Over-temperature detection method, device and equipment for reaction container and storage medium

Abstract

The invention provides an overtemperature detection method, device and equipment for a reaction container and a storage medium, and belongs to the technical field of chemical safety, and the method comprises the steps: obtaining the temperature-time relation, the temperature rise rate-temperature relation and the initial heat release temperature of a material when the material is subjected to an adiabatic test; carrying out correction treatment to obtain a real temperature rise rate change curve along with time under the heat insulation condition of the material; determining a heat release rate corresponding to the abnormal working condition initial temperature material; determining a heat transfer rate corresponding to the abnormal working condition initial temperature material; determining the temperature rise of the material in the retention time of the abnormal working condition, and determining the final temperature of the reaction container according to the temperature rise of the material in the retention time of the abnormal working condition; and when the final temperature of the reaction container is detected to be higher than the pre-stored design temperature, generating a first overtemperature detection result indicating that the reaction container has an overtemperature hidden danger. According to the invention, the preciseness of the detection process and the expected production process can be considered under severe working conditions, and the first overtemperature detection result is obtained.

Description

Technical Field

[0001] The present application relates to the field of chemical safety technology, and in particular to an over-temperature detection method, device, equipment and storage medium for a reaction container. Background Art

[0002] Under abnormal operating conditions of chemical plants, once secondary reactions of materials occur and the reaction vessel overheats, it may lead to serious problems such as material reaction rate and product quality, or even rupture and leakage of the reaction vessel. Therefore, it is necessary to evaluate the thermal risks in the reaction vessel during the production process to determine whether the reaction vessel has a safety hazard of overheating under this operating condition.

[0003] In the prior art, whether the material will undergo secondary reactions and cause the reaction vessel to overheat is an important part of HAZOP analysis (Hazard and Operability Analysis). In order to make the test results safer, the heat release characteristic parameters of the material under severe working conditions such as cooling failure are usually used to represent the thermal stability of the material.

[0004] However, the inventors have found that under some working conditions, such as too high starting temperature, too fast raw material feeding, non-adiabatic working conditions, over-temperature detection of the reaction vessel may lead to the problem of sacrificing the production process due to the overly rigorous detection process. Summary of the invention

[0005] The present application provides an over-temperature detection method, device, equipment and storage medium for a reaction container, which can take into account the rigor of the detection process and the expected production process under harsh working conditions, and obtain a detection result of whether the reaction container has an over-temperature hazard.

[0006] In a first aspect, the present application provides an over-temperature detection method for a reaction container, which is applied to a server, and the method comprises:

[0007] Obtain initial temperature data and material residence time under various abnormal working conditions corresponding to the reaction vessel;

[0008] When the material is subjected to adiabatic testing, the relationship between the material's temperature and time, the relationship between the temperature rise rate and the temperature, and the starting exothermic temperature are obtained;

[0009] According to the relationship between temperature and time, according to the starting exothermic temperature, and the preset basic test parameters, correction processing is performed to obtain a true temperature rise rate versus time curve of the material under adiabatic conditions;

[0010] According to the preset test basic parameters and the actual temperature rise rate over time curve of the material under the adiabatic condition, determine the heat release rate corresponding to the material at the initial temperature of the abnormal working condition;

[0011] According to the preset test basic parameters and the actual temperature rise rate over time curve of the material under the adiabatic condition, the heat transfer rate corresponding to the material at the initial temperature of the abnormal working condition is determined;

[0012] When it is detected that the heat transfer rate is less than or equal to the heat release rate, the temperature rise of the material during the residence time of the abnormal working condition is determined according to the heat release rate and the heat transfer rate, the preset basic test parameters and the temperature and time relationship of the material when the material is subjected to an adiabatic test, and the final temperature of the reaction container is determined according to the temperature rise of the material during the residence time of the abnormal working condition;

[0013] When it is detected that the final temperature of the reaction container is higher than the pre-stored design temperature, a first over-temperature detection result is generated indicating that the reaction container has a potential over-temperature risk.

[0014] In a possible implementation, the preset test basic parameters include the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, the mass of the material, the quasi-rate constant, the initial concentration of the reactant, the pre-exponential factor, the pre-stored reaction order and the gas constant;

[0015] Accordingly, the correction process is performed according to the relationship between temperature and time, the starting exothermic temperature, and the preset basic test parameters to obtain the actual temperature rise rate versus time curve of the material under adiabatic conditions, including:

[0016] Determine the thermal inertia factor according to the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, and the mass of the material in the preset basic test parameters;

[0017] Determine the activation energy according to the quasi-rate constant, the initial concentration of the reactant, the pre-exponential factor, the pre-existing reaction order, the gas constant and the temperature-time relationship in the preset test basic parameters;

[0018] According to the relationship between temperature and time, determine the temperature rise rate during the test;

[0019] Determine the corrected starting exothermic temperature, the temperature rise rate and the temperature data during the exothermic process according to the gas constant, the starting exothermic temperature, the temperature rise rate, the activation energy and the thermal inertia factor in the preset test basic parameters;

[0020] According to the corrected initial exothermic temperature, temperature rise rate and temperature data during the exothermic process, the actual temperature rise rate versus time curve of the material under adiabatic conditions is determined.

[0021] In a possible implementation, the inertia factor is determined according to the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, and the mass of the material in the preset test basic parameters, and the calculation formula is:

[0022]

[0023] In the formula, C p,b is the specific heat capacity of the reaction vessel, m b is the mass of the reaction vessel, C p,s is the specific heat capacity of the material, m s The quality of the material;

[0024] The activation energy is determined according to the quasi-rate constant, the initial concentration of the reactant, the pre-exponential factor, the pre-existing reaction order, the gas constant and the relationship between the temperature and time in the preset test basic parameters. The calculation formula is:

[0025]

[0026] In the formula, k * is the quasi-rate constant, C0 is the initial concentration of the reactant, A is the pre-exponential factor, E is the activation energy, n is the reaction order, R is the gas constant, and T is the temperature value determined according to the relationship between temperature and time;

[0027] The calculation formula for determining the corrected starting exothermic temperature, the temperature rise rate and the temperature data during the exothermic process according to the gas constant, the starting exothermic temperature, the temperature rise rate, the activation energy and the thermal inertia factor in the preset basic parameters is:

[0028]

[0029] Where T0 is the starting exothermic temperature, T' 0,ad is the corrected onset exothermic temperature, is the thermal inertia factor, is the corrected temperature rise rate, T′ ad is the corrected temperature of the entire exothermic process, is the temperature rise rate, E is the activation energy, R is the gas constant, and T is the temperature value determined according to the relationship between temperature and time.

[0030] In a possible implementation, the calculation formula for determining the heat release rate corresponding to the material at the initial temperature of the abnormal working condition according to the preset test basic parameters and the actual temperature rise rate versus time curve of the material under the adiabatic condition is:

[0031]

[0032] In the formula, q rx is the heat release rate of the material at the initial temperature, m is the mass of the material in the reaction vessel, C p is the specific heat capacity of the material, is the temperature rise rate corresponding to the initial temperature.

[0033] In a possible implementation, the preset test basic parameters also include the preset material reaction temperature of the abnormal working condition, the preset cooling medium temperature, the heat transfer coefficient and the heat transfer area; accordingly, the calculation formula for determining the heat transfer rate corresponding to the material at the initial temperature of the abnormal working condition according to the preset test basic parameters and the actual temperature rise rate versus time curve of the material under the adiabatic condition is:

[0034] q ex =US(T A -T0)

[0035] In the formula, q ex is the heat transfer rate of the material at the initial temperature, U is the heat transfer coefficient, S is the heat transfer area, T A is the preset material reaction temperature under abnormal working conditions, and T0 is the preset cooling medium temperature.

[0036] In a possible implementation, the temperature rise of the material during the residence time of the abnormal working condition is determined by the calculation formula according to the heat release rate and the heat transfer rate, the preset basic test parameters and the temperature and time relationship of the material obtained when the material is subjected to an adiabatic test:

[0037]

[0038] In the formula, C p is the specific heat capacity of the material, m is the mass of the material in the reaction vessel, T' ad is the corrected temperature of the entire exothermic process, T′ 0,ad is the corrected starting exothermic temperature, T and t can be respectively determined based on the temperature and time relationship of the material obtained when the material is subjected to an adiabatic test, the temperature and time relationship is plotted, and the temperature rise during the residence time is read from the graph to calculate the final temperature of the reaction vessel;

[0039] The calculation formula for determining the final temperature of the reaction vessel according to the temperature rise of the material during the residence time of the abnormal working condition is:

[0040] T A,f =T A,0 +ΔT

[0041] Where, T A,f is the final temperature of the reaction vessel under abnormal conditions, T A,0 is the initial temperature of the reaction vessel under abnormal conditions, and ΔT is the temperature rise of the material during the residence time of the reaction vessel under abnormal conditions.

[0042] In a possible implementation, the method further includes: when it is detected that the heat transfer rate is greater than or equal to the heat release rate, generating a second over-temperature detection result indicating that the reaction container is safe.

[0043] In a second aspect, the present application provides an over-temperature detection device for a reaction container, which is applied to a server, and the device comprises:

[0044] An acquisition module is used to obtain initial temperature data and material residence time under various abnormal working conditions corresponding to the reaction container;

[0045] The acquisition module is also used to obtain the relationship between the temperature and time, the relationship between the temperature rise rate and the temperature, and the starting heat release temperature of the material when the material is subjected to the adiabatic test;

[0046] A correction module, used to perform correction processing according to the relationship between temperature and time, the starting heat release temperature, and preset basic test parameters to obtain a true temperature rise rate versus time curve of the material under adiabatic conditions;

[0047] An over-temperature detection module is used to determine the heat release rate corresponding to the initial temperature of the material under abnormal working conditions according to the preset test basic parameters and the actual temperature rise rate over time curve of the material under adiabatic conditions;

[0048] The over-temperature detection module is also used to determine the heat transfer rate corresponding to the initial temperature of the material under abnormal working conditions according to the preset test basic parameters and the actual temperature rise rate over time curve of the material under the adiabatic condition;

[0049] The over-temperature detection module is further used to determine the temperature rise of the material during the residence time of the abnormal working condition according to the heat release rate and the heat transfer rate, the preset test basic parameters and the relationship between the temperature and time of the material when performing an adiabatic test on the material when detecting that the heat transfer rate is less than or equal to the heat release rate, and determine the final temperature of the reaction container according to the temperature rise of the material during the residence time of the abnormal working condition;

[0050] The over-temperature detection module is further used to generate a first over-temperature detection result indicating that the reaction container has an over-temperature risk when it is detected that the final temperature of the reaction container is higher than the pre-stored design temperature.

[0051] In a third aspect, the present application provides a server, comprising: at least one processor and a memory;

[0052] The memory stores computer-executable instructions;

[0053] The at least one processor executes the computer-executable instructions stored in the memory, so that the at least one processor executes the over-temperature detection method for a reaction container as described in the first aspect above.

[0054] In a fourth aspect, the present application provides a computer-readable storage medium, wherein the computer-readable storage medium stores a computer-executed instruction. When a processor executes the computer-executed instruction, the over-temperature detection method for a reaction container as described in the first aspect above is implemented.

[0055] The present application provides an over-temperature detection method, device, equipment and storage medium for a reaction vessel. The method first obtains the initial temperature data and material residence time under various abnormal working conditions corresponding to the reaction vessel, and then obtains the temperature and time relationship, the temperature rise rate and temperature relationship and the initial heat release temperature of the material when the material is subjected to an adiabatic test. Then, a correction process is performed to obtain the true temperature rise rate over time curve of the material under adiabatic conditions, and then determine the heat release rate corresponding to the initial temperature material of the abnormal working condition. Then determine the heat transfer rate corresponding to the initial temperature material of the abnormal working condition to achieve the purpose of obtaining the corresponding test data under non-adiabatic working conditions. Then, when it is detected that the heat transfer rate is less than or equal to the heat release rate, the temperature and time relationship of the material is obtained according to the heat release rate and the heat transfer rate, the preset basic test parameters and the adiabatic test of the material, and the temperature rise of the material during the residence time of the abnormal working condition is determined, and then the final temperature of the reaction vessel is determined. When it is detected that the final temperature of the reaction vessel is higher than the pre-stored design temperature, the first over-temperature detection result indicating that the reaction vessel has an over-temperature hazard is generated. Therefore, the present application can not only ensure the severity of over-temperature detection without sacrificing the process, but also quickly check whether the reaction container has over-temperature risks under adiabatic conditions, and can also check whether the reaction container has over-temperature risks under non-adiabatic conditions. BRIEF DESCRIPTION OF THE DRAWINGS

[0056] In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, a brief introduction will be given below to the drawings required for use in the embodiments or the description of the prior art. Obviously, the drawings described below are some embodiments of the present application. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying any creative labor.

[0057] Figure 1 A schematic diagram of an application scenario of an over-temperature detection method for a reaction container provided in an embodiment of the present application;

[0058] Figure 2 A schematic flow chart of an over-temperature detection method for a reaction container provided in an embodiment of the present application;

[0059] Figure 3 A schematic diagram of the relationship between temperature and time of a material provided in an embodiment of the present application;

[0060] Figure 4 A schematic diagram of the relationship between the temperature rise rate and the temperature provided in the embodiment of the present application;

[0061] Figure 5 A schematic diagram of the relationship between the corrected temperature rise rate and temperature provided in an embodiment of the present application;

[0062] Figure 6 A schematic diagram of the structure of an over-temperature detection device for a reaction container provided in an embodiment of the present application;

[0063] Figure 7 A schematic diagram of the hardware structure of an electronic device provided in an embodiment of the present application. DETAILED DESCRIPTION

[0064] In order to make the purpose, technical solution and advantages of the embodiments of the present application clearer, the technical solution in the embodiments of the present application will be clearly and completely described below in conjunction with the drawings in the embodiments of the present application. Obviously, the described embodiments are part of the embodiments of the present application, not all of the embodiments. Based on the embodiments in the present application, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of this application.

[0065] At present, the inventors have found that under some special working conditions, such as too high starting temperature, too fast raw material feeding or non-adiabatic working conditions, if only focusing on the heat release characteristics of the material and ignoring the heat transfer capacity of the reaction vessel, it will not meet the HAZOP analysis principle on the one hand, and on the other hand may lead to too harsh detection process and sacrifice the feasibility of the process. Therefore, how to provide an over-temperature detection method for a reaction vessel has become a technical problem to be solved urgently.

[0066] In order to solve the above technical problems, the embodiments of the present application provide the following technical concepts for solving the problems: first, sort out the possible abnormal working conditions of the reaction container, then perform an adiabatic test on the material in the reaction container, use the heat release characteristic parameters of the material to correct the temperature rise rate of the material, obtain the relationship between the actual temperature rise rate of the material under adiabatic conditions and time, and then calculate the heat release rate and heat transfer rate corresponding to the initial temperature of the material under abnormal working conditions. Then, the temperature rise of the material and the temperature of the reaction container during the residence time of the abnormal working condition are calculated by the heat release rate and the heat transfer rate, and the detection result of whether the reaction container has the hidden danger of overheating is obtained based on the temperature of the reaction container and the pre-designed design temperature.

[0067] Figure 1 A schematic diagram of an application scenario of an over-temperature detection method for a reaction container provided in an embodiment of the present application, such as Figure 1 As shown, it includes: a terminal 101 and a server 102.

[0068] The terminal 101 is used for the test personnel to view the test results, the data changes during the over-temperature detection process, and to issue control instructions. The server 102 is used to receive the parameter or temperature data transmitted from the cloud, other servers or mobile terminals, perform the detection operation, generate the over-temperature detection results and send them to the terminal 101.

[0069] Figure 2 The flowchart of the over-temperature detection method for a reaction container provided in the embodiment of the present application is shown in FIG. Figure 1 The server 102 in the illustrated embodiment may also be other computer-related devices, and there is no particular limitation on this embodiment.

[0070] like Figure 2 As shown, the over-temperature detection method for a reaction container comprises:

[0071] S201: Obtaining initial temperature data and material residence time under various abnormal working conditions corresponding to the reaction container.

[0072] In this embodiment, the reaction vessel can be a container device such as a reactor, a reaction pot, a decomposition pot or a polymerization kettle that provides a physical or chemical reaction space for the material. The initial temperature data under various abnormal working conditions corresponding to the reaction vessel can be determined according to the process characteristics and deviations when the reaction vessel is working, and the initial temperature data under different working conditions are different. For example: 1. The normal preheating temperature of the reaction raw material before the reaction is 50°C. When the preheater fails and the heating power is increased, the preheating temperature can reach 60°C to enter the reactor. At this time, the initial temperature of the abnormal working condition is 60°C; 2. Normal operation is 50°C, the reaction is exothermic, if the heat transfer of the reactor is interrupted, the initial temperature will increase to (normal operating temperature + adiabatic temperature rise of the reaction), and this corresponds to the adiabatic working condition; 3. The operating temperature is 50°C. Under the abnormal working condition of stopping stirring, the initial temperature will not increase and is still 50°C. At this time, the heat transfer capacity of the reaction vessel is normal, corresponding to the non-adiabatic working condition. The material residence time refers to the residence time of the material under abnormal working conditions. Step S201 can be obtained by sorting out data such as relevant parameters of the reaction container when it leaves the factory, which are pre-uploaded and stored from the cloud and the manufacturer's server. These data list as many abnormal operating conditions that the container may encounter and the corresponding design parameters under each abnormal operating condition as possible.

[0073] S202: When the material is subjected to an adiabatic test, the relationship between the temperature and time, the relationship between the temperature rise rate and the temperature, and the starting heat release temperature of the material are obtained.

[0074] In this embodiment, the adiabatic test refers to a test performed on the reaction vessel under adiabatic conditions, which is intended to detect the performance of the reaction vessel when it is isolated from external heat exchange. The temperature-time relationship of the material refers to the relationship between the temperature change over time during the adiabatic test. The temperature rise rate-temperature relationship refers to the relationship between the temperature rise rate and the temperature change. The starting exothermic temperature refers to the temperature corresponding to the starting time point of the exothermic section actually measured during the adiabatic test.

[0075] In this embodiment, when the material is subjected to an adiabatic test, the relationship between the temperature and time of the material, the relationship between the temperature rise rate and the temperature, and the initial exothermic temperature can be acquired through an adiabatic calorimeter, and the test steps of the adiabatic calorimeter are as follows: 1.559g of reaction liquid is weighed as material in a reaction vessel made of high-pressure stainless steel, the "heating-waiting-searching" mode is selected, the temperature step is set to 5°C, the detection sensitivity is 0.02°C / min, the temperature range of the test is 25-190°C, and the mass of the reaction vessel is 11.142g. Then an adiabatic test is performed, and the required data is collected in real time from the start of the test as the initial time, and returned to the execution subject of the method for subsequent steps of over-temperature detection.

[0076] S203: Correction processing is performed according to the relationship between temperature and time, the initial heat release temperature, and the preset basic test parameters to obtain a true temperature rise rate versus time curve of the material under adiabatic conditions.

[0077] In this embodiment, the correction process refers to the process of correcting the temperature rise rate of the heat release section in the adiabatic test of the material by using the relationship between temperature and time, the starting heat release temperature and the preset basic parameters. The preset test basic parameters can be obtained from the data in the operation manual or product manual of the reaction vessel and the initial data set during the actual adiabatic test: for example, the preset test basic parameters can include the maximum operating temperature of the reaction vessel, the type of cooling medium used, the specific heat capacity of the reaction vessel and the mass of the reaction vessel.

[0078] Specifically, the preset test basic parameters include the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, the mass of the material, the quasi-rate constant, the initial concentration of the reactant, the pre-exponential factor, the pre-stored reaction order and the gas constant; accordingly, in an optional embodiment of the present application, step S203 includes the following steps:

[0079] S203a: Determine the inertia factor according to the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, and the mass of the material in the preset basic test parameters.

[0080] In an optional embodiment of the present application, the calculation formula for determining the inertia factor in step S203a is:

[0081]

[0082] In the formula, C p,b is the specific heat capacity of the reaction vessel, m b is the mass of the reaction vessel, C p,s is the specific heat capacity of the material, m s The quality of the material.

[0083] S203b: Determine the activation energy based on the quasi-rate constant, initial concentration of reactants, pre-exponential factor, pre-existing reaction order, gas constant and temperature-time relationship in the preset test basic parameters.

[0084] In an optional embodiment of the present application, the calculation formula for determining the activation energy in step S203b is:

[0085]

[0086] In the formula, k * is the quasi-rate constant, C0 is the initial concentration of the reactant, A is the pre-exponential factor, E is the activation energy, n is the reaction order, R is the gas constant, and T is the temperature value determined according to the relationship between temperature and time.

[0087] In this embodiment, the test curve during the adiabatic test is pre-selected to make lnk * The relationship with (1 / T) is linear. If the appropriate reaction order n is selected, the slope of the test curve is the activation energy E.

[0088] S203c: Determine the temperature rise rate during the test based on the relationship between temperature and time.

[0089] In this embodiment, by plotting the relationship between temperature and time and calculating the corresponding slope of the temperature and time curve in the graph, the temperature rise rate during the test can be obtained to represent the value of the temperature rise per unit time during the adiabatic test.

[0090] S203d: Determine the corrected starting exothermic temperature, temperature rise rate and temperature data during the exothermic process according to the gas constant, starting exothermic temperature, temperature rise rate, activation energy and thermal inertia factor in the preset test basic parameters.

[0091] In an optional embodiment of the present application, the calculation formula for determining the corrected starting heat release temperature, temperature rise rate and temperature data during the heat release process in step S203d is:

[0092]

[0093] Where T0 is the starting exothermic temperature, T0′ ,ad is the corrected onset exothermic temperature, is the thermal inertia factor, is the corrected temperature rise rate, T a ' d is the corrected temperature of the entire exothermic process, is the temperature rise rate, E is the activation energy, R is the gas constant, and T is the temperature value determined according to the relationship between temperature and time.

[0094] In this embodiment, the temperature rise rate It refers to the temperature rise rate of the material (sample) and the reaction container system containing the test object during the actual test.

[0095] S203e: Based on the corrected initial exothermic temperature, temperature rise rate and temperature data during the exothermic process, determine the actual temperature rise rate versus time curve of the material under adiabatic conditions.

[0096] In this embodiment, when the material is subjected to an adiabatic test under adiabatic conditions, a curve of the temperature rise rate versus time can be drawn by using the relevant data obtained in steps S203a to S203d.

[0097] S204: Determine the heat release rate corresponding to the material at the initial temperature of the abnormal working condition according to the preset test basic parameters and the actual temperature rise rate versus time curve under the material adiabatic condition.

[0098] In an optional embodiment of the present application, the calculation formula for determining the heat release rate corresponding to the material at the initial temperature of the abnormal operating condition in step S204 is:

[0099]

[0100] In the formula, q rx is the heat release rate of the material at the initial temperature, m is the mass of the material in the reaction vessel, C p is the specific heat capacity of the material, is the temperature rise rate corresponding to the initial temperature.

[0101] From the calculation formula of step S204, it can be seen that:

[0102] S205: Determine the heat transfer rate corresponding to the material at the initial temperature of the abnormal working condition according to the preset test basic parameters and the actual temperature rise rate versus time curve under the material adiabatic condition.

[0103] Based on the above embodiment, in an optional embodiment of the present application, the preset test basic parameters also include the preset material reaction temperature of the abnormal working condition, the preset cooling medium temperature, the heat transfer coefficient and the heat transfer area; accordingly, the calculation formula for determining the heat transfer rate corresponding to the material at the initial temperature of the abnormal working condition in step S205 is:

[0104] q ex =US(T A -T0)

[0105] In the formula, q ex is the heat transfer rate of the material at the initial temperature, U is the heat transfer coefficient, S is the heat transfer area, T A is the preset material reaction temperature under abnormal working conditions, and T0 is the preset cooling medium temperature.

[0106] In this embodiment, the preset material reaction temperature of abnormal working conditions can be the original parameter of the reaction vessel when it is produced and shipped, which refers to the standard temperature of the material reaction in the reaction vessel under abnormal working conditions. The preset cooling medium temperature refers to the temperature of the cooling medium required to be used determined according to the different operating conditions of the reaction vessel, the properties of the reacted materials and the temperature control requirements to be achieved. For example: when the internal temperature of the reaction vessel is lower than 60°C, cooling water can be used as the cooling medium, and the preset cooling medium temperature at this time can be 55°C.

[0107] In this embodiment, it can be seen from step S204 and step S205 that these abnormal operating conditions have heat transfer rate and heat release rate corresponding to the material, which means that the over-temperature detection method for the reaction container provided in the embodiment of the present application can be used to detect whether the reaction container is over-temperature under non-adiabatic conditions.

[0108] S206: When it is detected that the heat transfer rate is less than or equal to the heat release rate, the temperature rise of the material during the residence time of the abnormal operating condition is determined according to the heat release rate and the heat transfer rate, the preset basic test parameters and the temperature and time relationship of the material when the material is subjected to an adiabatic test, and the final temperature of the reaction vessel is determined according to the temperature rise of the material during the residence time of the abnormal operating condition.

[0109] In an optional embodiment of the present application, in step S206, according to the heat release rate and heat transfer rate, the preset basic test parameters and the temperature and time relationship of the material obtained when the material is subjected to an adiabatic test, the calculation formula for determining the temperature rise of the material during the residence time of the abnormal working condition is:

[0110]

[0111] In the formula, C p is the specific heat capacity of the material, m is the mass of the material in the reaction vessel, T a ' d is the corrected temperature of the entire exothermic process, T0′ ,ad is the corrected starting exothermic temperature, T and t can be respectively determined based on the temperature and time relationship of the material obtained during the adiabatic test of the material. The temperature and time relationship is plotted, and the temperature rise during the residence time is read from the graph to calculate the final temperature of the reaction vessel.

[0112] In an optional embodiment of the present application, in step S206, the final temperature of the reaction container is determined according to the temperature rise of the material during the residence time of the abnormal operating condition, and the calculation formula is:

[0113] T A,f =T A,0 +ΔT

[0114] Where, T A,f is the final temperature of the reaction vessel under abnormal conditions, T A,0 is the initial temperature of the reaction vessel under abnormal conditions, and ΔT is the temperature rise of the material during the residence time of the reaction vessel under abnormal conditions.

[0115] S207: When it is detected that the final temperature of the reaction container is higher than the pre-stored design temperature, a first over-temperature detection result is generated, indicating that the reaction container has a potential over-temperature risk.

[0116] In this embodiment, the pre-stored design temperature refers to the temperature value pre-specified when the reaction container leaves the factory. The temperature value may be the highest operating temperature that the reaction container can withstand. For example, the pre-stored design temperature of a glass distillation flask is 200°C.

[0117] In this embodiment, the generated first over-temperature detection result may be feedback information such as text description, voice, numerical value or chart that can indicate that the reaction container has a potential over-temperature risk.

[0118] In an optional embodiment of the present application, the over-temperature detection method for a reaction container further includes:

[0119] Step A: When it is detected that the heat removal rate is greater than or equal to the heat release rate, a second over-temperature detection result indicating that the reaction container is safe is generated.

[0120] In this embodiment, the generated second over-temperature detection result may be feedback information in the form of text description, voice, numerical value or chart, etc., which can indicate that the reaction container has no risk of over-temperature.

[0121] In order to facilitate the understanding of the content of the above method embodiment, the present application embodiment also provides an example of using the over-temperature detection method for a reaction container provided in the above embodiment to perform over-temperature detection, as follows:

[0122] Assume that the volume of a reaction vessel is 500L, the pre-stored design temperature is 150℃, the operating temperature is 35℃, the heat is transferred by external circulation, the mass of the material is 1.559g, and the mass of the reaction vessel is 11.142g. Under the condition that the catalyst feed rate of the reaction vessel is too fast, the main reaction is accelerated and the temperature rises to 110℃. At this time, it is necessary to evaluate whether the reaction vessel is overheated during the reaction process.

[0123] Figure 3 This is a schematic diagram of the relationship between temperature and time of the material provided in the embodiments of the present application.

[0124] Figure 4 A schematic diagram of the relationship between the temperature rise rate and temperature provided in an embodiment of the present application.

[0125] Figure 5 A schematic diagram of the relationship between the corrected temperature rise rate and temperature provided in an embodiment of the present application.

[0126] In this example, the temperature and time relationship, temperature rise rate and temperature relationship, and starting exothermic temperature of the material obtained by the adiabatic test are as follows: for example, the starting temperature of the material is 105°C, and the adiabatic temperature rise is 150°C. The data obtained by the adiabatic test can be automatically drawn into a corresponding test curve using drawing software in the server 102, such as Figure 3 and Figure 4 As shown, the starting temperature is 105°C. At this time, according to:

[0127]

[0128] It can be calculated is 2.5. According to:

[0129]

[0130] The fitting results show that n is 1.16 and E is 115080 J / mol.

[0131]

[0132] The relationship between the corrected temperature rise rate and temperature is shown in Figure 3 , the temperature rise rate at 110℃ is 0.1K / min. The specific heat capacity of the material is 22kJ / (kg·K), the mass of the reaction liquid in the reaction container is 2t, according to

[0133]

[0134] The heat release rate of the reaction liquid is 800w. According to the inventor's practice, the heat transfer capacity of the reactor is 2000w. The heat transfer power of the reaction container at 110°C is greater than the heat release power. The secondary reaction of the material will not cause the temperature of the reaction container to continue to rise. Therefore, the first over-temperature detection result that will not cause the reaction container to overheat is generated for the inspector to review.

[0135] In summary, the over-temperature detection method for a reaction vessel provided in the embodiment of the present application first obtains the initial temperature data and the material residence time under various abnormal working conditions corresponding to the reaction vessel, and then obtains the temperature and time relationship, the temperature rise rate and temperature relationship, and the initial heat release temperature of the material when the material is subjected to an adiabatic test. Then, a correction process is performed to obtain the true temperature rise rate over time curve of the material under adiabatic conditions, and then determine the heat release rate corresponding to the initial temperature material of the abnormal working condition. Then determine the heat transfer rate corresponding to the initial temperature material of the abnormal working condition to achieve the purpose of obtaining the corresponding test data under non-adiabatic working conditions. Then, when it is detected that the heat transfer rate is less than or equal to the heat release rate, the temperature and time relationship of the material is obtained according to the heat release rate and the heat transfer rate, the preset basic test parameters, and the adiabatic test of the material, and the temperature rise of the material during the residence time of the abnormal working condition is determined, and then the final temperature of the reaction vessel is determined. When it is detected that the final temperature of the reaction vessel is higher than the pre-stored design temperature, the first over-temperature detection result indicating that the reaction vessel has an over-temperature hazard is generated. Therefore, the present application can not only ensure the severity of over-temperature detection without sacrificing the process, but also quickly check whether the reaction container has over-temperature risks under adiabatic conditions, and can also check whether the reaction container has over-temperature risks under non-adiabatic conditions.

[0136] Figure 6 This is a structural schematic diagram of an over-temperature detection device for a reaction container provided in an embodiment of the present application. The over-temperature detection device for a reaction container is applied to a server, and the device includes: an acquisition module 61, a correction module 62 and an over-temperature detection module 63.

[0137] The acquisition module 61 is used to obtain initial temperature data and material residence time under various abnormal working conditions corresponding to the reaction container.

[0138] The acquisition module 61 is also used to obtain the relationship between the temperature and time, the relationship between the temperature rise rate and the temperature, and the starting heat release temperature of the material when the material is subjected to the adiabatic test.

[0139] The correction module 62 is used to perform correction processing according to the relationship between temperature and time, the starting heat release temperature, and the preset basic test parameters to obtain the actual temperature rise rate change curve of the material under adiabatic conditions.

[0140] The over-temperature detection module 63 is used to determine the heat release rate corresponding to the initial temperature of the material under abnormal working conditions according to the preset test basic parameters and the actual temperature rise rate over time curve under the material adiabatic condition.

[0141] The over-temperature detection module 63 is also used to determine the heat transfer rate corresponding to the initial temperature of the material under abnormal working conditions according to the preset test basic parameters and the actual temperature rise rate over time curve under the material adiabatic condition.

[0142] The over-temperature detection module 63 is also used to determine the temperature rise of the material during the residence time of the abnormal operating condition based on the heat release rate and the heat transfer rate, the preset basic test parameters and the adiabatic test of the material when it is detected that the heat transfer rate is less than or equal to the heat release rate, and determine the final temperature of the reaction vessel based on the temperature rise of the material during the residence time of the abnormal operating condition.

[0143] The over-temperature detection module 63 is further used to generate a first over-temperature detection result indicating that the reaction container has an over-temperature risk when it is detected that the final temperature of the reaction container is higher than the pre-stored design temperature.

[0144] In an optional embodiment of the present application, the preset test basic parameters include the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, the mass of the material, the quasi-rate constant, the initial concentration of the reactants, the pre-exponential factor, the pre-stored reaction order and the gas constant; accordingly, the correction module 62 is specifically used to: determine the thermal inertia factor according to the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, and the mass of the material in the preset test basic parameters; determine the activation energy according to the quasi-rate constant, the initial concentration of the reactants, the pre-exponential factor, the pre-stored reaction order, the gas constant and the temperature-time relationship in the preset test basic parameters; determine the temperature rise rate during the test according to the temperature-time relationship; determine the corrected starting exothermic temperature, the temperature rise rate and the temperature data during the exothermic process according to the gas constant, the starting exothermic temperature, the temperature rise rate, the activation energy and the thermal inertia factor in the preset basic parameters; determine the actual temperature rise rate over time curve of the material under adiabatic conditions according to the corrected starting exothermic temperature, the temperature rise rate and the temperature data during the exothermic process.

[0145] In an optional embodiment of the present application, the correction module 62 is specifically used to determine the calculation formula of the inertia factor according to the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, and the mass of the material in the preset test basic parameters:

[0146]

[0147] In the formula, C p,b is the specific heat capacity of the reaction vessel, m b is the mass of the reaction vessel, C p,s is the specific heat capacity of the material, m s The quality of the material;

[0148] According to the preset test basic parameters, including the quasi-rate constant, the initial concentration of the reactant, the pre-exponential factor, the pre-existing reaction order, the gas constant and the relationship between temperature and time, the calculation formula for activation energy is determined as follows:

[0149]

[0150] In the formula, k * is the quasi-rate constant, C0 is the initial concentration of the reactant, A is the pre-exponential factor, E is the activation energy, n is the reaction order, R is the gas constant, and T is the temperature value determined according to the relationship between temperature and time;

[0151] According to the gas constant, initial exothermic temperature, temperature rise rate, activation energy and thermal inertia factor in the preset test basic parameters, the calculation formula for determining the corrected initial exothermic temperature, temperature rise rate and temperature data during the exothermic process is:

[0152]

[0153] Where T0 is the starting exothermic temperature, T' 0,ad is the corrected onset exothermic temperature, is the thermal inertia factor, is the corrected temperature rise rate; T′ ad is the corrected temperature of the entire exothermic process, is the temperature rise rate, E is the activation energy, R is the gas constant, and T is the temperature value determined according to the relationship between temperature and time.

[0154] In an optional embodiment of the present application, the over-temperature detection module 63 is specifically used to determine the heat release rate corresponding to the initial temperature material of the abnormal working condition according to the preset test basic parameters and the actual temperature rise rate over time curve under the material adiabatic condition. The calculation formula is:

[0155]

[0156] In the formula, q rx is the heat release rate of the material at the initial temperature, m is the mass of the material in the reaction vessel, C p is the specific heat capacity of the material, is the temperature rise rate corresponding to the initial temperature.

[0157] In an optional embodiment of the present application, the preset test basic parameters also include the preset material reaction temperature of the abnormal working condition, the preset cooling medium temperature, the heat transfer coefficient and the heat transfer area; accordingly, the over-temperature detection module 63 is specifically used to determine the calculation formula of the heat transfer rate corresponding to the material at the initial temperature of the abnormal working condition according to the preset test basic parameters and the actual temperature rise rate over time curve of the material under the adiabatic condition:

[0158] q ex =US(T A -T0)

[0159] In the formula, q ex is the heat transfer rate of the material at the initial temperature, U is the heat transfer coefficient, S is the heat transfer area, T Ais the preset material reaction temperature under abnormal working conditions, and T0 is the preset cooling medium temperature.

[0160] In an optional embodiment of the present application, the overtemperature detection module 63 is specifically used to obtain the temperature and time relationship of the material during the adiabatic test of the material according to the heat release rate and the heat transfer rate, the preset basic test parameters and the calculation formula for determining the temperature rise of the material during the residence time of the abnormal working condition:

[0161]

[0162] In the formula, C p is the specific heat capacity of the material, m is the mass of the material in the reaction vessel, T' ad is the corrected temperature of the entire exothermic process, T′ 0,ad is the corrected starting exothermic temperature, T and t can be respectively determined based on the temperature and time relationship of the material obtained when the material is subjected to an adiabatic test, the temperature and time relationship is plotted, and the temperature rise during the residence time is read from the graph to calculate the final temperature of the reaction vessel;

[0163] According to the temperature rise of the material during the residence time of abnormal working conditions, the final temperature of the reaction vessel is determined by the calculation formula:

[0164] T A,f =T A,0 +ΔT

[0165] Where, T A,f is the final temperature of the reaction vessel under abnormal conditions, T A,0 is the initial temperature of the reaction vessel under abnormal conditions, and ΔT is the temperature rise of the material during the residence time of the reaction vessel under abnormal conditions.

[0166] In an optional embodiment of the present application, the over-temperature detection module 63 is further used to: when it is detected that the heat transfer rate is greater than or equal to the heat release rate, generate a second over-temperature detection result indicating that the reaction container is safe.

[0167] The over-temperature detection device for a reaction container provided in this embodiment can be used to implement the technical solution of the above-mentioned method embodiment. Its implementation principle and technical effect are similar, and this embodiment will not be repeated here.

[0168] Figure 7 A schematic diagram of the hardware structure of an electronic device provided in an embodiment of the present application is shown in FIG. Figure 7 As shown, the electronic device includes: at least one processor 701 and a memory 702.

[0169] The memory 702 is used to store computer-executable instructions.

[0170] The processor 701 is used to execute the computer-executable instructions stored in the memory 702 to implement the various steps involved in the above method embodiment. For details, please refer to the relevant description in the above method embodiment.

[0171] Optionally, the memory 702 may be independent or integrated with the processor 701 .

[0172] When the memory 702 is independently provided, the electronic device further includes a bus 703 for connecting the memory 702 and the processor 701 .

[0173] An embodiment of the present application also provides a computer-readable storage medium, in which computer-executable instructions are stored. When a processor executes the computer-executable instructions, the above-mentioned over-temperature detection method for a reaction container is implemented.

[0174] An embodiment of the present application also provides a computer program product, including a computer program, which, when executed by a processor, implements the above-mentioned over-temperature detection method for a reaction container.

[0175] In the several embodiments provided in the present application, it should be understood that the disclosed devices and methods can be implemented in other ways. For example, the device embodiments described above are only schematic. For example, the division of the above modules is only a logical function division. There may be other division methods in actual implementation, such as multiple modules can be combined or integrated into another system, or some features can be ignored or not executed. Another point is that the mutual coupling or direct coupling or communication connection shown or discussed can be through some interfaces, indirect coupling or communication connection of devices or modules, which can be electrical, mechanical or other forms.

[0176] The modules described above as separate components may or may not be physically separated, and the components shown as modules may or may not be physical units, that is, they may be located in one place or distributed on multiple network units. Some or all of the modules may be selected according to actual needs to implement the solution of this embodiment.

[0177] In addition, each functional module in each embodiment of the present invention may be integrated into one processing unit, each module may exist physically separately, or two or more modules may be integrated into one unit. The unit composed of the above modules may be implemented in the form of hardware or in the form of hardware plus software functional units.

[0178] The above-mentioned integrated module implemented in the form of a software function module can be stored in a computer-readable storage medium. The above-mentioned software function module is stored in a storage medium, including a number of instructions for causing a computer device (which can be a personal computer, a server, or a network device, etc.) or a processor to perform some steps of the method of each embodiment of the present application.

[0179] It should be understood that the processor may be a central processing unit (CPU), or other general-purpose processors, digital signal processors (DSP), application-specific integrated circuits (ASIC), etc. A general-purpose processor may be a microprocessor or any conventional processor. The steps of the method disclosed in the invention may be directly implemented as being executed by a hardware processor, or may be implemented by a combination of hardware and software modules in the processor.

[0180] The memory may include a high-speed RAM memory, and may also include a non-volatile storage NVM, such as at least one disk memory, and may also be a USB flash drive, a mobile hard disk, a read-only memory, a magnetic disk or an optical disk, etc.

[0181] The bus may be an Industry Standard Architecture (ISA) bus, a Peripheral Component Interconnect (PCI) bus, or an Extended Industry Standard Architecture (EISA) bus, etc. The bus may be divided into an address bus, a data bus, a control bus, etc. For ease of representation, the bus in the drawings of the present application is not limited to only one bus or one type of bus.

[0182] The above storage medium can be implemented by any type of volatile or non-volatile storage device or a combination thereof, such as static random access memory (SRAM), electrically erasable programmable read-only memory (EEPROM), erasable programmable read-only memory (EPROM), programmable read-only memory (PROM), read-only memory (ROM), magnetic memory, flash memory, magnetic disk or optical disk. The storage medium can be any available medium that can be accessed by a general or special purpose computer.

[0183] An exemplary storage medium is coupled to a processor so that the processor can read information from the storage medium and write information to the storage medium. Of course, the storage medium can also be a component of the processor. The processor and the storage medium can be located in an application specific integrated circuit (ASIC). Of course, the processor and the storage medium can also exist as discrete components in an electronic device or a main control device.

[0184] Those skilled in the art can understand that all or part of the steps of implementing the above-mentioned method embodiments can be completed by hardware related to program instructions. The aforementioned program can be stored in a computer-readable storage medium. When the program is executed, the steps of the above-mentioned method embodiments are executed; and the aforementioned storage medium includes: ROM, RAM, disk or optical disk and other media that can store program codes.

[0185] The present invention is intended to illustrate the technical solution of the present application rather than to limit it. Although the present application has been described in detail with reference to the aforementioned embodiments, a person skilled in the art should understand that the technical solutions described in the aforementioned embodiments may still be modified, or some or all of the technical features may be replaced by equivalents. However, these modifications or replacements do not deviate the essence of the corresponding technical solution from the scope of the technical solutions of the embodiments of the present application.

Claims

1. A method for detecting overtemperature of a reaction vessel, characterized in that: Applied to a server, the method comprises: Obtain initial temperature data and material residence time under various abnormal working conditions corresponding to the reaction vessel; When the material is subjected to adiabatic testing, the relationship between the material's temperature and time, the relationship between the temperature rise rate and the temperature, and the starting exothermic temperature are obtained; According to the relationship between temperature and time, according to the starting exothermic temperature, and the preset basic test parameters, correction processing is performed to obtain a true temperature rise rate versus time curve of the material under adiabatic conditions; According to the preset test basic parameters and the actual temperature rise rate over time curve of the material under the adiabatic condition, determine the heat release rate corresponding to the material at the initial temperature of the abnormal working condition; According to the preset test basic parameters and the actual temperature rise rate over time curve of the material under the adiabatic condition, the heat transfer rate corresponding to the material at the initial temperature of the abnormal working condition is determined; When it is detected that the heat transfer rate is less than or equal to the heat release rate, the temperature rise of the material during the residence time of the abnormal working condition is determined according to the heat release rate and the heat transfer rate, the preset basic test parameters and the temperature and time relationship of the material when the material is subjected to an adiabatic test, and the final temperature of the reaction container is determined according to the temperature rise of the material during the residence time of the abnormal working condition; When it is detected that the final temperature of the reaction container is higher than the pre-stored design temperature, a first over-temperature detection result is generated indicating that the reaction container has a potential over-temperature risk.

2. The method according to claim 1, characterized in that The preset test basic parameters include the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, the mass of the material, the quasi-rate constant, the initial concentration of the reactant, the pre-exponential factor, the pre-stored reaction order and the gas constant; Accordingly, the correction process is performed according to the relationship between temperature and time, the starting exothermic temperature, and the preset basic test parameters to obtain the actual temperature rise rate versus time curve of the material under adiabatic conditions, including: Determine the thermal inertia factor according to the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, and the mass of the material in the preset basic test parameters; Determine the activation energy according to the quasi-rate constant, the initial concentration of the reactant, the pre-exponential factor, the pre-existing reaction order, the gas constant and the temperature-time relationship in the preset test basic parameters; According to the relationship between temperature and time, determine the temperature rise rate during the test; Determine the corrected starting exothermic temperature, the temperature rise rate and the temperature data during the exothermic process according to the gas constant, the starting exothermic temperature, the temperature rise rate, the activation energy and the thermal inertia factor in the preset test basic parameters; According to the corrected initial exothermic temperature, temperature rise rate and temperature data during the exothermic process, the actual temperature rise rate versus time curve of the material under adiabatic conditions is determined.

3. The method according to claim 2, characterized in that The calculation formula for determining the inertia factor according to the specific heat capacity of the reaction container, the mass of the reaction container, the specific heat capacity of the material, and the mass of the material in the preset test basic parameters is: In the formula, C p,b is the specific heat capacity of the reaction vessel, m b is the mass of the reaction vessel, C p,s is the specific heat capacity of the material, m s The quality of the material; The calculation formula for determining the activation energy according to the preset test basic parameters, the quasi-rate constant, the initial concentration of the reactant, the pre-exponential factor, the pre-existing reaction order, the gas constant and the temperature-time relationship is: In the formula, k * is the quasi-rate constant, C0 is the initial concentration of the reactant, A is the pre-exponential factor, E is the activation energy, n is the reaction order, R is the gas constant, and T is the temperature value determined according to the relationship between temperature and time; The calculation formula for determining the corrected starting exothermic temperature, the temperature rise rate and the temperature data during the exothermic process according to the gas constant, the starting exothermic temperature, the temperature rise rate, the activation energy and the thermal inertia factor in the preset test basic parameters is: Where T0 is the starting exothermic temperature, T' 0,ad is the corrected onset exothermic temperature, is the thermal inertia factor, is the corrected temperature rise rate, T′ ad is the corrected temperature of the entire exothermic process, is the temperature rise rate, E is the activation energy, R is the gas constant, and T is the temperature value determined according to the relationship between temperature and time.

4. The method according to claim 3, characterized in that The calculation formula for determining the heat release rate corresponding to the material at the initial temperature of the abnormal working condition according to the preset test basic parameters and the actual temperature rise rate versus time curve of the material under the adiabatic condition is: In the formula, q rx is the heat release rate of the material at the initial temperature, m is the mass of the material in the reaction vessel, C p is the specific heat capacity of the material, is the temperature rise rate corresponding to the initial temperature.

5. The method according to claim 4, characterized in that The preset test basic parameters also include the preset material reaction temperature of abnormal working conditions, the preset cooling medium temperature, the heat transfer coefficient and the heat transfer area; Accordingly, according to the preset test basic parameters and the actual temperature rise rate versus time curve of the material under the adiabatic condition, the calculation formula for determining the heat transfer rate corresponding to the material at the initial temperature of the abnormal working condition is: q ex =US(T A -T0) In the formula, q ex is the heat transfer rate of the material at the initial temperature, U is the heat transfer coefficient, S is the heat transfer area, T A is the preset material reaction temperature under abnormal working conditions, and T0 is the preset cooling medium temperature.

6. The method according to claim 1, characterized in that According to the heat release rate and heat transfer rate, the preset basic test parameters and the temperature and time relationship of the material obtained during the adiabatic test of the material, the calculation formula for determining the temperature rise of the material during the residence time of the abnormal working condition is: In the formula, C p is the specific heat capacity of the material, m is the mass of the material in the reaction vessel, T' ad is the corrected temperature of the entire exothermic process, T′ 0,ad is the corrected starting exothermic temperature, T and t can be respectively determined based on the temperature and time relationship of the material obtained when the material is subjected to an adiabatic test, the temperature and time relationship is plotted, and the temperature rise during the residence time is read from the graph to calculate the final temperature of the reaction vessel; The calculation formula for determining the final temperature of the reaction vessel according to the temperature rise of the material during the residence time of the abnormal working condition is: T A,f =T A,0 +ΔT Where, T A,f is the final temperature of the reaction vessel under abnormal conditions, T A,0 is the initial temperature of the reaction vessel under abnormal conditions, and ΔT is the temperature rise of the material during the residence time of the reaction vessel under abnormal conditions.

7. The method according to any one of claims 1 to 6, characterized in that Also includes: When it is detected that the heat removal rate is greater than or equal to the heat release rate, a second over-temperature detection result indicating that the reaction container is safe is generated.

8. An over-temperature detection device for a reaction vessel, characterized in that: Applied to a server, the device comprises: An acquisition module is used to obtain initial temperature data and material residence time under various abnormal working conditions corresponding to the reaction container; The acquisition module is also used to obtain the relationship between the temperature and time, the relationship between the temperature rise rate and the temperature, and the starting heat release temperature of the material when the material is subjected to the adiabatic test; A correction module, used to perform correction processing according to the relationship between temperature and time, the starting heat release temperature, and preset basic test parameters to obtain a true temperature rise rate versus time curve of the material under adiabatic conditions; An over-temperature detection module is used to determine the heat release rate corresponding to the initial temperature of the material under abnormal working conditions according to the preset test basic parameters and the actual temperature rise rate over time curve of the material under adiabatic conditions; The over-temperature detection module is also used to determine the heat transfer rate corresponding to the initial temperature of the material under abnormal working conditions according to the preset test basic parameters and the actual temperature rise rate over time curve of the material under the adiabatic condition; The over-temperature detection module is further used to determine the temperature rise of the material during the residence time of the abnormal working condition according to the heat release rate and the heat transfer rate, the preset test basic parameters and the relationship between the temperature and time of the material when performing an adiabatic test on the material when detecting that the heat transfer rate is less than or equal to the heat release rate, and determine the final temperature of the reaction container according to the temperature rise of the material during the residence time of the abnormal working condition; The over-temperature detection module is further used to generate a first over-temperature detection result indicating that the reaction container has an over-temperature risk when it is detected that the final temperature of the reaction container is higher than the pre-stored design temperature.

9. An electronic device, characterized in that: include: at least one processor and memory; The memory stores computer-executable instructions; The at least one processor executes the computer-executable instructions stored in the memory, so that the at least one processor performs the over-temperature detection method for a reaction container according to any one of claims 1 to 7.

10. A computer-readable storage medium, characterized in that: The computer-readable storage medium stores computer-executable instructions. When the processor executes the computer-executable instructions, the over-temperature detection method for a reaction container as described in any one of claims 1 to 7 is implemented.

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