A high-salt wastewater purification device and treatment method for lead-acid battery recovery

The high-salt wastewater of lead-acid batteries is treated through heating devices and crystallization devices, so that the water evaporates and precipitates salt and crystallizes, solving the problems of poor treatment effect of high-salt wastewater and environmental pollution in the prior art, and achieving efficient and low-cost purification effect.

CN116768303BActive Publication Date: 2025-08-08JIAN CHUANGCHENG ENVIRONMENTAL PROTECTION TECH CO LTD
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Patent Information

Application Number
CN202310791673.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-06-30
Publication Date
2025-08-08
Estimated Expiration
2043-06-30

AI Technical Summary

Technical Problem

In the prior art, when treating high-salt wastewater generated by lead-acid battery production, the biological treatment effect is poor and the physical and chemical method is high, and the treatment process is prone to environmental pollution.

Method used

The high-salt wastewater is heated by heating the water to evaporate and the salt crystallizes. The wastewater is continuously added through the water addition device, and the crystallization device is used to precipitate and collect salt crystallizes. Combined with the stirring and exhaust device, the water vapor is uniformly evaporated and discharged.

Benefits of technology

It realizes an efficient and low-cost salt crystallization process, reduces environmental pollution and improves the wastewater purification effect.

✦ Generated by Eureka AI based on patent content.

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Abstract

The present invention discloses a high-salt wastewater purification device and treatment method for lead-acid battery recycling. The present invention relates to the field of wastewater purification technology, comprising a first support rod, wherein the lower surface of the first support rod is fixedly connected to a support leg, and a heating device. By arranging the heating device, the high-salt wastewater for lead-acid battery recycling entering the inner cavity of an annular evaporation box can be heated, thereby evaporating the water in the high-salt wastewater for lead-acid battery recycling, and then allowing the salt to crystallize. The heating device comprises an annular evaporation box, which is in the shape of a circular ring and can therefore be evenly heated by a heat source in the middle, thereby allowing the high-salt wastewater for lead-acid battery recycling in the inner cavity of the annular evaporation box to be evenly heated. The annular evaporation box is fixedly connected to the end of the first support rod, and the inner circle of the annular evaporation box is fixedly connected to a fourth support rod, so as to achieve the effect of crystallizing and collecting the high-salt wastewater generated by the lead-acid battery production.
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Description

Technical Field

[0001] The present invention relates to the technical field of wastewater purification, and in particular to a high-salt wastewater purification device and treatment method for lead-acid battery recovery. Background Art

[0002] Lead-acid battery (VRLA) is a storage battery whose electrodes are mainly made of lead and its oxides, and whose electrolyte is sulfuric acid solution. When the lead-acid battery is in the discharged state, the main component of the positive electrode is lead dioxide, and the main component of the negative electrode is lead; in the charged state, the main components of the positive and negative electrodes are both lead sulfate. High-salt wastewater refers to wastewater with a total salt content of at least 3.5wt%. It mainly comes from chemical plants and the collection and processing of oil and natural gas. This wastewater contains a variety of substances (including salt, oil, organic heavy metals and). Salt-containing wastewater is produced in a wide range of ways, and the amount of water is increasing year by year. It is crucial to remove the impact of organic pollutants in salt-containing wastewater on the environment. When biological methods are used for treatment, high concentrations of salt substances have an inhibitory effect on microorganisms. When physical and chemical methods are used for treatment, the investment is large, the operating costs are high, and it is difficult to achieve the expected purification effect. The use of biological methods to treat such wastewater is still a focus of research at home and abroad;

[0003] A large amount of high-salt wastewater is generated during the production of lead-acid batteries. When treating high-salt wastewater, some methods, such as decomposition and incineration, will produce a large amount of waste gas, which will cause great pollution to the environment. Summary of the Invention

[0004] To achieve the above objectives, the present invention is implemented through the following technical solutions: A high-salt wastewater purification device and treatment method for lead-acid battery recycling, comprising a first support rod, a lower surface of which is fixedly connected to a support leg;

[0005] A heating device is provided, which can heat the high-salt wastewater for lead-acid battery recovery entering the inner cavity of the annular evaporation box, thereby evaporating the water in the high-salt wastewater for lead-acid battery recovery, and then allowing the salt to crystallize. The heating device includes an annular evaporation box, which is in the shape of a ring and can therefore be evenly heated by the heat source in the middle, so that the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporation box can be evenly heated. The annular evaporation box is fixedly connected to the end of the first support rod, and the inner ring of the annular evaporation box is fixedly connected to a fourth support rod;

[0006] A water adding device is provided, and high-salt wastewater for lead-acid battery recovery can be added to the inner cavity of the annular evaporation box, so that salt crystals can be continuously crystallized in the inner cavity of the annular evaporation box. The water adding device includes a fifth support rod, and the fifth support rod is fixedly connected to the inner circle of the annular evaporation box. The end of the fifth support rod away from the annular evaporation box is fixedly connected to the transfer box. The setting of the transfer box can transfer the high-salt wastewater for lead-acid battery recovery, so that the high-salt wastewater for lead-acid battery recovery can be evenly filled into the connecting pipe and enter the inner cavity of the annular evaporation box;

[0007] A crystallization device is provided to facilitate the precipitation of salt in high-salt wastewater for lead-acid battery recovery and the collection of crystallized salt. The crystallization device includes a top shell, which is movably connected to the inner cavity of the annular evaporation box.

[0008] Preferably, the end of the fourth support rod is fixedly connected to a heating motor, the output end of the heating motor is fixedly connected to a heating ring, and the heating ring is in the shape of a cylinder that is larger at the top and smaller at the bottom. The setting of the heating motor can enable the heating ring to generate heat, thereby heating the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporator box to evaporate. The heating ring is set in the shape of a cylinder that is larger at the top and smaller at the bottom, which can make the generated heat more evenly adhere to the inner circle of the annular evaporator box.

[0009] Preferably, a second support rod is fixedly connected to the inner wall of the annular evaporation box, and the end of the second support rod is fixedly connected to the first ring. A third support rod is fixedly connected to the inner wall of the annular evaporation box, and the end of the third support rod is fixedly connected to the second ring. The arrangement of the first ring and the second ring can limit the crystallization device, so that the crystallization device can rotate more smoothly when the crystallization device is rotated.

[0010] Preferably, the outer surface of the transfer box is fixedly connected to a first connecting box, the first connecting box passes through the transfer box, the outer surface of the first connecting box is fixedly connected to a connecting pipe, the end of the connecting pipe away from the first connecting box is fixedly connected to a second connecting box, the second connecting box passes through the bottom surface of the annular evaporation box. The arrangement of the first connecting box, the transfer box and the second connecting box can allow the high-salt wastewater for lead-acid battery recovery in the inner cavity of the transfer box to enter the inner cavity of the annular evaporation box.

[0011] Preferably, a water pump is fixedly connected to the axis center of the bottom surface of the inner cavity of the transfer box, and the water inlet end of the water pump is fixedly connected to a water inlet pipe. The water inlet pipe passes through the transfer box and extends to the lower surface of the transfer box. The setting of the water pump can allow the wastewater in the high-salt wastewater bucket for lead-acid battery recovery into which the water inlet pipe is inserted to enter the inner cavity of the transfer box.

[0012] Preferably, the upper surface of the top shell is fixedly connected with a rotating handle. The setting of the rotating handle can facilitate the operator to rotate the crystallization device, thereby stirring the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporator box to make it evaporate evenly. The upper surface of the top shell is fixedly connected with an exhaust pipe, and the exhaust pipe passes through the top shell. The exhaust pipe can discharge the water vapor generated in the inner cavity of the annular evaporator box. The lower surface of the top shell is fixedly connected with a limiting sleeve. The number of the limiting sleeves is several, and the several limiting sleeves are respectively slidably connected to the outer surfaces of the first ring and the second ring. The setting of the limiting sleeves can make the crystallization device rotate more smoothly on the outer surfaces of the first ring and the second ring.

[0013] Preferably, a partition is fixedly connected to the inner wall of the top shell, and the number of the partitions is several. The setting of the partition can enable the generated water vapor to be discharged and discharged from the exhaust pipe, and support and fix the collection device, and several of the partitions are arrayed on the inner wall of the top shell with the axis of the top shell as the center of the circle, and the inner surface of the partition is fixedly connected to the collection device.

[0014] Preferably, the collecting device includes a soft pad. By setting up the collecting device, the precipitated salt crystals can be collected and the wastewater in the annular evaporation box can be stirred to make it evaporate more evenly. The soft pad is fixedly connected to the inner surface of the partition, and the end of the soft pad is fixedly connected to a movable rod, and the bottom end of the movable rod is fixedly connected to a stirring frame. The setting of the soft pad can make the movable rod shake during the rotation process, thereby fully stirring the wastewater in the inner cavity of the annular evaporation box.

[0015] Preferably, a sixth support rod is fixedly connected to the top surface of the inner cavity of the stirring frame, and a precipitation sleeve is fixedly connected to one end of the sixth support rod away from the top surface of the inner cavity of the stirring frame. The setting of the precipitation sleeve can make the crystallized salt adsorbed on the outer surface of the precipitation sleeve, and a spring is fixedly connected to the port of the stirring frame, and the end of the spring is fixedly connected to a stirring plate. The setting of the spring and the stirring plate can stir the wastewater in the inner cavity of the annular evaporation box to make it evaporate evenly.

[0016] A method for treating high-salt wastewater for lead-acid battery recycling comprises the following steps:

[0017] Step 1: Before purifying the high-salt wastewater for lead-acid battery recycling, heat the high-salt wastewater for lead-acid battery recycling to 50 degrees, place the high-salt wastewater for lead-acid battery recycling in a barrel, and place the barrel filled with high-salt wastewater for lead-acid battery recycling directly under the water inlet pipe. After preparation, connect the water pump to the power supply and turn on the water pump switch;

[0018] Step 2: The high-salt wastewater for lead-acid battery recycling enters the inner cavity of the transfer box and enters the inner cavity of the annular evaporation box through the connecting pipe. When the height of the high-salt wastewater for lead-acid battery recycling in the inner cavity of the annular evaporation box reaches two-thirds of the short side of the annular evaporation box, the switch of the water pump is turned off so that the water pump no longer pumps the high-salt wastewater for lead-acid battery recycling into the inner cavity of the transfer box;

[0019] Step 3: After the high-salt wastewater for lead-acid battery recycling reaches a certain height in the annular evaporation box, the operator installs the crystallization device on top of the annular evaporation box, so that the top shell contacts the inner wall of the annular evaporation box, and the limiting sleeve is installed on the outer surfaces of the first and second rings to complete the installation of the device;

[0020] Step 4: After installing the crystallization device, connect the heating motor to the power supply and turn on the switch of the heating motor. After the heating motor is powered on, the heating ring generates heat to secondary heat the high-salt wastewater for lead-acid battery recycling until it boils. After the high-salt wastewater for lead-acid battery recycling is boiled, the generated water vapor is discharged from the exhaust pipe;

[0021] Step 5: When the water level of the high-salt wastewater for lead-acid battery recycling in the inner cavity of the annular evaporation box reaches one-third of the height of the inner wall of the short side of the annular evaporation box, hold the rotating handle and rotate it in a circle. The top shell drives the partition and the collecting device to rotate in the inner cavity of the annular evaporation box. During the rotation, the crystallized salt adheres to the outer surface of the precipitation sleeve. The stirring plate stirs the high-salt wastewater for lead-acid battery recycling remaining in the annular evaporation box to evaporate and crystallize as quickly as possible. After the crystallization is completed, the crystallization device is taken out to collect the salt crystals.

[0022] The present invention provides a high-salt wastewater purification device and treatment method for lead-acid battery recycling, which has the following beneficial effects:

[0023] 1. The high-salt wastewater purification device and treatment method for lead-acid battery recycling, by providing a heating device, can heat the high-salt wastewater for lead-acid battery recycling entering the inner cavity of the annular evaporation box, thereby evaporating the water in the high-salt wastewater for lead-acid battery recycling, and then allowing the salt to crystallize. The annular evaporation box is in the shape of a ring, so it can be evenly heated by the heat source in the middle, so that the high-salt wastewater for lead-acid battery recycling in the inner cavity of the annular evaporation box can be evenly heated.

[0024] 2. The high-salt wastewater purification device and treatment method for lead-acid battery recycling can add high-salt wastewater for lead-acid battery recycling into the inner cavity of the annular evaporation box by setting a water adding device, so that salt crystals can be continuously crystallized in the inner cavity of the annular evaporation box. The setting of the transfer box can transfer the high-salt wastewater for lead-acid battery recycling, so that the high-salt wastewater for lead-acid battery recycling can be evenly filled into the connecting pipe and enter the inner cavity of the annular evaporation box.

[0025] 3. The high-salt wastewater purification device and treatment method for lead-acid battery recycling facilitates the precipitation of salt in the high-salt wastewater for lead-acid battery recycling and facilitates the collection of the crystallized salt by setting a crystallization device.

[0026] Fourth, the high-salt wastewater purification device and treatment method for lead-acid battery recycling can facilitate the operator to rotate the crystallization device by turning the handle, thereby stirring the high-salt wastewater for lead-acid battery recycling in the inner cavity of the annular evaporation box to make it evaporate evenly. The exhaust pipe can discharge the water vapor generated in the inner cavity of the annular evaporation box. The setting of the limit sleeve can make the crystallization device rotate more smoothly on the outer surfaces of the first ring and the second ring.

[0027] 5. The high-salt wastewater purification device and treatment method for lead-acid battery recycling can collect the precipitated salt crystals by setting a collection device, and stir the wastewater in the annular evaporation box to make it evaporate more evenly. The setting of the soft pad can make the movable rod shake during the rotation process, thereby fully stirring the wastewater in the inner cavity of the annular evaporation box. BRIEF DESCRIPTION OF THE DRAWINGS

[0028] Figure 1 This is a schematic diagram of the external structure of a high-salt wastewater purification device for lead-acid battery recycling according to the present invention;

[0029] Figure 2 This is a schematic diagram of the disassembled structure of the present invention;

[0030] Figure 3 This is a schematic structural diagram of the heating device of the present invention;

[0031] Figure 4 This is a schematic diagram of the partial structure of the heating device of the present invention;

[0032] Figure 5 This is a schematic structural diagram of the water adding device of the present invention;

[0033] Figure 6 Schematic diagram of the crystallization device structure of the present invention;

[0034] Figure 7 Schematic diagram of the cross-sectional structure of the crystallization device of the present invention;

[0035] Figure 8 This is a schematic structural diagram of the collecting device of the present invention;

[0036] Figure 9 This is a schematic diagram of a method for treating high-salt wastewater for lead-acid battery recovery according to the present invention.

[0037] In the figure: 1. first support rod; 2. support leg; 3. heating device; 4. water adding device; 5. crystallization device; 31. annular evaporation box; 32. second support rod; 33. first circular ring; 34. third support rod; 35. second circular ring; 36. fourth support rod; 37. heating motor; 38. heating ring; 41. fifth support rod; 42. transfer box; 43. first connecting box; 44. connecting pipe; 45. second connecting box; 46. water pump; 47. water inlet pipe; 51. top shell; 52. rotating handle; 53. exhaust pipe; 54. limiting sleeve; 55. partition; 56. collecting device; 561. cushion; 562. movable rod; 563. stirring frame; 564. sixth support rod; 565. precipitation sleeve; 566. spring; 567. stirring plate. DETAILED DESCRIPTION

[0038] The present invention will be described in further detail below with reference to the accompanying drawings and specific embodiments. The embodiments of the present invention are provided for purposes of illustration and description and are not intended to be exhaustive or to limit the invention to the disclosed forms. Many modifications and variations will be apparent to those skilled in the art. The embodiments are chosen and described to better illustrate the principles of the invention and its practical application, and to enable those skilled in the art to understand the invention and design various embodiments with various modifications suitable for specific applications.

[0039] The first embodiment, as Figure 1-Figure 4 As shown, the present invention provides a technical solution: a high-salt wastewater purification device and treatment method for lead-acid battery recycling, comprising a first support rod 1, the lower surface of which is fixedly connected to a support leg 2;

[0040] The heating device 3 is provided to heat the high-salt wastewater for lead-acid battery recovery entering the inner cavity of the annular evaporation box 31, thereby evaporating the water in the high-salt wastewater for lead-acid battery recovery, and then allowing the salt to crystallize. The heating device 3 includes an annular evaporation box 31. The annular evaporation box 31 is in the shape of a ring, so it can be evenly heated by the heat source in the middle, so that the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporation box 31 can be evenly heated. The annular evaporation box 31 is fixedly connected to the end of the first support rod 1, and the inner ring of the annular evaporation box 31 is fixedly connected to a fourth support rod 36;

[0041] The water adding device 4 is provided to add high-salt wastewater for lead-acid battery recovery to the inner cavity of the annular evaporation box 31, so that salt crystals can be continuously crystallized in the inner cavity of the annular evaporation box 31. The water adding device 4 includes a fifth support rod 41, which is fixedly connected to the inner circle of the annular evaporation box 31. The end of the fifth support rod 41 away from the annular evaporation box 31 is fixedly connected to a transfer box 42. The transfer box 42 can transfer the high-salt wastewater for lead-acid battery recovery, so that the high-salt wastewater for lead-acid battery recovery can be evenly filled into the connecting pipe 44 and enter the inner cavity of the annular evaporation box 31.

[0042] The crystallization device 5 is provided to facilitate the precipitation of salt in high-salt wastewater for lead-acid battery recovery and the collection of crystallized salt. The crystallization device 5 includes a top shell 51 , which is movably connected to the inner cavity of the annular evaporation box 31 .

[0043] The end of the fourth support rod 36 is fixedly connected to a heating motor 37, and the output end of the heating motor 37 is fixedly connected to a heating ring 38, and the heating ring 38 is in the shape of a cylinder with a larger top and a smaller bottom. The setting of the heating motor 37 can make the heating ring 38 generate heat, so that the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporation box 31 is heated to evaporate. The heating ring 38 is set to be in the shape of a cylinder with a larger top and a smaller bottom, which can make the generated heat more evenly adhere to the inner circle of the annular evaporation box 31. The inner wall of the annular evaporation box 31 is fixedly connected to a second support rod 32, and the end of the second support rod 32 is fixedly connected to the first ring 33. The inner wall of the annular evaporation box 31 is fixedly connected to a third support rod 34, and the third support rod 34 The end portion is fixedly connected to the second ring 35. The setting of the first ring 33 and the second ring 35 can limit the crystallization device 5, so that the crystallization device 5 can rotate more smoothly when the crystallization device 5 is rotated. During use, after the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporation box 31 reaches a height, the operator installs the crystallization device 5 above the annular evaporation box 31 so that the top shell 51 contacts the inner wall of the annular evaporation box 31, and the limiting sleeve 54 is sleeved on the outer surfaces of the first ring 33 and the second ring 35. After the crystallization device is installed, the heating motor 37 is connected to the power supply and the switch of the heating motor 37 is turned on. After the heating motor 37 is energized, the heating ring 38 generates heat to perform secondary heating of the high-salt wastewater for lead-acid battery recovery until it boils.

[0044] The second embodiment, as Figure 5As shown, the outer surface of the transfer box 42 is fixedly connected to the first connecting box 43, the first connecting box 43 passes through the transfer box 42, the outer surface of the first connecting box 43 is fixedly connected to the connecting pipe 44, the end of the connecting pipe 44 away from the first connecting box 43 is fixedly connected to the second connecting box 45, the second connecting box 45 passes through the bottom surface of the annular evaporation box 31, the arrangement of the first connecting box 43, the transfer box 42 and the second connecting box 45 can make the high-salt wastewater for lead-acid battery recovery in the inner cavity of the transfer box 42 enter the inner cavity of the annular evaporation box 31, the axis center of the bottom surface of the inner cavity of the transfer box 42 is fixedly connected to the water pump 46, the water inlet end of the water pump 46 is fixedly connected to the water inlet pipe 47, the water inlet pipe 47 passes through the transfer box 42 and extends to the transfer box The lower surface of 42 is provided with a water pump 46, which can allow the wastewater in the high-salt wastewater bucket for lead-acid battery recovery, into which the water inlet pipe 47 is inserted, to enter the inner cavity of the transfer box 42. When in use, the barrel filled with high-salt wastewater for lead-acid battery recovery is placed directly below the water inlet pipe 47. After preparation, the water pump 46 is connected to the power supply and the switch of the water pump 46 is turned on. The high-salt wastewater for lead-acid battery recovery enters the inner cavity of the transfer box 42 and enters the inner cavity of the annular evaporation box 31 through the connecting pipe 44. When the height of the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporation box 31 reaches two-thirds of the short side of the annular evaporation box 31, the switch of the water pump 46 is turned off, so that the water pump 46 no longer pumps high-salt wastewater for lead-acid battery recovery into the inner cavity of the transfer box 42.

[0045] The third embodiment, as Figure 6-Figure 9As shown, the upper surface of the top shell 51 is fixedly connected with a rotating handle 52. The setting of the rotating handle 52 can facilitate the operator to rotate the crystallization device 5, thereby stirring the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporation box 31 to make it evaporate evenly. The upper surface of the top shell 51 is fixedly connected with an exhaust pipe 53. The exhaust pipe 53 runs through the top shell 51. The exhaust pipe 53 can discharge the water vapor generated in the inner cavity of the annular evaporation box 31. The lower surface of the top shell 51 is fixedly connected with a limiting sleeve 54. The number of the limiting sleeves 54 is several, and the several limiting sleeves 54 are respectively slidably connected to the outer surfaces of the first ring 33 and the second ring 35. The setting of the limiting sleeve 54 can make the crystallization device 5 between the first ring 33 and the second ring The outer surface of the ring 35 rotates more smoothly, and a partition 55 is fixedly connected to the inner wall of the top shell 51. There are several partitions 55. The setting of the partition 55 can discharge the generated water vapor and discharge it from the exhaust pipe 53, and support and fix the collecting device 56. Several of the partitions 55 are arranged on the inner wall of the top shell 51 with the axis of the top shell 51 as the center of the circle. The inner surface of the partition 55 is fixedly connected to the collecting device 56. When in use, when the water level of the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporation box 31 reaches one-third of the height of the inner wall of the short side of the annular evaporation box 31, hold the rotating handle 52 and rotate it in a circle. The top shell 51 drives the partition 55 and the collecting device 56 to rotate in the inner cavity of the annular evaporation box 31.

[0046] The collecting device 56 includes a soft pad 561. By setting the collecting device 56, the precipitated salt crystals can be collected and the wastewater in the annular evaporation box 31 can be stirred to make it evaporate more evenly. The soft pad 561 is fixedly connected to the inner surface of the partition 55. The end of the soft pad 561 is fixedly connected to a movable rod 562, and the bottom end of the movable rod 562 is fixedly connected to a stirring frame 563. The setting of the soft pad 561 can make the movable rod 562 shake during the rotation process, thereby fully stirring the wastewater in the inner cavity of the annular evaporation box 31. The top surface of the inner cavity of the stirring frame 563 is fixedly connected to a sixth support rod 564, and the sixth support rod 564 is away from the top surface of the inner cavity of the stirring frame 563. One end of the device 5 is fixedly connected to a precipitation sleeve 565. The setting of the precipitation sleeve 565 can make the crystallized salt adsorbed on the outer surface of the precipitation sleeve 565. The spring 566 is fixedly connected to the port of the stirring frame 563. The end of the spring 566 is fixedly connected to a stirring plate 567. The setting of the spring 566 and the stirring plate 567 can stir the wastewater in the inner cavity of the annular evaporation box 31 to make it evaporate evenly. When in use, during the rotation of the crystallization device 5, the crystallized salt adheres to the outer surface of the precipitation sleeve 565, and the stirring plate 567 stirs the high-salt wastewater for lead-acid battery recovery remaining in the annular evaporation box 31 to evaporate and crystallize as quickly as possible. After the crystallization is completed, the crystallization device 5 is taken out to collect the salt crystals.

[0047] A method for treating high-salt wastewater for lead-acid battery recycling comprises the following steps:

[0048] Step 1: Before purifying the high-salt wastewater for lead-acid battery recycling, heat the high-salt wastewater for lead-acid battery recycling to 50 degrees, place the high-salt wastewater for lead-acid battery recycling in a barrel, and place the barrel filled with the high-salt wastewater for lead-acid battery recycling directly under the water inlet pipe 47. After preparation, connect the water pump 46 to the power supply and turn on the switch of the water pump 46;

[0049] Step 2: The high-salt wastewater for lead-acid battery recovery enters the inner cavity of the transfer tank 42 and enters the inner cavity of the annular evaporation tank 31 through the connecting pipe 44. When the height of the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporation tank 31 reaches two-thirds of the short side of the annular evaporation tank 31, the switch of the pumping pump 46 is turned off so that the pumping pump 46 no longer pumps the high-salt wastewater for lead-acid battery recovery into the inner cavity of the transfer tank 42;

[0050] Step 3: After the high-salt wastewater for lead-acid battery recovery reaches a certain height in the annular evaporation box 31, the operator installs the crystallization device 5 above the annular evaporation box 31, so that the top shell 51 contacts the inner wall of the annular evaporation box 31, and the limiting sleeve 54 is placed on the outer surfaces of the first ring 33 and the second ring 35, completing the installation of the device;

[0051] Step 4: After installing the crystallization device 5, connect the heating motor 37 to the power supply and turn on the switch of the heating motor 37. After the heating motor 37 is powered on, the heating ring 38 generates heat to secondary heat the high-salt wastewater for lead-acid battery recycling until it boils. After the high-salt wastewater for lead-acid battery recycling is boiled, the generated water vapor is discharged from the exhaust pipe 53;

[0052] Step 5: When the water level of the high-salt wastewater for lead-acid battery recycling in the inner cavity of the annular evaporation box 31 reaches one-third of the height of the inner wall of the short side of the annular evaporation box 31, hold the rotating handle 52 and rotate it in a circle. The top shell 51 drives the partition 55 and the collecting device 56 to rotate in the inner cavity of the annular evaporation box 31. During the rotation, the crystallized salt adheres to the outer surface of the precipitation sleeve 565. The stirring plate 567 stirs the residual high-salt wastewater for lead-acid battery recycling in the annular evaporation box 31 to evaporate and crystallize as quickly as possible. After the crystallization is completed, the crystallization device 5 is taken out to collect the salt crystals.

[0053] Obviously, the embodiments described are only some of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field and related fields without making creative efforts should fall within the scope of protection of the present invention. Structures, devices, and operating methods not specifically described and explained in the present invention shall be implemented in accordance with conventional means in the field unless otherwise specified or limited.

Claims

1. A high-salt wastewater purification device for lead-acid battery recycling, comprising a first support rod (1), wherein a support leg (2) is fixedly connected to the lower surface of the first support rod (1), characterized in that: The high-salt wastewater purification device for lead-acid battery recycling also includes: A heating device (3), the heating device (3) comprising an annular evaporation box (31), the annular evaporation box (31) being fixedly connected to the end of the first support rod (1), and a fourth support rod (36) being fixedly connected to the inner ring of the annular evaporation box (31); A water adding device (4), the water adding device (4) comprising a fifth support rod (41), the fifth support rod (41) being fixedly connected to the inner circle of the annular evaporation box (31), and one end of the fifth support rod (41) away from the annular evaporation box (31) being fixedly connected to a transfer box (42); A crystallization device (5), the crystallization device (5) comprising a top shell (51), the top shell (51) being movably connected in the inner cavity of the annular evaporation box (31); The end of the fourth support rod (36) is fixedly connected to a heating motor (37), and the output end of the heating motor (37) is fixedly connected to a heating ring (38), and the heating ring (38) is in the shape of a cylinder with a larger top and a smaller bottom; A second support rod (32) is fixedly connected to the inner wall of the outer ring of the annular evaporation box (31), and the end of the second support rod (32) is fixedly connected to the first circular ring (33); a third support rod (34) is fixedly connected to the inner wall of the inner ring of the annular evaporation box (31), and the end of the third support rod (34) is fixedly connected to the second circular ring (35); The upper surface of the top shell (51) is fixedly connected to a rotating handle (52), the upper surface of the top shell (51) is fixedly connected to an exhaust pipe (53), the exhaust pipe (53) passes through the top shell (51), and the lower surface of the top shell (51) is fixedly connected to a limiting sleeve (54), the number of the limiting sleeves (54) is several, and the several limiting sleeves (54) are respectively slidably connected to the outer surfaces of the first ring (33) and the second ring (35); A partition (55) is fixedly connected to the inner wall of the top shell (51), and the number of the partitions (55) is several. The partitions (55) are arrayed on the inner wall of the top shell (51) with the axis of the top shell (51) as the center of the circle, and the inner surface of the partition (55) is fixedly connected to the collecting device (56).

2. A high-salt wastewater purification device for lead-acid battery recovery according to claim 1, characterized in that: The outer surface of the transfer box (42) is fixedly connected to a first connection box (43), the first connection box (43) passes through the transfer box (42), the outer surface of the first connection box (43) is fixedly connected to a connection pipe (44), one end of the connection pipe (44) away from the first connection box (43) is fixedly connected to a second connection box (45), and the second connection box (45) passes through the bottom surface of the annular evaporation box (31).

3. A high-salt wastewater purification device for lead-acid battery recovery according to claim 2, characterized in that: A water pump (46) is fixedly connected to the axis center of the bottom surface of the inner cavity of the transfer box (42), and a water inlet end of the water pump (46) is fixedly connected to a water inlet pipe (47). The water inlet pipe (47) passes through the transfer box (42) and extends to the lower surface of the transfer box (42).

4. A high-salt wastewater purification device for lead-acid battery recovery according to claim 3, characterized in that: The collecting device (56) comprises a soft pad (561), the soft pad (561) is fixedly connected to the inner surface of the partition (55), the end of the soft pad (561) is fixedly connected to a movable rod (562), and the bottom end of the movable rod (562) is fixedly connected to a stirring frame (563).

5. A high-salt wastewater purification device for lead-acid battery recovery according to claim 4, characterized in that: A sixth support rod (564) is fixedly connected to the top surface of the inner cavity of the stirring frame (563), and an end of the sixth support rod (564) away from the top surface of the inner cavity of the stirring frame (563) is fixedly connected to a precipitation sleeve (565). A spring (566) is fixedly connected to the port of the stirring frame (563), and an end of the spring (566) is fixedly connected to a stirring plate (567).

6. A method for treating high-salt wastewater for lead-acid battery recovery, characterized in that: The high-salt wastewater purification device for lead-acid battery recycling as claimed in claim 5 comprises the following steps: Step 1: Before purifying the high-salt wastewater for lead-acid battery recycling, heat the high-salt wastewater for lead-acid battery recycling to 50 degrees, place the high-salt wastewater for lead-acid battery recycling in a barrel, and place the barrel filled with the high-salt wastewater for lead-acid battery recycling directly under the water inlet pipe (47). After preparation, connect the water pump (46) to the power supply and turn on the switch of the water pump (46); Step 2: The high-salt wastewater for lead-acid battery recycling enters the inner cavity of the transfer box (42) and enters the inner cavity of the annular evaporation box (31) through the connecting pipe (44). When the height of the high-salt wastewater for lead-acid battery recycling in the inner cavity of the annular evaporation box (31) reaches two-thirds of the short side of the annular evaporation box (31), the switch of the pumping pump (46) is turned off so that the pumping pump (46) no longer pumps the high-salt wastewater for lead-acid battery recycling into the inner cavity of the transfer box (42); Step 3: After the high-salt wastewater for lead-acid battery recovery in the inner cavity of the annular evaporation box (31) reaches a certain height, the operator installs the crystallization device (5) above the annular evaporation box (31), so that the top shell (51) contacts the inner wall of the annular evaporation box (31), and the limiting sleeve (54) is sleeved on the outer surfaces of the first ring (33) and the second ring (35), thereby completing the installation of the device; Step 4: After installing the crystallization device (5), connect the heating motor (37) to the power supply and turn on the switch of the heating motor (37). After the heating motor (37) is powered on, the heating ring (38) generates heat to perform secondary heating on the high-salt wastewater for lead-acid battery recycling until it boils, and the generated water vapor is discharged from the exhaust pipe (53); Step 5: When the water level of the high-salt wastewater for lead-acid battery recycling in the inner cavity of the annular evaporation box (31) reaches one-third of the height of the inner wall of the short side of the annular evaporation box (31), hold the rotating handle (52) and rotate it in a circle. The top shell (51) drives the partition (55) and the collecting device (56) to rotate in the inner cavity of the annular evaporation box (31). During the rotation, the crystallized salt adheres to the outer surface of the precipitation sleeve (565). The stirring plate (567) stirs the residual high-salt wastewater for lead-acid battery recycling in the annular evaporation box (31) to evaporate and crystallize as quickly as possible. After the crystallization is completed, the crystallization device (5) is taken out to collect the salt crystals.

Citation Information

Patent Citations

  • High-salt wastewater continuous thin-layer drying device

    CN212832919U

  • Centrifugal crystallization refining apparatus

    US6080374A