A device and method for preparing high-purity manganese sulfate using industrial manganese

Abstract

The present invention discloses a device and method for preparing high-purity manganese sulfate using industrial manganese, and belongs to the technical field of preparing manganese sulfate. The device comprises a reactor, the upper end of which is connected to an operating chamber, and the upper end of which is connected to a feed assembly. When the temperature in the reaction chamber reaches 70°C, the reaction reagents will undergo a chemical reaction to generate gas. As the gas increases, an upward thrust will be generated on the sliding block, so that the sliding block moves upward, and then an upward thrust will be generated on the second conductive block, and the second conductive block will be separated from the connecting groove opened at the upper end of the third conductive block, so that the annular heating wire is powered off, and the annular heating wire stops heating, so that the temperature in the reaction chamber is maintained at 70°C, so that the decomposition reaction of the reaction reagents can achieve a physical power-off effect, thereby improving the accuracy of temperature control in the reaction chamber, and thus improving the work efficiency of purifying manganese sulfate.

Description

Technical Field

[0001] The present invention relates to the technical field of preparing manganese sulfate, and more specifically, to a device and method for preparing high-purity manganese sulfate by utilizing industrial manganese. Background Art

[0002] Manganese sulfate is an important basic chemical raw material, widely used in fertilizers, coatings, catalysts, ceramics, mineral processing and other fields. Manganese sulfate products or solutions of ordinary industrial grade purity can meet the needs of the above-mentioned fields, but cannot meet the use requirements in the field of lithium-ion battery materials. Lithium manganese oxide materials and nickel-cobalt-manganese multi-element materials have very high requirements for the purity of manganese sulfate. Lithium manganese oxide and nickel-cobalt-manganese multi-element materials are the core direction of the demand for lithium-ion power battery materials. With the gradual promotion and application of lithium-ion power batteries in new energy vehicles, the demand for high-purity manganese sulfate will explode. Therefore, the preparation and production technology of high-purity manganese sulfate has become a research hotspot in the field of manganese metallurgy.

[0003] At present, in the process of preparing high-purity manganese sulfate using industrial manganese, the optimal temperature threshold for the reaction of industrial manganese and sulfuric acid is in the range of 70 degrees Celsius to 80 degrees Celsius. At present, the reaction temperature is mainly controlled by sensing the temperature in the reaction chamber through sensors, and then adjusting the temperature of the reaction chamber according to the sensor data. However, the sensor may have signal perception abnormalities during long-term operation, resulting in insufficient reaction between industrial manganese and sulfuric acid when the temperature exceeds or falls below the optimal temperature threshold, which in turn affects the purity of manganese sulfate. Summary of the invention

[0004] The object of the present invention is to provide a device and method for preparing high-purity manganese sulfate using industrial manganese, so as to solve the problems raised in the above background technology.

[0005] A device for preparing high-purity manganese sulfate using industrial manganese comprises a reactor, the upper end of the reactor is connected to an operation chamber, the upper end of the operation chamber is connected to a feeding assembly, and the inner cavity of the reactor is connected to a heating assembly, the end of the heating assembly away from the reactor is provided with a reaction chamber, and the inner cavity of the reaction chamber is connected to a purification assembly;

[0006] The heating assembly comprises a first power transmission line, one end of the first power transmission line is connected to a first conductive block, one end of the first conductive block away from the first power transmission line is rotatably connected to a second conductive block, one end of the second conductive block away from the first conductive block is connected to a third conductive block, and one end of the third conductive block away from the second conductive block is connected to a ring-shaped heating wire;

[0007] The purification component includes a first drive motor, the output end of the first drive motor is sleeved with a first gear, one end of the first gear is meshed with a second gear, the middle part of the second gear is connected to a guide rod, the inner cavity of the guide rod is connected to a temperature control component, and the lower end surface of the guide rod is connected to a plurality of stirring rods, the first drive motor is installed in an operating cavity, and the output end of the first drive motor is connected to the first gear through the lower end surface that passes through the operating cavity.

[0008] Preferably, the inner wall of the reactor and the outer wall of the reaction chamber form an annular cavity, the annular heating wire is installed in the annular cavity, the upper end surfaces of the three conductive blocks are provided with connecting grooves, and the connecting groove opened on the upper end of the third conductive block fits with the second conductive block.

[0009] Preferably, the temperature control component includes a temperature control cavity, the inner cavity of the temperature control cavity is filled with reaction reagents, and the upper surface of the temperature control cavity is provided with a plurality of ventilation holes, the upper inner cavity of the temperature control cavity is connected to a sliding block, the lower end of the sliding block is provided with a plurality of air outlets, and one end of the temperature control cavity is connected to a feed pipe.

[0010] Preferably, the number of ventilation holes is equal to the number of air outlets, and the ventilation holes correspond to the air outlets, the sliding block contacts the lower end surface of the second conductive block through the ground penetrating the operating cavity, and the sliding block is rotatably connected to the lower end surface of the operating cavity, and the sliding block is made of insulating material, and the inner cavity of the lower end surface of the operating cavity is hollow.

[0011] Preferably, the feeding assembly includes a second driving motor, the output end of the second driving motor is sleeved with a third gear, one end of the third gear is meshed with a fourth gear, a first rotating belt is arranged above the fourth gear, and both ends of the first rotating belt are sleeved with conveying pipes.

[0012] Preferably, the upper end of each of the conveying pipes is connected to a storage cavity, and a circular connecting block is connected to the inner cavity of each of the storage cavity. The upper end of the circular connecting block arranged at one end close to the second driving motor is connected to a guide tube, a guide groove is provided on the outer surface of the guide tube, and a floating block is connected to the inner cavity of the guide tube, the lower end of the guide tube is connected to a circular trigger block, and the storage cavity in the feeding assembly is connected to the reactor through the connecting block.

[0013] Preferably, the outer surface of the conveying pipe sleeved on one end of the first rotating belt close to the second driving motor is connected to the fourth gear, the number of teeth arranged on the outer surface of the third gear is equal to one-quarter of the number of teeth arranged on the outer surface of the fourth gear, a trigger groove is provided on the lower end surface of the floating block, and the trigger groove on the lower end surface of the floating block matches with the circular trigger block, a plurality of rectangular feeding ports are provided on the outer surface of the circular connecting block, and a plurality of rectangular feeding ports are provided on the upper end surface of each conveying pipe, and at the same time, the diameter of the rectangular feeding port close to the second driving motor and the diameter of the rectangular feeding port are equal to half of the diameter of the rectangular feeding port and the diameter of the rectangular feeding port away from the second driving motor.

[0014] Preferably, a method for preparing high-purity manganese sulfate using industrial manganese comprises the following steps:

[0015] S1. First, industrial manganese is put into a ball mill for crushing, and the particle size of the powder is uniform. Then, the crushed manganese material is taken out. At this time, the crushed manganese material is put into a cleaning container, and enough clean water is added to the cleaning container to cover the manganese material. Then, a stirrer is used to make the water and the manganese material fully contact to promote the dissolution and shedding of impurities. Then, the washed manganese material is filtered through a filter to remove impurities and solid particles suspended in the water. The filtered manganese material should be dried for standby use;

[0016] S2. After the manganese material is dried, the manganese material is placed in a storage chamber installed at one end away from the second drive motor, and then the sulfuric acid solution is placed in the storage chamber installed at one end close to the second drive motor until the storage chamber is filled with the raw materials. At this time, the second drive motor is started, and the third gear is rotated one circle, so that the fourth gear is rotated ninety degrees, and then the first rotating belt and the conveying pipe sleeved at both ends are rotated ninety degrees, and the rectangular conveying port is made to correspond to the rectangular feeding port, and then the manganese material and the sulfuric acid solution are allowed to enter the reaction chamber through the conveying pipe;

[0017] S3, as the raw material in the storage chamber decreases, the floating block will move downward along the guide groove. When the trigger groove opened at the lower end of the floating block coincides with the circular trigger block, a complete circuit will be formed, so that the second drive motor will reverse one circle, and then the conveying pipe will reverse 90 degrees, so that the rectangular conveying port is separated from the rectangular feeding port, and the conveying of raw materials into the reaction chamber will stop;

[0018] S4. When the raw material is transported to the reaction chamber, power is turned on, so that the annular heating wire heats up, thereby heating the raw material in the reaction chamber. When the temperature in the reaction chamber reaches 70°C, the guide rod transmits the temperature to the reaction agent, and the reaction agent generates gas at 70°C, thereby pushing the sliding block to move upward along the temperature control cavity, thereby generating a thrust on the second conductive block, thereby separating the second conductive block from the connecting groove opened at the upper end of the third conductive block, thereby stopping the annular heating wire from heating;

[0019] S5. When the temperature in the reaction chamber reaches 70° C., the first drive motor is started to drive the rotation of the first gear, thereby driving the rotation of the second gear, and then driving the stirring rod to stir the reaction material, so that the manganese material and sulfuric acid can fully react. When the manganese material is completely dissolved, the stirring and heating are stopped, and then the solution is cooled to room temperature and taken out. At this time, the dissolved and cooled manganese sulfate solution is slowly poured into the filter, and then the filtering device is started to allow the solution to pass through the filter, and solid particles and impurities are intercepted on the filter medium, while the clear solution flows into the receiving container;

[0020] S6. When the solution completely passes through the filter, stop the operation of the filtering device, take out the filtered product in the receiving container, and then slowly pour the filtered manganese sulfate solution into the crystallization container, and adjust the temperature in the crystallization container according to the crystallization temperature of manganese sulfate, and then start the stirring device in the crystallization container to stir the solution, so that the solution is fully heated to promote the formation and growth of crystals. At the same time, during the crystallization process, regularly observe the state of the solution, such as the turbidity of the solution and the morphology of the crystals, to determine whether the crystallization has reached the desired degree;

[0021] S7. When the crystallization in the solution reaches the desired degree, stop heating or cooling to end the crystallization process, then separate the crystals and the solution in the crystallization container by a centrifuge, and dry the separated crystals to remove surface moisture to obtain dry manganese sulfate crystals. Finally, collect the dry manganese sulfate crystals, package and store them for subsequent use.

[0022] Compared with the prior art, the advantages of the present invention are:

[0023] 1. In the present invention, when the temperature in the reaction chamber reaches 70°C, the reaction reagent will undergo a chemical reaction to generate gas. As the gas increases, an upward thrust is generated on the sliding block, so that the sliding block moves upward, and then an upward thrust is generated on the second conductive block, and the second conductive block is separated from the connecting groove opened at the upper end of the third conductive block, thereby cutting off the power to the annular heating wire and stopping the heating of the annular heating wire, so that the temperature in the reaction chamber is maintained at 70°C. In this way, the decomposition reaction of the reaction reagent can achieve a physical power-off effect, thereby improving the accuracy of temperature control in the reaction chamber, and then improving the work efficiency of purifying manganese sulfate.

[0024] 2. In the present invention, by making the diameter of the rectangular feed port far from the second drive motor and the diameter of the rectangular feed port equal to half of the diameter of the rectangular feed port close to the second drive motor and the diameter of the rectangular feed port, sulfuric acid and industrial manganese can be fed in proportion. When the trigger groove opened at the lower end of the floating block coincides with the circular trigger block, a complete circuit will be formed, so that the second drive motor will reverse one circle, and then the conveying pipe will reverse ninety degrees, so that the rectangular feed port is separated from the rectangular feed port, and the conveying of raw materials into the reaction chamber will be stopped. In this way, when the feeding reaches a specific amount, the feeding will be stopped, thereby improving the degree of automation of the device.

[0025] 3. In the present invention, when the temperature in the reaction chamber reaches 70 degrees Celsius, the temperature will be conducted to the temperature control chamber through the guide rod. When the reaction agent decomposes at 70 degrees Celsius, the reaction agent will produce gas. As the gas increases, a thrust will be generated on the sliding block, so that the sliding block moves upward. When the gas outlet opened at the lower end of the sliding block corresponds to the vent opened at the upper end of the temperature control chamber, the gas in the temperature control chamber will be discharged. In this way, the temperature in the reaction chamber can be monitored by the reaction agent, and monitoring the temperature of the reaction chamber by the reaction agent can improve the monitoring accuracy. BRIEF DESCRIPTION OF THE DRAWINGS

[0026] Figure 1 It is a schematic diagram of the overall structure of the present invention;

[0027] Figure 2 It is a schematic diagram of the internal structure of the present invention;

[0028] Figure 3 It is a schematic diagram of the structure of the heating component of the present invention;

[0029] Figure 4 It is a schematic diagram of the structure of the purification component of the present invention;

[0030] Figure 5 It is a schematic diagram of the structure of the temperature control component of the present invention;

[0031] Figure 6 It is a schematic diagram of the structure of the feed assembly of the present invention.

[0032] Explanation of the reference numerals in the figure: 1, reactor; 2, operating chamber; 3, feeding assembly; 301, second driving motor; 302, third gear; 303, fourth gear; 304, first rotating belt; 305, conveying pipe; 306, storage chamber; 307, circular connecting block; 308, guide pipe; 309, guide groove; 310, floating block; 311, circular trigger block; 4, heating assembly; 401, first transmission line; 402, first conductive Block; 403, second conductive block; 404, third conductive block; 405, annular heating wire; 5, reaction chamber; 6, purification component; 601, first drive motor; 602, first gear; 603, second gear; 604, guide rod; 605, temperature control component; 606, stirring rod; 607, temperature control chamber; 608, reaction reagent; 609, vent; 610, sliding block; 611, air outlet; 612, feed pipe. DETAILED DESCRIPTION

[0033] Example: See Figure 1 and Figure 2 , a device for preparing high-purity manganese sulfate using industrial manganese, comprising a reactor 1, an operating chamber 2 is connected to the upper end of the reactor 1, a feeding assembly 3 is connected to the upper end of the operating chamber 2, a heating assembly 4 is connected to the inner cavity of the reactor 1, a reaction chamber 5 is arranged at one end of the heating assembly 4 away from the reactor 1, and a purification assembly 6 is connected to the inner cavity of the reaction chamber 5;

[0034] See also Figure 3 The heating component 4 includes a first power transmission line 401, one end of the first power transmission line 401 is connected to a first conductive block 402, one end of the first conductive block 402 away from the first power transmission line 401 is rotatably connected to a second conductive block 403, one end of the second conductive block 403 away from the first conductive block 402 is connected to a third conductive block 404, and one end of the third conductive block 404 away from the second conductive block 403 is connected to a ring-shaped heating wire 405;

[0035] See also Figure 4 The purification component 6 includes a first drive motor 601, the output end of the first drive motor 601 is sleeved with a first gear 602, one end of the first gear 602 is meshed with a second gear 603, the middle part of the second gear 603 is connected to a guide rod 604, the inner cavity of the guide rod 604 is connected to a temperature control component 605, and the lower end surface of the guide rod 604 is connected to a plurality of stirring rods 606, and the first drive motor 601 is installed in the operating cavity 2, and the output end of the first drive motor 601 is connected to the first gear 602 through the lower end surface of the operating cavity 2.

[0036] The inner wall of the reactor 1 and the outer wall of the reaction chamber 5 form an annular cavity, and the annular heating wire 405 is installed in the annular cavity. A connecting groove is provided on the upper end surface of the third conductive block 404, and the connecting groove provided on the upper end of the third conductive block 404 matches with the second conductive block 403.

[0037] See also Figure 5 The temperature control component 605 includes a temperature control cavity 607, the inner cavity of the temperature control cavity 607 is filled with a reaction agent 608, and a plurality of ventilation holes 609 are arranged on the upper surface of the temperature control cavity 607, a sliding block 610 is connected to the upper inner cavity of the temperature control cavity 607, a plurality of air outlets 611 are opened at the lower end of the sliding block 610, and a feed pipe 612 is connected to one end of the temperature control cavity 607.

[0038] Specifically, when the temperature in the reaction chamber 5 reaches 70° C., the reaction agent 608 will undergo a chemical reaction to generate gas. As the gas increases, an upward thrust is generated on the sliding block 610, so that the sliding block 610 moves upward, thereby generating an upward thrust on the second conductive block 403, and separating the second conductive block 403 from the connecting grooves opened at the upper ends of the third conductive block 404, thereby cutting off the power to the annular heating wire 405, and stopping the heating of the annular heating wire 405, so that the temperature in the inner cavity of the reaction chamber 5 is maintained at 70° C. In this way, the decomposition reaction of the reaction agent 608 can achieve a physical power-off effect, thereby improving the accuracy of temperature control in the reaction chamber 5, and thereby improving the work efficiency of purifying manganese sulfate.

[0039] The number of ventilation holes 609 is equal to the number of air outlets 611, and the ventilation holes 609 correspond to the air outlets 611. The sliding block 610 contacts the lower end surface of the second conductive block 403 through the ground penetrating the operating chamber 2, and the sliding block 610 is rotatably connected to the lower end surface of the operating chamber 2. The sliding block 610 is made of insulating material. At the same time, the inner cavity of the lower end surface of the operating chamber 2 is hollow. When the gas generated by the reaction agent makes the air outlet 611 correspond to the ventilation holes 609, the gas in the temperature control chamber 607 will be discharged into the hollow cavity opened on the lower end surface of the operating chamber 2, and then discharged to the outside from the hollow cavity.

[0040] See also Figure 6 The feeding assembly 3 includes a second driving motor 301, the output end of the second driving motor 301 is sleeved with a third gear 302, one end of the third gear 302 is meshed with a fourth gear 303, a first rotating belt 304 is arranged above the fourth gear 303, and both ends of the first rotating belt 304 are sleeved with conveying pipes 305.

[0041] See also Figure 6The upper end of each conveying pipe 305 is connected to a storage cavity 306, and a circular connecting block 307 is connected to the inner cavity of each storage cavity 306. The upper end of the circular connecting block 307 arranged at one end close to the second driving motor 301 is connected to a guide tube 308, and a guide groove 309 is provided on the outer surface of the guide tube 308. A floating block 310 is connected to the inner cavity of the guide tube 308, and a circular trigger block 311 is connected to the lower end of the guide tube 308. The storage cavity 306 in the feeding assembly 3 is connected to the reactor 1 through the connecting block.

[0042] Specifically, when the temperature in the reaction chamber 5 reaches 70 degrees Celsius, the temperature will be conducted to the temperature control chamber 607 through the guide rod 604. When the reaction agent 608 decomposes at 70 degrees Celsius, the reaction agent 608 will produce gas. As the gas increases, a thrust will be generated on the sliding block 610, so that the sliding block 610 moves upward. When the gas outlet 611 opened at the lower end of the sliding block 610 corresponds to the vent 609 opened at the upper end of the temperature control chamber 607, the gas in the temperature control chamber 607 will be discharged. In this way, the temperature in the reaction chamber 5 can be monitored by the reaction agent 608, and monitoring the temperature of the reaction chamber 5 by the reaction agent 608 can improve the monitoring accuracy.

[0043] The outer surface of the conveying pipe 305 sleeved on one end of the first rotating belt 304 near the second driving motor 301 is connected to the fourth gear 303, the number of teeth arranged on the outer surface of the third gear 302 is equal to one-fourth of the number of teeth arranged on the outer surface of the fourth gear 303, the lower end surface of the floating block 310 is provided with a trigger groove, and the trigger groove arranged on the lower end surface of the floating block 310 is matched with the circular trigger block 311, the outer surface of the circular connecting block 307 is provided with a plurality of rectangular feeding ports, and the upper end surface of each conveying pipe 305 is provided with a plurality of rectangular shaped feed port, and the diameter of the rectangular feed port opened near the second drive motor 301 and the diameter of the rectangular feed port are equal to half the diameter of the rectangular feed port opened away from the second drive motor 301 and the diameter of the rectangular feed port. When the trigger groove opened at the lower end of the floating block 310 coincides with the circular trigger block 311, the second drive motor 301 will form a complete circuit, so that the second drive motor 301 will reverse, so that the rectangular feed port is separated from the rectangular feed port, and then the raw material transportation to the inner cavity of the reaction chamber 5 is stopped.

[0044] Specifically, by making the diameter of the rectangular feed port far from the second drive motor 301 and the diameter of the rectangular feed port equal to half of the diameter of the rectangular feed port close to the second drive motor 301, sulfuric acid and industrial manganese can be fed in proportion. When the trigger groove at the lower end of the float 310 coincides with the circular trigger block 311, a complete circuit is formed, so that the second drive motor 301 reverses one circle, and then the delivery pipe 305 reverses ninety degrees, so that the rectangular feed port is separated from the rectangular feed port, and the delivery of raw materials to the reaction chamber 5 is stopped. In this way, when the material delivery reaches a specific amount, the material delivery will be stopped, thereby improving the degree of automation of the device.

[0045] A method for preparing high-purity manganese sulfate using industrial manganese comprises the following steps:

[0046] S1. First, industrial manganese is put into a ball mill for crushing, and the particle size of the powder is uniform. Then, the crushed manganese material is taken out. At this time, the crushed manganese material is put into a cleaning container, and enough clean water is added to the cleaning container to cover the manganese material. Then, a stirrer is used to make the water and the manganese material fully contact to promote the dissolution and shedding of impurities. Then, the washed manganese material is filtered through a filter to remove impurities and solid particles suspended in the water. The filtered manganese material should be dried for standby use;

[0047] S2. After the manganese material is dried, the manganese material is placed in the storage chamber 306 installed at one end away from the second drive motor 301, and then the sulfuric acid solution is placed in the storage chamber 306 installed at one end close to the second drive motor 301, until the storage chamber 306 is filled with raw materials. At this time, the second drive motor 301 is started, and the third gear 302 is rotated one circle, so that the fourth gear 303 is rotated ninety degrees, and then the first rotating belt 304 and the conveying pipe 305 with both ends connected are rotated ninety degrees, and the rectangular conveying port is made to correspond to the rectangular feeding port, and then the manganese material and the sulfuric acid solution are allowed to enter the reaction chamber 5 through the conveying pipe 305;

[0048] S3, as the raw material in the storage chamber 306 decreases, the floating block 310 moves downward along the guide groove 309, and when the trigger groove at the lower end of the floating block 310 overlaps with the circular trigger block 311, a complete circuit is formed, so that the second driving motor 301 reverses one circle, and then the conveying pipe 305 reverses ninety degrees, so that the rectangular conveying port is separated from the rectangular feeding port, and the conveying of raw materials into the reaction chamber 5 stops;

[0049] S4. When the raw material is transported to the reaction chamber 5, power is turned on, so that the annular heating wire 405 generates heat, thereby heating the raw material in the reaction chamber 5. When the temperature in the reaction chamber 5 reaches 70°C, the guide rod 604 transmits the temperature to the reaction agent 608. The reaction agent 608 generates gas at 70°C, thereby pushing the sliding block 610 to move upward along the temperature control cavity 607, thereby generating a thrust on the second conductive block 403, thereby separating the second conductive block 403 from the connecting groove opened at the upper end of the third conductive block 404, thereby stopping the annular heating wire 405 from heating.

[0050] S5. When the temperature in the reaction chamber 5 reaches 70° C., the first drive motor 601 is started to drive the first gear 602 to rotate, thereby driving the second gear 603 to rotate, and then driving the stirring rod 606 to stir the reaction material to allow the manganese material to fully react with the sulfuric acid. When the manganese material is completely dissolved, the stirring and heating are stopped, and then the solution is cooled to room temperature and taken out. At this time, the dissolved and cooled manganese sulfate solution is slowly poured into the filter, and then the filtering device is started to allow the solution to pass through the filter, and the solid particles and impurities are intercepted on the filter medium, while the clear solution flows into the receiving container;

[0051] S6. When the solution completely passes through the filter, stop the operation of the filtering device, take out the filtered product in the receiving container, and then slowly pour the filtered manganese sulfate solution into the crystallization container, and adjust the temperature in the crystallization container according to the crystallization temperature of manganese sulfate, and then start the stirring device in the crystallization container to stir the solution, so that the solution is fully heated to promote the formation and growth of crystals. At the same time, during the crystallization process, regularly observe the state of the solution, such as the turbidity of the solution and the morphology of the crystals, to determine whether the crystallization has reached the desired degree;

[0052] S7. When the crystallization in the solution reaches the desired degree, stop heating or cooling to end the crystallization process, then separate the crystals and the solution in the crystallization container by a centrifuge, and dry the separated crystals to remove surface moisture to obtain dry manganese sulfate crystals. Finally, collect the dry manganese sulfate crystals, package and store them for subsequent use.

[0053] The above shows and describes the basic principles, main features and advantages of the present invention. Those skilled in the art should understand that the present invention is not limited by the above embodiments. The above embodiments and descriptions are only preferred examples of the present invention and are not intended to limit the present invention. Without departing from the spirit and scope of the present invention, the present invention may have various changes and improvements, which fall within the scope of the present invention. The scope of protection of the present invention is defined by the attached claims and their equivalents.

Claims

1. A device for preparing high-purity manganese sulfate using industrial manganese, comprising a reaction kettle (1), characterized in that: The upper end of the reactor (1) is connected to an operating chamber (2), the upper end of the operating chamber (2) is connected to a feeding assembly (3), and the inner chamber of the reactor (1) is connected to a heating assembly (4), a reaction chamber (5) is provided at one end of the heating assembly (4) away from the reactor (1), and the inner chamber of the reaction chamber (5) is connected to a purification assembly (6); The heating component (4) comprises a first transmission line (401), one end of the first transmission line (401) is connected to a first conductive block (402), one end of the first conductive block (402) away from the first transmission line (401) is rotatably connected to a second conductive block (403), one end of the second conductive block (403) away from the first conductive block (402) is connected to a third conductive block (404), and one end of the third conductive block (404) away from the second conductive block (403) is connected to a ring-shaped heating wire (405); The purification component (6) comprises a first driving motor (601), the output end of the first driving motor (601) is sleeved with a first gear (602), one end of the first gear (602) is meshed with a second gear (603), the middle part of the second gear (603) is connected to a guide rod (604), the inner cavity of the guide rod (604) is connected to a temperature control component (605), and the lower end surface of the guide rod (604) is connected to a plurality of stirring rods (606); The temperature control component (605) comprises a temperature control cavity (607), the inner cavity of the temperature control cavity (607) is filled with a reaction agent (608), and the upper surface of the temperature control cavity (607) is provided with a plurality of vents (609), the upper inner cavity of the temperature control cavity (607) is connected to a sliding block (610), the lower end of the sliding block (610) is provided with a plurality of air outlets (611), and one end of the temperature control cavity (607) is connected to a feed pipe (612); The feeding assembly (3) comprises a second driving motor (301), the output end of the second driving motor (301) is sleeved with a third gear (302), one end of the third gear (302) is meshed with a fourth gear (303), a first rotating belt (304) is arranged above the fourth gear (303), and both ends of the first rotating belt (304) are sleeved with conveying pipes (305); The upper end of each conveying pipe (305) is connected to a material storage cavity (306), the inner cavity of each material storage cavity (306) is connected to a circular connection block (307), the upper end of the circular connection block (307) arranged at one end close to the second drive motor (301) is connected to a guide tube (308), the outer surface of the guide tube (308) is provided with a guide groove (309), the inner cavity of the guide tube (308) is connected to a floating block (310), and the lower end of the guide tube (308) is connected to a circular trigger block (311).

2. The device for preparing high-purity manganese sulfate using industrial manganese according to claim 1, characterized in that: The inner wall of the reaction kettle (1) and the outer wall of the reaction chamber (5) form an annular cavity, and the annular heating wire (405) is installed in the annular cavity.

3. The device for preparing high-purity manganese sulfate using industrial manganese according to claim 2, characterized in that: The number of the ventilation holes (609) is equal to the number of the air outlets (611), and the ventilation holes (609) correspond to the air outlets (611). The sliding block (610) contacts the lower end surface of the second conductive block (403) through the ground that passes through the operating cavity (2).

4. The device for preparing high-purity manganese sulfate using industrial manganese according to claim 3, characterized in that: The outer surface of the conveying pipe (305) sleeved on one end of the first rotating belt (304) close to the second driving motor (301) is connected to the fourth gear (303), the number of teeth arranged on the outer surface of the third gear (302) is equal to one-fourth the number of teeth arranged on the outer surface of the fourth gear (303), and a trigger groove is provided on the lower end surface of the floating block (310), and the trigger groove provided on the lower end surface of the floating block (310) fits with the circular trigger block (311).

5. A method for preparing high-purity manganese sulfate using industrial manganese, according to the device for preparing high-purity manganese sulfate using industrial manganese according to any one of claims 1 to 4, characterized in that: The following steps are involved: S1. First, industrial manganese is put into a ball mill for crushing, and the particle size of the powder is uniform. Then, the crushed manganese material is taken out. At this time, the crushed manganese material is put into a cleaning container, and enough clean water is added to the cleaning container to cover the manganese material. Then, a stirrer is used to make the water and the manganese material fully contact to promote the dissolution and shedding of impurities. Then, the washed manganese material is filtered through a filter to remove impurities and solid particles suspended in the water. The filtered manganese material should be dried for standby use; S2. After the manganese material is dried, the manganese material is placed in a storage chamber (306) installed at one end away from the second drive motor (301), and then the sulfuric acid solution is placed in the storage chamber (306) installed at one end close to the second drive motor (301), until the storage chamber (306) is filled with the raw materials. At this time, the second drive motor (301) is started, and the third gear (302) is rotated one circle, so that the fourth gear (303) is rotated ninety degrees, and then the first rotating belt (304) and the conveying pipe (305) sleeved at both ends are rotated ninety degrees, and the rectangular conveying port is made to correspond to the rectangular feeding port, and then the manganese material and the sulfuric acid solution are allowed to enter the reaction chamber (5) through the conveying pipe (305); S3, as the amount of raw material in the material storage chamber (306) decreases, the floating block (310) moves downward along the guide groove (309), and when the trigger groove formed at the lower end of the floating block (310) overlaps with the circular trigger block (311), a complete circuit is formed, thereby causing the second drive motor (301) to reverse one circle, and then causing the conveying pipe (305) to reverse ninety degrees, so that the rectangular conveying port is separated from the rectangular feeding port, and the conveying of raw materials into the reaction chamber (5) stops; S4. When the raw material is transported to the reaction chamber (5), power is turned on, so that the annular heating wire (405) generates heat, thereby heating the raw material in the reaction chamber (5). When the temperature in the reaction chamber (5) reaches 70° C., the guide rod (604) transmits the temperature to the reaction agent (608). The reaction agent (608) generates gas at 70° C., thereby pushing the sliding block (610) to move upward along the temperature control cavity (607), thereby generating a thrust on the second conductive block (403), thereby separating the second conductive block (403) from the connecting groove opened at the upper end of the third conductive block (404), thereby stopping the annular heating wire (405) from generating heat; S5. When the temperature in the reaction chamber (5) reaches 70° C., the first drive motor (601) is started to drive the first gear (602) to rotate, thereby driving the second gear (603) to rotate, and further driving the stirring rod (606) to stir the reaction material to allow the manganese material to fully react with the sulfuric acid. When the manganese material is completely dissolved, the stirring and heating are stopped, and the solution is cooled to room temperature and taken out. At this time, the dissolved and cooled manganese sulfate solution is slowly poured into the filter, and then the filtering device is started to allow the solution to pass through the filter, and solid particles and impurities are intercepted on the filter medium, while the clear solution flows into the receiving container; S6. When the solution completely passes through the filter, stop the operation of the filtering device, take out the filtered product in the receiving container, and then slowly pour the filtered manganese sulfate solution into the crystallization container, and adjust the temperature in the crystallization container according to the crystallization temperature of manganese sulfate, and then start the stirring device in the crystallization container to stir the solution, so that the solution is fully heated to promote the formation and growth of crystals. At the same time, during the crystallization process, regularly observe the state of the solution, and observe the turbidity of the solution and the morphology of the crystals to determine whether the crystallization has reached the desired degree; S7. When the crystallization in the solution reaches the desired degree, stop heating or cooling to end the crystallization process, then separate the crystals and the solution in the crystallization container by a centrifuge, and dry the separated crystals to remove surface moisture to obtain dry manganese sulfate crystals. Finally, collect the dry manganese sulfate crystals, package and store them for subsequent use.

Images