High-concentration industrial wastewater treatment equipment and process based on ozone-photocatalysis

Abstract

The ozone-photocatalysis-based high-concentration industrial wastewater treatment equipment comprises a main tank body, and the main tank body comprises a base, a tank body, an upper cover, a gas inlet, a gas outlet, a liquid inlet, a liquid outlet, an observation opening, a cleaning opening, a sewage collection area, a reaction area and a gas return area; the tank body is fixedly arranged on the base, the upper cover is fixedly arranged on the tank body, an air inlet and an air outlet are formed in the upper cover, a liquid inlet is formed in the bottom of the tank body, a liquid outlet, an observation opening and a cleaning opening are formed in the side face of the tank body, and the cleaning opening is close to the bottom of the tank body. The liquid outlet and the observation opening are close to the top of the tank body; the interior of the tank body is divided into a sewage collection area, a reaction area and a gas return area from bottom to top; the device can effectively improve the ozone utilization rate, reduce the ozone production energy consumption cost, reduce the tail gas recovery treatment cost, conveniently treat adhesive substances in the wastewater treatment equipment, conveniently replace the catalyst and improve the overall automation degree of the wastewater treatment equipment.

Description

Technical Field

[0001] The invention relates to the technical field of industrial wastewater treatment, in particular to a high-concentration industrial wastewater treatment device and process based on ozone-photocatalysis. Background Art

[0002] High-concentration wastewater mainly comes from a variety of industrial processes, including papermaking, leather, food, pharmaceuticals, pesticide production, etc. These industries produce a large amount of organic matter, phenolic substances, alcoholic substances, sugars, oils and fats during the production process, which are the main sources.

[0003] High-concentration wastewater has unstable water quality and complex components, including organic matter, heavy metals, etc. The pH, salt content, and heavy metal content vary greatly, making it difficult to treat. It is highly toxic and contains harmful substances such as cyanide and phenol, which can cause teratogenic or lethal effects on microorganisms. High-concentration wastewater has a wide range of sources and obvious characteristics, making it more complicated to treat. In practical applications, it is necessary to select a suitable treatment plan based on factors such as the nature of the wastewater, treatment requirements, and economic conditions to achieve the desired purification effect.

[0004] In the treatment of high-concentration industrial wastewater, high-efficiency ozone catalyst technology is a daily method. Through enrichment-catalytic activation-oxidative degradation, the degradation reaction speed and efficiency of residual organic matter in wastewater are greatly improved. The strong oxidizing properties of ozone are combined with the enrichment and catalytic activity characteristics of catalysts to more effectively solve a series of problems such as low ozone treatment efficiency, low ozone utilization rate, and high operating costs. Among them, ozone oxidation technology can improve ozone utilization rate by adding ozone catalysts, and at the same time increase COD removal rate to 30-50%. The advantages of ozone catalysts for industrial wastewater treatment are: High efficiency: The ozone catalytic efficiency is more than 4 times higher than that without catalysts. Subversive: Long life, can maintain activity for a long time, and can be restored to activity by rinsing. High utilization rate: Ozone is fully utilized with little residue. Economical: Save land and no secondary pollution.

[0005] Through ozone catalytic oxidation technology, ammonia nitrogen in wastewater can be converted into harmless substances, reducing the negative impact of wastewater on the environment and ecosystem. The principle of ozone catalytic oxidation technology to treat industrial park wastewater is to use ozone to undergo an oxidation reaction in wastewater to degrade organic matter into harmless water and carbon dioxide. In actual operation, steps such as oxygen supply, ozone generation, oxidation reaction, and gas-liquid separation are required. First, sufficient oxygen is supplied to the reactor through an oxygen supply system. Then, an ozone generator is used to generate ozone gas. Next, ozone gas is injected into high-ammonia nitrogen wastewater and an oxidation reaction is carried out in the reactor. Finally, the gas and liquid in the wastewater are separated by a gas-liquid separation device to obtain treated clean water.

[0006] Photocatalyst, also known as photocatalyst, is a general term for semiconductor materials with photocatalytic function, represented by titanium dioxide (TiO2). Photocatalyst technology does not consume earth energy or use harmful chemicals, but only uses the light energy of sunlight to remove and purify environmental pollutants at low concentrations. It can also be used as an antibacterial agent and mildewproof agent. Therefore, it is an environmental purification technology with broad application prospects. In addition to the functions of antibacterial, deodorizing and anti-fouling, photocatalysts can also be applied to the field of water purification. The titanium dioxide photocatalyst technology is used to degrade organic pollutants in water, especially when the concentration of organic pollutants in water is very high or difficult to treat by other methods. The purification effect of photocatalyst is very obvious.

[0007] For example, application number 202221931393.4 discloses a high-concentration industrial wastewater treatment equipment, including a shell, a feed box, an installation box, a bracket, a connecting block, a filter box and a control panel, wherein the feed box is fixedly connected to the top left side of the shell, the installation box is fixedly connected to the top middle of the feed box, the bracket is fixedly connected to the top right side of the shell, the connecting block is located on the upper side of the bracket, the filter box is fixedly connected to the top right side of the bracket, and the control panel is fixedly connected to the upper side of the right side wall of the shell. The high-concentration industrial wastewater treatment equipment has a reasonable structural design, which prevents blockage of the connecting pipes inside the equipment, ensures the normal use of the high-concentration industrial wastewater treatment equipment, realizes the removal of impurities such as metals in the wastewater, and improves the effect of the high-concentration industrial wastewater treatment equipment in actual use.

[0008] However, the current high-concentration wastewater treatment equipment has a low ozone utilization rate, the energy consumption cost of ozone production is high, the cost of recycling and treating underutilized ozone tail gas is high, the adhesives in the wastewater treatment equipment are not easy to remove, the catalyst is not easy to replace, and the overall automation level is not high. Summary of the invention

[0009] The technical problem to be solved by the present invention is to improve the utilization rate of ozone, reduce the energy consumption cost of ozone production, make full use of ozone, reduce the cost of tail gas recovery and treatment, conveniently handle the adhesion in the wastewater treatment equipment, conveniently replace the catalyst, and improve the overall automation level of the wastewater treatment equipment.

[0010] In order to solve the above technical problems, the present invention provides a high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis, including a main tank body, the main tank body including a base, a tank body, an upper cover, an air inlet, an air outlet, a liquid inlet, a liquid outlet, an observation port, a cleaning port, a sewage collection area, a reaction area, and a gas return area; the tank body is fixedly arranged on the base, the upper cover is fixedly arranged on the tank body, the upper cover is provided with an air inlet and an air outlet, the bottom of the tank body is provided with a liquid inlet, the side of the tank body is provided with a liquid outlet, an observation port, and a cleaning port, the cleaning port is close to the bottom of the tank body, and the liquid outlet and the observation port are close to the top of the tank body; the interior of the tank body is divided into a sewage collection area, a reaction area, and a gas return area from bottom to top;

[0011] A permeable membrane ozone mechanism for ozone-catalyzing wastewater is fixedly arranged in the main tank;

[0012] A catalytic reaction mechanism for photocatalytic wastewater is fixedly arranged in the main tank.

[0013] Preferably, the permeable membrane ozone mechanism comprises a supporting base, a supporting frame, a first air inlet pipe, an air pipe tee, a second air inlet pipe, a third air inlet pipe, a main air inlet, a main air pipe, a branch air inlet pipe, a breathable membrane, a lifting arm, and an ozone generator; the supporting base is fixedly arranged inside the tank body, the supporting frame is fixedly arranged on the supporting base, one side of the first air inlet pipe is connected to the ozone generator, and the other side is fixedly connected to the second air inlet pipe through the air pipe tee, and the other end of the second air inlet pipe is connected to the ozone generator through the air pipe tee. A third air inlet pipe is fixedly connected, and the third air inlet pipe is connected to the main air inlet after passing through the air inlet. The main air pipes are provided with multiple groups, and the main air inlet is fixedly connected to one group of the main air pipes. Multiple groups of air inlet pipes are fixedly provided on each group of the main air pipes, and each group of the sub-air inlet pipes is fixedly connected to a group of air permeable membranes. Multiple groups of the air permeable membranes are fixedly connected side by side through the support frame; two groups of lifting arms are fixedly provided on both sides of the upper part of the support frame for lifting the permeable ozone mechanism, and an ozone generator is fixedly provided on one side of the main tank body;

[0014] Preferably, the breathable membrane is a waterproof breathable membrane, so that gas can be smoothly passed through the breathable membrane, and when there is no ventilation, wastewater cannot penetrate into the breathable membrane;

[0015] Preferably, the permeable ozone mechanism further includes a first air outlet pipe, a second air outlet pipe, an air pipe solenoid valve, and a concentration monitor; one end of the first air outlet pipe is connected to the air outlet, and the other end is fixedly connected to the second air inlet pipe through the air pipe tee; one end of the second air outlet pipe is fixedly connected to the second air inlet pipe through the air pipe tee, and the other end is connected to the ozone tail gas treatment device; the second air inlet pipe, the first air outlet pipe, and the second air outlet pipe are respectively provided with air pipe solenoid valves, and the concentration monitor is fixedly arranged on the upper cover, and its detection contact penetrates into the return air zone inside the tank body at the lower end of the upper cover;

[0016] Preferably, the catalytic reaction mechanism comprises a porous horn support platform, a porous cylinder, sieve holes, and a support column; a porous horn support platform is fixedly provided on the upper side of the dirt collection area inside the tank body, the cleaning port is provided on the upper side of the porous horn support platform, a porous cylinder is provided downwardly at the center position of the porous horn support platform, the bottom of the porous cylinder is fixedly provided at the bottom of the tank body, and the liquid inlet is provided at the center position of the porous cylinder; the bottom of the porous horn support platform is fixedly connected by multiple groups of support columns, and the bottoms of multiple groups of support columns are fixedly connected to the bottom of the tank body;

[0017] Preferably, the porous speaker support platform and the porous cylinder are provided with multiple groups of sieve holes, and the diameter of the sieve holes is smaller than the diameter of the photocatalyst ball;

[0018] Preferably, the catalytic reaction mechanism further comprises a guide hole, an impact boss, an impact mandrel, and an impact cylinder; a guide hole is opened on the upper side of the inner part of the support column, an impact boss is fixedly arranged in the guide hole, one end of the impact boss is fixedly connected to the porous horn support platform, the mandrel is movably arranged inside the support column and moves linearly along its axial direction, the impact cylinder is fixedly arranged at the bottom of the support column, and its shaft end is fixedly connected to the impact mandrel;

[0019] Preferably, the ozone-photocatalytic high-concentration industrial wastewater treatment equipment also includes a multi-stage illumination mechanism, which includes a light belt groove, an upper mirror surface, an inner mirror surface, a lower mirror surface, and a light belt; the light belt groove is provided with multiple groups, fixedly arranged on the inner wall of the reaction zone of the tank body, and evenly arranged along the axial direction of the tank body, one side of the light belt groove is attached to the inner wall of the tank body, and the other three sides are respectively fixedly provided with an upper mirror surface, an inner mirror surface, and a lower mirror surface, and together with them form a cavity, and a light belt is arranged in the cavity;

[0020] Preferably, the ozone-photocatalytic high-concentration industrial wastewater treatment equipment also includes a monitoring and control mechanism, which includes a first liquid inlet pipe, a liquid pipe tee, a second liquid inlet pipe, an elbow, a third liquid inlet pipe, a fourth liquid inlet pipe, a discharge pipe, a fifth liquid inlet pipe, a first liquid outlet pipe, a second liquid outlet pipe, a third liquid outlet pipe, a first return liquid pipe, a second return liquid pipe, a water quality monitor, a liquid pipe solenoid valve, and a booster water pump; one end of the first liquid inlet pipe is connected to the wastewater discharge mechanism, and the other end is fixedly connected to the second liquid inlet pipe through the liquid pipe tee, the other end of the second liquid inlet pipe is fixedly connected to the third liquid inlet pipe through the elbow, the other end of the third liquid inlet pipe is fixedly connected to the fourth liquid inlet pipe through the liquid pipe tee, and the other end of the fourth liquid inlet pipe is fixedly set on the liquid inlet; one end of the discharge pipe is fixedly set On the liquid pipe tee fixedly connected to the fourth liquid inlet pipe, one end of the fifth liquid inlet pipe is fixedly arranged on the liquid pipe tee of the first liquid inlet pipe, one end of the first liquid outlet pipe is fixedly arranged on the liquid outlet, and the other end thereof is fixedly connected to the second liquid outlet pipe and the second liquid return pipe through the liquid pipe tee, the other end of the second liquid outlet pipe is fixedly connected to the third liquid outlet pipe and the first liquid return pipe through the liquid pipe tee, the other end of the third liquid outlet pipe is connected to an external collection device, the other end of the first liquid return pipe is fixedly connected to the fifth liquid inlet pipe and the second liquid return pipe through the liquid pipe tee, a liquid pipe solenoid valve is fixedly arranged on the discharge pipe, the fifth liquid inlet pipe, the third liquid outlet pipe and the second liquid return pipe, a water quality monitor is fixedly arranged on the first liquid return pipe, and a booster water pump is fixedly arranged on the fourth liquid inlet pipe;

[0021] A treatment process of a high-concentration industrial wastewater treatment device based on ozone-photocatalysis comprises the following steps:

[0022] S1, the ozone generator generates ozone gas, which reaches the main air inlet through the first air inlet pipe, the second air inlet pipe, and the third air inlet pipe, and then enters the main air pipe and the branch air inlet pipe, and finally enters the reaction zone of the tank through the breathable membrane to react with the wastewater for oxidation;

[0023] S2, when the first air inlet pipe enters the ozone gas, the air pipe solenoid valves on the first air outlet pipe and the second air outlet pipe are closed, and the gas enters the breathable membrane through the second air inlet pipe and the third air inlet pipe. After the reaction, the gas containing the residual ozone enters the return air zone and reaches the first air outlet pipe through the air outlet. The concentration monitor monitors the ozone concentration in the return air zone. When the concentration is higher than the set value, the air pipe solenoid valve on the first air outlet pipe is opened, and the air pipe solenoid valve on the second air inlet pipe is closed. The gas enters the breathable membrane for the second time through the third air inlet pipe for the secondary reaction, and the cycle repeats; until the concentration is lower than the set value, the air pipe solenoid valves on the second air inlet pipe and the second air outlet pipe are opened, and the tail gas enters the ozone tail gas treatment device through the second air outlet pipe;

[0024] S3, the photocatalyst balls enter through the liquid inlet together with the wastewater, and are impacted onto the porous speaker support platform by the water pressure of the porous cylinder, and the photocatalyst balls react with the wastewater under the irradiation of ultraviolet rays;

[0025] S4, the impact cylinder drives the impact mandrel to move up and down in a straight line along its axial direction. During the movement, the impact mandrel frequently hits the impact boss, and the impact boss drives the porous speaker support platform to vibrate; S5, the light strip emits ultraviolet light to irradiate the photocatalyst ball with ultraviolet light to complete the catalytic reaction of wastewater; S6, the wastewater enters the tank body through the first liquid inlet pipe, the second liquid inlet pipe, the third liquid inlet pipe, the fourth liquid inlet pipe, and the liquid inlet. The water after the catalytic oxidation reaction passes through the liquid outlet, the first liquid outlet pipe, The second liquid outlet pipe reaches the third liquid outlet pipe, and after being detected by the water quality monitor on the first liquid return pipe, if it meets the discharge standard, it is discharged through the third liquid outlet pipe. If it does not meet the discharge standard, it continues to enter the liquid inlet pipe through the first liquid return pipe and the fifth liquid inlet pipe for secondary reaction until it meets the discharge standard; the secondary liquid inlet power is provided by the booster water pump fixedly installed on the fourth liquid inlet pipe, the second liquid return pipe is a spare pipe, and the liquid pipe solenoid valve fixedly installed on the discharge pipe, the fifth liquid inlet pipe, the third liquid outlet pipe, and the second liquid return pipe is used to control the on-off;

[0026] Compared with the prior art, the present invention has the following beneficial effects:

[0027] 1. By setting up a permeable ozone mechanism, the contact area between wastewater and ozone is increased, especially bubble-free aeration can be achieved, which greatly improves the oxygen transfer efficiency in wastewater. Under the same conditions, it greatly reduces the use time of ozone, reduces oxygen production efficiency, and reduces manufacturing costs.

[0028] 2. By setting up a concentration monitor, the first air outlet pipe, and an air pipe solenoid valve, when the ozone concentration is higher than the set value, it will be circulated into the wastewater for secondary utilization. When the concentration is lower than the set value, it will be discharged through the air pipe solenoid valve, thereby improving the utilization rate of the intake ozone and reducing the cost of recovering the discharged ozone.

[0029] 3. By setting the impact boss and the impact mandrel in the catalytic reaction mechanism, the problem of wastewater sediment sticking to the porous horn support platform during the catalytic oxidation process can be effectively solved. When the impact mandrel is acted upon by the cylinder and hits the porous horn support platform, vibration is generated, and the sediment sticking on the porous horn support platform is vibrated to the sewage collection area;

[0030] 4. By setting a porous speaker support platform and a porous cylinder, the contact area between the photocatalyst ball and the wastewater is increased. At the same time, the photocatalyst ball is affected by the liquid inlet pressure and flows into the liquid inlet. Under the pressure of the liquid inlet, the photocatalyst ball cannot enter the liquid inlet under normal working conditions and remains in the porous speaker support platform and the porous cylinder. When the photocatalyst ball needs to be replaced, it is discharged through the drain pipe with the reflux of the liquid inlet, which is convenient for the injection and replacement of the photocatalyst ball.

[0031] 5. By setting up a multi-level illumination mechanism, the contact surface between the ultraviolet light and the waste liquid and the photocatalyst balls in the waste liquid is increased, and the catalytic reaction is carried out at multiple levels and angles, which increases the reaction speed, reduces the energy consumption of equipment operation, and increases the waste liquid treatment capacity per unit time;

[0032] 6. By setting up a monitoring and control mechanism, the liquid after the catalytic reaction is monitored in real time. If it is qualified, it will be discharged. If it is unqualified, the catalytic reaction will continue to circulate, which improves the automation of the equipment; BRIEF DESCRIPTION OF THE DRAWINGS

[0033] The present invention is further described in detail below in conjunction with the accompanying drawings:

[0034] Figure 1 It is a schematic diagram of the three-dimensional structure of the present invention;

[0035] Figure 2 It is a side view of the present invention;

[0036] Figure 3 It is the front view of the present invention;

[0037] Figure 4 for Figure 2 Schematic diagram of the structure of the cross section in the AA direction;

[0038] Figure 5 for Figure 3 Structural schematic diagram of the cross section in the middle BB direction;

[0039] Figure 6 for Figure 4 A partial enlarged schematic diagram of the middle C area;

[0040] Figure 7 for Figure 5 A partial enlarged schematic diagram of the middle D area;

[0041] Figure 8 for Figure 5 A partial enlarged schematic diagram of the middle E area;

[0042] Fig. 9 for Figure 3 A partial enlarged schematic diagram of the middle F area;

[0043] In the figure:

[0044] 1. Main tank body; 101. Base; 102. Tank body; 103. Upper cover; 104. Air inlet; 105. Air outlet; 106. Liquid inlet; 107. Liquid outlet; 108. Observation port; 109. Cleaning port; 110. Pollution collection area; 111. Reaction area; 112. Air return area; 2. Transmembrane ozone mechanism; 201. Support base; 202. Support frame; 203. First air inlet pipe; 204, air pipe tee; 205, second air inlet; 206, third air inlet; 207, first air outlet; 208, second air outlet; 209, main air inlet; 210, main air pipe; 211, branch air inlet; 212, breathable membrane; 213, lifting arm; 214, ozone generator; 215, air pipe solenoid valve; 216, concentration monitor; 3, catalytic reaction mechanism; 301, porous horn 302, porous cylinder; 303, sieve hole; 304, support column; 305, guide hole; 306, impact boss; 307, impact mandrel; 308, impact cylinder; 4, multi-level lighting mechanism; 401, light belt groove; 402, upper mirror surface; 403, inner mirror surface; 404, lower mirror surface; 405, light belt; 5, monitoring and control mechanism; 501, first liquid inlet pipe; 502, liquid pipe Tee; 503, second liquid inlet pipe; 504, elbow; 505, third liquid inlet pipe; 506, fourth liquid inlet pipe; 507, discharge pipe; 508, fifth liquid inlet pipe; 509, first liquid outlet pipe; 510, second liquid outlet pipe; 511, third liquid outlet pipe; 512, first liquid return pipe; 513, second liquid return pipe; 514, water quality monitor; 515, liquid pipe solenoid valve; 516, booster pump; DETAILED DESCRIPTION

[0045] Embodiment 1:

[0046] The following will be combined with the drawings in the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0047] See also Figure 1-Figure 9 A high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis, comprising a main tank body 1, wherein the main tank body 1 comprises a base 101, a tank body 102, an upper cover 103, an air inlet 104, an air outlet 105, a liquid inlet 106, a liquid outlet 107, an observation port 108, a cleaning port 109, a sewage collection area 110, a reaction area 111, and a gas return area 112; the tank body 102 is fixedly arranged on the base 101, and the upper cover 103 is fixedly arranged on the tank body 102 The upper cover 103 is provided with an air inlet 104 and an air outlet 105, the bottom of the tank body 102 is provided with a liquid inlet 106, the side of the tank body 102 is provided with a liquid outlet 107, an observation port 108, and a cleaning port 109, the cleaning port 109 is close to the bottom of the tank body 102, and the liquid outlet 107 and the observation port 108 are close to the top of the tank body 102; the interior of the tank body 102 is divided into a sewage collection area 110, a reaction area 111, and a gas return area 112 from bottom to top;

[0048] A permeable membrane ozone mechanism 2 for ozone catalyzing wastewater is fixedly arranged in the main tank body 1;

[0049] The main tank body 1 is fixedly provided with a catalytic reaction mechanism 3 for photocatalyzing wastewater.

[0050] In some embodiments, see Figure 2 , Figure 3 , Figure 5 , Figure 6The permeable membrane ozone mechanism 2 includes a support base 201, a support frame 202, a first air inlet pipe 203, an air pipe tee 204, a second air inlet pipe 205, a third air inlet pipe 206, a main air inlet port 209, a main air pipe 210, a branch air inlet pipe 211, a breathable membrane 212, a lifting arm 213, and an ozone generator 214; the support base 201 is fixedly arranged inside the tank body 102, the support frame 202 is fixedly arranged on the support base 201, one side of the first air inlet pipe is connected to the ozone generator 214, and the other side is fixedly connected to the second air inlet pipe 205 through the air pipe tee 204, the other end of the second air inlet pipe 205 is fixedly connected to the third air inlet pipe 206 through the air pipe tee 204, the third air inlet pipe 206 is connected to the main air inlet port 209 after passing through the air inlet port 104, and the main air pipe 210 There are multiple groups, the main air inlet 209 is fixedly connected to one of the main air pipes 210, each group of the main air pipes 210 is fixedly provided with multiple groups of air inlet pipes 211, each group of the branch air inlet pipes 211 is fixedly connected to a group of air permeable membranes 212, and multiple groups of air permeable membranes 212 are fixedly connected side by side through the support frame 202; two groups of lifting arms 213 are fixedly provided on both sides of the upper part of the support frame 202 for hanging the permeable ozone mechanism 2, and an ozone generator 214 is fixedly provided on one side of the main tank body 1; when in use, the ozone generator 214 generates ozone gas, which reaches the main air inlet 209 through the first air inlet pipe 203, the second air inlet pipe 205, and the third air inlet pipe 206, and then enters the main air pipe 210 and the branch air inlet pipe 211, and finally enters the reaction zone 111 of the tank body 102 through the air permeable membrane 212 to undergo oxidation reaction with the wastewater;

[0051] In some embodiments, see Figure 5 The breathable membrane 212 is a waterproof breathable membrane, so that gas can be smoothly passed into the breathable membrane 212. When there is no ventilation, wastewater cannot penetrate into the inside of the breathable membrane. By setting up a permeable ozone mechanism, the contact area between wastewater and ozone is increased, and in particular, bubble-free aeration can be achieved, which greatly improves the oxygen transfer efficiency in wastewater. Under the same conditions, the use time of ozone is greatly reduced, the oxygen production efficiency is reduced, and the manufacturing cost is reduced.

[0052] In some embodiments, see Figure 2 , Figure 3The permeable ozone mechanism 2 also includes a first air outlet pipe 207, a second air outlet pipe 208, an air pipe solenoid valve 215, and a concentration monitor 216; one end of the first air outlet pipe 207 is connected to the air outlet 105, and the other end is fixedly connected to the second air inlet pipe 205 through the air pipe tee 204; one end of the second air outlet pipe 208 is fixedly connected to the second air inlet pipe 205 through the air pipe tee 204, and the other end is connected to the ozone tail gas treatment device; the second air inlet pipe 205, the first air outlet pipe 207, the second air outlet pipe 208, the first air outlet pipe 207, the second air inlet pipe 205, the first air outlet pipe 208, the second air inlet pipe 205, the first air outlet pipe 207, the second air inlet pipe 215, and the first air outlet pipe 207. The first air inlet pipe 207 and the second air outlet pipe 208 are respectively provided with an air pipe solenoid valve 215, and a concentration monitor 216 is fixedly arranged on the upper cover 103, and its detection contact penetrates into the return air zone 112 inside the tank body 102 at the lower end of the upper cover 103; when in use, when the first air inlet pipe 203 enters the ozone gas, the air pipe solenoid valve 215 on the first air outlet pipe 207 and the second air outlet pipe 208 is closed, and the gas enters the breathable membrane 2 through the second air inlet pipe 205 and the third air inlet pipe 206. 12, the gas containing residual ozone after the reaction enters the return air zone 112, reaches the first outlet pipe 207 through the outlet port 105, and the concentration monitor 216 monitors the ozone concentration in the return air zone 112. When the concentration is higher than the set value, the air pipe solenoid valve 215 on the first outlet pipe 207 is opened, and the air pipe solenoid valve 215 on the second inlet pipe 205 is closed, and the gas enters the air permeable membrane 212 for a second time through the third inlet pipe 206 for a second reaction. The process repeats itself over and over again; until the concentration is lower than the set value, the air pipe solenoid valve 215 on the second air inlet pipe 205 and the second air outlet pipe 208 is opened, and the tail gas enters the ozone tail gas treatment device through the second air outlet pipe 208; by setting a concentration monitor, a first air outlet pipe, and an air pipe solenoid valve, when the ozone concentration is higher than the set value, it is circulated into the wastewater for secondary utilization, and when the concentration is lower than the set value, it is discharged through the air pipe solenoid valve, thereby improving the utilization rate of the intake ozone and reducing the cost of recovering the discharged ozone;

[0053] In some embodiments, see Figure 5 The catalytic reaction mechanism 3 includes a porous horn support platform 301, a porous cylinder 302, a sieve hole 303, and a support column 304; a porous horn support platform 301 is fixedly provided on the upper side of the dirt collection area 110 inside the tank body 102, the cleaning port 109 is provided on the upper side of the porous horn support platform 301, a porous cylinder 302 is provided downwardly at the center position of the porous horn support platform 301, the bottom of the porous cylinder 302 is fixedly provided at the bottom of the tank body 102, and the liquid inlet 106 is provided at the center position of the porous cylinder 302; the bottom of the porous horn support platform 301 is fixedly connected by multiple groups of the support columns 304, and the bottoms of the multiple groups of the support columns 304 are fixedly connected to the bottom of the tank body 102;

[0054] In some embodiments, see Figure 5 The porous speaker support platform 301 and the porous cylinder 302 are provided with a plurality of groups of sieve holes 303, and the diameter of the sieve holes 303 is smaller than the diameter of the photocatalyst ball. When in use, the photocatalyst ball enters through the liquid inlet 106 together with the wastewater, and is impacted onto the porous speaker support platform 301 by the water pressure of the porous cylinder 302, and the photocatalyst ball reacts catalytically with the wastewater under ultraviolet irradiation. By providing the porous speaker support platform and the porous cylinder, the contact area between the photocatalyst ball and the wastewater is increased, and the photocatalyst ball is affected by the liquid inlet pressure and flows into the liquid inlet. Under the normal working state, the photocatalyst ball cannot enter the liquid inlet, and is kept in the porous speaker support platform and the porous cylinder. When the photocatalyst ball needs to be replaced, it is discharged through the drain pipe along with the reflux of the liquid inlet, so as to facilitate the injection and replacement of the photocatalyst ball.

[0055] In some embodiments, see Figure 7 The catalytic reaction mechanism 3 also includes a guide hole 305, an impact boss 306, an impact core shaft 307, and an impact cylinder 308; a guide hole 305 is opened on the upper side of the support column 304, and an impact boss 306 is fixedly arranged in the guide hole 305, one end of the impact boss 306 is fixedly connected to the porous speaker support platform 301, the core shaft 307 is movably arranged in the support column 304, and moves linearly along its axial direction, the impact cylinder 308 is fixedly arranged at the bottom of the support column 304, and its shaft end is fixedly connected to the impact core shaft 307. When in use, the impact cylinder 308 drives the impact mandrel 307 to move up and down in a straight line along its axial direction. During the movement, the impact mandrel 307 frequently hits the impact boss 306, and the impact boss 306 drives the porous horn support platform 301 to vibrate. By setting the impact boss and the impact mandrel in the catalytic reaction mechanism, the problem of wastewater sediment sticking to the porous horn support platform during catalytic oxidation can be effectively solved. When the impact mandrel is acted upon by the cylinder and hits the porous horn support platform, vibration is generated, and the sediment sticking on the porous horn support platform is vibrated to the sewage collection area.

[0056] In some embodiments, see Figure 8The ozone-photocatalytic high-concentration industrial wastewater treatment equipment also includes a multi-stage illumination mechanism 4, which includes a light belt groove 401, an upper mirror surface 402, an inner mirror surface 403, a lower mirror surface 404, and a light belt 405; the light belt groove 401 is provided with multiple groups, fixedly arranged on the inner wall of the reaction zone 111 of the tank body 102, and evenly arranged along the axial direction of the tank body 102, one side of the light belt groove 401 is attached to the inner wall of the tank body 102, and the other three sides are respectively fixed with upper and lower mirror surfaces. The mirror surface 402, the inner mirror surface 403, and the lower mirror surface 404 together form a cavity, and a light strip 405 is arranged in the cavity; when in use, the light strip 405 emits ultraviolet light to irradiate the photocatalyst balls with ultraviolet light to complete the catalytic reaction of wastewater; by setting a multi-level illumination mechanism, the contact surface of the ultraviolet light on the waste liquid and the photocatalyst balls in the waste liquid is increased, and the catalytic reaction is carried out at multiple levels and angles, thereby increasing the reaction speed, reducing the energy consumption of the equipment operation, and increasing the amount of waste liquid treated per unit time;

[0057] In some embodiments, see Figure 2 , Fig. 9The ozone-photocatalytic high-concentration industrial wastewater treatment equipment also includes a monitoring and control mechanism 5, which includes a first liquid inlet pipe 501, a liquid pipe tee 502, a second liquid inlet pipe 503, an elbow 504, a third liquid inlet pipe 505, a fourth liquid inlet pipe 506, a discharge pipe 507, a fifth liquid inlet pipe 508, a first liquid outlet pipe 509, a second liquid outlet pipe 510, a third liquid outlet pipe 511, a first liquid return pipe 512, a second liquid return pipe 513, a water quality monitor 514, a liquid pipe solenoid valve 515, and a booster water pump 516; one end of the first liquid inlet pipe 501 is connected to the wastewater discharge mechanism, and the other end is fixedly connected to the second liquid inlet pipe 503 through the liquid pipe tee 502 The other end of the second liquid inlet pipe 503 is fixedly connected to the third liquid inlet pipe 505 through the elbow 504, and the other end of the third liquid inlet pipe 505 is fixedly connected to the fourth liquid inlet pipe 506 through the liquid pipe tee 502, and the other end of the fourth liquid inlet pipe 506 is fixedly arranged on the liquid inlet port 106; one end of the liquid discharge pipe 507 is fixedly arranged on the liquid pipe tee 502 fixedly connected to the fourth liquid inlet pipe 506, one end of the fifth liquid inlet pipe 508 is fixedly arranged on the liquid pipe tee 502 of the first liquid inlet pipe 501, and one end of the first liquid outlet pipe 509 is fixedly arranged on the liquid outlet port 107, and the other end thereof is connected to the liquid pipe tee 502 through the liquid pipe tee 50 2 is fixedly connected to the second liquid outlet pipe 510 and the second liquid return pipe 513, the other end of the second liquid outlet pipe 510 is fixedly connected to the third liquid outlet pipe 511 and the first liquid return pipe 512 through the liquid pipe tee 502, the other end of the third liquid outlet pipe 511 is connected to an external collection device, the other end of the first liquid return pipe 512 is fixedly connected to the fifth liquid inlet pipe 508 and the second liquid return pipe 513 through the liquid pipe tee 502, the liquid discharge pipe 507, the fifth liquid inlet pipe 508, the third liquid outlet pipe 511, and the second liquid return pipe 513 are fixedly provided with a liquid pipe solenoid valve 515, the first liquid return pipe 512 is fixedly provided with a water quality monitor 514, the fourth liquid inlet pipe 5 06 is fixedly provided with a booster water pump 516; when in use, waste water enters the tank body 102 through the first liquid inlet pipe 501, the second liquid inlet pipe 503, the third liquid inlet pipe 505, the fourth liquid inlet pipe 506, and the liquid inlet 106, and the water after the catalytic oxidation reaction passes through the liquid outlet 107, the first liquid outlet pipe 509, and the second liquid outlet pipe 510 to reach the third liquid outlet pipe 511, and after being detected by the water quality monitor 514 on the first liquid return pipe 512, if the discharge standard is met, it is discharged through the third liquid outlet pipe 511, and if the discharge standard is not met, it continues to enter the liquid inlet pipeline through the first liquid return pipe 512 and the fifth liquid inlet pipe 508 for secondary reaction until the discharge standard is met;The secondary liquid inlet power is provided by a booster water pump 516 fixedly installed on the fourth liquid inlet pipe 506. The second liquid return pipe 513 is a spare pipe. The liquid pipe solenoid valve 515 fixedly installed on the discharge pipe 507, the fifth liquid inlet pipe 508, the third liquid outlet pipe 511, and the second liquid return pipe 513 is used to control the on-off. By setting a monitoring and control mechanism, the liquid after the catalytic reaction is monitored in real time. If it is qualified, it is discharged. If it is unqualified, the catalytic reaction continues to circulate, thereby improving the automation of the equipment.

[0058] A treatment process of a high-concentration industrial wastewater treatment device based on ozone-photocatalysis comprises the following steps:

[0059] S1, the ozone generator 214 generates ozone gas, which reaches the main air inlet 209 through the first air inlet pipe 203, the second air inlet pipe 205, and the third air inlet pipe 206, and then enters the main air pipe 210 and the branch air inlet pipe 211, and finally enters the reaction zone 111 of the tank body 102 through the air permeable membrane 212 to react with the wastewater for oxidation; S2, when the ozone gas enters the first air inlet pipe 203, the air pipe solenoid valve 215 on the first air outlet pipe 207 and the second air outlet pipe 208 is closed, and the gas enters the air permeable membrane 212 through the second air inlet pipe 205 and the third air inlet pipe 206, and the gas containing the remaining ozone after the reaction enters the The return air zone 112 reaches the first outlet pipe 207 through the outlet 105, and the concentration monitor 216 monitors the ozone concentration in the return air zone 112. When the concentration is higher than the set value, the air pipe solenoid valve 215 on the first outlet pipe 207 is opened, and the air pipe solenoid valve 215 on the second inlet pipe 205 is closed, and the gas enters the breathable membrane 212 for a second time through the third inlet pipe 206 to perform a secondary reaction, and the cycle repeats; until the concentration is lower than the set value, the air pipe solenoid valve 215 on the second inlet pipe 205 and the second outlet pipe 208 is opened, and the tail gas enters the ozone tail gas treatment device through the second outlet pipe 208;

[0060] S3, the photocatalyst balls enter through the liquid inlet 106 together with the wastewater, and are impacted onto the porous speaker support platform 301 by the water pressure of the porous cylinder 302, and the photocatalyst balls react with the wastewater by catalysis under the irradiation of ultraviolet rays;

[0061] S4, the impact cylinder 308 drives the impact mandrel 307 to move up and down in a straight line along its axis direction. During the movement, the impact mandrel 307 frequently hits the impact boss 306, and the impact boss 306 drives the porous speaker support platform 301 to vibrate;

[0062] S5, the light strip 405 emits ultraviolet light to irradiate the photocatalyst ball with ultraviolet light to complete the catalytic reaction of the wastewater;

[0063] S6, waste water enters the tank body 102 through the first liquid inlet pipe 501, the second liquid inlet pipe 503, the third liquid inlet pipe 505, the fourth liquid inlet pipe 506, and the liquid inlet port 106. After the catalytic oxidation reaction, the water reaches the third liquid outlet pipe 511 through the liquid outlet port 107, the first liquid outlet pipe 509, and the second liquid outlet pipe 510. After being detected by the water quality monitor 514 on the first liquid return pipe 512, if it meets the discharge standard, it is discharged through the third liquid outlet pipe 511. 1 is discharged. If the discharge standard is not met, the liquid continues to enter the liquid inlet pipe for secondary reaction through the first liquid return pipe 512 and the fifth liquid inlet pipe 508 until the discharge standard is met; the secondary liquid inlet power is provided by a booster water pump 516 fixedly installed on the fourth liquid inlet pipe 506, the second liquid return pipe 513 is a spare pipe, and the liquid pipe solenoid valve 515 fixedly installed on the discharge pipe 507, the fifth liquid inlet pipe 508, the third liquid outlet pipe 511, and the second liquid return pipe 513 is used to control the on-off;

[0064] Obviously, the above embodiments are merely examples for clearly explaining the present invention, and are not intended to limit the implementation methods of the present invention. For those skilled in the art, other different forms of changes or modifications can be made based on the above description. It is not necessary and impossible to list all the implementation methods here. However, these obvious changes or modifications derived from the spirit of the present invention are still within the protection scope of the present invention.

Claims

1. A high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis, characterized in that: The invention comprises a main tank body (1), wherein the main tank body (1) comprises a base (101), a tank body (102), an upper cover (103), an air inlet (104), an air outlet (105), a liquid inlet (106), a liquid outlet (107), an observation port (108), a cleaning port (109), a dirt collecting area (110), a reaction area (111), and an air return area (112); the tank body (102) is fixedly arranged on the base (101), the upper cover (103) is fixedly arranged on the tank body (102), and the upper cover (103) is opened. An air inlet (104) and an air outlet (105) are provided, a liquid inlet (106) is provided at the bottom of the tank body (102), a liquid outlet (107), an observation port (108), and a cleaning port (109) are provided at the side of the tank body (102), the cleaning port (109) is close to the bottom of the tank body (102), and the liquid outlet (107) and the observation port (108) are close to the top of the tank body (102); the interior of the tank body (102) is divided from bottom to top into a sewage collection area (110), a reaction area (111), and a gas return area (112); A permeable membrane ozone mechanism (2) for ozone-catalyzing wastewater is fixedly arranged in the main tank (1); A catalytic reaction mechanism (3) for photocatalyzing wastewater is fixedly arranged in the main tank body (1).

2. The high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis according to claim 1 is characterized in that: The permeable membrane ozone mechanism (2) comprises a support base (201), a support frame (202), a first air inlet pipe (203), an air pipe tee (204), a second air inlet pipe (205), a third air inlet pipe (206), a main air inlet port (209), a main air pipe (210), a branch air inlet pipe (211), a permeable membrane (212), a lifting arm (213), and an ozone generator (214); the support base (201) is fixedly arranged inside the tank body (102), the support frame (202) is fixedly arranged on the support base (201), one side of the first air inlet pipe is connected to the ozone generator (214), and the other side is fixedly connected to the second air inlet pipe (205) via the air pipe tee (204), and the other end of the second air inlet pipe (205) is connected to the ozone generator (214) via the air pipe tee (204). The passage (204) is fixedly connected to the third air inlet pipe (206), and the third air inlet pipe (206) is connected to the main air inlet (209) after passing through the air inlet (104). The main air pipes (210) are provided with a plurality of groups, and the main air inlet (209) is fixedly connected to one group of the main air pipes (210). Each group of the main air pipes (210) is fixedly provided with a plurality of groups of air inlet pipes (211), and each group of the group of the air inlet pipes (211) is fixedly connected to a group of air permeable membranes (212). The plurality of groups of the air permeable membranes (212) are fixedly connected side by side through the support frame (202); two groups of lifting arms (213) are fixedly provided on both sides of the upper part of the support frame (202) for lifting the permeable ozone mechanism (2), and an ozone generator (214) is fixedly provided on one side of the main tank body (1).

3. The high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis according to claim 2 is characterized in that: The breathable membrane (212) is a waterproof breathable membrane, so that gas can smoothly pass through the breathable membrane (212); when no air is passed through, wastewater cannot penetrate into the breathable membrane.

4. The high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis according to claim 3 is characterized in that: The membrane-transmitting ozone mechanism (2) further comprises a first air outlet pipe (207), a second air outlet pipe (208), an air pipe solenoid valve (215), and a concentration monitor (216); one end of the first air outlet pipe (207) is connected to the air outlet (105), and the other end is fixedly connected to the second air inlet pipe (205) via the air pipe tee (204); one end of the second air outlet pipe (208) is fixedly connected to the second air inlet pipe (205) via the air pipe tee (204), and the other end is connected to an ozone tail gas treatment device; the second air inlet pipe (205), the first air outlet pipe (207), and the second air outlet pipe (208) are respectively provided with an air pipe solenoid valve (215); the concentration monitor (216) is fixedly arranged on the upper cover (103), and its detection contact extends deep into the return air zone (112) inside the tank body (102) at the lower end of the upper cover (103).

5. The high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis according to claim 4 is characterized in that: The catalytic reaction mechanism (3) comprises a porous horn support platform (301), a porous cylinder (302), a sieve hole (303), and a support column (304); the porous horn support platform (301) is fixedly arranged on the upper side of the dirt collection area (110) inside the tank body (102); the cleaning port (109) is arranged on the upper side of the porous horn support platform (301); a porous cylinder (302) is arranged downward at the center of the porous horn support platform (301); the bottom of the porous cylinder (302) is fixedly arranged at the bottom of the tank body (102); and the liquid inlet (106) is arranged at the center of the porous cylinder (302); the bottom of the porous horn support platform (301) is fixedly connected by multiple groups of the support columns (304); and the bottoms of the multiple groups of the support columns (304) are fixedly connected to the bottom of the tank body (102).

6. The high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis according to claim 5 is characterized in that: The porous speaker support platform (301) and the porous cylinder (302) are provided with a plurality of groups of sieve holes (303), and the diameter of the sieve holes (303) is smaller than the diameter of the photocatalyst ball.

7. The high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis according to claim 6 is characterized in that: The catalytic reaction mechanism (3) further comprises a guide hole (305), an impact boss (306), an impact mandrel (307), and an impact cylinder (308); the guide hole (305) is opened on the upper side of the interior of the support column (304); the impact boss (306) is fixedly arranged in the guide hole (305); one end of the impact boss (306) is fixedly connected to the porous speaker support platform (301); the mandrel (307) is movably arranged in the interior of the support column (304) and moves linearly along its axial direction; the impact cylinder (308) is fixedly arranged at the bottom of the support column (304); the shaft end of the impact cylinder is fixedly connected to the impact mandrel (307).

8. The high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis according to claim 7 is characterized in that: The ozone-photocatalytic high-concentration industrial wastewater treatment equipment further comprises a multi-stage illumination mechanism (4), the multi-stage illumination mechanism (4) comprising a light strip groove (401), an upper mirror surface (402), an inner mirror surface (403), a lower mirror surface (404), and a light strip (405); the light strip groove (401) is provided with a plurality of groups, fixedly arranged on the inner wall of the reaction zone (111) of the tank body (102), and evenly arranged along the axial direction of the tank body (102); one side of the light strip groove (401) is in contact with the inner wall of the tank body (102), and the other three sides are respectively fixedly provided with an upper mirror surface (402), an inner mirror surface (403), and a lower mirror surface (404), and together with the light strip groove (401) form a cavity, and the light strip (405) is arranged in the cavity.

9. The high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis according to claim 8 is characterized in that: The ozone-photocatalytic high-concentration industrial wastewater treatment equipment further comprises a monitoring and control mechanism (5), wherein the monitoring and control mechanism (5) comprises a first liquid inlet pipe (501), a liquid pipe tee (502), a second liquid inlet pipe (503), an elbow (504), a third liquid inlet pipe (505), a fourth liquid inlet pipe (506), a liquid discharge pipe (507), a fifth liquid inlet pipe (508), a first liquid outlet pipe (509), a second liquid outlet pipe (510), a third liquid outlet pipe (511), a first liquid return pipe (512), a second liquid return pipe (513), a water quality monitor (514), and a liquid pipe solenoid valve (515). , a booster water pump (516); one end of the first liquid inlet pipe (501) is connected to the wastewater discharge mechanism, and the other end is fixedly connected to the second liquid inlet pipe (503) through the liquid pipe tee (502); the other end of the second liquid inlet pipe (503) is fixedly connected to the third liquid inlet pipe (505) through the elbow (504); the other end of the third liquid inlet pipe (505) is fixedly connected to the fourth liquid inlet pipe (506) through the liquid pipe tee (502); the other end of the fourth liquid inlet pipe (506) is fixedly arranged on the liquid inlet port (106); one end of the liquid discharge pipe (507) is fixedly arranged The liquid pipe tee (502) is fixedly connected to the fourth liquid inlet pipe (506); one end of the fifth liquid inlet pipe (508) is fixedly arranged on the liquid pipe tee (502) of the first liquid inlet pipe (501); one end of the first liquid outlet pipe (509) is fixedly arranged on the liquid outlet (107); the other end of the first liquid outlet pipe (509) is fixedly connected to the second liquid outlet pipe (510) and the second liquid return pipe (513) through the liquid pipe tee (502); the other end of the second liquid outlet pipe (510) is fixedly connected to the third liquid outlet pipe (511) and the first liquid return pipe (513) through the liquid pipe tee (502). 2) fixedly connected, the other end of the third liquid outlet pipe (511) is connected to an external collection device, the other end of the first liquid return pipe (512) is fixedly connected to the fifth liquid inlet pipe (508) and the second liquid return pipe (513) through the liquid pipe tee (502), a liquid pipe solenoid valve (515) is fixedly provided on the discharge pipe (507), the fifth liquid inlet pipe (508), the third liquid outlet pipe (511), and the second liquid return pipe (513), a water quality monitor (514) is fixedly provided on the first liquid return pipe (512), and a booster water pump (516) is fixedly provided on the fourth liquid inlet pipe (506).

10. The treatment process of a high-concentration industrial wastewater treatment equipment based on ozone-photocatalysis according to claim 9, characterized in that: The steps include: S1, the ozone generator (214) generates ozone gas, which reaches the main air inlet (209) through the first air inlet pipe (203), the second air inlet pipe (205), and the third air inlet pipe (206), and then enters the main air pipe (210) and the branch air inlet pipe (211), and finally enters the reaction zone (111) of the tank body (102) through the air permeable membrane (212) to react with the wastewater for oxidation; S2. When ozone gas enters the first air inlet pipe (203), the air pipe solenoid valve (215) on the first air outlet pipe (207) and the second air outlet pipe (208) is closed, and the gas enters the air permeable membrane (212) through the second air inlet pipe (205) and the third air inlet pipe (206). After the reaction, the gas containing residual ozone enters the return air zone (112) and reaches the first air outlet pipe (207) through the air outlet (105). The concentration monitor (216) monitors the ozone concentration in the return air zone (112). When When the concentration is higher than the set value, the air pipe solenoid valve (215) on the first air outlet pipe (207) is opened, and the air pipe solenoid valve (215) on the second air inlet pipe (205) is closed, and the gas enters the air permeable membrane (212) for a second time through the third air inlet pipe (206) to undergo a secondary reaction, which is repeated over and over again; until the concentration is lower than the set value, the air pipe solenoid valves (215) on the second air inlet pipe (205) and the second air outlet pipe (208) are opened, and the exhaust gas enters the ozone exhaust gas treatment device through the second air outlet pipe (208); S3, the photocatalyst balls enter through the liquid inlet (106) together with the wastewater, and are impacted onto the porous speaker support platform (301) by the water pressure through the porous cylinder (302), and the photocatalyst balls react with the wastewater under the irradiation of ultraviolet rays; S4, the impact cylinder (308) drives the impact mandrel (307) to move up and down in a straight line along its axial direction, and during the movement, the impact mandrel (307) frequently impacts the impact boss (306), and the impact boss (306) drives the porous speaker support platform (301) to vibrate; S5, the light strip (405) emits ultraviolet light to irradiate the photocatalyst ball with ultraviolet light to complete the catalytic reaction of the wastewater; S6, waste water enters the tank body (102) through the first liquid inlet pipe (501), the second liquid inlet pipe (503), the third liquid inlet pipe (505), the fourth liquid inlet pipe (506), and the liquid inlet port (106). After the catalytic oxidation reaction, the water reaches the third liquid outlet pipe (511) through the liquid outlet port (107), the first liquid outlet pipe (509), the second liquid outlet pipe (510), and is detected by the water quality monitor (514) on the first liquid return pipe (512). If the water meets the discharge standard, the water is discharged through the third liquid outlet pipe (514). If the liquid does not meet the discharge standard, it will continue to enter the liquid inlet pipe through the first liquid return pipe (512) and the fifth liquid inlet pipe (508) for secondary reaction until it meets the discharge standard; the secondary liquid inlet power is provided by a booster water pump (516) fixedly arranged on the fourth liquid inlet pipe (506), the second liquid return pipe (513) is a spare pipe, and the liquid pipe solenoid valve (515) fixedly arranged on the discharge pipe (507), the fifth liquid inlet pipe (508), the third liquid outlet pipe (511), and the second liquid return pipe (513) is used to control the on-off.

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