Modification system of carbon-based purification material

Abstract

The utility model discloses a modification system for a carbon-based purification material. The modification system comprises a tower body and an inner cavity, a feeding hole and a discharging hole are formed in the tower body. The inner cavity comprises an upper feeding chamber, a middle modification chamber and a lower discharging chamber. A modified gas inlet mechanism is arranged at the upper part of the tower body at the lower discharge chamber, and a modified gas exhaust mechanism is arranged at the upper part of the tower body at the middle modification chamber. The upper material arrangement device, the lower material arrangement device, the modified gas inlet mechanism, the modified gas exhaust mechanism and the like are ingeniously arranged in the inner cavity of the tower body, so that uniform and temperature oxidation modification of a carbon-based material can be realized by adopting low-cost oxidants such as air, and the equipment and production input cost is low. In addition, the device also has the characteristics of simple structure, easiness in operation, low equipment investment cost, simplicity in maintenance, good oxidation modification effect, stable modification effect, high practicability and the like.

Description

Technical Field

[0001] The utility model relates to the production and processing of carbon-based purification materials, in particular to a modification system of carbon-based purification materials, and belongs to the technical field of carbon-based purification material production and processing equipment. Background Art

[0002] With the increasing requirements of environmental protection in my country, more and more types of air pollutants are being controlled, and emission standards are becoming more stringent, and the demand for multi-pollutant treatment of industrial flue gas is becoming more urgent. The activated carbon flue gas purification technology with carbon-based materials as the core has been rapidly applied and promoted due to its advantages of high pollutant removal efficiency, no secondary pollution, simple operation, low operating cost, and resource-based by-products. With the rapid promotion of activated carbon flue gas purification technology, the market demand for flue gas purification carbon-based material products has grown rapidly, and the requirements for performance indicators have also been continuously improved. At present, the quality of flue gas purification carbon-based material products still has the problems of low desulfurization and denitrification performance and poor stability, which makes it difficult to adapt to higher flue gas purification requirements, and also directly leads to high operating costs of activated carbon flue gas purification technology; in addition, the technology of flue gas purification carbon-based material preparation industry is relatively backward, the level of automation of production equipment is low, large-scale equipment is rarely put into operation, and there is a lack of unified process equipment standards, which directly leads to low production efficiency and production capacity, and also leads to high production costs. The above problems will affect the quality assurance of carbon-based materials, which will in turn restrict the further development of activated carbon flue gas purification technology. In the prior art, the desulfurization efficiency of carbon-based materials is usually improved by adjusting the raw material formula, but the improvement effect is limited. Because the adjustment of the raw material formula requires a better quality coal, this usually easily leads to increased costs. Studies have shown that it is feasible to modify carbon-based materials to improve their desulfurization efficiency, but the existing activated carbon modification method generally uses a liquid oxidant for oxidation modification. For example, CN113117642B discloses the use of at least one of a nitric acid solution and a hydrogen peroxide solution to impregnate the activated carbon, which requires a large amount of modifiers and has a high investment cost. There are few records of the use of oxidizing gases (such as air) to modify activated carbon in the prior art, and there is also a lack of gas-based modification equipment with low investment costs and stable modification effects. Utility Model Content

[0003] In view of the problems in the prior art such as high production cost of high-quality carbon-based modified materials and unstable modification effect due to the lack of equipment with low investment cost for gas-based modification of carbon-based materials, the utility model provides a modification system for carbon-based purification materials. The system is a gas-based modification system that can use low-cost oxidants such as air to achieve oxidative modification of carbon-based materials. In addition, through the built-in upper and lower feeders, uniform convective contact between carbon-based materials and oxidative modification gases can be achieved, thereby improving the uniformity and stability of the modification effect.

[0004] In order to achieve the above technical objectives, the technical solutions adopted by the present utility model are as follows:

[0005] A modification system for carbon-based purification materials, the system comprising a tower body and an inner cavity. A feed port is provided at the top of the tower body, and a discharge port is provided at the bottom of the tower body. The inner cavity is divided into an upper feed chamber, a modified middle chamber, and a discharge lower chamber by an upper material collector and a lower material collector. A modified gas inlet mechanism is provided at the upper part of the tower body at the discharge lower chamber, and a modified gas exhaust mechanism is provided at the upper part of the tower body at the modified middle chamber.

[0006] Preferably, the upper material collector comprises an upper sealing plate and an upper material passage. The upper sealing plate is horizontally arranged at the junction of the upper feeding chamber and the modified middle chamber, and the upper sealing plate is connected to the tower body on all sides. A plurality of upper material passages are installed on the upper sealing plate and connect the upper feeding chamber and the modified middle chamber.

[0007] Preferably, the plurality of upper material passing tubes are evenly distributed on the upper sealing plate, specifically: the center point of the upper sealing plate is the center of the central upper material passing tube, and then six upper material passing tubes are arranged around the central upper material passing tube in a regular hexagonal distribution manner, and then six upper material passing tubes are arranged around each upper material passing tube in the regular hexagon in a regular hexagonal distribution manner of the same size, and so on and so forth, gradually spreading outward. That is, the radial spacing between any two adjacent upper material passing tubes is the same.

[0008] Preferably, the diameter of the lumen of the upper feed pipe is 20 to 300 mm, preferably 30 to 200 mm, and more preferably 50 to 100 mm.

[0009] Preferably, the radial spacing between any two adjacent upper feeding tubes (referring to the spacing between the tube walls in the line connecting the centers of the two upper feeding tubes) is 0-100 mm, preferably 3-50 mm, and more preferably 5-20 mm.

[0010] Preferably, the upper end of the upper material passage penetrates the upper sealing plate and is flush with the upper surface of the upper sealing plate, and the lower end of the upper material passage penetrates the upper sealing plate and extends downward into the modified middle chamber. Preferably, the depth to which the lower end of the upper material passage penetrates the upper sealing plate and extends downward is 1 to 30 cm, preferably 3 to 20 cm, and more preferably 5 to 15 cm.

[0011] Preferably, the lower material collector comprises a lower sealing plate and a lower material passing pipe. The lower sealing plate is horizontally arranged at the junction of the discharge lower chamber and the modified middle chamber, and the surrounding of the lower sealing plate is connected to the tower body. A plurality of the lower material passing pipes are installed on the lower sealing plate and connect the discharge lower chamber and the modified middle chamber.

[0012] Preferably, the plurality of lower feed pipes are evenly distributed on the lower sealing plate, specifically: the center point of the lower sealing plate is the center of the central lower feed pipe, and then six lower feed pipes are arranged around the central lower feed pipe in a regular hexagonal distribution manner, and then six lower feed pipes are arranged around each lower feed pipe in the regular hexagon in a regular hexagonal distribution manner of the same size, and so on and so forth, gradually spreading outward. That is, the radial spacing between any two adjacent lower feed pipes is the same.

[0013] Preferably, the lumen diameter of the lower feed pipe is 20 to 300 mm, preferably 30 to 200 mm, and more preferably 50 to 100 mm.

[0014] The radial spacing between any two adjacent lower feed tubes (referring to the spacing between the tube walls in the line connecting the centers of the two lower feed tubes) is 0-100 mm, preferably 3-50 mm, and more preferably 5-20 mm.

[0015] Preferably, the upper end of the lower feed pipe is flush with the upper surface of the lower sealing plate after passing through the lower sealing plate, and the lower end of the lower feed pipe extends downward into the lower discharge chamber after passing through the lower sealing plate. Preferably, the depth of the lower end of the lower feed pipe extending downward after passing through the lower sealing plate is 1 to 30 cm, preferably 3 to 20 cm, and more preferably 5 to 15 cm.

[0016] Preferably, the lower discharge chamber is designed with a constricted opening from top to bottom, and a material leveling hopper is arranged in the lower discharge chamber. A plurality of material leveling hoppers are evenly distributed in the lower discharge chamber and connected to each other to form a horizontal grid structure.

[0017] Preferably, multiple layers of material hoppers with a masonry structure are arranged from top to bottom in the lower discharge chamber, and the number of material hoppers in the upper masonry structure is 1.5 to 3.5 times, preferably 1.8 to 3 times, the number of material hoppers in the lower masonry structure.

[0018] Preferably, the modified gas intake mechanism includes an intake main pipe and an intake branch pipe. A plurality of the intake branch pipes are evenly distributed around the tower body, and the exhaust end of the intake branch pipe is connected to the lower discharge chamber at a position close to the lower surface of the lower material collector, and the intake ends of the intake branch pipes are connected to the intake main pipe. Preferably, the intake branch pipe is tilted outside the tower body in a manner that the airflow flows obliquely downward, and an intake grille is provided on the tower body where the intake branch pipe is connected to the lower discharge chamber.

[0019] Preferably, the modified gas exhaust mechanism includes an exhaust main pipe and an exhaust branch pipe. A plurality of the exhaust branch pipes are evenly distributed around the tower body, and the exhaust end of the exhaust branch pipe is connected to the modified middle chamber at a position close to the lower surface of the upper material collector, and the air inlet end of the exhaust branch pipe is connected to the exhaust main pipe. Preferably, the exhaust branch pipe is tilted outside the tower body in a manner that the airflow flows obliquely upward, and an exhaust grille is provided on the tower body where the exhaust branch pipe is connected to the modified middle chamber.

[0020] Preferably, explosion-proof valves are independently provided on the air intake main pipe and the exhaust main pipe.

[0021] Preferably, a water cooling jacket is provided on the outer side of the tower body corresponding to the lower discharge chamber, a cooling water inlet is provided at the lower part of the water cooling jacket, and a cooling water outlet is provided at the upper part of the water cooling jacket.

[0022] Preferably, one or more temperature sensor interfaces are independently arranged on the tower bodies corresponding to the upper feeding chamber, the middle modification chamber and the lower discharging chamber.

[0023] Preferably, the feed port and the discharge port are independently provided with air lock rotary valves. An inspection door is also provided on the tower body corresponding to the modified middle chamber.

[0024] In the utility model, the inner cavity of the tower body is divided from top to bottom into an upper feeding chamber, a modified middle chamber and a discharging lower chamber by an upper feeder and a lower feeder, wherein a feed port is provided on the upper feeding chamber for receiving carbon-based materials added from the feed port, and the carbon-based materials are buffered in the upper feeding chamber, and then can be uniformly dropped into the modified middle chamber through the upper feeder, that is, the upper feeding chamber is provided to buffer the carbon-based materials and fully disperse them before passing through the upper feeder, thereby ensuring the consistency of the carbon-based materials from various regions through the upper feeder to ensure the uniformity and stability of the drop. The carbon-based materials in the modified middle chamber flow uniformly from top to bottom, and the oxygen-containing modified gas (such as air) flows from bottom to top, and the carbon-based materials are oxidatively modified in a high temperature environment (such as 400~700℃, which can be achieved by additional heating or the modified gas itself has a high temperature) to increase the specific oxygen-containing functional groups on the surface of the carbon-based materials, thereby improving their adsorption and purification performance. Furthermore, uniform material flow and airflow in the modified chamber are important links in the modification effect. Uniform logistics and airflow are conducive to uniform modification, and can also prevent the oxidation transition caused by uneven modification and the subsequent spontaneous combustion caused by excessive temperature. Therefore, a lower feeder is provided to control the discharge speed of the descending carbon-based material in the modified chamber to achieve uniform discharge. That is to say, uniform feeding is achieved through the upper feeder, and uniform discharging is achieved through the lower feeder, thereby effectively ensuring the uniformity of the material flow rate during the oxidation modification process, which is beneficial to ensuring and promoting the stability and uniformity of the modification effect.

[0025] In the present invention, in order to meet the uniformity of the material in and out of the chamber during the modification, in the preferred embodiment of the present invention, the upper and lower feeders are basically the same in structure, and both include a sealing plate and a feed pipe (i.e., an upper sealing plate, a lower sealing plate, an upper feed pipe, and a lower feed pipe). Taking the above feeder as an example, in the upper sealing plate, an upper feed pipe is provided at the center thereof, which is called the central upper feed pipe. On the outer side of the central upper feed pipe, a plurality of upper feed pipes are arranged in a regular hexagonal arrangement manner (i.e., the centers of all upper feed pipes in the same layer are connected in sequence to form a hexagon, the closer to the outside, the larger the regular hexagon, and the spacing between any two adjacent layers of regular hexagons is the same) until it is spread over the entire upper sealing plate, that is, the radial spacing between any two adjacent upper feed pipes is the same. That is, through the design of the upper and lower feeders with special structural designs, the uniform downward movement of carbon-based materials in the oxidation modification area is achieved, which is conducive to promoting the uniformity of the modification effect.

[0026] In the utility model, in order to make the modified gas evenly distributed, gas inlets and outlets are respectively arranged on the outer side of the tower body at the lower end of the lower and upper bulkers. The gas inlets and outlets are designed to be symmetrically arranged on at least two opposite side walls of the tower body, and can also be evenly distributed around the outer wall of the entire tower body. The main airflow pipeline (including the air intake main pipe and the exhaust main pipe) is connected to the inlet and outlet through multiple airflow branches (including the air intake branch pipe and the exhaust branch pipe), and is provided with a high-temperature gasket and fixed to the tower body by bolts. In order to prevent the beneficial large particles from flowing out of the pipeline, a grid with a certain slope is set at the gas inlet and outlet. In addition, the feed pipes (including the upper feed pipe and the lower feed pipe) extend downward from the sealing plate to a certain length. After the material flows out of the feed pipe, an empty area will be formed between the feed pipe outlet and the sealing plate, which is conducive to the formation of an air chamber. The modified gas enters the oxidation zone from the air chamber at the lower end of the lower sealing plate through the lower feed pipe and penetrates the material layer, and then converges in the air chamber at the lower end of the upper sealing plate, and then flows out through the gas outlet. This is conducive to the gas flowing into the lower feed pipes of all the lower feeders, and then evenly distributed in the oxidation zone, so as to improve the uniformity of contact between the modified gas and the carbon-based material.

[0027] In the utility model, the lower discharge chamber is a top-down tapered design, and a material hopper is arranged in the lower discharge chamber. A plurality of material hoppers are evenly distributed in the lower discharge chamber and are connected to each other to form a horizontal lattice structure. In the lower discharge chamber, multi-layer lattice structure material hoppers are arranged from top to bottom, and the number of material hoppers in the upper lattice structure is 1.5 to 3.5 times the number of material hoppers in the lower lattice structure (preferably 2 times, and the number of material hoppers in the lowest layer is 1, that is, all material hoppers form an inverted pyramid distribution as a whole). The design of multi-layer lattice structure material hoppers further improves the uniformity of carbon-based material discharge, which is conducive to ensuring the uniformity of carbon-based materials flowing downward in the entire tower body inner cavity.

[0028] In the utility model, multiple temperature sensor interfaces are provided on the tower body, and temperature sensors of different lengths can be installed to track the temperature changes in different areas of the oxidation zone. If there is a sharp increase in local temperature, corresponding measures can be taken to solve it. In addition, a water cooling jacket is provided outside the constriction section of the lower chamber of the discharge, and the material is quickly cooled by circulating cooling water.

[0029] Compared with the prior art, the beneficial technical effects of the utility model are as follows:

[0030] 1: The modification system of the carbon-based purification material of the utility model can realize uniform and temperature oxidation modification of the carbon-based material by using low-cost oxidants such as air, by cleverly arranging an upper material loader, a lower material loader, a modified gas intake mechanism and a modified gas exhaust mechanism in the inner cavity of the tower body, and the equipment and production investment costs are low.

[0031] 2: The modification system of the carbon-based purification material of the utility model also has the characteristics of simple structure, easy operation, low equipment investment cost, simple maintenance, good oxidation modification effect, stable modification effect, and strong practicality. BRIEF DESCRIPTION OF THE DRAWINGS

[0032] Figure 1 It is a front view structural schematic diagram of the system of the utility model.

[0033] Figure 2 It is a side structural schematic diagram of the system of the utility model.

[0034] Figure 3 for Figure 1 Schematic diagram of the AA cross-section structure.

[0035] Figure 4 for Figure 1 Schematic diagram of the BB cross-section structure.

[0036] Figure 5 for Figure 1 Schematic diagram of the CC cross-section structure.

[0037] Figure 6 for Figure 2 Enlarged structural diagram at D in the middle.

[0038] Figure numerals: 1: tower body; 101: feed port; 102: discharge port; 103: temperature sensor interface; 104: inspection door; 2: inner cavity; 201: upper feed chamber; 202: middle modified chamber; 203: lower discharge chamber; 3: upper material handler; 301: upper sealing plate; 302: upper material passage; 4: lower material handler; 401: lower sealing plate; 402: lower material passage; 5: modified gas intake mechanism; 501: intake main pipe; 502: intake branch pipe; 6: modified gas exhaust mechanism; 601: exhaust main pipe; 602: exhaust branch pipe; 7: material hopper; 8: water-cooling jacket; 801: cooling water inlet; 802: cooling water outlet. DETAILED DESCRIPTION

[0039] The technical solution of the utility model is illustrated below, and the scope of protection requested for the utility model includes but is not limited to the following embodiments.

[0040] A modification system for carbon-based purification materials, the system comprises a tower body 1 and an inner cavity 2. A feed port 101 is provided at the top of the tower body 1, and a discharge port 102 is provided at the bottom of the tower body 1. The inner cavity 2 is divided into an upper feed chamber 201, a modified middle chamber 202, and a discharge lower chamber 203 by an upper material collector 3 and a lower material collector 4. A modified gas inlet mechanism 5 is provided at the upper part of the tower body 1 at the discharge lower chamber 203, and a modified gas exhaust mechanism 6 is provided at the upper part of the tower body 1 at the modified middle chamber 202.

[0041] Preferably, the upper material collector 3 includes an upper sealing plate 301 and an upper material passage 302. The upper sealing plate 301 is horizontally arranged at the junction of the feed upper chamber 201 and the modified middle chamber 202, and the upper sealing plate 301 is connected to the tower body 1 around the periphery. A plurality of upper material passages 302 are installed on the upper sealing plate 301 and connect the feed upper chamber 201 and the modified middle chamber 202.

[0042] Preferably, the plurality of upper material pipes 302 are evenly distributed on the upper sealing plate 301, specifically: the center point of the upper sealing plate 301 is the center of the central upper material pipe 302, and then six upper material pipes 302 are arranged around the central upper material pipe 302 in a regular hexagonal distribution manner, and then six upper material pipes 302 of the same size are arranged around each upper material pipe 302 in the regular hexagonal distribution manner, and so on and so forth, gradually spreading outward. That is, the radial spacing between any two adjacent upper material pipes 302 is the same.

[0043] Preferably, the diameter of the lumen of the upper feed pipe 302 is 20-300 mm, preferably 30-200 mm, and more preferably 50-100 mm.

[0044] Preferably, the radial spacing between any two adjacent upper feed pipes 302 is 0-100 mm, preferably 3-50 mm, and more preferably 5-20 mm.

[0045] Preferably, the upper end of the upper material tube 302 penetrates the upper sealing plate 301 and is flush with the upper surface of the upper sealing plate 301, and the lower end of the upper material tube 302 penetrates the upper sealing plate 301 and extends downward into the modified middle chamber 202. Preferably, the lower end of the upper material tube 302 penetrates the upper sealing plate 301 and extends downward to a depth of 1 to 30 cm, preferably 3 to 20 cm, and more preferably 5 to 15 cm.

[0046] Preferably, the lower material collector 4 includes a lower sealing plate 401 and a lower material pipe 402. The lower sealing plate 401 is horizontally arranged at the junction of the discharge lower chamber 203 and the modified middle chamber 202, and the surrounding of the lower sealing plate 401 is connected to the tower body 1. A plurality of lower material pipes 402 are installed on the lower sealing plate 401 and connect the discharge lower chamber 203 and the modified middle chamber 202.

[0047] Preferably, the plurality of lower feed pipes 402 are evenly distributed on the lower sealing plate 401, specifically: the center point of the lower sealing plate 401 is the center of the central lower feed pipe 402, and then six lower feed pipes 402 are arranged around the central lower feed pipe 402 in a regular hexagonal distribution manner, and then six lower feed pipes 402 are arranged around each lower feed pipe 402 in the regular hexagon in a regular hexagonal distribution manner of the same size, and so on and so forth, gradually spreading outward. That is, the radial spacing between any two adjacent lower feed pipes 402 is the same.

[0048] Preferably, the diameter of the lumen of the lower feed pipe 402 is 20 to 300 mm, preferably 30 to 200 mm, and more preferably 50 to 100 mm.

[0049] The radial spacing between any two adjacent lower feed pipes 402 is 0-100 mm, preferably 3-50 mm, and more preferably 5-20 mm.

[0050] Preferably, the upper end of the lower material pipe 402 passes through the lower sealing plate 401 and is flush with the upper surface of the lower sealing plate 401, and the lower end of the lower material pipe 402 passes through the lower sealing plate 401 and extends downward into the lower discharge chamber 203. Preferably, the lower end of the lower material pipe 402 passes through the lower sealing plate 401 and extends downward to a depth of 1 to 30 cm, preferably 3 to 20 cm, and more preferably 5 to 15 cm.

[0051] Preferably, the lower discharge chamber 203 is designed as a top-down contraction type, and a material leveling hopper 7 is arranged in the lower discharge chamber 203. A plurality of material leveling hoppers 7 are evenly distributed in the lower discharge chamber 203 and connected to each other to form a horizontal grid structure.

[0052] Preferably, a multi-layer lattice structured material hopper 7 is arranged from top to bottom in the lower discharge chamber 203, and the number of the material hoppers 7 in the upper lattice structure is 1.5 to 3.5 times, preferably 1.8 to 3 times, the number of the material hoppers 7 in the lower lattice structure.

[0053] Preferably, the modified gas intake mechanism 5 includes an intake main pipe 501 and an intake branch pipe 502. A plurality of the intake branch pipes 502 are evenly distributed around the tower body 1, and the exhaust end of the intake branch pipe 502 is connected to the lower discharge chamber 203 at a position close to the lower surface of the lower material collector 4, and the intake end of the intake branch pipe 502 is connected to the intake main pipe 501. Preferably, the intake branch pipe 502 is tilted outside the tower body 1 in a manner that the airflow flows obliquely downward, and an intake grille is provided on the tower body 1 where the intake branch pipe 502 is connected to the lower discharge chamber 203.

[0054] Preferably, the modified gas exhaust mechanism 6 includes an exhaust main pipe 601 and an exhaust branch pipe 602. A plurality of the exhaust branch pipes 602 are evenly distributed around the tower body 1, and the exhaust end of the exhaust branch pipe 602 is connected to the position of the modified middle chamber 202 adjacent to the lower surface of the upper material collector 3, and the air inlet end of the exhaust branch pipe 602 is connected to the exhaust main pipe 601. Preferably, the exhaust branch pipe 602 is tilted outside the tower body 1 in a manner that the airflow flows obliquely upward, and an exhaust grille is provided on the tower body 1 where the exhaust branch pipe 602 is connected to the modified middle chamber 202.

[0055] Preferably, explosion-proof valves are independently provided on the air intake main pipe 501 and the exhaust main pipe 601 .

[0056] Preferably, a water cooling jacket 8 is further provided on the outer side of the tower body 1 corresponding to the lower discharge chamber 203 , a cooling water inlet 801 is provided at the lower part of the water cooling jacket 8 , and a cooling water outlet 802 is provided at the upper part of the water cooling jacket 8 .

[0057] Preferably, one or more temperature sensor interfaces 103 are independently provided on the tower body 1 corresponding to each of the feed upper chamber 201 , the modification middle chamber 202 and the discharge lower chamber 203 .

[0058] Preferably, air lock rotary valves are independently provided on the feed port 101 and the discharge port 102. An inspection door 104 is also provided on the tower body 1 corresponding to the modified middle chamber 202. Example 1

[0059] like Figure 1-6 As shown, a modification system for carbon-based purification materials includes a tower body 1 and an inner cavity 2. A feed port 101 is provided at the top of the tower body 1, and a discharge port 102 is provided at the bottom of the tower body 1. The inner cavity 2 is divided into an upper feed chamber 201, a modified middle chamber 202, and a discharge lower chamber 203 by an upper material collector 3 and a lower material collector 4. A modified gas inlet mechanism 5 is provided at the upper part of the tower body 1 at the discharge lower chamber 203, and a modified gas exhaust mechanism 6 is provided at the upper part of the tower body 1 at the modified middle chamber 202. Example 2

[0060] Example 1 is repeated, except that the upper material collector 3 includes an upper sealing plate 301 and an upper material passage 302. The upper sealing plate 301 is horizontally arranged at the junction of the feed upper chamber 201 and the modified middle chamber 202, and the upper sealing plate 301 is connected to the tower body 1 around the periphery. A plurality of upper material passages 302 are installed on the upper sealing plate 301 and connect the feed upper chamber 201 and the modified middle chamber 202. Example 3

[0061] Repeat Example 2, except that the plurality of upper material pipes 302 are evenly distributed on the upper sealing plate 301, specifically: the center point of the upper sealing plate 301 is taken as the center of the central upper material pipe 302, and then six upper material pipes 302 are arranged around the central upper material pipe 302 in a regular hexagonal distribution manner, and then six upper material pipes 302 of the same size are arranged around each upper material pipe 302 in the regular hexagonal distribution manner, and so on and so forth, gradually spreading outward. That is, the radial spacing between any two adjacent upper material pipes 302 is the same. Example 4

[0062] Example 3 is repeated, except that the diameter of the lumen of the upper feed pipe 302 is 35 mm. Example 5

[0063] Example 4 is repeated, except that the radial distance between any two adjacent upper feed pipes 302 is 6 mm. Example 6

[0064] Example 5 was repeated, except that the upper end of the upper material pipe 302 penetrated the upper sealing plate 301 and was flush with the upper surface of the upper sealing plate 301, and the lower end of the upper material pipe 302 penetrated the upper sealing plate 301 and extended downward into the modified middle chamber 202. The lower end of the upper material pipe 302 penetrated the upper sealing plate 301 and extended downward to a depth of 10 cm. Example 7

[0065] Example 6 is repeated, except that the lower material collector 4 includes a lower sealing plate 401 and a lower material pipe 402. The lower sealing plate 401 is horizontally arranged at the junction of the discharge lower chamber 203 and the modified middle chamber 202, and the surrounding of the lower sealing plate 401 is connected to the tower body 1. A plurality of lower material pipes 402 are installed on the lower sealing plate 401 and connect the discharge lower chamber 203 and the modified middle chamber 202. Example 8

[0066] Repeat Example 7, except that the plurality of lower feed pipes 402 are evenly distributed on the lower sealing plate 401, specifically: the center point of the lower sealing plate 401 is the center of the central lower feed pipe 402, and then six lower feed pipes 402 are arranged around the central lower feed pipe 402 in a regular hexagonal distribution manner, and then six lower feed pipes 402 of the same size are arranged around each lower feed pipe 402 in the regular hexagonal distribution manner, and so on and so forth, gradually spreading outward. That is, the radial spacing between any two adjacent lower feed pipes 402 is the same. Example 9

[0067] Example 8 is repeated, except that the lumen diameter of the lower feed pipe 402 is 25 mm. Example 10

[0068] Example 9 is repeated, except that the radial spacing between any two adjacent down pipes 402 is 5 mm. Embodiment 11

[0069] Example 10 was repeated, except that the upper end of the lower feed pipe 402 passed through the lower sealing plate 401 and was flush with the upper surface of the lower sealing plate 401, and the lower end of the lower feed pipe 402 passed through the lower sealing plate 401 and extended downward into the lower discharge chamber 203. The lower end of the lower feed pipe 402 passed through the lower sealing plate 401 and extended downward to a depth of 10 cm. Example 12

[0070] The embodiment 11 is repeated, except that the lower discharge chamber 203 is designed as a top-down contraction type, and a material hopper 7 is arranged in the lower discharge chamber 203. A plurality of material hoppers 7 are evenly distributed in the lower discharge chamber 203 and connected to each other to form a horizontal grid structure. Embodiment 13

[0071] Example 12 is repeated, except that multiple layers of material hoppers 7 of a masonry structure are arranged from top to bottom in the lower discharge chamber 203, and the number of material hoppers 7 in the upper masonry structure is twice the number of material hoppers 7 in the lower masonry structure. Embodiment 14

[0072] Example 13 is repeated, except that the modified gas intake mechanism 5 includes an intake main pipe 501 and an intake branch pipe 502. A plurality of the intake branch pipes 502 are evenly distributed around the tower body 1, and the exhaust end of the intake branch pipe 502 is connected to the lower discharge chamber 203 at a position close to the lower surface of the lower material collector 4, and the intake end of the intake branch pipe 502 is connected to the intake main pipe 501. The intake branch pipe 502 is tilted outside the tower body 1 in such a way that the airflow flows obliquely downward, and an intake grille is provided on the tower body 1 where the intake branch pipe 502 is connected to the lower discharge chamber 203. Embodiment 15

[0073] Example 14 is repeated, except that the modified gas exhaust mechanism 6 includes an exhaust main pipe 601 and an exhaust branch pipe 602. A plurality of the exhaust branch pipes 602 are evenly distributed around the tower body 1, and the exhaust end of the exhaust branch pipe 602 is connected to the position of the modified middle chamber 202 adjacent to the lower surface of the upper material collector 3, and the air inlet end of the exhaust branch pipe 602 is connected to the exhaust main pipe 601. The exhaust branch pipe 602 is tilted outside the tower body 1 in such a way that the airflow flows obliquely upward, and an exhaust grille is provided on the tower body 1 where the exhaust branch pipe 602 is connected to the modified middle chamber 202. Example 16

[0074] Example 15 is repeated, except that explosion-proof valves are independently provided on the air intake main pipe 501 and the exhaust main pipe 601. Embodiment 17

[0075] Example 16 is repeated, except that a water cooling jacket 8 is further provided on the outer side of the tower body 1 corresponding to the lower discharge chamber 203 , a cooling water inlet 801 is provided at the lower portion of the water cooling jacket 8 , and a cooling water outlet 802 is provided at the upper portion of the water cooling jacket 8 . Embodiment 18

[0076] Example 17 is repeated, except that one or more temperature sensor interfaces 103 are independently provided on the tower body 1 corresponding to each of the feed upper chamber 201 , the modification middle chamber 202 and the discharge lower chamber 203 . Embodiment 19

[0077] Example 18 was repeated, except that air lock rotary valves were independently provided on the feed port 101 and the discharge port 102. An inspection door 104 was also provided on the tower body 1 corresponding to the modified middle chamber 202.

Claims

1. A modification system for carbon-based purification materials, characterized in that: The system comprises a tower body (1) and an inner cavity (2); a feed port (101) is provided at the top of the tower body (1), and a discharge port (102) is provided at the bottom of the tower body (1); the inner cavity (2) is divided into a feed upper chamber (201), a modified middle chamber (202) and a discharge lower chamber (203) by an upper material collector (3) and a lower material collector (4); a modified gas inlet mechanism (5) is provided at the upper part of the tower body (1) located at the discharge lower chamber (203), and a modified gas exhaust mechanism (6) is provided at the upper part of the tower body (1) located at the modified middle chamber (202).

2. The system according to claim 1, characterized in that: The upper material collector (3) comprises an upper sealing plate (301) and an upper material passage pipe (302); the upper sealing plate (301) is horizontally arranged at the junction of the feed upper chamber (201) and the modified middle chamber (202), and the upper sealing plate (301) is connected to the tower body (1) on all sides; a plurality of upper material passage pipes (302) are installed on the upper sealing plate (301) and connect the feed upper chamber (201) and the modified middle chamber (202).

3. The system according to claim 2, characterized in that: The plurality of upper material passing pipes (302) are evenly distributed on the upper sealing plate (301), specifically: the center point of the upper sealing plate (301) is taken as the center of the circle of the central upper material passing pipe (302), and then six upper material passing pipes (302) are arranged around the central upper material passing pipe (302) in a regular hexagonal distribution manner, and then six upper material passing pipes (302) are arranged around each upper material passing pipe (302) in the regular hexagon in a regular hexagonal distribution manner of the same size, and so on and so forth, gradually spreading outward; that is, the radial spacing between any two adjacent upper material passing pipes (302) is the same.

4. The system according to claim 3, characterized in that: The diameter of the lumen of the upper feed pipe (302) is 20 to 300 mm; and / or The radial distance between any two adjacent upper feed pipes (302) is 0 to 100 mm.

5. The system according to claim 4, characterized in that: The diameter of the lumen of the upper feed pipe (302) is 30 to 200 mm; and / or The radial distance between any two adjacent upper material passages (302) is 3 to 50 mm.

6. The system according to claim 5, characterized in that: The diameter of the lumen of the upper feed pipe (302) is 50 to 100 mm; and / or The radial distance between any two adjacent upper feed pipes (302) is 5 to 20 mm.

7. The system according to claim 2, characterized in that: The upper end of the upper material passage (302) passes through the upper sealing plate (301) and is flush with the upper surface of the upper sealing plate (301), and the lower end of the upper material passage (302) passes through the upper sealing plate (301) and extends downward into the modified middle chamber (202).

8. The system according to claim 7, characterized in that: The lower end of the upper material passage (302) penetrates the upper sealing plate (301) and extends downward to a depth of 1 to 30 cm.

9. The system according to claim 8, characterized in that: The lower end of the upper material passage (302) penetrates the upper sealing plate (301) and extends downward to a depth of 3 to 20 cm.

10. The system according to claim 9, characterized in that: The lower end of the upper material passage (302) penetrates the upper sealing plate (301) and extends downward to a depth of 5 to 15 cm.

11. The system according to any one of claims 1 to 10, characterized in that: The lower material collector (4) comprises a lower sealing plate (401) and a lower material passage pipe (402); the lower sealing plate (401) is horizontally arranged at the junction of the discharge lower chamber (203) and the modified middle chamber (202), and the four sides of the lower sealing plate (401) are connected to the tower body (1); a plurality of the lower material passage pipes (402) are installed on the lower sealing plate (401) and connect the discharge lower chamber (203) and the modified middle chamber (202).

12. The system according to claim 11, characterized in that: The plurality of lower feed pipes (402) are evenly distributed on the lower sealing plate (401), specifically: the center point of the lower sealing plate (401) is taken as the center of the circle of the central lower feed pipe (402), and then six lower feed pipes (402) are arranged around the central lower feed pipe (402) in a regular hexagonal distribution manner, and then six lower feed pipes (402) are arranged around each lower feed pipe (402) in the regular hexagon in a regular hexagonal distribution manner of the same size, and so on and so forth, gradually spreading outward; that is, the radial spacing between any two adjacent lower feed pipes (402) is the same.

13. The system according to claim 12, characterized in that: The diameter of the lumen of the lower feed pipe (402) is 20 to 300 mm; and / or The radial distance between any two adjacent lower feed pipes (402) is 0 to 100 mm.

14. The system according to claim 13, characterized in that: The diameter of the lumen of the lower feed pipe (402) is 30 to 200 mm; and / or The radial distance between any two adjacent lower feed pipes (402) is 3 to 50 mm.

15. The system according to claim 14, characterized in that: The diameter of the lumen of the lower feed pipe (402) is 50 to 100 mm; and / or The radial distance between any two adjacent lower feed pipes (402) is 5 to 20 mm.

16. The system according to claim 11, characterized in that: The upper end of the lower material passage (402) passes through the lower sealing plate (401) and is flush with the upper surface of the lower sealing plate (401), and the lower end of the lower material passage (402) passes through the lower sealing plate (401) and extends downward into the lower discharge chamber (203).

17. The system according to claim 16, characterized in that: The lower end of the lower material passage (402) penetrates through the lower sealing plate (401) and extends downward to a depth of 1 to 30 cm.

18. The system according to claim 16, characterized in that: The lower end of the lower material passage (402) passes through the lower sealing plate (401) and extends downward to a depth of 3 to 20 cm.

19. The system according to claim 16, characterized in that: The lower end of the lower material passage (402) passes through the lower sealing plate (401) and extends downward to a depth of 5 to 15 cm.

20. The system according to any one of claims 1-10, 12-19, characterized in that: The lower discharge chamber (203) is designed to be tapered from top to bottom, and a material hopper (7) is arranged in the lower discharge chamber (203); a plurality of material hoppers (7) are evenly distributed in the lower discharge chamber (203) and are connected to each other to form a horizontal grid structure.

21. The system according to claim 20, characterized in that: Multiple layers of material hoppers (7) of a masonry structure are arranged from top to bottom in the lower discharge chamber (203), and the number of material hoppers (7) in the upper masonry structure is 1.5 to 3.5 times the number of material hoppers (7) in the lower masonry structure.

22. The system according to claim 21, characterized in that: The number of the material hoppers (7) in the upper layer of the masonry structure is 1.8 to 3 times the number of the material hoppers (7) in the lower layer of the masonry structure.

23. The system according to any one of claims 1-10, 12-19, 21-22, characterized in that: The modified gas intake mechanism (5) comprises an intake main pipe (501) and an intake branch pipe (502); a plurality of the intake branch pipes (502) are evenly distributed around the tower body (1), and the exhaust ends of the intake branch pipes (502) are connected to the lower discharge chamber (203) at a position close to the lower surface of the lower material collector (4), and the intake ends of the intake branch pipes (502) are all connected to the intake main pipe (501); and / or The modified gas exhaust mechanism (6) comprises an exhaust main pipe (601) and an exhaust branch pipe (602); a plurality of the exhaust branch pipes (602) are evenly distributed around the tower body (1), and the exhaust ends of the exhaust branch pipes (602) are connected to the modified middle chamber (202) at a position close to the lower surface of the upper material collector (3), and the air inlet ends of the exhaust branch pipes (602) are connected to the exhaust main pipe (601).

24. The system according to claim 23, characterized in that: The air intake branch pipe (502) is arranged outside the tower body (1) in a manner such that the air flow flows obliquely downward, and an air intake grille is arranged on the tower body (1) where the air intake branch pipe (502) is connected to the lower discharge chamber (203); and / or The exhaust branch pipe (602) is arranged outside the tower body (1) in an inclined manner so that the airflow flows obliquely upward, and an exhaust grille is arranged on the tower body (1) where the exhaust branch pipe (602) is connected to the modified middle chamber (202).

25. The system according to claim 23, characterized in that: Explosion-proof valves are independently provided on the air intake main pipe (501) and the exhaust main pipe (601).

26. The system according to any one of claims 1-10, 12-19, 21-22, 24-25, characterized in that: A water cooling jacket (8) is further provided on the outer side of the tower body (1) corresponding to the lower discharge chamber (203), a cooling water inlet (801) is provided at the lower part of the water cooling jacket (8), and a cooling water outlet (802) is provided at the upper part of the water cooling jacket (8); and / or One or more temperature sensor interfaces (103) are independently arranged on the tower body (1) corresponding to each of the feed upper chamber (201), the modified middle chamber (202) and the discharge lower chamber (203); and / or An air-locking rotary valve is independently provided on the feed port (101) and the discharge port (102); and an inspection door (104) is also provided on the tower body (1) corresponding to the modified middle chamber (202).

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