Dimethyl Ether: A Pathway to Cleaner Industrial Processes
JUL 1, 20259 MIN READ
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DME Technology Evolution and Objectives
Dimethyl ether (DME) has emerged as a promising alternative fuel and chemical feedstock, offering a pathway to cleaner industrial processes. The evolution of DME technology can be traced back to the early 20th century, with significant advancements occurring in recent decades. Initially, DME was primarily used as a propellant in aerosol products due to its non-toxicity and environmental friendliness.
The technological trajectory of DME has been driven by the growing need for cleaner energy sources and more sustainable industrial processes. In the 1990s, researchers began exploring DME's potential as a fuel, recognizing its clean-burning properties and compatibility with existing diesel engine technology. This shift in focus marked a turning point in DME's technological development, spurring research into more efficient production methods and broader applications.
One of the key objectives in DME technology development has been to optimize production processes. Traditional methods of DME production involved a two-step process: first synthesizing methanol from syngas, then dehydrating methanol to form DME. However, recent advancements have led to the development of single-step processes, significantly improving efficiency and reducing production costs.
Another critical goal has been to expand DME's applications beyond its use as a fuel. Researchers have been exploring its potential as a chemical intermediate in the production of various materials, including olefins, aromatics, and hydrogen. This diversification of applications has been crucial in driving continued investment and innovation in DME technology.
Environmental considerations have played a significant role in shaping the objectives of DME technology development. As global efforts to reduce greenhouse gas emissions intensify, DME has gained attention for its potential to serve as a low-carbon alternative to conventional fuels. Consequently, a major focus has been on developing production methods that utilize renewable feedstocks, such as biomass and waste materials, to further enhance DME's environmental credentials.
The evolution of DME technology has also been influenced by regulatory frameworks and policy initiatives aimed at promoting cleaner energy solutions. This has led to increased collaboration between industry, academia, and government bodies to accelerate research and development efforts. The ultimate goal is to position DME as a viable, sustainable option for various industrial applications, contributing to the transition towards a more environmentally friendly energy landscape.
Looking ahead, the objectives for DME technology development include further improvements in production efficiency, expansion of feedstock options, and enhancement of DME's performance characteristics for specific applications. Additionally, there is a growing focus on integrating DME production with carbon capture and utilization technologies, aligning with broader efforts to achieve carbon neutrality in industrial processes.
The technological trajectory of DME has been driven by the growing need for cleaner energy sources and more sustainable industrial processes. In the 1990s, researchers began exploring DME's potential as a fuel, recognizing its clean-burning properties and compatibility with existing diesel engine technology. This shift in focus marked a turning point in DME's technological development, spurring research into more efficient production methods and broader applications.
One of the key objectives in DME technology development has been to optimize production processes. Traditional methods of DME production involved a two-step process: first synthesizing methanol from syngas, then dehydrating methanol to form DME. However, recent advancements have led to the development of single-step processes, significantly improving efficiency and reducing production costs.
Another critical goal has been to expand DME's applications beyond its use as a fuel. Researchers have been exploring its potential as a chemical intermediate in the production of various materials, including olefins, aromatics, and hydrogen. This diversification of applications has been crucial in driving continued investment and innovation in DME technology.
Environmental considerations have played a significant role in shaping the objectives of DME technology development. As global efforts to reduce greenhouse gas emissions intensify, DME has gained attention for its potential to serve as a low-carbon alternative to conventional fuels. Consequently, a major focus has been on developing production methods that utilize renewable feedstocks, such as biomass and waste materials, to further enhance DME's environmental credentials.
The evolution of DME technology has also been influenced by regulatory frameworks and policy initiatives aimed at promoting cleaner energy solutions. This has led to increased collaboration between industry, academia, and government bodies to accelerate research and development efforts. The ultimate goal is to position DME as a viable, sustainable option for various industrial applications, contributing to the transition towards a more environmentally friendly energy landscape.
Looking ahead, the objectives for DME technology development include further improvements in production efficiency, expansion of feedstock options, and enhancement of DME's performance characteristics for specific applications. Additionally, there is a growing focus on integrating DME production with carbon capture and utilization technologies, aligning with broader efforts to achieve carbon neutrality in industrial processes.
DME Market Demand Analysis
The global market for dimethyl ether (DME) is experiencing significant growth driven by increasing demand for cleaner alternative fuels and industrial processes. DME's versatility as a fuel and chemical feedstock positions it as a promising solution for reducing carbon emissions across various sectors.
In the energy sector, DME is gaining traction as a substitute for liquefied petroleum gas (LPG) and diesel fuel. Its clean-burning properties and compatibility with existing LPG infrastructure make it an attractive option for residential and commercial cooking and heating applications. The transportation industry is also showing interest in DME as a potential replacement for diesel in heavy-duty vehicles, offering reduced emissions without compromising engine performance.
The chemical industry represents another key market for DME, where it serves as a crucial intermediate in the production of various chemicals, including methyl acetate, dimethyl sulfate, and acetic acid. The growing demand for these chemicals in manufacturing processes is expected to drive DME consumption in this sector.
Geographically, Asia-Pacific dominates the DME market, with China leading in production and consumption. The region's rapid industrialization, coupled with stringent environmental regulations, is fueling the adoption of DME as a cleaner alternative to traditional fuels. Europe and North America are also witnessing increased interest in DME, primarily driven by sustainability initiatives and the push for renewable energy sources.
Market analysts project a compound annual growth rate (CAGR) for the global DME market in the range of 8-10% over the next five years. This growth is attributed to factors such as increasing environmental concerns, government support for clean energy technologies, and ongoing research and development efforts to improve DME production efficiency.
However, the market faces challenges, including competition from other alternative fuels and the need for significant infrastructure investments to support widespread DME adoption. The volatility of feedstock prices, particularly methanol, also impacts the economic viability of DME production.
Despite these challenges, the long-term outlook for DME remains positive. As industries and governments worldwide intensify their efforts to reduce carbon footprints, DME's potential as a clean, versatile fuel and chemical feedstock is likely to drive continued market expansion and technological innovation in the coming years.
In the energy sector, DME is gaining traction as a substitute for liquefied petroleum gas (LPG) and diesel fuel. Its clean-burning properties and compatibility with existing LPG infrastructure make it an attractive option for residential and commercial cooking and heating applications. The transportation industry is also showing interest in DME as a potential replacement for diesel in heavy-duty vehicles, offering reduced emissions without compromising engine performance.
The chemical industry represents another key market for DME, where it serves as a crucial intermediate in the production of various chemicals, including methyl acetate, dimethyl sulfate, and acetic acid. The growing demand for these chemicals in manufacturing processes is expected to drive DME consumption in this sector.
Geographically, Asia-Pacific dominates the DME market, with China leading in production and consumption. The region's rapid industrialization, coupled with stringent environmental regulations, is fueling the adoption of DME as a cleaner alternative to traditional fuels. Europe and North America are also witnessing increased interest in DME, primarily driven by sustainability initiatives and the push for renewable energy sources.
Market analysts project a compound annual growth rate (CAGR) for the global DME market in the range of 8-10% over the next five years. This growth is attributed to factors such as increasing environmental concerns, government support for clean energy technologies, and ongoing research and development efforts to improve DME production efficiency.
However, the market faces challenges, including competition from other alternative fuels and the need for significant infrastructure investments to support widespread DME adoption. The volatility of feedstock prices, particularly methanol, also impacts the economic viability of DME production.
Despite these challenges, the long-term outlook for DME remains positive. As industries and governments worldwide intensify their efforts to reduce carbon footprints, DME's potential as a clean, versatile fuel and chemical feedstock is likely to drive continued market expansion and technological innovation in the coming years.
DME Production Challenges
The production of dimethyl ether (DME) faces several significant challenges that hinder its widespread adoption as a cleaner alternative in industrial processes. One of the primary obstacles is the high energy consumption associated with traditional DME production methods. The conventional two-step process, which involves methanol synthesis followed by methanol dehydration, requires substantial energy input, leading to increased production costs and reduced overall efficiency.
Another major challenge lies in the feedstock flexibility for DME production. While natural gas is the most common feedstock, there is a growing interest in utilizing alternative sources such as biomass, coal, and even carbon dioxide. However, each of these feedstocks presents unique technical difficulties in terms of conversion efficiency, impurity removal, and process optimization. The development of cost-effective and efficient catalysts capable of handling diverse feedstocks remains a critical area of research.
Scale-up and process integration pose additional challenges in DME production. As the demand for DME grows, there is a need to develop larger-scale production facilities that can maintain high efficiency and product quality. This requires careful engineering and design considerations to optimize heat integration, minimize energy losses, and ensure consistent product specifications across different production scales.
The purity of the final DME product is another crucial aspect that demands attention. Trace impurities can significantly affect the performance and emissions profile of DME when used as a fuel or chemical feedstock. Developing efficient purification techniques that can remove contaminants without substantially increasing production costs is an ongoing challenge for researchers and engineers in the field.
Environmental concerns also play a role in DME production challenges. While DME itself is considered a cleaner alternative to conventional fuels, its production process still generates greenhouse gas emissions. Addressing these emissions through carbon capture and utilization technologies, or by developing carbon-neutral production pathways, is essential for ensuring the long-term sustainability of DME as a clean energy solution.
Lastly, the economic viability of DME production remains a significant hurdle. The capital costs associated with building DME production facilities, coupled with fluctuating feedstock prices and competition from established fuels and chemicals, create uncertainties in the market. Overcoming these economic challenges requires a combination of technological advancements to reduce production costs, supportive policy frameworks, and the development of new markets and applications for DME.
Another major challenge lies in the feedstock flexibility for DME production. While natural gas is the most common feedstock, there is a growing interest in utilizing alternative sources such as biomass, coal, and even carbon dioxide. However, each of these feedstocks presents unique technical difficulties in terms of conversion efficiency, impurity removal, and process optimization. The development of cost-effective and efficient catalysts capable of handling diverse feedstocks remains a critical area of research.
Scale-up and process integration pose additional challenges in DME production. As the demand for DME grows, there is a need to develop larger-scale production facilities that can maintain high efficiency and product quality. This requires careful engineering and design considerations to optimize heat integration, minimize energy losses, and ensure consistent product specifications across different production scales.
The purity of the final DME product is another crucial aspect that demands attention. Trace impurities can significantly affect the performance and emissions profile of DME when used as a fuel or chemical feedstock. Developing efficient purification techniques that can remove contaminants without substantially increasing production costs is an ongoing challenge for researchers and engineers in the field.
Environmental concerns also play a role in DME production challenges. While DME itself is considered a cleaner alternative to conventional fuels, its production process still generates greenhouse gas emissions. Addressing these emissions through carbon capture and utilization technologies, or by developing carbon-neutral production pathways, is essential for ensuring the long-term sustainability of DME as a clean energy solution.
Lastly, the economic viability of DME production remains a significant hurdle. The capital costs associated with building DME production facilities, coupled with fluctuating feedstock prices and competition from established fuels and chemicals, create uncertainties in the market. Overcoming these economic challenges requires a combination of technological advancements to reduce production costs, supportive policy frameworks, and the development of new markets and applications for DME.
Current DME Production Methods
01 Production of dimethyl ether
Various methods for producing dimethyl ether are described, including catalytic dehydration of methanol, direct synthesis from syngas, and conversion of other hydrocarbons. These processes often involve specific catalysts and reaction conditions to optimize yield and selectivity.- Production of dimethyl ether: Various methods for producing dimethyl ether are described, including catalytic dehydration of methanol, direct synthesis from syngas, and conversion of other hydrocarbons. These processes often involve specific catalysts and reaction conditions to optimize yield and selectivity.
- Catalysts for dimethyl ether synthesis: Different types of catalysts are used in the production of dimethyl ether, including zeolites, metal oxides, and composite catalysts. The choice and preparation of catalysts significantly influence the efficiency and selectivity of the dimethyl ether synthesis process.
- Applications of dimethyl ether: Dimethyl ether has various applications, including use as a fuel additive, aerosol propellant, and refrigerant. It is also being explored as an alternative clean fuel for diesel engines and power generation due to its favorable combustion properties.
- Purification and separation of dimethyl ether: Methods for purifying and separating dimethyl ether from reaction mixtures or other compounds are described. These processes often involve distillation, adsorption, or membrane separation techniques to obtain high-purity dimethyl ether.
- Environmental and safety considerations: Research on the environmental impact and safety aspects of dimethyl ether production and use is ongoing. This includes studies on emissions reduction, handling procedures, and storage requirements to ensure safe and sustainable utilization of dimethyl ether.
02 Catalysts for dimethyl ether synthesis
Different types of catalysts are used in the production of dimethyl ether, including zeolites, metal oxides, and composite catalysts. The choice and preparation of catalysts significantly affect the efficiency and selectivity of the dimethyl ether synthesis process.Expand Specific Solutions03 Applications of dimethyl ether
Dimethyl ether has various applications, including use as a fuel additive, aerosol propellant, and refrigerant. It is also being explored as an alternative clean fuel for diesel engines and power generation due to its low emissions and high cetane number.Expand Specific Solutions04 Purification and separation of dimethyl ether
Methods for purifying and separating dimethyl ether from reaction mixtures or other compounds are described. These processes often involve distillation, adsorption, or membrane separation techniques to obtain high-purity dimethyl ether.Expand Specific Solutions05 Environmental and safety considerations
Research on the environmental impact and safety aspects of dimethyl ether production and use is ongoing. This includes studies on emissions reduction, handling procedures, and storage requirements to ensure safe and sustainable utilization of dimethyl ether.Expand Specific Solutions
Key DME Industry Players
The dimethyl ether (DME) market is in a growth phase, driven by increasing demand for cleaner industrial processes. The global market size is projected to expand significantly in the coming years, fueled by environmental regulations and the push for sustainable alternatives. Technologically, DME production is relatively mature, with established players like China Petroleum & Chemical Corp. and SK Energy Co., Ltd. leading commercial-scale operations. However, there is ongoing research and development, particularly in catalyst technology and process efficiency, involving companies such as Haldor Topsøe A/S and research institutions like the Chinese Academy of Science Guangzhou Energy Research Institute. The competitive landscape is characterized by a mix of large energy corporations and specialized chemical companies, with potential for new entrants as the market grows.
China Petroleum & Chemical Corp.
Technical Solution: China Petroleum & Chemical Corp. (Sinopec) has developed an innovative process for producing dimethyl ether (DME) from syngas. Their technology involves a single-step synthesis method, which combines methanol synthesis and dehydration in one reactor. This process achieves a syngas conversion rate of up to 95% and a DME selectivity of over 99%[1]. Sinopec has also implemented a large-scale DME production facility with an annual capacity of 1 million tons, demonstrating the commercial viability of their technology[2]. The company has further improved the catalyst system, incorporating a hybrid catalyst that enhances stability and reduces coke formation, leading to extended catalyst life and improved process efficiency[3].
Strengths: High conversion rate and selectivity, proven large-scale production capability, and improved catalyst system. Weaknesses: Potential dependency on coal-based syngas, which may limit the environmental benefits of DME production.
Haldor Topsøe A/S
Technical Solution: Haldor Topsøe has developed a proprietary technology for DME production called TIGAS (Topsøe Improved Gasoline Synthesis). This process integrates syngas production, methanol synthesis, and DME synthesis into a single loop, offering significant advantages in terms of efficiency and cost-effectiveness. The TIGAS technology can produce DME from various feedstocks, including natural gas, coal, and biomass[4]. Haldor Topsøe's process achieves a carbon efficiency of up to 80% and can be tailored to produce different ratios of DME and methanol based on market demands[5]. The company has also developed advanced catalysts that improve selectivity and reduce byproduct formation, leading to higher overall process efficiency and reduced environmental impact[6].
Strengths: Flexible feedstock options, high carbon efficiency, and integrated process design. Weaknesses: May require significant capital investment for implementation in existing facilities.
DME Synthesis Innovations
Process for preparing dimethylether from methanol
PatentInactiveEP1597225A1
Innovation
- A dual-charged catalyst system is employed, where the upper reactor part is filled with a hydrophilic solid acid catalyst such as gamma-alumina or silica-alumina and the lower part with a hydrophobic zeolite catalyst, with a SiO2/Al2O3 ratio between 20 and 200, allowing continuous methanol dehydration in the presence of dimethyl ether and water to maintain high catalyst activity and increase yield.
Process and system for producing dimethyl ether
PatentActiveUS20200399195A1
Innovation
- A process combining conventional DME synthesis with a separation-enhanced reverse water gas shift reaction, allowing for efficient DME production using any carbon oxide species, reducing the need for CO2 recycles, and minimizing methanol recycles, while utilizing a catalyst system capable of converting synthesis gas to DME.
Environmental Impact of DME
Dimethyl ether (DME) has emerged as a promising alternative fuel and chemical feedstock, offering significant environmental benefits compared to traditional fossil fuels. The environmental impact of DME is multifaceted, encompassing various aspects of its production, use, and disposal.
In terms of air quality, DME combustion produces significantly lower emissions of particulate matter, nitrogen oxides, and sulfur oxides compared to conventional diesel fuel. This characteristic makes DME particularly attractive for use in urban areas where air pollution is a major concern. Studies have shown that replacing diesel with DME in heavy-duty vehicles can lead to substantial reductions in smog-forming pollutants and improve overall air quality.
The greenhouse gas (GHG) emissions associated with DME depend largely on its production method. When produced from renewable sources such as biomass or waste materials, DME can offer substantial GHG reductions compared to fossil fuels. Life cycle assessments have demonstrated that bio-based DME can achieve up to 95% reduction in GHG emissions compared to conventional diesel. However, when produced from fossil fuels like natural gas or coal, the GHG benefits are less pronounced but still generally favorable compared to traditional petroleum-based fuels.
Water consumption and quality are important considerations in DME production. The water footprint of DME varies depending on the feedstock and production process. While DME production from natural gas typically requires less water than many biofuel production processes, it is essential to implement proper water management practices to minimize environmental impact. Additionally, the risk of water contamination from DME spills is relatively low due to its high volatility and biodegradability.
Land use changes associated with DME production are minimal when using existing industrial infrastructure for natural gas-based DME. However, if large-scale production of bio-based DME is pursued, careful consideration must be given to potential impacts on land use, biodiversity, and food security. Sustainable land management practices and the use of waste or marginal lands for biomass feedstock can help mitigate these concerns.
The end-of-life environmental impact of DME is generally favorable. As a volatile compound, DME does not persist in the environment and does not contribute to soil or water pollution in the same way as liquid hydrocarbon fuels. Its rapid biodegradation in the atmosphere further reduces long-term environmental risks.
In industrial processes, the use of DME as a solvent or propellant offers environmental advantages over traditional options. Its low toxicity, absence of ozone-depleting potential, and minimal contribution to photochemical smog formation make it an environmentally friendly choice for various applications, from aerosol propellants to refrigerants.
In terms of air quality, DME combustion produces significantly lower emissions of particulate matter, nitrogen oxides, and sulfur oxides compared to conventional diesel fuel. This characteristic makes DME particularly attractive for use in urban areas where air pollution is a major concern. Studies have shown that replacing diesel with DME in heavy-duty vehicles can lead to substantial reductions in smog-forming pollutants and improve overall air quality.
The greenhouse gas (GHG) emissions associated with DME depend largely on its production method. When produced from renewable sources such as biomass or waste materials, DME can offer substantial GHG reductions compared to fossil fuels. Life cycle assessments have demonstrated that bio-based DME can achieve up to 95% reduction in GHG emissions compared to conventional diesel. However, when produced from fossil fuels like natural gas or coal, the GHG benefits are less pronounced but still generally favorable compared to traditional petroleum-based fuels.
Water consumption and quality are important considerations in DME production. The water footprint of DME varies depending on the feedstock and production process. While DME production from natural gas typically requires less water than many biofuel production processes, it is essential to implement proper water management practices to minimize environmental impact. Additionally, the risk of water contamination from DME spills is relatively low due to its high volatility and biodegradability.
Land use changes associated with DME production are minimal when using existing industrial infrastructure for natural gas-based DME. However, if large-scale production of bio-based DME is pursued, careful consideration must be given to potential impacts on land use, biodiversity, and food security. Sustainable land management practices and the use of waste or marginal lands for biomass feedstock can help mitigate these concerns.
The end-of-life environmental impact of DME is generally favorable. As a volatile compound, DME does not persist in the environment and does not contribute to soil or water pollution in the same way as liquid hydrocarbon fuels. Its rapid biodegradation in the atmosphere further reduces long-term environmental risks.
In industrial processes, the use of DME as a solvent or propellant offers environmental advantages over traditional options. Its low toxicity, absence of ozone-depleting potential, and minimal contribution to photochemical smog formation make it an environmentally friendly choice for various applications, from aerosol propellants to refrigerants.
DME Regulatory Framework
The regulatory framework surrounding Dimethyl Ether (DME) as a cleaner industrial process alternative is complex and evolving. At the international level, the United Nations Framework Convention on Climate Change (UNFCCC) and the Paris Agreement provide overarching guidelines for reducing greenhouse gas emissions, indirectly influencing DME adoption. The International Maritime Organization (IMO) has also recognized DME as a potential marine fuel, subject to its regulations on ship emissions.
In the United States, the Environmental Protection Agency (EPA) plays a crucial role in regulating DME use. The EPA has approved DME as a renewable fuel under the Renewable Fuel Standard (RFS) program, allowing it to qualify for Renewable Identification Numbers (RINs). This designation incentivizes DME production from renewable sources. Additionally, the Department of Energy (DOE) supports research and development of DME technologies through various funding programs.
The European Union has established a comprehensive regulatory framework for alternative fuels, including DME. The Alternative Fuels Infrastructure Directive (AFID) and the Renewable Energy Directive (RED II) promote the use of clean fuels like DME in transportation and industry. These directives set targets for renewable energy use and mandate the development of necessary infrastructure.
In Asia, countries like China and Japan have implemented policies to encourage DME adoption. China's Air Pollution Prevention and Control Action Plan has led to increased interest in DME as a cleaner alternative to coal and diesel. Japan's Strategic Energy Plan includes DME as part of its efforts to diversify energy sources and reduce emissions.
Safety regulations for DME handling and storage are critical components of the regulatory framework. Organizations such as the National Fire Protection Association (NFPA) in the US and the European Committee for Standardization (CEN) have developed specific guidelines for DME safety. These standards cover aspects such as storage tank design, transportation requirements, and handling procedures.
Emissions regulations also significantly impact DME adoption. Many countries have implemented stringent emissions standards for vehicles and industrial processes, indirectly promoting cleaner alternatives like DME. For instance, the Euro 6 standards in Europe and Tier 4 standards in the US have pushed industries to explore low-emission fuel options.
As DME gains traction as a cleaner industrial process, regulatory bodies are likely to develop more specific frameworks. This may include standardization of DME quality, expansion of infrastructure requirements, and integration into existing energy policies. The ongoing global focus on decarbonization and sustainable development will continue to shape the regulatory landscape for DME, potentially leading to more favorable policies and incentives for its adoption across various industrial sectors.
In the United States, the Environmental Protection Agency (EPA) plays a crucial role in regulating DME use. The EPA has approved DME as a renewable fuel under the Renewable Fuel Standard (RFS) program, allowing it to qualify for Renewable Identification Numbers (RINs). This designation incentivizes DME production from renewable sources. Additionally, the Department of Energy (DOE) supports research and development of DME technologies through various funding programs.
The European Union has established a comprehensive regulatory framework for alternative fuels, including DME. The Alternative Fuels Infrastructure Directive (AFID) and the Renewable Energy Directive (RED II) promote the use of clean fuels like DME in transportation and industry. These directives set targets for renewable energy use and mandate the development of necessary infrastructure.
In Asia, countries like China and Japan have implemented policies to encourage DME adoption. China's Air Pollution Prevention and Control Action Plan has led to increased interest in DME as a cleaner alternative to coal and diesel. Japan's Strategic Energy Plan includes DME as part of its efforts to diversify energy sources and reduce emissions.
Safety regulations for DME handling and storage are critical components of the regulatory framework. Organizations such as the National Fire Protection Association (NFPA) in the US and the European Committee for Standardization (CEN) have developed specific guidelines for DME safety. These standards cover aspects such as storage tank design, transportation requirements, and handling procedures.
Emissions regulations also significantly impact DME adoption. Many countries have implemented stringent emissions standards for vehicles and industrial processes, indirectly promoting cleaner alternatives like DME. For instance, the Euro 6 standards in Europe and Tier 4 standards in the US have pushed industries to explore low-emission fuel options.
As DME gains traction as a cleaner industrial process, regulatory bodies are likely to develop more specific frameworks. This may include standardization of DME quality, expansion of infrastructure requirements, and integration into existing energy policies. The ongoing global focus on decarbonization and sustainable development will continue to shape the regulatory landscape for DME, potentially leading to more favorable policies and incentives for its adoption across various industrial sectors.
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