A flexible crystal and optical waveguide material, and a preparation method and application thereof in high-pressure color-changing materials

Flexible crystals were prepared by reacting phenoxazine, dimethyl 5-bromoisophthalate, potassium carbonate, and Pd[P(t-Bu)3]2, which solved the problems of brittleness and single color change in organic crystal materials and achieved flexible and multi-color changing properties, making them suitable for optical waveguides and wearable devices.

CN122404249APending Publication Date: 2026-07-17ZHEJIANG UNIV OF TECH
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ZHEJIANG UNIV OF TECH
Filing Date
2026-05-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing organic crystal materials have several drawbacks in flexible electronics applications, including brittleness and fragility, difficulty in achieving flexibility and high crystallinity, induction of only a single emission color change under a single external stimulus, easy quenching of light emission in pressure-sensitive materials, and a lack of clear structure-property relationships.

Method used

Optical waveguide materials were prepared by using phenoxazine, dimethyl 5-bromoisophthalate, potassium carbonate and Pd[P(t-Bu)3]2 as raw materials, through heating reaction, extraction, drying and column chromatography separation and purification. Subsequently, a flexible crystal was grown by dissolving and adding a poor solvent and allowing it to stand, thus realizing the flexibility and high-pressure color-changing properties of the material.

Benefits of technology

The prepared flexible crystal material has good flexibility, is not easy to break, and can achieve multicolor changes under high pressure. It is suitable for optical waveguides and flexible wearable devices, enhancing its application potential in fields such as information encryption.

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Abstract

本发明提供了一种柔性晶体及光波导材料及其制备方法和在高压变色材料中的应用,属于柔性晶体光波导材料技术领域。本发明材料分子结构是以吩噁嗪为核心,5‑溴间苯二甲酸二甲酯为修饰基团进行构筑的,其发光波长位于绿光波段,本发明具有合成简单、晶体柔性好,具有良好的光波导性质,这使得该物质在柔性光电子领域上有着巨大应用潜力。同时,可以作为优异的力刺激响应型变色材料,可用于压力检测、传感器、信息存储器件、防伪材料、记忆材料或生物探针。
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