Gel polymer electrolyte and lithium secondary battery comprising same

The gel polymer electrolyte with a crosslinked polymer and fluorinated linear alkyl phosphate compound addresses lithium dendrite growth and flammable electrolyte issues, enhancing battery safety and performance.

WO2026111116A1PCT designated stage Publication Date: 2026-05-28SAMSUNG SDI CO LTD
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Patent Information

Application Number
PCT/KR2025/013547
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-11-20
Filing Date
2025-09-03
Publication Date
2026-05-28

AI Technical Summary

Technical Problem

Lithium-ion rechargeable batteries face limitations in energy density and safety due to lithium dendrite growth and flammable electrolytes, leading to safety issues and reduced lifespan.

Method used

A gel polymer electrolyte comprising a crosslinked polymer, fluorinated linear alkyl phosphate compound, and lithium salt is used, which forms a stable SEI film, enhancing safety and ionic conductivity.

Benefits of technology

The gel polymer electrolyte improves battery safety, capacity retention, and lifespan by preventing dendrite growth and extinguishing combustion reactions.

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Abstract

According to an embodiment of the present disclosure, aiming to resolve a technical problem, this gel polymer electrolyte comprises a crosslinked polymer, a fluorinated linear alkyl phosphate compound, a lithium salt, and an organic solvent, wherein the total content of the crosslinked polymer is 3-50 wt % relative to the total weight of the gel polymer electrolyte, and the total content of the fluorinated linear alkyl phosphate compound is 3-20 wt % relative to the total weight of the lithium salt, the organic solvent, and the fluorinated linear alkyl phosphate compound.
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Citation Information

Patent Citations

  • Electrolyte Composition, Gel polymer electrolyte and Lithium battery comprising gel polymer electrolyte

    KR1020130058403A

  • Gel polymer electrolyte and electrochemical device comprising the same

    KR1020150050083A

  • Gel polymer electrolyte and electrochemical device comprising the same

    KR1020150050508A

  • High-elasticity polymer for lithium metal protection, lithium secondary battery and manufacturing method

    US20220223926A1

  • KR20220038006A