Rat bite-proof adhesive film and preparation method thereof

Abstract

The invention belongs to the field of adhesives, and particularly relates to an adhesive film with the classification number of C09J7 / 00, in particular to a rat bite prevention adhesive film and a preparation method thereof. The rat-bite-proof adhesive film structurally comprises an adhesive layer and a base material layer, the adhesive layer is made of an adhesive, the adhesive is prepared from at least a basic polymer, tackifying resin and a smell repellent, and the smell repellent comprises bitter essence S and capsaicin. The prepared rat-bite-proof adhesive film is excellent in adhesive performance and rat-proof effect and can be completely peeled off after being used, no adhesive residue appears, in addition, the rat-bite-proof adhesive film is wide in preparation raw material source and low in cost, and the product has the excellent actual use effect.

Description

Technical Field

[0001] The present invention belongs to the field of adhesives, and in particular relates to classification number: C09J7 / 00, and more specifically, to a rat-proof adhesive film and a preparation method thereof. Background Art

[0002] As we all know, rats' teeth grow throughout their lives. To prevent their teeth from growing too long, rats often choose to grind their teeth by constantly gnawing on objects. Communication optical cables, especially the plastic protective layer of optical cables, are often eaten by rats because of their special smell. After the optical cables are eaten, the plastic protective layer on the outer layer of the optical cables is damaged, exposing the inner cable core. Once the cable core is damaged, the communication transmission function of the optical cable will be seriously affected, resulting in serious drop in communication signals, network interruption, data loss and other problems, causing significant economic losses. Therefore, preventing optical cables from being bitten by rats has become a global problem.

[0003] Patent CN117170054A discloses a rat-proof optical cable with a multi-layer rat-proof structure, which includes a physical rat-proof layer and a chemical rat-proof layer, wherein the physical rat-proof layer includes a cone-thorn layer, the cone-thorn layer includes an inner ring layer and a multi-layer tooth layer, and the sharp teeth of adjacent tooth layers are staggered, which can effectively prevent rat bites, but the structure of the physical rat-proof layer is relatively complex, which is not conducive to large-scale promotion; Patent CN109585083A discloses an anti-rat and ant protective material, and its preparation raw materials include: rubber, polyethylene, polyolefin, regenerated rubber, silane coupling agent, filler, camphor, pyrethrin, aromatic hydrocarbon sustained-release agent, etc., but the preparation raw materials of the protective material are relatively large and the cost is relatively high, which is also not conducive to large-scale promotion. Therefore, how to provide a rat-proof adhesive film with excellent rat-proof effect and relatively low preparation cost has become an industry technical problem that needs to be solved urgently. Summary of the invention

[0004] In order to solve the above technical problems, the first aspect of the present invention provides a rat-proof adhesive film, the structure of which includes: a substrate layer and an adhesive layer arranged on at least one surface of the substrate layer;

[0005] The rodent-proof adhesive film can be wound into a roll and can be partially unrolled.

[0006] The rat-proof adhesive film described in the present invention can also be processed into sheets or strips in any form, and can not only be wrapped around the adherend, but also be attached to the adherend. It is preferably used in a winding manner. After the rat-proof adhesive film is wrapped around the adhered object, the adhesive film can wrap the adhered object evenly and tightly in an environment at -40 to 170°C.

[0007] The present invention can provide excellent peeling force in the environment where the above-mentioned adhered objects are stored, and will not fall off from the adhered objects, nor cause damage or pollution to the adhered objects. The rat resistance level is not lower than FS2 (the surface of the sample protective layer has bite marks greater than 1mm, but the value should not be greater than 1 / 2 of the thickness of the outer protective layer), and preferably meets the condition of FS1 (the surface of the sample protective layer has no tooth marks or visible bite marks, and the bite depth should be less than 1mm); if the surface of the above-mentioned adhered object does not have an adhesive film with rat-proof function, the adhered object can be easily bitten and damaged by mice, and the appearance and function of the adhered object will be damaged.

[0008] The raw materials for preparing the adhesive layer include an adhesive, and the softening point of the adhesive is 50-170° C. The raw materials for preparing the adhesive include: one or more of a base polymer, a tackifying resin, a functional additive, and an odorant.

[0009] In some preferred embodiments, the 180° peel force of the rat-proof adhesive film relative to SUS304 stainless steel plate at 10-30°C, preferably at around 23°C is 0.2-5 N / cm, preferably 0.5-3 N / cm; when the peel force of the rat-proof adhesive film at 23°C is within the above range, it can show good adhesion. If the peel force of the rat-proof adhesive film at around 23°C is less than 0.2 N / cm, it is easy to fall off the adherend. If the peel force of the rat-proof adhesive film at around 23°C is greater than 5 N / cm, it is not easy to peel off from the adherend. The above peel force can be measured in subsequent examples.

[0010] Base material layer

[0011] The substrate layer constituting the rat-proof adhesive film disclosed in the present invention is selected according to the use mode and method of the rat-proof adhesive film, and preferably a high-temperature resistant polymer material is used as the substrate, for example: a polyolefin film with polyolefins such as polypropylene, polystyrene, and cycloolefin polymer as the main component, a polyester film and a polyester cloth with polyesters such as polymethyl methacrylate, polyethylene naphthalate, polyethylene terephthalate, and polycarbonate as the main component; or a polyvinyl chloride film with polyvinyl chloride and polyvinylidene chloride as the main component, and polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), fluorinated ethylene propylene copolymer (FEP), polyvinyl fluoride ( Fluorine-containing polymer films with PVF) ethylene-tetrafluoroethylene copolymer (ETFE), ethylene-chlorotrifluoroethylene copolymer (ECTFE) and FKM (fluororubber) as main components, silicon-containing polymer films with polydimethylsiloxane as main component, plant fiber films such as kraft paper, masking paper, cellophane with plant fiber as main component, metal films with copper, aluminum and zinc as main components. The main components of the materials of the above films can be one or more composite materials, and the molding process can be one or more of cast film, extrusion stretching, calendering, blow molding, foaming, melt blowing, weaving, impregnation, coating, electroplating, chemical deposition, physical deposition and composite.

[0012] The substrate layer of the present invention, especially the side contacting the adhesive layer, can be treated on the substrate surface in the following ways in order to improve the bonding strength between the substrate layer and the adhesive layer. The treatment methods may include voltage surface breakdown treatment, flame baking treatment, ozone contact treatment, primer treatment, plasma treatment, etc.

[0013] The thickness of the substrate layer according to the present invention can be set to any reasonable thickness according to the application requirements. The thickness of the substrate layer is preferably 0.02 to 0.53 mm, and more preferably 0.03 to 0.5 mm.

[0014] Furthermore, the bonded layer includes at least one of fluoroplastics, polyethylene, silicone rubber, cross-linked EPDM rubber, polyvinyl chloride, paper, and polyester cloth.

[0015] Furthermore, the dyne value of the bonded layer is 20mN / m-100mN / m, and the Shore hardness is 10A-90D.

[0016] Furthermore, the thickness ratio of the substrate layer to the adhesive layer is (100-150):(10-50).

[0017] Furthermore, the thickness ratio of the substrate layer to the adhesive layer is (100-150):(10-20).

[0018] As an implementable case, the thickness of the rat-proof adhesive film is preferably 0.05 to 0.55 mm, and more preferably 0.06 to 0.3 mm; within this thickness range, excellent adhesion and chewing resistance can be achieved.

[0019] Adhesive layer

[0020] As the adhesive layer constituting the above-mentioned rat-proof adhesive film, any material that meets the requirements can be selected as long as the purpose of the present invention is achieved. For example, rubber-based polymers, polyurethane-based polymers, silicone-based polymers, etc. can be used as base polymers, wherein the component of the base polymer accounts for more than 20% by weight of the total adhesive layer, and the form of the base polymer can be emulsion type, organic solvent type, hot melt type, solvent-free type; the curing method can be physical cross-linking type, thermal curing type, light curing type, etc.

[0021] Hereinafter, each component of the adhesive layer of the present invention will be specifically described. The raw material of the adhesive layer is a binder.

[0022] As an implementable example, the raw materials for preparing the adhesive at least include: a base polymer, a tackifying resin and an anti-odor agent.

[0023] As an implementable example, the mass ratio of the base polymer to the tackifying resin is 10:(1-15).

[0024] Base polymer

[0025] The present invention does not have any special range requirements for the base polymer content. Based on the reliable adhesion requirements, relative to the total amount of the adhesive layer (100% solid content), preferably more than 30% by mass of the base polymer, more preferably more than 35% by mass of the base polymer, by adjusting the content of the base polymer in the adhesive layer to the above range, it can be ensured that the adhesive layer has good wettability and cohesion.

[0026] The base polymer disclosed in the present invention preferably contains the following components: at least one of polyolefin liquid rubber, thermoplastic elastomer, and acrylate polymer; preferably acrylate polymer and thermoplastic elastomer, more preferably a base polymer with a viscosity of 10000 to 700000 mPa·s at 80 to 190°C, more preferably a base polymer with a viscosity of 20000 to 500000 mPa·s at 100 to 150°C.

[0027] As an implementable example, the thermoplastic elastomer includes a styrene-based thermoplastic elastomer.

[0028] As an implementable example, the brand of the acrylic ester polymer includes 65267, which can be purchased from Changxing Chemical.

[0029] As an implementable case, the styrene-based thermoplastic elastomer includes at least one of SBS (styrene-butadiene-styrene block copolymer), SEBS (styrene-ethylene-butylene-styrene block copolymer), SIS (styrene-isoprene-styrene block copolymer), and SEPS (styrene-ethylene-propylene-styrene block copolymer).

[0030] Furthermore, the styrene-based thermoplastic elastomer includes at least one of SBS and SIS.

[0031] As an implementable case, the brand of SBS includes YH-792, which can be purchased from Baling Petrochemical; the brand of SIS includes 4213, which can be purchased from Taiwan Rubber Corporation.

[0032] Tackifying resin

[0033] In a preferred embodiment, the softening point of the tackifying resin is 70 to 180°C, preferably 80 to 170°C, and more preferably 85 to 160°C, in view of the temperature resistance of the adhesive layer and the performance of improving cohesion; the softening point of the tackifying resin is determined based on the softening point test method specified in ASTM E 28.

[0034] As an implementable case, the tackifying resin includes: one or more of terpene phenol resin and its derivatives, petroleum resin and its derivatives, rosin resin and its derivatives.

[0035] As a tackifying resin for rosin resin and its derivatives, it contains tricyclic phenanthrene skeleton strong hydrophobic rigid groups and carbonyl weak hydrophilic groups. These two groups can be modified to give them compatibility with different base polymers, temperature resistance, aging resistance and other properties.

[0036] As an implementable case, the rosin resin and its derivatives are exemplified as follows: gum rosin, tall oil rosin, wood rosin, hydrogenated rosin, polymerized rosin, disproportionated rosin, esterified rosin, maleated rosin and other tackifying resins.

[0037] In the present invention, the terpene phenol resin and its derivatives refer to polymers containing a certain amount of terpene groups, including terpenes and terpene-modified polymers, especially the products of terpene homopolymerization or copolymerization, which may include: α-polyterpene resin, β-terpene resin, terpene phenolic resin and other tackifying resins.

[0038] As an implementable case, the petroleum resin and its derivatives include: one of C5 petroleum resin, hydrogenated C5 petroleum resin, C9 petroleum resin, hydrogenated C9 petroleum resin, C5 / C9 copolymer petroleum resin, and DCPD (dicyclopentadiene) resin.

[0039] As an implementable example, the tackifying resin includes: terpene phenol resin and / or petroleum resin.

[0040] Furthermore, the tackifying resin includes terpene phenol resin and / or C5 petroleum resin.

[0041] As an implementable case, the brands of the terpene phenol resin include T-803L, which can be purchased from Arakawa, Japan; the brands of the C5 petroleum resin include JH-3024, which can be purchased from Jinhai Chemical.

[0042] In the present invention, a specific base polymer and a tackifying resin are selected for compounding, wherein the base polymer includes an acrylate polymer and / or a styrene base polymer, and the tackifying resin includes a terpene phenol resin and / or a C5 petroleum resin; wherein the acrylate polymer and the terpene phenol resin have good mutual solubility and both have large polarity, so after the two are compounded, they can be attached to substrates such as steel plates due to strong polarity; and the styrene base polymer and the C5 petroleum resin have good mutual solubility and both have small polarity, so after the two are compounded, they can be attached to substrates such as PP films and PE films due to weak polarity, but it does not mean that the acrylate polymer can only be compounded with the terpene phenol resin, and the styrene base polymer can only be compounded with the C5 petroleum resin. According to the needs of the actual application scenario, the types of base polymers and tackifying resins, mass ratios, etc. can be reasonably selected to meet the coating requirements of different types of substrate layers.

[0043] Functional additives

[0044] As an implementable case, the functional additives include: one or more of antioxidants, plasticizers, anti-UV agents, thixotropic agents, flame retardants, antibacterial agents, pigments, antistatic agents, dispersants, lubricants, toughening agents, and photoinitiators; in the present invention, the functional additives can be reasonably selected according to the performance requirements of the actual product.

[0045] Antioxidants

[0046] As one of the important components of the adhesive layer, the antioxidant has an important role in resisting the thermal oxidation aging and decomposition of the adhesive layer, although the amount of antioxidant added is not much. The antioxidant used in the adhesive mixture is characterized in that the antioxidant is a substance that can destroy free radicals or decompose active hydroperoxides, and it can be at least one of aromatic amines, hindered phenols, phosphites and thioesters.

[0047] In a preferred embodiment, from the viewpoint of preventing or slowing down the decomposition of the polymer in the adhesive layer, taking into account the compatibility, volatility, precipitation and temperature resistance of the antioxidant in the adhesive layer, at least one of the hindered phenol and phosphite antioxidants with an antioxidant molecular weight of 600 to 1300 is preferred.

[0048] Furthermore, the antioxidant is antioxidant 1010 and / or antioxidant 168.

[0049] Plasticizers

[0050] In the present invention, in order to ensure that the adhesive layer has good adhesion even at low temperatures, the adhesive layer preferably contains a plasticizer. The plasticizer can be liquid rubber, mineral oil plasticizer, phthalate plasticizer, fatty dicarboxylic acid, phosphate, polyester, epoxy, and these plasticizers can be used alone or in combination.

[0051] As phthalate plasticizers, benzene compounds containing two ester groups in the molecule can be used, such as dioctyl phthalate (DOP), dibutyl phthalate (DBP), diisooctyl phthalate (DIOP), dioctyl terephthalate (DOTP), diisodecyl phthalate (DIDP), diisononyl phthalate (DINP), diisobutyl phthalate (DIBP), butyl benzyl phthalate (BBP), dimethyl phthalate (DMP), diethyl phthalate (DEP), dicyclohexyl phthalate (DCHP). Preferably, phthalate plasticizers that meet the requirements of Reach and RohS2.0 are used.

[0052] As the liquid rubber plasticizer, there can be mentioned diene liquid rubber, olefin liquid rubber, polyurethane liquid rubber (polyether polyol, polyester polyol), liquid silicone rubber, liquid polysulfide rubber and liquid fluororubber.

[0053] Preferred are diene liquid rubbers and olefin liquid rubbers that can flow at room temperature, such as liquid polybutadiene rubber, liquid nitrile rubber, liquid polyisoprene rubber, liquid styrene butadiene rubber, liquid polyisoprene rubber, liquid polyisobutylene rubber, and the like.

[0054] Diene liquid rubber and olefin liquid rubber having a molecular weight of 500 to 10,000 are preferred. The liquid rubber may be used alone or in combination of two or more.

[0055] Specific examples of the mineral oil plasticizer include, without particular limitation, naphthenic oil, aromatic oil and paraffin oil.

[0056] Preferably, the cycloparaffinic oil has one or more saturated cyclic carbon chain structure molecules in one molecule. The amount of the cycloparaffinic oil used is not particularly limited. For example, 5 to 80 parts of the base polymer are preferably used, and 10 to 70 parts are more preferably used.

[0057] Examples of the fatty dicarboxylic acid plasticizer include dioctyl oxalate (DOA), dioctyl azelate (DOZ), dioctyl sebacate (DOS), and dibutyl sebacate (DBS).

[0058] The phosphate plasticizer may be one or more of tricresyl phosphate, trioctyl phosphate, triphenyl phosphate (TPP), and tributyl phosphate (TBP).

[0059] The polyester plasticizer may be a polyester plasticizer obtained by esterification polymerization of oxalic acid series and diol, or sebacic acid series and diol.

[0060] Examples of the epoxy plasticizer include epoxidized soybean oil, epoxidized linseed oil, epoxidized butyl oleate, epoxidized octyl ester, and epoxidized tetrahydrophthalate.

[0061] Furthermore, the plasticizer is cyclohexane oil.

[0062] Flame retardants

[0063] The adhesive layer is added with flame retardants to improve the flame resistance of the rat-proof adhesive film material, prevent the material from being ignited and inhibit the spread of flames, which helps prevent fires and slow down the spread of fire when a fire occurs. Halogen flame retardants, phosphorus-containing flame retardants, and inorganic flame retardants can be used as flame retardants.

[0064] As a flame retardant, it can prevent the flame from continuing to burn the material by absorbing heat, covering, interrupting chain reactions, or asphyxiating the gas. It can be used alone or in combination with one or more.

[0065] As halogen flame retardants, additive flame retardants mainly include: decabromodiphenyl ether (DBDPO), tetrabromobisphenol A, octabromodiphenyl ether (OBDPO), etc.; reactive flame retardants mainly include: tetrabromobisphenol A (TBBPA), 2,4,6-tribromophenol, etc.; polymer flame retardants mainly include brominated polystyrene, brominated epoxy, tetrabromobisphenol A carbonate polymer, etc.

[0066] As phosphorus-containing flame retardants, ammonium polyphosphate, tricresyl phosphate (TCP), diphenylcresyl phosphate (CDP) and triphenyl phosphate (TPP) can be used. Among aliphatic phosphates, the more important ones are trioctyl phosphate (TOP), phosphaphenanthrene (DOPO), phosphazene compounds, organic phosphinic acid and organic phosphinic acid salts.

[0067] As the inorganic flame retardant, aluminum oxide, magnesium hydroxide, expanded graphite, borate, aluminum oxalate, zinc sulfide, and the like can be used.

[0068] The rat-proof adhesive film preferably has a flame retardant grade not lower than Grade C, and the flame retardant grade is determined based on the test method for "Combustion Characteristics of Automobile Interior Materials" specified in GB 8410-2006.

[0069] Furthermore, the functional additives include: antioxidants and / or plasticizers.

[0070] Odor-repellent

[0071] As the repellent, conventional repellents can be used, for example bittering agents, spicy agents, odorants, etc. These repellents can be used alone or in combination of two or more. From the perspective of irritation to mice, preferred are: denatonium benzoate bittering agents and / or capsaicin-type spicy substances.

[0072] As bittering agents among the repellents, benzoic acid [2-[(2,6-dimethylphenyl)amino]-N,N-diethylbenzylammonium (bitter) and o-sulfonylbenzoimide [2-[(2,6-dimethylphenyl)amino]-2-oxoethyl]-N,N-diethylbenzylammonium (bitter S) can be used. Among them, the bitterness of bitter S is about 4 times that of bitter, but bitter is highly soluble in water, while bitter S is not easily soluble in water. As the pungent agent among the repellents, trans-8-methyl-N-vanillyl-6-nonenamide (capsaicin) and its modified compounds with pungent function can be used.

[0073] Furthermore, the capsaicinoid spicy substance includes capsaicin; and the denatonium benzoate bittering agent includes bitters S.

[0074] Furthermore, the mass percentage of the repellent in the adhesive is 0.3-18%.

[0075] In order to improve the rat-repellent effect of the rat-proof adhesive film, the present invention preferably uses bitters S or capsaicin as the taste-repellent, wherein the strong bitter taste of bitters S is a very unpleasant taste for mice. When mice come into contact with the rat-proof adhesive film containing bitters S, they will choose to avoid these items due to the unbearable bitter taste. In addition, compared with some chemical rodenticides, bitters S has higher safety and will not kill mice directly, but will drive them away through bitterness, so it is relatively friendly to humans and other animals. Capsaicin can stimulate the central nervous system and peripheral nerve endings of mice, especially the capsaicin receptor (VR1). This stimulation will cause mice to have a highly nervous and fearful reaction, thereby The rat repellent effect can be achieved, and capsaicin is safe, non-toxic, natural, green and effective, and is also relatively friendly to humans and other animals. However, the amount of the repellent used needs to be further limited. When the amount of the repellent is too small, the rat repellent effect is not obvious, and when the amount of the repellent is too large, the mass proportion of the base polymer and the tackifying resin in the adhesive raw material system is relatively small, so the cohesive force of the adhesive layer is significantly reduced, and the peeling force is also increased accordingly. The rat-proof adhesive film is peeled off after use, and residual glue is likely to appear. Therefore, the present invention limits the mass percentage of the repellent in the adhesive to 0.3-18%, so as to achieve a performance balance between effective rat repellent and peeling without residual glue.

[0076] The second aspect of the present invention provides a method for preparing a rat-proof adhesive film.

[0077] The rat-proof adhesive film of the present invention can be produced by any suitable method, for example, by the following method: first preparing an adhesive, coating the adhesive on a substrate layer to form an adhesive layer; or coating the adhesive on a suitable substrate layer to form an adhesive layer, and then attaching the adhesive layer to a substrate by laminating the substrate layer, etc.

[0078] The manufacturing method of the above-mentioned rat-proof adhesive film can be achieved by any suitable coating process. For example, each layer can be achieved by coating or by UV irradiation after coating. The following can be listed as coating methods: multi-pass coating, gravure printing, extrusion coating, spraying, painting, impregnation coating, screen printing, blade coating, reverse roller coating, lip coating, etc. The processing temperature can be set to any suitable temperature while satisfying the material properties of the processing object.

[0079] As an practicable example, the method for preparing the rat-proof adhesive film comprises:

[0080] S1. Put the base polymer into a stirred tank, evacuate the tank, and heat for 20-40 minutes;

[0081] S2, then add 30-60% of the total amount of tackifying resin, evacuate, and heat for 20-40 minutes;

[0082] S3, then put the remaining tackifying resin into the stirring kettle, evacuate the vacuum, and heat for 20-40 minutes;

[0083] S4, then put the odor-repellent into the stirring kettle, evacuate the kettle, and heat for 20-40 minutes;

[0084] S5, discharging and cooling to room temperature to obtain an adhesive;

[0085] S6. Evenly apply the adhesive to one side of the substrate layer to form an adhesive layer, thereby obtaining a rat-proof adhesive film.

[0086] The rat-proof adhesive film disclosed in the present invention can be pasted or wrapped around various equipment or devices for protection purposes. For example, the rat-proof adhesive film can be used for wires and cables, ropes, pipes, leather goods, wooden products and any other items and parts thereof that have been gnawed by rats, in indoor or outdoor places where rats are present.

[0087] Beneficial Effects

[0088] (i) The raw materials of the adhesive in the present invention are selected from the base polymer and the tackifying resin, which can ensure that the adhesive layer has a high peeling force and excellent bonding performance. It can not only be attached to the adhered object in the form of a sheet, but also can be wrapped around the protected object in the form of a strip, with excellent adhesion.

[0089] (ii) Based on the different types of substrates to be bonded, the present invention can select different types of base polymers and tackifying resins for compounding, and the application range of the rat-proof adhesive film is relatively large.

[0090] (III) The present invention preferably uses bitter essence S and capsaicin as the taste retardants, which can effectively prevent mice from continuously gnawing and destroying the protected objects. It not only has excellent rodent repelling effect, but also has no effect on the life safety of humans and other creatures.

[0091] (iv) The rat-proof adhesive film prepared by the present invention not only has excellent adhesive properties, but can also be completely peeled off after use without residual adhesive, and has excellent use effect.

[0092] (V) The raw materials for preparing the rat-proof adhesive film provided by the present invention are from a wide range of sources and have a low cost. In addition, the structure of the rat-proof adhesive film is simple and is expected to be market-oriented and applied. BRIEF DESCRIPTION OF THE DRAWINGS

[0093] Figure 1 This is a schematic diagram of the unfolded structure of the rat-proof adhesive layer prepared in Example 1.

[0094] Figure 2 Schematic diagram of the structure of the rat-proof adhesive layer prepared in Example 1, wherein: 1-adhesive layer, 2-substrate layer.

[0095] Figure 3 Schematic diagram of the winding structure of the rodent-proof adhesive film in the rodent-proof grade test.

[0096] Figure 4-7 Schematic diagram of the actual results of third-party testing of rodent resistance performance. DETAILED DESCRIPTION

[0097] Example 1

[0098] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0099] The raw materials for preparing the adhesive layer include adhesive; the raw materials of the adhesive include, by weight, 100 parts of SIS, 150 parts of terpene phenol resin, 1.4 parts of antioxidant 1010, 2.8 parts of antioxidant 168, 30 parts of cyclohexane oil, and 2.84 parts of capsaicin.

[0100] Among them, the brand of SIS is 4213, purchased from TSRC; the brand of terpene phenol resin is T-803L, purchased from Arakawa, Japan; antioxidant 168 and antioxidant 1010 are both common commercial products; the brand of cyclohexane oil is KN4010, purchased from Karamay; capsaicin is a common commercial product.

[0101] The substrate layer is polyester cloth.

[0102] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0103] S1. Open the reactor and heat it to 90°C. Add the weighed SIS, antioxidant 1010, antioxidant 168 and half of the total amount of cyclohexane oil into the stirred tank. Then heat it to 160°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0104] S2. Add one third of the total amount of T-803L into the stirring kettle, evacuate the kettle, and continue stirring at 160°C for 20 minutes.

[0105] S3. Add the remaining terpene phenol resin into the stirring kettle, evacuate the kettle, and continue stirring at 160° C. for 20 min.

[0106] S4. Add the remaining cycloalkane oil into the stirred kettle, evacuate the kettle, and continue stirring at 160°C for 20 minutes.

[0107] S5. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 160° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is then stored at room temperature.

[0108] S6. Use a polyester cloth with a gram weight of 100 g and a thickness of 125 μm as the base layer, and evenly apply an adhesive with a temperature of 150° C. on one side of the base layer to form an adhesive layer with a thickness of 10 μm.

[0109] The schematic diagram of the unfolded structure of the rat-proof adhesive layer prepared in this example is as follows Figure 1 shown.

[0110] The schematic diagram of the structure of the rat-proof adhesive layer prepared in this example is as follows Figure 2 As shown, wherein: 1-adhesive layer, 2-substrate layer.

[0111] Example 2

[0112] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0113] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of SBS, 150 parts of terpene phenol resin, 1.4 parts of antioxidant 1010, 2.8 parts of antioxidant 168, 30 parts of cyclohexane oil, and 2.84 parts of capsaicin.

[0114] Among them, the brand of SBS is YH-792, purchased from Baling Petrochemical; the brand of terpene phenol resin is T-803L, purchased from Arakawa, Japan; antioxidant 168 and antioxidant 1010 are both common commercial products; the brand of cyclohexane oil is KN4010, purchased from Karamay; capsaicin is a common commercial product.

[0115] The substrate layer is polyester cloth.

[0116] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0117] S1. Open the reactor and heat it to 90°C. Add the weighed SBS, antioxidant 1010, antioxidant 168 and half of the total amount of cyclohexane oil into the stirred tank. Then heat it to 160°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0118] S2. Add one third of the total amount of T-803L into the stirring kettle, evacuate the kettle, and continue stirring at 160°C for 20 minutes.

[0119] S3. Add the remaining terpene phenol resin into the stirring kettle, evacuate the kettle, and continue stirring at 160° C. for 20 min.

[0120] S4. Add the remaining cycloalkane oil into the stirred kettle, evacuate the kettle, and continue stirring at 160°C for 20 minutes.

[0121] S5. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 160° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is then stored at room temperature.

[0122] S6. Use a polyester cloth with a gram weight of 100 g and a thickness of 125 μm as the base layer, and evenly apply an adhesive with a temperature of 150° C. on one side of the base layer to form an adhesive layer with a thickness of 10 μm.

[0123] Example 3

[0124] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0125] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of an acrylate polymer, 10 parts of a terpene phenol resin, and 1.1 parts of capsaicin.

[0126] The acrylate polymer was of brand 65267 purchased from Changxing Chemical; the terpene phenol resin was of brand T-803L purchased from Arakawa, Japan; and capsaicin was a common commercial product.

[0127] The substrate layer is polyester cloth.

[0128] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0129] S1. Open the reactor and heat it to 90°C. Put the weighed acrylate polymer into the stirring reactor under a yellow light. Then heat it to 150°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0130] S2. Pour one third of the total amount of T-803L into the stirring kettle, evacuate the vessel, and continue stirring at 150°C for 20 minutes.

[0131] S3. Add the remaining terpene phenol resin into the stirring kettle, evacuate the kettle, and continue stirring at 150° C. for 20 min.

[0132] S4. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 150° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature away from light.

[0133] S5, a polyester cloth with a weight of 100g and a thickness of 125μm is used as the substrate layer. An adhesive with a temperature of 150℃ is evenly coated on one side of the substrate layer to form an adhesive layer with a thickness of 10μm. Then, the adhesive layer is exposed to UVC light with an energy of 40mJ / cm 2 Under the conditions of UV light, use UV lamp for light curing to obtain the product.

[0134] Example 4

[0135] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0136] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of an acrylic acid ester polymer, 10 parts of a terpene phenol resin, and 0.33 parts of bitter S.

[0137] The acrylate polymer was of brand 65267 purchased from Changxing Chemical; the terpene phenol resin was of brand T-803L purchased from Arakawa, Japan; and bitter essence S was a common commercial product.

[0138] The substrate layer is polyester cloth.

[0139] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0140] S1. Open the reactor and heat it to 90°C. Put the weighed acrylate polymer into the stirring reactor under a yellow light. Then heat it to 150°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0141] S2. Pour one third of the total amount of T-803L into the stirring kettle, evacuate the vessel, and continue stirring at 150°C for 20 minutes.

[0142] S3. Add the remaining terpene phenol resin into the stirring kettle, evacuate the kettle, and continue stirring at 150° C. for 20 min.

[0143] S4. Add bitter essence S into a stirring kettle, evacuate the kettle, continue stirring at 150° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature away from light.

[0144] S5, a polyester cloth with a weight of 100g and a thickness of 125μm is used as the substrate layer. An adhesive with a temperature of 150°C is evenly coated on one side of the substrate layer to form an adhesive layer with a thickness of 20μm. Then, the adhesive layer is exposed to UVC light with an energy of 40mJ / cm 2 Under the conditions of UV light, use UV lamp for light curing to obtain the product.

[0145] Example 5

[0146] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0147] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of an acrylate polymer, 10 parts of a terpene phenol resin, and 2.2 parts of capsaicin.

[0148] The acrylate polymer was of brand 65267 purchased from Changxing Chemical; the terpene phenol resin was of brand T-803L purchased from Arakawa, Japan; and capsaicin was a common commercial product.

[0149] The substrate layer is polyester cloth.

[0150] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0151] S1. Open the reactor and heat it to 90°C. Put the weighed acrylate polymer into the stirring reactor under a yellow light. Then heat it to 150°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0152] S2. Pour one third of the total amount of T-803L into the stirring kettle, evacuate the vessel, and continue stirring at 150°C for 20 minutes.

[0153] S3. Add the remaining terpene phenol resin into the stirring kettle, evacuate the kettle, and continue stirring at 150° C. for 20 min.

[0154] S4. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 150° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature away from light.

[0155] S5, a polyester cloth with a weight of 100g and a thickness of 125μm is used as the substrate layer. An adhesive with a temperature of 150°C is evenly coated on one side of the substrate layer to form an adhesive layer with a thickness of 20μm. Then, the adhesive layer is exposed to UVC light with an energy of 40mJ / cm 2 Under the conditions of UV light, use UV lamp for light curing to obtain the product.

[0156] Example 6

[0157] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0158] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of an acrylic acid ester polymer, 20 parts of a terpene phenol resin, and 2.4 parts of capsaicin.

[0159] The acrylate polymer was of brand 65267 purchased from Changxing Chemical; the terpene phenol resin was of brand T-803L purchased from Arakawa, Japan; and capsaicin was a common commercial product.

[0160] The substrate layer is polyester cloth.

[0161] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0162] S1. Open the reactor and heat it to 90°C. Put the weighed acrylate polymer into the stirring reactor under a yellow light. Then heat it to 150°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0163] S2. Pour one third of the total amount of T-803L into the stirring kettle, evacuate the vessel, and continue stirring at 150°C for 20 minutes.

[0164] S3. Add the remaining terpene phenol resin into the stirring kettle, evacuate the kettle, and continue stirring at 150° C. for 20 min.

[0165] S4. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 150° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature away from light.

[0166] S5, a polyester cloth with a weight of 100g and a thickness of 125μm is used as the substrate layer. An adhesive with a temperature of 150°C is evenly coated on one side of the substrate layer to form an adhesive layer with a thickness of 20μm. Then, the adhesive layer is exposed to UVC light with an energy of 40mJ / cm 2 Under the conditions of UV light, use UV lamp for light curing to obtain the product.

[0167] Example 7

[0168] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0169] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of an acrylic acid ester polymer, 10 parts of a C5 petroleum resin, and 2.2 parts of capsaicin.

[0170] Among them, the brand of acrylate polymer is 65267, purchased from Changxing Chemical; the brand of C5 petroleum resin is JH-3204, purchased from Jinhai Chemical; and capsaicin is a common commercial product.

[0171] The substrate layer is polyester cloth.

[0172] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0173] S1. Open the reactor and heat it to 90°C. Put the weighed acrylate polymer into the stirring reactor under a yellow light. Then heat it to 150°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0174] S2. Add half of the total amount of C5 petroleum resin into the stirring kettle, evacuate the kettle, and continue stirring at 150°C for 20 minutes.

[0175] S3. Add the remaining amount of C5 petroleum resin into the stirring kettle, evacuate the mixture, and continue stirring at 150°C for 20 minutes.

[0176] S4. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 150° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature away from light.

[0177] S5, a polyester cloth with a weight of 100g and a thickness of 125μm is used as the substrate layer. An adhesive with a temperature of 150°C is evenly coated on one side of the substrate layer to form an adhesive layer with a thickness of 20μm. Then, the adhesive layer is exposed to UVC light with an energy of 40mJ / cm 2 Under the conditions of UV light, use UV lamp for light curing to obtain the product.

[0178] Example 8

[0179] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0180] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of an acrylic acid ester polymer, 10 parts of a C5 petroleum resin, and 12.22 parts of capsaicin.

[0181] Among them, the brand of acrylate polymer is 65267, purchased from Changxing Chemical; the brand of C5 petroleum resin is JH-3204, purchased from Jinhai Chemical; and capsaicin is a common commercial product.

[0182] The substrate layer is polyester cloth.

[0183] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0184] S1. Open the reactor and heat it to 90°C. Put the weighed acrylate polymer into the stirring reactor under a yellow light. Then heat it to 150°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0185] S2. Add half of the total amount of C5 petroleum resin into the stirring kettle, evacuate the kettle, and continue stirring at 150°C for 20 minutes.

[0186] S3. Add the remaining amount of C5 petroleum resin into the stirring kettle, evacuate the mixture, and continue stirring at 150°C for 20 minutes.

[0187] S4. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 150° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature away from light.

[0188] S5, a polyester cloth with a weight of 100g and a thickness of 125μm is used as the substrate layer. An adhesive with a temperature of 150°C is evenly coated on one side of the substrate layer to form an adhesive layer with a thickness of 20μm. Then, the adhesive layer is exposed to UVC light with an energy of 40mJ / cm 2 Under the conditions of UV light, use UV lamp for light curing to obtain the product.

[0189] Example 9

[0190] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0191] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of an acrylic acid ester polymer, 20 parts of a terpene phenol resin, and 0.6 parts of capsaicin.

[0192] The acrylate polymer was of brand 65267 purchased from Changxing Chemical; the terpene phenol resin was of brand T-803L purchased from Arakawa, Japan; and capsaicin was a common commercial product.

[0193] The substrate layer is polyester cloth.

[0194] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0195] S1. Open the reactor and heat it to 90°C. Put the weighed acrylate polymer into the stirring reactor under a yellow light. Then heat it to 150°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0196] S2. Pour one third of the total amount of T-803L into the stirring kettle, evacuate the vessel, and continue stirring at 150°C for 20 minutes.

[0197] S3. Add the remaining terpene phenol resin into the stirring kettle, evacuate the kettle, and continue stirring at 150° C. for 20 min.

[0198] S4. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 150° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature away from light.

[0199] S5, a polyester cloth with a weight of 100g and a thickness of 125μm is used as the substrate layer. An adhesive with a temperature of 150℃ is evenly coated on one side of the substrate layer to form an adhesive layer with a thickness of 10μm. Then, the adhesive layer is exposed to UVC light with an energy of 40mJ / cm 2 Under the conditions of UV light, use UV lamp for light curing to obtain the product.

[0200] Comparative Example 1

[0201] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0202] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of an acrylate polymer, 20 parts of a terpene phenol resin, and 0.24 parts of capsaicin.

[0203] The acrylate polymer was of brand 65267 purchased from Changxing Chemical; the terpene phenol resin was of brand T-803L purchased from Arakawa, Japan; and capsaicin was a common commercial product.

[0204] The substrate layer is polyester cloth.

[0205] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0206] S1. Open the reactor and heat it to 90°C. Put the weighed acrylate polymer into the stirring reactor under a yellow light. Then heat it to 150°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0207] S2. Pour one third of the total amount of T-803L into the stirring kettle, evacuate the vessel, and continue stirring at 150°C for 20 minutes.

[0208] S3. Add the remaining terpene phenol resin into the stirring kettle, evacuate the kettle, and continue stirring at 150° C. for 20 min.

[0209] S4. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 150° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature away from light.

[0210] S5, a polyester cloth with a weight of 100g and a thickness of 125μm is used as the substrate layer. An adhesive with a temperature of 150℃ is evenly coated on one side of the substrate layer to form an adhesive layer with a thickness of 10μm. Then, the adhesive layer is exposed to UVC light with an energy of 40mJ / cm 2 Under the conditions of UV light, use UV lamp for light curing to obtain the product.

[0211] Comparative Example 2

[0212] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0213] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of SIS, 0.65 parts of antioxidant 1010, 1.3 parts of antioxidant 168, 30 parts of cyclohexane oil, and 0.66 parts of capsaicin.

[0214] Among them, the brand of SIS is 4213, purchased from TSRC; antioxidant 168 and antioxidant 1010 are both common commercial products; the brand of cyclohexane oil is KN4010, purchased from Karamay; capsaicin is a common commercial product.

[0215] The substrate layer is polyester cloth.

[0216] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0217] S1. Open the reactor and heat it to 90°C. Add the weighed 4213, antioxidant 1010, antioxidant 168 and half of the total amount of cyclohexane oil into the stirred tank. Then heat it to 160°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0218] S2. Add the remaining cyclohexane oil into the stirred kettle, evacuate the kettle, and continue stirring at 160°C for 20 minutes.

[0219] S3. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 160° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature.

[0220] S4. Use a polyester cloth with a gram weight of 100 g and a thickness of 125 μm as the base layer, and evenly coat an adhesive with a temperature of 150° C. on one side of the base layer to form an adhesive layer with a thickness of 10 μm.

[0221] Comparative Example 3

[0222] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0223] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of an acrylic acid ester polymer, 10 parts of a terpene phenol resin, and 0.17 parts of bitter S.

[0224] The acrylate polymer was of brand 65267 purchased from Changxing Chemical; the terpene phenol resin was of brand T-803L purchased from Arakawa, Japan; and bitter essence S was a common commercial product.

[0225] The substrate layer is polyester cloth.

[0226] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0227] S1. Open the reactor and heat it to 90°C. Put the weighed acrylate polymer into the stirring reactor under a yellow light. Then heat it to 150°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0228] S2. Pour one third of the total amount of T-803L into the stirring kettle, evacuate the vessel, and continue stirring at 150°C for 20 minutes.

[0229] S3. Add the remaining terpene phenol resin into the stirring kettle, evacuate the kettle, and continue stirring at 150° C. for 20 min.

[0230] S4. Add bitter essence S into a stirring kettle, evacuate the kettle, continue stirring at 150° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature away from light.

[0231] S5, a polyester cloth with a weight of 100g and a thickness of 125μm is used as the substrate layer. An adhesive with a temperature of 150°C is evenly coated on one side of the substrate layer to form an adhesive layer with a thickness of 20μm. Then, the adhesive layer is exposed to UVC light with an energy of 40mJ / cm 2 Under the conditions of UV light, use UV lamp for light curing to obtain the product.

[0232] Comparative Example 4

[0233] In a first aspect, the present example provides a rat-proof adhesive film, which includes an adhesive layer and a substrate layer.

[0234] The raw materials for preparing the adhesive layer include an adhesive; the raw materials of the adhesive include, by weight, 100 parts of an acrylic acid ester polymer, 10 parts of a terpene phenol resin, and 27.5 parts of capsaicin.

[0235] The acrylate polymer was of brand 65267 purchased from Changxing Chemical; the terpene phenol resin was of brand T-803L purchased from Arakawa, Japan; and capsaicin was a common commercial product.

[0236] The substrate layer is polyester cloth.

[0237] The second aspect of this example provides a method for preparing a rat-proof adhesive film, comprising:

[0238] S1. Open the reactor and heat it to 90°C. Put the weighed acrylate polymer into the stirring reactor under a yellow light. Then heat it to 150°C, evacuate it, and heat and stir for about 30 minutes until the raw materials are completely melted.

[0239] S2. Pour one third of the total amount of T-803L into the stirring kettle, evacuate the vessel, and continue stirring at 150°C for 20 minutes.

[0240] S3. Add the remaining terpene phenol resin into the stirring kettle, evacuate the kettle, and continue stirring at 150° C. for 20 min.

[0241] S4. Add capsaicin into the stirring kettle, evacuate the kettle, continue stirring at 150° C. for 20 min, then discharge the mixture and cool it to room temperature to obtain an adhesive, which is stored at room temperature away from light.

[0242] S5, a polyester cloth with a weight of 100g and a thickness of 125μm is used as the substrate layer. An adhesive with a temperature of 150°C is evenly coated on one side of the substrate layer to form an adhesive layer with a thickness of 20μm. Then, the adhesive layer is exposed to UVC light with an energy of 40mJ / cm 2 Under the condition of , UV lamp is used for light curing to obtain. The component raw material information of Examples 1-9 and Comparative Examples 1-4 is shown in Table 1 and Table 1 continuation.

[0243] Table 1

[0244]

[0245]

[0246] Table 1 continued

[0247]

[0248]

[0249] Performance Testing

[0250] 1. Peel force test

[0251] The rat-proof adhesive films in Examples 1-9 and Comparative Examples 1-4 were made into samples with a length of 150 mm and a width of 25 mm. A SUS430 steel plate cleaned with toluene and anhydrous ethanol was used as a test laminate. The sample was laminated on the 430 steel plate in a standard environment of 23°C and 50% RH (humidity). An automatic roller press was used with a rolling speed of 600±30 mm / min and a 2 kg rubber roller was rolled back and forth 2 times to press the sample on the 430 steel plate. After the sample was prepared, it was necessary to test it within 1 minute. According to the provisions of ISO 29862, a universal material testing machine (Kejian tensile machine) was used to peel it at a tensile speed of 300 m / min and a peeling angle of 180°. Three samples were tested in each group, and the arithmetic mean of the three data results was taken as the result; unit: N / cm.

[0252] The experimental test results are recorded in Table 3.

[0253] 2. Residual adhesive test

[0254] The rat-proof adhesive films in Examples 1-9 and Comparative Examples 1-4 were made into samples with a length of 150 mm and a width of 25 mm. A SUS430 steel plate cleaned with toluene and anhydrous ethanol was used as a test laminate. The sample was laminated on the 430 steel plate in a standard environment of 23°C and 50% RH. An automatic roller press was used with a rolling speed of 600±30 mm / min and a 2 kg rubber roller was rolled back and forth 2 times to press the sample on the 430 steel plate. After the sample was prepared, it was necessary to test it within 1 minute. According to ISO 29862, a universal material testing machine (Kejian tensile machine) was used to peel it at a tensile speed of 300 m / min and a peeling angle of 180°. Three samples were tested in each group, and the surface of the 430 steel plate after peeling was observed.

[0255] ○: No residual glue under 100x optical microscope observation.

[0256] ×: There is residual adhesive when observed under a 100x optical microscope.

[0257] The experimental test results are recorded in Table 3.

[0258] 3. Rodent-proof level test

[0259] The rat-proof adhesive film was made into a strip with a width of 25 mm and a length of 700 mm. The strip was wound with 12 0.5 mm 2 The cable should be tightly wound and bundled. The tape should be applied to the test sample from the bottom, and each circle of tape should overlap the width of the previous tape by half, making a 300mm long wire harness to be tested. The two ends are fixed with iron wire. The wound structure is as follows: Figure 3 shown.

[0260] Refer to JB / T 10696.10 Test methods for mechanical and physical and chemical properties of wires and cables Part 10: Rat gnawing test, and test the samples for 14 consecutive days. Feed SD (Sprague Dawley) rats normally every day, observe the rat activities, diet and sample gnawing conditions, and make a description record of the sample surface, and assess the protection level according to Table 2 below.

[0261] Table 2 Evaluation of the protection level of rat-proof adhesive film to rats

[0262]

[0263] The experimental test results are recorded in Table 3.

[0264] Table 3

[0265]

[0266]

[0267] As can be seen from Table 3, Examples 1 to 9 have excellent protection levels. After the objects are adhered or wrapped with the rat-proof adhesive film, the adhered objects can be significantly protected from being damaged by the gnawing of outdoor SD rats. In addition, the rat-proof adhesive film has excellent peelability, not only having good adhesion but also being able to be peeled off after use without leaving residual adhesive pollution on the adhered objects.

[0268] In Comparative Examples 1 to 4, as shown in Table 3, due to the low content of the anorectant in Comparative Examples 1 and 3, the protective effect against rats' gnawing cannot be achieved, resulting in the wires being damaged by rats' gnawing and exposing the metal wires. In Comparative Example 2, since no tackifying resin is included, the peeling force is low and the adhesive cannot be closely attached to the adhered object, resulting in unsatisfactory protective effect. In Comparative Example 4, the glue cohesion is poor and it is not easy to peel off after use, resulting in residual glue pollution after peeling, and the requirement of no residual glue after peeling cannot be met.

[0269] 4. Third-party testing of anti-rat bite performance

[0270] Test object: the product prepared in Example 1.

[0271] Test method: third-party inspection, testing unit: National Wire and Cable Quality Inspection and Testing Center / Shanghai Guolan Testing Co., Ltd.

[0272] Test basis: Refer to GB / T 12706.1-2020 Rated voltage 1kV (Um=1.2kV) to 35kV (Um=40.5kV) extruded insulated power cables and accessories Part 1: Rated voltage 1kV (Um=1.2kV) and 3kV (Um=3.6kV) cables Refer to JB / T 10696.10-2011 Test methods for mechanical and physical and chemical properties of wires and cables Part 10: Rat bite test.

[0273] Judgment basis: JB / T 10696.10-2011 Test methods for mechanical and physical and chemical properties of wires and cables: Part 10: Rat gnawing test, the test results are as follows Figure 4-7 shown.

[0274] Test conclusion: The sample tape structure dimensions only provide test results. The rat gnawing test item meets the significant protection level requirements of the JB / T10696.10-2011 standard.

Claims

1. A rat-proof adhesive film, characterized in that: The rat-proof adhesive film comprises: a substrate layer and an adhesive layer disposed on at least one surface of the substrate layer; The raw materials for preparing the adhesive layer include an adhesive; The raw materials for preparing the adhesive include: one or more of a base polymer, a tackifying resin, a functional additive, and an odor-repellent; The substrate layer comprises: a polyolefin film, a polyester film, a fluorine-containing polymer film, a silicon-containing polymer film, a plant fiber film, a metal film or a woven fabric of the above materials.

2. The rat-proof adhesive film according to claim 1, characterized in that: The softening point of the tackifying resin is 70-180°C.

3. The rat-proof adhesive film according to any one of claims 1 to 2, characterized in that: The mass ratio of the base polymer to the tackifying resin is 10:(1-15).

4. The rat-proof adhesive film according to claim 1, characterized in that: The base polymer includes: one or more of polyolefin liquid rubber, thermoplastic elastomer, and acrylic polymer.

5. The rat-proof adhesive film according to claim 1, characterized in that: The tackifying resin includes one or more of terpene resin and its derivatives, petroleum resin and its derivatives, rosin resin and its derivatives.

6. The rat-proof adhesive film according to claim 5, characterized in that: The petroleum resin and its derivatives include: one of C5 petroleum resin, hydrogenated C5 petroleum resin, C9 petroleum resin, hydrogenated C9 petroleum resin, C5 / C9 copolymerized petroleum resin and DCPD resin.

7. The rat-proof adhesive film according to claim 1, characterized in that: The functional additives include: one or more of antioxidants, plasticizers, anti-UV agents, thixotropic agents, flame retardants, antibacterial agents, pigments, antistatic agents, dispersants, lubricants, toughening agents, photoinitiators, and fillers.

8. The rat-proof adhesive film according to claim 1, characterized in that: The repulsive agents include: denatonium benzoate bittering agents and / or capsaicin-type spicy substances.

9. The rat-proof adhesive film according to claim 1, characterized in that: The mass percentage of the repellent in the adhesive is 0.3-18%.

10. A method for preparing the rat-proof adhesive film according to any one of claims 1 to 9, characterized in that: include: The adhesive is first prepared, and then coated on the substrate layer to form an adhesive layer.

Images