Colored environment-friendly fadable bubble powder and preparation method thereof

Abstract

The invention provides colored environment-friendly fadable bubble powder and a preparation method thereof. The bubble powder provided by the invention comprises the following components in parts by mass: 2-10 parts of a film-forming agent, 50-70 parts of a surfactant, 20 parts of a color developing agent, 3-5 parts of an acidity regulator, 2-10 parts of a humectant, 0.2-4 parts of a preservative and 0.3-4 parts of a flavoring agent. The preparation method comprises the following steps: uniformly mixing the components according to the proportion, regulating the mass ratio of the total amount of the powder to ethanol / water (v / v 2: 1) within the range of 1: 0.3-1: 2.1, fully mixing and reacting, evaporating the solvent to dryness, and grinding. The bubble powder and the water are fully mixed, so that the blown bubbles are uniform in color, good in visual effect and rich in bubble amount; the bubble liquid remains in the air and can fade to be colorless after waiting for a period of time, thereby being environment-friendly and non-toxic. On this basis, the most important advantage is that the color depth and variety can be regulated according to the needs of a user, and the LED lamp is more flexible and convenient, and is easier to store and carry. In addition, compared with traditional bubble liquid, the bubble powder can greatly save transportation cost and can achieve good economic benefits.

Description

Technical Field

[0001] The invention belongs to the field of daily chemicals, and in particular relates to a colorful, environment-friendly and fadeable bubble powder with self-adjustable colors and a preparation method thereof. Background Art

[0002] In daily life, bubble liquid has a wide range of applications, one of the main applications is as a children's toy, providing entertainment and educational value. At present, there are two main categories of patents on bubble liquid: one is colorless bubble liquid, and the other is colored bubble liquid. For colorless bubble liquid, the main method is to optimize the formula of bubble liquid to make the bubbles richer, the glossiness of the bubbles better, and the time they stay in the air longer, and to focus on the use of natural raw materials to achieve the purpose of no irritation and no harm to the human body, such as "A bubble liquid and its preparation method" (CN202310036969.3) invented by Gao Panjin, Zhou Qian, Gou Juanjuan, etc.; the other is colored bubble liquid, which contains dyes of various colors. These dyes mainly use some plant dyes such as carmine, lemon yellow, etc., such as "Colored bubble liquid" (CN201510929928.2) invented by Jiao Xiuhua. Its defects are high cost and not easy to fade, which also limits its application. Based on the above-mentioned colored bubble liquid, our research group invented environmentally friendly and fadeable colorful bubble liquid, such as "a colored bubble liquid (CN201110034788.4)" invented by Yang Zhenhua, Bian Wei, Zhang Yuexia, etc., but it cannot achieve the regulation of bubble color, and it is inconvenient to carry and easy to leak, and the transportation cost is high. Based on this, the bubble powder invented by this patent can overcome the defects of the above-mentioned bubble liquid. As a new product, bubble powder has the potential to become a new favorite in the children's market, meeting the market's demand for diversified and personalized children's products. Summary of the invention

[0003] The purpose of the present invention is to provide a colorful, environmentally friendly, fadeable bubble powder and a preparation method thereof. The bubble powder can realize the regulation of bubble color on the basis of being colorful, fadeable and environmentally friendly, and the color can be adjusted by oneself, and it is easy to carry and has low transportation cost.

[0004] The present invention provides a colorful, environmentally friendly, fadeable bubble powder, the components and contents of which are calculated by weight: 2-10 parts of film-forming agent starch, 50-70 parts of surfactant, 20 parts of developer, 3-5 parts of acidity regulator, 2-10 parts of moisturizer, 0.2-4 parts of preservatives, 0.3-4 parts of flavoring agent; The preparation method of bubble powder comprises the following steps: The film former, surfactant, color developer, acidity regulator, humectant, preservative and flavoring agent are uniformly mixed in proportion, and the mass ratio of the mixture to ethanol / water (v / v 2:1) is 1:0.3-1:2.1. They are mixed and fully reacted for 12 hours until there is no precipitation, and then heated on an intelligent magnetic heating stirrer until the solvent is completely evaporated, and the bubble powder is obtained by grinding.

[0005] The surfactant is any one of dodecyl dimethyl benzyl ammonium chloride, hydroxysulfobetaine, and dodecyl glucoside, preferably dodecyl dimethyl benzyl ammonium chloride.

[0006] The acidity regulator is any one of oxalic acid and dilute hydrochloric acid, preferably oxalic acid.

[0007] The color developer is any one of the fluorane dyes CK-16, LBC-51, LBC-27 and CVL-S.

[0008] The humectant is sucrose.

[0009] The preservative is any one of sodium benzoate and potassium sorbate, preferably potassium sorbate.

[0010] The flavoring agent is food flavor, specifically citrus flavor or apple flavor.

[0011] The method for preparing bubble liquid by using the colorful bubble powder of the present invention: The prepared bubble powder of different colors is fully mixed with water in the ratio of 1:1, 1:5, 1:10, 1:20, and 1:30 until there is no precipitation. Pour it into the bubble liquid reservoir of a commercially available bubble gun to blow out bubbles of four colors, namely red, purple, green, and blue, of different shades.

[0012] The method for preparing bubble liquid by compounding red and blue bubble powders of the present invention: The prepared red bubble powder and blue bubble powder are mixed in a mass ratio of 1:1, 1:2, 1:3, 1:4, and 1:5, and the mixed bubble powder and water are fully mixed in a ratio of 1:10 until there is no precipitation, and the mixture is poured into the bubble liquid reservoir of a commercially available bubble gun to blow out bubbles of colors different from red and blue.

[0013] Compared with the prior art, the present invention has the following beneficial effects: 1. The bubble powder of the present invention can realize color regulation and can be mixed with water in different proportions at any time according to one's needs and preferences to adjust the concentration and amount of the bubble liquid, so as to blow out red, purple, green and blue bubbles of different shades. In addition, bubble powders of different colors can be mixed and compounded as required to obtain bubbles with more colorful colors. Compared with directly purchased liquid bubble liquid, the bubble powder is more flexible and convenient, can increase the fun of children's play, enhance children's observation ability and hands-on ability, and promote intellectual development, color perception, artistic interest and creativity.

[0014] 2. The bubble powder of the present invention is easier to store and carry than the traditional liquid bubble liquid, and there is no need to worry about leakage, so it is convenient for parents and children to carry it with them when going out; 3. The bubble powder of the present invention can greatly save transportation costs: Since the main component of traditional bubble liquid is water, which accounts for 60%-80%, this also leads to excessively high transportation costs. Making it into powder can save the transportation cost of water and achieve good economic benefits.

[0015] 4. The bubble powders of four colors, red, purple, green and blue, prepared by the present invention can produce abundant bubbles with bright colors and good visual effects from the bubble liquid. After the bubbles burst, the residues can fade to colorless after standing in the air for a period of time. The bubble liquid is safe, non-toxic and more environmentally friendly. BRIEF DESCRIPTION OF THE DRAWINGS

[0016] Figure 1 The purple bubble powder was prepared using LBC-51; Figure 2 This is a picture of bubbles blown out of the red bubble powder prepared with CK-16 and dissolved in water at a ratio of 1:5; Figure 3 This is a picture of bubbles blown when the purple bubble powder prepared with LBC-51 is dissolved in water at a ratio of 1:5; Figure 4 This is a picture of bubbles blown out of the green bubble powder prepared with CVL-S and dissolved in water at a ratio of 1:5; Figure 5 This is a picture of bubbles blown when the blue bubble powder prepared with LBC-27 is dissolved in water at a ratio of 1:5.

[0017] Figure 6 This is a picture of bubbles blown by mixing red bubble powder and blue bubble powder in a mass ratio of 1:3. DETAILED DESCRIPTION Example 1

[0018] A red bubble powder formula: Starch 0.6g Dodecyl dimethyl benzyl ammonium chloride 6g CK-16 2g Oxalic acid 0.3g Sucrose 0.5g Potassium sorbate 0.4g Apple flavor 0.2g Preparation of bubble powder: weigh 0.6g starch, 6g dodecyldimethylbenzyl ammonium chloride, 2g CK-16, 0.3g oxalic acid, 0.5g sucrose, 0.4g potassium sorbate, and 0.2g apple essence, mix well, add 6mL ethanol / water (v / v 2:1) mixed solution to react for 12h until there is no precipitation, heat on an intelligent magnetic heating stirrer until the solvent is completely evaporated, and grind to obtain red bubble powder. Example 2

[0019] A purple bubble powder recipe: Starch 1g Dodecyl dimethyl benzyl ammonium chloride 5g LBC-51 2g Oxalic acid 0.4g Sucrose 0.9g Potassium sorbate 0.3g Apple flavor 0.4g Preparation of bubble powder: weigh 1g starch, 5g dodecyl dimethyl benzyl ammonium chloride, 2g LBC-51, 0.4g oxalic acid, 0.9g sucrose, 0.3g potassium sorbate, and 0.4g apple essence, mix well, add 6mL ethanol / water (v / v 2:1) mixed solution to fully react for 12h until no precipitation, heat on an intelligent magnetic heating stirrer until the solvent is completely evaporated, and grind to obtain purple bubble powder (see Figure 1 ). Example 3

[0020] A green bubble powder recipe: Starch 0.25g Dodecyl dimethyl benzyl ammonium chloride 7g LBC-27 2g Oxalic acid 0.4g Sucrose 0.3g Potassium sorbate 0.05g Citrus flavor 0.1g Preparation of bubble powder: weigh 0.25g starch, 7g dodecyldimethylbenzyl ammonium chloride, 2g LBC-27, 0.4g oxalic acid, 0.3g sucrose, 0.05g potassium sorbate, and 0.1g citrus flavor, mix well, add 6mL ethanol / water (v / v 2:1) mixed solution to react for 12h until there is no precipitation, heat on an intelligent magnetic heating stirrer until the solvent is completely evaporated, and grind to obtain green bubble powder. Example 4

[0021] A blue bubble powder recipe: Starch 0.7g Dodecyl dimethyl benzyl ammonium chloride 6.5g CVL-S 2g Oxalic acid 0.5g Sucrose 0.25g Potassium sorbate 0.02g Citrus flavor 0.03g Preparation of bubble powder: weigh 0.7 g starch, 6.5 g dodecyl dimethyl benzyl ammonium chloride, 2 g CVL-S, 0.5 g oxalic acid, 0.25 g sucrose, 0.02 g potassium sorbate, and 0.03 g citrus flavor, mix well, add 6 mL ethanol / water (v / v 2:1) mixed solution to react for 12 h until there is no precipitation, heat on an intelligent magnetic heating stirrer until the solvent is completely evaporated, and grind to obtain blue bubble powder. Example 5

[0022] 10 mg of the red bubble powder prepared in Example 1 was fully mixed with 10 ml, 50 ml, 100 ml, 200 ml, and 300 ml of water respectively until no precipitation occurred, and then poured into the bubble liquid reservoir of a commercially available bubble gun to blow out red bubbles of different shades (see Figure 2 ). Example 6

[0023] 10 mg of the purple bubble powder prepared in Example 2 was fully mixed with 10 ml, 50 ml, 100 ml, 200 ml, and 300 ml of water respectively until no precipitation occurred, and then poured into the bubble liquid reservoir of a commercially available bubble gun to blow out purple bubbles of different shades (see Figure 3 ). Example 7

[0024] 10 mg of the green bubble powder prepared in Example 3 was mixed with 10 ml, 50 ml, 100 ml, 200 ml, and 300 ml of water respectively until there was no precipitation, and then poured into the bubble liquid reservoir of a commercially available bubble gun to blow out green bubbles of different shades (see Figure 4 ). Example 8

[0025] 10 mg of the blue bubble powder prepared in Example 4 was fully mixed with 10 ml, 50 ml, 100 ml, 200 ml, and 300 ml of water respectively until no precipitation occurred, and then poured into the bubble liquid reservoir of a commercially available bubble gun to blow out blue bubbles of different shades (see Figure 5 ). Example 9

[0026] 10 mg of the red bubble powder prepared in Example 1 was fully mixed with 10 mg, 20 mg, 30 mg, 40 mg, and 50 mg of the blue bubble powder prepared in Example 4, and 200 ml, 300 ml, 400 ml, 500 ml, and 600 ml of water were added to mix thoroughly until no precipitation was found. The mixture was poured into the bubble liquid reservoir of a commercially available bubble gun to blow out bubbles of different compound colors (see Figure 6 ).

[0027] The color of the bubbles blown out of Example 5-9 that remain in the environment after bursting can be faded to colorless by using a small amount of water or standing in the air for a period of time. It is safe, non-toxic and environmentally friendly.

[0028] The above embodiments illustrate that the prepared bubble powder can adjust the color depth and type according to one's own needs, that is, the color of the bubble can be adjusted by oneself, which is more flexible and convenient, and easier to store and carry.

[0029] The above description is not a limitation of the present invention. It should be pointed out that for ordinary technicians in this technical field, several changes, modifications, additions or substitutions can be made without departing from the essential scope of the present invention. These improvements and modifications should also be regarded as the scope of protection of the present invention.

Claims

1. A colorful, environmentally friendly, fading bubble powder, characterized in that: The components and contents of bubble powder are calculated by weight: 2-10 parts of film-forming agent starch, 50-70 parts of surfactant, 20 parts of developer, 3-5 parts of acidity regulator, 2-10 parts of moisturizer, 0.2-4 parts of preservatives, 0.3-4 parts of flavoring agent; The preparation method of bubble powder comprises the following steps: uniformly mixing a film former, a surfactant, a color developer, an acidity regulator, a moisturizer, a preservative and a flavoring agent according to a proportion, mixing them according to a mass ratio of the mixed material to ethanol / water solution of 1:0.3-2.1 and fully reacting until no precipitation occurs, heating on an intelligent magnetic heating stirrer until the solvent is completely evaporated, and grinding to obtain the bubble powder; The volume ratio of ethanol to water in the ethanol / water solution is 2:

1.

2. A colorful, environmentally friendly, fadeable bubble powder as claimed in claim 1, characterized in that: The surfactant is any one of dodecyl dimethyl benzyl ammonium chloride, hydroxysulfobetaine and dodecyl glucoside.

3. The colorful, environmentally friendly, fadeable bubble powder according to claim 1, characterized in that: The acidity regulator is oxalic acid or dilute hydrochloric acid.

4. The colorful, environmentally friendly, fadeable bubble powder according to claim 1, characterized in that: The color developer is any one of the fluorane dyes CK-16, LBC-51, LBC-27 and CVL-S.

5. The colorful, environmentally friendly, fadeable bubble powder according to claim 1, characterized in that: The humectant is sucrose.

6. The colorful, environmentally friendly, fadeable bubble powder according to claim 1, characterized in that: The preservative is sodium benzoate or potassium sorbate.

7. The colorful, environmentally friendly, fadeable bubble powder according to claim 1, characterized in that: The flavoring agent is citrus essence or apple essence.

8. The colorful, environmentally friendly, decolorizable bubble powder as claimed in claim 1 is used to prepare bubble liquid.

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