure the amount of dissolved hydrogen in the reduced mineral hydrogen powder (fired coral calcium hydrogen powder) according to the present embodiment. As a result, in terms of the amount of dissolved hydrogen (redox method), 840 ppb was measured after 10 minutes, 1,096 ppb after 2 hours, 1,085 ppb after 6 hours, and 1,045 ppb after 24 hours. Also, at the "Northeastern Shiga Industrial Technology Center", an ultraviolet-visible near-infrared spectroscopic altimeter was used to conduct an investigation of the amount of hydrogen ion generation (conducted by a third-party research institution). The measurement principle is to measure NADH generated by the reaction with NAD reagent due to the presence of hydrogen and calculate the amount of hydrogen. 10 ml of distilled water was added to 1 g of the sample, stirred, left standing for 1 hour, and then the supernatant was analyzed. As a result, the amount of hydrogen ions generated from 1 g of the powder was 3.55×10^20 (3.55 trillion), and it was found that it can supply 5.7 million hydrogen ions per cell for 60 trillion human cells.

[0060] Thus, in addition to the confirmation that hydrogen was dissolved for a long time, the abundant generation of hydrogen ions was also confirmed. Therefore, it can be expected that the oral composition (fired coral calcium hydrogen powder) according to this embodiment can approach the intestine and liver. The intestine is said to generate about 90% of the active oxygen in the body, and the liver is the largest detoxifying organ in the body and is constantly exposed to active oxygen. The fact that the possibility of approaching both organs has been found indicates the potential of hydrogen power.

[0061] Furthermore, the aldehyde elimination ability using an ultraviolet-visible near-infrared spectrometer at the "Northeastern Shiga Industrial Technology Center" was also investigated (conducted by a third-party research institution). The test was carried out by adding 0.2 g of the sample (fired coral calcium hydrogen powder) to 200 ml of shochu and stirring for 15 minutes. After standing, the supernatant was analyzed. As a result, the aldehyde concentration decreased from 10 mg / l to 1.9 mg / l, and an elimination rate of 81% was confirmed. The fact that acetaldehyde, which is also said to be the cause of hangover, is eliminated suggests the effectiveness of hangover countermeasures and liver health improvement.

[0062] [Verification Example 20] The inventors commissioned a third-party research institution to verify the hydroxyl radical elimination function of the reduced mineral hydrogen powder (fired coral calcium hydrogen powder) according to this embodiment. The verification method is as follows. Usually, it is drunk at 420 mg - 820 mg / 100 ml. Therefore, the fired coral calcium hydrogen powder was suspended in distilled water (32.8 mg / ml) and allowed to stand for about 1 hour to obtain a stock solution. In the measurement, (1) a 10-fold diluted solution of the stock solution and (2) the stock solution were prepared and finally added to the active oxygen generation system, resulting in dilutions of 40-fold and 4-fold (drinking concentration), respectively. The "hydroxyl radical generation method" was carried out by irradiating hydrogen peroxide with ultraviolet light.

[0063] Next, the adjusted samples were collected in an ESR flat cell, and ESR measurement was performed under the following measurement conditions. Center Field: 335mT Modulation Width : 100μT Sweep Width:± 5.0mT Time Constant : 0.1sec Sweep Time : 1min Gain : 50

[0064] Next, using DMPO as a hydroxyl radical scavenger, the hydroxyl radical scavenging activity of the sample was measured using the following protocol. Distilled water (control), solution (1) or (2): 50 μL 5.7M DMPO: 20 μL 2.5 mM H2O2: 130 μL After irradiating with ultraviolet light for 30 seconds, measurement was performed by ESR.

[0065] In Fig. 4, from the signal intensity enclosed by the square of the obtained ESR spin adduct, with the control taken as 100%, the values obtained with each sample addition were evaluated as "% of control". The signal intensity of the spin adduct was analyzed from the ratio to the ESR signal of the external standard sample Mn2+ (left end in Fig. 4). And statistical processing was carried out using individual data. The number of data for each condition was 2 and 3, and for the statistical processing, Tukey's analysis of variance was used, with a significance level of 5% or less.

[0066] The results showing the hydroxyl radical scavenging activity are as shown in Figs. 4 to 6. That is, compared with the control (a in Fig. 4), significant hydroxyl radical scavenging was observed for both sample (1) 0.82 mg / mL (b in Fig. 4) and sample (2) 8.2 mg / mL (c in Fig. 4) (p < 0.05, Tukey multiple test).

[0067] Also, in this embodiment, instead of coral powder, powders impregnated with deep sea water, hydroxyapatite derived from natural organisms or minerals, deep sea water powder, seaweed powder, weathered shell calcium powder, oyster shell powder, scallop shell powder, pearl oyster shell powder, fine particles It is also possible to use a powder containing an essential and trace mineral containing at least one of silicon dioxide (silica) and water-soluble silicon (hydrous silica such as metasilicic acid or orthosilicic acid). This makes it possible to produce a reduced mineral hydrogen powder rich in minerals. By impregnating deep ocean water, it becomes possible to carry (adsorb) hydrogen by low-temperature and high-pressure processing on various powder raw materials such as collagen and lactic acid bacteria raw materials.

[0068] [Verification Example 21] As described above, instead of coral powder, it is possible to produce "a powder impregnated with deep ocean water and a reduced mineral hydrogen powder containing hydroxyapatite and fine silicon dioxide (silica)". The dissolved hydrogen amount and oxidation-reduction potential of this "silk hydrogen pearl powder (trademark registration application filed) containing silk powder impregnated with deep ocean water, hydroxyapatite derived from pearl oyster, and fine silicon dioxide" were measured. The test method was to use "ENH-2000 manufactured by Trustlex Co., Ltd." as the dissolved hydrogen meter and "YK-23RP-ADV manufactured by Sato Shoji Co., Ltd." as the oxidation-reduction potential meter, and 1 g of "silk hydrogen pearl powder" was added to 100 mL of tap water in Yokohama City and stirred for measurement. The results are as follows. In the following description, for convenience, a "▲" will be attached to negative numerical values. (Initial value) Dissolved hydrogen amount... 0 ppb Oxidation-reduction potential... +600 mV pH 7 (After 10 minutes) Dissolved hydrogen amount... 1312 ppb Oxidation-reduction potential... ▲725 mV pH 10.81 (After 1 hour) Dissolved hydrogen amount... 1827 ppb Oxidation-reduction potential... ▲906 mV pH 10.83 (After 12 hours) Dissolved hydrogen amount... 1847 ppb Oxidation-reduction potential... ▲920 mV pH 10.66 (After 20 hours) Dissolved hydrogen content…1730 ppb Redox potential… - 888 mV pH 10.12 (After 32 hours) Dissolved hydrogen content…908 ppb Redox potential… - 357 mV pH 8.51 (After 45 hours) Dissolved hydrogen content…552 ppb Redox potential… - 182 mV pH 8.30 (After 60 hours) Dissolved hydrogen content…336 ppb Redox potential… - 46 mV pH 8.36 (After 66 hours) Dissolved hydrogen content…220 ppb Redox potential… - 14 mV pH 8.16

[0069] As described above, the dissolved hydrogen content after 12 hours was 1847 ppb. This means that even after 12 hours, the hydrogen content is 2.3 to 4.6 times that of commercially available hydrogen water at the time of shipment. Also, the redox potential after 12 hours was - 920 mV. From this, it was found that "Silk Hydrogen Pearl Powder" effectively removes active oxygen and has a high antioxidant function.

[0070] [Verification Example 22] The quantification of hydrogen generated from the "Silk Hydrogen Pearl Powder" according to this embodiment was performed. The test method was to measure the amount of hydrogen generated from the "Silk Hydrogen Pearl Powder" according to this embodiment by gas chromatography. Specifically, the "First Silk Hydrogen Pearl Powder" and the "Second Silk Hydrogen Pearl Powder" according to this embodiment were pulverized in a mortar, and then 5 mg and 2 mg were collected, added to a 125 mL vial, 25 mL of purified water was added thereto, the lid was quickly closed, and ultrasonic extraction was performed for 30 minutes. After standing at room temperature for 48 hours or more, 0.5 mL of the headspace gas in the vial was injected into a gas chromatograph to measure hydrogen. The results are as follows.

[0071]

Table 19

[0072] It is said that hydrogen water filled in commercially available aluminum cans contains 0.16 mg to 0.32 mg (0.4 ppm to 0.8 ppm) of hydrogen per 410 ml at the time of shipment. Due to recent technological advancements, this amount of hydrogen is considered to be quite large. In contrast, 140 (mL / g) of hydrogen was detected from the first silk hydrogen pearl powder. Since this corresponds to 12.5 mg, it means that the first silk hydrogen pearl powder contains 40 to 78 times more hydrogen than commercially available hydrogen water. Also, 3.5 (mL / g) of hydrogen was detected from the second silk hydrogen pearl powder. Since this corresponds to 0.3 mg, it means that it contains almost the same amount of hydrogen as commercially available hydrogen water. From this, it can be seen that the first silk hydrogen pearl powder according to this embodiment carries an amount of hydrogen that has not been seen conventionally.

[0073] Thus, since "Silk Hydrogen Pearl Powder" has a high hydrogen content, it is expected to have antioxidant, anti-inflammatory, anti-allergic, anti-cancer effects, promote energy production in mitochondria, improve lipid metabolism, improve glucose tolerance, inhibit the onset of arteriosclerosis, and improve symptoms of Parkinson's disease. Furthermore, by mixing it with hydroxyapatite or deep sea water, it is possible to enjoy these benefits.

[0074] [Verification example 22] The inventors also conducted a "human clinical trial" together with the Japanese Society of Oxidative Therapy Medicine. A human clinical trial was conducted using a hybrid hydrogen supplement filled with a mixture of "marine mineral hydrogen powder" as a hydrogen generating raw material. This "marine mineral hydrogen powder" is a "composite mineral-containing powder" that generates hydrogen gas and hydrogen ions by subjecting deep sea water powder and fine silicon dioxide to hydrogen-carrying processing according to the present embodiment. In this test, as shown in Figure 7, a statistically significant decrease was observed in the "average values before and five days after ingestion" of the "8-OHdG creatinine ratio," a marker that indicates genetic damage in urine (oxidative stress in the body), over a period of five days after ingestion began. It was found that this is a raw material that fully exerts the penetrating power of hydrogen in a short period of time.

[0075] As described above, according to the present invention, it is possible to provide a method for producing Super Cleanse activated carbon that improves the adsorption properties of carbon and activated carbon, and a method for producing reduced mineral hydrogen powder that can support (adsorb) a large amount of hydrogen. The present invention can be used not only for food applications, but also for cosmetics and miscellaneous goods.

Claims

1. A method for producing hydrogen powder that supplements essential and trace minerals, comprising: a step of setting the atmospheric pressure in a furnace to 1 to 6 atmospheres and firing coral powder at 50°C to 200°C; a step of generating hydrogen loading using "deep ocean water or water containing water-soluble silicon" that has been reductively processed with hydrogen. A method for producing hydrogen powder, characterized by including at least these steps.

2. The method for producing hydrogen powder according to claim 1, characterized in that instead of the coral powder, silk powder impregnated with deep ocean water, hydroxyapatite derived from pearl oyster, and silk hydrogen pearl powder containing fine silicon dioxide are used.

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