Water-based color chip

By using high-grade aqueous solid acrylic resin and auxiliary materials such as aluminum hydroxide and silicon carbide in aqueous color films, the problems of poor acid and alkali resistance and fragility after drying are solved, and higher acid and alkali resistance and convenience of use are achieved.

CN119798897APending Publication Date: 2025-04-11CHIBI QUANXIN NEW MATERIALS CO LTD
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Patent Information

Application Number
CN202311314100.7
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-10-11
Publication Date
2025-04-11

AI Technical Summary

Technical Problem

The existing water-based colored tablets have poor acid and alkali resistance, are fragile after drying, are inconvenient to use, and soften at high temperatures, affecting the effect.

Method used

High-grade aqueous solid acrylic resin is used as a carrier, and auxiliary materials such as aluminum hydroxide and silicon carbide are added. Through specific formulations and manufacturing processes, the acid and alkali resistance of color sheets is improved, and the brittleness after drying is reduced by adding sludge and paste.

Benefits of technology

It significantly improves the acid and alkali resistance of water-based color tablets, reduces the fragility after drying, makes the color tablets more convenient to use in drying environments, and is not easy to soften at high temperatures, improving the use effect.

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Abstract

The invention provides a water-based color chip. The color chip is prepared from, by weight, 50-60 parts of acrylic resin, 30-40 parts of butyl rubber, 30-40 parts of pigment, 5-10 parts of dispersing agent, 8-16 parts of aluminum hydroxide, 10-20 parts of zinc oxide, 15-25 parts of silicon carbide, 6-10 parts of ointment and 3-7 parts of daub. According to the water-based color chip disclosed by the invention, the water-based flaky solid pre-dispersed pigment prepared by taking high-grade water-based solid acrylic resin as a carrier can be dissolved in various water-based coatings, and auxiliary materials such as aluminum hydroxide and silicon carbide are added, so that the acid-resisting and alkali-resisting effects of the water-based color chip can be effectively improved; and moreover, by adding auxiliary materials such as daub and ointment, the brittleness of the dried water-based color chip can be reduced, so that the water-based color chip can be fragile in a dry environment, and troubles cannot be brought to taking out and using of the water-based color chip in the later period.
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Description

Technical Field

[0001] The invention belongs to the technical field of water-based color tablets, and in particular relates to a water-based color tablet. Background Art

[0002] Water-based acrylic color chips are made of high-quality organic pigments, high-grade water-based acrylic resin as a carrier, and the pigments are pre-dispersed in the carrier resin. This series of color chips are used in water-based printing inks and have been used in water-based inks for paper flexographic printing, such as preparation, food and beverage packaging, etc.

[0003] The pigment content of water-based acrylic color chips is up to 65%, and no additives are added, which makes AC water-based color chips give the greatest flexibility in ink formulation in application. They can be directly loaded into the ink formulation or first produced into color paste, and then the color paste is added to the ink in the form of ink oil to produce the required ink with appropriate water-based resin. Water-based acrylic color chips are easy to disperse on high-speed dispersers, give high color concentration and gloss, and are easy to transport and have a long storage time.

[0004] The acid and alkali resistance of the water-based color tablets in the prior art is poor, and the water-based color tablets themselves tend to become fragile after drying, which makes it difficult to take them out for use after drying. In addition, the water-based color tablets soften under high temperatures, which makes them inconvenient to use and may affect the effect. Summary of the invention

[0005] The purpose of the present invention is to solve the problems in the prior art that the acid and alkali resistance of water-based color tablets is poor, and the water-based color tablets themselves are prone to become fragile after drying, which makes it more troublesome to take out and use them after drying in the later stage, and the water-based color tablets soften under high temperatures, which is inconvenient to use and may affect the effect, and to propose a water-based color tablet.

[0006] In order to achieve the above object, the present invention adopts the following technical solutions:

[0007] A water-based color sheet comprises the following components in percentage by weight: 50-60 parts of acrylic resin, 30-40 parts of butyl rubber, 30-40 parts of pigment, 5-10 parts of dispersant, 8-16 parts of aluminum hydroxide, 10-20 parts of zinc oxide, 15-25 parts of silicon carbide, 6-10 parts of ointment and 3-7 parts of cement.

[0008] As a further description of the above technical solution:

[0009] The dispersant includes anionic dispersants and / or nonionic dispersants.

[0010] As a further description of the above technical solution:

[0011] Any one of the colors of the pigment may be a combination pigment of multiple colors.

[0012] The method for preparing a water-based color film specifically comprises the following steps:

[0013] S1, putting acrylic resin and butyl rubber into a hot melt pot to melt and stir so that the acrylic resin and butyl rubber can be fully mixed together;

[0014] S2. Add dispersant, aluminum hydroxide and silicon carbide during stirring, and continue heating to fully mix them;

[0015] S3, adding the cement and ointment again and stirring and mixing;

[0016] S4, adding water to the mixed materials, and putting them into a kneading machine for thorough kneading;

[0017] S5. Continue to heat until the acrylic resin and butyl rubber are completely dissolved and mixed with the pigment and then pour out;

[0018] S6, putting the fused material into a ball mill for grinding;

[0019] S7, pouring out the fused material to cool it, and drying it with a dryer to solidify it;

[0020] S8. When the material solidifies, use a slicer to slice it so that it can reach a suitable size and finally reach a qualified color slice.

[0021] As a further description of the above technical solution:

[0022] In S1, the stirring time is controlled to be 30-40 minutes, the heating time is controlled to be the same as the stirring time, and the heating temperature is controlled to be maintained at 80-90°C.

[0023] As a further description of the above technical solution:

[0024] In S2-S3, the mixing time is controlled to be 20 min and 30 min respectively.

[0025] As a further description of the above technical solution:

[0026] In S5, the temperature is controlled to be 100-120°C.

[0027] As a further description of the above technical solution:

[0028] In S6, the grinding fineness of the material is maintained below 5UM.

[0029] In summary, due to the adoption of the above technical solution, the beneficial effects of the present invention are:

[0030] The water-based color tablets of the present invention are water-based flaky solid pre-dispersed pigments made by using high-grade water-based solid acrylic resin as a carrier, which can be dissolved in various water-based coatings. By adding auxiliary materials such as aluminum hydroxide and silicon carbide, the acid and alkali resistance of the water-based color tablets can be effectively improved. By adding auxiliary materials such as clay and ointment, the brittleness of the water-based color tablets after drying can be reduced, so that the water-based color tablets will not be fragile in a dry environment, and will not cause trouble for the removal and use of the water-based color tablets in the later stage. DETAILED DESCRIPTION

[0031] The following will be combined with the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0032] The present invention provides a technical solution:

[0033] Example 1

[0034] A water-based color sheet, comprising the following components in percentage by weight: 50 parts of acrylic resin, 30 parts of butyl rubber, 30 parts of pigment, 5 parts of dispersant, 8 parts of aluminum hydroxide, 10 parts of zinc oxide, 15 parts of silicon carbide, 6 parts of ointment and 3 parts of cement, wherein the dispersant comprises an anionic dispersant and / or a non-ionic dispersant, and the pigment is any one of any colors and can be a combination pigment of multiple colors.

[0035] A method for preparing a water-based color film, characterized in that it specifically comprises the following steps:

[0036] S1. Put the acrylic resin and butyl rubber into a hot melt pot for melting and stirring so that the acrylic resin and butyl rubber can be fully mixed together, control the stirring time to be 30 minutes, control the heating time to be the same as the stirring time, and control the heating temperature to be maintained at 80° C.;

[0037] S2. Add dispersant, aluminum hydroxide and silicon carbide during stirring, and continue heating to fully mix them;

[0038] S3, adding the cement and ointment again and stirring and mixing, wherein the mixing time in S2-S3 is controlled to be 20 min and 30 min respectively;

[0039] S4, adding water to the mixed materials, and putting them into a kneading machine for thorough kneading;

[0040] S5, continue to raise the temperature until the acrylic resin and butyl rubber are completely dissolved and mixed with the pigment, then pour it out, wherein the temperature in S5 is controlled to be 100° C.;

[0041] S6, putting the fused material into a ball mill for grinding, wherein in S6, the grinding fineness of the material is maintained below 5UM;

[0042] S7, pouring out the fused material to cool it, and drying it with a dryer to solidify it;

[0043] S8. When the material solidifies, use a slicer to slice it so that it can reach a suitable size and finally reach a qualified color slice.

[0044] Example 2

[0045] A water-based color tablet, comprising the following components in percentage by weight: 50-60 parts of acrylic resin, 32 parts of butyl rubber, 32 parts of pigment, 8 parts of dispersant, 12 parts of aluminum hydroxide, 15 parts of zinc oxide, 20 parts of silicon carbide, 8 parts of ointment and 5 parts of cement, wherein the dispersant comprises anionic dispersant and / or nonionic dispersant, and the pigment is any one of any colors and can be a combination pigment of multiple colors.

[0046] A method for preparing a water-based color film, characterized in that it specifically comprises the following steps:

[0047] S1. Put the acrylic resin and butyl rubber into a hot melt pot to melt and stir them so that the acrylic resin and butyl rubber can be fully mixed together, control the stirring time to be 35 minutes, control the heating time to be the same as the stirring time, and control the heating temperature to be maintained at 85° C.;

[0048] S2. Add dispersant, aluminum hydroxide and silicon carbide during stirring, and continue heating to fully mix them;

[0049] S3, adding the cement and ointment again and stirring and mixing, wherein the mixing time in S2-S3 is controlled to be 20 min and 30 min respectively;

[0050] S4, adding water to the mixed materials, and putting them into a kneading machine for thorough kneading;

[0051] S5, continue to heat until the acrylic resin and butyl rubber are completely dissolved and mixed with the pigment, then pour out, wherein the temperature in S5 is controlled to be 110° C.;

[0052] S6, putting the fused material into a ball mill for grinding, wherein in S6, the grinding fineness of the material is maintained below 5UM;

[0053] S7, pouring out the fused material to cool it, and drying it with a dryer to solidify it;

[0054] S8. When the material solidifies, use a slicer to slice it so that it can reach a suitable size and finally reach a qualified color slice.

[0055] Example 3

[0056] A water-based color sheet, comprising the following components in percentage by weight: 60 parts of acrylic resin, 40 parts of butyl rubber, 40 parts of pigment, 10 parts of dispersant, 16 parts of aluminum hydroxide, 20 parts of zinc oxide, 25 parts of silicon carbide, 10 parts of oil and 7 parts of cement, wherein the dispersant comprises anionic dispersant and / or nonionic dispersant, and the pigment is any one of any colors and can be a combination pigment of multiple colors.

[0057] A method for preparing a water-based color film, characterized in that it specifically comprises the following steps:

[0058] S1. Put the acrylic resin and butyl rubber into a hot melt pot to melt and stir them so that the acrylic resin and butyl rubber can be fully mixed together, control the stirring time to be 40 minutes, control the heating time to be the same as the stirring time, and control the heating temperature to be maintained at 90° C.;

[0059] S2. Add dispersant, aluminum hydroxide and silicon carbide during stirring, and continue heating to fully mix them;

[0060] S3, adding the cement and ointment again and stirring and mixing, wherein the mixing time in S2-S3 is controlled to be 20 min and 30 min respectively;

[0061] S4, adding water to the mixed materials, and putting them into a kneading machine for thorough kneading;

[0062] S5, continue to heat until the acrylic resin and butyl rubber are completely dissolved and mixed with the pigment, then pour out, wherein the temperature in S5 is controlled to be 120° C.;

[0063] S6, putting the fused material into a ball mill for grinding, wherein in S6, the grinding fineness of the material is maintained below 5UM;

[0064] S7, pouring out the fused material to cool it, and drying it with a dryer to solidify it;

[0065] S8. When the material solidifies, use a slicer to slice it so that it can reach a suitable size and finally reach a qualified color slice.

[0066] The above description is only a preferred specific implementation manner of the present invention, but the protection scope of the present invention is not limited thereto. Any technician familiar with the technical field can make equivalent replacements or changes according to the technical scheme and inventive concept of the present invention within the technical scope disclosed by the present invention, which should be covered by the protection scope of the present invention.

Claims

1. A water-based color film, characterized in that: The color sheet comprises the following components in percentage by weight: 50-60 parts of acrylic resin, 30-40 parts of butyl rubber, 30-40 parts of pigment, 5-10 parts of dispersant, 8-16 parts of aluminum hydroxide, 10-20 parts of zinc oxide, 15-25 parts of silicon carbide, 6-10 parts of ointment and 3-7 parts of cement.

2. A water-based color film according to claim 1, characterized in that: The dispersant includes anionic dispersants and / or nonionic dispersants.

3. A water-based color film according to claim 1, characterized in that: Any one of the colors of the pigment may be a combination pigment of multiple colors.

4. A method for preparing a water-based color film according to any one of claims 1 to 3, characterized in that: The specific steps include: S1, putting acrylic resin and butyl rubber into a hot melt pot to melt and stir so that the acrylic resin and butyl rubber can be fully mixed together; S2. Add dispersant, aluminum hydroxide and silicon carbide during stirring, and continue heating to fully mix them; S3, adding the cement and ointment again and stirring and mixing; S4, adding water to the mixed materials, and putting them into a kneading machine for thorough kneading; S5. Continue to heat until the acrylic resin and butyl rubber are completely dissolved and mixed with the pigment and then pour out; S6, putting the fused material into a ball mill for grinding; S7, pouring out the fused material to cool it, and drying it with a dryer to solidify it; S8. When the material solidifies, use a slicer to slice it so that it can reach a suitable size and finally reach a qualified color slice.

5. A water-based color film according to claim 4, characterized in that: In S1, the stirring time is controlled to be 30-40 minutes, the heating time is controlled to be the same as the stirring time, and the heating temperature is controlled to be maintained at 80-90°C.

6. A water-based color film according to claim 4, characterized in that: In S2-S3, the mixing time is controlled to be 20 min and 30 min respectively.

7. A water-based color film according to claim 4, characterized in that: In S5, the temperature is controlled to be 100-120°C.

8. A water-based color film according to claim 4, characterized in that: In S6, the grinding fineness of the material is maintained below 5UM.