Control method for transverse corner cracks of niobium-containing steel casting blank
By controlling the argon blowing flow rate, cover agent addition and cooling water of the steel casting billet, the problem of transverse cracks caused by Nb elements is solved, and the effect of reducing the transverse crack rate of the casting billet and improving the mechanical properties is achieved.
Patent Information
- Application Number
- CN202311042426.9
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2023-08-18
- Publication Date
- 2025-02-25
AI Technical Summary
The addition of Nb elements to the steel species leads to the development of columnar crystals of the casting blank. During the solidification process, the microsegregation of Nb elements at the dendrites boundary leads to the precipitation of precipitates at high temperatures, reducing the grain boundary strength, and easily generating transverse cracks of the casting blank.
By controlling the flow rate of argon blowing at the long water outlet, adding cover agent, adjusting the amount of cold water, and increasing the bending straightening temperature, the N content is reduced during continuous casting, reducing the precipitation and precipitation of NbN at the grain boundary, and reducing the occurrence of cracks on the surface of the casting billet.
It effectively reduces the cross-crack rate at the corners of the casting blank, improves the mechanical properties of the casting blank, has strong applicability and operability, and reduces the probability of cracks on the surface of the casting blank.
Abstract
Description
Technical Field
[0001] The invention relates to a method for controlling transverse cracks at corners of a niobium-containing steel ingot, and belongs to the field of steel smelting and material processing. Background Art
[0002] Adding Nb to carbon manganese steel can refine the grains, strengthen the steel through phase transformation and precipitation, and improve the mechanical properties of the steel. However, when Nb is added to the steel, the columnar crystals of the ingot are well developed. During the solidification process, the microsegregation of Nb at the dendrite boundary leads to the precipitation of precipitates at high temperatures. Its second phase particles sink to the bottom of the coarse austenite grain boundary, reducing the grain boundary strength and easily causing transverse cracks in the ingot. Literature search: (1) The "Proceedings of the 8th (2011) China Iron and Steel Annual Conference" published the "Research on the Control Technology of Transverse Cracks on the Surface of 400mm Extra Thick Slabs" in 2011. This study adopts a weak cooling method for the vertical section and straightening section to increase the shell temperature and avoid the brittle temperature zone; adopts low-frequency, high-amplitude vibration parameters; and optimizes the protective slag to improve the transverse cracks on the surface of the slab. (2) "The Effect of Nb, V, and Ti Microalloying Elements on the Surface Quality of Continuous Casting Ingots" was published in the 4th issue of Wide and Heavy Plates in 2003. By reducing the secondary cooling water volume, reducing the Nb, V, and Ti microalloying elements, and increasing the drawing speed to avoid the brittle temperature range of steel from the high temperature side, the incidence of corner cracks in the ingots was significantly reduced. Summary of the invention
[0003] The purpose of the present invention is to provide a method for controlling transverse cracks at the corners of a niobium-containing steel ingot, which can reduce the N content during the continuous casting process and reduce the precipitation of NbN at the grain boundaries. At the same time, only the cooling water volume in zones 3 and 7 is reduced, and the bending straightening temperature is increased. The method has strong applicability and operability and reduces the probability of cracks on the surface of the ingot.
[0004] The implementation method of the present invention is a method for controlling transverse cracks at the corners of a niobium-containing steel ingot, which is implemented according to the following steps: (1) The argon blowing flow rate of the long nozzle is controlled at 200-300 l / min to ensure that the nozzle is immersed in the molten pool of the tundish, the liquid surface in the impact zone is turned over appropriately, and a small amount of steel flowers are splashed; the argon gas flow rate between the tundish plates is controlled at 20-40 l / min to ensure that no air is inhaled between the plates; (2) After the molten steel in the tundish reaches 10 tons, add covering agent when the molten steel covers the lower mouth of the long nozzle; the amount of covering agent added: 200-350kg is added to the start-up furnace, 100-200kg to the stopper area, and 100-150kg to the impact area. Add the impact area first, 100-150kg to the second furnace, 80-100kg to the third furnace, 50-80kg to the fourth furnace, and add an appropriate amount according to the liquid level after the fifth furnace to ensure that the liquid surface is covered and no molten steel is leaking; (3) The secondary cooling water in zone 3 is reduced to 100-150 l / min, and the surface temperature of the ingot is raised to above 1000°C during bending. The secondary cooling water in zone 7 is reduced to 50-80 l / min, and the surface temperature of the ingot is raised to above 950°C during straightening. (4) The overheat of the furnace when starting or inserting the climbing head is ≤40℃, and the overheat of the continuous casting furnace is ≤30℃ to reduce the growth of columnar crystals; (5) All ingots are sent hot and hot loaded into the heating furnace for rolling to prevent cracks from regenerating and expanding during the slow cooling process.
[0005] The transverse crack rate of the niobium-containing steel ingot produced by this method is reduced by half, mass production is achieved, the surface crack rate of medium and thick plates is greatly reduced, and the one-time fulfillment rate of the contract is improved. The method of the present invention reduces the N content added during the continuous casting process, reduces the precipitation of NbN at the grain boundary, and only reduces the cooling water volume in zones 3 and 7, increases the bending straightening temperature, has strong applicability and operability, and reduces the probability of surface cracks on the ingot. Implementation
[0006] A method for controlling transverse cracks at the corners of a niobium-containing steel ingot is implemented according to the following steps: (1) The argon blowing flow rate of the long nozzle is controlled at 200-300 l / min to ensure that the nozzle is immersed in the molten pool of the tundish, the liquid surface in the impact zone is turned over appropriately, and a small amount of steel flowers are splashed; the argon gas flow rate between the tundish plates is controlled at 20-40 l / min to ensure that no air is inhaled between the plates; (2) After the molten steel in the tundish reaches 10 tons, add covering agent when the molten steel covers the lower mouth of the long nozzle; the amount of covering agent added: 200-350kg is added to the start-up furnace, 100-200kg to the stopper area, and 100-150kg to the impact area. Add the impact area first, 100-150kg to the second furnace, 80-100kg to the third furnace, 50-80kg to the fourth furnace, and add an appropriate amount according to the liquid level after the fifth furnace to ensure that the liquid surface is covered and no molten steel is leaking; (3) The secondary cooling water in zone 3 is reduced to 100-150 l / min, and the surface temperature of the ingot is raised to above 1000°C during bending. The secondary cooling water in zone 7 is reduced to 50-80 l / min, and the surface temperature of the ingot is raised to above 950°C during straightening. (4) The overheat of the furnace when starting or inserting the climbing head is ≤40℃, and the overheat of the continuous casting furnace is ≤30℃ to reduce the growth of columnar crystals; (5) All ingots are sent hot and hot loaded into the heating furnace for rolling to prevent cracks from regenerating and expanding during the slow cooling process.
Claims
1. A method for controlling transverse cracks at the corners of a niobium-containing steel ingot, characterized in that Follow these steps to implement: (1) The argon blowing flow rate of the long nozzle is controlled at 200-300 l / min to ensure that the nozzle is immersed in the molten pool of the tundish, the liquid surface in the impact zone is turned over appropriately, and a small amount of steel flowers are splashed; the argon gas flow rate between the tundish plates is controlled at 20-40 l / min to ensure that no air is inhaled between the plates; (2) After the molten steel in the tundish reaches 10 tons, add covering agent when the molten steel covers the lower mouth of the long nozzle; the amount of covering agent added: 200-350kg is added to the start-up furnace, 100-200kg to the stopper area, and 100-150kg to the impact area. Add the impact area first, 100-150kg to the second furnace, 80-100kg to the third furnace, 50-80kg to the fourth furnace, and add an appropriate amount according to the liquid level after the fifth furnace to ensure that the liquid surface is covered and no molten steel is leaking; (3) The secondary cooling water in zone 3 is reduced to 100-150 l / min, and the surface temperature of the ingot is raised to above 1000°C during bending. The secondary cooling water in zone 7 is reduced to 50-80 l / min, and the surface temperature of the ingot is raised to above 950°C during straightening. (4) The overheat of the furnace when starting or inserting the climbing head is ≤40℃, and the overheat of the continuous casting furnace is ≤30℃ to reduce the growth of columnar crystals; (5) All ingots are sent hot and hot loaded into the heating furnace for rolling to prevent cracks from regenerating and expanding during the slow cooling process.