一种具有空气稳定性的硫化物固态电解质及其制备方法和应用

By doping LPSC-type sulfide solid electrolytes with Co and F, the problems of air instability and interfacial instability of sulfide solid electrolytes are solved, resulting in higher air stability and conductivity, and improved battery performance.

CN122418014APending Publication Date: 2026-07-17SHANGHAI FIRM LITHIUM NEW ENERGY TECH CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHANGHAI FIRM LITHIUM NEW ENERGY TECH CO LTD
Filing Date
2026-04-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing sulfide solid electrolytes are unstable in air, causing the materials to deteriorate rapidly when exposed to air, increasing environmental control costs and battery manufacturing difficulties. Furthermore, the unstable interface with the lithium metal anode limits the improvement of battery performance.

Method used

Co and F are used to double-dop the LPSC-type sulfide solid electrolyte. Co doping enhances the PS bond strength, while F doping forms a stable lithium fluoride/fluoride passivation layer, which inhibits the reaction of the material with moisture in the air and improves the air stability of the material.

Benefits of technology

It significantly improves the air stability and conductivity of sulfide solid electrolytes, enhances interfacial stability with lithium metal anodes, broadens the electrochemical window, and reduces the complexity and cost of battery manufacturing.

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Abstract

本发明属于固态电解质技术领域,涉及一种具有优异空气稳定性的硫化物固态电解质及其制备方法和应用,为Co、F双掺杂的LPSC型硫化物固态电解质,其化学通式为:Li6+2xP1‑xCoxS5Cl1‑3yF3y,其中0<x<0.1,0<y<0.1。并公开了所述硫化物固态电解质的制备方法及应用,本发明在LPSC型硫化物电解质中同时进行Co和F双掺杂,Co的掺杂增强了P‑S键强度,使其不易断裂,F的掺杂形成富含LiF的SEI层,稳定硫化物 / 锂金属界面的同时可以抑制本体材料与空气中水分的进一步反应,进而实现其空气稳定性的提高。二者同时掺杂,同步实现了硫化物固态电解质的空气稳定性。
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