Electrolyte detection equipment and system and control method thereof
Through automated electrolyte detection equipment and systems, the problems of large workload and low convenience caused by manual sampling in lithium-ion battery electrolyte detection are solved, and the automation and accuracy of electrolyte detection are improved.
Patent Information
- Application Number
- CN202411614497.6
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2024-11-13
- Publication Date
- 2024-12-20
AI Technical Summary
In the existing lithium-ion battery electrolyte detection, manual sampling and detection methods lead to large workload, low convenience and long test waiting period.
Design an electrolyte detection equipment and system to connect the electrolyte storage device, moisture detection device and hydrofluoric acid content detection device, and use the on-off control component to realize the automatic transmission and quantitative control of the electrolyte to reduce work and detection time to improve the convenience of detection and avoid manual detection errors.
The electrolyte detection is automated, the workload and detection time are reduced, the accuracy and convenience of detection are improved, the errors caused by manual sampling are avoided, and the detection reliability is improved through quantitative extraction and automatic cleaning.
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Figure CN119165034A_ABST
Abstract
Description
Technical Field
[0001] The present application relates to the field of battery technology, and in particular to an electrolyte detection device, system and control method thereof. Background Art
[0002] In the production process of lithium-ion batteries, the water content of the electrolyte is an important parameter to characterize the decomposition of lithium salts. A high water content will cause the decomposition of lithium salts and the battery cell to swell. The decomposition product hydrofluoric acid (HF) will damage the SEI film, resulting in poor cycle performance. At the same time, hydrofluoric acid will react with the impurities in the electrode, causing the battery cell to produce gas. Therefore, it is necessary to test the water content and hydrofluoric acid (HF) content of the electrolyte before injection.
[0003] At present, the water content and hydrofluoric acid (HF) content of electrolyte in the filling process are generally detected by manual detection method, that is, samples are taken manually from the head and tail of the filling tank and each filling machine station, and a test order number is written and sent to the testing laboratory for queue testing. This manual sampling and testing method leads to the defects of large workload and low convenience of electrolyte testing. Summary of the invention
[0004] In view of the above problems, the present application provides an electrolyte detection device, system and control method thereof, which can solve the problems of heavy workload, low convenience and long test waiting period in the current manual sampling detection method for electrolyte detection.
[0005] In the first aspect, the present application provides an electrolyte detection device, including a multifunctional testing device; the multifunctional testing device includes a moisture detection device and a hydrofluoric acid content detection device; the moisture detection device and the hydrofluoric acid content detection device are connected to an electrolyte storage device through an electrolyte pipeline, and an on-off control component is provided on the electrolyte pipeline; the on-off control component is used to control the electrolyte in the electrolyte storage device to be transmitted to the moisture detection device and the hydrofluoric acid content detection device respectively through the electrolyte pipeline; the moisture detection device is used to perform moisture detection on the received electrolyte to obtain a moisture detection result; the hydrofluoric acid content detection device is used to perform hydrofluoric acid content detection on the received electrolyte to obtain a hydrofluoric acid content detection result.
[0006] The electrolyte detection equipment designed as above, this scheme connects the electrolyte storage device to the moisture detection device and the hydrofluoric acid content detection device through pipelines, and then controls the transmission and quantitative control of the electrolyte through the on-off control component, thereby realizing automatic detection of the electrolyte, thereby reducing the workload and detection time of the electrolyte detection, improving the convenience of the electrolyte detection, and avoiding errors caused by manual detection and interference from the sampling and delivery environment.
[0007] In some embodiments, the electrolyte storage device includes an electrolyte storage tank and an injection machine; the electrolyte pipeline includes a first pipeline and a second pipeline; the electrolyte storage tank is connected to the moisture detection device and the hydrofluoric acid content detection device through the first pipeline, and the injection machine is connected to the moisture detection device and the hydrofluoric acid content detection device through the second pipeline; the on-off control component includes a first on-off control component and a second on-off control component; the first on-off control component is arranged on the first pipeline, and the second on-off control component is arranged on the second pipeline.
[0008] In the above implementation mode, this scheme can detect both the electrolyte storage tank and the liquid injection machine, and the electrolyte storage tank and the liquid injection machine use different electrolyte pipelines, thereby avoiding mutual interference between the electrolyte components on the electrolyte storage tank and the liquid injection machine, thereby improving the accuracy of electrolyte detection.
[0009] In some embodiments, the first pipeline includes a first branch pipeline and a second branch pipeline; the top of the electrolyte storage tank is connected to the moisture detection device and the hydrofluoric acid content detection device respectively through the first branch pipeline; the bottom of the electrolyte storage tank is connected to the moisture detection device and the hydrofluoric acid content detection device respectively through the second branch pipeline.
[0010] In the above embodiment, the electrolyte in different parts of the electrolyte storage tank can enter the moisture detection device and the hydrofluoric acid content detection device through the first branch pipe and the second branch pipe for detection, thereby realizing the detection of the electrolyte water content and hydrofluoric acid content at different positions in the electrolyte storage tank, thereby improving the accuracy of the detection of the electrolyte water content and hydrofluoric acid content in the electrolyte storage tank.
[0011] In some embodiments, the second pipeline includes a workstation transmission pipeline and a third branch pipeline; the first end of the workstation transmission pipeline is connected to the injection station of the injection machine, and the second end of the workstation transmission pipeline is connected to the moisture detection device and the hydrofluoric acid content detection device respectively through the third branch pipeline.
[0012] In the above implementation mode, this scheme can realize electrolyte transportation to multiple injection stations of the injection machine through the station transmission pipeline and the third branch pipeline, and then realize electrolyte moisture detection and hydrofluoric acid content detection of multiple injection stations, thereby improving the reliability and convenience of electrolyte detection of the injection machine.
[0013] In some embodiments, the liquid injection machine includes a plurality of liquid injection stations, the number of the station transmission pipelines is the same as the number of the liquid injection stations, and each liquid injection station is connected to a station transmission pipeline.
[0014] In the above implementation, each injection station is connected to a station transmission pipeline, so that the injection machine does not need to be rotated to switch between the station transmission pipeline and different injection machines, thereby improving the transmission convenience of electrolyte at different injection stations of the injection machine.
[0015] In some embodiments, the electrolyte detection equipment also includes a clean water storage tank, a clean water pipeline and a clean water control valve; the clean water control valve is arranged in the clean water pipeline, and the clean water storage tank is connected to the moisture detection device and the hydrofluoric acid content detection device respectively through the clean water pipeline; the clean water control valve is used to control the clean water in the clean water storage tank to enter the moisture detection device and the hydrofluoric acid content detection device to clean the moisture detection device and the hydrofluoric acid content detection device.
[0016] In the above implementation mode, the present solution controls the clean water through the clean water control valve to clean the moisture detection device and the hydrofluoric acid content detection device, thereby avoiding the influence of the residual liquid of the previous detection on the next detection, thereby improving the accuracy of the electrolyte detection.
[0017] In some embodiments, the electrolyte detection equipment also includes a waste liquid discharge pipe and a waste liquid control valve. The waste liquid control valve is arranged in the waste liquid discharge pipe, and the waste liquid discharge pipe is respectively connected to the moisture detection device and the hydrofluoric acid content detection device; the waste liquid control valve is used to control the discharge of waste liquid in the moisture detection device and the hydrofluoric acid content detection device.
[0018] In the above-mentioned implementation mode, this scheme controls the discharge of waste liquid that has been detected in the moisture detection device and / or the hydrofluoric acid content detection device, thereby facilitating subsequent detection and ensuring that the waste liquid left over from the previous detection will not affect the next detection, thereby improving the accuracy and automation of electrolyte detection.
[0019] In some embodiments, the moisture detection device includes a reaction cell; the reaction cell includes an anode, a cathode, an electrode, a built-in reaction space, a reagent pipeline and a reagent storage tank; the cathode and the electrode are arranged in the built-in reaction space, and a liquid inlet and a reagent pipeline port are opened on the reaction cell, the liquid inlet is connected to the electrolyte pipeline, one end of the reagent pipeline is connected to the reagent storage tank, and the other end of the reagent pipeline is connected to the reagent pipeline port, and a reagent control valve is arranged in the reagent pipeline; an on-off control component is used to control the first target capacity of electrolyte in the electrolyte pipeline to be transmitted to the built-in reaction space of the reaction cell; the reagent control valve is used to control the second target capacity of moisture detection reagent in the reagent storage tank to be transmitted to the built-in reaction space of the reaction cell, so that the moisture detection reagent reacts with the electrolyte to achieve moisture measurement.
[0020] In some embodiments, the hydrofluoric acid content detection device includes a sample injection turntable and a potentiometric titrator; a plurality of sample stations are arranged on the sample injection turntable, and each sample station enters the titration area of the potentiometric titrator in turn when the sample injection turntable rotates; a reagent addition pipeline is arranged on the potentiometric titrator, and the potentiometric titrator is used to titrate the hydrofluoric acid content detection reagent in the reagent addition pipeline into the sample station entering the titration area; the electrolyte pipeline is connected to the sample injection turntable to transfer the electrolyte to each sample station of the sample injection turntable in turn.
[0021] In a second aspect, the present application provides an electrolyte detection system, which includes an electrolyte detection device and a control device of any optional embodiment in the first aspect, and the control device is electrically connected to the on-off control component to control the opening and closing of the on-off control component.
[0022] The electrolyte detection system designed as above, this scheme connects the electrolyte storage device to the moisture detection device and the hydrofluoric acid content detection device through pipelines, and then controls the transmission and quantitative control of the electrolyte through the on-off control component, thereby realizing automatic detection of the electrolyte, thereby reducing the workload and detection time of the electrolyte detection, improving the convenience of the electrolyte detection, and avoiding errors caused by manual detection and interference from the sampling and delivery environment.
[0023] In a third aspect, the present application provides an electrolyte detection control method, which is applied to the control device in the second aspect, and the method includes: controlling the on-off control component to open according to the electrolyte detection request, and controlling the on-off control component to close after a preset time period, so as to control the electrolyte of a preset capacity in the electrolyte storage device to be transmitted to the moisture detection device and the hydrofluoric acid content detection device through the electrolyte pipeline respectively; controlling the moisture detection device to perform moisture detection on the received electrolyte to obtain a moisture detection result; controlling the hydrofluoric acid content detection device to perform hydrofluoric acid content detection on the received electrolyte to obtain a hydrofluoric acid content detection result.
[0024] The electrolyte detection control method designed above connects the electrolyte storage device to the moisture detection device and the hydrofluoric acid content detection device through pipelines, and then controls the transmission and quantitative control of the electrolyte through the on-off control component, thereby realizing automatic detection of the electrolyte, thereby reducing the workload and detection time of the electrolyte detection, improving the convenience of the electrolyte detection, and avoiding errors caused by manual detection and interference from the sampling and delivery environment.
[0025] In an optional embodiment of the third aspect, the electrolyte detection equipment also includes a clean water storage tank, a clean water pipe and a clean water control valve, the clean water control valve is arranged in the clean water pipe, and the clean water storage tank is connected to the moisture detection device and the hydrofluoric acid content detection device respectively through the clean water pipe; the method also includes: detecting whether the moisture detection device and / or the hydrofluoric acid content detection device completes the current detection; if the moisture detection device and / or the hydrofluoric acid content detection device completes the current detection, controlling the clean water control valve to open, so as to control the clean water in the clean water storage tank to clean the moisture detection device and / or the hydrofluoric acid content detection device.
[0026] In an optional implementation of the third aspect, the electrolyte detection equipment also includes a waste liquid discharge pipeline and a waste liquid control valve, and the waste liquid discharge pipeline is respectively connected to the moisture detection device and the hydrofluoric acid content detection device; the method also includes: detecting whether the moisture detection device and / or the hydrofluoric acid content detection device completes the current detection; if the moisture detection device and / or the hydrofluoric acid content detection device completes the current detection, controlling the waste liquid control valve to open, so as to control the waste liquid in the moisture detection device and the hydrofluoric acid content detection device to be discharged.
[0027] In a fourth aspect, the present application provides an electronic device, comprising a memory and a processor, wherein the memory stores a computer program, and when the processor executes the computer program, the method in the third aspect and any optional implementation manner in the third aspect is executed.
[0028] In a fifth aspect, the present application provides a computer-readable storage medium having a computer program stored thereon, and when the computer program is executed by a processor, the method in the third aspect or any optional implementation in the third aspect is executed.
[0029] In a sixth aspect, the present application provides a computer program product, which, when running on a computer, enables the computer to execute the method in the third aspect or any optional implementation manner of the third aspect.
[0030] The above description is only an overview of the technical solution of the present application. In order to more clearly understand the technical means of the present application, it can be implemented in accordance with the contents of the specification. In order to make the above and other purposes, features and advantages of the present application more obvious and easy to understand, the specific implementation methods of the present application are listed below. BRIEF DESCRIPTION OF THE DRAWINGS
[0031] Various other advantages and benefits will become apparent to those of ordinary skill in the art by reading the detailed description of the preferred embodiments below. The accompanying drawings are only for the purpose of illustrating the preferred embodiments and are not to be considered as limiting the present application. Moreover, the same reference numerals are used throughout the drawings to represent the same components. In the drawings: Figure 1 A first structural schematic diagram of an electrolyte detection device provided in an embodiment of the present application; Figure 2 A second structural schematic diagram of the electrolyte detection device provided in an embodiment of the present application; Figure 3 A third structural schematic diagram of the electrolyte detection device provided in an embodiment of the present application; Figure 4 A fourth structural schematic diagram of the electrolyte detection device provided in an embodiment of the present application; Figure 5 A fifth structural schematic diagram of the electrolyte detection device provided in an embodiment of the present application; Figure 6 A sixth structural schematic diagram of the electrolyte detection device provided in an embodiment of the present application; Figure 7 A seventh structural schematic diagram of the electrolyte detection device provided in an embodiment of the present application; Figure 8 An eighth structural schematic diagram of the electrolyte detection device provided in an embodiment of the present application; Fig. 9 A first structural schematic diagram of a moisture detection device provided in an embodiment of the present application; Fig.10 A second structural schematic diagram of the moisture detection device provided in an embodiment of the present application; Fig.11 A schematic diagram of the structure of a hydrofluoric acid content detection device provided in an embodiment of the present application; Fig.12 A first structural schematic diagram of an electrolyte detection system provided in an embodiment of the present application; Fig.13 A second structural schematic diagram of the electrolyte detection system provided in an embodiment of the present application; Fig.14 A schematic diagram of a flow chart of an electrolyte detection method provided in an embodiment of the present application; Fig.15 A schematic diagram of the structure of an electronic device provided in an embodiment of the present application.
[0032] Icons: 1-electrolyte detection equipment; 2-control device; 3-display screen; 10-multi-function test device; 110-water detection device; 1110-reaction pool; 1110A-liquid inlet; 1110B-reagent pipeline port; 1110C-clean water port; 1120-reagent storage tank; 1130-control valve; N1-anode; N2-cathode; N3-electrode; N4-built-in reaction space; 120-hydrofluoric acid content detection device; 1210-injection turntable; 1210A-sample station; 1220-potentiometric titrator; 1220A-reagent addition pipeline; 20-electrolyte pipeline; 210-first pipeline; 2110-first Branch pipeline; 2120-second branch pipeline; 220-second pipeline; 2210-station transmission pipeline; 2220-third branch pipeline; 30-electrolyte storage device; 310-electrolyte storage tank; 320-liquid injection machine; 3210-liquid injection station; 40-on-off control component; 410-first on-off control component; 420-second on-off control component; 50-first water pump; 60-second water pump; 70-clean water storage tank; 80-clean water pipeline; 90-clean water control valve; 91-waste liquid discharge pipeline; 92-waste liquid control valve; 15-electronic equipment; 1501-processor; 1502-memory; 1503-communication bus. DETAILED DESCRIPTION
[0033] The following embodiments of the technical solution of the present application are described in detail in conjunction with the accompanying drawings. The following embodiments are only used to more clearly illustrate the technical solution of the present application, and are therefore only used as examples, and cannot be used to limit the scope of protection of the present application.
[0034] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by technicians in the technical field to which this application belongs; the terms used herein are only for the purpose of describing specific embodiments and are not intended to limit this application; the terms "including" and "having" in the specification and claims of this application and the above-mentioned figure descriptions and any variations thereof are intended to cover non-exclusive inclusions.
[0035] In the description of the embodiments of the present application, the technical terms "first", "second", etc. are only used to distinguish different objects, and cannot be understood as indicating or implying relative importance or implicitly indicating the number, specific order or primary and secondary relationship of the indicated technical features. In the description of the embodiments of the present application, the meaning of "multiple" is more than two, unless otherwise clearly and specifically defined.
[0036] Reference to "embodiments" herein means that a particular feature, structure, or characteristic described in conjunction with the embodiments may be included in at least one embodiment of the present application. The appearance of the phrase in various locations in the specification does not necessarily refer to the same embodiment, nor is it an independent or alternative embodiment that is mutually exclusive with other embodiments. It is explicitly and implicitly understood by those skilled in the art that the embodiments described herein may be combined with other embodiments.
[0037] In the description of the embodiments of the present application, the term "and / or" is only a description of the association relationship of the associated objects, indicating that there may be three relationships. For example, A and / or B can represent: A exists alone, A and B exist at the same time, and B exists alone. In addition, the character " / " in this article generally indicates that the associated objects before and after are in an "or" relationship.
[0038] In the description of the embodiments of the present application, the term "multiple" refers to more than two (including two). Similarly, "multiple groups" refers to more than two groups (including two groups), and "multiple pieces" refers to more than two pieces (including two pieces).
[0039] In the description of the embodiments of the present application, the technical terms "center", "longitudinal", "lateral", "length", "width", "thickness", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside", "outside", "clockwise", "counterclockwise", "axial", "radial", "circumferential", etc. indicate orientations or positional relationships based on the orientations or positional relationships shown in the accompanying drawings, which are only for the convenience of describing the embodiments of the present application and simplifying the description, and do not indicate or imply that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be understood as a limitation on the embodiments of the present application.
[0040] In the description of the embodiments of the present application, unless otherwise clearly specified and limited, technical terms such as "installed", "connected", "connected", "fixed" and the like should be understood in a broad sense. For example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium, and it can be the internal connection of two elements or the interaction relationship between two elements. For those of ordinary skill in the art, the specific meanings of the above terms in the embodiments of the present application can be understood according to the specific circumstances.
[0041] In the production process of lithium-ion batteries, the water content of the electrolyte is an important parameter to characterize the decomposition of lithium salts. A high water content will cause the decomposition of lithium salts and the battery cell to swell. The decomposition product hydrofluoric acid (HF) will damage the SEI film, resulting in poor cycle performance. At the same time, hydrofluoric acid will react with the impurities in the electrode, causing the battery cell to produce gas. Therefore, it is necessary to test the water content and hydrofluoric acid (HF) content of the electrolyte before injection.
[0042] At present, the water content and hydrofluoric acid (HF) content of electrolyte in the filling process are generally detected by manual detection method, that is, samples are taken manually from the head and tail of the filling tank and each filling machine station, and a test order number is written and sent to the testing laboratory for queue testing. This manual sampling and testing method leads to the defects of large workload, low convenience and long test waiting period for electrolyte testing.
[0043] Based on the above problems, the present application designs an electrolyte detection device, system and control method thereof, wherein the electrolyte storage device is connected to the moisture detection device and the hydrofluoric acid content detection device through pipelines, and then the transmission and quantitative control of the electrolyte are controlled by the on-off control component, so as to realize the automatic detection of the electrolyte, thereby reducing the workload and detection time of the electrolyte detection, improving the convenience of the electrolyte detection, and avoiding the errors caused by the interference of the manual detection and the sampling and sample delivery environment. In addition, the present scheme also realizes the electrolyte detection by quantitatively extracting the electrolyte from different points of the electrolyte storage device, thereby improving the detection reliability. At the same time, the present scheme also automatically completes the waste liquid discharge and the introduction of pure water for cleaning after the test is completed, thereby avoiding the mutual interference of the detection liquid and improving the detection accuracy. Furthermore, the present scheme can also be equipped with liquid level monitoring for the reagents and waste liquids, and can issue a warning of insufficient reagents and a warning of the waste liquid page exceeding the warning, so as to timely remind the reagents to be replenished and the waste liquid to be discharged in time.
[0044] Based on the above ideas, the present application first provides an electrolyte detection device, such as Figure 1 As shown, the electrolyte detection equipment includes a multifunctional testing device 10, which includes a moisture detection device 110 and a hydrofluoric acid content detection device 120. The moisture detection device 110 is used to detect the moisture content in the electrolyte. For example, the moisture detection device 110 can use Karl Fischer reagent to detect the water content of the electrolyte. The hydrofluoric acid content detection device 120 is used to detect the hydrofluoric acid content in the electrolyte. For example, the hydrofluoric acid content detection device 120 can detect the hydrofluoric acid content in the electrolyte by chemical titration.
[0045] Please continue to refer to Figure 1 The moisture detection device 110 and the hydrofluoric acid content detection device 120 are both connected to the electrolyte storage device 30 through the electrolyte pipeline 20, and the electrolyte pipeline 20 is provided with an on-off control component 40.
[0046] In the electrolyte detection equipment designed as above, the on-off control component 40 can control whether the electrolyte in the electrolyte pipeline 20 flows or not by opening or closing itself. When performing detection, the on-off control component 40 can be opened, so that the electrolyte in the electrolyte storage device 30 flows to the moisture detection device 110 and the hydrofluoric acid content detection device 120 respectively through the electrolyte pipeline 20, thereby performing moisture detection and hydrofluoric acid detection on the electrolyte in the electrolyte storage device 30, thereby realizing automatic detection of the electrolyte.
[0047] The electrolyte detection equipment designed as above, this scheme connects the electrolyte storage device to the moisture detection device and the hydrofluoric acid content detection device through pipelines, and then controls the transmission and quantitative control of the electrolyte through the on-off control component, thereby realizing automatic detection of the electrolyte, thereby reducing the workload and detection time of the electrolyte detection, improving the convenience of the electrolyte detection, and avoiding errors caused by manual detection and interference from the sampling and delivery environment.
[0048] As a possible implementation, Figure 2 As shown, the electrolyte storage device 30 designed in this scheme may include an electrolyte storage tank 310 and a liquid injection machine 320, the electrolyte pipeline 20 may include a first pipeline 210 and a second pipeline 220, the electrolyte storage tank 310 is connected to the moisture detection device 110 and the hydrofluoric acid content detection device 120 through the first pipeline 210, and the liquid injection machine 320 is connected to the moisture detection device 110 and the hydrofluoric acid content detection device 120 through the second pipeline 220; the on-off control component 40 includes a first on-off control component 410 and a second on-off control component 420; the first on-off control component 410 is arranged on the first pipeline 210, and the second on-off control component 420 is arranged on the second pipeline 220.
[0049] In the above-mentioned implementation mode, this scheme can detect both the electrolyte storage tank 310 and the injection machine 320, and the electrolyte pipelines used in the electrolyte storage tank 310 and the injection machine 320 are different, thereby avoiding mutual interference between the electrolyte components on the electrolyte storage tank 310 and the injection machine 320, thereby improving the accuracy of electrolyte detection.
[0050] Specifically, Figure 3 As shown, the first pipeline 210 designed in this scheme may include a first branch pipeline 2110 and a second branch pipeline 2120. The top of the electrolyte storage tank 310 is connected to the moisture detection device 110 and the hydrofluoric acid content detection device 120 respectively through the first branch pipeline 2110, and the bottom of the electrolyte storage tank 310 is connected to the moisture detection device 110 and the hydrofluoric acid content detection device 120 respectively through the second branch pipeline 2120.
[0051] Since the composition of the electrolyte at different positions in the electrolyte storage tank 310 may be different, the above-mentioned implementation method of the present scheme connects the top and the bottom of the electrolyte storage tank 310 respectively through the first branch pipe 2110 and the second branch pipe 2120, so that the electrolyte in different parts of the electrolyte storage tank 310 can enter the moisture detection device 110 and the hydrofluoric acid content detection device 120 through the first branch pipe 2110 and the second branch pipe 2120 for detection, thereby realizing the detection of the electrolyte water content and the hydrofluoric acid content at different positions in the electrolyte storage tank 310, thereby improving the accuracy of the detection of the electrolyte water content and the hydrofluoric acid content in the electrolyte storage tank 310.
[0052] As a specific implementation method, Figure 4 As shown, the first branch pipeline 2110 and the second branch pipeline 2120 designed in this solution can be as follows Figure 4 The pipeline A, pipeline B, pipeline C, pipeline D and pipeline F are shown, wherein the first end of pipeline A is connected to the top of the electrolyte storage tank 310, the second end of pipeline A is connected to the first end of pipeline B, the first end of pipeline C is connected to the bottom of the electrolyte storage tank 310, the second end of pipeline C is also connected to the first end of pipeline B, the second end of pipeline B is connected to the moisture detection device 110 through pipeline D, and the second end of pipeline B is also connected to the hydrofluoric acid content detection device 120 through pipeline F.
[0053] In the implementation mode of the above-mentioned design, the electrolyte flowing out from the top of the electrolyte storage tank 310 can flow to the moisture detection device 110 through the pipeline D, and flow to the hydrofluoric acid content detection device 120 through the pipeline F, and the electrolyte at the bottom of the electrolyte storage tank 310 can also be transmitted to the moisture detection device 110 through the pipeline D, and transmitted to the hydrofluoric acid content detection device 120 through the pipeline F. In this way, the electrolyte at the top and bottom of the electrolyte storage tank 310 share the pipeline D and the pipeline F, thereby realizing pipeline sharing and achieving the purpose of saving pipeline costs.
[0054] In an optional implementation of this embodiment, if Figure 4 As shown, the electrolyte detection equipment designed in this scheme may also include a first water pump 50, which can be set on the pipeline B. The first water pump 50 can extract the electrolyte from the top or bottom of the electrolyte storage tank 310, thereby applying power to the extracted electrolyte, so that the electrolyte is transmitted to the moisture detection device 110 through the pipeline D, and is transmitted to the hydrofluoric acid content detection device 120 through the pipeline F.
[0055] In the implementation method of the above-mentioned design, this solution accelerates the flow rate of the electrolyte in the electrolyte storage tank to the moisture detection device and the hydrofluoric acid content detection device through the first water pump, thereby improving the detection efficiency of the electrolyte.
[0056] In an optional implementation of this embodiment, if Figure 4As shown, the first on-off control component 410 designed in the present solution may specifically include a first valve A1, a second valve A2, a third valve A3 and a fourth valve A4. The first valve A1 is arranged in the pipeline A, the second valve A2 is arranged in the pipeline C, the third valve A3 is arranged in the pipeline D, and the fourth valve A4 is arranged in the pipeline F. In this way, the flow rate control and flow direction control of the electrolyte flowing out of the electrolyte storage tank 310 can be achieved by controlling the multiple valves.
[0057] For example, assuming that the electrolyte at the top of the electrolyte storage tank 310 needs to be tested for moisture. In this case, the present solution only needs to control the first valve A1 and the third valve A3 to be opened, and the second valve A2 and the fourth valve A4 to be closed. In this way, the electrolyte at the top of the electrolyte storage tank 310 can be transmitted to the moisture detection device 110 through the pipeline A, the pipeline B and the pipeline D for moisture detection; for another example, assuming that the electrolyte at the bottom of the electrolyte storage tank 310 needs to be tested for moisture and hydrofluoric acid content. In this case, the present solution controls the first valve A1 to be closed, and the second valve A2, the third valve A3 and the fourth valve A4 to be opened. In this way, the electrolyte at the bottom of the electrolyte storage tank can be transmitted to the moisture detection device 110 and the hydrofluoric acid content detection device 120 through the pipeline C, the pipeline B, the pipeline D and the pipeline F respectively to realize moisture and hydrofluoric acid content detection.
[0058] In the implementation scheme of the above-mentioned design, multiple valves are arranged in multiple pipes, so that the electrolyte at the top and / or bottom of the electrolyte storage tank 310 can realize arbitrary detection control of moisture detection and hydrofluoric acid detection through the control of multiple valves, thereby improving the controllability of electrolyte detection.
[0059] Of course, the first branch pipe and the second branch pipe designed in this solution can be in any other form, as long as the electrolyte at the top and bottom of the electrolyte storage tank 310 can be transmitted to the moisture detection device 110 and the hydrofluoric acid content detection device 120 respectively. For example, Figure 5 As shown, the first branch pipe 2110 and the second branch pipe 2120 can be as follows Figure 5 In the form of pipeline A, pipeline B, pipeline C, pipeline D, pipeline E and pipeline F shown, the top of the electrolyte storage tank 310 is connected to the first end of pipeline A, the second end of pipeline A is connected to the first end of pipeline B and the first end of pipeline C, the second end of pipeline B is connected to the moisture detection device 110, and the second end of pipeline C is connected to the hydrofluoric acid content detection device 120; the bottom of the electrolyte storage tank 310 is connected to the first end of pipeline D, the second end of pipeline D is connected to the first end of pipeline E and the first end of pipeline F, the second end of pipeline E is connected to the moisture detection device 110, and the second end of pipeline F is connected to the hydrofluoric acid content detection device 120.
[0060] In an optional implementation of this embodiment, if Figure 6 As shown, the liquid injection machine 320 includes multiple liquid injection stations 3210. In this case, the second pipeline 220 designed in this scheme may include a station transmission pipeline 2210 and a third branch pipeline 2220. The first end of the station transmission pipeline 2210 is connected to the liquid injection station 3210 of the liquid injection machine, and the second end of the station transmission pipeline 2210 is connected to the moisture detection device 110 and the hydrofluoric acid content detection device 120 through the third branch pipeline 2220.
[0061] In the above embodiment, the liquid injection machine 320 includes a plurality of liquid injection stations 3210, each of which carries electrolyte, and the positions of the plurality of liquid injection stations 3210 can change with the rotation of the liquid injection machine 320, so that during the rotation process, the plurality of liquid injection stations 3210 are respectively docked with the station transmission pipeline 2210, so that the electrolyte in each liquid injection station 3210 on the liquid injection machine 320 can be transmitted to the third branch pipeline 2220 through the station transmission pipeline 2210, and then transmitted to the moisture detection device 110 and the hydrofluoric acid content detection device 120, so as to realize moisture detection and hydrofluoric acid content detection.
[0062] In the above implementation mode, this scheme can realize electrolyte transportation of multiple injection stations 3210 of the injection machine 320 through the station transmission pipeline 2210 and the third branch pipeline 2220, and then realize electrolyte moisture detection and hydrofluoric acid content detection of multiple injection stations 3210, thereby improving the reliability and convenience of electrolyte detection of the injection machine.
[0063] As a possible implementation manner, the number of station transmission pipelines 2210 in this scheme is the same as the number of injection stations 3210 of the injection machine 320. In this way, each injection station 3210 is connected to a station transmission pipeline 2210, so that the injection machine 320 does not need to be rotated to switch between the station transmission pipelines 2210 and different injection stations 3210, thereby improving the convenience of transferring the electrolyte on different injection stations 3210 of the injection machine 320.
[0064] As a specific implementation method, Figure 7 As shown, the third branch pipeline 2220 designed in this scheme may specifically include pipeline J, pipeline K and pipeline L. The first end of pipeline J is connected to the workstation transmission pipeline 2210, the second end of pipeline J is connected to the moisture detection device through pipeline K, and the second end of pipeline J is also connected to the hydrofluoric acid content detection device through pipeline L, thereby realizing the transmission of electrolyte.
[0065] In an optional implementation of this embodiment, the electrolyte detection equipment designed in this scheme may also include a second water pump 60, which can be set on the pipeline J, so that the electrolyte in the injection station 3210 is extracted by the second water pump 60 and then transmitted to the pipeline K or pipeline L for detection.
[0066] In the above-mentioned implementation mode, the present solution accelerates the transmission speed of the electrolyte from the liquid injection machine 320 to the moisture detection device 110 and / or the hydrofluoric acid content detection device 120 by the second water pump 60, thereby improving the detection efficiency.
[0067] In an optional implementation of this embodiment, if Figure 7 As shown, the second on-off control component 420 designed in this scheme may include a fifth valve A5, a sixth valve A6 and a seventh valve A7, wherein the fifth valve is arranged in the workstation transmission pipeline 2210, the sixth valve A6 is arranged in the pipeline K, and the seventh valve A7 is arranged in the pipeline L, so that various detection controls can be realized through valve control.
[0068] In an optional implementation of this embodiment, if Figure 8 As shown, the electrolyte detection equipment designed in this scheme also includes a clean water storage tank 70, a clean water pipeline 80 and a clean water control valve 90. The clean water control valve 90 is arranged in the clean water pipeline 80, and the clean water storage tank 70 is connected to the moisture detection device 110 and the hydrofluoric acid content detection device 120 respectively through the clean water pipeline 80.
[0069] In the electrolyte detection equipment designed as above, the clean water control valve 90 can control the clean water stored in the clean water storage tank 70 to be transmitted to the moisture detection device 110 and the hydrofluoric acid content detection device 120 through the clean water pipeline 80, thereby cleaning the moisture detection device 110 and the hydrofluoric acid content detection device 120.
[0070] As a possible implementation mode, this scheme can control the clean water control valve 90 to open when the moisture detection device 110 completes the current detection and / or the hydrofluoric acid content detection device 120 completes the current detection, so that the clean water in the clean water storage tank can clean the moisture detection device 110 and / or the hydrofluoric acid content detection device 120 that have completed the current detection, thereby avoiding the influence of the residual liquid from the previous detection on the next detection, thereby improving the accuracy of electrolyte detection.
[0071] In an optional implementation of this embodiment, if Figure 8 As shown, the electrolyte detection equipment designed in this scheme also includes a waste liquid discharge pipeline 91 and a waste liquid control valve 92. The waste liquid control valve 92 is arranged in the waste liquid discharge pipeline 91, and the waste liquid discharge pipeline 91 is respectively connected to the moisture detection device 110 and the hydrofluoric acid content detection device 120.
[0072] In the implementation manner of the above-mentioned design, the waste liquid control valve 92 can control the waste liquid in the water content detection device 110 and / or the hydrofluoric acid content detection device 120 to be discharged. Specifically, this solution can control the waste liquid control valve 92 to be opened when the water content detection device 110 completes the current detection and / or the hydrofluoric acid content detection device 120 completes the current detection, so that the waste liquid that has been detected in the water content detection device 110 and / or the hydrofluoric acid content detection device 120 is discharged, thereby facilitating subsequent detection and ensuring that the waste liquid left over from the previous detection will not affect the next detection, thereby improving the accuracy and automation of electrolyte detection.
[0073] In an optional implementation of this embodiment, if Fig. 9 As shown, the moisture detection device 110 designed in this scheme may include a reaction cell 1110, and the reaction cell 1110 may include an anode N1, a cathode N2, an electrode N3 and a built-in reaction space N4, the cathode N2 and the electrode N3 are arranged in the built-in reaction space N4, the anode N1 is arranged at the edge of the reaction cell 1110, and a liquid inlet 1110A and a reagent pipeline port 1110B are opened on the reaction cell 1110, the liquid inlet 1110A can be connected to the electrolyte pipeline 20, for example, the liquid inlet 1110A can be connected to the pipeline D described above, and the liquid inlet 1110A can also be connected to the pipeline K described above, and the reagent pipeline port 1110B is used to add a moisture detection reagent.
[0074] In the moisture detection device designed as above, the liquid inlet 1110A can transfer the electrolyte to be detected transmitted by the electrolyte pipeline 20 to the built-in reaction space N4 of the reaction cell 1110, and the reagent pipeline port 1110B can add the moisture detection reagent to the built-in reaction space N4, so that the electrolyte and the moisture detection reagent react to realize the moisture detection of the electrolyte. Specifically, when the electrode N3 detects water in the electrolyte, the electrolyte near the anode N1 is I - Begins to be oxidized to I 2 It then produces a quantitative chemical reaction with water. According to Faraday's law of electrolysis, the amount of electricity generated by electrolysis is directly proportional to the water content. In this way, the water content in the electrolyte can be obtained through the linear relationship between electricity and water content.
[0075] As a possible implementation, Fig. 9As shown, the reagent pipeline port 1110B can be connected to the reagent storage tank 1120, and a certain volume of reagent is stored in the reagent storage tank 1120. A reagent control valve 1130 can be set at the reagent pipeline port 1110B. This solution can control the volume of reagent transmitted from the reagent pipeline port 1110B to the reaction tank 1110 by controlling the reagent control valve 1130, thereby realizing quantitative extraction of the reagent; in the case of realizing quantitative extraction of the reagent, this solution can control the volume of electrolyte entering the reaction tank 1110 by controlling the opening time of the on-off control component 40 in the electrolyte pipeline 20, thereby realizing quantitative extraction of the electrolyte to be detected, and then the volume of electrolyte and reagent entering the reaction tank can be controlled, realizing quantitative and sufficient reaction of the reagent and the electrolyte, and then the water content in the electrolyte can be calculated by obtaining the amount of electricity generated by electrolysis, thereby improving the accuracy and controllability of electrolyte detection.
[0076] Furthermore, the present solution may be provided with a liquid level monitoring device in the reagent storage tank 1120 to monitor the reagent liquid level in the reagent storage tank 1120. When the reagent liquid level in the reagent storage tank 1120 is less than the monitoring liquid level, an alarm is issued to remind the staff to add reagents. Among them, the moisture detection reagent used in the present solution may be a Karl Fischer reagent. Specifically, the liquid level monitoring device may be an infrared sensor, which is arranged on a side wall in the reagent storage tank 1120. When the reagent liquid level in the reagent storage tank is below the infrared detection light emitted by the infrared sensor, the infrared sensor sends an alarm signal, thereby realizing an alarm reminder.
[0077] In an optional implementation manner of the present embodiment, the bottom of the reaction pool 1110 designed in the present scheme can be connected to the waste liquid discharge pipe 91. After the electrolyte and detection reagent testing in the reaction pool 1110 is completed, the present scheme can control the waste liquid control valve 92 to open, so that the mixed waste liquid formed by the electrolyte and detection reagent in the reaction pool 1110 is discharged through the waste liquid discharge pipe 91, thereby avoiding the waste liquid from affecting the next electrolyte detection.
[0078] In an optional implementation of this embodiment, if Fig.10 As shown, the reaction pool 1110 designed in this solution is also provided with a clean water port 1110C, which can be connected to the clean water pipeline 80 described above. After the electrolyte and detection reagent tests in the reaction pool 1110 are completed, the solution can control the clean water control valve 90 to open, so that the clean water in the clean water storage tank 70 enters the reaction pool 1110 through the clean water port 1110C, thereby cleaning the reaction pool 1110. As a possible implementation, the solution can control the clean water control valve to open after the waste liquid in the reaction pool 1110 is discharged, so that the reaction pool 1110 is cleaned with clean water, and the waste liquid generated by cleaning the reaction pool 1110 is discharged through the waste liquid discharge pipeline 91.
[0079] In an optional implementation of this embodiment, if Fig.11 As shown, the hydrofluoric acid content detection device 120 designed in this scheme may include a sample injection turntable 1210 and a potentiometric titrator 1220, and a plurality of sample stations 1210A are arranged on the sample injection turntable 1210, and each sample station 1210A enters the titration area of the potentiometric titrator 1220 in sequence when the sample injection turntable 1210 rotates; a reagent addition pipeline 1220A is arranged on the potentiometric titrator 1220, and the potentiometric titrator 1220 is used to titrate the hydrofluoric acid content detection reagent added through the reagent addition pipeline into the entered sample station 1210A; the electrolyte pipeline 20 is connected to the sample injection turntable 1210 to transfer the electrolyte to each sample station 1210A of the sample injection turntable 1210 in sequence.
[0080] In the case of the above design, the second on-off control component 420 can be disposed between the electrolyte pipeline 20 and the injection turntable 1210 , so as to control the electrolyte flowing from the electrolyte pipeline 20 to the injection turntable 1210 .
[0081] In the above implementation, the present solution realizes the detection of the hydrofluoric acid content of the electrolyte by using the sample injection turntable 1210 and the potentiometric titrator 1220, wherein the calculation of the hydrofluoric acid content detection can be obtained by the following formula: ; Where, 0.01 represents the concentration of NaOH standard solution, in mol / L; V 0 It indicates the volume reading of the burette before the titration starts, in ml; V indicates the volume reading of the burette after the electrolyte sample is added and the titration reaches the end point, in ml; 20 indicates the molar molecular weight of HF, in g / mol; m indicates the amount of electrolyte in the sample station, in g; 10 6 Indicates the coefficient for conversion to μg / g.
[0082] In the above embodiment, the electrolyte capacity in the sample station can be controlled by the second on-off control component 420, that is, the electrolyte capacity in the sample station 1210A is fixed, that is, m is a constant. On this basis, the potentiometric titrator 1220 can control the reagent capacity added in the reagent addition pipeline 1220A. When the potentiometric titrator 1220 automatically determines that the reaction has reached the end point, it controls the reagent to stop adding. When the reagent stops adding, the potentiometric titrator 1220 can automatically obtain the liquid level difference before and after the reagent is added to the reagent addition pipeline, and then obtain the capacity difference before and after the reagent is added in the reagent addition pipeline 1220A, and obtain VV 0 , and then the hydrofluoric acid content can be calculated by the above formula.
[0083] In the above implementation mode, the present scheme controls the electrolyte to enter the area to be detected (injection station) through the second on-off control component 420, and then rotates the electrolyte in the injection station into the titration area in sequence through the injection turntable, and the reagent addition pipeline automatically adds quantitative reagent, and the reaction end point is automatically determined by the potentiometric titrator, and then the hydrofluoric acid content can be calculated according to the capacity difference before and after the reagent is added in the reagent addition pipeline, thereby realizing the automated testing and content calculation process of hydrofluoric acid.
[0084] In an optional implementation of the present embodiment, the sampling turntable 1210 can also be connected to the clean water pipe 80 and the waste liquid discharge pipe 91 described above. In this way, after all sample stations 1210A of the sampling turntable 1210 have completed the hydrofluoric acid test, the sampling turntable 1210 can discharge the waste liquid of all sample stations 1210A through the waste liquid discharge pipe 91, and introduce clean water through the clean water pipe 80 to clean the sample station 1210A, thereby avoiding the influence of the residual liquid from the previous test on the next test, thereby improving the accuracy of electrolyte detection.
[0085] The present application also provides an electrolyte detection system, such as Fig.12 As shown, the system includes an electrolyte detection device 1 and a control device 2 of any optional embodiment described above, and the control device 2 is electrically connected to the on-off control component 40 to control the opening and closing of the on-off control component 40.
[0086] The electrolyte detection system designed as above, this scheme connects the electrolyte storage device to the moisture detection device and the hydrofluoric acid content detection device through pipelines, and then controls the transmission and quantitative control of the electrolyte through the on-off control component, thereby realizing automatic detection of the electrolyte, thereby reducing the workload and detection time of the electrolyte detection, improving the convenience of the electrolyte detection, and avoiding errors caused by manual detection and interference from the sampling and delivery environment.
[0087] In an optional implementation of this embodiment, in the case of having a clean water control valve 90 and a waste liquid control valve 92, the control device 2 designed in this solution also communicates with the clean water control valve 90 and the waste liquid control valve 92 respectively, so as to control the waste liquid in the moisture detection device 110 and / or the hydrofluoric acid content detection device 120 to be discharged, and control the clean water to clean the moisture detection device 110 and / or the hydrofluoric acid content detection device 120. Among them, the specific process of waste liquid discharge control and the specific process of clean water control have been described above and will not be repeated here.
[0088] In an optional implementation manner of the present embodiment, a reagent control valve 1130 is provided in the reagent pipeline port 1110B of the moisture detection device, and a liquid level monitoring device is provided in the reagent storage tank 1120. The control device 2 designed in the present scheme can communicate with the reagent control valve 1130, the liquid level monitoring device and the potentiometric titrator 1220 respectively, so that the reagent addition of the moisture detection device 110 can be controlled by controlling the reagent control valve 1130, the reagent capacity in the reagent storage tank of the moisture detection device 110 can be monitored by receiving the monitoring data of the liquid level monitoring device, and the liquid level difference before and after the reagent is added to the reagent addition pipeline obtained by receiving the potentiometric titrator 1220 can be used to calculate the hydrofluoric acid content.
[0089] In an optional implementation of this embodiment, if Fig.13 As shown, the control device 2 designed in this solution can also be electrically connected to the display screen 3, and the control device 2 can display the calculated moisture content and hydrofluoric acid content on the display screen 3.
[0090] The present application also provides an electrolyte detection control method, which can be applied to the control device described above. The method can be implemented in the following manner: Fig.14 As shown, including: Step S1400: Control the on-off control component to open according to the electrolyte detection request, and control the on-off control component to close after a preset time period, so as to control the electrolyte of a preset capacity in the electrolyte storage device to be transmitted to the moisture detection device and the hydrofluoric acid content detection device respectively through the electrolyte pipeline.
[0091] Step S1410: Control the moisture detection device to perform moisture detection on the received electrolyte to obtain a moisture detection result.
[0092] Step S1420: controlling the hydrofluoric acid content detection device to detect the hydrofluoric acid content of the received electrolyte to obtain a hydrofluoric acid content detection result.
[0093] In the above embodiment, the electrolyte detection request may be obtained by a staff sending an electrolyte detection request to the control device. For example, the staff may operate a terminal device to send an electrolyte detection request to the control device.
[0094] As for step S1410, it is described above that the control device designed in the present scheme can perform quantitative control on the addition of the moisture detection reagent of the moisture detection device. For example, the control device can communicate with the reagent control valve, and realize the quantitative addition of the moisture detection reagent by controlling the opening time of the reagent control valve. In this case, the present scheme can control the opening of the reagent control valve to transmit a fixed volume of moisture detection reagent to the moisture detection device, so that the moisture detection reagent reacts with the electrolyte entering the moisture detection device, so that the amount of electricity generated by the electrolysis of the moisture detection device is proportional to the moisture content, and the moisture content can be calculated through the linear relationship between the amount of electricity and the moisture content.
[0095] As for step S1420, it is described above that the potentiometric titrator can quantitatively control the reagent addition of the hydrofluoric acid content detection device. In this case, the control device can communicate with the potentiometric titrator. When the potentiometric titrator automatically determines that the reaction has reached the endpoint, the liquid level difference before and after the reagent is added to the reagent adding pipeline detected by the potentiometric titrator is obtained, and then the volume difference before and after the reagent is added in the reagent adding pipeline can be obtained, and VV can be obtained. 0 , and then the hydrofluoric acid content can be calculated using the hydrofluoric acid content calculation formula described above.
[0096] The electrolyte detection control method designed above connects the electrolyte storage device to the moisture detection device and the hydrofluoric acid content detection device through pipelines, and then controls the transmission and quantitative control of the electrolyte through the on-off control component, thereby realizing automatic detection of the electrolyte, thereby reducing the workload and detection time of the electrolyte detection, improving the convenience of the electrolyte detection, and avoiding errors caused by manual detection and interference from the sampling and delivery environment.
[0097] In an optional implementation manner of the present embodiment, in the case of having a clean water control valve and a waste liquid control valve, the control device designed in the present scheme also communicates with the clean water control valve and the waste liquid control valve respectively. Based on this, the present scheme can detect whether the moisture detection device and / or the hydrofluoric acid content detection device has completed the current detection; if the moisture detection device and / or the hydrofluoric acid content detection device has completed the current detection, the clean water control valve is controlled to open to control the clean water in the clean water storage tank to clean the moisture detection device and / or the hydrofluoric acid content detection device, and the waste liquid control valve is controlled to open to control the waste liquid in the moisture detection device and the hydrofluoric acid content detection device to be discharged.
[0098] Among them, the completion of the current detection by the moisture detection device can be that the moisture detection reagent and the electrolyte in the reaction cell fully complete the reaction. The characterization of the fully completed reaction can be determined by collecting the number of times the moisture detection reagent is added, that is, the capacity of the electrolyte added in the moisture detection device is fixed, and the capacity of the moisture detection reagent required for the fixed capacity of the electrolyte to complete the full reaction is also fixed. In this regard, this scheme can add enough moisture detection reagent at one time, or it can be added in multiple times. The number of additions in this scheme can be set in advance. After adding the electrolyte once, this scheme can determine the number of additions of the moisture detection reagent. If the number of additions set in advance is reached, it indicates that the reaction is fully completed, and the above-mentioned waste liquid discharge and cleaning control can be performed.
[0099] The hydrofluoric acid content detection device can complete the current detection by completing the titration and detection of the potentiometric titrator at the last sampling station of the liquid inlet turntable. In this scheme, the above-mentioned waste liquid discharge and cleaning control can be performed.
[0100] According to some embodiments of the present application, Fig.15 As shown, the present application provides an electronic device 15, including: a processor 1501 and a memory 1502, the processor 1501 and the memory 1502 are interconnected and communicate with each other through a communication bus 1503 and / or other forms of connection mechanisms (not shown), the memory 1502 stores a computer program executable by the processor 1501, and when the computing device is running, the processor 1501 executes the computer program to execute a method of any optional implementation method, such as step S1400 and step S1420: according to the electrolyte detection request, the on-off control component is controlled to be turned on, and after a preset time period, the on-off control component is controlled to be turned off, so as to control the electrolyte of a preset capacity in the electrolyte storage device to be transmitted to the moisture detection device and the hydrofluoric acid content detection device respectively through the electrolyte pipeline; the moisture detection device is controlled to perform moisture detection on the received electrolyte to obtain a moisture detection result; the hydrofluoric acid content detection device is controlled to perform hydrofluoric acid content detection on the received electrolyte to obtain a hydrofluoric acid content detection result.
[0101] The present application provides a computer-readable storage medium, on which a computer program is stored. When the computer program is executed by a processor, the method in any of the aforementioned optional implementations is executed.
[0102] Among them, the storage medium can be implemented by any type of volatile or non-volatile storage device or a combination thereof, such as static random access memory (SRAM), electrically erasable programmable read-only memory (EEPROM), erasable programmable read-only memory (EPROM), programmable red-only memory (PROM), read-only memory (ROM), magnetic storage, flash memory, magnetic disk or optical disk.
[0103] The present application provides a computer program product. When the computer program product is run on a computer, the computer is enabled to execute the method in any optional implementation manner.
[0104] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present application, rather than to limit them; although the present application has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or replace some or all of the technical features therein by equivalents; and these modifications or replacements do not make the essence of the corresponding technical solutions deviate from the scope of the technical solutions of the embodiments of the present application, and they should all be included in the scope of the claims and specification of the present application. In particular, as long as there is no structural conflict, the various technical features mentioned in the various embodiments can be combined in any way. The present application is not limited to the specific embodiments disclosed herein, but includes all technical solutions that fall within the scope of the claims.
Claims
1. An electrolyte detection device, It is characterized in that The electrolyte detection equipment includes a multifunctional testing device; The multifunctional testing device comprises a moisture detection device and a hydrofluoric acid content detection device; The moisture detection device and the hydrofluoric acid content detection device are connected to the electrolyte storage device through an electrolyte pipeline, and an on-off control component is provided on the electrolyte pipeline; The on-off control component is used to control the electrolyte in the electrolyte storage device to be transmitted to the moisture detection device and the hydrofluoric acid content detection device through the electrolyte pipeline respectively; The moisture detection device is used to detect the moisture of the received electrolyte to obtain a moisture detection result; The hydrofluoric acid content detection device is used to detect the hydrofluoric acid content of the received electrolyte to obtain the hydrofluoric acid content detection result.
2. The electrolyte detection device according to claim 1, It is characterized in that The electrolyte storage device includes an electrolyte storage tank and a liquid injection machine; the electrolyte pipeline includes a first pipeline and a second pipeline; The electrolyte storage tank is connected to the moisture detection device and the hydrofluoric acid content detection device through a first pipeline, and the liquid injection machine is connected to the moisture detection device and the hydrofluoric acid content detection device through a second pipeline; The on-off control component includes a first on-off control component and a second on-off control component; the first on-off control component is arranged on the first pipeline, and the second on-off control component is arranged on the second pipeline.
3. The electrolyte detection device according to claim 2, It is characterized in that The first pipeline includes a first branch pipeline and a second branch pipeline; the top of the electrolyte storage tank is connected to the moisture detection device and the hydrofluoric acid content detection device respectively through the first branch pipeline; The bottom of the electrolyte storage tank is connected to the moisture detection device and the hydrofluoric acid content detection device respectively through the second branch pipeline.
4. The electrolyte detection device according to claim 2, It is characterized in that The second pipeline includes a workstation transmission pipeline and a third branch pipeline; The first end of the station transmission pipeline is connected to the liquid injection station of the liquid injection machine, and the second end of the station transmission pipeline is connected to the moisture detection device and the hydrofluoric acid content detection device respectively through the third branch pipeline.
5. The electrolyte detection device according to claim 4, It is characterized in that The liquid injection machine comprises a plurality of liquid injection stations, the number of the station transmission pipelines is the same as the number of the liquid injection stations, and each liquid injection station is connected to a station transmission pipeline.
6. The electrolyte detection device according to claim 1, It is characterized in that The electrolyte detection equipment also includes a clean water storage tank, a clean water pipeline and a clean water control valve; The clean water control valve is arranged in the clean water pipeline, and the clean water storage tank is connected to the moisture detection device and the hydrofluoric acid content detection device respectively through the clean water pipeline; The clean water control valve is used to control the clean water in the clean water storage tank to enter the moisture detection device and the hydrofluoric acid content detection device to clean the moisture detection device and the hydrofluoric acid content detection device.
7. The electrolyte detection device according to claim 1, It is characterized in that The electrolyte detection device also includes a waste liquid discharge pipeline and a waste liquid control valve, wherein the waste liquid control valve is arranged in the waste liquid discharge pipeline, and the waste liquid discharge pipeline is connected to the moisture detection device and the hydrofluoric acid content detection device respectively; The waste liquid control valve is used to control the discharge of waste liquid in the moisture detection device and the hydrofluoric acid content detection device.
8. The electrolyte detection device according to claim 1, It is characterized in that The moisture detection device comprises a reaction cell; the reaction cell comprises an anode, a cathode, an electrode, a built-in reaction space, a reagent pipeline and a reagent storage tank; The cathode and the electrode are arranged in the built-in reaction space, the reaction pool is provided with a liquid inlet and a reagent pipeline port, the liquid inlet is connected to the electrolyte pipeline, one end of the reagent pipeline is connected to the reagent storage tank, and the other end of the reagent pipeline is connected to the reagent pipeline port, and a reagent control valve is arranged in the reagent pipeline; The on-off control component is used to control the electrolyte of the first target volume in the electrolyte pipeline to be transmitted to the built-in reaction space of the reaction cell; The reagent control valve is used to control the second target volume of the moisture detection reagent in the reagent storage tank to be transmitted to the built-in reaction space of the reaction cell, so that the moisture detection reagent reacts with the electrolyte to achieve moisture measurement.
9. The electrolyte detection device according to claim 1, It is characterized in that The hydrofluoric acid content detection device comprises a sample injection turntable and a potentiometric titrator; the sample injection turntable is provided with a plurality of sample stations, and each sample station sequentially enters the titration area of the potentiometric titrator when the sample injection turntable rotates; The potentiometric titrator is provided with a reagent adding pipeline, and the potentiometric titrator is used to titrate the hydrofluoric acid content detection reagent in the reagent adding pipeline into the sample station entering the titration area; The electrolyte pipeline is connected to the sample injection turntable to sequentially transfer the electrolyte to each sample station of the sample injection turntable.
10. An electrolyte detection system, It is characterized in that The electrolyte detection system comprises the electrolyte detection equipment and a control device according to any one of claims 1 to 9, wherein the control device is electrically connected to an on-off control component to control the opening and closing of the on-off control component.
11. An electrolyte detection and control method, It is characterized in that The electrolyte detection control method is applied to the control device according to claim 10, and the method comprises: Controlling the on-off control component to turn on according to an electrolyte detection request, and controlling the on-off control component to turn off after a preset time period, so as to control the electrolyte of a preset capacity in the electrolyte storage device to be transmitted to the moisture detection device and the hydrofluoric acid content detection device through the electrolyte pipeline respectively; Controlling the moisture detection device to perform moisture detection on the received electrolyte to obtain a moisture detection result; The hydrofluoric acid content detection device is controlled to detect the hydrofluoric acid content of the received electrolyte to obtain a hydrofluoric acid content detection result.
12. The method according to claim 11, It is characterized in that in, The electrolyte detection device further comprises a clean water storage tank, a clean water pipeline and a clean water control valve, wherein the clean water control valve is arranged in the clean water pipeline, and the clean water storage tank is connected to the moisture detection device and the hydrofluoric acid content detection device respectively through the clean water pipeline; The method further comprises: Check whether the moisture detection device and / or the hydrofluoric acid content detection device has completed the current detection; If the moisture detection device and / or the hydrofluoric acid content detection device completes the current detection, the clean water control valve is controlled to open to control the clean water in the clean water storage tank to clean the moisture detection device and / or the hydrofluoric acid content detection device.
13. The method according to claim 11, It is characterized in that The electrolyte detection device also includes a waste liquid discharge pipeline and a waste liquid control valve, wherein the waste liquid control valve is arranged in the waste liquid discharge pipeline, and the waste liquid discharge pipeline is connected to the moisture detection device and the hydrofluoric acid content detection device respectively; The method further comprises: Check whether the moisture detection device and / or the hydrofluoric acid content detection device has completed the current detection; If the moisture detection device and / or the hydrofluoric acid content detection device completes the current detection, the waste liquid control valve is controlled to open to control the waste liquid in the moisture detection device and the hydrofluoric acid content detection device to be discharged.
14. An electronic device comprising a memory and a processor, wherein the memory stores a computer program, It is characterized in that When the processor executes the computer program, the method according to any one of claims 11 to 13 is implemented.
15. A computer-readable storage medium having a computer program stored thereon, It is characterized in that When the computer program is executed by a processor, the method according to any one of claims 11 to 13 is implemented.
Citation Information
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