A method and system for on-line monitoring of material behavior in lead-bismuth fast reactor

By using a three-electrode system electrochemical impedance spectroscopy probe and equivalent circuit model in a lead-bismuth fast reactor, online, continuous, non-destructive, and quantitative monitoring of the thickness of multilayer oxide films on the surface of structural materials in the lead-bismuth fast reactor was achieved. This solves the problem of insufficient early warning of corrosion status in existing technologies and improves the accuracy and predictive ability of corrosion status assessment.

CN122409772APending Publication Date: 2026-07-17HEFEI INSTITUTE OF PHYSICAL SCIENCE CHINESE ACADEMY OF SCIENCES
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HEFEI INSTITUTE OF PHYSICAL SCIENCE CHINESE ACADEMY OF SCIENCES
Filing Date
2026-06-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to achieve online, continuous, non-destructive, and quantitative monitoring of the thickness of multilayer oxide films on the surface of lead-bismuth fast reactor structural materials, resulting in insufficient early warning of corrosion status.

Method used

An electrochemical impedance spectroscopy probe with an internally integrated three-electrode system is used to collect electrochemical impedance spectroscopy data by applying sinusoidal potential perturbation. Combined with equivalent circuit model fitting and dielectric constant estimation, the oxide film thickness can be quantitatively estimated, and corrosion status can be predicted based on the electrochemical impedance spectroscopy data.

Benefits of technology

This technology enables online, continuous, non-destructive, and quantitative monitoring of the thickness of multilayer oxide films on the surface of lead-bismuth fast reactor materials. It can provide timely early warning of material corrosion status and improve the accuracy and predictive ability of corrosion status assessment.

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Abstract

本发明公开了一种铅铋快堆材料服役行为在线监测方法和系统,涉及核反应堆材料腐蚀在线监测技术领域,具体包括:将内部集成有三电极体系的电化学阻抗谱探针暴露于液态铅铋环境中,施加正弦电位扰动并采集电化学阻抗谱数据,采用等效电路模型拟合得到常相位元件参数和氧化膜电阻,换算等效电容,结合多层物相组成确定有效介电常数范围,并基于等效电容、有效介电常数范围和工作电极的有效暴露面积估算氧化膜厚度范围,旨在实现铅铋快堆材料服役过程中氧化膜厚度的在线定量监测和腐蚀状态预警。
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