Electrically peelable adhesive sheet and bonded body

Abstract

The present invention relates to an electrically peelable adhesive sheet which is sequentially provided, in the following order, with: a conductive base material that comprises a supporting base material and a conductive layer; a coating layer; and an electrically peelable adhesive layer, the adhesion of which is decreased by the application of a voltage. With respect to this electrically peelable adhesive sheet, the coating layer is formed on a surface of the conductive layer, said surface being on the reverse side from the supporting base material, and the electrically peelable adhesive layer and the coating layer are in contact with each other.

Description

[Technical Field]

[0001] The present invention relates to an electrically releasable pressure-sensitive adhesive sheet and a bonded body. [Background technology]

[0002] In electronic component manufacturing processes, etc., there is an increasing demand for rework to improve yields and recycling by disassembling and recovering components after use. To meet these demands, double-sided electrically peelable pressure-sensitive adhesive sheets that have a certain level of adhesive strength and releasability are sometimes used to join components in electronic component manufacturing processes, etc.

[0003] Known double-sided electrically peelable adhesive sheets that achieve the above-mentioned adhesive strength and releasability include electrically peelable adhesive sheets (electrically peelable adhesive sheets) that use an ionic liquid consisting of cations and anions as a component that forms the adhesive composition, and that peel off by applying a voltage to the adhesive layer (Patent Documents 1 to 3). [Prior art documents] [Patent documents]

[0004] [Patent Document 1] Japanese Patent Application Publication No. 2010-037354 [Patent Document 2] Japanese Patent No. 6097112 [Patent Document 3] Japanese Patent No. 4139851 Summary of the Invention [Problem to be solved by the invention]

[0005] It is preferable that the electrically peelable pressure-sensitive adhesive sheet firmly bonds members when no voltage is applied, and can be peeled off with little force when a voltage is applied.

[0006] However, in conventional technology, when an electrically peelable pressure-sensitive adhesive sheet is attached to a conductive adherend, the conductive layer peels off from the supporting substrate when electrically peeling is attempted in a high-temperature, high-humidity environment, which can cause the electrically peelable pressure-sensitive adhesive sheet to fail to function or can lead to contamination of the adherend. The present invention has been completed in view of the above, and its first object is to provide an electrically peelable pressure-sensitive adhesive sheet and an assembly that suppress peeling of the conductive layer from the supporting substrate in a high-temperature, high-humidity environment.

[0007] Furthermore, in conventional technology, in a bonded structure in which an electrically peelable pressure-sensitive adhesive sheet is attached to a conductive substrate, the adhesive strength between the electrically peelable pressure-sensitive adhesive layer constituting the electrically peelable pressure-sensitive adhesive sheet and the conductive substrate decreases in a high-temperature environment, causing peeling, and the structure may not be reliable as a component. The present invention was completed in view of the above, and a second object of the present invention is to provide an electrically peelable adhesive sheet and an assembly that can prevent a decrease in the adhesive strength between the electrically peelable adhesive layer that constitutes the electrically peelable adhesive sheet and the conductive substrate in a high-temperature environment, and as a result, can suppress a decrease in the adhesive strength of the electrically peelable adhesive sheet.

[0008] Furthermore, the situations in which electrically peelable pressure-sensitive adhesive sheets are used are becoming more diverse. When used in electronic devices, etc., there are cases where electrical peeling is not desired within the voltage range that flows through the electronic device itself. Also, when used in processes, etc., there is a step in which a voltage is applied after the electrically peelable pressure-sensitive adhesive sheet is applied, and there are cases where electrical peeling is desired by applying a higher voltage, so the applied voltage and application time required for electrical peeling vary. Furthermore, there is also concern about the risk of peeling due to electrical leakage, etc. The present invention was completed in view of the above, and a third object of the present invention is to provide an electrically peelable pressure-sensitive adhesive sheet and assembly that, by laminating a coating layer on a conductive layer, makes it possible to control conditions such as the applied voltage and application time at which peeling performance is expressed according to the purpose. [Means for solving the problem]

[0009] As a result of extensive investigations, the present inventors have found that by providing a coating layer in contact with the electrically releasing pressure-sensitive adhesive layer between the electrically releasing pressure-sensitive adhesive layer and the electrically releasing pressure-sensitive adhesive layer, peeling of the electrically releasing layer from the support substrate can be suppressed even under high temperature and high humidity conditions. It has also been found that peeling of the electrically releasing pressure-sensitive adhesive layer from the electrically releasing pressure-sensitive adhesive layer can be suppressed. Furthermore, it has been found that conditions such as applied voltage and application time at which peeling performance is exhibited can be controlled according to the purpose.

[0010] The means for solving the above problems are as follows. [1] a conductive substrate including a supporting substrate and a conductive layer; A coating layer; an electrically peelable pressure-sensitive adhesive layer whose adhesive strength decreases upon application of a voltage, the coating layer is formed on a surface of the conductive layer opposite to the supporting substrate, The electrically releasable pressure-sensitive adhesive sheet is one in which the electrically releasable pressure-sensitive adhesive layer and the coating layer are in contact with each other. [2] The electrically peelable pressure-sensitive adhesive sheet according to [1], wherein the electrically peelable pressure-sensitive adhesive layer contains a polymer and an ionic liquid. [3] [3] The electrically peelable pressure-sensitive adhesive sheet according to [2], wherein the content of the ionic liquid is 0.5 parts by mass or more and 30 parts by mass or less per 100 parts by mass of the polymer. [4] The electrically peelable pressure-sensitive adhesive sheet according to [2] or [3], wherein the anion of the ionic liquid is at least one selected from the group consisting of bis(fluorosulfonyl)imide anion and / or bis(trifluoromethanesulfonyl)imide anion. [5] The electrically peelable pressure-sensitive adhesive sheet according to any one of [2] to [4], wherein the cation of the ionic liquid is at least one selected from the group consisting of a nitrogen-containing onium cation, a sulfur-containing onium cation, and a phosphorus-containing onium cation. [6] The electrically peelable pressure-sensitive adhesive sheet according to any one of [1] to [5], wherein the coating layer contains at least one resin selected from polyester resins, acrylic resins, epoxy resins, and urethane resins, or at least one inorganic material selected from SiNx, SiOx, Al2O3, Ni, and NiCr. [7] Further, another adhesive layer is provided, The electrically peelable pressure-sensitive adhesive sheet according to any one of [1] to [6], wherein the other pressure-sensitive adhesive layer is formed on the surface of the supporting substrate opposite to the conductive layer. [8] Further comprising another adhesive layer, a second conductive layer, and a second other adhesive layer, the other pressure-sensitive adhesive layer is formed on the surface of the supporting substrate opposite to the conductive layer, the second conductive layer and a second other pressure-sensitive adhesive layer are formed in this order on the surface of the electrically releasing pressure-sensitive adhesive layer opposite to the coating layer, The electrically peelable pressure-sensitive adhesive sheet according to any one of [1] to [6], wherein the electrically peelable pressure-sensitive adhesive layer and the second conductive layer are in contact with each other. However, a second coating layer may be provided between the electrically releasable pressure-sensitive adhesive layer and the second conductive layer so as to be in contact with the electrically releasable pressure-sensitive adhesive layer. [9] [1] to [7], and a conductive material, A bonded body in which the electrically peelable pressure-sensitive adhesive layer is adhered to the conductive material.

[10] [8] An electrically peelable pressure-sensitive adhesive sheet according to the present invention, and an adherend material, A bonded body in which the other pressure-sensitive adhesive layer is attached to the adherend material. [Effects of the Invention]

[0011] The electrically peelable pressure-sensitive adhesive sheet of the present invention prevents the conductive layer from peeling from the support substrate when a voltage is applied even in a high-temperature, high-humidity environment, and also prevents the electrically peelable pressure-sensitive adhesive layer from peeling from the conductive layer even in a high-temperature environment, thereby maintaining sufficient adhesive strength. [Brief explanation of the drawings]

[0012] [Figure 1] 1 is a cross-sectional view showing an example of an electrically peelable pressure-sensitive adhesive sheet of the present invention. [Figure 2] FIG. 2 is a cross-sectional view showing another example of the electrically releasable pressure-sensitive adhesive sheet of the present invention. [Figure 3] FIG. 2 is a cross-sectional view showing another example of the electrically releasable pressure-sensitive adhesive sheet of the present invention. [Figure 4] FIG. 2 is a cross-sectional view showing another example of the electrically releasable pressure-sensitive adhesive sheet of the present invention. [Figure 5] FIG. 2 is a cross-sectional view showing another example of the electrically releasable pressure-sensitive adhesive sheet of the present invention. [Figure 6] FIG. 2 is a cross-sectional view showing an outline of the method for the 180° peel test in the examples. [Figure 7] FIG. 10 is a diagram for explaining the voltage control evaluation of Examples 1 and 8 of the present invention. [Figure 8] FIG. 10 is a diagram for explaining the voltage control evaluation of Examples 9 and 10 of the present invention. [Figure 9] FIG. 10 is a diagram for explaining the voltage control evaluation of Examples 13 and 14 of the present invention. [Figure 10] FIG. 10 is a diagram for explaining the voltage control evaluation of Example 15 of the present invention and Comparative Example 1. [Figure 11] FIG. 10 is a diagram for explaining the voltage control evaluation of Examples 16 and 17 of the present invention. DETAILED DESCRIPTION OF THE INVENTION

[0013] DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The following describes in detail the preferred embodiments of the present invention, but the present invention is not limited to the following preferred embodiments.

[0014] [Electrically peelable adhesive sheet] (Configuration of electrically peelable adhesive sheet) The electrically peelable pressure-sensitive adhesive sheet according to an embodiment of the present invention comprises a conductive substrate including a supporting substrate and a conductive layer; A coating layer; an electrically peelable pressure-sensitive adhesive layer whose adhesive strength decreases upon application of a voltage, the coating layer is formed on a surface of the conductive layer opposite to the supporting substrate, The electrically releasable pressure-sensitive adhesive layer and the coating layer are in contact with each other.

[0015] The electrically releasing pressure-sensitive adhesive sheet according to the embodiment of the present invention includes a coating layer, which prevents the conductive layer from peeling off from the support substrate. Furthermore, the contact between the electrically releasing pressure-sensitive adhesive layer and the coating layer improves the adhesion between the electrically releasing pressure-sensitive adhesive layer and the conductive layer, thereby preventing peeling in the electrically releasing pressure-sensitive adhesive sheet when exposed to a high-temperature environment.

[0016] The electrically peelable pressure-sensitive adhesive sheet of this embodiment may have multiple conductive layers, conductive substrates, coating layers, and electrically peelable pressure-sensitive adhesive layers, and may also have pressure-sensitive adhesive layers, intermediate layers, undercoat layers, etc. in addition to the conductive layers, conductive substrates, coating layers, and electrically peelable pressure-sensitive adhesive layers. The electrically peelable pressure-sensitive adhesive sheet of this embodiment may be in the form of, for example, a roll or a sheet. Note that the term "electrically peelable pressure-sensitive adhesive sheet" also includes the meaning of "adhesive tape." That is, the electrically peelable pressure-sensitive adhesive sheet of this embodiment may be an adhesive tape in the form of a tape.

[0017] The electrically releasing pressure-sensitive adhesive sheet of this embodiment may be a single-sided electrically releasing pressure-sensitive adhesive sheet having a conductive substrate and a coating layer and an electrically releasing pressure-sensitive adhesive layer on only one side of the conductive substrate. The electrically peelable pressure-sensitive adhesive sheet of this embodiment may further comprise another pressure-sensitive adhesive layer that does not have electrical peeling properties, or may further comprise another pressure-sensitive adhesive layer on the surface of the electrically peelable pressure-sensitive adhesive sheet facing the supporting substrate. In addition, the electrically peelable pressure-sensitive adhesive sheet of this embodiment may be a double-sided electrically peelable pressure-sensitive adhesive sheet in which the conductive substrate has conductive layers on both sides of the supporting substrate, and each conductive layer is provided with a coating layer and an electrically peelable pressure-sensitive adhesive layer. The electrically peelable pressure-sensitive adhesive sheet of this embodiment may have a separator (release liner) for the purpose of protecting the surface of the electrically peelable pressure-sensitive adhesive layer and other pressure-sensitive adhesive layers, but the separator is not included in the electrically peelable pressure-sensitive adhesive sheet of this embodiment.

[0018] The electrically peelable pressure-sensitive adhesive sheet according to an embodiment of the present invention further comprises another pressure-sensitive adhesive layer, It is also preferable that the electrically peelable pressure-sensitive adhesive sheet has the other pressure-sensitive adhesive layer formed on the surface of the supporting substrate opposite to the conductive layer.

[0019] Moreover, the electrically peelable pressure-sensitive adhesive sheet according to an embodiment of the present invention further comprises another pressure-sensitive adhesive layer, a second conductive layer, and a second other pressure-sensitive adhesive layer, the other pressure-sensitive adhesive layer is formed on the surface of the supporting substrate opposite to the conductive layer, the second conductive layer and a second other pressure-sensitive adhesive layer are formed in this order on the surface of the electrically releasing pressure-sensitive adhesive layer opposite to the coating layer, It is also preferable that the electrically releasable pressure-sensitive adhesive sheet is one in which the electrically releasable pressure-sensitive adhesive layer and the second conductive layer are in contact with each other. However, a second coating layer may be provided between the electrically releasable pressure-sensitive adhesive layer and the second conductive layer so as to be in contact with the electrically releasable pressure-sensitive adhesive layer.

[0020] The structure of the electrically peelable adhesive sheet of this embodiment is not particularly limited, but preferred examples include electrically peelable adhesive sheet X1 shown in FIG. 1, electrically peelable adhesive sheet X2 shown in FIG. 2, electrically peelable adhesive sheet X3 shown in FIG. 3, electrically peelable adhesive sheet X4 shown in FIG. 4, and electrically peelable adhesive sheet X5 shown in FIG. 5. The electrically peelable pressure-sensitive adhesive sheet X1 shown in FIG. 1 is an electrically peelable pressure-sensitive adhesive sheet having a layer structure of an electrically peelable pressure-sensitive adhesive layer 1, a coating layer 2, and a conductive substrate 5 (a conductive layer 3 and a supporting substrate 4). The electrically peelable pressure-sensitive adhesive sheet X2 shown in Figure 2 is an electrically peelable pressure-sensitive adhesive sheet having a layer structure of another pressure-sensitive adhesive layer 6, a conductive substrate 5 (support substrate 4 and conductive layer 3), a coating layer 2, and an electrically peelable pressure-sensitive adhesive layer 1. The electrically releasing pressure-sensitive adhesive sheet X3 shown in Fig. 3 is an electrically releasing pressure-sensitive adhesive sheet having a layer configuration comprising, in this order, another pressure-sensitive adhesive layer 6, a conductive substrate 5 (supporting substrate 4, conductive layer 3), a coating layer 2, an electrically releasing pressure-sensitive adhesive layer 1, a coating layer 2, a conductive substrate 5 (conductive layer 3, supporting substrate 4), and another pressure-sensitive adhesive layer 6. That is, the electrically releasing pressure-sensitive adhesive layer 1 in the electrically releasing pressure-sensitive adhesive sheet X3 shown in Fig. 3 is a double-sided electrically releasing pressure-sensitive adhesive sheet comprising, on both sides thereof, a coating layer 2, a conductive layer 3, a supporting substrate 4, and another pressure-sensitive adhesive layer 6, in this order. The electrically peeling pressure-sensitive adhesive sheet X4 shown in Figure 4 is a double-sided electrically peeling pressure-sensitive adhesive sheet having a layer structure including, in this order, another pressure-sensitive adhesive layer 6, a conductive substrate 5 (support substrate 4, conductive layer 3), a coating layer 2, an electrically peeling pressure-sensitive adhesive layer 1, a conductive substrate 5 (conductive layer 3, support substrate 4), and another pressure-sensitive adhesive layer 6. The electrically peeling adhesive sheet X5 shown in Figure 5 is a double-sided electrically peeling adhesive sheet having a layer structure including another adhesive layer 6, a conductive substrate 5 (support substrate 4, conductive layer 3), a coating layer 2, an electrically peeling adhesive layer 1, a conductive layer 3, and another adhesive layer 6 in this order.

[0021] The coating layer 2 is formed on the surface of the conductive layer 3 opposite to the supporting substrate 4 and is a layer in contact with the electrically peelable pressure-sensitive adhesive layer 1. The electrically peelable adhesive sheet of this embodiment has a coating layer 2, which acts as a barrier to prevent the ionic liquid contained in the electrically peelable adhesive layer 1 from penetrating into the conductive layer 3 when a voltage is applied, thereby preventing the conductive layer 3 from peeling off from the support substrate 4. Furthermore, the coating layer 2 is in contact with the electrically releasing pressure-sensitive adhesive layer 1, thereby improving the adhesive strength between the electrically releasing pressure-sensitive adhesive layer 1 and the conductive layer 3. The electrically releasing pressure-sensitive adhesive layer is thermally cured by being exposed to a high-temperature environment, and the adhesive strength between the electrically releasing pressure-sensitive adhesive layer and the conductive layer 3 is improved. Base material This has the effect of preventing the interfacial adhesive strength with the electrically peelable pressure-sensitive adhesive sheet from decreasing and causing the sheet to peel off within the sheet.

[0022] The coating layer 2 is a layer whose main component is a resin or an inorganic substance, and can be formed from a resin composition whose main component is a resin component or a composition whose main component is an inorganic substance. The coating layer 2 preferably contains at least one resin selected from polyester resins, acrylic resins, epoxy resins, and urethane resins, or at least one inorganic material selected from SiNx, SiOx, Al2O3, Ni, and NiCr.

[0023] When the coating layer 2 is primarily composed of a resin, the resin components constituting the coating layer 2 (resin coating layer) include, for example, epoxy-based resins, polyester-based resins, acrylic-based resins, or urethane-based resins, which can be used alone or as a mixture.

[0024] The resin composition that forms the coating layer 2 preferably contains the above-mentioned resin component (polymer) as a main component. The polymer content in the resin composition of this embodiment is preferably 50% by mass or more and 99.9% by mass or less relative to the total amount of the resin composition (100% by mass), with the upper limit being more preferably 99.5% by mass, and even more preferably 99% by mass, and the lower limit being more preferably 60% by mass, and even more preferably 70% by mass.

[0025] The resin composition may further contain a curing agent, which may be a commonly used curing agent such as an isocyanate-based curing agent, an epoxy-based curing agent, or a melamine-based curing agent.

[0026] The resin composition of this embodiment may also contain various additives such as fillers, plasticizers, antioxidants, antioxidants, pigments (dyes), flame retardants, solvents, surfactants (leveling agents), rust inhibitors, corrosion inhibitors, and antistatic agents. The total content of these components is not particularly limited as long as the effects of the present invention are achieved, but is preferably 0.01 parts by mass or more and 20 parts by mass or less, more preferably 10 parts by mass or less, and even more preferably 5 parts by mass or less, per 100 parts by mass of the resin.

[0027] Examples of fillers include silica, iron oxide, zinc oxide, aluminum oxide, titanium oxide, barium oxide, magnesium oxide, calcium carbonate, magnesium carbonate, zinc carbonate, pyrophyllite clay, kaolin clay, and calcined clay. The plasticizer may be any known or commonly used plasticizer used in general resin compositions, etc., and examples thereof include oils such as paraffin oil and process oil, liquid rubbers such as liquid polyisoprene, liquid polybutadiene, and liquid ethylene-propylene rubber, tetrahydrophthalic acid, azelaic acid, benzoic acid, phthalic acid, trimellitic acid, pyromellitic acid, adipic acid, sebacic acid, fumaric acid, maleic acid, itaconic acid, citric acid, and derivatives thereof, dioctyl phthalate (DOP), dibutyl phthalate (DBP), dioctyl adipate, diisononyl adipate (DINA), and isodecyl succinate. Examples of antioxidants include hindered phenol compounds, and aliphatic and aromatic hindered amine compounds. Examples of antioxidants include butylhydroxytoluene (BHT) and butylhydroxyanisole (BHA). Examples of pigments include inorganic pigments such as titanium dioxide, zinc oxide, ultramarine, red iron oxide, lithopone, lead, cadmium, iron, cobalt, aluminum, hydrochlorides, and sulfates, and organic pigments such as azo pigments and copper phthalocyanine pigments. Examples of the rust inhibitor include zinc phosphate, tannic acid derivatives, phosphoric acid esters, basic sulfonates, and various rust-preventive pigments. Examples of corrosion inhibitors include carbodiimide compounds, adsorption inhibitors, and chelating-type metal deactivators. For example, those described in JP 2019-059908 A can be used. Examples of antistatic agents generally include quaternary ammonium salts, or hydrophilic compounds such as polyglycolic acid and ethylene oxide derivatives.

[0028] The form of the resin composition containing a resin as a main component is not particularly limited, and may be, for example, an aqueous resin composition, a solvent-based resin composition, a hot-melt resin composition, an active energy ray-curable resin composition, etc. Here, the aqueous resin composition refers to a resin composition in a form containing a coating layer-forming component in a solvent (aqueous solvent) containing water as a main component, and is a concept that encompasses a water-dispersed resin composition in which the components constituting the coating layer are dispersed in water, and a water-soluble resin composition in which the components constituting the coating layer are dissolved in water.

[0029] The coating layer 2 (resin coating layer) containing a resin as its main component can be formed by applying a resin composition using a known technique such as gravure coating, reverse roll coating, roll coating, dip coating, or comma coating, drying it, and then curing it by irradiating it with ultraviolet light, electron beams, or the like, as necessary.

[0030] The thickness of the coating layer 2 (resin coating layer) is preferably 10 nm or more and 5000 nm or less. The upper limit of the thickness of the coating layer 2 (resin coating layer) is more preferably 2000 nm, even more preferably 1000 nm, even more preferably 500 nm, even more preferably 200 nm, even more preferably 170 nm, even more preferably 150 nm, even more preferably 130 nm, even more preferably 100 nm, and the lower limit is more preferably 15 nm, even more preferably 20 nm, even more preferably 30 nm, even more preferably 50 nm.

[0031] Furthermore, when the coating layer 2 is mainly composed of an inorganic substance, examples of the inorganic substance that constitutes the coating layer 2 (inorganic coating layer) include metals, metal alloys, metal oxides, and metal nitrides. Examples of metals include silicon, aluminum, nickel, chromium, tin, gold, silver, platinum, zinc, titanium, tungsten, zirconium, and palladium. As the inorganic substance, Al2O3, Ni, NiCr, or inorganic nitrides or inorganic oxides of non-stoichiometric composition such as SiNx or SiOx are preferable. The coating layer 2 (inorganic coating layer) containing an inorganic substance as a main component can be formed by a sputtering method, a vapor deposition method, or the like.

[0032] From the viewpoint of electrical peelability, the thickness of the coating layer 2 (inorganic coating layer) containing an inorganic substance as the main component is preferably 1 nm or more and 1000 nm or less. The upper limit of the thickness of the coating layer 2 (inorganic coating layer) is more preferably 700 nm, even more preferably 500 nm, even more preferably 200 nm, even more preferably 170 nm, even more preferably 150 nm, even more preferably 130 nm, even more preferably 100 nm, and the lower limit is more preferably 10 nm, even more preferably 20 nm, even more preferably 30 nm, even more preferably 50 nm.

[0033] The conductive layer 3 is not particularly limited as long as it is a layer having conductivity, but may be a metal substrate such as a metal (e.g., aluminum, magnesium, copper, iron, tin, gold, etc.) foil, a metal plate (e.g., aluminum, magnesium, copper, iron, tin, silver, etc.), a conductive polymer, or the like, or may be a metal vapor deposition film provided on a supporting substrate 4.

[0034] The thickness of the conductive layer 3 is preferably 0.001 μm or more and 1000 μm or less. The upper limit of the thickness is more preferably 500 μm, even more preferably 300 μm, even more preferably 100 μm, even more preferably 50 μm, even more preferably 10 μm, even more preferably 5 μm, even more preferably 1 μm, even more preferably 0.5 μm, and the lower limit is more preferably 0.01 μm, even more preferably 0.02 μm, even more preferably 0.03 μm, even more preferably 0.04 μm, even more preferably 0.05 μm.

[0035] The support substrate 4 is not particularly limited, but examples thereof include paper-based substrates such as paper, fiber-based substrates such as cloth and nonwoven fabric, plastic-based substrates such as films and sheets made of various plastics (polyolefin-based resins such as polyethylene and polypropylene, polyester-based resins such as polyethylene terephthalate, acrylic resins such as polymethyl methacrylate, etc.), and laminates thereof. The substrate may have a single layer structure or a multi-layer structure. The substrate may be subjected to various treatments such as back surface treatment, antistatic treatment, and primer treatment as necessary.

[0036] The thickness of the support substrate 4 is preferably 10 μm or more and 1000 μm or less. The upper limit of the thickness is more preferably 500 μm, even more preferably 300 μm, even more preferably 100 μm, even more preferably 70 μm, even more preferably 50 μm, and even more preferably 40 μm, and the lower limit is more preferably 12 μm, even more preferably 25 μm.

[0037] The conductive substrate 5 is not particularly limited as long as it includes a support substrate 4 and a conductive layer 3, but examples thereof include a support substrate 4 on which a conductive layer is formed, such as a support substrate 4 exemplified above, on whose surface the conductive layer is formed by plating, chemical vapor deposition, sputtering, or the like.

[0038] The thickness of the conductive substrate 5 is preferably 10 μm or more and 1000 μm or less. The upper limit of the thickness is more preferably 500 μm, even more preferably 300 μm, even more preferably 100 μm, even more preferably 70 μm, even more preferably 50 μm, and even more preferably 40 μm, and the lower limit is more preferably 12 μm, even more preferably 25 μm.

[0039] The electrically peelable pressure-sensitive adhesive sheet can be attached to a conductive material to form a bonded body. Examples of conductive materials include adherends such as metal-coated surfaces. Examples of metal-coated surfaces include surfaces made of metals primarily composed of aluminum, copper, iron, magnesium, tin, gold, silver, and lead, with surfaces made of metals containing aluminum being preferred. Examples of adherends having metal-coated surfaces include sheets, parts, and plates made of metals primarily composed of aluminum, copper, iron, magnesium, tin, gold, silver, and lead. Adherends other than those having metal-coated surfaces include, but are not limited to, fiber sheets such as paper, cloth, and nonwoven fabric, and various plastic films and sheets.

[0040] The electrically peelable pressure-sensitive adhesive layer 1 is a pressure-sensitive adhesive layer having the property that its adhesive strength decreases when a voltage is applied. The electrically releasable adhesive layer contains a polymer as an adhesive and an electrolyte. The electrolyte contained in the electrically peelable pressure-sensitive adhesive layer is a substance that can be ionized into anions and cations, and examples of such electrolytes include ionic liquids, alkali metal salts, and alkaline earth metal salts. From the viewpoint of realizing good electrical peelability in the electrically peelable pressure-sensitive adhesive layer, the electrolyte contained in the electrically peelable pressure-sensitive adhesive layer is preferably an ionic liquid. Ionic liquids are salts that are liquid at room temperature (about 25°C) and contain anions and cations. That is, the electrically peelable pressure-sensitive adhesive layer preferably contains a polymer and an ionic liquid. The electrically peelable pressure-sensitive adhesive layer 1 can be formed from a pressure-sensitive adhesive composition containing a polymer and an ionic liquid. The pressure-sensitive adhesive composition of this embodiment will be described below. In this specification, the adhesive strength when no voltage is applied is sometimes referred to as "initial adhesive strength." Furthermore, a composition containing components other than the ionic liquid among the components contained in the pressure-sensitive adhesive composition may be referred to as an "ionic liquid-free pressure-sensitive adhesive composition." Furthermore, a pressure-sensitive adhesive layer formed from an ionic liquid-free pressure-sensitive adhesive composition may be referred to as an "ionic liquid-free pressure-sensitive adhesive layer." Furthermore, the property of adhesive strength decreasing with the application of voltage is called "electrical releasability," and a large rate of decrease in adhesive strength with the application of voltage is sometimes referred to as "excellent electrical releasability."

[0041] <Components of Pressure-Sensitive Adhesive Composition> (polymer) The pressure-sensitive adhesive composition of the present embodiment contains a polymer. In the present embodiment, the polymer is not particularly limited as long as it is a general organic polymer compound, and is, for example, a polymer or partial polymer of a monomer. The monomer may be one type of monomer or a mixture of two or more types of monomers. Note that the partial polymer refers to a polymer in which at least a part of the monomer or monomer mixture is partially polymerized.

[0042] The polymer in this embodiment is not particularly limited as long as it is normally used as a pressure-sensitive adhesive and has adhesive properties, and examples thereof include acrylic polymers, rubber polymers, vinyl alkyl ether polymers, silicone polymers, polyester polymers, polyamide polymers, urethane polymers, fluorine-containing polymers, and epoxy polymers. The polymers can be used alone or in combination of two or more. In order to increase the dielectric constant of the components other than the ionic liquid in the resulting electrically peelable pressure-sensitive adhesive layer and improve the electrical peelability, it is preferable that the polymer have a high dielectric constant. From this perspective, the polymer in this embodiment preferably contains at least one selected from the group consisting of polyester polymers and acrylic polymers having carboxyl groups and / or hydroxyl groups. Because polyester polymers have easily polarizable hydroxyl groups at their terminals, and because acrylic polymers having carboxyl groups and / or hydroxyl groups have easily polarizable carboxyl groups and / or hydroxyl groups, using these polymers makes it possible to obtain polymers with relatively high dielectric constants. The total content of the polyester polymer and the acrylic polymer having carboxyl groups and / or hydroxyl groups in the polymer of this embodiment is preferably 60% by mass or more, more preferably 80% by mass or more. In particular, in order to improve costs, productivity, and initial adhesive strength, the polymer in this embodiment is preferably an acrylic polymer. That is, the pressure-sensitive adhesive composition of the present embodiment is preferably an acrylic pressure-sensitive adhesive composition containing an acrylic polymer as the polymer.

[0043] The acrylic polymer preferably contains a monomer unit derived from a (meth)acrylic acid alkyl ester (the following formula (1)) having an alkyl group having 1 to 14 carbon atoms. Such a monomer unit is suitable for obtaining a large initial adhesive strength. In addition, in order to increase the relative dielectric constant of the components of the electrically peelable pressure-sensitive adhesive layer other than the ionic liquid and improve the electrical peelability, the alkyl group R in the following formula (1) b The number of carbon atoms is preferably small, particularly preferably 8 or less, and more preferably 4 or less. CH2=C(R a )COOR b (1) [R in formula (1)] a is a hydrogen atom or a methyl group, and R b is an alkyl group having 1 to 14 carbon atoms which may have a substituent.

[0044] Examples of (meth)acrylic acid alkyl esters having an alkyl group having 1 to 14 carbon atoms include methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, sec-butyl (meth)acrylate, 1,3-dimethylbutyl acrylate, pentyl (meth)acrylate, isopentyl (meth)acrylate, hexyl (meth)acrylate, and 2-ethylbutyl (meth)acrylate. acrylate, heptyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, n-nonyl (meth)acrylate, isononyl (meth)acrylate, n-decyl (meth)acrylate, isodecyl (meth)acrylate, n-dodecyl (meth)acrylate, n-tridecyl (meth)acrylate, n-tetradecyl (meth)acrylate, and 2-methoxyethyl acrylate. Among these, n-butyl acrylate, 2-ethylhexyl acrylate, isononyl acrylate, and 2-methoxyethyl acrylate are preferred. (Meth)acrylic acid alkyl esters having an alkyl group of 1 to 14 carbon atoms can be used alone or in combination of two or more.

[0045] The proportion of the (meth)acrylic acid alkyl ester having an alkyl group of 1 to 14 carbon atoms relative to all monomer components (100% by mass) constituting the acrylic polymer is not particularly limited, but is preferably 70% by mass or more, more preferably 80% by mass or more, and even more preferably 85% by mass or more. When the proportion of the (meth)acrylic acid alkyl ester having an alkyl group of 1 to 14 carbon atoms is 70% by mass or more, a large initial adhesive strength is easily obtained.

[0046] For the purpose of improving cohesive strength, heat resistance, crosslinkability, etc., the acrylic polymer preferably contains a monomer unit derived from a polar group-containing monomer copolymerizable with a (meth)acrylic acid alkyl ester having an alkyl group having 1 to 14 carbon atoms, in addition to the monomer unit. The monomer unit can provide crosslinking points and is suitable for obtaining high initial adhesive strength. Furthermore, from the viewpoint of increasing the relative permittivity of components other than the ionic liquid in the electrically peelable pressure-sensitive adhesive layer and improving electrical peelability, it is also preferable to contain a monomer unit derived from a polar group-containing monomer.

[0047] Examples of polar group-containing monomers include carboxyl group-containing monomers, hydroxyl group-containing monomers, cyano group-containing monomers, vinyl group-containing monomers, aromatic vinyl monomers, amide group-containing monomers, imide group-containing monomers, amino group-containing monomers, epoxy group-containing monomers, vinyl ether monomers, N-acryloylmorpholine, sulfo group-containing monomers, phosphate group-containing monomers, and acid anhydride group-containing monomers. Among these, carboxyl group-containing monomers, hydroxyl group-containing monomers, and amide group-containing monomers are preferred from the viewpoint of excellent cohesion, and carboxyl group-containing monomers are particularly preferred. Carboxyl group-containing monomers are particularly suitable for obtaining high initial adhesive strength. Polar group-containing monomers can be used alone or in combination of two or more.

[0048] Examples of carboxyl group-containing monomers include acrylic acid, methacrylic acid, carboxyethyl (meth)acrylate, carboxypentyl (meth)acrylate, itaconic acid, maleic acid, fumaric acid, crotonic acid, and isocrotonic acid. Acrylic acid is particularly preferred. The carboxyl group-containing monomers can be used alone or in combination of two or more.

[0049] Examples of hydroxyl group-containing monomers include 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 6-hydroxyhexyl (meth)acrylate, 8-hydroxyoctyl (meth)acrylate, 10-hydroxydecyl (meth)acrylate, 12-hydroxylauryl (meth)acrylate, (4-hydroxymethylcyclohexyl)methyl (meth)acrylate, N-methylol (meth)acrylamide, vinyl alcohol, allyl alcohol, 2-hydroxyethyl vinyl ether, 4-hydroxybutyl vinyl ether, and diethylene glycol monovinyl ether. 2-hydroxyethyl (meth)acrylate and 4-hydroxybutyl (meth)acrylate are particularly preferred. The hydroxyl group-containing monomers can be used alone or in combination.

[0050] Examples of amide group-containing monomers include acrylamide, methacrylamide, N-vinylpyrrolidone, N,N-dimethylacrylamide, N,N-dimethylmethacrylamide, N,N-diethylacrylamide, N,N-diethylmethacrylamide, N,N'-methylenebisacrylamide, N,N-dimethylaminopropylacrylamide, N,N-dimethylaminopropylmethacrylamide, and diacetoneacrylamide. The amide group-containing monomers can be used alone or in combination of two or more.

[0051] Examples of cyano group-containing monomers include acrylonitrile and methacrylonitrile.

[0052] Examples of vinyl group-containing monomers include vinyl esters such as vinyl acetate, vinyl propionate, and vinyl laurate, with vinyl acetate being particularly preferred.

[0053] Examples of aromatic vinyl monomers include styrene, chlorostyrene, chloromethylstyrene, α-methylstyrene, and other substituted styrenes.

[0054] Examples of imide group-containing monomers include cyclohexylmaleimide, isopropylmaleimide, N-cyclohexylmaleimide, and itaconimide.

[0055] Examples of amino group-containing monomers include aminoethyl (meth)acrylate, N,N-dimethylaminoethyl (meth)acrylate, and N,N-dimethylaminopropyl (meth)acrylate.

[0056] Examples of epoxy group-containing monomers include glycidyl (meth)acrylate, methyl glycidyl (meth)acrylate, and allyl glycidyl ether.

[0057] Examples of vinyl ether monomers include methyl vinyl ether, ethyl vinyl ether, and isobutyl vinyl ether.

[0058] The proportion of the polar group-containing monomer relative to all monomer components (100% by mass) constituting the acrylic polymer is preferably 0.1% by mass or more and 35% by mass or less. The upper limit of the proportion of the polar group-containing monomer is more preferably 25% by mass, even more preferably 20% by mass, and the lower limit is more preferably 0.5% by mass, even more preferably 1% by mass, and particularly preferably 2% by mass. When the proportion of the polar group-containing monomer is 0.1% by mass or more, cohesive force is easily obtained, so that adhesive residue is less likely to remain on the adherend surface after peeling off the electrically peelable pressure-sensitive adhesive layer, and the electrical peelability is improved. Furthermore, when the proportion of the polar group-containing monomer is 35 When the content is 2% by mass or less, it is easy to prevent the electrically-release pressure-sensitive adhesive layer from adhering too closely to the adherend, resulting in heavy release. In particular, when the content is 2% by mass or more and 20% by mass or less, it is easy to achieve both good releasability from the adherend and good adhesion between the electrically-release pressure-sensitive adhesive layer and other layers.

[0059] Furthermore, the monomer components constituting the acrylic polymer may contain a polyfunctional monomer in order to introduce a crosslinked structure into the acrylic polymer and make it easier to obtain the required cohesive strength.

[0060] Examples of polyfunctional monomers include ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, neopentyl glycol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, dipentaerythritol hexa(meth)acrylate, divinylbenzene, and N,N'-methylenebisacrylamide. The polyfunctional monomers can be used alone or in combination of two or more.

[0061] The content of the polyfunctional monomer relative to all monomer components (100% by mass) constituting the acrylic polymer is preferably 0.1% by mass or more and 15% by mass or less. The upper limit of the polyfunctional monomer content is more preferably 10% by mass, and the lower limit is more preferably 3% by mass. When the content of the polyfunctional monomer is 0.1% by mass or more, the flexibility and adhesiveness of the electrically peelable pressure-sensitive adhesive layer are easily improved, which is preferable. When the content of the polyfunctional monomer is 15% by mass or less, the cohesive force is not too high, and appropriate adhesiveness is easily obtained.

[0062] Polyester-based polymers are typically polymers having a structure formed by condensation of a polycarboxylic acid such as a dicarboxylic acid or its derivative (hereinafter also referred to as a "polycarboxylic acid monomer") with a polyhydric alcohol such as a diol or its derivative (hereinafter referred to as a "polyhydric alcohol monomer").

[0063] The polycarboxylic acid monomer is not particularly limited, but examples thereof include adipic acid, azelaic acid, dimer acid, sebacic acid, 1,4-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,2-cyclohexanedicarboxylic acid, 4-methyl-1,2-cyclohexanedicarboxylic acid, dodecenylsuccinic anhydride, fumaric acid, succinic acid, dodecanedioic acid, hexahydrophthalic anhydride, tetrahydrophthalic anhydride, maleic acid, maleic anhydride, itaconic acid, citraconic acid, and derivatives thereof. The polycarboxylic acid monomers can be used alone or in combination of two or more kinds.

[0064] The polyhydric alcohol monomer is not particularly limited, but examples thereof include ethylene glycol, 1,2-propylene glycol, 1,3-propanediol, 2-methyl-1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 3-methyl-1,5-pentanediol, neopentyl glycol, diethylene glycol, dipropylene glycol, 2,2,4-trimethyl-1,5-pentanediol, 2-ethyl-2-butylpropanediol, 1,9-nonanediol, 2-methyloctanediol, 1,10-decanediol, and derivatives thereof. The polyhydric alcohol monomers can be used alone or in combination of two or more.

[0065] The polymer of this embodiment may also contain an ionic polymer. The ionic polymer is a polymer having an ionic functional group. When the polymer contains an ionic polymer, the relative dielectric constant of the polymer increases, improving the electro-separation properties. When the polymer contains an ionic polymer, the content of the ionic polymer is preferably 0.05 parts by mass or more and 2 parts by mass or less per 100 parts by mass of the polymer.

[0066] In this embodiment, the polymer can be obtained by (co)polymerizing monomer components. The polymerization method is not particularly limited, but examples thereof include solution polymerization, emulsion polymerization, bulk polymerization, suspension polymerization, and photopolymerization (active energy ray polymerization). In particular, from the viewpoints of cost and productivity, solution polymerization is preferred. When copolymerized, the polymer may be any of a random copolymer, a block copolymer, an alternating copolymer, a graft copolymer, and the like.

[0067] The solution polymerization method is not particularly limited, but examples thereof include a method in which a monomer component, a polymerization initiator, etc. are dissolved in a solvent and heated to polymerize, thereby obtaining a polymer solution containing a polymer.

[0068] As the solvent used in the solution polymerization method, various common solvents can be used. Examples of such solvents (polymerization solvents) include organic solvents such as aromatic hydrocarbons such as toluene, benzene, and xylene; esters such as ethyl acetate and n-butyl acetate; aliphatic hydrocarbons such as n-hexane and n-heptane; alicyclic hydrocarbons such as cyclohexane and methylcyclohexane; and ketones such as methyl ethyl ketone and methyl isobutyl ketone. The solvents can be used alone or in combination of two or more.

[0069] The amount of the solvent used is not particularly limited, but is preferably 10 parts by mass or more and 1,000 parts by mass or less relative to the total monomer components (100 parts by mass) constituting the polymer. The upper limit of the amount of the solvent used is more preferably 500 parts by mass, and the lower limit is more preferably 50 parts by mass.

[0070] The polymerization initiator used in the solution polymerization method is not particularly limited, but examples thereof include peroxide-based polymerization initiators, azo-based polymerization initiators, etc. The peroxide-based polymerization initiator is not particularly limited, but examples thereof include peroxycarbonate, ketone peroxide, peroxyketal, hydroperoxide, dialkyl peroxide, diacyl peroxide, and peroxyester, and more specific examples thereof include benzoyl peroxide, t-butyl hydroperoxide, di-t-butyl peroxide, t-butyl peroxybenzoate, dicumyl peroxide, 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane, and 1,1-bis(t-butylperoxy)cyclododecane, etc. The azo polymerization initiator is not particularly limited, but examples thereof include 2,2'-azobisisobutyronitrile, 2,2'-azobis-2-methylbutyronitrile, 2,2'-azobis(2,4-dimethylvaleronitrile), 2,2'-azobis(2-methylpropionate)dimethyl, 2,2'-azobis(4-methoxy-2,4-dimethylvaleronitrile), 1,1'-azobis(cyclohexane-1-carbonitrile), 2,2'-azobis(2,4,4-trimethylpentane), 4,4'-azobis Examples of suitable polymerization initiators include 4-cyanovaleric acid, 2,2'-azobis(2-amidinopropane) dihydrochloride, 2,2'-azobis[2-(5-methyl-2-imidazolin-2-yl)propane] dihydrochloride, 2,2'-azobis(2-methylpropionamidine) disulfate, 2,2'-azobis(N,N'-dimethyleneisobutylamidine) hydrochloride, and 2,2'-azobis[N-(2-carboxyethyl)-2-methylpropionamidine] hydrate. The polymerization initiators can be used alone or in combination of two or more.

[0071] The amount of the polymerization initiator used is not particularly limited, but is preferably 0.01 to 5 parts by mass relative to the total monomer components (100 parts by mass) constituting the polymer. The upper limit of the amount of the polymerization initiator used is more preferably 3 parts by mass, and the lower limit is more preferably 0.05 parts by mass.

[0072] In the solution polymerization method, the heating temperature when polymerizing by heating is not particularly limited, but is, for example, 50° C. to 80° C. The heating time is not particularly limited, but is, for example, 1 hour to 24 hours.

[0073] The weight-average molecular weight of the polymer is not particularly limited, but is preferably 100,000 or more and 5,000,000 or less. The upper limit of the weight-average molecular weight is more preferably 4,000,000, and even more preferably 3,000,000, and the lower limit is more preferably 200,000, and even more preferably 300,000. When the weight-average molecular weight is 100,000 or more, the cohesive force is reduced, which effectively prevents the problem of adhesive residue remaining on the adherend surface after peeling off the electrically-peelable pressure-sensitive adhesive layer. Furthermore, when the weight-average molecular weight is 5,000,000 or less, it effectively prevents the problem of insufficient wettability on the adherend surface after peeling off the electrically-peelable pressure-sensitive adhesive layer.

[0074] The weight-average molecular weight is obtained by measurement using a gel permeation chromatography (GPC) method. More specifically, for example, it can be measured using a GPC measurement device (trade name "HLC-8220GPC" manufactured by Tosoh Corporation) under the following conditions, and calculated as a value converted into standard polystyrene. (Weight average molecular weight measurement conditions) Sample concentration: 0.2% by mass (tetrahydrofuran solution) Sample injection volume: 10 μL Sample column: TSKguardcolumn SuperHZ-H (1 column) + TSKgel SuperHZM-H (2 columns) Reference column: TSKgel SuperH-RC (1 column) Eluent: tetrahydrofuran (THF) ·Flow rate: 0.6mL / min Detector: Differential refractometer (RI) Column temperature (measurement temperature): 40℃

[0075] The glass transition temperature (Tg) of the polymer is not particularly limited, but is preferably 0° C. or lower because this can prevent a decrease in the initial adhesive strength, more preferably −10° C. or lower, and even more preferably −20° C. or lower. Furthermore, a temperature of −40° C. or lower is particularly preferred because the rate of decrease in adhesive strength due to voltage application is particularly large, and is most preferably −50° C. or lower.

[0076] The glass transition temperature (Tg) can be calculated, for example, based on the following formula (Y) (Fox formula). 1 / Tg=W1 / Tg1+W2 / Tg2++Wn / Tgn (Y) [In formula (Y), Tg is the glass transition temperature of the polymer (unit: K), Tgi (i = 1, 2, . . . n) is the glass transition temperature (unit: K) when monomer i forms a homopolymer, and Wi (i = 1, 2, . . . n) is the mass fraction of monomer i in all monomer components.] The above formula (Y) is a calculation formula when the polymer is composed of n types of monomer components: Monomer 1, Monomer 2, . . . , Monomer n.

[0077] The glass transition temperature of a homopolymer refers to the glass transition temperature of a homopolymer of the monomer, and refers to the glass transition temperature (Tg) of a polymer formed using only a certain monomer (sometimes referred to as "monomer X") as the monomer component. Specific values ​​are listed in "Polymer Handbook" (3rd ed., John Wiley & Sons, Inc., 1989). The glass transition temperature (Tg) of a homopolymer not listed in this document refers to a value obtained, for example, by the following measurement method. Specifically, 100 parts by mass of monomer X, 0.2 parts by mass of 2,2'-azobisisobutyronitrile, and 200 parts by mass of ethyl acetate as a polymerization solvent are placed in a reactor equipped with a thermometer, a stirrer, a nitrogen inlet tube, and a reflux condenser, and the mixture is stirred for 1 hour while introducing nitrogen gas. After removing oxygen from the polymerization system in this way, the temperature is raised to 63°C and the reaction is continued for 10 hours. The mixture is then cooled to room temperature to obtain a homopolymer solution with a solids concentration of 33% by mass. The homopolymer solution was then cast onto a release liner and dried to prepare a test sample (homopolymer sheet) approximately 2 mm thick. Approximately 1-2 mg of this test sample was then weighed into an aluminum open cell, and the reversing heat flow (specific heat component) behavior of the homopolymer was measured using a temperature-modulated DSC (product name "Q-2000" manufactured by TA Instruments) at a heating rate of 5°C / min under a nitrogen atmosphere at 50 mL / min. Referring to JIS-K-7121, the glass transition temperature (Tg) of the homopolymer was determined by the temperature at the point where the line equidistant along the vertical axis from the line extending the low-temperature and high-temperature baselines of the reversing heat flow intersects with the curve representing the stepwise change in the glass transition.

[0078] The polymer content in the pressure-sensitive adhesive composition of the present embodiment is preferably 50% by mass or more and 99.9% by mass or less, relative to the total amount of the pressure-sensitive adhesive composition (100% by mass), with the upper limit being more preferably 99.5% by mass, and even more preferably 99% by mass, and the lower limit being more preferably 60% by mass, and even more preferably 70% by mass.

[0079] (ionic liquid) The ionic liquid in this embodiment is not particularly limited as long as it is a molten salt (room-temperature molten salt) composed of a pair of anion and cation and is liquid at 25° C. Examples of anions and cations are given below, but among the ionic substances obtained by combining these, those that are liquid at 25° C. are ionic liquids, and those that are solid at 25° C. are not ionic liquids but ionic solids, which will be described later.

[0080] The anion of the ionic liquid is, for example, (FSO2)2N - , (CF3SO2)2N - , (CF3CF2SO2)2N - , (CF3SO2)3C - , Br - , AlCl4 - , Al2Cl7 - , NO3 - , BF4 - , PF6 - , CH3COO - , CF3COO - , CF3CF2CF2COO - , CF3SO3 - , CF3(CF2)3SO3 - , AsF6 - , SbF6 - , and F(HF) n - Among them, the anion is (FSO2)2N - [bis(fluorosulfonyl)imide anion], and (CF3SO2)2N - Anions of sulfonylimide compounds such as bis(trifluoromethanesulfonyl)imide anions are preferred because they are chemically stable and suitable for improving electrical peelability. That is, the anion of the ionic liquid is preferably at least one selected from the group consisting of bis(fluorosulfonyl)imide anions and / or bis(trifluoromethanesulfonyl)imide anions.

[0081] The cation in the ionic liquid is preferably at least one selected from the group consisting of nitrogen-containing onium cations, sulfur-containing onium cations, and phosphorus-containing onium cations, as these are chemically stable and suitable for improving electrical peelability, and imidazolium-based, ammonium-based, pyrrolidinium-based, and pyridinium-based cations are more preferred.

[0082] Examples of imidazolium cations include 1-methylimidazolium cation, 1-ethyl-3-methylimidazolium cation, 1-propyl-3-methylimidazolium cation, 1-butyl-3-methylimidazolium cation, 1-pentyl-3-methylimidazolium cation, 1-hexyl-3-methylimidazolium cation, 1-heptyl-3-methylimidazolium cation, 1-octyl-3-methylimidazolium cation, 1-nonyl-3-methylimidazolium cation, 1-undecyl-3-methylimidazolium cation, and 1-dodecyl-3-methylimidazolium cation. imidazolium cation, 1-tridecyl-3-methylimidazolium cation, 1-tetradecyl-3-methylimidazolium cation, 1-pentadecyl-3-methylimidazolium cation, 1-hexadecyl-3-methylimidazolium cation, 1-heptadecyl-3-methylimidazolium cation, 1-octadecyl-3-methylimidazolium cation, 1-undecyl-3-methylimidazolium cation, 1-benzyl-3-methylimidazolium cation, 1-butyl-2,3-dimethylimidazolium cation, and 1,3-bis(dodecyl)imidazolium cation.

[0083] Examples of pyridinium-based cations include 1-butylpyridinium cation, 1-hexylpyridinium cation, 1-butyl-3-methylpyridinium cation, 1-butyl-4-methylpyridinium cation, and 1-octyl-4-methylpyridinium cation.

[0084] Examples of pyrrolidinium cations include 1-ethyl-1-methylpyrrolidinium cation and 1-butyl-1-methylpyrrolidinium cation.

[0085] Examples of ammonium cations include tetraethylammonium cation, tetrabutylammonium cation, methyltrioctylammonium cation, tetradecylammonium cation, and tetradecylammonium cation. L Examples include trihexylammonium cation, glycidyltrimethylammonium cation, and trimethylaminoethyl acrylate cation.

[0086] From the viewpoint of increasing the rate of decrease in adhesive strength when a voltage is applied, it is preferable to select a cation having a molecular weight of 160 or less as the constituent cation of the ionic liquid. - [Bis(fluorosulfonyl)imide anion] or (CF3SO2)2N - Particularly preferred is an ionic liquid containing a [bis(trifluoromethanesulfonyl)imide anion] and a cation having a molecular weight of 160 or less. Examples of the cation having a molecular weight of 160 or less include a 1-methylimidazolium cation, a 1-ethyl-3-methylimidazolium cation, a 1-propyl-3-methylimidazolium cation, a 1-butyl-3-methylimidazolium cation, a 1-pentyl-3-methylimidazolium cation, a 1-butylpyridinium cation, a 1-hexylpyridinium cation, a 1-butyl-3-methylpyridinium cation, a 1-butyl-4-methylpyridinium cation, a 1-ethyl-1-methylpyrrolidinium cation, a 1-butyl-1-methylpyrrolidinium cation, a tetraethylammonium cation, a glycidyltrimethylammonium cation, and a trimethylaminoethyl acrylate cation.

[0087] Furthermore, as the cation of the ionic liquid, cations represented by the following formulas (2-A) to (2-D) are also preferred.

[0088] [ka]

[0089] R in formula (2-A) 1 represents a hydrocarbon group having 4 to 10 carbon atoms (preferably a hydrocarbon group having 4 to 8 carbon atoms, more preferably a hydrocarbon group having 4 to 6 carbon atoms), which may contain a heteroatom; R 2 and R 3 are the same or different and represent a hydrogen atom or a hydrocarbon group having 1 to 12 carbon atoms (preferably a hydrocarbon group having 1 to 8 carbon atoms, more preferably a hydrocarbon group having 2 to 6 carbon atoms, and even more preferably a hydrocarbon group having 2 to 4 carbon atoms), and may contain a heteroatom. However, when a nitrogen atom forms a double bond with an adjacent carbon atom, R 3 does not exist.

[0090] R in formula (2-B) 4 represents a hydrocarbon group having 2 to 10 carbon atoms (preferably a hydrocarbon group having 2 to 8 carbon atoms, more preferably a hydrocarbon group having 2 to 6 carbon atoms), which may contain a heteroatom; R 5 , R 6 , and R 7 are the same or different and represent a hydrogen atom or a hydrocarbon group having 1 to 12 carbon atoms (preferably a hydrocarbon group having 1 to 8 carbon atoms, more preferably a hydrocarbon group having 2 to 6 carbon atoms, and even more preferably a hydrocarbon group having 2 to 4 carbon atoms), and may contain a heteroatom.

[0091] R in formula (2-C) 8 represents a hydrocarbon group having 2 to 10 carbon atoms (preferably a hydrocarbon group having 2 to 8 carbon atoms, more preferably a hydrocarbon group having 2 to 6 carbon atoms), which may contain a heteroatom; R 9 , R 10 , and R 11 are the same or different and represent a hydrogen atom or a hydrocarbon group having 1 to 16 carbon atoms (preferably a hydrocarbon group having 1 to 10 carbon atoms, more preferably a hydrocarbon group having 1 to 8 carbon atoms), which may contain a heteroatom.

[0092] In formula (2-D), X represents a nitrogen, sulfur, or phosphorus atom, and R 12 , R 13 , R14 , and R 15 are the same or different and represent a hydrocarbon group having 1 to 16 carbon atoms (preferably a hydrocarbon group having 1 to 14 carbon atoms, more preferably a hydrocarbon group having 1 to 10 carbon atoms, even more preferably a hydrocarbon group having 1 to 8 carbon atoms, and particularly preferably a hydrocarbon group having 1 to 6 carbon atoms), which may contain a heteroatom. However, when X is a sulfur atom, R 12 does not exist.

[0093] The molecular weight of the cation in the ionic liquid is, for example, 500 or less, preferably 400 or less, more preferably 300 or less, even more preferably 250 or less, particularly preferably 200 or less, and most preferably 160 or less. It is usually 50 or more. It is believed that the cation in the ionic liquid has the property of migrating to the cathode side in the electrically releasing pressure-sensitive adhesive layer when a voltage is applied, and being biased toward the interface between the electrically releasing pressure-sensitive adhesive layer and the adherend. For this reason, in the present invention, the adhesive strength during voltage application decreases relative to the initial adhesive strength, resulting in electro-releasability. Cations with a small molecular weight, such as a molecular weight of 500 or less, are suitable for facilitating the migration of cations to the cathode side in the electrically releasing pressure-sensitive adhesive layer and increasing the rate of decrease in adhesive strength when a voltage is applied.

[0094] Examples of commercially available ionic liquids include "ELEXCEL AS-110," "ELEXCEL MP-442," "ELEXCEL IL-210," "ELEXCEL MP-471," "ELEXCEL MP-456," and "ELEXCEL AS-804" manufactured by Daiichi Kogyo Seiyaku Co., Ltd.; "HMI-FSI" manufactured by Mitsubishi Materials Corporation; and "CIL-312" and "CIL-313" manufactured by Nippon Carlit Co., Ltd.

[0095] The ionic conductivity is preferably 0.1 mS / cm or more and 10 mS / cm or less. The upper limit of the ionic conductivity is more preferably 5 mS / cm, even more preferably 3 mS / cm, and the lower limit is more preferably 0.3 mS / cm, even more preferably 0.5 mS / cm. By having an ionic conductivity within this range, the adhesive strength is sufficiently reduced even at a low voltage. The ionic conductivity can be measured by the AC impedance method, for example, using a Solartron 1260 frequency response analyzer.

[0096] The content (blending amount) of the ionic liquid in the pressure-sensitive adhesive composition of this embodiment is preferably 0.5 parts by mass or more relative to 100 parts by mass of the polymer from the viewpoint of reducing adhesive strength during voltage application, and preferably 30 parts by mass or less from the viewpoint of increasing initial adhesive strength. From the same viewpoint, it is more preferably 20 parts by mass or less, even more preferably 15 parts by mass or less, particularly preferably 10 parts by mass or less, and most preferably 5 parts by mass or less. Furthermore, it is more preferably 0.6 parts by mass or more, even more preferably 0.8 parts by mass or more, particularly preferably 1.0 part by mass or more, and most preferably 1.5 parts by mass or more.

[0097] (Other ingredients) The pressure-sensitive adhesive composition of the present embodiment may contain one or more components other than the polymer and the ionic liquid (hereinafter, sometimes referred to as "other components"), as needed, within a range that does not impair the effects of the present invention. Hereinafter, the other components that may be contained in the pressure-sensitive adhesive composition of the present embodiment will be described.

[0098] The pressure-sensitive adhesive composition of the present embodiment may contain an ionic additive. As the ionic additive, for example, an ionic solid can be used.

[0099] The ionic solid is an ionic substance that is solid at 25°C. The ionic solid is not particularly limited, but for example, a solid ionic substance obtained by combining an anion and a cation as exemplified in the section describing the ionic liquid above can be used. When the pressure-sensitive adhesive composition contains an ionic solid, the content of the ionic solid is preferably 0.5 parts by mass or more and 10 parts by mass or less per 100 parts by mass of the polymer.

[0100] The pressure-sensitive adhesive composition of the present embodiment may contain a crosslinking agent, if necessary, to improve creep and shear properties by crosslinking the polymer. Examples of crosslinking agents include isocyanate-based crosslinking agents, carbodiimide-based crosslinking agents, epoxy-based crosslinking agents, melamine-based crosslinking agents, peroxide-based crosslinking agents, urea-based crosslinking agents, metal alkoxide-based crosslinking agents, metal chelate-based crosslinking agents, metal salt-based crosslinking agents, oxazoline-based crosslinking agents, aziridine-based crosslinking agents, and amine-based crosslinking agents. Examples of isocyanate-based crosslinking agents include toluene diisocyanate and methylene bisphenyl isocyanate. Examples of epoxy-based crosslinking agents include N,N,N',N'-tetraglycidyl-m-xylylenediamine, diglycidylaniline, 1,3-bis(N,N-diglycidylaminomethyl)cyclohexane, and 1,6-hexanediol diglycidyl ether. When a crosslinking agent is contained, the content thereof is preferably 0.1 parts by mass or more and 50 parts by mass or less relative to 100 parts by mass of the polymer. The crosslinking agents may be used alone or in combination of two or more.

[0101] The pressure-sensitive adhesive composition of the present embodiment may contain polyethylene glycol, if necessary, to aid the movement of the ionic liquid when a voltage is applied. As the polyethylene glycol, one having a number average molecular weight of 200 to 6000 can be used. When polyethylene glycol is contained, the content is preferably 0.1 parts by mass or more and 30 parts by mass or less per 100 parts by mass of the polymer.

[0102] The pressure-sensitive adhesive composition of the present embodiment may contain a conductive filler, if necessary, for the purpose of imparting conductivity to the pressure-sensitive adhesive composition. The conductive filler is not particularly limited, and a commonly known or commonly used conductive filler can be used, such as graphite, carbon black, carbon fiber, or metal powder such as silver or copper. When a conductive filler is contained, the content thereof is preferably 0.1 parts by mass or more and 200 parts by mass or less relative to 100 parts by mass of the polymer.

[0103] The pressure-sensitive adhesive composition of the present embodiment may also contain various additives such as fillers, plasticizers, antioxidants, antioxidants, pigments (dyes), flame retardants, solvents, surfactants (leveling agents), rust inhibitors, adhesion-imparting resins, corrosion inhibitors, and antistatic agents. The total content of these components is not particularly limited as long as the effects of the present invention are achieved, but is preferably 0.01 parts by mass or more and 20 parts by mass or less, more preferably 10 parts by mass or less, and even more preferably 5 parts by mass or less, per 100 parts by mass of the polymer.

[0104] Examples of fillers include silica, iron oxide, zinc oxide, aluminum oxide, titanium oxide, barium oxide, magnesium oxide, calcium carbonate, magnesium carbonate, zinc carbonate, pyrophyllite clay, kaolin clay, and calcined clay. The plasticizer can be a known, commonly used plasticizer used in general resin compositions, etc., and examples thereof include oils such as paraffin oil and process oil; liquid rubbers such as liquid polyisoprene, liquid polybutadiene, and liquid ethylene-propylene rubber; tetrahydrophthalic acid, azelaic acid, benzoic acid, phthalic acid, trimellitic acid, pyromellitic acid, adipic acid, sebacic acid, fumaric acid, maleic acid, itaconic acid, citric acid, and derivatives thereof; dioctyl phthalate (DOP), dibutyl phthalate (DBP), dioctyl adipate, diisononyl adipate (DINA), and isodecyl succinate. Examples of antioxidants include hindered phenol compounds, and aliphatic and aromatic hindered amine compounds. Examples of antioxidants include butylhydroxytoluene (BHT) and butylhydroxyanisole (BHA). Examples of pigments include inorganic pigments such as titanium dioxide, zinc oxide, ultramarine, red iron oxide, lithopone, lead, cadmium, iron, cobalt, aluminum, hydrochlorides, and sulfates, and organic pigments such as azo pigments and copper phthalocyanine pigments. Examples of the rust inhibitor include zinc phosphate, tannic acid derivatives, phosphoric acid esters, basic sulfonates, and various rust-preventive pigments. Examples of adhesion promoters include titanium coupling agents and zirconium coupling agents. Examples of antistatic agents generally include quaternary ammonium salts, or hydrophilic compounds such as polyglycolic acid and ethylene oxide derivatives. Examples of tackifying resins include rosin-based tackifying resins, terpene-based tackifying resins, phenol-based tackifying resins, hydrocarbon-based tackifying resins, ketone-based tackifying resins, as well as polyamide-based tackifying resins, epoxy-based tackifying resins, and elastomer-based tackifying resins. These tackifying resins can be used alone or in combination of two or more. Examples of corrosion inhibitors include carbodiimide compounds, adsorption inhibitors, and chelating-type metal deactivators. For example, those described in JP 2019-059908 A can be used.

[0105] <Initial adhesive strength, adhesive strength decrease rate due to voltage application> The adhesive strength of the electrically peelable pressure-sensitive adhesive layer of this embodiment can be evaluated by various methods, for example, the 180° peel test described in the Examples section.

[0106] The electrically peelable pressure-sensitive adhesive layer of this embodiment is prepared by forming an electrically peelable pressure-sensitive adhesive sheet as described in the Examples section and conducting a 180° peel test. The initial adhesive strength of the electrically peelable pressure-sensitive adhesive layer is preferably 2.0 N / cm or more, more preferably 2.5 N / cm or more, and most preferably 3.0 N / cm or more. An initial adhesive strength of 3.0 N / cm or more ensures sufficient adhesion to the adherend, making it less likely for the adherend to peel off or slip.

[0107] The applied voltage is preferably 1 V or more, more preferably 3 V or more, more preferably 5 V or more, more preferably 6 V or more, and even more preferably 10 V or more. Also, it is preferably 500 V or less, more preferably 300 V or less, even more preferably 100 V or less, and particularly preferably 50 V or less. The voltage application time is preferably 300 seconds or less, more preferably 180 seconds or less, even more preferably 120 seconds or less, even more preferably 60 seconds or less, and particularly preferably 30 seconds or less. In such cases, workability is excellent. The shorter the application time, the better, but it is usually 1 second or more.

[0108] The pressure-sensitive adhesive composition according to an embodiment of the present invention is not particularly limited, but can be produced by appropriately stirring and mixing a polymer, an ionic liquid, an additive, and, if necessary, a crosslinking agent, polyethylene glycol, a conductive filler, and the like.

[0109] From the viewpoint of initial adhesive strength, the thickness of the electrically peeling pressure-sensitive adhesive layer 1 is preferably 1 μm or more and 1000 μm or less. The upper limit of the thickness of the electrically peeling pressure-sensitive adhesive layer 1 is more preferably 500 μm, even more preferably 300 μm, even more preferably 200 μm, even more preferably 150 μm, even more preferably 100 μm, even more preferably 80 μm, even more preferably 70 μm, even more preferably 60 μm, even more preferably 50 μm, and the lower limit is more preferably 5 μm, even more preferably 10 μm, even more preferably 20 μm, even more preferably 30 μm.

[0110] The thickness of the electrically peelable pressure-sensitive adhesive sheet of this embodiment is preferably 20 μm or more and 3000 μm or less. The upper limit of the thickness is more preferably 1000 μm, even more preferably 500 μm, even more preferably 300 μm, even more preferably 250 μm, even more preferably 200 μm, even more preferably 150 μm, and even more preferably 100 μm, and the lower limit is more preferably 30 μm, even more preferably 50 μm.

[0111] In particular, in the case of electrically peelable pressure-sensitive adhesive sheets X1 and X2 shown in Figures 1 and 2, the thickness of the electrically peelable pressure-sensitive adhesive sheet is preferably 50 μm or more and 2000 μm or less. The upper limit of the thickness is more preferably 1000 μm, even more preferably 500 μm, even more preferably 300 μm, even more preferably 250 μm, even more preferably 200 μm, and even more preferably 150 μm, and the lower limit is preferably 50 μm, more preferably 80 μm, and even more preferably 100 μm.

[0112] In particular, in the case of electrically peelable pressure-sensitive adhesive sheets X3, X4, and X5 shown in Figures 3 to 5, the thickness of the electrically peelable pressure-sensitive adhesive sheet is preferably 100 μm or more and 3000 μm or less. The upper limit of the thickness is more preferably 1000 μm, even more preferably 500 μm, even more preferably 300 μm, even more preferably 250 μm, even more preferably 200 μm, and even more preferably 150 μm, and the lower limit is more preferably 50 μm, even more preferably 80 μm, and even more preferably 100 μm.

[0113] The electrically releasing adhesive layer of the electrically releasing adhesive sheet of this embodiment, and the surface of the adhesive layer if any other adhesive layer is present, may be protected by a separator (release liner). Examples of separators include, but are not limited to, release liners in which the surface of a substrate (liner substrate) such as paper or plastic film is silicone-treated, and release liners in which the surface of a substrate (liner substrate) such as paper or plastic film is laminated with a polyolefin resin. The thickness of the separator is not particularly limited, but is preferably 10 μm or more, more preferably 20 μm or more, and even more preferably 30 μm or more, and preferably 100 μm or less, more preferably 80 μm or less, and even more preferably 50 μm or less.

[0114] (Method of manufacturing electrically peelable pressure-sensitive adhesive sheet) The electrically peelable pressure-sensitive adhesive sheet of this embodiment can be produced by any known or commonly used production method. The electrically releasing adhesive layer in the electrically releasing adhesive sheet of this embodiment can be formed by, for example, applying a solution of the adhesive composition of this embodiment, if necessary, in a solvent, onto a separator, followed by drying and / or curing. When providing another adhesive layer, the other adhesive layer can be formed by, for example, applying a solution of an adhesive composition that does not contain an ionic liquid or additives, if necessary, in a solvent, onto a separator, followed by drying and / or curing. The solvents and separators listed above can be used.

[0115] For application, a conventional coater (for example, a gravure roll coater, a reverse roll coater, a kiss roll coater, a dip roll coater, a bar coater, a knife coater, a spray roll coater, etc.) can be used.

[0116] The above method can be used to produce an electrically peelable pressure-sensitive adhesive layer and other pressure-sensitive adhesive layers, and the electrically peelable pressure-sensitive adhesive sheet of this embodiment can be produced by appropriately laminating a conductive substrate, a coating layer, an electrically peelable pressure-sensitive adhesive layer, and, if necessary, other pressure-sensitive adhesive layers. Instead of the separator, a coating layer may be used to apply the pressure-sensitive adhesive composition to form an electrically peelable pressure-sensitive adhesive layer.

[0117] (Method for electrically peeling off electrically peelable adhesive sheets) The electrically peelable pressure-sensitive adhesive sheet of this embodiment can be peeled from an adherend by applying a voltage to the electrically peelable pressure-sensitive adhesive layer to generate a potential difference in the thickness direction of the electrically peelable pressure-sensitive adhesive layer. For example, an assembly in which the electrically-releasable pressure-sensitive adhesive sheet X1 or X2 is attached to a conductive adherend can be peeled off by passing electricity through the conductive adherend and applying a voltage to the electrically-releasable pressure-sensitive adhesive layer. For example, in the case of electrically releasable pressure-sensitive adhesive sheets X3 to X5, they can be peeled from the adherend by passing electricity through both conductive layers and applying a voltage to the electrically releasable pressure-sensitive adhesive layer. The current is preferably applied by connecting terminals to one end and the other end of the electrically-releasable pressure-sensitive adhesive sheet so that a voltage is applied to the entire electrically-releasable pressure-sensitive adhesive layer. When the adherend has a metal surface, the one end and the other end may be part of the adherend having a metal surface. During peeling, water may be added to the interface between the conductive adherend surface and the electrically-releasable pressure-sensitive adhesive layer before applying a voltage.

[0118] (Applications of electrically peelable adhesive sheets) Conventional peeling technologies include adhesive layers that are hardened and peeled off by ultraviolet (UV) irradiation, and adhesive layers that are peeled off by heat. adhesive sheetHowever, it cannot be used in cases where ultraviolet (UV) irradiation is difficult or where heat damages the adherend member. The electrically peeling pressure-sensitive adhesive sheet of the present embodiment, which is provided with the electrically peeling pressure-sensitive adhesive layer, does not use ultraviolet light or heat, and therefore can be easily peeled off by applying a voltage without damaging the adherend member. Therefore, the electrically peeling pressure-sensitive adhesive sheet of the present embodiment is suitable for use in fixing secondary batteries (e.g., lithium-ion battery packs) used in mobile terminals such as smartphones, mobile phones, laptops, video cameras, and digital cameras to the housings.

[0119] Rigid members that can be bonded with the electrically peelable pressure-sensitive adhesive sheet of this embodiment include, for example, silicon substrates for semiconductor wafers, sapphire substrates for LEDs, SiC substrates and metal-based substrates, TFT substrates and color filter substrates for displays, and base substrates for organic EL panels. Fragile members that can be bonded with the double-sided electrically peelable pressure-sensitive adhesive sheet include, for example, semiconductor substrates such as compound semiconductor substrates, silicon substrates for MEMS devices, passive matrix substrates, surface cover glass for smartphones, OGS (One Glass Solution) substrates in which a touch panel sensor is attached to the cover glass, organic substrates and organic-inorganic hybrid substrates mainly composed of silsesquioxane, flexible glass substrates for flexible displays, and graphene sheets.

[0120] [zygote] The bonded body according to an embodiment of the present invention comprises an electrically peelable pressure-sensitive adhesive sheet according to an embodiment of the present invention and a conductive material, and the electrically peelable pressure-sensitive adhesive layer of the electrically peelable pressure-sensitive adhesive sheet is adhered to the conductive material. The conductive material is preferably an adherend having a metal surface, and examples of adherends having a metal surface include those made of metals whose main components are aluminum, copper, iron, magnesium, tin, gold, silver, and lead, and among these, metals containing aluminum are preferred.

[0121] Examples of the bonded body of this embodiment include an electrically peelable adhesive sheet X1 and a bonded body in which the electrically peelable adhesive layer 1 side of the electrically peelable adhesive sheet X1 is attached to a conductive adherend having, for example, a metal adherend surface.

[0122] In the case where the electrically releasing pressure-sensitive adhesive sheet according to the embodiment of the present invention further comprises another pressure-sensitive adhesive layer, a second conductive substrate, and a second other pressure-sensitive adhesive layer, the other pressure-sensitive adhesive layer being formed on the surface of the support substrate opposite the conductive layer, the second conductive substrate and the second other pressure-sensitive adhesive layer being formed in this order on the surface of the electrically releasing pressure-sensitive adhesive layer opposite the coating layer, and the electrically releasing pressure-sensitive adhesive layer and the second conductive substrate are in contact, another aspect of the joined body according to the embodiment of the present invention is a joined body comprising the electrically releasing pressure-sensitive adhesive sheet according to the embodiment of the present invention and an adherend material, and the other pressure-sensitive adhesive layer is attached to the adherend material. The adherend material is selected from conductive materials and non-conductive materials.

[0123] Examples of the bonded body of this embodiment include a bonded body in which the other adhesive layer 6 on both sides of the electrically peeling adhesive sheet X3 is adhered to a conductive material having, for example, a metal coating surface, and a bonded body in which any of the other adhesive layers 6 in the electrically peeling adhesive sheet X3 is adhered to a non-conductive material. [Example]

[0124] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples. The weight-average molecular weights shown below were measured by gel permeation chromatography (GPC) using the method described above.

[0125] (Preparation of acrylic polymer 1 solution) Monomer components, including 87 parts by mass of n-butyl acrylate (BA), 10 parts by mass of 2-methoxyethyl acrylate (MEA), and 3 parts by mass of acrylic acid (AA), and 150 parts by mass of ethyl acetate as a polymerization solvent, were placed in a separable flask and stirred for 1 hour while introducing nitrogen gas. After removing oxygen from the polymerization system in this manner, 0.2 parts by mass of 2,2'-azobisisobutyronitrile (AIBN) was added as a polymerization initiator, and the mixture was heated to 63°C and reacted for 6 hours. Ethyl acetate was then added to obtain an acrylic polymer 1 solution with a solids concentration of 30% by mass. The weight-average molecular weight of the resulting acrylic polymer 1 was 700,000.

[0126] (Preparation of acrylic polymer 2 solution) Monomer components, 95 parts by mass of n-butyl acrylate (BA), 5 parts by mass of acrylic acid (AA), and 150 parts by mass of ethyl acetate as a polymerization solvent were placed in a separable flask and stirred for 1 hour while introducing nitrogen gas. After removing oxygen from the polymerization system in this way, 0.2 parts by mass of 2,2'-azobisisobutyronitrile (AIBN) was added as a polymerization initiator, and the mixture was heated to 63°C and reacted for 6 hours. Ethyl acetate was then added to obtain an acrylic polymer 2 solution with a solids concentration of 30% by mass. The weight-average molecular weight of the resulting acrylic polymer 2 was 650,000.

[0127] [Examples 1 to 7] (Preparation of Electrically Peelable Adhesive Layer) The acrylic polymer (solution), crosslinking agent, ionic liquid, additives (adsorption inhibitor, chelating-type metal deactivator), and ethyl acetate obtained above were added and stirred and mixed to obtain each electro-peelable pressure-sensitive adhesive composition (solution) adjusted to a solids concentration of 25% by mass.

[0128] Tables 1 and 3 show the amounts of each component. The values ​​of each component in Tables 1 and 3 below are in parts by mass. The same applies to Tables 2 and 4. The obtained electrically peelable pressure-sensitive adhesive composition (solution) was applied to a uniform thickness using an applicator onto the release-treated surface of a polyethylene terephthalate separator (trade name "MRF38", manufactured by Mitsubishi Plastics, Inc.). Next, the coating was dried by heating at 150°C for 3 minutes, and the release-treated surface of the polyethylene terephthalate separator (trade name "MRE38", manufactured by Mitsubishi Plastics, Inc.) was laminated onto the pressure-sensitive adhesive using a hand roller to obtain a 50 μm-thick electrically peelable pressure-sensitive adhesive layer.

[0129] The abbreviations for the ionic liquids, crosslinkers, adsorptive inhibitors, and chelating-type metal deactivators in Tables 1 and 3 are as follows. The same applies to Tables 2 and 4.

[0130] (ionic liquid) AS-110: Cation: 1-ethyl-3-methylimidazolium cation, Anion: bis(fluorosulfonyl)imide anion, trade name "Elexcel AS-110", manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd. (Crosslinking agent) V-05: Polycarbodiimide resin, product name "Carbodilite V-05", manufactured by Nisshinbo Chemical Inc. (adsorption inhibitor) AMINE O: 2-(8-heptadecen-1-yl)-4,5-dihydro-1H-imidazole-1-ethanol, trade name "AMINE O", manufactured by BASF Japan Ltd. Irgacor DSSG: Sodium sebacate, product name "Irgacor DSSG", manufactured by BASF Japan Ltd. (Chelate-forming metal deactivator) Irgamet 30: N,N-bis(2-ethylhexyl)-[(1,2,4-triazol-1-yl)methyl]amine, product name "Irgamet 30", manufactured by BASF Japan Ltd.

[0131] (Preparation of single-sided electrically peelable adhesive sheet) The polyethylene terephthalate separator (MRE38) from the obtained electrically peelable adhesive layer was peeled off, and the coating layer side of a metal layer-attached film (conductive substrate) (product name "1005CR", manufactured by Toray Advanced Film Co., Ltd., thickness 12 μm), which is a laminate (laminate 8) consisting of a coating layer, a conductive layer (metal layer), and a supporting substrate laminated in that order, was bonded to the surface of the exposed electrically peelable adhesive layer to form a single-sided electrically peelable adhesive sheet.

[0132] (Preparation of three-layer electrically peelable double-sided adhesive sheet) The polyethylene terephthalate separator (MRE38) was peeled off from each electrically releasing pressure-sensitive adhesive layer (adhesive sheet) prepared in the same manner as above, and the coating layer side of a metal layer-attached film (product name "1005CR", manufactured by Toray Advanced Film Co., Ltd., thickness 12 μm), which is a laminate consisting of a coating layer, a conductive layer (metal layer), and a support substrate laminated in that order, was attached to the surface of the exposed electrically releasing pressure-sensitive adhesive layer to produce a single-sided electrically releasing pressure-sensitive adhesive sheet. Furthermore, double-sided tape (product name "No. 56405", manufactured by Nitto Denko Corporation) was attached to the surface of the single-sided electrically releasing pressure-sensitive adhesive sheet facing the support substrate to produce a three-layer electrically releasing double-sided pressure-sensitive adhesive sheet in which one side was the electrically releasing pressure-sensitive adhesive layer and the other side was the other pressure-sensitive adhesive layer.

[0133] (Preparation of 5-layer electrically peelable double-sided adhesive sheet) The polyethylene terephthalate separator (MRF38) was peeled off from a three-layer electrically peeling double-sided pressure-sensitive adhesive sheet prepared in the same manner as above, and the conductive layer side of a metal layer-attached film (product name "Metal Me 25S", manufactured by Toray Industries, Inc., thickness 25 μm), which is a laminate consisting of a conductive layer (metal layer) and a supporting substrate laminated in that order, was bonded to the surface of the exposed electrically peeling pressure-sensitive adhesive layer.Furthermore, double-sided tape (product name "No. 56405", manufactured by Nitto Denko Corporation) was bonded to the surface facing the supporting substrate, resulting in a five-layer electrically peeling double-sided pressure-sensitive adhesive sheet in which both sides contain other pressure-sensitive adhesive layers.

[0134] (Preparation of junction 1) The separator (MRF38) was peeled off from the three-layer electrically peeling double-sided pressure-sensitive adhesive sheet obtained above, and a stainless steel plate (SUS316, size: 30 mm x 120 mm) was attached to the peeled surface as a conductive adherend so that one end of the double-sided pressure-sensitive adhesive sheet protruded from the adherend by about 2 mm. The sheet was then pressed back and forth once with a 2 kg roller and left to stand in an environment of 23°C for 30 minutes, thereby obtaining the joints 1 of Examples 1 to 7 in which the electrically peeling adhesive layer 1 of the electrically peeling pressure-sensitive adhesive sheet was adhered to the conductive adherend (conductive adherend 7).

[0135] (Preparation of junction 2) The five-layer electrically peelable double-sided adhesive sheet obtained above Separator The double-sided adhesive sheet was peeled off, and an acrylic plate (size: 30 mm × 120 mm) was attached to the peeled surface as adherend 2 so that one end of the double-sided adhesive sheet protruded from the adherend by about 2 mm, and pressed back and forth once with a 2 kg roller. The resulting mixture was left in an environment of 23°C for 30 minutes, yielding joined bodies 2 of Examples 1 to 7 in which the other adhesive layer of the five-layer electrically peelable double-sided adhesive sheet was attached to adherend 2.

[0136] [Example 8] (Preparation of single-sided electrically peelable adhesive sheet) An electrically peelable pressure-sensitive adhesive layer was prepared in the same manner as above using an electrically peelable pressure-sensitive adhesive composition (solution, solids concentration 25% by mass) having the composition shown in Tables 1 and 3. Furthermore, a 50 μm thick film with a metal layer (product name "Metal Me TS" manufactured by Toray Industries, Inc.) was laminated with a conductive layer (metal layer) and a support substrate in that order. A polyester resin solution with a solids concentration of 5% by mass, obtained by stirring and mixing 5 parts by mass of a polyester resin (product name "Elitel UE9200" manufactured by Unitika Ltd.) and 95 parts by mass of ethyl acetate, was applied to the metal layer side using a wire bar to a uniform thickness, thereby laminating a 100 nm thick coating layer. The polyethylene terephthalate separator (MRE38) from the obtained electrically peelable pressure-sensitive adhesive layer was peeled off, and the coating layer side of the metal layer-containing film with the coating layer laminated thereon was attached to the exposed surface of the electrically peelable pressure-sensitive adhesive layer, thereby producing a single-sided electrically peelable pressure-sensitive adhesive sheet.

[0137] (Preparation of three-layer electrically peelable double-sided adhesive sheet) An electrically peelable pressure-sensitive adhesive layer was prepared in the same manner as above using an electrically peelable pressure-sensitive adhesive composition (solution, solid content concentration 25% by mass) having the composition shown in Tables 1 and 3. A metal layer-attached film (product name "Metal Me TS" manufactured by Toray Industries, Inc., thickness 50 μm) is a laminate in which a conductive layer (metal layer) and a supporting substrate are laminated in this order. 5 parts by mass of polyester resin (product name "Elitel UE9200" manufactured by Unitika Co., Ltd.) and 95 parts by mass of ethyl acetate are applied to the metal layer side of the film. of The polyester resin solution having a solid content concentration of 5% by mass obtained by stirring and mixing was applied to a uniform thickness using a wire bar to form a coating layer having a thickness of 100 nm. The polyethylene terephthalate separator (MRE38) from the obtained electrically peelable adhesive layer was peeled off, and the coated layer side of the metal layered film with a coated layer laminated thereon was attached to the surface of the exposed electrically peelable adhesive to form a single-sided electrically peelable adhesive sheet. Furthermore, a double-sided tape (product name "No. 56405", manufactured by Nitto Denko Corporation) was attached to the surface of the single-sided electrically peeling adhesive sheet facing the support substrate, to form a three-layer electrically peeling double-sided adhesive sheet in which one surface was an electrically peeling adhesive layer and the other surface was another adhesive layer.

[0138] (Preparation of 5-layer electrically peelable double-sided adhesive sheet) The polyethylene terephthalate separator (MRF38) was peeled off from a three-layer electrically peeling double-sided pressure-sensitive adhesive sheet prepared in the same manner as above, and the conductive layer side of a metal layer-attached film (product name "Metal Me 25S", manufactured by Toray Industries, Inc., thickness 25 μm), which is a laminate consisting of a conductive layer (metal layer) and a supporting substrate laminated in that order, was bonded to the surface of the exposed electrically peeling pressure-sensitive adhesive layer.Furthermore, double-sided tape (product name "No. 56405", manufactured by Nitto Denko Corporation) was bonded to the surface facing the supporting substrate, resulting in a five-layer electrically peeling double-sided pressure-sensitive adhesive sheet in which both sides contain other pressure-sensitive adhesive layers.

[0139] (Preparation of junction 1) The separator (MRF38) was peeled off from the three-layer electrically peeling double-sided pressure-sensitive adhesive sheet obtained above, and a stainless steel plate (SUS316, size: 30 mm × 120 mm) was attached to the peeled surface as a conductive adherend 1 so that one end of the double-sided pressure-sensitive adhesive sheet protruded from the adherend by about 2 mm. The sheet was then pressed back and forth once with a 2 kg roller and left to stand in an environment of 23°C for 30 minutes, yielding a joint 1 of Example 8 in which the electrically peeling adhesive layer 1 of the electrically peeling pressure-sensitive adhesive sheet was attached to the conductive adherend 1 (conductive adherend 7 in Figure 6).

[0140] (Preparation of junction 2) The five-layer electrically peelable double-sided adhesive sheet obtained above Separator The double-sided pressure-sensitive adhesive sheet was peeled off, and an acrylic plate (size: 30 mm × 120 mm) was attached to the peeled surface as adherend 2 so that one end of the double-sided pressure-sensitive adhesive sheet protruded from the adherend by about 2 mm, and the sheet was pressed back and forth once with a 2 kg roller and left to stand in an environment of 23°C for 30 minutes, thereby obtaining a bonded body 2 of Example 8 in which the other pressure-sensitive adhesive layer of the five-layer electrically peelable double-sided pressure-sensitive adhesive sheet was attached to adherend 2.

[0141] [Example 9] A single-sided electrically peeling pressure-sensitive adhesive sheet, a three-layer electrically peeling double-sided pressure-sensitive adhesive sheet, a five-layer electrically peeling double-sided pressure-sensitive adhesive sheet, and assemblies 1 and 2 of Example 9 were obtained in the same manner as in Example 8, except that the thickness of the coating layer was changed to 200 nm.

[0142] [Example 10] A single-sided electrically peeling pressure-sensitive adhesive sheet, a three-layer electrically peeling double-sided pressure-sensitive adhesive sheet, a five-layer electrically peeling double-sided pressure-sensitive adhesive sheet, and assemblies 1 and 2 of Example 10 were obtained in the same manner as in Example 8, except that the thickness of the coating layer was changed to 300 nm.

[0143] [Example 11] The single-sided electrically peeling adhesive sheet, three-layer electrically peeling double-sided adhesive sheet, five-layer electrically peeling double-sided adhesive sheet and assemblies 1 and 2 of Example 11 were obtained in the same manner as Example 9, except that the metal layer-equipped film used to prepare the single-sided electrically peeling adhesive sheet was changed to a metal layer-equipped film (product name "ML PET", manufactured by Mitsui Chemicals, Inc., thickness 12 μm) which is a laminate consisting of a conductive layer (metal layer) and a supporting substrate laminated in that order.

[0144] [Example 12] The single-sided electrically peeling adhesive sheet, three-layer electrically peeling double-sided adhesive sheet, five-layer electrically peeling double-sided adhesive sheet, and assemblies 1 and 2 of Example 12 were obtained in the same manner as Example 9, except that the metal layer-equipped film used to prepare the single-sided electrically peeling adhesive sheet was changed to a metal layer-equipped film (product name "ML PET-C", manufactured by Mitsui Chemicals, Inc., thickness 12 μm) which is a laminate consisting of a conductive layer (metal layer) and a supporting substrate laminated in that order.

[0145] [Example 13] The single-sided electrically peeling pressure-sensitive adhesive sheet, three-layer electrically peeling double-sided pressure-sensitive adhesive sheet, five-layer electrically peeling double-sided pressure-sensitive adhesive sheet and assemblies 1 and 2 of Example 13 were obtained in the same manner as in Example 1, except that the metal layer-equipped film used to prepare the single-sided electrically peeling pressure-sensitive adhesive sheet was changed to a metal layer-equipped film (product name "DMS(X42)PC", manufactured by Toray Industries, Inc., thickness 50 μm) which is a laminate comprising a coating layer, a conductive layer (metal layer), and a supporting substrate laminated in that order.

[0146] [Example 14] The single-sided electrically peeling pressure-sensitive adhesive sheet, three-layer electrically peeling double-sided pressure-sensitive adhesive sheet, five-layer electrically peeling double-sided pressure-sensitive adhesive sheet, and assemblies 1 and 2 of Example 14 were obtained in the same manner as in Example 9, except that the resin used in the coating layer was an acrylic resin (product name "ARUFON UH-2170", manufactured by Toagosei Co., Ltd.).

[0147] [Example 15] The single-sided electrically peeling pressure-sensitive adhesive sheet, three-layer electrically peeling double-sided pressure-sensitive adhesive sheet, five-layer electrically peeling double-sided pressure-sensitive adhesive sheet and assemblies 1 and 2 of Example 15 were obtained in the same manner as Example 9, except that the metal layer-equipped film used to prepare the single-sided electrically peeling pressure-sensitive adhesive sheet was changed to a metal layer-equipped film (product name "AL-PET", manufactured by Panac Corporation, thickness 50 μm) which is a laminate consisting of a conductive layer (metal layer) and a supporting substrate laminated in that order.

[0148] [Example 16] A metal layered film (product name "Metal Me TS", manufactured by Toray Advanced Film Co., Ltd., thickness 50 μm) was prepared, which is a laminate consisting of a conductive layer (metal layer (aluminum vapor deposition layer)) and a supporting substrate (polyethylene terephthalate (PET)) laminated in this order. Next, a Si target (AC: 40 kHz) was attached to an AC sputtering device, and sputtering was performed while introducing O2 gas and N2 gas to form a 50 nm inorganic coating layer (SiNx layer) on the metal layer of the metal-layered film, producing substrate A. The temperature of the metal-layered film was set to -8°C when forming the SiNx layer. A single-sided electrically releasing pressure-sensitive adhesive sheet, a three-layer electrically releasing double-sided pressure-sensitive adhesive sheet, a five-layer electrically releasing double-sided pressure-sensitive adhesive sheet, and Assemblies 1 and 2 of Example 16 were obtained in the same manner as in Example 1, except that the metal layer-equipped film used in producing the single-sided electrically releasing pressure-sensitive adhesive sheet was changed to Substrate A. The results of Example 16 are shown in Tables 2 and 4.

[0149] [Example 17] A metal layered film (product name "Metal Me TS", manufactured by Toray Advanced Film Co., Ltd., thickness 50 μm) was prepared, which is a laminate consisting of a conductive layer (metal layer (aluminum vapor deposition layer)) and a supporting substrate (polyethylene terephthalate (PET)) laminated in this order. Next, a nickel (Ni) target was attached to an AC sputtering device (AC: 40 kHz), and sputtering was performed while introducing Ar gas to form a 100 nm thick metal layer (Ni layer) on the metal layer of the metal layer-coated film, thereby producing substrate B. The temperature of the metal layer-coated film during the formation of the Ni layer was set to -8°C. A single-sided electrically peeling pressure-sensitive adhesive sheet, a three-layer electrically peeling double-sided pressure-sensitive adhesive sheet, a five-layer electrically peeling double-sided pressure-sensitive adhesive sheet, and Assemblies 1 and 2 of Example 17 were obtained in the same manner as Example 16, except that substrate A was changed to substrate B. The results of Example 17 are shown in Tables 2 and 4.

[0150] [Comparative Examples 1 to 7] An electrically peeling pressure-sensitive adhesive layer was prepared in the same manner as above using an electrically peeling pressure-sensitive adhesive composition (solution, solids concentration 25% by mass) having the composition shown in Tables 1 and 3, and the metal layer-attached film used above was replaced with a metal layer-attached film (product name "Metal Me TS", manufactured by Toray Industries, Inc., thickness 50 μm) which is a laminate comprising a conductive layer (metal layer) and a supporting substrate laminated in this order, and the metal layer side of the metal layer-attached film was attached to the exposed surface of the electrically peeling pressure-sensitive adhesive. Single-sided electrically peeling pressure-sensitive adhesive sheets, a three-layer electrically peeling double-sided pressure-sensitive adhesive sheet, a five-layer electrically peeling double-sided pressure-sensitive adhesive sheet and Assemblies 1 and 2 of Comparative Examples 1 to 7 were obtained in the same manner as in Examples 1 to 7, except that

[0151] [Comparative Example 8] The single-sided electrically releasing adhesive sheet, a three-layer electrically releasing double-sided adhesive sheet, a five-layer electrically releasing double-sided adhesive sheet and assemblies 1 and 2 of Comparative Example 8 were obtained in the same manner as in Example 8, except that the metal layer-equipped film used to prepare the single-sided electrically releasing adhesive sheet was changed to a metal layer-equipped film (product name "ML PET", manufactured by Mitsui Chemicals, Inc., thickness 12 μm) which is a laminate consisting of a conductive layer (metal layer) and a supporting substrate laminated in that order, and the metal layer side of the metal layer-equipped film was bonded to the surface of the electrically releasing adhesive layer without providing a coating layer to form a single-sided electrically releasing adhesive sheet.

[0152] Comparative Example 9 The single-sided electrically releasing adhesive sheet, a three-layer electrically releasing double-sided adhesive sheet, a five-layer electrically releasing double-sided adhesive sheet and assemblies 1 and 2 of Comparative Example 8 were obtained in the same manner as in Example 8, except that the metal layer-equipped film used to prepare the single-sided electrically releasing adhesive sheet was changed to a metal layer-equipped film (product name "ML PET-C", manufactured by Mitsui Chemicals, Inc., thickness 12 μm) which is a laminate consisting of a conductive layer (metal layer) and a supporting substrate laminated in that order, and the metal layer side of the metal layer-equipped film was bonded to the surface of the electrically releasing adhesive layer without providing a coating layer to form a single-sided electrically releasing adhesive sheet.

[0153] [Comparative Example 10] The single-sided electrically releasing adhesive sheet, a three-layer electrically releasing double-sided adhesive sheet, a five-layer electrically releasing double-sided adhesive sheet and assemblies 1 and 2 of Comparative Example 10 were obtained in the same manner as in Example 8, except that the metal layer-equipped film used to prepare the single-sided electrically releasing adhesive sheet was changed to a metal layer-equipped film (product name "AL-PET", manufactured by Panac Corporation, thickness 50 μm) which is a laminate consisting of a conductive layer (metal layer) and a supporting substrate laminated in that order, and the metal layer side of the metal layer-equipped film was bonded to the surface of the electrically releasing adhesive layer without providing a coating layer to form a single-sided electrically releasing adhesive sheet.

[0154] (Adhesive strength) Examples 1 to 13, 16, and 17 and Comparative Examples 1 to 9 were evaluated. The bonded body 1 thus produced was peeled in the direction of the arrow in FIG. 6 using a peel tester (product name "Variable Angle Peel Tester YSP", manufactured by Asahi Seiko Co., Ltd.). Direction The adhesive strength was measured in a 180° peel test (pulling speed: 300 mm / min, peeling temperature: 23°C). The bonded body 2 was peeled off from the electrically peelable pressure-sensitive adhesive layer 1, and the adhesive strength was measured.

[0155] (Electrical peeling force (initial)) Before peeling, the DC current machine was applied to the α and β points of the joint 1 in Figure 6. Positive and negative poles The electrodes were attached to the test piece, and the voltages shown in Tables 1 and 2 were applied while the test piece was rotated in the direction of the arrows in Figure 6. DirectionThe electrical peeling force (initial) was measured in the same manner as in the above adhesive strength measurement, except that the adhesive strength was peeled off. For the bonded body 2, the negative and positive electrodes of a DC current machine were attached to the two conductive layers of the bonded body 2, respectively, and the bonded body 2 was peeled from the electrically releasing pressure-sensitive adhesive layer 1 while applying the voltages shown in Tables 1 and 2, and the initial electrical peeling force was measured.

[0156] (Electric peeling force (60℃ / 90%RH 24hr)) The above-mentioned bonded structures 1 and 2 were stored in a thermo-hygrostat at 60°C and 90% RH for 24 hours, and after removal, were left to stand at 22°C and 50% RH for 30 minutes to cool down. Thereafter, the electrical peel strength (60 / 90 24 hours) was measured in the same manner as in the adhesive strength measurement described above.

[0157] When measuring the electrical peeling force, the surface after peeling was checked on the adherend 1 side for Joint 1, and on the adherend 2 side for Joint 2. When vapor deposition peeling occurred, with the electrically peeling-type pressure-sensitive adhesive layer and the metal layer peeling from the support substrate remaining on the adherend surface, it was evaluated as "vapor deposition peeling."

[0158] The results obtained are shown in Tables 1 and 2.

[0159] [Table 1] [Table 2]

[0160] The results in Tables 1 and 2 show that in Comparative Examples 1 to 9, which do not have a coating layer, when an electrically-release pressure-sensitive adhesive sheet was attached to a conductive adherend and placed in a high-temperature, high-humidity environment, attempting to electrically peel the sheet caused the conductive layer (metal layer) to peel off from the support substrate (Comparative Examples 1 to 9). This peeling of the metal layer is thought to be caused by the ionic liquid contained in the electrically-release pressure-sensitive adhesive layer passing through the metal layer when voltage is applied, affecting the interaction between the metal layer and the support substrate and weakening the bonding strength. Comparative Examples 1 to 9 did not peel off at the intended interface, indicating that they did not function as electrically-release pressure-sensitive adhesive sheets.

[0161] (Accelerated heating test (storage conditions)) Bonded structures prepared in the same manner as in Examples 1, 7 to 17 and Comparative Examples 1, 7 to 10 were stored in a thermo-hygrostat at 85°C for 800 hours. After removal, they were allowed to stand at 22°C and 50% RH for 30 minutes to cool. Thereafter, the adhesive strength (85°C, 800 hours) was measured in the same manner as in the adhesive strength measurement described above. When measuring adhesive strength, the adherend surface was observed. When the adherend surface was exposed, the peeling mode was evaluated as "adherend interface." When the electrically peelable pressure-sensitive adhesive layer was transferred to the adherend surface, the peeling mode was evaluated as "peeling from the substrate." Regarding reliability, "adherend interface" was evaluated as ◯ (pass) and "peeling from substrate" was evaluated as × (fail). The results obtained are shown in Tables 3 and 4.

[0162] [Table 3] [Table 4]

[0163] Table 3 and 4 From the results, Comparative Examples 1, 7 to 10, which do not have a coating layer, When an electrically peelable pressure-sensitive adhesive sheet is attached to a conductive adherend and placed in a high-temperature environment, the electrically peelable pressure-sensitive adhesive layer that constitutes the electrically peelable pressure-sensitive adhesive sheet and the conductive Base materialThe interfacial adhesive strength with the material was reduced, resulting in a decrease in the adhesive reliability of the material (Comparative Examples 1 and 7). ~10 This deterioration in adhesive reliability is due to the thermal hardening of the electrically peelable adhesive layer, which causes the electrically peelable adhesive layer to separate from the conductive adhesive. Base material This is thought to be due to a decrease in the interfacial adhesive strength with the electrically peelable adhesive sheet, causing it to peel off within the sheet.

[0164] (Voltage control test) For the bonded bodies 1 produced in Examples 1, 8 to 10, 13 to 17, and Comparative Examples 1, 8 to 10, a voltage was applied in increments of 10 V up to 50 V in the same manner as in the above-mentioned electrical peeling force measurement. The application time was in increments of 10 seconds, and the operable range was evaluated. When the electric peeling force was 2 N / cm or less, the peeling performance was evaluated as OK, and when the electric peeling force was more than 2 N / cm, the peeling performance was not evaluated as NG. The results obtained for Examples 1, 8 to 10, 13 to 17, and Comparative Example 1 are shown in Figures 7 to 11. The numerical values ​​in Figures 7 to 11 are measured values. The results obtained for Comparative Examples 8 to 10 were similar to those of Comparative Example 1. Furthermore, the same results as those of the bonded body 1 were obtained for the bonded body 2. Those that could control the conditions for manifesting peeling performance by changing the voltage and application time within the measurement range were evaluated as ◯ (pass), and those that could not be controlled were evaluated as × (fail). As a result, Example 1 was evaluated as ◯ because the conditions for manifesting peeling performance could be controlled by lengthening the application time or increasing the applied voltage, changing from NG to OK, while Comparative Examples 1 and 8 to 10 were evaluated as × because the conditions for manifesting peeling performance could not be controlled and all application times and applied voltages were OK.

[0165] The results of FIGS. 7 to 11 show that for the bonded bodies 1 of Examples 1, 8 to 10, and 13 to 17, the conditions for exhibiting peeling performance can be controlled by changing the voltage and application time within the measurement range. Electrically peelable pressure-sensitive adhesive sheets are used in a variety of situations, and the target operating voltage often differs depending on the customer. However, it has been found that the bonded body according to an embodiment of the present invention, by providing a coating layer, makes it possible to control the conditions under which the desired peel performance is achieved by varying the voltage and application time. [Industrial Applicability]

[0166] According to the present invention, an electrically releasing adhesive sheet and an assembly are provided that suppress peeling of the conductive layer from the supporting substrate in a high-temperature, high-humidity environment; an electrically releasing adhesive sheet and an assembly are provided that prevent a decrease in the adhesive strength between the electrically releasing adhesive layer that constitutes the electrically releasing adhesive sheet and the conductive substrate in a high-temperature environment, and as a result, can suppress a decrease in the adhesive strength of the electrically releasing adhesive sheet; and an electrically releasing adhesive sheet and an assembly are provided that, by laminating a coating layer on the conductive layer, allow control of the conditions such as the applied voltage and application time at which the release performance is expressed according to the purpose.

[0167] Although the present invention has been described in detail and with reference to specific embodiments, it will be apparent to those skilled in the art that various changes and modifications can be made without departing from the spirit and scope of the invention. This application is based on a Japanese patent application filed on August 7, 2020 (Patent Application No. 2020-135065) and a Japanese patent application filed on February 5, 2021 (Patent Application No. 2021-017545), the contents of which are incorporated herein by reference. [Explanation of symbols]

[0168] X1, X2, X3, X4, X5 Electric peeling adhesive sheet 1 Electrically peelable adhesive layer 2 Coating Layer 3 Conductive layer 4 Supporting base material 5 Conductive base material 6 Other adhesive layers 7 Conductive adherend 8 Laminate

Claims

1. a conductive substrate including a supporting substrate and a conductive layer; A coating layer; an electrically peelable pressure-sensitive adhesive layer whose adhesive strength decreases upon application of a voltage, the coating layer is formed on a surface of the conductive layer opposite to the supporting substrate, the electrically releasable pressure-sensitive adhesive layer and the coating layer are in contact with each other, The coating layer contains at least one resin selected from polyester-based resins, acrylic-based resins, epoxy-based resins, and urethane-based resins, or at least one inorganic material selected from SiNx, SiOx, Al2O3, Ni, and NiCr. Electrically peelable adhesive sheet.

2. The electrically peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the electrically peelable pressure-sensitive adhesive layer contains a polymer and an ionic liquid.

3. The electrically peelable pressure-sensitive adhesive sheet according to claim 2 , wherein the content of the ionic liquid is 0.5 parts by mass or more and 30 parts by mass or less relative to 100 parts by mass of the polymer.

4. 4. The electrically peelable pressure-sensitive adhesive sheet according to claim 2, wherein the anion of the ionic liquid is at least one selected from the group consisting of a bis(fluorosulfonyl)imide anion and / or a bis(trifluoromethanesulfonyl)imide anion.

5. The electrically peelable pressure-sensitive adhesive sheet according to any one of claims 2 to 4, wherein the cation of the ionic liquid is at least one selected from the group consisting of a nitrogen-containing onium cation, a sulfur-containing onium cation, and a phosphorus-containing onium cation.

6. Further, another adhesive layer is provided, The electrically peelable pressure-sensitive adhesive sheet according to any one of claims 1 to 5, wherein the other pressure-sensitive adhesive layer is formed on the surface of the supporting substrate opposite to the conductive layer.

7. further comprising another pressure-sensitive adhesive layer, a second conductive layer, and a second other pressure-sensitive adhesive layer; the other pressure-sensitive adhesive layer is formed on the surface of the supporting substrate opposite to the conductive layer, the second conductive layer and a second other pressure-sensitive adhesive layer are formed in this order on a surface of the electrically releasing pressure-sensitive adhesive layer opposite to the coating layer; The electrically peeling pressure-sensitive adhesive sheet according to any one of claims 1 to 5, wherein the electrically peeling pressure-sensitive adhesive layer and the second conductive layer are in contact with each other. However, a second coating layer may be provided between the electrically releasable pressure-sensitive adhesive layer and the second conductive layer so as to be in contact with the electrically releasable pressure-sensitive adhesive layer.

8. An electrically peelable pressure-sensitive adhesive sheet according to any one of claims 1 to 7 and a conductive material, A bonded body in which the electrically peelable pressure-sensitive adhesive layer is adhered to the conductive material.

9. A method for manufacturing a sheet comprising the electrically peelable pressure-sensitive adhesive sheet according to claim 7 and an adherend material, A bonded body in which the other pressure-sensitive adhesive layer is attached to the adherend material.

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