Grain-oriented electrical steel sheet

By eliminating chromium compounds from the insulating film of directional electromagnetic steel plates, using a combination of phosphate and colloidal silica, and adjusting the structure of the insulating film using nuclear magnetic resonance, the problem of increased phosphorus leaching was solved, achieving excellent moisture resistance and stable insulation performance.

CN122161957APending Publication Date: 2026-06-05NIPPON STEEL CORPORATION
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Patent Information

Application Number
CN202580005788.1
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2024-01-30
Filing Date
2025-01-30
Publication Date
2026-06-05

AI Technical Summary

Technical Problem

In the prior art, when directional electromagnetic steel sheets are in the absence of chromate-free insulating film, the amount of phosphorus leaching increases under long-term storage and high temperature and humidity conditions, leading to adhesion between rolls and difficulty in unwinding, and failing to meet the requirements for moisture resistance and phosphorus leaching.

Method used

By eliminating chromium compounds from the insulating film, using a specific ratio of phosphate and colloidal silica, and combining nuclear magnetic resonance (31P-NMR) to adjust the structure of the insulating film, the peak area ratio of the Q0 structure is controlled, thereby optimizing the moisture resistance and phosphorus leaching of the insulating film.

Benefits of technology

It achieves low phosphorus leaching during long-term storage under high temperature and humidity conditions, excellent moisture resistance, avoids adhesion problems between rolls, and ensures the stability and performance of the insulating film.

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Abstract

The insulating coating of the grain-oriented electrical steel sheet does not contain a chromium compound but contains a phosphate, and when a 31P-NMR spectrum obtained by measuring the insulating coating by nuclear magnetic resonance is subjected to Gaussian fitting within the range of 16-90 ppm, the ratio of the peak area of the Q0 structure to the total peak area is more than 0% but 10% or less.
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