Preparation method and application method of non-high-temperature pyrolysis metal monatomic catalyst

A three-dimensional porous non-high-temperature pyrolysis metal single-atom catalyst was prepared by a solvothermal method under low-temperature conditions, which solved the problems of low efficiency and secondary pollution of traditional catalysts and achieved efficient and stable degradation of organic pollutants.

CN122076513APending Publication Date: 2026-05-26HENAN AGRICULTURAL UNIVERSITY
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Patent Information

Application Number
CN202610139301.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-01-30
Publication Date
2026-05-26

AI Technical Summary

Technical Problem

Traditional heterogeneous catalysts suffer from problems such as low atom utilization, insufficient exposure of active sites, and easy precipitation of metal ions when treating recalcitrant organic pollutants, resulting in low catalytic efficiency and easy secondary pollution. High-temperature pyrolysis preparation methods are also prone to metal atom aggregation and support structure collapse.

Method used

A non-high-temperature pyrolysis metal single-atom catalyst was prepared under low-temperature conditions using a solvothermal method. Amide solvents were used as dispersants, reducing agents, and nitrogen sources, combined with graphene oxide and transition metal compounds to form a three-dimensional porous non-high-temperature pyrolysis metal single-atom catalyst, thus avoiding metal atom aggregation and support structure collapse caused by high-temperature pyrolysis.

Benefits of technology

This catalyst achieves high atom utilization and good stability, exhibits high efficiency in catalyzing the degradation of organic pollutants by persulfate, and avoids high energy consumption and secondary pollution. It also features a three-dimensional porous structure that provides abundant mass transfer channels and high catalytic activity.

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Abstract

The invention discloses a preparation method and application method of a non-high-temperature pyrolysis metal monatomic catalyst, and the preparation method comprises the following steps: dispersion: respectively dispersing graphene oxide and a transition metal compound in an amide solvent to obtain a graphene oxide dispersion liquid and a metal precursor dispersion liquid; mixing: mixing the graphene oxide dispersion liquid with the metal precursor dispersion liquid, and carrying out homogenization treatment under physical field auxiliary treatment to obtain a mixed precursor suspension liquid; solvothermal: placing the mixed precursor suspension in a closed reaction container, carrying out solvothermal reaction under self-generated pressure and heating conditions, and cooling after the reaction is finished to obtain an intermediate product containing metal-graphene hydrogel; and purification and drying: washing and purifying the intermediate product by using a polar solvent, and then carrying out vacuum drying to obtain the non-high-temperature pyrolysis metal monatomic catalyst, and grinding: grinding the obtained non-high-temperature pyrolysis metal monatomic catalyst into powder.
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