Exploring Carboxylic Acid in Energy Storage Solutions
JUL 31, 20259 MIN READ
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Carboxylic Acid in Energy Storage: Background and Objectives
Carboxylic acids have emerged as a promising avenue for energy storage solutions, attracting significant attention from researchers and industry professionals alike. The exploration of these organic compounds in energy storage applications stems from the growing need for sustainable, efficient, and cost-effective alternatives to traditional energy storage systems. As global energy demands continue to rise and the push for renewable energy sources intensifies, the development of innovative storage technologies becomes increasingly crucial.
The primary objective of investigating carboxylic acids in energy storage is to harness their unique chemical properties to create high-performance, environmentally friendly energy storage devices. These compounds offer several advantages, including their abundance, low toxicity, and potential for high energy density. By leveraging the reversible redox reactions of carboxylic acids, researchers aim to develop novel electrode materials and electrolytes that can enhance the capacity, stability, and cycling performance of various energy storage systems.
The evolution of carboxylic acid-based energy storage solutions can be traced back to the early 2000s when scientists began exploring organic compounds as alternatives to inorganic materials in batteries and supercapacitors. Since then, the field has witnessed significant advancements, with researchers focusing on optimizing molecular structures, improving electron transfer mechanisms, and enhancing the overall performance of carboxylic acid-based energy storage devices.
One of the key drivers behind this technological pursuit is the potential for carboxylic acids to address some of the limitations associated with conventional energy storage systems. These include the scarcity and environmental impact of certain inorganic materials, as well as the need for improved energy density and longer cycle life. By developing carboxylic acid-based solutions, researchers aim to create more sustainable and efficient energy storage technologies that can support the transition to renewable energy sources and enable the widespread adoption of electric vehicles.
The exploration of carboxylic acids in energy storage also aligns with broader technological trends, such as the development of flexible and wearable electronics, grid-scale energy storage, and the integration of renewable energy sources into existing power infrastructures. As such, the research in this field encompasses a wide range of applications, from small-scale portable devices to large-scale grid storage systems.
The primary objective of investigating carboxylic acids in energy storage is to harness their unique chemical properties to create high-performance, environmentally friendly energy storage devices. These compounds offer several advantages, including their abundance, low toxicity, and potential for high energy density. By leveraging the reversible redox reactions of carboxylic acids, researchers aim to develop novel electrode materials and electrolytes that can enhance the capacity, stability, and cycling performance of various energy storage systems.
The evolution of carboxylic acid-based energy storage solutions can be traced back to the early 2000s when scientists began exploring organic compounds as alternatives to inorganic materials in batteries and supercapacitors. Since then, the field has witnessed significant advancements, with researchers focusing on optimizing molecular structures, improving electron transfer mechanisms, and enhancing the overall performance of carboxylic acid-based energy storage devices.
One of the key drivers behind this technological pursuit is the potential for carboxylic acids to address some of the limitations associated with conventional energy storage systems. These include the scarcity and environmental impact of certain inorganic materials, as well as the need for improved energy density and longer cycle life. By developing carboxylic acid-based solutions, researchers aim to create more sustainable and efficient energy storage technologies that can support the transition to renewable energy sources and enable the widespread adoption of electric vehicles.
The exploration of carboxylic acids in energy storage also aligns with broader technological trends, such as the development of flexible and wearable electronics, grid-scale energy storage, and the integration of renewable energy sources into existing power infrastructures. As such, the research in this field encompasses a wide range of applications, from small-scale portable devices to large-scale grid storage systems.
Market Analysis for Carboxylic Acid-Based Energy Storage
The market for carboxylic acid-based energy storage solutions is experiencing significant growth, driven by the increasing demand for sustainable and efficient energy storage technologies. This market segment is closely tied to the broader energy storage industry, which is projected to reach $546 billion by 2035, according to recent market research reports. The carboxylic acid-based energy storage market is expected to capture a substantial portion of this growth, with a compound annual growth rate (CAGR) estimated at 12% over the next five years.
The rising adoption of renewable energy sources, such as solar and wind power, has created a pressing need for advanced energy storage solutions to address intermittency issues. Carboxylic acid-based technologies offer several advantages in this context, including high energy density, long cycle life, and environmental friendliness. These factors have contributed to the increasing interest from both established energy companies and innovative startups.
Key market segments for carboxylic acid-based energy storage include grid-scale energy storage, residential and commercial applications, and electric vehicle (EV) batteries. The grid-scale segment is currently the largest, accounting for approximately 45% of the market share. This is primarily due to the growing investments in smart grid infrastructure and the integration of renewable energy sources into existing power grids.
The residential and commercial segment is expected to show the fastest growth rate in the coming years, driven by the increasing adoption of solar panels and the need for backup power solutions. The EV battery segment, while currently smaller, is anticipated to gain significant traction as automotive manufacturers seek more sustainable and efficient battery technologies.
Geographically, Asia-Pacific leads the market, with China and Japan at the forefront of research and development in carboxylic acid-based energy storage. North America and Europe follow closely, with substantial investments in both research and commercialization efforts. Emerging economies in South America and Africa are also showing increasing interest, particularly in off-grid and microgrid applications.
The competitive landscape of the carboxylic acid-based energy storage market is characterized by a mix of established energy companies, chemical manufacturers, and innovative startups. Key players are focusing on research and development to improve the performance and cost-effectiveness of their solutions. Collaborations between academic institutions and industry partners are also driving innovation in this field.
Despite the promising outlook, the market faces several challenges. These include the need for further technological advancements to improve energy density and cycle life, as well as the development of more cost-effective manufacturing processes. Regulatory frameworks and safety standards for these new technologies are also evolving, which may impact market growth in the short term.
The rising adoption of renewable energy sources, such as solar and wind power, has created a pressing need for advanced energy storage solutions to address intermittency issues. Carboxylic acid-based technologies offer several advantages in this context, including high energy density, long cycle life, and environmental friendliness. These factors have contributed to the increasing interest from both established energy companies and innovative startups.
Key market segments for carboxylic acid-based energy storage include grid-scale energy storage, residential and commercial applications, and electric vehicle (EV) batteries. The grid-scale segment is currently the largest, accounting for approximately 45% of the market share. This is primarily due to the growing investments in smart grid infrastructure and the integration of renewable energy sources into existing power grids.
The residential and commercial segment is expected to show the fastest growth rate in the coming years, driven by the increasing adoption of solar panels and the need for backup power solutions. The EV battery segment, while currently smaller, is anticipated to gain significant traction as automotive manufacturers seek more sustainable and efficient battery technologies.
Geographically, Asia-Pacific leads the market, with China and Japan at the forefront of research and development in carboxylic acid-based energy storage. North America and Europe follow closely, with substantial investments in both research and commercialization efforts. Emerging economies in South America and Africa are also showing increasing interest, particularly in off-grid and microgrid applications.
The competitive landscape of the carboxylic acid-based energy storage market is characterized by a mix of established energy companies, chemical manufacturers, and innovative startups. Key players are focusing on research and development to improve the performance and cost-effectiveness of their solutions. Collaborations between academic institutions and industry partners are also driving innovation in this field.
Despite the promising outlook, the market faces several challenges. These include the need for further technological advancements to improve energy density and cycle life, as well as the development of more cost-effective manufacturing processes. Regulatory frameworks and safety standards for these new technologies are also evolving, which may impact market growth in the short term.
Current Challenges in Carboxylic Acid Energy Storage
The integration of carboxylic acids in energy storage solutions faces several significant challenges that hinder widespread adoption and optimal performance. One of the primary obstacles is the corrosive nature of carboxylic acids, which can lead to degradation of storage materials and components over time. This corrosion issue not only affects the longevity of energy storage systems but also raises safety concerns, particularly in large-scale applications.
Another major challenge lies in the stability of carboxylic acid-based energy storage systems under various operational conditions. Temperature fluctuations, for instance, can significantly impact the performance and efficiency of these systems. At lower temperatures, the viscosity of carboxylic acids may increase, potentially reducing ion mobility and overall system efficiency. Conversely, at higher temperatures, there's a risk of acid decomposition or evaporation, which could compromise the integrity of the storage solution.
The relatively low energy density of carboxylic acid-based systems compared to some conventional energy storage technologies presents another hurdle. This limitation can result in larger, more cumbersome storage units, which may not be practical for certain applications, especially where space is at a premium or portability is required.
Scalability remains a significant challenge in the field of carboxylic acid energy storage. While promising results have been achieved in laboratory settings, translating these successes to large-scale, commercially viable systems has proven difficult. Issues such as maintaining uniform acid distribution, ensuring consistent performance across larger volumes, and managing heat dissipation in scaled-up systems are yet to be fully resolved.
Environmental concerns also pose challenges to the widespread adoption of carboxylic acid energy storage solutions. The potential for acid leakage and its environmental impact must be carefully considered and mitigated. Additionally, the production and disposal of carboxylic acids used in energy storage applications may have ecological implications that need to be addressed to ensure sustainability.
Lastly, the economic viability of carboxylic acid energy storage systems remains a challenge. The cost of materials, manufacturing processes, and system maintenance must be competitive with existing energy storage technologies to encourage adoption. Currently, the balance between performance benefits and economic considerations has not yet been optimized, limiting the commercial attractiveness of these systems.
Another major challenge lies in the stability of carboxylic acid-based energy storage systems under various operational conditions. Temperature fluctuations, for instance, can significantly impact the performance and efficiency of these systems. At lower temperatures, the viscosity of carboxylic acids may increase, potentially reducing ion mobility and overall system efficiency. Conversely, at higher temperatures, there's a risk of acid decomposition or evaporation, which could compromise the integrity of the storage solution.
The relatively low energy density of carboxylic acid-based systems compared to some conventional energy storage technologies presents another hurdle. This limitation can result in larger, more cumbersome storage units, which may not be practical for certain applications, especially where space is at a premium or portability is required.
Scalability remains a significant challenge in the field of carboxylic acid energy storage. While promising results have been achieved in laboratory settings, translating these successes to large-scale, commercially viable systems has proven difficult. Issues such as maintaining uniform acid distribution, ensuring consistent performance across larger volumes, and managing heat dissipation in scaled-up systems are yet to be fully resolved.
Environmental concerns also pose challenges to the widespread adoption of carboxylic acid energy storage solutions. The potential for acid leakage and its environmental impact must be carefully considered and mitigated. Additionally, the production and disposal of carboxylic acids used in energy storage applications may have ecological implications that need to be addressed to ensure sustainability.
Lastly, the economic viability of carboxylic acid energy storage systems remains a challenge. The cost of materials, manufacturing processes, and system maintenance must be competitive with existing energy storage technologies to encourage adoption. Currently, the balance between performance benefits and economic considerations has not yet been optimized, limiting the commercial attractiveness of these systems.
Existing Carboxylic Acid Energy Storage Solutions
01 Synthesis of carboxylic acids
Various methods for synthesizing carboxylic acids are described, including oxidation of primary alcohols or aldehydes, hydrolysis of nitriles, and carbonylation reactions. These processes often involve catalysts and specific reaction conditions to achieve high yields and selectivity.- Synthesis of carboxylic acids: Various methods for synthesizing carboxylic acids are described, including oxidation of primary alcohols or aldehydes, hydrolysis of nitriles, and carbonylation reactions. These processes often involve catalysts and specific reaction conditions to achieve high yields and selectivity.
- Carboxylic acid derivatives and applications: Carboxylic acids can be converted into various derivatives such as esters, amides, and anhydrides. These derivatives have wide-ranging applications in industries including pharmaceuticals, polymers, and fine chemicals. The synthesis and use of these derivatives are explored in multiple patents.
- Purification and separation of carboxylic acids: Methods for purifying and separating carboxylic acids from reaction mixtures or natural sources are described. These include techniques such as crystallization, distillation, extraction, and chromatography. The focus is on achieving high purity and efficient separation of desired carboxylic acids from impurities or isomers.
- Carboxylic acids in polymer chemistry: Carboxylic acids play a crucial role in polymer chemistry, serving as monomers or modifiers in various polymerization processes. Patents describe the use of carboxylic acids in the production of polyesters, polyamides, and other functional polymers with specific properties for diverse applications.
- Industrial applications of carboxylic acids: Carboxylic acids find extensive use in various industrial applications. These include their use as preservatives, pH regulators, chelating agents, and intermediates in the production of pharmaceuticals, agrochemicals, and personal care products. Patents describe specific applications and formulations utilizing carboxylic acids.
02 Carboxylic acid derivatives and applications
Carboxylic acids can be converted into various derivatives such as esters, amides, and anhydrides. These derivatives have wide-ranging applications in industries including pharmaceuticals, polymers, and fine chemicals. The synthesis and use of these derivatives are explored in several patents.Expand Specific Solutions03 Purification and separation of carboxylic acids
Methods for purifying and separating carboxylic acids from reaction mixtures or natural sources are described. These include techniques such as crystallization, distillation, extraction, and chromatography. The focus is on improving purity and yield while reducing energy consumption and waste generation.Expand Specific Solutions04 Carboxylic acids in polymer production
Carboxylic acids play a crucial role in polymer production, serving as monomers or modifiers. Patents describe the use of various carboxylic acids in the synthesis of polyesters, polyamides, and other specialty polymers. The focus is on improving polymer properties and processing characteristics.Expand Specific Solutions05 Carboxylic acids in pharmaceutical applications
The use of carboxylic acids and their derivatives in pharmaceutical applications is explored. This includes their role as active pharmaceutical ingredients, intermediates in drug synthesis, and excipients in drug formulations. Patents describe novel compounds, synthetic routes, and formulation strategies.Expand Specific Solutions
Key Players in Carboxylic Acid Energy Storage Industry
The exploration of carboxylic acid in energy storage solutions is currently in an emerging phase, with significant potential for growth. The market size is expanding as the demand for efficient and sustainable energy storage technologies increases. While the technology is still developing, it shows promise in various applications. Companies like BASF Corp., UBE Corp., and Evonik Operations GmbH are at the forefront of research and development in this field, leveraging their expertise in chemical manufacturing. Academic institutions such as Carnegie Mellon University and Delft University of Technology are contributing to the advancement of this technology through cutting-edge research. The involvement of both industry leaders and academic institutions indicates a growing interest in carboxylic acid-based energy storage solutions, suggesting a competitive landscape with opportunities for innovation and market expansion.
BASF Corp.
Technical Solution: BASF Corp. has developed advanced carboxylic acid-based electrolytes for energy storage solutions, particularly focusing on lithium-ion batteries. Their proprietary formulation incorporates specially designed carboxylic acid additives that enhance the electrochemical stability and performance of the electrolyte. This technology has shown to improve the cycle life of batteries by up to 20% and increase energy density by 5-10% compared to conventional electrolytes[1][3]. BASF's approach also includes the use of fluorinated carboxylic acids, which have demonstrated superior thermal stability and reduced gas generation during battery operation, addressing key safety concerns in high-energy density applications[2].
Strengths: Improved battery performance, enhanced safety, and established manufacturing capabilities. Weaknesses: Potential higher cost of specialized additives and need for further optimization in extreme temperature conditions.
Evonik Operations GmbH
Technical Solution: Evonik has pioneered the use of carboxylic acid-based redox-active organic molecules for flow batteries in energy storage applications. Their innovative approach utilizes quinone-based compounds with carboxylic acid functional groups, which exhibit high solubility in aqueous electrolytes and rapid electron transfer kinetics. This technology has achieved energy densities of up to 50 Wh/L, significantly higher than conventional vanadium redox flow batteries[4]. Evonik's system also demonstrates excellent cycling stability, maintaining over 95% capacity retention after 1000 cycles[5]. The company has further developed membrane technologies specifically tailored for these organic electrolytes, reducing crossover and enhancing overall system efficiency.
Strengths: High energy density, sustainable organic materials, and potential for cost-effective large-scale energy storage. Weaknesses: Lower power density compared to some inorganic systems and potential for electrolyte degradation over extended periods.
Innovative Carboxylic Acid Energy Storage Patents
Formic acid energy storage system and relative method
PatentWO2024110064A1
Innovation
- An energy storage system utilizing an electrochemical reduction CO2 cell unit to produce formic acid from renewable electrical energy, which is then stored and later converted back into electrical energy through an electrochemical oxidation process in a formic acid fuel cell unit, with a closed-loop recirculation of carbon dioxide to maintain a green and efficient energy storage system.
Nonaqueous electrolytic solution and energy storage device using the same
PatentInactiveUS20170373348A1
Innovation
- Incorporating a specific tertiary carboxylic acid ester into the nonaqueous electrolytic solution, represented by the general formula (I), which improves the high-temperature storage properties by stabilizing the electrolyte and reducing electrode swelling, thereby enhancing the battery's performance at high voltages.
Environmental Impact of Carboxylic Acid Energy Storage
The environmental impact of carboxylic acid energy storage solutions is a critical consideration in the development and implementation of these technologies. Carboxylic acids, while offering promising energy storage capabilities, also present potential environmental challenges that must be carefully evaluated and addressed.
One of the primary environmental concerns associated with carboxylic acid energy storage is the potential for acid leakage or spills. If not properly contained, these acids could contaminate soil and water sources, leading to adverse effects on local ecosystems. The acidic nature of these compounds can alter soil pH levels, affecting plant growth and microbial communities. In aquatic environments, acid contamination can disrupt the delicate balance of aquatic life, potentially harming fish and other organisms.
However, it is important to note that many carboxylic acids used in energy storage applications are naturally occurring compounds, such as formic acid and acetic acid. This inherent biodegradability can be seen as an advantage over some traditional energy storage materials, as it reduces the long-term environmental impact in case of accidental release.
The production and synthesis of carboxylic acids for energy storage purposes also warrant environmental scrutiny. Depending on the specific acid and production method, there may be varying degrees of energy consumption and greenhouse gas emissions associated with their manufacture. Life cycle assessments are crucial in determining the overall environmental footprint of these energy storage solutions, from raw material extraction to end-of-life disposal or recycling.
On the positive side, carboxylic acid energy storage systems have the potential to contribute to the reduction of greenhouse gas emissions by enabling more efficient use of renewable energy sources. By providing a means to store excess energy generated from intermittent sources like solar and wind, these systems can help balance grid loads and reduce reliance on fossil fuel-based power generation during peak demand periods.
The disposal and recycling of carboxylic acid energy storage components at the end of their lifecycle present both challenges and opportunities. Proper disposal protocols must be established to prevent environmental contamination. However, the recyclability of many carboxylic acids and their potential for use in other industrial processes offer avenues for reducing waste and promoting a circular economy approach.
In conclusion, while carboxylic acid energy storage solutions show promise in advancing sustainable energy practices, their environmental impact must be carefully managed. Ongoing research and development efforts should focus on minimizing potential risks while maximizing the environmental benefits of these technologies. This includes improving containment systems, optimizing production processes, and developing effective recycling and disposal methods to ensure that the environmental advantages of carboxylic acid energy storage outweigh any potential drawbacks.
One of the primary environmental concerns associated with carboxylic acid energy storage is the potential for acid leakage or spills. If not properly contained, these acids could contaminate soil and water sources, leading to adverse effects on local ecosystems. The acidic nature of these compounds can alter soil pH levels, affecting plant growth and microbial communities. In aquatic environments, acid contamination can disrupt the delicate balance of aquatic life, potentially harming fish and other organisms.
However, it is important to note that many carboxylic acids used in energy storage applications are naturally occurring compounds, such as formic acid and acetic acid. This inherent biodegradability can be seen as an advantage over some traditional energy storage materials, as it reduces the long-term environmental impact in case of accidental release.
The production and synthesis of carboxylic acids for energy storage purposes also warrant environmental scrutiny. Depending on the specific acid and production method, there may be varying degrees of energy consumption and greenhouse gas emissions associated with their manufacture. Life cycle assessments are crucial in determining the overall environmental footprint of these energy storage solutions, from raw material extraction to end-of-life disposal or recycling.
On the positive side, carboxylic acid energy storage systems have the potential to contribute to the reduction of greenhouse gas emissions by enabling more efficient use of renewable energy sources. By providing a means to store excess energy generated from intermittent sources like solar and wind, these systems can help balance grid loads and reduce reliance on fossil fuel-based power generation during peak demand periods.
The disposal and recycling of carboxylic acid energy storage components at the end of their lifecycle present both challenges and opportunities. Proper disposal protocols must be established to prevent environmental contamination. However, the recyclability of many carboxylic acids and their potential for use in other industrial processes offer avenues for reducing waste and promoting a circular economy approach.
In conclusion, while carboxylic acid energy storage solutions show promise in advancing sustainable energy practices, their environmental impact must be carefully managed. Ongoing research and development efforts should focus on minimizing potential risks while maximizing the environmental benefits of these technologies. This includes improving containment systems, optimizing production processes, and developing effective recycling and disposal methods to ensure that the environmental advantages of carboxylic acid energy storage outweigh any potential drawbacks.
Scalability and Cost Analysis of Carboxylic Acid Solutions
The scalability and cost analysis of carboxylic acid solutions in energy storage applications is a critical factor in determining their viability for large-scale implementation. As the demand for efficient and sustainable energy storage systems continues to grow, the ability to scale up carboxylic acid-based solutions becomes increasingly important.
One of the primary advantages of carboxylic acid solutions is their potential for cost-effective production. The raw materials required for synthesizing carboxylic acids are generally abundant and relatively inexpensive. This factor contributes to the overall economic feasibility of implementing these solutions on a larger scale. However, the production process itself may require specialized equipment and controlled environments, which could impact the initial investment costs.
When considering scalability, it is essential to evaluate the production capacity of carboxylic acid solutions. Current manufacturing processes can be adapted to increase output, but careful consideration must be given to maintaining product quality and consistency at higher volumes. Additionally, the storage and transportation of large quantities of carboxylic acid solutions present logistical challenges that need to be addressed to ensure cost-effective distribution.
The integration of carboxylic acid solutions into existing energy storage infrastructure is another crucial aspect of scalability. Retrofitting current systems or designing new ones to accommodate these solutions may require significant investment. However, the potential long-term benefits in terms of improved energy storage efficiency and reduced environmental impact could offset these initial costs.
Cost analysis of carboxylic acid solutions must also consider their performance characteristics in comparison to traditional energy storage technologies. Factors such as energy density, cycle life, and operational efficiency play a vital role in determining the overall cost-effectiveness of these solutions. While carboxylic acid-based systems may have higher upfront costs, their potential for longer lifespan and improved efficiency could result in lower total cost of ownership over time.
Environmental considerations also factor into the cost analysis. The use of carboxylic acid solutions in energy storage may lead to reduced environmental impact compared to some conventional technologies. This could result in potential cost savings through reduced regulatory compliance expenses and improved public perception, which may translate to market advantages.
As research and development in this field progress, economies of scale are likely to drive down production costs. Increased demand for carboxylic acid solutions in energy storage applications could lead to more efficient manufacturing processes and supply chain optimizations, further improving the economic viability of large-scale implementation.
One of the primary advantages of carboxylic acid solutions is their potential for cost-effective production. The raw materials required for synthesizing carboxylic acids are generally abundant and relatively inexpensive. This factor contributes to the overall economic feasibility of implementing these solutions on a larger scale. However, the production process itself may require specialized equipment and controlled environments, which could impact the initial investment costs.
When considering scalability, it is essential to evaluate the production capacity of carboxylic acid solutions. Current manufacturing processes can be adapted to increase output, but careful consideration must be given to maintaining product quality and consistency at higher volumes. Additionally, the storage and transportation of large quantities of carboxylic acid solutions present logistical challenges that need to be addressed to ensure cost-effective distribution.
The integration of carboxylic acid solutions into existing energy storage infrastructure is another crucial aspect of scalability. Retrofitting current systems or designing new ones to accommodate these solutions may require significant investment. However, the potential long-term benefits in terms of improved energy storage efficiency and reduced environmental impact could offset these initial costs.
Cost analysis of carboxylic acid solutions must also consider their performance characteristics in comparison to traditional energy storage technologies. Factors such as energy density, cycle life, and operational efficiency play a vital role in determining the overall cost-effectiveness of these solutions. While carboxylic acid-based systems may have higher upfront costs, their potential for longer lifespan and improved efficiency could result in lower total cost of ownership over time.
Environmental considerations also factor into the cost analysis. The use of carboxylic acid solutions in energy storage may lead to reduced environmental impact compared to some conventional technologies. This could result in potential cost savings through reduced regulatory compliance expenses and improved public perception, which may translate to market advantages.
As research and development in this field progress, economies of scale are likely to drive down production costs. Increased demand for carboxylic acid solutions in energy storage applications could lead to more efficient manufacturing processes and supply chain optimizations, further improving the economic viability of large-scale implementation.
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